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Ozone Water Treatment Application and Design American Society of Plumbing EngineersSeminar  19 February 2009 Anthony Sacco Spartan Environmental Technologies, LLC 440-368-3563 [email_address] www.SpartanWaterTreatment.com
Ozone Water Treatment -  Application and Design: Topics for Today’s Talk ,[object Object],[object Object],[object Object],[object Object]
Spartan Environmental Technologies, LLC ,[object Object],[object Object],[object Object],[object Object],[object Object]
Spartan Supplies a Broad Range of Ozone Generator Systems, Components and Services ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
What is Ozone ,[object Object],[object Object],[object Object]
How is ozone made? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Ozone Generators 500 lb/day Ozone Generator Water Cooled 5 lb/day Air Cooled Ozone Generator
Ozone’s properties  provides multiple benefits in water treatment: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Photo Courtesy of SNWA
Ozone disinfects by destroying cell structure of  bacteria, viruses, cysts and parasites:
 
Ct Values (mg x min./L) For 99.9 %  Inactivation of Giardia and 99.99%Virus Taken from: “Optimizing Water Treatment Plant Performance Using Composite Correction Program.” prepared by Process Applications, Inc., for the U.S. EPA, Office of Drinking Water, Cincinnati, Ohio.  Data for 5°C
Microflocculation ,[object Object],[object Object],[object Object],[object Object],[object Object]
Microflocculation
[object Object],[object Object],[object Object],[object Object],Organic Color Reduction Textile Mill Wastewater Treated with Ozone
Taste & Odor ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Because of its various biocide and oxidation properties ozone has many applications in water treatment: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
Ozonation of Bottled Water ,[object Object],[object Object],[object Object],[object Object],Champaign Springs Water Company
Industrial Wastewater Treatment ,[object Object],[object Object],[object Object],[object Object]
Cooling Water Treatment ,[object Object],[object Object],[object Object],[object Object],[object Object]
Rainwater harvesting prevents the loss of a valuable natural resource: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Components of an Ozone System Feed-Gas Supply Options (Select 1) Ozone Generator Power Supply Unit O 3  % wt Flow Meter Ozone Generation Blower O 3  Destruct Off-Gas Flow Control Valve M Ozone Contacting Options (Select 1) Flow Meter Ambient Air Supply Air   O 2 Purchased LOX CRYO  O 2  System PSA O 2  System VPSA O 2  System Moisture Removal  System O 2 O 2 O 2 Injection Ozone Contactor Bubble Diffuser Ozone Contactor
Design considerations for ozone water treatment systems: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Ozone generator elements that promote reliability: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
From Air to Oxygen: Pre-1987, 1987 to 1993 and Post 1993 0 1 2 3 4 5 6 7 8 9 10 0 1 2 3 4 5 6 7 8 9 10 11 12 Ozone Concentration, %wt Specific Energy, kWh/lb Low Frequency Air-fed Medium Frequency Air-fed Medium Frequency  Oxygen-fed Medium Frequency  High Efficiency  Oxygen-fed 2.2 6.6 8.8 13.2 17.6 15.4 10.0 4.4 kWh/kg
 
PSA System Configuration
Ozone Transfer Efficiency: Getting ozone into solutions: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
Ozone Dissolution Options Historically, the most common  ozone contacting option Bubble Diffuser Side Stream For many reasons, the side stream option is becoming more popular today High Efficiency  Venturi Injectors o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o o  o - - - - Ozone Water Flow G L
Option 1 - Designed to maximize ozone transfer within the side stream flow From Ozone Generators Sidestream Pump Degas  Vessel Venturi Injector Liquid Trap M Heater Ozone Destruct To Atmosphere FM M Check Valve Pressure Control Gas flow control valve Fail-close Shut-off Valve M P s High Pressure Switch Pressure Control (Optional) Water Flow FM Mixing-enhancement  nozzles P P P P P P P P
Option 2 - Designed to utilize ozone contactor  for ozone transfer assistance From Ozone Generators Sidestream Pump Venturi Injector Liquid Trap M Heater Destruct To Atmosphere FM M Check Valve Gas flow control valve Fail-close Shut-off Valve M P s High Pressure Switch Water Flow FM Mixing-enhancement  nozzles P P P P P P G L
Ozone Generator Control Through Ozone Residual Monitoring:  ,[object Object],[object Object],Display Range: 0-200.0 PPB, 0-2.000 PPM  Accuracy: ± 0.02 PPM or 0.5% of F.S. Repeatability: ± 0.01 PPM or 0.3% of F.S. Linearity: 0.1% of F.S. Zero Drift: < 0.01 PPM per month
Materials of construction that provide excellent to good performance with ozone: ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
International Ozone Association www.io3a.org   Joint IOA & IUVA Conference 04 – 06 May 2009 Boston, MA Anthony Sacco Spartan Environmental Technologies, LLC 440-368-3563 [email_address] www.SpartanWaterTreatment.com

