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Nanoscience and Energy
      Lecture 3
Energy and Nanotechnology
Lecture 3.        Energy and Nanotechnology
             Review of Alternate Energy
             Sources
             Review of Electronic Properties of
             Solids:
             Free- electron Fermi gas
             Energy bands in Solids
             Semiconductors and doping
             pn junctions
             Amorphous semiconductors
Gb/yr

30

25                                   Rest of World


20
                                         Middle East
15
                              E-Europe/Asia
10                                     W-Europe
                      USA
 5

 0                     Year


     30 40    50 60    70 80             90       0    10 20
Societal Drivers - Fossil Fuel Depletion
     D.E.Carlson, BP Solar




 World oil discovery rates declined since early 1960s; oil is
  consumed ~ 4 X greater rate than discovery rate.

                             John A. Woollam, PV talk UNL 2007
Societal Drivers - Fossil Fuel Depletion
D.E.Carlson, BP Solar




   Laherrere (2001): world oil production peaks ~ 2010.
   Natural gas by ~ 2030.
                        John A. Woollam, PV talk UNL 2007
BioMass


 •   In 2003 — and for the fourth year in a row — biomass was the
     leading source of renewable energy in the United States, providing
     2.9 Quadrillion Btu of energy. Biomass was the source for 47% of all
     renewable energy or 4% of the total energy produced in the United
     States). Agriculture and forestry residues, and in particular residues
     from paper mills, are the most common biomass resources used for
     generating electricity, and industrial process heat and steam and
     for a variety of biobased products. These are the organic
     byproducts of food, fiber, and forest production. In fact, 48% or 1.1
     Quad Btu of biomass energy was consumed by the pulp and paper
     industry, solely using black liquor. Current biomass consumption in
     the United States is dominated by industrial use, largely derived
     from wood. Use of liquid transportation fuels such as ethanol and
     biodiesel, however, currently derived primarily from agricultural
     crops, is increasing dramatically. In 2003 ethanol produced from
     corn reached 2.81 billion gallons.
Hydropower


    With 80,000 megawatts of generating
    capacity, hydropower is the nation's
    largest renewable electricity source.
    Working with industry, the Wind and
    Hydropower Technologies Program
    pursues R&D to develop more
    environmentally friendly
    technologies to maintain the nation's
    existing hydropower capacity.
Solar irradiation in the USA

Shown is the average
radiation received on a
horizontal surface
across the continental
United States in the
month of June. Units
are in kWh/m2




                                   Clemson Summer School
  6.6.06 - 8.6.06           Dr. Karl Molter / FH Trier / molter@fh-   23
                                            trier.de
Solar Irradiation worlwide
                    (kWh/m² a) on horizontal surface




                                Clemson Summer School
6.6.06 - 8.6.06          Dr. Karl Molter / FH Trier / molter@fh-   24
                                         trier.de
ENERGIA EOLICA
LA CONVERSION DE LA FUERZA
DEL    VIENTO  A   ENERGIA
ELECTRICA       EMPLEANDO
AEROGENERADORES
ENERIA EOLICA ES UNA DE LAS
MAS BARATAS DE DIFERENTES
FORMAS       DE     ENERGIA
RENOVABLE
Wind Energy

•   In 2005, the United States installed more new wind
    energy capacity than any other country in the world.
    The new capacity, totaling 2,431 megawatts (MW), was
    worth more than $3 billion in generating equipment,
    and it brought the total national wind energy capacity
    to 9,149 MW. That's enough electricity to power 2.3
    million average American households. In 2006, an
    additional 2,454 MW were installed, bringing the
    Nation's total installed capacity to 11,603 MW.
Centralized Solar Power
Review of Electronic Properties of
              Solids
     Free Electron Fermi Gas
Energy Bands, Semiconductors,
           Doping
Hydrogen Molecule
energy-states in solids:
                             Band-Pattern



