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Fibre, Nylon &
Polyester
Presented by:
 Noor Azurah Abdul Razak
(20101037502)
 Wan Norazwani Mahusin
(D20101037506)
 Ira Nusrat Jaafar
(D20101037533)
Lecturer : Dr Noorsyida
Fibre
• Fibres are the base unit
of all textile materials
and products.
• They are slender thread-
like structures that can
be spun into yarns and
thread, and woven,
knitted or felted into
materials.
Wool Fibres
CottonFibres
Fibre Classifications
Man-made Fibre
- Synthetic Fibre
-Regenerated
Fibre
Natural
Fibre
 Composed of atoms of various elements, such as
carbon, hydrogen, oxygen, sometimes of nitrogen
and other elements (sulphur) in lower quantities
 Come from plants, animals and minerals.
 Have short fibres, called staple fibres.
 The exception to this rule is silk, a natural fibre
whose continuous filaments are up to one
kilometre in length.
Sources of natural fibres
• Cotton from the cotton plant
• Linen from the flax plant
• Wool from sheep
• Silk from silkworms
Natural Fibres
 Cotton
 Linen/Flax
 Hemp
Hemp
1) Plant Fibres - Cellulose Fibres
Flax
Cotton
2) Animal Fibres – Protein
Fibres
 Silk
 Wool
 Alpaca
 Angora/Mohair
Angora
Alpaca Silk
Man-made Fibres
 Man is involved in the actual fibre
formation process.
 Synthetic fibres and regenerated fibres
are man-made, usually from chemical
and natural polymer sources.
 Continuous filament fibres: Fibres are
long and do not always have to be spun
into yarn.
Sources of synthetic fibres
• Viscose comes from pine trees or
petrochemicals.
• Acrylic, nylon and polyester come from
oil and coal.
Viscose
 Slick and abrasion resistant
 Strong and resilient
 Resistant to most common fibre
degradants: sunlight (except for
nylon)
 Flame resistance varies widely
 Low density
 Non-biodegradable
Common Properties
Man-made – Synthetic Fibres
• Fibers made by chemical
synthesis are often called
synthetic fibers.
• Examples:
 Polyester
 Acrylic
 Lycra
 Nylon
Polyester
Nylon
Man-made – Regenerated Fibres
 Fibres regenerated
from natural
polymer sources.
 Examples:
 Rayon
 Acetate
Acetate
Rayon
Common Manufacturing
Process
o Polymerization (poly condensation or
poly- addition)
o Spinning
o Drawing
Polymerization
• Process of macromolecules formation through repetition
of basic units (synthesis fibres).
• Activated and controlled during the process by various
parameters: Temperature, pressure, catalysers and
reaction stabilizers
• Two mechanisms of chemical reaction available for the
synthesis of linear polymers:
 Poly-condensation - two molecules of same type or of
different types are joined together to form macromolecules
by removing simple secondary products as water,
hydrochloric acid, alcohol.
 Poly-addition - joins together several molecules and
redistributes the valence links existing in the monomers,
however without removing secondary products.
Spinning
• The term spinning defines the extrusion process through
spinnerets of fluid polymer masses which are able to solidify
in a continuous flow.
• The polymer processing from the solid to the fluid state can
take place with two methods:
Melting: applied on thermoplastic polymers which
show stable performances at the processing
temperatures (used by 70% of the fibres)
Solution: the polymer is solved in variable
concentrations according to the kind of polymer and of
solvent, anyhow such as to produce a sufficiently
viscous liquid. (used by 30% of the fibres)
Drawing
• The polymer extruded by the spinnerets in
form of filaments has not yet the properties
which are typical of a textile fibre: poor
thermal and chemical stability, low resistance
to ageing, high plasticity
• To develop strength, pliability, toughness, and
elasticity properties.
Issue 1: Silk Production Causes
Painful Death for Insects
• Silkworm is a domesticated insect.
• Undergoes stages of metamorphosis: egg,
larva, pupa, and adult.
• Silk derived from the cocoons of larvae. Most
of the insects raised by the industry don’t live
past the pupa stage
• They are steamed or gassed alive in their
cocoons. Approximately 3,000 silkworms are
killed to make every pound of silk.
NYLON
18
• belonging to a class of polymers
called polyamides
• It is made of repeating units linked
by amide bonds and is frequently
referred to as polyamide
• Developed in the 1930s as an
alternative to silk
• Developed by Wallace Carothers at
the Dupont Chemical company
19
General Properties of Nylon
• Functional group is amide
• Light in weight
• Incredible tensile strength
• Durability
• Resistance to damage
• Takes dye easily
• Absorbs most water
• Greater stretchability
• Dries slower
• smoother and softer fabric than
polyester
• Somewhat UV resistant
20
Type of Nylon and its Manufacture
• In nylon, the repeating units contain
chains of carbon atoms.
