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Morphology of Polybutadiene TPU
 and Blends with Polypropylene


      Poly bd® and Krasol®
Overview


    • Polybutadiene Based TPUs
       - Solubility Index
       - Acid & Base Resistance
    • Intro to Poly bd® and Krasol®
    • PP-TPU Alloy
       - Surface Morphology




2          Cray Valley HSC
Polybutadiene-based TPU




3        Cray Valley HSC
Solubility Index




4          Cray Valley HSC
Acid & Base Resistance




5         Cray Valley HSC
Introduction – Poly bd® & Krasol®




6         Cray Valley HSC
50/50 of PP/TPU 7840 (TEM)




7        Cray Valley HSC
PP-TPU Alloy (AFM)




8        Cray Valley HSC
Dispersion Results




9         Cray Valley HSC
Surface Morphology of Alloy




10     Cray Valley HSC
Cray Valley HSC

 • Leading global supplier of hydrocarbon resins, diene-
   based resins, and specialty monomers
     - Wingtack® and Norsolene® (C5 & C9 tackifiers)
     - Poly bd®, KrasolTM and Ricon® (low molecular weight liquid
     polybutadiene resins)
     - SMA® (styrene-maleic anhydride copolymer resins)
     - DymalinkTM (metal centered monomers)
 • Annual sales over $350 million and has more than 340
   employees worldwide
 • Company’s more than 250 products are manufactured at
   9 sites in 4 countries

11         Cray Valley HSC
Cray Valley HSC
 A Division of Total SA




                          Upstream               Downstream                 Chemicals
                 • Oil & gas exploration    • Trading & shipping      • Base chemicals
                 • Production               • Refining & marketing    • Industrial & consumer
     Focus
                 • Gas & power              • Commodity & specialty   market specialty
                 • Alternative energy       fluids                    chemicals
      Sales
                              $24.6                 $163.4                     $23.2
     (billion)
 Employees                   17,192                 32,631                     41,658

                              Total, a partner in your challenges

12               Cray Valley HSC
Cray Valley HSC
 Focus Markets




              • Performance                    • Pressure                     • Printed




                                                             Growth Markets
                additives                        sensitive                      circuit
                                                                                boards

                                   Adhesives
              • Tire & hose                    • Reactive
     Rubber




                applications                     adhesives                    • Pigment
                                                                                Dispersants
              • Co-curing                      • Insulated
                agents                           Glass                        • Mineral
                                                 Sealants                       Dispersants




13               Cray Valley HSC
Cray Valley HSC
 Global Presence




14       Cray Valley HSC
Cray Valley HSC



 • For additional information about Cray Valley, its products
       or its work in Hydrocarbon Specialty Chemicals,
             visit www.CVPolymerAdditives.com




15       Cray Valley HSC

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Form & Structure: The Effects of Polybutadiene TPU with Polypropylene

  • 1. Morphology of Polybutadiene TPU and Blends with Polypropylene Poly bd® and Krasol®
  • 2. Overview • Polybutadiene Based TPUs - Solubility Index - Acid & Base Resistance • Intro to Poly bd® and Krasol® • PP-TPU Alloy - Surface Morphology 2 Cray Valley HSC
  • 3. Polybutadiene-based TPU 3 Cray Valley HSC
  • 4. Solubility Index 4 Cray Valley HSC
  • 5. Acid & Base Resistance 5 Cray Valley HSC
  • 6. Introduction – Poly bd® & Krasol® 6 Cray Valley HSC
  • 7. 50/50 of PP/TPU 7840 (TEM) 7 Cray Valley HSC
  • 8. PP-TPU Alloy (AFM) 8 Cray Valley HSC
  • 9. Dispersion Results 9 Cray Valley HSC
  • 10. Surface Morphology of Alloy 10 Cray Valley HSC
  • 11. Cray Valley HSC • Leading global supplier of hydrocarbon resins, diene- based resins, and specialty monomers - Wingtack® and Norsolene® (C5 & C9 tackifiers) - Poly bd®, KrasolTM and Ricon® (low molecular weight liquid polybutadiene resins) - SMA® (styrene-maleic anhydride copolymer resins) - DymalinkTM (metal centered monomers) • Annual sales over $350 million and has more than 340 employees worldwide • Company’s more than 250 products are manufactured at 9 sites in 4 countries 11 Cray Valley HSC
  • 12. Cray Valley HSC A Division of Total SA Upstream Downstream Chemicals • Oil & gas exploration • Trading & shipping • Base chemicals • Production • Refining & marketing • Industrial & consumer Focus • Gas & power • Commodity & specialty market specialty • Alternative energy fluids chemicals Sales $24.6 $163.4 $23.2 (billion) Employees 17,192 32,631 41,658 Total, a partner in your challenges 12 Cray Valley HSC
  • 13. Cray Valley HSC Focus Markets • Performance • Pressure • Printed Growth Markets additives sensitive circuit boards Adhesives • Tire & hose • Reactive Rubber applications adhesives • Pigment Dispersants • Co-curing • Insulated agents Glass • Mineral Sealants Dispersants 13 Cray Valley HSC
  • 14. Cray Valley HSC Global Presence 14 Cray Valley HSC
  • 15. Cray Valley HSC • For additional information about Cray Valley, its products or its work in Hydrocarbon Specialty Chemicals, visit www.CVPolymerAdditives.com 15 Cray Valley HSC