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Water’s Journey Through
                                       the Shale Gas Drilling and
                                       Production Processes in the
                                       Mid-Atlantic Region




The Mid-Atlantic Water Program is a
coordinated effort among Delaware
State University; University of
Delaware; University of the District
of Columbia; University of Maryland;
University of Maryland, Eastern
Shore; Penn State; Virginia State
University; Virginia Tech; and West
Virginia University.
Robert Donnan
Gas pipeline being laid along a stream, Wetzel County, West Virginia.




Cover: Marcellus shale drilling in progress, Beaver Run Reservoir, Westmoreland County. Credit: Robert Donnan.
Introduction

Water is a critical ingredient for extracting gas from the Marcel-     cellus development, see the Penn State Extension publication
lus shale, which lies up to 9,000 feet underground beneath south-      “River Basin Approaches to Water Management in the Mid-
ern New York, northern and western Pennsylvania, the eastern           Atlantic States” at extension.psu.edu/water/marcellus-shale
half of Ohio, and most of West Virginia. In the Mid-Atlantic           /regulations/river-basin-approaches-to-water-management
region the shale around most new gas wells has to be hydrauli-         -in-the-mid-atlantic-states.
cally fractured to release the trapped gas so that it can be brought   	     This publication illustrates the various paths for a water
to the surface. The drilling process itself can require more than      droplet used in the Marcellus shale natural gas industry in the
100,000 gallons of water, and the hydraulic fracturing (“frac-         Mid-Atlantic region. Using publicly available information,
ing”) process can require 2.5 million to 8 million gallons per         we attempt to track and quantify current water use through the
well. Fracing uses high-pressure water, sand, and chemicals to         stages of the gas well development process. This publication fo-
break up the gas-holding rock and create pathways for the flow         cuses mostly on Pennsylvania because it has the most Marcellus
of gas to the borehole.                                                drilling activity of any state to date. All data reported are based
	    Horizontal drilling is used to increase the well’s contact with   on wells in Pennsylvania. Much of the data comes from the
the shale rock formation. After drilling several thousand feet         Susquehanna River Basin Commission (SRBC), which has been
into the earth, this technology allows the borehole to be gradu-       out in front in collecting water use data. We raise issues pertinent
ally turned 90 degrees over several hundred feet and horizontal        to most other Mid-Atlantic states with Marcellus shale, as well
drilling to continue for about a mile. Fracing a horizontal well       as Ohio. For the purposes of illustration we have simplified vari-
requires significantly more water than a traditional vertical well.    ous steps in the process. Note also that other shale deposits, such
For a more detailed introduction to water-related issues sur-          as the Utica shale, underlie parts of these states. These may also
rounding the development of Marcellus shale natural gas wells,         eventually be drilled for gas, with the accompanying use of wa-
see the Penn State Water Resources Extension publication “In-          ter and generation of wastewater.
troduction to Hydrofracturing” at extension.psu.edu/water              	     Outside of the Susquehanna River basin, it is difficult to
/marcellus-shale/hydrofracturing/introduction-to                       accurately assess the amounts and sources of water used in Mar-
-hydrofracturing-1.                                                    cellus well development and the amounts of wastewater being
	    Development of the Marcellus shale resource in Pennsylva-         generated, treated, and disposed of through various paths. A sys-
nia began in 2007 and has proceeded rapidly. As of November            tem for tracking water flows has only recently been implemented
2011, there were about 4,200 wells tapping natural gas in the          in Pennsylvania and needs significant improvement. Additional
Marcellus shale in Pennsylvania, and more than 3,000 additional        errors may occur because of inconsistencies in how drilling com-
wells had been permitted but not yet drilled. As of April 2011,        panies self-reported water-related statistics. Numbers cited here
there were about 1,400 completed Marcellus wells in West Vir-          give insight only about general trends, but they are useful for
ginia and 1,300 wells permitted but not yet drilled.                   painting a big picture of the industry’s water use.
	    State and intrastate government agency resources are being        	     Challenges to safely disposing of Marcellus wastewater ex-
challenged to keep up with the rapid pace of shale gas develop-        ist from its generation in many places that already have water
ment. New technologies are being tried in both the resource            quality problems due to acidic mine drainage from coal mining.
development process and in managing environmental and water            This drainage impairs more than 3,000 miles of streams in Penn-
quality and quantity impacts. The regional river basin commis-         sylvania and about 5,000 miles in West Virginia. The presence
sions, which exist largely in the eastern part of the Marcellus        of acidic mine drainage and, in some areas, pollutants from other
region, have been actively addressing Marcellus water manage-          industries, such as public wastewater treatment facilities and
ment issues by developing regulations to address the industry’s        pharmaceutical and chemical manufacturers, reduces the ability
demands on water resources and potential quantity and quality          of waterways to assimilate pollutants in treated Marcellus waste-
issues. For more detail on river basin commission roles in Mar-        water.
Jeffery Mathison




Fracing a horizontal Marcellus well may          water that returns to the surface (called        municipal wastewater, abandoned mine
use 2.5 million to 8 million gallons of water,   “flowback water”) is the primary source          drainage water, or nonpotable water sold
typically within about a week. This water        of wastewater from shale gas drilling            by public water supply agencies) is usually
may come from surface or groundwater or          activities. Flowback water contains very         used for make-up water. Treated water may
emerging alternate sources such as mine          high amounts of total dissolved solids (salts    be discharged into a river, creek, lake, or
drainage. It is usually transported to the       and metals) and may also contain naturally       other surface water body only if it meets
drilling site via truck, but in some cases       occurring radioactive materials originating      stringent state discharge standards. Some
water pipelines are used.                        from the shale.                                  flowback water is disposed of without
	     Currently, in the Marcellus region two     	    Flowback water may be trucked to            treatment via underground injection
to eight gas production wells typically          a treatment facility and treated, and then       into suitable geologic formations very
extend underground in various directions         trucked to another well pad, where it is         far below the lowest fresh groundwater
from one 3- to 5-acre well pad. At the           stored in lagoons or tanks until it is reused.   zone, although this activity is extremely
well pad water is mixed with sand and            Frac-related water treatment often occurs        limited in Pennsylvania. In Pennsylvania,
chemicals that may include oils, gels, acids,    farther from the drill pad than does water       this process requires a permit from both
alcohols, and various manufactured organic       acquisition.                                     the U.S. Environmental Protection Agency
chemicals. This solution, called “frac           	    Because only about 10 percent of the        (EPA) and the Pennsylvania Department of
water,” is then forced under high pressure       frac water is recaptured as flowback water,      Environmental Protection (PaDEP).
into the subsurface rock formation at            and some of that water is subsequently lost      	    The well development process
the appropriate depth. Depending on              during the treatment process, additional         includes a number of points where
the area within the Marcellus region,            water (termed “make-up water”) typically         accidents, spills, or leaks could occur due
between 60 and 90 percent of this water          has to be added to the treated flowback          to mechanical failure or human error. More
remains underground, where it is trapped         water. Fresh water, or relatively clean          detail about each of these processes is
within the shale formation itself. The           water from another source (such as treated       included below.
A. Water Acquisition

