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     Angela Liu
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Algae need resources
 Climate          Water         Carbon Dioxide   Land




  [+ Nutrients]



                          Algae Fuel
Site Selection
Just a few considerations:
 “Areas with more than 5% slope can be
  effectively eliminated from consideration for
  site development not only due to the intrinsic
  needs of the technology, but also due to the
  increased costs of site development.” – DOE
  2009
 “Siting requirements for efficient microalgal
  cultivation may rarely coincide with high-
  volume point sources of CO2.” – DOE 2009
Site Selection – Wastewater
              “Wastewater treatment facilities, for
           example, tend to be near metropolitan
           areas with high land prices and limited
         land availability, and it is not practical to
                  transport wastewater over long
                           distances.” – DOE 2009
Ma’alaea Oil Power Plant -
Maui
 July 15, 2008 –      200 x 1000 m =
  HR Biopetroleum      50 acres
  collaborative
  announced
  planned algal
  farm adjacent to
  Ma'alaea Plant,
  Maui.
 Satellite imagery
  reveals potential
  production site of
  approximately 50
  acres (enough to
  supply 200-350
  thousand
  gal/year)
Site Selection – Challenges
To be successful the algal fuels industry must:
 Carefully choose sites that balance climate, water,
 
   carbon dioxide, land, and nutrient requirements –
   while ensuring and maintaining adequate levels of
   each.
 Seek to integrate existing waste streams as input
   streams for production processes (CO2,
   wastewater and others).
 Work collaboratively with government and the
   public sector to ensure public acceptance and
   protect existing interests.
Technological Challenges:
   Immature Technologies
      Raceway Ponds – Invasive species
      Photobioreactor – High capital cost
   Algae Selection
      Indigenous species and/or
      bioengineered organisms                mvm.uni-karlsruhe.de
      High lipid production
      Fast growth rate
      Strained nutrient conditions
   Other infrastructure
      Nutrient and CO2 Sources
          Wastewater? Oil Plant Emissions?
Challenges:
   Represents ~30% of cost of producing algal biofuel
   Extremely low biomass density
      ~1800 Gallons culture -> 1 Gallon biofuel
   Known methods inadequate
      Centrifugation = too expensive
      High-temperature drying may degrade lipids
   Suggested methods unproven on commercial scale
      Flocculation and gravity settling
Reactions to convert lipids to biofuel exist
   Transesterification  Biodiesel
   Catalytic Hydroprocessing  Green gasoline, jet fuel, etc.
Challenges:
   Large, commercial scale refining facilities required
   Refining processes need to be optimized for algal lipid
   feedstock




TAG
Many problems are well-defined and can be solved via
testing and applied research
Much is still unknown about algal ecosystems
   Improve lipid content and algal yield
   Improve robustness of desired strain or identify beneficial
   relationships between strains
Lipid extraction
   Creative approaches to avoid energy-intensive drying
   process
Economic Analysis
Limits and Challenges
 Currently in R&D phase.
   It is difficult to do an economic analysis comparing the
    price of algal biodiesel to petrol-diesel since biodiesel
    is not being marketed and sold.
Goal of the Economic
Analysis
 To encourage investor confidence
    The goal is to raise money so further research can be
     conducted.
 Investors in algal biofuels in Hawaii
    Oil companies
         Cellana LLC is a joint venture with HR Biopetroleum, University of
          Hawai’I, and Royal Dutch Shell Petroleum
    Local companies
      Alexander & Baldwin
      Hawaiian Electric Company
    State and Federal Funding
      NELHA - invested $100-150 million
       in 2009
      State and Federal Funding –
       $645,000 for military jet fuel research
Biodiesel
Source                          Type of Reactor        Biomass             Cost
                                                         Cost             ($/gal)
                                                        ($/gal)
Benemann & Oswald                      RW                0.80               1.64
(1996)                                                   0.49               1.00
Moline Grime et al. (2004)             PBR              101.33
Moheimani (2005)                       RW                20.33
                                       RW            15.67 - 23.00
van Harmelen & Oonk                    RW
(2006)                                                    1.23              4.00
Chisti (2007)                          PBR                1.57              5.33
                                       RW                 2.00              6.83
Huntley & Redalje (2007)              Hybrid           0.36 - 1.19       0.93 - 3.02
Carlsson et al. (2007)                 RW             6.67 - 50.00
Alabi et al. (2009)                    PBR                19.67
                                       RW                 7.13
Pienkos & Darzins (2009)                                                   25.00
                                                                            7.50
                                                                            2.50
Present account                       Hybrid           1.19 - 2.17      3.00 - 11.67
Production Costs. RW = Open Raceway; PBR = Photobioreactor; Hybrid = RW + PBR
Adapted from Williams, P. and Laurens Microalgae as biodiesel & biomass feedstocks,
2010
Production Costs I