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Aspe Presentation 02 17 09

  • 1. Ozone Water Treatment Application and Design American Society of Plumbing EngineersSeminar 19 February 2009 Anthony Sacco Spartan Environmental Technologies, LLC 440-368-3563 [email_address] www.SpartanWaterTreatment.com
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  • 7. Ozone Generators 500 lb/day Ozone Generator Water Cooled 5 lb/day Air Cooled Ozone Generator
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  • 9. Ozone disinfects by destroying cell structure of bacteria, viruses, cysts and parasites:
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  • 11. Ct Values (mg x min./L) For 99.9 % Inactivation of Giardia and 99.99%Virus Taken from: “Optimizing Water Treatment Plant Performance Using Composite Correction Program.” prepared by Process Applications, Inc., for the U.S. EPA, Office of Drinking Water, Cincinnati, Ohio. Data for 5°C
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  • 22. Components of an Ozone System Feed-Gas Supply Options (Select 1) Ozone Generator Power Supply Unit O 3 % wt Flow Meter Ozone Generation Blower O 3 Destruct Off-Gas Flow Control Valve M Ozone Contacting Options (Select 1) Flow Meter Ambient Air Supply Air O 2 Purchased LOX CRYO O 2 System PSA O 2 System VPSA O 2 System Moisture Removal System O 2 O 2 O 2 Injection Ozone Contactor Bubble Diffuser Ozone Contactor
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  • 25. From Air to Oxygen: Pre-1987, 1987 to 1993 and Post 1993 0 1 2 3 4 5 6 7 8 9 10 0 1 2 3 4 5 6 7 8 9 10 11 12 Ozone Concentration, %wt Specific Energy, kWh/lb Low Frequency Air-fed Medium Frequency Air-fed Medium Frequency Oxygen-fed Medium Frequency High Efficiency Oxygen-fed 2.2 6.6 8.8 13.2 17.6 15.4 10.0 4.4 kWh/kg
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  • 30. Ozone Dissolution Options Historically, the most common ozone contacting option Bubble Diffuser Side Stream For many reasons, the side stream option is becoming more popular today High Efficiency Venturi Injectors o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o o - - - - Ozone Water Flow G L
  • 31. Option 1 - Designed to maximize ozone transfer within the side stream flow From Ozone Generators Sidestream Pump Degas Vessel Venturi Injector Liquid Trap M Heater Ozone Destruct To Atmosphere FM M Check Valve Pressure Control Gas flow control valve Fail-close Shut-off Valve M P s High Pressure Switch Pressure Control (Optional) Water Flow FM Mixing-enhancement nozzles P P P P P P P P
  • 32. Option 2 - Designed to utilize ozone contactor for ozone transfer assistance From Ozone Generators Sidestream Pump Venturi Injector Liquid Trap M Heater Destruct To Atmosphere FM M Check Valve Gas flow control valve Fail-close Shut-off Valve M P s High Pressure Switch Water Flow FM Mixing-enhancement nozzles P P P P P P G L
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  • 35. International Ozone Association www.io3a.org Joint IOA & IUVA Conference 04 – 06 May 2009 Boston, MA Anthony Sacco Spartan Environmental Technologies, LLC 440-368-3563 [email_address] www.SpartanWaterTreatment.com