About two-thirds of the fresh water used
for fracing is withdrawn from permitted
surface water sources and 30 percent is
purchased from public water suppliers.
The average amount of water used to hy-
draulically fracture a well is approximately
4.2 million gallons, 90 percent of which is
fresh water and 10 percent is reused flow-
back water from a previous well fracing.
These numbers are based strictly on water
withdrawal activity in the Susquehanna
River basin in Pennsylvania from June
2008 to August 1, 2011 (831 wells report-
ing). Surface water is a primary source for
hydraulic fracturing because it is acces-
sible to most drilling sites and is therefore
less costly to use. In some cases, discharg-
es of pollutants, such as acidic mine drain-
age, from upstream sources can adversely
affect the quality of the water that the gas
industry wishes to use, necessitating treat-
ment before use.
	    Regulatory requirements govern-
ing withdrawals for Marcellus drilling
operations are in flux throughout the Mid-
Atlantic region. Pennsylvania’s regulatory
climate is currently more settled than the
others in the region, although some observ-
ers expect further revision of the state’s
oil and gas laws or regulations in the near                                                                                                     Chuck Anderson
future. Because of concerns with shale gas
in various parts of the country, EPA is con-    Table 1. Water withdrawal requirements and state of the industry in the Mid-Atlantic states.
sidering more oversight of state handling of    Jurisdiction             Activity                       Water withdrawal requirement
environmental aspects of this industry.         Pennsylvania             Active drilling and production Water management plan required for Marcellus
	    The government institutions involved                                                               operations throughout state; Act 220 (Water
in water acquisition for Marcellus drilling                                                             Resources Planning Act) requirements must also
and the process and approvals required                                                                  be met if withdrawal meets Act 220 threshold
differ by state and even within states              Susquehanna          Active drilling and production Above, plus SRBC approval required
(Table 1). For example, water withdrawals           River basin
of any amount in the Susquehanna River              Delaware             Drilling suspended pending       Water management plan, Act 220 requirements,
watershed to develop gas wells in the               River basin          development of revised           plus DRBC approval required
Marcellus and other shale formations re-                                 regulations by Delaware River
quire approvals from the SRBC, a federal/                                Basin Commission (DRBC)
interstate commission that seeks to protect     New York                 State government is taking     New water withdrawal permitting law passed;
                                                                         steps to end effective         applications for withdrawal of 2 million gallons a
and manage the water resources of the ba-
                                                                         moratorium on Marcellus        day or more will likely be due by Feb. 2015, while
sin. Water withdrawals are also regulated
                                                                         drilling                       those for 0.5–1.99 MGD will not be due until Feb.
by the PaDEP throughout Pennsylvania,                                                                   2016;* SRBC approval would also be required
including in areas of the state within the      West Virginia            Active drilling and production Water management plan to West Virginia
Ohio River basin. The Delaware River                                                                    Department of Environmental Protection required
Basin Commission has the authority to                                                                   for companies that withdraw more than 210,000
regulate water withdrawals and discharges                                                               gallons of water per month
and is currently developing regulations         Maryland                 Leasing activity; a few
specifically for the natural gas industry.                               drilling permit applications;
Regardless of which river basin the water                                Department of the Environment
source is located in, an approved water                                  proposed two-year drilling
management plan is required as a special                                 delay (Feb. 2011)
condition of a well permit under the Oil        *See “Draft Supplemental Generic Environmental Impact Statement,” www.dec.ny.gov/energy/75370.html. The new law
and Gas Act throughout Pennsylvania.            was signed on August 15, 2011.
Some water for fracing is withdrawn
                                                                                    B. Water Use
                                      from pristine headwater streams, some
                                      of which may run low on water during          Of the water used to frac a well, about 90      into the atmosphere when the natural gas
                                      seasonal droughts in summer and fall.         percent is fresh and 10 percent is reused       is combusted.
                                      This occurred a few times in Pennsylva-       from a previous frac job. These numbers         	     There is no publicly available
                                      nia, mostly in the early years of Marcel-     are based strictly on withdrawals in the        evidence to date that groundwater con-
                                      lus development. The SRBC considers           Susquehanna River basin in Pennsylvania         tamination with fluids used in hydraulic
                                      cumulative flow impacts when regulating       from June 2008 to August 1, 2011 (831           fracturing has occurred as a direct result
                                      surface withdrawals to protect against        wells reporting). After the fracing, about      of the fracing process in the Marcellus. A
                                      loss of water for other beneficial uses by    10 percent (for these 831 wells) of the         typical Marcellus gas well extends 4,000
                                      specifying that water withdrawal must be      water injected into the ground returns to       to 8,500 feet into the earth. In Pennsyl-
                                      limited or stopped when certain low flow      the land surface within 30 days (this por-      vania, groundwater-bearing rock layers
                                      volumes are reached. In summer 2011,          tion is called flowback water), and the         tapped for private water wells typically
                                      SRBC ordered gas companies to stop wa-        rest remains underground, absorbed by           extend only 20 to 500 feet below the
                                      ter withdrawals from about 40 permitted       the relatively dry shale bed. Wider ranges      surface. Because of the large distances
                                      locations because of low flows.               of flowback water amounts may be expe-          between the Marcellus shale layer and
                                      	    In the Mid-Atlantic, water avail-        rienced outside the Susquehanna River           the much shallower “fresh” groundwater
                                      ability changes from season to season         basin in Pennsylvania.                          tapped by drinking water wells, there is
                                      and year to year. If a drought occurs,        	    Once the well is in production, wa-        little chance that the water used to frac
                                      some surface water sources become             ter generated is called produced water          the Marcellus shale layer could later
                                      temporarily unavailable for Marcellus         or production water. Produced water is          contaminate these private water wells.
                                      withdrawals. Pennsylvania, New York,          removed from the gas at the top of the          Except under pressure, water does not run
                                      and both of the river basin commissions       wellhead before the gas goes into the           up hill. Stricter state regulations that went
                                      have or are developing rules through          pipeline. This water is stored onsite and       into effect in Pennsylvania in early 2011
                                      which minimum “stream pass-by flows”          periodically removed for treatment or           require more protective well casing and
                                      will be established and incorporated into     disposal. It is generated at lower volumes      cementing practices through the ground-
                                      water withdrawal permits. Stream pass-        than flowback throughout the operational        water-bearing rock layers to help prevent
                                      by flows are meant to ensure that enough      life of the well.                               this problem.
                                      water remains within the waterway to          	    Some laypeople and water manage-           	     There have been incidents of stray or
                                      protect the aquatic habitat and indigenous    ment professionals have raised concerns         migrating methane gas that has affected
                                      species as well as any downstream water       about the large amounts of water that           private water wells located near Marcel-
                                      quantity needs.                               remain below ground after fracing—that          lus wells in some areas of Pennsylvania.
                                      	    Water quantity and quality are close-    this water may be permanently (or at least      Methane migration has typically been
                                      ly linked. At low flow, streams are more      in the very long term) removed from the         traced to faulty well casings or inad-
                                      sensitive to the addition of potential con-   water cycle. At this time it is premature to    equate cement seals on the wells. The
                                      taminants because less water is available     conclude this because data for produced         stricter well construction and casing regu-
                                      for diluting pollutants.                      water are limited. The shale may absorb         lations in Pennsylvania should reduce the
                                      	    Many areas of the Mid-Atlantic, both     the water. In addition to the flowback and      potential for this problem to occur in the
                                      within and outside the Marcellus shale        produced water that returns to the earth’s      future. These regulations were strength-
                                      field, have no river basin commission         surface to rejoin the water cycle once          ened in response to these methane migra-
                                      focused on water quantity. This has raised    treated, water vapor is released back           tion incidents.
                                      a number of issues about equity and
                                      uniform permit requirements. In Pennsyl-
                                      vania, for example, PaDEP is applying
                                      SRBC’s low-flow guidelines in the area
                                      of the state outside SRBC’s and DRBC’s
                                      oversight to ensure a consistent regula-
                                      tory approach statewide.
Kathy Pike, Altoona Water Authority




                                                                                                                                                                               Craig McKibben




                                      A bulk water filling station operated by      A Marcellus site in Bradford County, Pa. The red tanks hold water.
                                      Altoona Water Authority, Pa.
C. Wastewater Treatment

Of the water used in fracing that returns
to the land surface as flowback water,
some of it may be reused in another frac
job. This practice has been increasing in
Pennsylvania over the last several years.
The average percentage of flowback
water now reused in Pennsylvania is un-
certain, but it is estimated to be about 75
percent. Nearly all of this flowback water
is treated prior to reuse. Only about 5 per-
cent is disposed of without treatment via
underground injection (data from PaDEP
for July to December 2011).
	     Flowback water presents treatment
challenges because it contains extremely
high amounts of total dissolved solids
(TDS). The longer frac water remains
below ground in contact with the shale,
the more TDS, metals, and naturally oc-
curring radioactivity it picks up from the