 Production of algae
    Open raceway
         Capital cost: ~$5,000 per unit
         Production cost: $0.80 - $50 /gal algae produced
     Photobioreactor
         Capital cost: ~$150,000 per unit
         Production cost: $1.57 – $101 /gal algae produced
     Hybrid
         Production cost: $1.19-$2.27/gal
Production Costs II
 CO2 source
   Coal-power plant or BioEnergy
    Hawai’i LLC, a power plant that
    uses commercial waste.
  • Nutrient source
     Wastewater treatment plant
     Other ingredients like insolation
      (sunlight) and water are plentiful in
      Hawaii.

 Harvesting
   Expensive to centrifuge large
      amounts of algae so research is
      being done in flocculation and a
      combination of both.
Production Costs III
 Production Costs are offset by the sale of Co-Products




From Zemke, Wood, & Dye, Technoeconomic Analysis of Algal Photobioreactors for Oil Production, Utah
   State University
 MERA Pharmaceuticals, Inc. (Hawaiian Co.)
      Producing astaxanthin-based products: AstaFactor and AquaXan
      Photobioreactor capacity: 6,000 gallons (25,000 liters)
      AstaFactor is $29.95/bottle
Overall Production Costs vs
Price of Petroleum
 According to Pienkos and Darzins (2009), overall production
  costs of biodiesel are:
     Low productivity: $25/gal biodiesel
     High productivity: $2.50/gal biodiesel
 Compared to the current cost of gasoline in Hawaii:
    $2.97/gal (US average is $2.29/gal)
 Compared to next most profitable oil:
    Palm oil: $2.50/gallon
Environmental Impacts of Corn-based
Ethanol
 Depletion of topsoil        Less land conserved in
 Soil nutrients depletion     the Conservation Reserve
 Toxins from pesticides       Program
 Eutrophication              High amounts of erosion
 Contamination of ground     Biodiversity disappears
  water                       CO2 from farm equipment
 Depletion of Aquifers
Air
 Locally grown: emission
  reductions from not having to
  ship oil to the islands
 Net Zero carbon: burned algae
  fuel does not add additional CO2
  to the atmosphere
 Reduction in other emissions
  which leads to less smog and
  respiratory illnesses
 CO2 is recycled from power
  plants
 Growing algae adds more
  oxygen to the air
Source:
http://www.giss.nasa.go
v/meetings/pollution200
2/d3_kaya.html
Water




 By using waste water to feed the algae, nitrogen and
  phosphorus can be diverted from the water bodies to help
  prevent problems such as dead zones.
 With a recycled source of water, water resources would not
  be depleted
Land Use
 Algae farming takes
  up considerable less
  land than other
  biofuels
 Algae does not need
  farmable land to grow
  so does not compete
  with food sources
 Growing and
  harvesting of algae is
  not harsh on the land
Social and Policy Implications –
•Increased jobs and economic growth
•Private sector investment is currently estimated
at $1 Billion
•Continue to develop policy supportive of biofuels
•Value of CO2 capture in a possible
carbon market
Social and Policy Implications –
   Policy Drivers
•US and Hawaiian Renewable Energy Initiatives