                  Atom           Molecule/Solid
                                                                        • • • • • • • •
 energy-states




                                     Clemson Summer School
6.6.06 - 8.6.06               Dr. Karl Molter / FH Trier / molter@fh-                     46
                                              trier.de
energy-states in solids:
                                 Insulator
electron-energy
                                                                          conduction-band




                Fermi-                                                       bandgap EG
                level EF                                                     (> 5 eV)




                                                                          valence-band


                                       Clemson Summer School
   6.6.06 - 8.6.06              Dr. Karl Molter / FH Trier / molter@fh-                   47
                                                trier.de
Figure 9.12. A valence electron jumping across the energy gap in pure
silicon resulting in the generation of a free electron and hole in the crystal:
                   (a) energy band model, (b) bond model.
Figure 9.13. Extrinsic n-type silicon doped with P donor atoms. (a) Energy
                    band diagram and (b) Bond model.
Figure 9.14. Extrinsic p-type silicon doped with B acceptor atoms. (a)
              Energy band diagram and (b) Bond model.
energy-states in solids :
                             metal / conductor
electron-energy




                Fermi-
                level EF


                                                                          conduction-band


                                       Clemson Summer School
   6.6.06 - 8.6.06              Dr. Karl Molter / FH Trier / molter@fh-                 53
                                                trier.de
energy-states in solids:
                              semiconductor
electron-energy


                                                                          conduction-band




                Fermi-                                                       bandgap EG
                level EF                                                     ( 0,5 – 2 eV)




                                                                          valence-band


                                       Clemson Summer School
   6.6.06 - 8.6.06              Dr. Karl Molter / FH Trier / molter@fh-                   54
                                                trier.de
Figure 9.11. (a) Energy levels in an isolated silicon atom and (b) in a
silicon crystal of N atoms, illustrating the formation of energy bands. The
  valence band contains 4N states and can accommodate all 4N valence
                                  electrons.
pn Junctions
Amorphous Semiconductors
2012 tus lecture 3
2012 tus lecture 3
2012 tus lecture 3