                                                                                                                                       Patrick Drohan
rock. Produced water also contains these
pollutants, and at higher concentrations
than in flowback.                              Close-up of Marcellus impoundment, Clearfield County, Pa.
	     In Pennsylvania in 2010 new regula-
tions affecting discharges of natural gas      ties; or underground injection. These are     	    Many industrial treatment plants
wastewater (including both flowback            discussed in more detail below.               treat high-TDS wastewater by combining
and produced water) high in TDS took           	     Most municipal wastewater treat-        traditional physical/chemical processes
effect to protect water bodies and public      ment plants, which use a biological treat-    with thermal distillation and end up
drinking water. The regulations limit the      ment system, are not set up to adequately     with concentrated brine that is typically
amount of TDS and other pollutants that        treat the high-TDS flowback water. All        disposed of in permitted deep injection
can be discharged into waterways. The          they can do is dilute the TDS, which is       disposal wells. Crystallizers have been
regulations established effluent standards     insufficient given the large volume of        proposed to create salt, but this waste-
for natural gas wastewater of 500 mil-         flowback water generated in some locali-      water treatment by-product would then
ligrams per liter (mg/L) for TDS, 250          ties. PaDEP asked gas drilling operators      have to be landfilled, triggering another
mg/L for chlorides, and 10 mg/L for bari-      to voluntarily stop using these plants for    set of regulatory requirements. Other ad-
um and strontium for new and expanding         Marcellus wastewater disposal by May          vanced wastewater treatment techniques
facilities treating natural gas wastewa-       2011 because of mounting water qual-          under development involve membranes
ter. These four standards are based on         ity concerns downstream of municipal          and ultrafiltration, but these systems also
monthly averages. Discharges of water          wastewater discharge points. Agency           produce a concentrated brine solution as
containing elevated levels of TDS exist-       data from 2011 indicate that statewide        a waste by-product, which must be prop-
ing prior to August 21, 2010, are exempt       use of municipal wastewater treatment         erly disposed of.
from the regulation unless or until they       plants accounts for less than 1 percent       	    Only a few advanced treatment sys-
expand. The May 2011 PaDEP request to          of the volume of Marcellus wastewater         tems are already operational in Pennsyl-
the industry to cease disposal of Marcel-      disposed of in the state. The discharge       vania, but dozens of other technologies
lus wastewater at publicly owned treat-        of high volumes of treated Marcellus          were in the permit application process in
ment plants virtually shut down this type      wastewater from a biological treatment        mid-2011.
of treatment, although drilling wastewater     system could be of particular concern for     	    Underground injection is discussed
from traditional shallow wells is still go-    waterways that have limited ability to as-    in the next section because no treatment
ing to these plants.                           similate additional salt loadings. Bromide    is performed before injection.
	     Current options for treatment of         was of special concern to state regulators
flowback water include onsite or offsite       because it combines with chlorine added
dedicated treatment facilities, a few of       during public water supply treatment to
which are already operational, but many        form trihalomethanes, which can cause
more of which are proposed and/or under        cancer in humans over the long term if in
construction; reuse with or without pre-       high enough concentration in sources of
treatment on or offsite; advanced facili-      drinking water.
D. Wastewater Discharge/Return


                Reuse                                           months of 2011, this value decreased to      is not clear if these numbers reflect current
                Many drilling companies aim to reuse            about 35 percent. At least some of these     or future water flows across the region.
                100 percent of the flowback water. With         facilities are explicitly set up to treat    West Virginia has had a wastewater report-
                the publicly available reporting system         water and return it to the operators (the    ing system since April 2010, and the first
                currently in place, it is difficult to as-      water trucks are full in both directions).   report is expected in November 2011. New
                certain whether the companies are able          In 2011, this process of treatment and       York has proposed such a system.
                to reach these very high levels of reuse.       return of wastewater has been reported as
                Reuse reduces the total amount of fresh         “reuse” rather than “brine or industrial”    Underground Injection
                water needed and wastewater generated           treatment, partially explaining the large    In underground injection, untreated Mar-
                as well as associated truck trips.              difference in values between the two time    cellus wastewater is forced below ground
                	    It is difficult to accurately assess the   periods. Likewise, reported reuse ac-        out into rocks bounded above by an im-
                amounts of Marcellus wastewater being           counted for about 25 percent of tracked      permeable rock layer(s). This injection is
                treated and disposed of via the various         wastewater during the last six months of     regulated under the federal Safe Drinking
                paths because a system for tracking this        2010 but increased to about 55 percent       Water Act and requires an underground
                wastewater has only recently been de-           during the first six months of 2011. As      injection control (UIC) permit. EPA is
                veloped in Pennsylvania and it needs to         noted above, statistics cited here may       responsible for permitting these wells in
                be refined to capture the true amount of        indicate trends and are useful for get-      Pennsylvania (about 8 wells) and New
                wastewater recycling. Further confusion         ting a big-picture sense of the industry’s   York (6 wells). The state environmental
                may result from inconsistencies in how          water use. It is unclear from the 2011       agencies administer EPA’s Underground
                drilling companies self-reported waste-         PaDEP database how about 5 percent of        Injection Control Program in West Vir-
                water statistics, how to define “wastewa-       the Marcellus wastewater is treated and/     ginia (74 wells), Ohio (~170 wells), and
                ter,” and how to classify landfilled wastes     or disposed of, but the 5 percent could be   Maryland (no wells). Pennsylvania’s
                that contain water. Given these caveats,        lost in sludge or evaporate, or is within    wells have little or no available capacity,
                according to the PaDEP data, industry re-       the measurement error of the various flow    so most Marcellus wastewater disposed
                ported that about 65 percent of the waste       meters used.                                 of via this route is trucked to West Vir-
                fluid went to “brine or industrial” treat-      	    No state in the region other than       ginia or Ohio. In addition, some experts
                ment facilities during the last six months      Pennsylvania has yet reported data on        believe that much of the geology of Penn-
                of 2010. However, during the first six          Marcellus wastewater management, so it       sylvania may not be suitable for these
                                                                                                             wells, but several proposed wells are un-
                                                                                                             der review by EPA. Underground injec-
                                                                                                             tion is commonly used in other shale gas
                                                                                                             fields, such as the Barnett shale in Texas,
                                                                                                             where the geology is more suitable.
                                                                                                             	     PaDEP data show that about 400
                                                                                                             million gallons of Marcellus wastewater
                                                                                                             were generated in the first six months of
                                                                                                             2011 in Pennsylvania. Twenty-one mil-
                                                                                                             lion gallons were disposed of in Ohio
                                                                                                             underground injection wells and a very
                                                                                                             small amount—about 5,000 gallons—in
                                                                                                             West Virginia underground injection
                                                                                                             wells during the same period. These data
                                                                                                             are imperfect, as discussed above. Still,
                                                                                                             the information is the best currently
                                                                                                             available. At this point it appears that out-
                                                                                                             of-state disposal accounts for relatively
Robert Donnan




                                                                                                             little in the bigger picture of the indus-
                                                                                                             try’s overall wastewater disposal.
                Residual wastewater tanker headed south on I-79 near Washington, Pa.
Accidents, Spills, and Leaks

The chemicals used in fracing may              Environmental Protection requires such        to meet the state’s best management prac-
include oils, gels, acids, alcohols, and       disclosure for companies that withdraw        tice requirements, which are intended to
various manufactured organic chemicals,        more than 210,000 gallons of water per        protect against environmental damage in
which are often transported to drill pads      month in the state.                           case of an accident, spill, or leak. Most
on rural roads. The storage, treatment,        	    The overall drilling process includes    operators now use closed-loop drilling
and return of these waste fluids to the        numerous points where accidents, spills,      mud systems, steel tanks, secondary con-
environment are water quality concerns.        or leaks could occur, potentially affecting   tainment, and lined well pads to minimize
SRBC and DRBC require disclosure of            surface and/or groundwater. These releas-     the potential for a release of any fluids
the chemicals used in well development,        es could result from mechanical failure       and to capture it should a release occur.
although the exact ratios are proprietary.     or human error. Water resources could be      	    States and river basin commissions
PaDEP regulations that took effect in          affected by a well blowout; spill of frac-    are reviewing their regulatory require-
2011 also require that the chemicals used      ing chemicals or flowback water, includ-      ments to identify ways to further protect
to frac wells be submitted as part of the      ing tanker truck accident; tank rupture;      waterways and other natural resources
well completion report. Under an emer-         equipment failure; vandalism; or fire. As     in the face of accidents, spills, and leaks
gency order issued by the governor in          a condition of their stormwater manage-       related to Marcellus drilling.
July 2011, West Virginia Department of         ment permits, gas companies are required




