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Strategies 
and 
Considera@ons 
in 
Developing 
[©co 
2m01p4a 
Bnrye 
wnaerm 
Seci]e 
–nc 
New 
Materials 
for 
3D 
Prin@ng 
[ed, 
aIntce.] 
1 
Inside 
3D 
Prin@ng 
10/23/14 
Carlton 
Washburn 
Director 
of 
Business 
Intelligence
Inside 
3D 
Prin@ng 
– 
10/23/14 
2 
Transforming 
ideas 
into 
integrated 
solu@ons 
INVENT 
MANUFACTURE 
INTEGRATE 
Core 
competency 
and 
excep@onal 
exper@se 
in 
materials 
science 
related 
to 
advanced 
polymeric 
materials 
and 
their 
process 
integra@on
Inside 
3D 
Prin@ng 
– 
10/23/14 
3 
• 33 
years 
ago, 
in 
1981… 
– MTV 
was 
launched 
– Xerox 
introduced 
the 
computer 
mouse 
– IBM 
released 
the 
first 
PC 
• Model 
5150 
with 
a 
4.77-­‐MHz 
Intel 
8088 
processor 
• Base 
price 
of 
$1,565 
(> 
$4,000 
today) 
• Used 
MS-­‐DOS, 
released 
by 
Microsoa 
– L2 
was 
released 
by 
Brewer 
Science
At 
around 
the 
same 
@me… 
Inside 
3D 
Prin@ng 
– 
10/23/14 
4 
Bourell, 
D. 
L., 
et 
al. 
"A 
brief 
history 
of 
addi@ve 
manufacturing 
and 
the 
2009 
roadmap 
for 
addi@ve 
manufacturing: 
looking 
back 
and 
looking 
ahead." 
US-­‐Turkey 
Workshop 
on 
Rapid 
Technologies. 
2009. 
Herbert, 
3M, 
1979 
Photopolymer 
Kodama, 
Nagoya, 
1981 
Photopolymer 
Householder, 
patent 
1981 
Concrete
Inside 
3D 
Prin@ng 
– 
10/23/14 
5 
Over 
30 
years 
of 
innova@on 
3D 
Prin4ng 
1980s 
1990s 
2000s 
2010s 
Materials
Inside 
3D 
Prin@ng 
– 
10/23/14 
6 
All 
ini@al 
materials 
were 
commercially 
available 
O 
N2 
light 
H2O 
O OH 
+ N2 
Base insoluble sensitizer Base soluble photoproduct
1980s 
Inside 
3D 
Prin@ng 
– 
10/23/14 
7 
Over 
30 
years 
of 
innova@on 
3D 
Prin4ng 
Materials 
1990s 
2000s 
2010s
Inside 
3D 
Prin@ng 
– 
10/23/14 
8 
Material 
model 
Off 
the 
shelf 
Adapt 
Time 
Value
Determine 
specifica@ons 
Inside 
3D 
Prin@ng 
– 
10/23/14 
9 
How 
do 
you 
adapt 
a 
material? 
Find 
suitable 
materials 
Test 
Develop 
Commercialize
Inside 
3D 
Prin@ng 
– 
10/23/14 
10 
Which 
comes 
first, 
materials, 
processes, 
or 
tools? 
Work Breakdown Structure Timeline 
Jan Feb Mar Apr May Jun Jul 
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 
1.0 Project planning 
1.1 Determine scope statement 
1.2 Select team 
1.3 Plan activites 
2.0 Specifications 
3.0 Prototype 
3.1 Review design 
Build prototype 
Test A 
Test B 
Test C 
4.0 Select suppliers 
5.0 Verify tool design 
6.0 Qualifcation testing 
7.0 Redesign contingency 
8.0 Commercialization
Inside 
3D 
Prin@ng 
– 
10/23/14 
11 
Where 
are 
we 
today?
Inside 
3D 
Prin@ng 
– 
10/23/14 
12 
Processes 
Process 
Polymers 
Metals 
Other 
Vat 
Photopolymeriza@on 
(SLA) 
✓ 
Material 
Extrusion 
(FDM) 
✓ 
Material 
Jemng 
✓ 
Binder 
Jemng 
✓ 
✓ 
✓ 
Powder 
Bed 
Fusion 
✓ 
✓ 
Sheet 
Lamina@on 
✓ 
✓ 
Directed 
Energy 
Deposi@on 
✓ 
ASTM, 
Comminee 
F42 
on 
Addi@ve 
Manufacturing 
Technologies, 
West 
Conshohocken, 
Pa., 
2009.