• There are various different types of nylon
depending on the nature of those chains
for example:
– Nylon-6,6
– Nylon-6
21
22
Nylon-6,6
• synthesised by polycondensation of
hexamethylenediamine and adipic acid.
Nylon -6,6
23
Reactor Evaporator
Reaction
Vessel
Spinning
Process
24
• Hexamethylene diamine and adipic acid are combined with water in a
reactor. This produces nylon salt.
• The nylon salt is then sent to an evaporator where excess water is
removed.
• The nylon salt goes into a reaction vessel where a continuous
polymerization process takes place. This chemical process makes molten
nylon 6-6.
• The molten nylon -6,6 undergoes a spinning process, where the nylon 6-6
is extruded and sent through a spinneret, which is a small metal plate
with fine holes.
• The nylon is then air-cooled to form filaments.
25
Uses of Nylons
• Synthetic replacement for silk
• It replaced silk in military applications
such as parachutes and flak
vests, and was used in many types of
vehicle tires.
• Used in many applications, including
fabrics, bridal veils, carpets, musical
strings, and rope.
26
Carpets
27
Tyres
Air bags
28
Ropes Zip ties
Hoses
conveyor belts
29
Guitar Nut
30
Toothbrush
31
Parachutes
32
Bridal veils
Flak vest
33
ISSUE 2:
ADVANCED MATERIAL Artificial
Muscles From Fishing Line And Thread
34
35
• Artificial muscles have been crafted out of materials including
metal wires and carbon nanotubes, but they have proven to be
costly to make and tricky to control.
• According to research published in the journal Science on 20th
February 2014, these scientists instead turned to high-strength
polymer fibres made of polyethylene and nylon, materials found
in everyday items like fishing line and sewing thread. They
twisted the fibres into very tight coils and used changes in
temperature to make the artificial muscles contract and relax.
36
POLYESTER
The name "polyester“ (aka Terylene) refers
to the linkage of several monomers (esters)
within the fibre.
37
Esters are formed when alcohol reacts
with a carboxylic acid:
Example :
38
Forms of
Polyester
Filament
Staple
Tow
Fiberfill
39
filament form :
polyester fiber continuous in
length, producing smooth-surfaced fabrics
Staple form :
filaments are cut to short, predetermined
lengths.
easier to blend with other fibers
Tow :
A form in which continuous filament are
drawn loosely together
Fiberfill :
the voluminous form used in the manufacture of pillows
and outerwear
40
41
Different Structures Of Polyester
42
o Colorless and transparent
o Smooth and lustrous
o Shape as we require
o Shiny glass rod like
43
Characteristics of
polyester
Strong
Very durable
Resistant to stretching and shrinking
Quick drying
Wrinkle resistant
Mildew resistant
Retains its shape good for making outdoor
clothing
Easily washed
44
Manufacturing Polyester
Polymerization Spinning Drawing
45
46
Drawing
• when polyester emerges from the spinneret, it is soft and
easily elongated up to 5 times its original length.
• This helps to reduce the fibre width.
• This fibre is now ready and would into cones as filaments. It
can also be crimped and cut into staple lengths as per
requirement
47
Some Major
Polyester Fibre Uses
Apparel: Every form of clothing
Home Furnishings: Carpets, curtains, draperies, sheets
and pillow cases, wall coverings
Other Uses: hoses, power belting, ropes and
nets, thread, tire cord, auto upholstery, sails, floppy disk
liners, and fiberfill for various products including pillows
and furniture
48
49
Issue 3: Advanced
material
of polyester
Transforming
plastic bottles
into polyester
fabric
50
51
Comparison
Between
Polyester
and Nylon
52
Nylon Polyester
Functional group is amide Functional group is ester
Absorbs most water Absorbs some water
Greater stretchability Resistant to stretching
Dries slower Dries quickly
smoother and softer fabric than
polyester
polyester has always been a
rougher fabric than nylon
Somewhat UV resistant More UV resistant
lightweight and durable synthetic fabrics
Mildew resistant
53
Let’s play the
game 
54
Q1: What are the base unit of all textile
materials and products?
55
Answer: Fibre
Q2 : State 2 classifications of fibre
56
Ans: Man-made & Natural
Fibre
Q3 : State 3 common manufacturing
process of fibre
57
Ans:
•Polymerization
(polycondensation or poly-
addition)
•Spinning
•Drawing
Q4 : Give 2 example of synthetic fibres
58
Ans:
•Nylon
•Polyester
•Acrylic
•Lycra
Q5 : Name 4 forms of polyester
59
Ans:
• Filament
•Staple
•Tow
•Fiberfill
Q6 : What is the functional group for
polyester?
60
Ans:
• Ester
Q7 : Gives 2 type of nylon
61
Ans:
• Nylon -6
•Nylon -6,6
Q8 : What is the product when alcohol
reacts with carboxylic acid?