                                                                                                                                      Robert Donnan




Active Marcellus drilling site and impoundment, Greene County, Pa.
Conclusion

Water’s journey through the Marcellus            activities in states in the Marcellus region   States that are now or will develop data-
shale drilling and production processes          can meet the applicable standards to pro-      bases could learn from the revisions to
is complex and roundabout. Some water            tect water resources.                          Pennsylvania’s database.
no longer cycles because it is trapped in        	     Throughout the region the rami-          	    Future developments to watch for
the shale as a consequence of hydraulic          fications of the different states’ policy      include new regulations and legislation
fracturing. We need to understand where          responses to the recent boom in gas in-        in Pennsylvania, Maryland, Ohio, New
the water from this industry comes from,         dustry exploration and development in          York, and West Virginia; the potential
how it is handled and what the industry          the Marcellus region remain unclear. As        for a greater role for the U.S. EPA in
adds to it, how it is treated, and how           of December 2011, New York, Maryland,          management and oversight of gas well
much of it returns to the water cycle. We        West Virginia, and the Delaware River          wastewater reuse and disposal; river ba-
also need to know about places where             Basin Commission have yet to establish         sin commission rulemaking; out-of-basin
water essentially leaves the water cycle         clear policies and administrative rules        and out-of-state flows of fresh water and
or is moved across watershed boundaries.         for permitting well drilling and water         wastewater; radioactivity in wastewater;
Having this knowledge helps us identify          withdrawals. The evolving nature of wa-        potential innovation in wastewater treat-
points of concern about water quality            ter resources policy is a source of great      ment technologies; increased reuse of
and/or quantity.                                 uncertainty influencing development of         wastewater; and improved systems for
	    This publication discusses water use        the Marcellus shale gas play. The pace of      tracking Marcellus freshwater and waste-
by the industry at multiple levels—re-           institutional change is rapid, but the pace    water flows.
gional, local, and the drilling pad itself. At   of industrial change is even faster. Check
each level different issues are important.       the resources below for updated informa-
For example, at a regional level, some wa-       tion.
ter managers are concerned about tracking        	     The other source of uncertainty re-
out-of-basin transfers of water for fracing      lated to water in the Marcellus industry
and wastewater treatment. At the local           is how and where its wastewater will be
level, we want to be sure that streams are       treated and discharged or disposed in the
not dewatered (pass-by flow requirements         future. There is a rush to develop new
would prevent this), especially during           treatment technologies and permit and
drought. At the drilling pad level, concerns     build new treatment plants, but capacity is
often center around what chemicals are           still lacking within Pennsylvania. Only a
added to the frac water and the potential        small percentage of Marcellus wastewater
for damage to local water resources due to       leaves Pennsylvania, but it’s unclear what
accidents, spills, and leaks.                    would happen if Pennsylvania was forced
	    Water acquisition and water dis-            to handle all wastes that are now disposed
charge/return illustrate how the decisions       of via underground injection, landfills, and
made within one state, such as Penn-             treatment facilities in other states.
sylvania’s recent call to the natural gas        	     Note again that some of the data pre-
industry to stop sending Marcellus waste-        sented here are preliminary and are based
water to municipal wastewater treatment          on the industry’s self-reporting to a new
plants, affect other states—in this case by      database that has acknowledged weak-
transportation of wastewater to Ohio and         nesses and is currently under revision.
West Virginia treatment facilities and un-       The data presented are for Pennsylvania
derground injection wells. The transport         only because the industry’s development
of water or wastewater across state and/         is farthest along there and that is where
or river basin lines interrupts the water        data are available. Numbers will likely
cycle, although the amount of interbasin         vary for other states based on local condi-
transfers currently occurring is a rela-         tions. This publication points out defi-
tively small volume of water.                    ciencies in our knowledge about water’s
	    Aside from the land area within the         journey through the Marcellus shale natu-
Delaware River basin, the Marcellus area         ral gas drilling and production process.
is not covered by one river basin com-           	     The caveats about the data also point
mission with both water quantity and             out the need for better Marcellus water
quality regulatory authority. Because of         and wastewater data systems in Pennsyl-
this, there may be a lack of consideration       vania. Ideally, data systems should be de-
for the broader watershed picture. Water         veloped collaboratively among states in
doesn’t stop flowing at state boundar-           the region so that valid data comparisons
ies. More interstate and possibly federal        could be made across states and out-of-
cooperation and coordination may be              basin transfers of water could be tracked.
needed to ensure that gas exploration
Resources                                                                              Acknowledgments

Abdalla, C., and J. Drohan. “Marcellus      Susquehanna River Basin Commission.        This material is based on work supported
Education Fact Sheet: Water Withdrawals     “Managing and Protecting Water             in part by the National Institute of Food
for Development of Marcellus Shale Gas      Resources in the Susquehanna River         and Agriculture, U.S. Department of
in Pennsylvania.” University Park: Penn     Basin.” Presented August 19, 2010, at      Agriculture, under Agreement No. 2008-
State Cooperative Extension, 2010. pubs     Marywood University.                       51130-19500. Sincere thanks to the fol-
.cas.psu.edu/FreePubs/pdfs/ua460.pdf        www.srbc.net/programs/docs/JLRH%20         lowing reviewers for helpful comments
                                            presentation%20MarywoodUniversity          and suggestions:
Abdalla, C., J. Drohan, B. Swistock, and    .pdf.                                      •	 Paula Ballaron, manager, policy imple-
S. Boser. “Marcellus Shale Gas Well                                                       mentation and outreach, and Andrew
Drilling: Regulations to Protect Water      Swistock, B. “Water Facts #28: Gas Well       Gavin, manager, monitoring and pro-
Supplies in Pennsylvania.” University       Drilling and Your Private Water Supply.”      tection program, Susquehanna River
Park: Penn State Cooperative Extension,     University Park: Penn State Cooperative       Basin Commission
2011. extension.psu.edu/water/marcellus     Extension, 2011. extension.psu.edu         •	 Jim Clark, extension educator, McKean
-shale/regulations/regulations-to-protect   /water/marcellus-shale/drinking-water         County; Tom Murphy, extension educa-
-water-supplies-in-pennsylvania-1.          /gas-well-drilling-and-your-private           tor, Lycoming County, and codirector
                                            -water-supply-2/gas-well-drilling-and         of the Marcellus Center for Outreach
Abdalla, C., J. Drohan, K. Saacke Blunk,    -your-private-water-supply/view.              and Research; and David Yoxtheimer,
and J. Edson. “Marcellus Shale Wastewa-                                                   extension associate in earth and mineral
ter Issues in Pennsylvania—Current and      West Virginia Department of Environ-          sciences, Penn State
Emerging Treatment and Disposal Tech-       mental Protection, Resources from the
                                                                                       •	 Libby Ford, senior environmental
nologies.” University Park: Penn State      Office of Oil and Gas: www.dep.wv.gov
                                                                                          health engineer, Nixon Peabody
Cooperative Extension, 2011. extension      /oil-and-gas/Resources/Pages/default
.psu.edu/water/marcellus-shale/waste        .aspx.                                     •	 Elizabeth Nolan and Trisha Salvia, as-
-water/current-and-emerging-treatment                                                     sistant counsels, Bureau of Regulatory
-and-disposal-technologies-1.                                                             Counsel; Eugene Pine, chief, subsur-
                                                                                          face activities section, Bureau of Oil
Delaware River Basin Commission:                                                          and Gas Management; and Seth Pelep-
www.state.nj.us/drbc                                                                      ko, Bureau of Planning and Program
                                                                                          Management, Pennsylvania Department
New York State Department of Environ-                                                     of Environmental Protection
mental Conservation (NYSDEC). “Pre-                                                    Any opinions, findings, conclusions, or
liminary Revised Draft Supplemental Ge-                                                recommendations expressed in this pub-
neric Environmental Impact Statement on                                                lication are those of the author(s) and do
the Oil, Gas, and Solution Mining Regu-                                                not necessarily reflect the view of the U.S.
latory Program, Well Permit Issuance for                                               Department of Agriculture.
Horizontal Drilling and High-Volume
Hydraulic Fracturing to Develop the Mar-                                               Prepared by Charles Abdalla, professor of ag-
cellus Shale and Other Low-Permeability                                                ricultural and environmental economics, Penn
Gas Reservoirs.” Albany: NYSDEC, Di-                                                   State; Joy Drohan, freelance science writer and
vision of Mineral Resources, 2011.                                                     editor; Brian Rahm, research associate, New
www.dec.ny.gov/energy/75370.html.                                                      York State Water Resources Institute; Jeffrey
                                                                                       Jacquet, Ph.D. candidate, Department of Natu-
                                                                                       ral Resources, Cornell University; John Becker,
Penn State Extension Natural Gas Web-
                                                                                       professor emeritus of agricultural economics
site: extension.psu.edu/naturalgas                                                     and law, Penn State; Alan Collins, professor
                                                                                       of agricultural and resource economics, West
Pennsylvania Department of Environ-                                                    Virginia University; Allen Klaiber, assistant
mental Protection Marcellus Information:                                               professor of agricultural economics, Ohio
www.portal.state.pa.us/portal/server.pt                                                State; Gregory Poe, professor of environmental
/community/marcellus_shale/20296                                                       policy, Cornell University; and Deb Grantham,
                                                                                       water resources specialist, Cornell University.
Susquehanna River Basin Commission:
www.srbc.net
A cooperative effort of
Penn State,
Cornell University,
West Virginia University,
Ohio State University