•Engages multiple stakeholders (Government, Academia, and Industry)

• Reduce   potential for social
stress
   •Co-siting with CO2 source or
   Wastewater treatment
   •Can be used on marginal
   lands
Algal Biofuels for Local Consumption

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Algal Biofuels for Local Consumption

  • 1. Ross Barnowski Angela Liu Duncan Clauson Katie Peige Logan Stephens
  • 2. Algae need resources Climate Water Carbon Dioxide Land [+ Nutrients] Algae Fuel
  • 3. Site Selection Just a few considerations:  “Areas with more than 5% slope can be effectively eliminated from consideration for site development not only due to the intrinsic needs of the technology, but also due to the increased costs of site development.” – DOE 2009  “Siting requirements for efficient microalgal cultivation may rarely coincide with high- volume point sources of CO2.” – DOE 2009
  • 4. Site Selection – Wastewater “Wastewater treatment facilities, for example, tend to be near metropolitan areas with high land prices and limited land availability, and it is not practical to transport wastewater over long distances.” – DOE 2009
  • 5. Ma’alaea Oil Power Plant - Maui  July 15, 2008 – 200 x 1000 m = HR Biopetroleum 50 acres collaborative announced planned algal farm adjacent to Ma'alaea Plant, Maui.  Satellite imagery reveals potential production site of approximately 50 acres (enough to supply 200-350 thousand gal/year)
  • 6. Site Selection – Challenges To be successful the algal fuels industry must:  Carefully choose sites that balance climate, water,  carbon dioxide, land, and nutrient requirements – while ensuring and maintaining adequate levels of each.  Seek to integrate existing waste streams as input streams for production processes (CO2, wastewater and others).  Work collaboratively with government and the public sector to ensure public acceptance and protect existing interests.
  • 7.
  • 8. Technological Challenges: Immature Technologies Raceway Ponds – Invasive species Photobioreactor – High capital cost Algae Selection Indigenous species and/or bioengineered organisms mvm.uni-karlsruhe.de High lipid production Fast growth rate Strained nutrient conditions Other infrastructure Nutrient and CO2 Sources Wastewater? Oil Plant Emissions?
  • 9. Challenges: Represents ~30% of cost of producing algal biofuel Extremely low biomass density ~1800 Gallons culture -> 1 Gallon biofuel Known methods inadequate Centrifugation = too expensive High-temperature drying may degrade lipids Suggested methods unproven on commercial scale Flocculation and gravity settling
  • 10. Reactions to convert lipids to biofuel exist Transesterification  Biodiesel Catalytic Hydroprocessing  Green gasoline, jet fuel, etc. Challenges: Large, commercial scale refining facilities required Refining processes need to be optimized for algal lipid feedstock TAG
  • 11. Many problems are well-defined and can be solved via testing and applied research Much is still unknown about algal ecosystems Improve lipid content and algal yield Improve robustness of desired strain or identify beneficial relationships between strains Lipid extraction Creative approaches to avoid energy-intensive drying process
  • 12. Economic Analysis Limits and Challenges  Currently in R&D phase.  It is difficult to do an economic analysis comparing the price of algal biodiesel to petrol-diesel since biodiesel is not being marketed and sold.
  • 13. Goal of the Economic Analysis  To encourage investor confidence  The goal is to raise money so further research can be conducted.  Investors in algal biofuels in Hawaii  Oil companies  Cellana LLC is a joint venture with HR Biopetroleum, University of Hawai’I, and Royal Dutch Shell Petroleum  Local companies  Alexander & Baldwin  Hawaiian Electric Company  State and Federal Funding  NELHA - invested $100-150 million in 2009  State and Federal Funding – $645,000 for military jet fuel research