Inside 
3D 
Prin@ng 
– 
10/23/14 
13 
Material 
extrusion 
Material 
Key 
Characteris@cs 
ABS-­‐M30, 
Versa@le, 
touch 
ABSplus 
ABS-­‐ESD7 
Electrosta@c 
discharge 
resistant 
ABS-­‐M30i 
Biocompa@ble 
ABSi 
Translucent 
PC 
Strong 
(tension) 
PC-­‐ABS 
Strong 
(impact) 
PC-­‐ISO 
Biocompa@ble 
ULTEM 
9085 
Mechanically 
well-­‐rounded, 
FST 
cer@fica@on 
PPSF 
Resistant, 
both 
thermal 
and 
chemical 
Nylon 
12 
Strong 
(high 
fa@gue 
resistance) 
PLA 
Color 
selec@on, 
defini@on, 
plant-­‐based
Inside 
3D 
Prin@ng 
– 
10/23/14 
14 
SLA 
and 
SLS 
Stereolithography 
SLA 
Materials 
Laser 
Sintering 
SLS 
Materials 
1 
Accura® 
25 
CastForm™ 
PS 
2 
Accura® 
48HTR 
DuraForm® 
EX 
Black 
3 
Accura® 
55 
DuraForm® 
EX 
Natural 
4 
Accura® 
60 
DuraForm® 
Flex 
5 
Accura® 
ABS 
Black 
(SL 
7820) 
DuraForm® 
FR 
100 
6 
Accura® 
ABS 
White 
(SL 
7810) 
DuraForm® 
GF 
7 
Accura® 
Amethyst™ 
DuraForm® 
HST 
Composite 
8 
Accura® 
Bluestone™ 
DuraForm® 
PA 
9 
Accura® 
CastPro™ 
DuraForm® 
ProX™ 
10 
Accura® 
CastPro™ 
Free 
(SL7800) 
11 
Accura® 
CeraMAX™ 
Composite 
12 
Accura® 
ClearVue™ 
13 
Accura® 
ClearVue™ 
Free 
(SL 
7870) 
14 
Accura® 
e-­‐Stone™ 
15 
Accura® 
PEAK™ 
16 
Accura® 
Sapphire 
17 
Accura® 
SL 
7840 
18 
Accura® 
Xtreme™ 
19 
Accura® 
Xtreme™ 
White 
200
1980s 
Inside 
3D 
Prin@ng 
– 
10/23/14 
15 
Over 
30 
years 
of 
innova@on 
3D 
Prin4ng 
Materials 
1990s 
2000s 
2010s
Choice 
Inside 
3D 
Prin@ng 
– 
10/23/14 
16 
Material 
model 
Off 
the 
shelf 
Adapt 
Time 
Value 
Immediate 
Months 
Defined
Inside 
3D 
Prin@ng 
– 
10/23/14 
17 
Adap@ng 
a 
material 
Used 
by 
permission 
from 
taulman 
3D
Inside 
3D 
Prin@ng 
– 
10/23/14 
18 
How 
was 
it 
done? 
Adap@ng 
Nylon 
Time 
Value 
18 
Months 
Choice 
• 4 
full-­‐@me 
testers 
• 4 
specialists 
• 9 
months 
for 
capability 
• Learning 
cycles
Inside 
3D 
Prin@ng 
– 
10/23/14 
19 
3D 
printed 
microbanery 
Sun, 
K., 
Wei, 
T.-­‐S., 
Ahn, 
B. 
Y., 
Seo, 
J. 
Y., 
Dillon, 
S. 
J. 
and 
Lewis, 
J. 
A. 
(2013), 
3D 
Prin@ng 
of 
Interdigitated 
Li-­‐Ion 
Microbanery 
Architectures. 
Adv. 
Mater., 
25: 
4539–4543.
1980s 
Inside 
3D 
Prin@ng 
– 
10/23/14 
20 
Over 
30 
years 
of 
innova@on 
3D 
Prin4ng 
Materials 
1990s 
2000s 
2010s
Individualiza@on 
Choice 
Inside 
3D 
Prin@ng 
– 
10/23/14 
21 
Material 
model 
Off 
the 
shelf 
Adapt 
Custom 
Time 
Value 
Immediate 
Months 
Months 
to 
Years 
Defined
Inside 
3D 
Prin@ng 
– 
10/23/14 
22 
We 
appear 
to 
be 
at 
a 
crossroad
Inside 
3D 
Prin@ng 
– 
10/23/14 
23 
Market 
fulcrum 
Ver@cal 
Integra@on 
Outside 
Services 
Cost 
focus 
Lower 
risk 
Independence
Inside 
3D 
Prin@ng 
– 
10/23/14 
24 
What 
needs 
to 
happen 
next 
for 
3D 
prin@ng 
materials?
Inside 
3D 
Prin@ng 
– 
10/23/14 
25 
Avoid 
locked 
tools 
and 
processes. 
