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What is Carbon Capture and Storage ?


                     Dr AK (Tony) Booer, Schlumberger Carbon Services, Abingdon, UK

April 14, 2010
The problem…




                             Schlumberger Public
               30-Oct-2006
Where do the GHG1 emissions come from ?




                                          Schlumberger Public
    1   GHG = Greenhouse Gas
Achieving Global GHG Stabilisation
  Requires a Technology Revolution
                                                                                                                        ENERGY
                                 70                                                    CCS industry                  TECHNOLOGY
     CO2 emissions (Gt CO2/yr)




                                                                                       and transformation 9%         PERSPECTIVES
                                 60                                                    CCS power generation 10%
                                 50                                                    Nuclear 6%
                                                                                       Renewables 21%
                                                                                                                      Scenarios &
                                 40                                                    Power generation efficiency     Strategies
                                                                                       & fuel switching 7%              to 2050

                                 30                                                    End-use fuel switching 11%
                                                                                       End use electricity
                                 20                                                    efficiency 12%

                                 10                                                     End use fuel
                                      WEO2007 450 ppm case ETP2008 BLUE Map scenario    efficiency 24%
                                  0
                                  2005                                           2050




In support of the G8 Plan of Action
CCS : CO2 Capture,and Storage and Storage
          Capture TRANSPORT



        Capture
      Power Plants
Other industrial processes




                                                    Schlumberger Public
Associated Gas production


                   Transport
                    Pipelines
                     Ships


                        Geological Storage
                      Depleted oil/gas reservoirs
                       Deep saline formations
Carbon Capture & Storage


 What are the issues ?

                         Public                       Technology:




                                                                                 Schlumberger Public
                      Awareness:                       ...we have
                        Climate,                       enough to
                      Energy, CCS,                         start
                        NGOs,
                       NUMBY…

                                                                    Projects:
       Financial:                                                    Europe,
                                      Regulatory
      Carbon Price,                                                 Australia,
                                     Framework:
       Incentives,                                                  America…
                                     International,
       Funding…
                                      National, …
Capture Options


Post Combustion:                                    ~15% CO2
                         Air
                                                                             CO2
                         Fuel        Combustion                Separator                  >95% CO2




                                                                                                     Schlumberger Public
Oxyfuel:
                                     O2
                                     Fuel        Combustion                >90% CO2




Pre Combustion:                                  ~99% CO2
                  H2 O
     Fuel (gas)                Reformer               Combustion                   H2 O
      eg. CH4                               H2
Transport options


Pipelines:

● Permanent
  infrastructure




                                                          Schlumberger Public
● Short to
  medium distance


Shipping:

● Flexible option
● Medium to
  long distance
                    Tanker image courtesy of IM Skaugen
Storage Options

Stored in geological formations:
● Depleted oil or gas fields
                                                          Depth:
● Deep saline formations
                                                      1,500 – 3,000m




                                                                                      Schlumberger Public
                                                      5,000 – 10,000ft

 TWO KEY POINTS:
 Storage sites are NOT huge caverns…
      …but „solid rocks‟ like a sponge.
                                                                         Secondary
 CO2 is NOT a gas, at depth,                                             seals
      but like a dense liquid.
                                                                         Primary
                                                                         seals


„Enhanced Oil Recovery‟ is NOT the same as storage.                       Storage
                                                                          reservoir
CO2 Enhanced Oil Recovery versus Storage

 Enhanced Oil Recovery             Storage
 ● CO2 rate depends on             ● CO2 rate determined by source
   production strategy             ● CO2 stored
 ● CO2 recycled                    ● Legislation under new CO2 regime




                                                                            Schlumberger Public
 ● Legislation under               ● Long-term monitoring
   petroleum industry
                                   ● High public awareness
 ● No Monitoring
                                   ● Revenue from price of carbon
 ● Revenue from hydrocarbon




                              Significant experience in CO2 pipelines and
                              injection wells gained from US EOR
                              activities in the last 30+ years.
Storage mechanisms & containment

Storage sites evolve over time...

●   Structural & stratigraphic trapping
●   Residual – in pore space




                                                                  Schlumberger Public
●   Solubility – in water
●   Mineralisation – “turned to stone”

Oil/gas fields demonstrate
    storage times of millions of years.