62
Ans:
• Ester
Q9 : What are the process to form
polyester?
63
Ans:
• Polymerization
•Spinning
•Drawing
Q10 : What is the another name for
nylon
64
Ans:
• Polyamide

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Fibre, nylon & polyester

  • 1.
  • 2. Fibre, Nylon & Polyester Presented by:  Noor Azurah Abdul Razak (20101037502)  Wan Norazwani Mahusin (D20101037506)  Ira Nusrat Jaafar (D20101037533) Lecturer : Dr Noorsyida
  • 3. Fibre • Fibres are the base unit of all textile materials and products. • They are slender thread- like structures that can be spun into yarns and thread, and woven, knitted or felted into materials. Wool Fibres CottonFibres
  • 4. Fibre Classifications Man-made Fibre - Synthetic Fibre -Regenerated Fibre Natural Fibre
  • 5.  Composed of atoms of various elements, such as carbon, hydrogen, oxygen, sometimes of nitrogen and other elements (sulphur) in lower quantities  Come from plants, animals and minerals.  Have short fibres, called staple fibres.  The exception to this rule is silk, a natural fibre whose continuous filaments are up to one kilometre in length. Sources of natural fibres • Cotton from the cotton plant • Linen from the flax plant • Wool from sheep • Silk from silkworms Natural Fibres
  • 6.  Cotton  Linen/Flax  Hemp Hemp 1) Plant Fibres - Cellulose Fibres Flax Cotton
  • 7. 2) Animal Fibres – Protein Fibres  Silk  Wool  Alpaca  Angora/Mohair Angora Alpaca Silk
  • 8. Man-made Fibres  Man is involved in the actual fibre formation process.  Synthetic fibres and regenerated fibres are man-made, usually from chemical and natural polymer sources.  Continuous filament fibres: Fibres are long and do not always have to be spun into yarn. Sources of synthetic fibres • Viscose comes from pine trees or petrochemicals. • Acrylic, nylon and polyester come from oil and coal. Viscose
  • 9.  Slick and abrasion resistant  Strong and resilient  Resistant to most common fibre degradants: sunlight (except for nylon)  Flame resistance varies widely  Low density  Non-biodegradable Common Properties
  • 10. Man-made – Synthetic Fibres • Fibers made by chemical synthesis are often called synthetic fibers. • Examples:  Polyester  Acrylic  Lycra  Nylon Polyester Nylon
  • 11. Man-made – Regenerated Fibres  Fibres regenerated from natural polymer sources.  Examples:  Rayon  Acetate Acetate Rayon
  • 12. Common Manufacturing Process o Polymerization (poly condensation or poly- addition) o Spinning o Drawing
  • 13. Polymerization • Process of macromolecules formation through repetition of basic units (synthesis fibres). • Activated and controlled during the process by various parameters: Temperature, pressure, catalysers and reaction stabilizers • Two mechanisms of chemical reaction available for the synthesis of linear polymers:  Poly-condensation - two molecules of same type or of different types are joined together to form macromolecules by removing simple secondary products as water, hydrochloric acid, alcohol.  Poly-addition - joins together several molecules and redistributes the valence links existing in the monomers, however without removing secondary products.
  • 14. Spinning • The term spinning defines the extrusion process through spinnerets of fluid polymer masses which are able to solidify in a continuous flow. • The polymer processing from the solid to the fluid state can take place with two methods: Melting: applied on thermoplastic polymers which show stable performances at the processing temperatures (used by 70% of the fibres) Solution: the polymer is solved in variable concentrations according to the kind of polymer and of solvent, anyhow such as to produce a sufficiently viscous liquid. (used by 30% of the fibres)
  • 15. Drawing • The polymer extruded by the spinnerets in form of filaments has not yet the properties which are typical of a textile fibre: poor thermal and chemical stability, low resistance to ageing, high plasticity • To develop strength, pliability, toughness, and elasticity properties.
  • 16.
  • 17. Issue 1: Silk Production Causes Painful Death for Insects • Silkworm is a domesticated insect. • Undergoes stages of metamorphosis: egg, larva, pupa, and adult. • Silk derived from the cocoons of larvae. Most of the insects raised by the industry don’t live past the pupa stage • They are steamed or gassed alive in their cocoons. Approximately 3,000 silkworms are killed to make every pound of silk.