extension.psu.edu




Penn State College of Agricultural Sciences re-
search and extension programs are funded in part by
Pennsylvania counties, the Commonwealth of Penn-
sylvania, and the U.S. Department of Agriculture.
This publication is available from the Publications
Distribution Center, The Pennsylvania State Univer-
sity, 112 Agricultural Administration Building, Uni-
versity Park, PA 16802. For information telephone
814-865-6713.
Where trade names appear, no discrimination is
intended, and no endorsement by Penn State Coop-
erative Extension is implied.

This publication is available in alternative
media on request.
The Pennsylvania State University is committed to
the policy that all persons shall have equal access
to programs, facilities, admission, and employ-
ment without regard to personal characteristics not
related to ability, performance, or qualifications
as determined by University policy or by state or
federal authorities. It is the policy of the University
to maintain an academic and work environment
free of discrimination, including harassment. The
Pennsylvania State University prohibits discrimina-
tion and harassment against any person because of
age, ancestry, color, disability or handicap, national
origin, race, religious creed, sex, sexual orientation,
gender identity, or veteran status. Discrimination or
harassment against faculty, staff, or students will not
be tolerated at The Pennsylvania State University.
Direct all inquiries regarding the nondiscrimina-
tion policy to the Affirmative Action Director, The
Pennsylvania State University, 328 Boucke Build-
ing, University Park, PA 16802-5901; Tel 814-865-
4700/V, 814-863-1150/TTY.
Produced by Ag Communications and Marketing
© The Pennsylvania State University 2012
Code # EE0023	         3.8M4/12CT 5133

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Water’s Journey Through the Shale Gas Drilling and Production Processes