It’s 
a 
pathway 
that 
narrows 
op@ons 
for 
innova@on.
Individualiza@on 
Choice 
Inside 
3D 
Prin@ng 
– 
10/23/14 
26 
Material 
model 
Off 
the 
shelf 
Adapt 
Custom 
Time 
Value 
Immediate 
Months 
Months 
to 
Years 
Defined
How 
is 
a 
custom 
material 
developed? 
Inside 
3D 
Prin@ng 
– 
10/23/14 
27 
Plan 
project 
Determine 
material 
specifica@ons 
Test 
Determine 
tool 
& 
process 
Feedback 
Develop 
Commercialize 
Test 
specifica@ons
Materials 
Inside 
3D 
Prin@ng 
– 
10/23/14 
28 
Roadmap 
example 
Tools 
Processes
Inside 
3D 
Prin@ng 
– 
10/23/14 
29 
One 
op@on
Inside 
3D 
Prin@ng 
– 
10/23/14 
30 
Market 
fulcrum 
Ver@cal 
Integra@on 
Outside 
Services 
Innova@on 
Cost 
focus 
Individualiza@on 
Lower 
risk 
Independence 
Speed
Inside 
3D 
Prin@ng 
– 
10/23/14 
31 
Over 
50+ 
years 
of 
innova@on 
3D 
Prin4ng 
2010s 
Materials 
2020s 
2030s
Inside 
3D 
Prin@ng 
– 
10/23/14 
32 
Thank 
you!

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Strategies and Considerations in Developing Eco-friendly Materials for 3D Printing

  • 1. Strategies and Considera@ons in Developing [©co 2m01p4a Bnrye wnaerm Seci]e –nc New Materials for 3D Prin@ng [ed, aIntce.] 1 Inside 3D Prin@ng 10/23/14 Carlton Washburn Director of Business Intelligence
  • 2. Inside 3D Prin@ng – 10/23/14 2 Transforming ideas into integrated solu@ons INVENT MANUFACTURE INTEGRATE Core competency and excep@onal exper@se in materials science related to advanced polymeric materials and their process integra@on
  • 3. Inside 3D Prin@ng – 10/23/14 3 • 33 years ago, in 1981… – MTV was launched – Xerox introduced the computer mouse – IBM released the first PC • Model 5150 with a 4.77-­‐MHz Intel 8088 processor • Base price of $1,565 (> $4,000 today) • Used MS-­‐DOS, released by Microsoa – L2 was released by Brewer Science
  • 4. At around the same @me… Inside 3D Prin@ng – 10/23/14 4 Bourell, D. L., et al. "A brief history of addi@ve manufacturing and the 2009 roadmap for addi@ve manufacturing: looking back and looking ahead." US-­‐Turkey Workshop on Rapid Technologies. 2009. Herbert, 3M, 1979 Photopolymer Kodama, Nagoya, 1981 Photopolymer Householder, patent 1981 Concrete
  • 5. Inside 3D Prin@ng – 10/23/14 5 Over 30 years of innova@on 3D Prin4ng 1980s 1990s 2000s 2010s Materials
  • 6. Inside 3D Prin@ng – 10/23/14 6 All ini@al materials were commercially available O N2 light H2O O OH + N2 Base insoluble sensitizer Base soluble photoproduct
  • 7. 1980s Inside 3D Prin@ng – 10/23/14 7 Over 30 years of innova@on 3D Prin4ng Materials 1990s 2000s 2010s
  • 8. Inside 3D Prin@ng – 10/23/14 8 Material model Off the shelf Adapt Time Value
  • 9. Determine specifica@ons Inside 3D Prin@ng – 10/23/14 9 How do you adapt a material? Find suitable materials Test Develop Commercialize
  • 10. Inside 3D Prin@ng – 10/23/14 10 Which comes first, materials, processes, or tools? Work Breakdown Structure Timeline Jan Feb Mar Apr May Jun Jul 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 1.0 Project planning 1.1 Determine scope statement 1.2 Select team 1.3 Plan activites 2.0 Specifications 3.0 Prototype 3.1 Review design Build prototype Test A Test B Test C 4.0 Select suppliers 5.0 Verify tool design 6.0 Qualifcation testing 7.0 Redesign contingency 8.0 Commercialization
  • 11. Inside 3D Prin@ng – 10/23/14 11 Where are we today?
  • 12. Inside 3D Prin@ng – 10/23/14 12 Processes Process Polymers Metals Other Vat Photopolymeriza@on (SLA) ✓ Material Extrusion (FDM) ✓ Material Jemng ✓ Binder Jemng ✓ ✓ ✓ Powder Bed Fusion ✓ ✓ Sheet Lamina@on ✓ ✓ Directed Energy Deposi@on ✓ ASTM, Comminee F42 on Addi@ve Manufacturing Technologies, West Conshohocken, Pa., 2009.
