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Ions-needed for life!
        Dr. Robert D. Craig, Ph.D.
• Experiment on rections of ions with acids and
  bases
• Ions effect pH
• Ions effect Diffusion
• Ions effect Homeostasis
• Ions are responsible for nervous system
Let’s begin
Ions-needed for life
•   Ions effect pH
•   Ions effect Diffusion
•   Ions effect Homeostasis
•   Ions are responsible for nervous system
Nine essential
•   PO4 2-                      Mg 2+
•   OH-                         Ca 2+
•   HCO32-                      Na+
•   Cl-                         K+ , H+
•   Nervous system
•   pH
•   Ion channel-lipid bilayer
•   Fe2+-Hemoglobin
.
•
• In Part A, a series of tests for the chemical
  properties of known compounds in aqueous
  solutions are conducted. A similar series of
  tests are conducted on an unknown set of
  compounds in Part B.
.
• A similar series of tests are conducted on a
  unknown set of compounds in Part B. In each
  case, an unknown compound is identified
For the reaction matrix
• You should discuss and interpret your
  observations as follows:
Please label everything
• You will carry out 15 chemical reactions
  against these reagents
• Sodium Chloride
• Sodium Carbonate
• Magnesium Sulfate
• Ammonium Chloride
• Water
Your matrix for reagent one (1)
            NaCl(s)   Na2CO3(aq)   MgSO4(aq)   NH4Cl(aq)   H2O(l)


AgNO3(aq)
terminology
• The report sheet or the “Reaction matix”
• Is designed to help organized Your work
• Because the space is limited –You can use codes
  to fill in data:
• “P” – precipitate + color
• “c” – cloudy + color
• “nr”- no reaction
• “g” –gas no odor
• “go” –gas , odor
What is the nature of a chemical
           reaction>
Most reactions take place
Scientist describe reactions in terms
                   of:
• Molecular
• Total Molecular
• Net Ionic: “it is the net ionic that contains the
  important players” The rest of the reaction
  are “spectators”
How do I know a chemical reaction has
           taken place????
What to look for . . .
•   A gas evolved
•   A precipitate “solid” appears
•   Heat may be evolved or absorbed
•   A color change might take place
•   A change in odor
•   Possibly a “sound”
H2S – rotten eggs
• For well over a century, hydrogen sulfide was important in
  analytical chemistry, in the qualitative inorganic analysis of
  metal ions. In these analyses, heavy metal (and nonmetal)
  ions (e.g., Pb(II), Cu(II), Hg(II), As(III)) are precipitated from
  solution upon exposure to H2S. The components of the
  resulting precipitate redissolve with some selectivity
silver chloride (AgCl)
• An example of a precipitation reaction:
  Aqueous silver nitrate (AgNO3) is added to a
  solution containing potassium chloride (KCl),
  the precipitation of a white solid, silver
  chloride is observed. (Zumdahl, 2005)
• AgNO3 (aq) + KCl (aq) → AgCl (s) + KNO3 (aq)
• The silver chloride (AgCl) has formed a solid,
  which is observed as a precipitate.
the ionic equation
• This reaction can be written emphasizing the
  dissociated ions in a combined solution. This is
  known as the ionic equation.

  Ag+ (aq) + NO3− (aq) + K+ (aq) + Cl− (aq) →
  AgCl (s) + K+ (aq) + NO3− (aq)
(Zumdahl, 2005)
• A final way to represent a precipitate reaction
  is known as a net ionic reaction. In this case,
  any spectator ions (those that do not
  contribute to the reaction) are left out of the
  formula completely. This simplifies the above
  equations to the following:
• Ag+ (aq) + Cl− (aq) → AgCl (s)
•
Oxidation and reduction
.
• In addition, the following multistep acid-base
  reactions affect the course of rust formation:
• Fe2+ + 2 H2O ⇌  Fe(OH)2 + 2 H+
• Fe3+ + 3 H2O ⇌ Fe(OH)3 + 3 H+
Simple dissolution MgOH2
Burning Mg(s)
Mg(s) + O2 (g) -> MgO(s) + Heat +
               light
Heat may be absorbed

• Icy –hot or sprinkling salt on snow
Please Turn to figures . . .
• 2.2a and 2.2b
2. Observations sodium hydroxide test
               reagent
•   1. label five tubes(fig 2.3)
•   2. set up 24 well plate
•   ***Label B1-B5
•   3. Place 5-10 drops of each of the five known
•   Solutions
•   4. Deliver the NaOH—check for Gas!!!
•   5. Please be careful!!!!!!
3. Observations with HCl reagent
•   1. label five tubes(fig 2.4)
•   2. set up 24 well plate
•   ***Label C1-C5
•   3. Place 5-10 drops of each of the five known
•   Solutions
•   4. Deliver the HCl—check for Gas!!!
•   5. Please be careful!!!!!!
Part B
•   Chemical properties of unknown solutions
•   1. preparation of solutions
•   2. preparation of reagents
•   3. testing the solutions
•   4. Identification of unkwown
Last part –environmental testing
• Obtain a sample of soil , add water