  • 1. Water’s Journey Through the Shale Gas Drilling and Production Processes in the Mid-Atlantic Region The Mid-Atlantic Water Program is a coordinated effort among Delaware State University; University of Delaware; University of the District of Columbia; University of Maryland; University of Maryland, Eastern Shore; Penn State; Virginia State University; Virginia Tech; and West Virginia University.
  • 2. Robert Donnan Gas pipeline being laid along a stream, Wetzel County, West Virginia. Cover: Marcellus shale drilling in progress, Beaver Run Reservoir, Westmoreland County. Credit: Robert Donnan.
  • 3. Introduction Water is a critical ingredient for extracting gas from the Marcel- cellus development, see the Penn State Extension publication lus shale, which lies up to 9,000 feet underground beneath south- “River Basin Approaches to Water Management in the Mid- ern New York, northern and western Pennsylvania, the eastern Atlantic States” at extension.psu.edu/water/marcellus-shale half of Ohio, and most of West Virginia. In the Mid-Atlantic /regulations/river-basin-approaches-to-water-management region the shale around most new gas wells has to be hydrauli- -in-the-mid-atlantic-states. cally fractured to release the trapped gas so that it can be brought This publication illustrates the various paths for a water to the surface. The drilling process itself can require more than droplet used in the Marcellus shale natural gas industry in the 100,000 gallons of water, and the hydraulic fracturing (“frac- Mid-Atlantic region. Using publicly available information, ing”) process can require 2.5 million to 8 million gallons per we attempt to track and quantify current water use through the well. Fracing uses high-pressure water, sand, and chemicals to stages of the gas well development process. This publication fo- break up the gas-holding rock and create pathways for the flow cuses mostly on Pennsylvania because it has the most Marcellus of gas to the borehole. drilling activity of any state to date. All data reported are based Horizontal drilling is used to increase the well’s contact with on wells in Pennsylvania. Much of the data comes from the the shale rock formation. After drilling several thousand feet Susquehanna River Basin Commission (SRBC), which has been into the earth, this technology allows the borehole to be gradu- out in front in collecting water use data. We raise issues pertinent ally turned 90 degrees over several hundred feet and horizontal to most other Mid-Atlantic states with Marcellus shale, as well drilling to continue for about a mile. Fracing a horizontal well as Ohio. For the purposes of illustration we have simplified vari- requires significantly more water than a traditional vertical well. ous steps in the process. Note also that other shale deposits, such For a more detailed introduction to water-related issues sur- as the Utica shale, underlie parts of these states. These may also rounding the development of Marcellus shale natural gas wells, eventually be drilled for gas, with the accompanying use of wa- see the Penn State Water Resources Extension publication “In- ter and generation of wastewater. troduction to Hydrofracturing” at extension.psu.edu/water Outside of the Susquehanna River basin, it is difficult to /marcellus-shale/hydrofracturing/introduction-to accurately assess the amounts and sources of water used in Mar- -hydrofracturing-1. cellus well development and the amounts of wastewater being Development of the Marcellus shale resource in Pennsylva- generated, treated, and disposed of through various paths. A sys- nia began in 2007 and has proceeded rapidly. As of November tem for tracking water flows has only recently been implemented 2011, there were about 4,200 wells tapping natural gas in the in Pennsylvania and needs significant improvement. Additional Marcellus shale in Pennsylvania, and more than 3,000 additional errors may occur because of inconsistencies in how drilling com- wells had been permitted but not yet drilled. As of April 2011, panies self-reported water-related statistics. Numbers cited here there were about 1,400 completed Marcellus wells in West Vir- give insight only about general trends, but they are useful for ginia and 1,300 wells permitted but not yet drilled. painting a big picture of the industry’s water use. State and intrastate government agency resources are being Challenges to safely disposing of Marcellus wastewater ex- challenged to keep up with the rapid pace of shale gas develop- ist from its generation in many places that already have water ment. New technologies are being tried in both the resource quality problems due to acidic mine drainage from coal mining. development process and in managing environmental and water This drainage impairs more than 3,000 miles of streams in Penn- quality and quantity impacts. The regional river basin commis- sylvania and about 5,000 miles in West Virginia. The presence sions, which exist largely in the eastern part of the Marcellus of acidic mine drainage and, in some areas, pollutants from other region, have been actively addressing Marcellus water manage- industries, such as public wastewater treatment facilities and ment issues by developing regulations to address the industry’s pharmaceutical and chemical manufacturers, reduces the ability demands on water resources and potential quantity and quality of waterways to assimilate pollutants in treated Marcellus waste- issues. For more detail on river basin commission roles in Mar- water.
  • 4. Jeffery Mathison Fracing a horizontal Marcellus well may water that returns to the surface (called municipal wastewater, abandoned mine use 2.5 million to 8 million gallons of water, “flowback water”) is the primary source drainage water, or nonpotable water sold typically within about a week. This water of wastewater from shale gas drilling by public water supply agencies) is usually may come from surface or groundwater or activities. Flowback water contains very used for make-up water. Treated water may emerging alternate sources such as mine high amounts of total dissolved solids (salts be discharged into a river, creek, lake, or drainage. It is usually transported to the and metals) and may also contain naturally other surface water body only if it meets drilling site via truck, but in some cases occurring radioactive materials originating stringent state discharge standards. Some water pipelines are used. from the shale. flowback water is disposed of without Currently, in the Marcellus region two Flowback water may be trucked to treatment via underground injection to eight gas production wells typically a treatment facility and treated, and then into suitable geologic formations very extend underground in various directions trucked to another well pad, where it is far below the lowest fresh groundwater from one 3- to 5-acre well pad. At the stored in lagoons or tanks until it is reused. zone, although this activity is extremely well pad water is mixed with sand and Frac-related water treatment often occurs limited in Pennsylvania. In Pennsylvania, chemicals that may include oils, gels, acids, farther from the drill pad than does water this process requires a permit from both alcohols, and various manufactured organic acquisition. the U.S. Environmental Protection Agency chemicals. This solution, called “frac Because only about 10 percent of the (EPA) and the Pennsylvania Department of water,” is then forced under high pressure frac water is recaptured as flowback water, Environmental Protection (PaDEP). into the subsurface rock formation at and some of that water is subsequently lost The well development process the appropriate depth. Depending on during the treatment process, additional includes a number of points where the area within the Marcellus region, water (termed “make-up water”) typically accidents, spills, or leaks could occur due between 60 and 90 percent of this water has to be added to the treated flowback to mechanical failure or human error. More remains underground, where it is trapped water. Fresh water, or relatively clean detail about each of these processes is within the shale formation itself. The water from another source (such as treated included below.
  • 5. A. Water Acquisition About two-thirds of the fresh water used for fracing is withdrawn from permitted surface water sources and 30 percent is purchased from public water suppliers. The average amount of water used to hy- draulically fracture a well is approximately 4.2 million gallons, 90 percent of which is fresh water and 10 percent is reused flow- back water from a previous well fracing. These numbers are based strictly on water withdrawal activity in the Susquehanna River basin in Pennsylvania from June 2008 to August 1, 2011 (831 wells report- ing). Surface water is a primary source for hydraulic fracturing because it is acces- sible to most drilling sites and is therefore less costly to use. In some cases, discharg- es of pollutants, such as acidic mine drain- age, from upstream sources can adversely affect the quality of the water that the gas industry wishes to use, necessitating treat- ment before use. Regulatory requirements govern- ing withdrawals for Marcellus drilling operations are in flux throughout the Mid- Atlantic region. Pennsylvania’s regulatory climate is currently more settled than the others in the region, although some observ- ers expect further revision of the state’s oil and gas laws or regulations in the near Chuck Anderson future. Because of concerns with shale gas in various parts of the country, EPA is con- Table 1. Water withdrawal requirements and state of the industry in the Mid-Atlantic states. sidering more oversight of state handling of Jurisdiction Activity Water withdrawal requirement environmental aspects of this industry. Pennsylvania Active drilling and production Water management plan required for Marcellus The government institutions involved operations throughout state; Act 220 (Water in water acquisition for Marcellus drilling Resources Planning Act) requirements must also and the process and approvals required be met if withdrawal meets Act 220 threshold differ by state and even within states Susquehanna Active drilling and production Above, plus SRBC approval required (Table 1). For example, water withdrawals River basin of any amount in the Susquehanna River Delaware Drilling suspended pending Water management plan, Act 220 requirements, watershed to develop gas wells in the River basin development of revised plus DRBC approval required Marcellus and other shale formations re- regulations by Delaware River quire approvals from the SRBC, a federal/ Basin Commission (DRBC) interstate commission that seeks to protect New York State government is taking New water withdrawal permitting law passed; steps to end effective applications for withdrawal of 2 million gallons a and manage the water resources of the ba- moratorium on Marcellus day or more will likely be due by Feb. 2015, while sin. Water withdrawals are also regulated drilling those for 0.5–1.99 MGD will not be due until Feb. by the PaDEP throughout Pennsylvania, 2016;* SRBC approval would also be required including in areas of the state within the West Virginia Active drilling and production Water management plan to West Virginia Ohio River basin. The Delaware River Department of Environmental Protection required Basin Commission has the authority to for companies that withdraw more than 210,000 regulate water withdrawals and discharges gallons of water per month and is currently developing regulations Maryland Leasing activity; a few specifically for the natural gas industry. drilling permit applications; Regardless of which river basin the water Department of the Environment source is located in, an approved water proposed two-year drilling management plan is required as a special delay (Feb. 2011) condition of a well permit under the Oil *See “Draft Supplemental Generic Environmental Impact Statement,” www.dec.ny.gov/energy/75370.html. The new law and Gas Act throughout Pennsylvania. was signed on August 15, 2011.