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2012 tus lecture 3

  • 1. Nanoscience and Energy Lecture 3 Energy and Nanotechnology
  • 2. Lecture 3. Energy and Nanotechnology Review of Alternate Energy Sources Review of Electronic Properties of Solids: Free- electron Fermi gas Energy bands in Solids Semiconductors and doping pn junctions Amorphous semiconductors
  • 3.
  • 4. Gb/yr 30 25 Rest of World 20 Middle East 15 E-Europe/Asia 10 W-Europe USA 5 0 Year 30 40 50 60 70 80 90 0 10 20
  • 5.
  • 6. Societal Drivers - Fossil Fuel Depletion D.E.Carlson, BP Solar  World oil discovery rates declined since early 1960s; oil is consumed ~ 4 X greater rate than discovery rate. John A. Woollam, PV talk UNL 2007
  • 7. Societal Drivers - Fossil Fuel Depletion D.E.Carlson, BP Solar  Laherrere (2001): world oil production peaks ~ 2010.  Natural gas by ~ 2030. John A. Woollam, PV talk UNL 2007
  • 8.
  • 9.
  • 10.
  • 11.
  • 12.
  • 13.
  • 14.
  • 15.
  • 16. BioMass • In 2003 — and for the fourth year in a row — biomass was the leading source of renewable energy in the United States, providing 2.9 Quadrillion Btu of energy. Biomass was the source for 47% of all renewable energy or 4% of the total energy produced in the United States). Agriculture and forestry residues, and in particular residues from paper mills, are the most common biomass resources used for generating electricity, and industrial process heat and steam and for a variety of biobased products. These are the organic byproducts of food, fiber, and forest production. In fact, 48% or 1.1 Quad Btu of biomass energy was consumed by the pulp and paper industry, solely using black liquor. Current biomass consumption in the United States is dominated by industrial use, largely derived from wood. Use of liquid transportation fuels such as ethanol and biodiesel, however, currently derived primarily from agricultural crops, is increasing dramatically. In 2003 ethanol produced from corn reached 2.81 billion gallons.
  • 17. Hydropower With 80,000 megawatts of generating capacity, hydropower is the nation's largest renewable electricity source. Working with industry, the Wind and Hydropower Technologies Program pursues R&D to develop more environmentally friendly technologies to maintain the nation's existing hydropower capacity.
  • 18.
  • 19.
  • 20.
  • 21.
  • 22.
  • 23. Solar irradiation in the USA Shown is the average radiation received on a horizontal surface across the continental United States in the month of June. Units are in kWh/m2 Clemson Summer School 6.6.06 - 8.6.06 Dr. Karl Molter / FH Trier / molter@fh- 23 trier.de
  • 24. Solar Irradiation worlwide (kWh/m² a) on horizontal surface Clemson Summer School 6.6.06 - 8.6.06 Dr. Karl Molter / FH Trier / molter@fh- 24 trier.de
  • 25. ENERGIA EOLICA LA CONVERSION DE LA FUERZA DEL VIENTO A ENERGIA ELECTRICA EMPLEANDO AEROGENERADORES ENERIA EOLICA ES UNA DE LAS MAS BARATAS DE DIFERENTES FORMAS DE ENERGIA RENOVABLE
  • 26. Wind Energy • In 2005, the United States installed more new wind energy capacity than any other country in the world. The new capacity, totaling 2,431 megawatts (MW), was worth more than $3 billion in generating equipment, and it brought the total national wind energy capacity to 9,149 MW. That's enough electricity to power 2.3 million average American households. In 2006, an additional 2,454 MW were installed, bringing the Nation's total installed capacity to 11,603 MW.
  • 28.
  • 29.
  • 30. Review of Electronic Properties of Solids Free Electron Fermi Gas
  • 31.
  • 32.
  • 33.
  • 34.
  • 35.
  • 36.
  • 39.
  • 40.
  • 41.
  • 42.
  • 43.
  • 44.
  • 45.
  • 46. energy-states in solids: Band-Pattern Atom Molecule/Solid • • • • • • • • energy-states Clemson Summer School 6.6.06 - 8.6.06 Dr. Karl Molter / FH Trier / molter@fh- 46 trier.de
  • 47. energy-states in solids: Insulator electron-energy conduction-band Fermi- bandgap EG level EF (> 5 eV) valence-band Clemson Summer School 6.6.06 - 8.6.06 Dr. Karl Molter / FH Trier / molter@fh- 47 trier.de
  • 48.
  • 49. Figure 9.12. A valence electron jumping across the energy gap in pure silicon resulting in the generation of a free electron and hole in the crystal: (a) energy band model, (b) bond model.
  • 50. Figure 9.13. Extrinsic n-type silicon doped with P donor atoms. (a) Energy band diagram and (b) Bond model.
  • 51. Figure 9.14. Extrinsic p-type silicon doped with B acceptor atoms. (a) Energy band diagram and (b) Bond model.
  • 52.
  • 53. energy-states in solids : metal / conductor electron-energy Fermi- level EF conduction-band Clemson Summer School 6.6.06 - 8.6.06 Dr. Karl Molter / FH Trier / molter@fh- 53 trier.de
  • 54. energy-states in solids: semiconductor electron-energy conduction-band Fermi- bandgap EG level EF ( 0,5 – 2 eV) valence-band Clemson Summer School 6.6.06 - 8.6.06 Dr. Karl Molter / FH Trier / molter@fh- 54 trier.de
  • 55.
  • 56. Figure 9.11. (a) Energy levels in an isolated silicon atom and (b) in a silicon crystal of N atoms, illustrating the formation of energy bands. The valence band contains 4N states and can accommodate all 4N valence electrons.
  • 58.
  • 59.
  • 60.