• http://bronxriver.org/?pg=content&p=aboutu
  s&m1=1

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Reaction matrix ions needed for life

  • 1. Ions-needed for life! Dr. Robert D. Craig, Ph.D. • Experiment on rections of ions with acids and bases • Ions effect pH • Ions effect Diffusion • Ions effect Homeostasis • Ions are responsible for nervous system
  • 3. Ions-needed for life • Ions effect pH • Ions effect Diffusion • Ions effect Homeostasis • Ions are responsible for nervous system
  • 4. Nine essential • PO4 2- Mg 2+ • OH- Ca 2+ • HCO32- Na+ • Cl- K+ , H+ • Nervous system • pH • Ion channel-lipid bilayer • Fe2+-Hemoglobin
  • 5. . • • In Part A, a series of tests for the chemical properties of known compounds in aqueous solutions are conducted. A similar series of tests are conducted on an unknown set of compounds in Part B.
  • 6. . • A similar series of tests are conducted on a unknown set of compounds in Part B. In each case, an unknown compound is identified
  • 7. For the reaction matrix • You should discuss and interpret your observations as follows:
  • 8. Please label everything • You will carry out 15 chemical reactions against these reagents • Sodium Chloride • Sodium Carbonate • Magnesium Sulfate • Ammonium Chloride • Water
  • 9. Your matrix for reagent one (1) NaCl(s) Na2CO3(aq) MgSO4(aq) NH4Cl(aq) H2O(l) AgNO3(aq)
  • 10. terminology • The report sheet or the “Reaction matix” • Is designed to help organized Your work • Because the space is limited –You can use codes to fill in data: • “P” – precipitate + color • “c” – cloudy + color • “nr”- no reaction • “g” –gas no odor • “go” –gas , odor
  • 11. What is the nature of a chemical reaction>
  • 13. Scientist describe reactions in terms of: • Molecular • Total Molecular • Net Ionic: “it is the net ionic that contains the important players” The rest of the reaction are “spectators”
  • 14. How do I know a chemical reaction has taken place????
  • 15. What to look for . . . • A gas evolved • A precipitate “solid” appears • Heat may be evolved or absorbed • A color change might take place • A change in odor • Possibly a “sound”
  • 16. H2S – rotten eggs • For well over a century, hydrogen sulfide was important in analytical chemistry, in the qualitative inorganic analysis of metal ions. In these analyses, heavy metal (and nonmetal) ions (e.g., Pb(II), Cu(II), Hg(II), As(III)) are precipitated from solution upon exposure to H2S. The components of the resulting precipitate redissolve with some selectivity
  • 17. silver chloride (AgCl) • An example of a precipitation reaction: Aqueous silver nitrate (AgNO3) is added to a solution containing potassium chloride (KCl), the precipitation of a white solid, silver chloride is observed. (Zumdahl, 2005) • AgNO3 (aq) + KCl (aq) → AgCl (s) + KNO3 (aq) • The silver chloride (AgCl) has formed a solid, which is observed as a precipitate.
  • 18. the ionic equation • This reaction can be written emphasizing the dissociated ions in a combined solution. This is known as the ionic equation. Ag+ (aq) + NO3− (aq) + K+ (aq) + Cl− (aq) → AgCl (s) + K+ (aq) + NO3− (aq)
  • 19. (Zumdahl, 2005) • A final way to represent a precipitate reaction is known as a net ionic reaction. In this case, any spectator ions (those that do not contribute to the reaction) are left out of the formula completely. This simplifies the above equations to the following: • Ag+ (aq) + Cl− (aq) → AgCl (s) •
  • 21. . • In addition, the following multistep acid-base reactions affect the course of rust formation: • Fe2+ + 2 H2O ⇌  Fe(OH)2 + 2 H+ • Fe3+ + 3 H2O ⇌ Fe(OH)3 + 3 H+
  • 23. Burning Mg(s) Mg(s) + O2 (g) -> MgO(s) + Heat + light
  • 24. Heat may be absorbed • Icy –hot or sprinkling salt on snow
  • 25. Please Turn to figures . . . • 2.2a and 2.2b
  • 26. 2. Observations sodium hydroxide test reagent • 1. label five tubes(fig 2.3) • 2. set up 24 well plate • ***Label B1-B5 • 3. Place 5-10 drops of each of the five known • Solutions • 4. Deliver the NaOH—check for Gas!!! • 5. Please be careful!!!!!!
  • 27. 3. Observations with HCl reagent • 1. label five tubes(fig 2.4) • 2. set up 24 well plate • ***Label C1-C5 • 3. Place 5-10 drops of each of the five known • Solutions • 4. Deliver the HCl—check for Gas!!! • 5. Please be careful!!!!!!
  • 28. Part B • Chemical properties of unknown solutions • 1. preparation of solutions • 2. preparation of reagents • 3. testing the solutions • 4. Identification of unkwown
  • 29. Last part –environmental testing • Obtain a sample of soil , add water • http://bronxriver.org/?pg=content&p=aboutu s&m1=1