  • 6. Some water for fracing is withdrawn B. Water Use from pristine headwater streams, some of which may run low on water during Of the water used to frac a well, about 90 into the atmosphere when the natural gas seasonal droughts in summer and fall. percent is fresh and 10 percent is reused is combusted. This occurred a few times in Pennsylva- from a previous frac job. These numbers There is no publicly available nia, mostly in the early years of Marcel- are based strictly on withdrawals in the evidence to date that groundwater con- lus development. The SRBC considers Susquehanna River basin in Pennsylvania tamination with fluids used in hydraulic cumulative flow impacts when regulating from June 2008 to August 1, 2011 (831 fracturing has occurred as a direct result surface withdrawals to protect against wells reporting). After the fracing, about of the fracing process in the Marcellus. A loss of water for other beneficial uses by 10 percent (for these 831 wells) of the typical Marcellus gas well extends 4,000 specifying that water withdrawal must be water injected into the ground returns to to 8,500 feet into the earth. In Pennsyl- limited or stopped when certain low flow the land surface within 30 days (this por- vania, groundwater-bearing rock layers volumes are reached. In summer 2011, tion is called flowback water), and the tapped for private water wells typically SRBC ordered gas companies to stop wa- rest remains underground, absorbed by extend only 20 to 500 feet below the ter withdrawals from about 40 permitted the relatively dry shale bed. Wider ranges surface. Because of the large distances locations because of low flows. of flowback water amounts may be expe- between the Marcellus shale layer and In the Mid-Atlantic, water avail- rienced outside the Susquehanna River the much shallower “fresh” groundwater ability changes from season to season basin in Pennsylvania. tapped by drinking water wells, there is and year to year. If a drought occurs, Once the well is in production, wa- little chance that the water used to frac some surface water sources become ter generated is called produced water the Marcellus shale layer could later temporarily unavailable for Marcellus or production water. Produced water is contaminate these private water wells. withdrawals. Pennsylvania, New York, removed from the gas at the top of the Except under pressure, water does not run and both of the river basin commissions wellhead before the gas goes into the up hill. Stricter state regulations that went have or are developing rules through pipeline. This water is stored onsite and into effect in Pennsylvania in early 2011 which minimum “stream pass-by flows” periodically removed for treatment or require more protective well casing and will be established and incorporated into disposal. It is generated at lower volumes cementing practices through the ground- water withdrawal permits. Stream pass- than flowback throughout the operational water-bearing rock layers to help prevent by flows are meant to ensure that enough life of the well. this problem. water remains within the waterway to Some laypeople and water manage- There have been incidents of stray or protect the aquatic habitat and indigenous ment professionals have raised concerns migrating methane gas that has affected species as well as any downstream water about the large amounts of water that private water wells located near Marcel- quantity needs. remain below ground after fracing—that lus wells in some areas of Pennsylvania. Water quantity and quality are close- this water may be permanently (or at least Methane migration has typically been ly linked. At low flow, streams are more in the very long term) removed from the traced to faulty well casings or inad- sensitive to the addition of potential con- water cycle. At this time it is premature to equate cement seals on the wells. The taminants because less water is available conclude this because data for produced stricter well construction and casing regu- for diluting pollutants. water are limited. The shale may absorb lations in Pennsylvania should reduce the Many areas of the Mid-Atlantic, both the water. In addition to the flowback and potential for this problem to occur in the within and outside the Marcellus shale produced water that returns to the earth’s future. These regulations were strength- field, have no river basin commission surface to rejoin the water cycle once ened in response to these methane migra- focused on water quantity. This has raised treated, water vapor is released back tion incidents. a number of issues about equity and uniform permit requirements. In Pennsyl- vania, for example, PaDEP is applying SRBC’s low-flow guidelines in the area of the state outside SRBC’s and DRBC’s oversight to ensure a consistent regula- tory approach statewide. Kathy Pike, Altoona Water Authority Craig McKibben A bulk water filling station operated by A Marcellus site in Bradford County, Pa. The red tanks hold water. Altoona Water Authority, Pa.
  • 7. C. Wastewater Treatment Of the water used in fracing that returns to the land surface as flowback water, some of it may be reused in another frac job. This practice has been increasing in Pennsylvania over the last several years. The average percentage of flowback water now reused in Pennsylvania is un- certain, but it is estimated to be about 75 percent. Nearly all of this flowback water is treated prior to reuse. Only about 5 per- cent is disposed of without treatment via underground injection (data from PaDEP for July to December 2011). Flowback water presents treatment challenges because it contains extremely high amounts of total dissolved solids (TDS). The longer frac water remains below ground in contact with the shale, the more TDS, metals, and naturally oc- curring radioactivity it picks up from the Patrick Drohan rock. Produced water also contains these pollutants, and at higher concentrations than in flowback. Close-up of Marcellus impoundment, Clearfield County, Pa. In Pennsylvania in 2010 new regula- tions affecting discharges of natural gas ties; or underground injection. These are Many industrial treatment plants wastewater (including both flowback discussed in more detail below. treat high-TDS wastewater by combining and produced water) high in TDS took Most municipal wastewater treat- traditional physical/chemical processes effect to protect water bodies and public ment plants, which use a biological treat- with thermal distillation and end up drinking water. The regulations limit the ment system, are not set up to adequately with concentrated brine that is typically amount of TDS and other pollutants that treat the high-TDS flowback water. All disposed of in permitted deep injection can be discharged into waterways. The they can do is dilute the TDS, which is disposal wells. Crystallizers have been regulations established effluent standards insufficient given the large volume of proposed to create salt, but this waste- for natural gas wastewater of 500 mil- flowback water generated in some locali- water treatment by-product would then ligrams per liter (mg/L) for TDS, 250 ties. PaDEP asked gas drilling operators have to be landfilled, triggering another mg/L for chlorides, and 10 mg/L for bari- to voluntarily stop using these plants for set of regulatory requirements. Other ad- um and strontium for new and expanding Marcellus wastewater disposal by May vanced wastewater treatment techniques facilities treating natural gas wastewa- 2011 because of mounting water qual- under development involve membranes ter. These four standards are based on ity concerns downstream of municipal and ultrafiltration, but these systems also monthly averages. Discharges of water wastewater discharge points. Agency produce a concentrated brine solution as containing elevated levels of TDS exist- data from 2011 indicate that statewide a waste by-product, which must be prop- ing prior to August 21, 2010, are exempt use of municipal wastewater treatment erly disposed of. from the regulation unless or until they plants accounts for less than 1 percent Only a few advanced treatment sys- expand. The May 2011 PaDEP request to of the volume of Marcellus wastewater tems are already operational in Pennsyl- the industry to cease disposal of Marcel- disposed of in the state. The discharge vania, but dozens of other technologies lus wastewater at publicly owned treat- of high volumes of treated Marcellus were in the permit application process in ment plants virtually shut down this type wastewater from a biological treatment mid-2011. of treatment, although drilling wastewater system could be of particular concern for Underground injection is discussed from traditional shallow wells is still go- waterways that have limited ability to as- in the next section because no treatment ing to these plants. similate additional salt loadings. Bromide is performed before injection. Current options for treatment of was of special concern to state regulators flowback water include onsite or offsite because it combines with chlorine added dedicated treatment facilities, a few of during public water supply treatment to which are already operational, but many form trihalomethanes, which can cause more of which are proposed and/or under cancer in humans over the long term if in construction; reuse with or without pre- high enough concentration in sources of treatment on or offsite; advanced facili- drinking water.
  • 8. D. Wastewater Discharge/Return Reuse months of 2011, this value decreased to is not clear if these numbers reflect current Many drilling companies aim to reuse about 35 percent. At least some of these or future water flows across the region. 100 percent of the flowback water. With facilities are explicitly set up to treat West Virginia has had a wastewater report- the publicly available reporting system water and return it to the operators (the ing system since April 2010, and the first currently in place, it is difficult to as- water trucks are full in both directions). report is expected in November 2011. New certain whether the companies are able In 2011, this process of treatment and York has proposed such a system. to reach these very high levels of reuse. return of wastewater has been reported as Reuse reduces the total amount of fresh “reuse” rather than “brine or industrial” Underground Injection water needed and wastewater generated treatment, partially explaining the large In underground injection, untreated Mar- as well as associated truck trips. difference in values between the two time cellus wastewater is forced below ground It is difficult to accurately assess the periods. Likewise, reported reuse ac- out into rocks bounded above by an im- amounts of Marcellus wastewater being counted for about 25 percent of tracked permeable rock layer(s). This injection is treated and disposed of via the various wastewater during the last six months of regulated under the federal Safe Drinking paths because a system for tracking this 2010 but increased to about 55 percent Water Act and requires an underground wastewater has only recently been de- during the first six months of 2011. As injection control (UIC) permit. EPA is veloped in Pennsylvania and it needs to noted above, statistics cited here may responsible for permitting these wells in be refined to capture the true amount of indicate trends and are useful for get- Pennsylvania (about 8 wells) and New wastewater recycling. Further confusion ting a big-picture sense of the industry’s York (6 wells). The state environmental may result from inconsistencies in how water use. It is unclear from the 2011 agencies administer EPA’s Underground drilling companies self-reported waste- PaDEP database how about 5 percent of Injection Control Program in West Vir- water statistics, how to define “wastewa- the Marcellus wastewater is treated and/ ginia (74 wells), Ohio (~170 wells), and ter,” and how to classify landfilled wastes or disposed of, but the 5 percent could be Maryland (no wells). Pennsylvania’s that contain water. Given these caveats, lost in sludge or evaporate, or is within wells have little or no available capacity, according to the PaDEP data, industry re- the measurement error of the various flow so most Marcellus wastewater disposed ported that about 65 percent of the waste meters used. of via this route is trucked to West Vir- fluid went to “brine or industrial” treat- No state in the region other than ginia or Ohio. In addition, some experts ment facilities during the last six months Pennsylvania has yet reported data on believe that much of the geology of Penn- of 2010. However, during the first six Marcellus wastewater management, so it sylvania may not be suitable for these wells, but several proposed wells are un- der review by EPA. Underground injec- tion is commonly used in other shale gas fields, such as the Barnett shale in Texas, where the geology is more suitable. PaDEP data show that about 400 million gallons of Marcellus wastewater were generated in the first six months of 2011 in Pennsylvania. Twenty-one mil- lion gallons were disposed of in Ohio underground injection wells and a very small amount—about 5,000 gallons—in West Virginia underground injection wells during the same period. These data are imperfect, as discussed above. Still, the information is the best currently available. At this point it appears that out- of-state disposal accounts for relatively Robert Donnan little in the bigger picture of the indus- try’s overall wastewater disposal. Residual wastewater tanker headed south on I-79 near Washington, Pa.
