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Pyrolysis oil
Kasperi Karhapää
FIBIC –seminar
20.11.2013, Fortum

1
Titles
1) Why Fortum decided to produce
pyrolysis oil
2) How pyrolysis oil is produced
3) Pyrolysis oil characteristics
4) Where to use pyrolysis oil
5) Future visions
6) “Broad” sustainability of pyrolysis
oil

2
1) Why Fortum decided to produce pyrolysis oil
Future energy system is based on emission free and inexhaustible energy sources

Intermediate goal on the way towards solar power is
the use of biomass – in solid, liquid and gas form

3
Why pyrolysis oil is Fortum’s selection
•
•
•
•

Fast pyrolysis is one of the most cost efficient ways to liquefy biomass
Pyrolysis oil is bioenergy in a dense form
Helps to decrease CO2 – emissions, SOx emissions
Pyrolysis oil production is integrated into CHP-power plant. Benefits of integrating
include:
– Increase in CHP-plant’s utilization rate
– Complete utilization of by-products in energy production
– Combined raw material and fuel purchase, combined control room operations

• Yearly production is 50 000 tons of pyrolysis oil

4
Pyrolysis oil is bioenergy in a dense form

© OECD/IEA 2012 (Anselm Eisentraut, Jönköping 30.5.2012)
5
2) Production of pyrolysis oil

CHP –boiler integrated
process

6
3) Pyrolysis oil characteristics
•
•
•
•

Sulphur ’free’
Acidic, pH 2‒3
Viscosity between HFO and LFO
Lower Heating Value 13-18 MJ/kg
(LHV)
• Water content 20-35 p-%
• Flash point 40-110 °C
• Density 1.1-1.3 kg/l

7

Source: VTT
4) Where to use pyrolysis oil
• Replace HFO
– In Finland about 400–600 heat boilers use HFO or
LFO as main fuel.
– Environmental norms for <50 MW boilers tightening
(PINO –norms)
• Especially sulphur limits make the use of HFO more
difficult in the future

– Switching a heating boiler from HFO to pyrolysis oil
requires relatively small investment

• In the future
– Refining – requires scientific work
– Diesel engines
– Gas turbines
– Co-firing

8
5) Future visions
Biooil

Separate
Upgrade

Boiler

Gasify

Reform

Engine
Synthesis
Turbine

Heat

Electricity

Transportation Fuels

Lähde: Biomass Pyrolysis, IEA Task 34 Booklet

Hydrogen

Chemicals
6) “Broad” sustainability of pyrolysis oil
Raw material
• Renewable wood
– Harvesting residues, saw dust, wood from energy
thinnings

• Sustainably produced
– Sustainability controlled with sustainability system

Total efficiency in integrated concept
• Increased total efficiency of the existing CHP-plants
• Complete utilization of pyrolysis oil production byproducts in energy production
• Pyrolysis oil use in existing heating boilers
Green “addings”
• Pyrolysis oil is green fuel for the heating boilers
• Decreasing SOx emissions
• Increased green electricity production in the
integrated concept
10
Thank you!
Kasperi Karhapää
Head of pyrolysis and business development
kasperi.karhapaa@fortum.com

11

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Sustainable Bioenergy Solutions, Kasperi Karhapää

  • 1. Pyrolysis oil Kasperi Karhapää FIBIC –seminar 20.11.2013, Fortum 1
  • 2. Titles 1) Why Fortum decided to produce pyrolysis oil 2) How pyrolysis oil is produced 3) Pyrolysis oil characteristics 4) Where to use pyrolysis oil 5) Future visions 6) “Broad” sustainability of pyrolysis oil 2
  • 3. 1) Why Fortum decided to produce pyrolysis oil Future energy system is based on emission free and inexhaustible energy sources Intermediate goal on the way towards solar power is the use of biomass – in solid, liquid and gas form 3
  • 4. Why pyrolysis oil is Fortum’s selection • • • • Fast pyrolysis is one of the most cost efficient ways to liquefy biomass Pyrolysis oil is bioenergy in a dense form Helps to decrease CO2 – emissions, SOx emissions Pyrolysis oil production is integrated into CHP-power plant. Benefits of integrating include: – Increase in CHP-plant’s utilization rate – Complete utilization of by-products in energy production – Combined raw material and fuel purchase, combined control room operations • Yearly production is 50 000 tons of pyrolysis oil 4
  • 5. Pyrolysis oil is bioenergy in a dense form © OECD/IEA 2012 (Anselm Eisentraut, Jönköping 30.5.2012) 5
  • 6. 2) Production of pyrolysis oil CHP –boiler integrated process 6
  • 7. 3) Pyrolysis oil characteristics • • • • Sulphur ’free’ Acidic, pH 2‒3 Viscosity between HFO and LFO Lower Heating Value 13-18 MJ/kg (LHV) • Water content 20-35 p-% • Flash point 40-110 °C • Density 1.1-1.3 kg/l 7 Source: VTT
  • 8. 4) Where to use pyrolysis oil • Replace HFO – In Finland about 400–600 heat boilers use HFO or LFO as main fuel. – Environmental norms for <50 MW boilers tightening (PINO –norms) • Especially sulphur limits make the use of HFO more difficult in the future – Switching a heating boiler from HFO to pyrolysis oil requires relatively small investment • In the future – Refining – requires scientific work – Diesel engines – Gas turbines – Co-firing 8
  • 10. 6) “Broad” sustainability of pyrolysis oil Raw material • Renewable wood – Harvesting residues, saw dust, wood from energy thinnings • Sustainably produced – Sustainability controlled with sustainability system Total efficiency in integrated concept • Increased total efficiency of the existing CHP-plants • Complete utilization of pyrolysis oil production byproducts in energy production • Pyrolysis oil use in existing heating boilers Green “addings” • Pyrolysis oil is green fuel for the heating boilers • Decreasing SOx emissions • Increased green electricity production in the integrated concept 10
  • 11. Thank you! Kasperi Karhapää Head of pyrolysis and business development kasperi.karhapaa@fortum.com 11