  • 14. Biodiesel Source Type of Reactor Biomass Cost Cost ($/gal) ($/gal) Benemann & Oswald RW 0.80 1.64 (1996) 0.49 1.00 Moline Grime et al. (2004) PBR 101.33 Moheimani (2005) RW 20.33 RW 15.67 - 23.00 van Harmelen & Oonk RW (2006) 1.23 4.00 Chisti (2007) PBR 1.57 5.33 RW 2.00 6.83 Huntley & Redalje (2007) Hybrid 0.36 - 1.19 0.93 - 3.02 Carlsson et al. (2007) RW 6.67 - 50.00 Alabi et al. (2009) PBR 19.67 RW 7.13 Pienkos & Darzins (2009) 25.00 7.50 2.50 Present account Hybrid 1.19 - 2.17 3.00 - 11.67 Production Costs. RW = Open Raceway; PBR = Photobioreactor; Hybrid = RW + PBR Adapted from Williams, P. and Laurens Microalgae as biodiesel & biomass feedstocks, 2010
  • 15. Production Costs I  Production of algae  Open raceway  Capital cost: ~$5,000 per unit  Production cost: $0.80 - $50 /gal algae produced  Photobioreactor  Capital cost: ~$150,000 per unit  Production cost: $1.57 – $101 /gal algae produced  Hybrid  Production cost: $1.19-$2.27/gal
  • 16. Production Costs II  CO2 source  Coal-power plant or BioEnergy Hawai’i LLC, a power plant that uses commercial waste. • Nutrient source  Wastewater treatment plant  Other ingredients like insolation (sunlight) and water are plentiful in Hawaii.  Harvesting  Expensive to centrifuge large amounts of algae so research is being done in flocculation and a combination of both.
  • 17. Production Costs III  Production Costs are offset by the sale of Co-Products From Zemke, Wood, & Dye, Technoeconomic Analysis of Algal Photobioreactors for Oil Production, Utah State University  MERA Pharmaceuticals, Inc. (Hawaiian Co.)  Producing astaxanthin-based products: AstaFactor and AquaXan  Photobioreactor capacity: 6,000 gallons (25,000 liters)  AstaFactor is $29.95/bottle
  • 18. Overall Production Costs vs Price of Petroleum  According to Pienkos and Darzins (2009), overall production costs of biodiesel are:  Low productivity: $25/gal biodiesel  High productivity: $2.50/gal biodiesel  Compared to the current cost of gasoline in Hawaii:  $2.97/gal (US average is $2.29/gal)  Compared to next most profitable oil:  Palm oil: $2.50/gallon
  • 19.
  • 20. Environmental Impacts of Corn-based Ethanol  Depletion of topsoil  Less land conserved in  Soil nutrients depletion the Conservation Reserve  Toxins from pesticides Program  Eutrophication  High amounts of erosion  Contamination of ground  Biodiversity disappears water  CO2 from farm equipment  Depletion of Aquifers
  • 21. Air  Locally grown: emission reductions from not having to ship oil to the islands  Net Zero carbon: burned algae fuel does not add additional CO2 to the atmosphere  Reduction in other emissions which leads to less smog and respiratory illnesses  CO2 is recycled from power plants  Growing algae adds more oxygen to the air
  • 23. Water  By using waste water to feed the algae, nitrogen and phosphorus can be diverted from the water bodies to help prevent problems such as dead zones.  With a recycled source of water, water resources would not be depleted
  • 24. Land Use  Algae farming takes up considerable less land than other biofuels  Algae does not need farmable land to grow so does not compete with food sources  Growing and harvesting of algae is not harsh on the land
  • 25. Social and Policy Implications – •Increased jobs and economic growth •Private sector investment is currently estimated at $1 Billion •Continue to develop policy supportive of biofuels •Value of CO2 capture in a possible carbon market
  • 26. Social and Policy Implications – Policy Drivers •US and Hawaiian Renewable Energy Initiatives •Engages multiple stakeholders (Government, Academia, and Industry) • Reduce potential for social stress •Co-siting with CO2 source or Wastewater treatment •Can be used on marginal lands