  • 19. • belonging to a class of polymers called polyamides • It is made of repeating units linked by amide bonds and is frequently referred to as polyamide • Developed in the 1930s as an alternative to silk • Developed by Wallace Carothers at the Dupont Chemical company 19
  • 20. General Properties of Nylon • Functional group is amide • Light in weight • Incredible tensile strength • Durability • Resistance to damage • Takes dye easily • Absorbs most water • Greater stretchability • Dries slower • smoother and softer fabric than polyester • Somewhat UV resistant 20
  • 21. Type of Nylon and its Manufacture • In nylon, the repeating units contain chains of carbon atoms. • There are various different types of nylon depending on the nature of those chains for example: – Nylon-6,6 – Nylon-6 21
  • 22. 22
  • 23. Nylon-6,6 • synthesised by polycondensation of hexamethylenediamine and adipic acid. Nylon -6,6 23
  • 25. • Hexamethylene diamine and adipic acid are combined with water in a reactor. This produces nylon salt. • The nylon salt is then sent to an evaporator where excess water is removed. • The nylon salt goes into a reaction vessel where a continuous polymerization process takes place. This chemical process makes molten nylon 6-6. • The molten nylon -6,6 undergoes a spinning process, where the nylon 6-6 is extruded and sent through a spinneret, which is a small metal plate with fine holes. • The nylon is then air-cooled to form filaments. 25
  • 26. Uses of Nylons • Synthetic replacement for silk • It replaced silk in military applications such as parachutes and flak vests, and was used in many types of vehicle tires. • Used in many applications, including fabrics, bridal veils, carpets, musical strings, and rope. 26
  • 34. ISSUE 2: ADVANCED MATERIAL Artificial Muscles From Fishing Line And Thread 34
  • 35. 35
  • 36. • Artificial muscles have been crafted out of materials including metal wires and carbon nanotubes, but they have proven to be costly to make and tricky to control. • According to research published in the journal Science on 20th February 2014, these scientists instead turned to high-strength polymer fibres made of polyethylene and nylon, materials found in everyday items like fishing line and sewing thread. They twisted the fibres into very tight coils and used changes in temperature to make the artificial muscles contract and relax. 36
  • 37. POLYESTER The name "polyester“ (aka Terylene) refers to the linkage of several monomers (esters) within the fibre. 37
  • 38. Esters are formed when alcohol reacts with a carboxylic acid: Example : 38
  • 40. filament form : polyester fiber continuous in length, producing smooth-surfaced fabrics Staple form : filaments are cut to short, predetermined lengths. easier to blend with other fibers Tow : A form in which continuous filament are drawn loosely together Fiberfill : the voluminous form used in the manufacture of pillows and outerwear 40
  • 41. 41
  • 42. Different Structures Of Polyester 42
  • 43. o Colorless and transparent o Smooth and lustrous o Shape as we require o Shiny glass rod like 43
  • 44. Characteristics of polyester Strong Very durable Resistant to stretching and shrinking Quick drying Wrinkle resistant Mildew resistant Retains its shape good for making outdoor clothing Easily washed 44
  • 46. 46
  • 47. Drawing • when polyester emerges from the spinneret, it is soft and easily elongated up to 5 times its original length. • This helps to reduce the fibre width. • This fibre is now ready and would into cones as filaments. It can also be crimped and cut into staple lengths as per requirement 47
  • 48. Some Major Polyester Fibre Uses Apparel: Every form of clothing Home Furnishings: Carpets, curtains, draperies, sheets and pillow cases, wall coverings Other Uses: hoses, power belting, ropes and nets, thread, tire cord, auto upholstery, sails, floppy disk liners, and fiberfill for various products including pillows and furniture 48
  • 49. 49
  • 50. Issue 3: Advanced material of polyester Transforming plastic bottles into polyester fabric 50
  • 51. 51
  • 53. Nylon Polyester Functional group is amide Functional group is ester Absorbs most water Absorbs some water Greater stretchability Resistant to stretching Dries slower Dries quickly smoother and softer fabric than polyester polyester has always been a rougher fabric than nylon Somewhat UV resistant More UV resistant lightweight and durable synthetic fabrics Mildew resistant 53
  • 55. Q1: What are the base unit of all textile materials and products? 55 Answer: Fibre
  • 56. Q2 : State 2 classifications of fibre 56 Ans: Man-made & Natural Fibre
  • 57. Q3 : State 3 common manufacturing process of fibre 57 Ans: •Polymerization (polycondensation or poly- addition) •Spinning •Drawing
  • 58. Q4 : Give 2 example of synthetic fibres 58 Ans: •Nylon •Polyester •Acrylic •Lycra
  • 59. Q5 : Name 4 forms of polyester 59 Ans: • Filament •Staple •Tow •Fiberfill
  • 60. Q6 : What is the functional group for polyester? 60 Ans: • Ester
  • 61. Q7 : Gives 2 type of nylon 61 Ans: • Nylon -6 •Nylon -6,6
  • 62. Q8 : What is the product when alcohol reacts with carboxylic acid? 62 Ans: • Ester
  • 63. Q9 : What are the process to form polyester? 63 Ans: • Polymerization •Spinning •Drawing
  • 64. Q10 : What is the another name for nylon 64 Ans: • Polyamide