    Natural accumulations of CO2 have
    been safely stored for millions of years.
                                                from IPCC, 2005
Finding the right Storage Site


What do we need?
                                                                      Other:
                            Injectivity:                         • Environment
                          The ease with                         • Infrastructure




                                                                                    Schlumberger Public
                          which the CO2                           • Regulation
                          can be injected                       • Public opinion
                                                                    • Finance
         Capacity:                           Containment:
       The amount of                          The ability to
        CO2 that can                           store CO2
         be safely                             safely and
          stored                              permanently



 …the best risk reduction approach is to choose the right site in the first place
CCS is ready to go (on an industrial scale …)

                               In Salah                                                       each
                               Sahara desert,                                              ~1 M-tonne
                               Algeria                                                     of CO2 per
                                                                                              year
Weyburn




                                                                                                                         Schlumberger Public
Canada, at end                                                                                          Sleipner
of 200km                                                                                                Norwegian
pipeline                                                                                                North Sea
                                                                     Remote
                                                                  regions have
                                                                   fewer public
                                                                    awareness
                                                                      issues

                                CO2 can be                                                              Carbon
                                transported                                                              taxes
                              long distances                                                             work!
                                 by pipeline



 Courtesy of IEA Weyburn CO2 Storage and Monitoring Project , BP, Sonatrach, and Statoil                            13
80 companies saying they‟re ready to help do CCS




                                                   Schlumberger Public
For Q&A session




                               Schlumberger Public
Additional slides




                              15
Examples of natural CO2 leaks ...
                     ...not the end of the world




                                                                                         Schlumberger Public
                           Collage of leaks courtesy Stuart Haszeldine, U of Edinburgh
Lake Nyos

● Lake Nyos, Cameroon -- Lake Nyos is
  one of about thirty similar crater lakes in   This was a natural disaster –
  western Cameroon.                               not the result of a poorly
                                                   managed storage site




                                                                                                 Schlumberger Public
● On August 21, 1986, Lake Nyos released
  a massive cloud of CO2 gas that
  overwhelmed Nyos village and adjacent
  settlements.

● The gas cloud asphyxiated 1,742 people
  and thousands of cattle and birds.

● The CO2 eruption brought up iron-rich
  bottom waters which were oxidized to
  give the lake waters a red-brown color.                 Photo courtesy J. P. Lockwood, USGS.
Degassing Lake Nyos…




                                                                                                   Schlumberger Public
    CO2 Water Jet, Lake Nyos, Cameroon – remediation at work.
                                       http://pagesperso-orange.fr/mhalb/nyos/2006/index2006.htm
Not just a gas:
CO2 – density and volume as a function of depth



                                                  “Supercritical” CO2

                                                     As dense as a




                                                                          Schlumberger Public
                                                         liquid…
                                                       but with the
                                                    viscosity of a gas.




Source: IEA
CO2 Monitoring – 3 objectives




                                                                                                 Schlumberger Public
                           #3: Monitor the environment
 Freshwater                                                     Well Integrity
   aquifer
                         Containment
                                                 #2: Watch possible leakage paths
                                       Sealed fault


              #1: Watch stored CO2
                                                                                 Boundaries




                      CO2
                                               Monitoring       Abandoned           Monitoring
                   injection
                                                 well              well               well
                      well
Finding the right Storage Site




                                 Schlumberger Public
Modeling & Measurement to reduce Uncertainty




                                               Schlumberger Public

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Carbon Capture and Storage breakfast seminar