  • 13. Inside 3D Prin@ng – 10/23/14 13 Material extrusion Material Key Characteris@cs ABS-­‐M30, Versa@le, touch ABSplus ABS-­‐ESD7 Electrosta@c discharge resistant ABS-­‐M30i Biocompa@ble ABSi Translucent PC Strong (tension) PC-­‐ABS Strong (impact) PC-­‐ISO Biocompa@ble ULTEM 9085 Mechanically well-­‐rounded, FST cer@fica@on PPSF Resistant, both thermal and chemical Nylon 12 Strong (high fa@gue resistance) PLA Color selec@on, defini@on, plant-­‐based
  • 14. Inside 3D Prin@ng – 10/23/14 14 SLA and SLS Stereolithography SLA Materials Laser Sintering SLS Materials 1 Accura® 25 CastForm™ PS 2 Accura® 48HTR DuraForm® EX Black 3 Accura® 55 DuraForm® EX Natural 4 Accura® 60 DuraForm® Flex 5 Accura® ABS Black (SL 7820) DuraForm® FR 100 6 Accura® ABS White (SL 7810) DuraForm® GF 7 Accura® Amethyst™ DuraForm® HST Composite 8 Accura® Bluestone™ DuraForm® PA 9 Accura® CastPro™ DuraForm® ProX™ 10 Accura® CastPro™ Free (SL7800) 11 Accura® CeraMAX™ Composite 12 Accura® ClearVue™ 13 Accura® ClearVue™ Free (SL 7870) 14 Accura® e-­‐Stone™ 15 Accura® PEAK™ 16 Accura® Sapphire 17 Accura® SL 7840 18 Accura® Xtreme™ 19 Accura® Xtreme™ White 200
  • 15. 1980s Inside 3D Prin@ng – 10/23/14 15 Over 30 years of innova@on 3D Prin4ng Materials 1990s 2000s 2010s
  • 16. Choice Inside 3D Prin@ng – 10/23/14 16 Material model Off the shelf Adapt Time Value Immediate Months Defined
  • 17. Inside 3D Prin@ng – 10/23/14 17 Adap@ng a material Used by permission from taulman 3D
  • 18. Inside 3D Prin@ng – 10/23/14 18 How was it done? Adap@ng Nylon Time Value 18 Months Choice • 4 full-­‐@me testers • 4 specialists • 9 months for capability • Learning cycles
  • 19. Inside 3D Prin@ng – 10/23/14 19 3D printed microbanery Sun, K., Wei, T.-­‐S., Ahn, B. Y., Seo, J. Y., Dillon, S. J. and Lewis, J. A. (2013), 3D Prin@ng of Interdigitated Li-­‐Ion Microbanery Architectures. Adv. Mater., 25: 4539–4543.
  • 20. 1980s Inside 3D Prin@ng – 10/23/14 20 Over 30 years of innova@on 3D Prin4ng Materials 1990s 2000s 2010s
  • 21. Individualiza@on Choice Inside 3D Prin@ng – 10/23/14 21 Material model Off the shelf Adapt Custom Time Value Immediate Months Months to Years Defined
  • 22. Inside 3D Prin@ng – 10/23/14 22 We appear to be at a crossroad
  • 23. Inside 3D Prin@ng – 10/23/14 23 Market fulcrum Ver@cal Integra@on Outside Services Cost focus Lower risk Independence
  • 24. Inside 3D Prin@ng – 10/23/14 24 What needs to happen next for 3D prin@ng materials?
  • 25. Inside 3D Prin@ng – 10/23/14 25 Avoid locked tools and processes. It’s a pathway that narrows op@ons for innova@on.
  • 26. Individualiza@on Choice Inside 3D Prin@ng – 10/23/14 26 Material model Off the shelf Adapt Custom Time Value Immediate Months Months to Years Defined
  • 27. How is a custom material developed? Inside 3D Prin@ng – 10/23/14 27 Plan project Determine material specifica@ons Test Determine tool & process Feedback Develop Commercialize Test specifica@ons
  • 28. Materials Inside 3D Prin@ng – 10/23/14 28 Roadmap example Tools Processes
  • 29. Inside 3D Prin@ng – 10/23/14 29 One op@on
  • 30. Inside 3D Prin@ng – 10/23/14 30 Market fulcrum Ver@cal Integra@on Outside Services Innova@on Cost focus Individualiza@on Lower risk Independence Speed
  • 31. Inside 3D Prin@ng – 10/23/14 31 Over 50+ years of innova@on 3D Prin4ng 2010s Materials 2020s 2030s
  • 32. Inside 3D Prin@ng – 10/23/14 32 Thank you!