  • 9. Accidents, Spills, and Leaks The chemicals used in fracing may Environmental Protection requires such to meet the state’s best management prac- include oils, gels, acids, alcohols, and disclosure for companies that withdraw tice requirements, which are intended to various manufactured organic chemicals, more than 210,000 gallons of water per protect against environmental damage in which are often transported to drill pads month in the state. case of an accident, spill, or leak. Most on rural roads. The storage, treatment, The overall drilling process includes operators now use closed-loop drilling and return of these waste fluids to the numerous points where accidents, spills, mud systems, steel tanks, secondary con- environment are water quality concerns. or leaks could occur, potentially affecting tainment, and lined well pads to minimize SRBC and DRBC require disclosure of surface and/or groundwater. These releas- the potential for a release of any fluids the chemicals used in well development, es could result from mechanical failure and to capture it should a release occur. although the exact ratios are proprietary. or human error. Water resources could be States and river basin commissions PaDEP regulations that took effect in affected by a well blowout; spill of frac- are reviewing their regulatory require- 2011 also require that the chemicals used ing chemicals or flowback water, includ- ments to identify ways to further protect to frac wells be submitted as part of the ing tanker truck accident; tank rupture; waterways and other natural resources well completion report. Under an emer- equipment failure; vandalism; or fire. As in the face of accidents, spills, and leaks gency order issued by the governor in a condition of their stormwater manage- related to Marcellus drilling. July 2011, West Virginia Department of ment permits, gas companies are required Robert Donnan Active Marcellus drilling site and impoundment, Greene County, Pa.
  • 10. Conclusion Water’s journey through the Marcellus activities in states in the Marcellus region States that are now or will develop data- shale drilling and production processes can meet the applicable standards to pro- bases could learn from the revisions to is complex and roundabout. Some water tect water resources. Pennsylvania’s database. no longer cycles because it is trapped in Throughout the region the rami- Future developments to watch for the shale as a consequence of hydraulic fications of the different states’ policy include new regulations and legislation fracturing. We need to understand where responses to the recent boom in gas in- in Pennsylvania, Maryland, Ohio, New the water from this industry comes from, dustry exploration and development in York, and West Virginia; the potential how it is handled and what the industry the Marcellus region remain unclear. As for a greater role for the U.S. EPA in adds to it, how it is treated, and how of December 2011, New York, Maryland, management and oversight of gas well much of it returns to the water cycle. We West Virginia, and the Delaware River wastewater reuse and disposal; river ba- also need to know about places where Basin Commission have yet to establish sin commission rulemaking; out-of-basin water essentially leaves the water cycle clear policies and administrative rules and out-of-state flows of fresh water and or is moved across watershed boundaries. for permitting well drilling and water wastewater; radioactivity in wastewater; Having this knowledge helps us identify withdrawals. The evolving nature of wa- potential innovation in wastewater treat- points of concern about water quality ter resources policy is a source of great ment technologies; increased reuse of and/or quantity. uncertainty influencing development of wastewater; and improved systems for This publication discusses water use the Marcellus shale gas play. The pace of tracking Marcellus freshwater and waste- by the industry at multiple levels—re- institutional change is rapid, but the pace water flows. gional, local, and the drilling pad itself. At of industrial change is even faster. Check each level different issues are important. the resources below for updated informa- For example, at a regional level, some wa- tion. ter managers are concerned about tracking The other source of uncertainty re- out-of-basin transfers of water for fracing lated to water in the Marcellus industry and wastewater treatment. At the local is how and where its wastewater will be level, we want to be sure that streams are treated and discharged or disposed in the not dewatered (pass-by flow requirements future. There is a rush to develop new would prevent this), especially during treatment technologies and permit and drought. At the drilling pad level, concerns build new treatment plants, but capacity is often center around what chemicals are still lacking within Pennsylvania. Only a added to the frac water and the potential small percentage of Marcellus wastewater for damage to local water resources due to leaves Pennsylvania, but it’s unclear what accidents, spills, and leaks. would happen if Pennsylvania was forced Water acquisition and water dis- to handle all wastes that are now disposed charge/return illustrate how the decisions of via underground injection, landfills, and made within one state, such as Penn- treatment facilities in other states. sylvania’s recent call to the natural gas Note again that some of the data pre- industry to stop sending Marcellus waste- sented here are preliminary and are based water to municipal wastewater treatment on the industry’s self-reporting to a new plants, affect other states—in this case by database that has acknowledged weak- transportation of wastewater to Ohio and nesses and is currently under revision. West Virginia treatment facilities and un- The data presented are for Pennsylvania derground injection wells. The transport only because the industry’s development of water or wastewater across state and/ is farthest along there and that is where or river basin lines interrupts the water data are available. Numbers will likely cycle, although the amount of interbasin vary for other states based on local condi- transfers currently occurring is a rela- tions. This publication points out defi- tively small volume of water. ciencies in our knowledge about water’s Aside from the land area within the journey through the Marcellus shale natu- Delaware River basin, the Marcellus area ral gas drilling and production process. is not covered by one river basin com- The caveats about the data also point mission with both water quantity and out the need for better Marcellus water quality regulatory authority. Because of and wastewater data systems in Pennsyl- this, there may be a lack of consideration vania. Ideally, data systems should be de- for the broader watershed picture. Water veloped collaboratively among states in doesn’t stop flowing at state boundar- the region so that valid data comparisons ies. More interstate and possibly federal could be made across states and out-of- cooperation and coordination may be basin transfers of water could be tracked. needed to ensure that gas exploration
  • 11. Resources Acknowledgments Abdalla, C., and J. Drohan. “Marcellus Susquehanna River Basin Commission. This material is based on work supported Education Fact Sheet: Water Withdrawals “Managing and Protecting Water in part by the National Institute of Food for Development of Marcellus Shale Gas Resources in the Susquehanna River and Agriculture, U.S. Department of in Pennsylvania.” University Park: Penn Basin.” Presented August 19, 2010, at Agriculture, under Agreement No. 2008- State Cooperative Extension, 2010. pubs Marywood University. 51130-19500. Sincere thanks to the fol- .cas.psu.edu/FreePubs/pdfs/ua460.pdf www.srbc.net/programs/docs/JLRH%20 lowing reviewers for helpful comments presentation%20MarywoodUniversity and suggestions: Abdalla, C., J. Drohan, B. Swistock, and .pdf. • Paula Ballaron, manager, policy imple- S. Boser. “Marcellus Shale Gas Well mentation and outreach, and Andrew Drilling: Regulations to Protect Water Swistock, B. “Water Facts #28: Gas Well Gavin, manager, monitoring and pro- Supplies in Pennsylvania.” University Drilling and Your Private Water Supply.” tection program, Susquehanna River Park: Penn State Cooperative Extension, University Park: Penn State Cooperative Basin Commission 2011. extension.psu.edu/water/marcellus Extension, 2011. extension.psu.edu • Jim Clark, extension educator, McKean -shale/regulations/regulations-to-protect /water/marcellus-shale/drinking-water County; Tom Murphy, extension educa- -water-supplies-in-pennsylvania-1. /gas-well-drilling-and-your-private tor, Lycoming County, and codirector -water-supply-2/gas-well-drilling-and of the Marcellus Center for Outreach Abdalla, C., J. Drohan, K. Saacke Blunk, -your-private-water-supply/view. and Research; and David Yoxtheimer, and J. Edson. “Marcellus Shale Wastewa- extension associate in earth and mineral ter Issues in Pennsylvania—Current and West Virginia Department of Environ- sciences, Penn State Emerging Treatment and Disposal Tech- mental Protection, Resources from the • Libby Ford, senior environmental nologies.” University Park: Penn State Office of Oil and Gas: www.dep.wv.gov health engineer, Nixon Peabody Cooperative Extension, 2011. extension /oil-and-gas/Resources/Pages/default .psu.edu/water/marcellus-shale/waste .aspx. • Elizabeth Nolan and Trisha Salvia, as- -water/current-and-emerging-treatment sistant counsels, Bureau of Regulatory -and-disposal-technologies-1. Counsel; Eugene Pine, chief, subsur- face activities section, Bureau of Oil Delaware River Basin Commission: and Gas Management; and Seth Pelep- www.state.nj.us/drbc ko, Bureau of Planning and Program Management, Pennsylvania Department New York State Department of Environ- of Environmental Protection mental Conservation (NYSDEC). “Pre- Any opinions, findings, conclusions, or liminary Revised Draft Supplemental Ge- recommendations expressed in this pub- neric Environmental Impact Statement on lication are those of the author(s) and do the Oil, Gas, and Solution Mining Regu- not necessarily reflect the view of the U.S. latory Program, Well Permit Issuance for Department of Agriculture. Horizontal Drilling and High-Volume Hydraulic Fracturing to Develop the Mar- Prepared by Charles Abdalla, professor of ag- cellus Shale and Other Low-Permeability ricultural and environmental economics, Penn Gas Reservoirs.” Albany: NYSDEC, Di- State; Joy Drohan, freelance science writer and vision of Mineral Resources, 2011. editor; Brian Rahm, research associate, New www.dec.ny.gov/energy/75370.html. York State Water Resources Institute; Jeffrey Jacquet, Ph.D. candidate, Department of Natu- ral Resources, Cornell University; John Becker, Penn State Extension Natural Gas Web- professor emeritus of agricultural economics site: extension.psu.edu/naturalgas and law, Penn State; Alan Collins, professor of agricultural and resource economics, West Pennsylvania Department of Environ- Virginia University; Allen Klaiber, assistant mental Protection Marcellus Information: professor of agricultural economics, Ohio www.portal.state.pa.us/portal/server.pt State; Gregory Poe, professor of environmental /community/marcellus_shale/20296 policy, Cornell University; and Deb Grantham, water resources specialist, Cornell University. Susquehanna River Basin Commission: www.srbc.net
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