  • 1. What is Carbon Capture and Storage ? Dr AK (Tony) Booer, Schlumberger Carbon Services, Abingdon, UK April 14, 2010
  • 2. The problem… Schlumberger Public 30-Oct-2006
  • 3. Where do the GHG1 emissions come from ? Schlumberger Public 1 GHG = Greenhouse Gas
  • 4. Achieving Global GHG Stabilisation Requires a Technology Revolution ENERGY 70 CCS industry TECHNOLOGY CO2 emissions (Gt CO2/yr) and transformation 9% PERSPECTIVES 60 CCS power generation 10% 50 Nuclear 6% Renewables 21% Scenarios & 40 Power generation efficiency Strategies & fuel switching 7% to 2050 30 End-use fuel switching 11% End use electricity 20 efficiency 12% 10 End use fuel WEO2007 450 ppm case ETP2008 BLUE Map scenario efficiency 24% 0 2005 2050 In support of the G8 Plan of Action
  • 5. CCS : CO2 Capture,and Storage and Storage Capture TRANSPORT Capture Power Plants Other industrial processes Schlumberger Public Associated Gas production Transport Pipelines Ships Geological Storage Depleted oil/gas reservoirs Deep saline formations
  • 6. Carbon Capture & Storage What are the issues ? Public Technology: Schlumberger Public Awareness: ...we have Climate, enough to Energy, CCS, start NGOs, NUMBY… Projects: Financial: Europe, Regulatory Carbon Price, Australia, Framework: Incentives, America… International, Funding… National, …
  • 7. Capture Options Post Combustion: ~15% CO2 Air CO2 Fuel Combustion Separator >95% CO2 Schlumberger Public Oxyfuel: O2 Fuel Combustion >90% CO2 Pre Combustion: ~99% CO2 H2 O Fuel (gas) Reformer Combustion H2 O eg. CH4 H2
  • 8. Transport options Pipelines: ● Permanent infrastructure Schlumberger Public ● Short to medium distance Shipping: ● Flexible option ● Medium to long distance Tanker image courtesy of IM Skaugen
  • 9. Storage Options Stored in geological formations: ● Depleted oil or gas fields Depth: ● Deep saline formations 1,500 – 3,000m Schlumberger Public 5,000 – 10,000ft TWO KEY POINTS: Storage sites are NOT huge caverns… …but „solid rocks‟ like a sponge. Secondary CO2 is NOT a gas, at depth, seals but like a dense liquid. Primary seals „Enhanced Oil Recovery‟ is NOT the same as storage. Storage reservoir
  • 10. CO2 Enhanced Oil Recovery versus Storage Enhanced Oil Recovery Storage ● CO2 rate depends on ● CO2 rate determined by source production strategy ● CO2 stored ● CO2 recycled ● Legislation under new CO2 regime Schlumberger Public ● Legislation under ● Long-term monitoring petroleum industry ● High public awareness ● No Monitoring ● Revenue from price of carbon ● Revenue from hydrocarbon Significant experience in CO2 pipelines and injection wells gained from US EOR activities in the last 30+ years.
  • 11. Storage mechanisms & containment Storage sites evolve over time... ● Structural & stratigraphic trapping ● Residual – in pore space Schlumberger Public ● Solubility – in water ● Mineralisation – “turned to stone” Oil/gas fields demonstrate storage times of millions of years. Natural accumulations of CO2 have been safely stored for millions of years. from IPCC, 2005
  • 12. Finding the right Storage Site What do we need? Other: Injectivity: • Environment The ease with • Infrastructure Schlumberger Public which the CO2 • Regulation can be injected • Public opinion • Finance Capacity: Containment: The amount of The ability to CO2 that can store CO2 be safely safely and stored permanently …the best risk reduction approach is to choose the right site in the first place
  • 13. CCS is ready to go (on an industrial scale …) In Salah each Sahara desert, ~1 M-tonne Algeria of CO2 per year Weyburn Schlumberger Public Canada, at end Sleipner of 200km Norwegian pipeline North Sea Remote regions have fewer public awareness issues CO2 can be Carbon transported taxes long distances work! by pipeline Courtesy of IEA Weyburn CO2 Storage and Monitoring Project , BP, Sonatrach, and Statoil 13
  • 14. 80 companies saying they‟re ready to help do CCS Schlumberger Public
  • 15. For Q&A session Schlumberger Public Additional slides 15
  • 16. Examples of natural CO2 leaks ... ...not the end of the world Schlumberger Public Collage of leaks courtesy Stuart Haszeldine, U of Edinburgh
  • 17. Lake Nyos ● Lake Nyos, Cameroon -- Lake Nyos is one of about thirty similar crater lakes in This was a natural disaster – western Cameroon. not the result of a poorly managed storage site Schlumberger Public ● On August 21, 1986, Lake Nyos released a massive cloud of CO2 gas that overwhelmed Nyos village and adjacent settlements. ● The gas cloud asphyxiated 1,742 people and thousands of cattle and birds. ● The CO2 eruption brought up iron-rich bottom waters which were oxidized to give the lake waters a red-brown color. Photo courtesy J. P. Lockwood, USGS.
  • 18. Degassing Lake Nyos… Schlumberger Public CO2 Water Jet, Lake Nyos, Cameroon – remediation at work. http://pagesperso-orange.fr/mhalb/nyos/2006/index2006.htm
  • 19. Not just a gas: CO2 – density and volume as a function of depth “Supercritical” CO2 As dense as a Schlumberger Public liquid… but with the viscosity of a gas. Source: IEA
  • 20. CO2 Monitoring – 3 objectives Schlumberger Public #3: Monitor the environment Freshwater Well Integrity aquifer Containment #2: Watch possible leakage paths Sealed fault #1: Watch stored CO2 Boundaries CO2 Monitoring Abandoned Monitoring injection well well well well
  • 21. Finding the right Storage Site Schlumberger Public
  • 22. Modeling & Measurement to reduce Uncertainty Schlumberger Public