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REVIEW




                                      Coconut Oil: Chemistry,
                                  Production and Its Applications -
                                             A Review
                                  Gopala Krishna A.G.,* Gaurav Raj, Ajit Singh Bhatnagar, Prasanth Kumar P.K.
                                                          and Preeti Chandrashekar


                                                Abstract                         chemistry, MCT and its applications
                                                                                 taking a holistic approach on the good
                                C     oconut oil is produced by
                                      crushing copra, the dried
                                kernel, which contains about 60-
                                                                                 and bad effects of coconut oil reported
                                                                                 in the literature.
                                65% of the oil. The oil has the natural                       Introduction
 Coconut oil is consumed in     sweet taste of coconut and contains
     tropical countries for     92% of saturated fatty acids(in the                  Coconut oil is an edible oil that
 thousands of years. Studies    form of triglycerides), most of them             has been consumed in tropical
 done on native diets high in   (about 70%) are lower chain                      countries for thousands of years. As
coconut oil consumption show    saturated fatty acids known as                   it has a long shelf life and a melting
                                medium chain fatty acids (MCFAs).                point of 76 °F, it is used in baking
    that this population is
                                MCFAs are not common to different                industries. A negative campaign
   generally in good health.
                                vegetable oils with lauric acid at 45-           against saturated fats in general, and
 Coconut oil has a long shelf
                                56%. Various fractions of coconut oil            the tropical oils in particular, led to
  life and is used in baking    have medium chain triglycerides and              most food manufacturers abandoning
 industries, processed foods,   are excellent solvent for flavours,              coconut oil in recent years in favor
        infant formulae,        essences, emulsifiers etc. These fatty           of hydrogenated polyunsaturated
 pharmaceuticals, cosmetics     acids are used in the preparation of             oils, particularly soy, which contain
         and as hair oil.       emulsifiers, as drugs and also in                trans fatty acids. Studies done on
                                cosmetics. Its metabolism is different           populations consuming diets high in
                                from that of the normal vegetable oils           coconut oil show no adverse effects
                                containing long chain fatty acids.               on the health of the population (1).
                                Hence, it cannot be generalized as an
                                oil similar in properties to that of a               Coconut oil has >90% saturated
                                92% long chain saturated fatty acids             fatty acids, hence is less attractive
                                containing oil/fat. More studies are             to consumers. Saturated fat is one
                                required to prove the good effects of            that has no unsaturation or double
                                coconut oil, medium chain                        bonds and tends to be solid at room
                                triglycerides (MCT) and the fatty                temperature. Coconut oil is rich in
                                acids on humans especially on the ill            short and medium chain fatty acids.
                                effects on cardiovascular and other              Shorter chain length allows fatty
                                diseases. The review covers the                  acids to be metabolized without use
                                production of coconut oil, its                   of the carnitine transport system.

                                Department of Lipid Science & Traditional Foods, Central Food Technological Research Institute
                                (CSIR), Mysore - 570020

l 15                                                                                                     Indian Coconut Journal
REVIEW




Various fractions of coconut oil are      and type 3 (grades 1, 2 and 3),                              manipulative methods. Part III
used as drugs. Butyric acid is used       milling copra for oil extraction. The                        prescribes detailed laboratory
to treat cancer, while lauric acid is     material shall be the kernels                                techniques for determination of:
effective in treating viral infections.   obtained from the fruits of Cocos                            colour (lovibond scale); sp. gr. (sp.
Hence, the literature is reviewed         nucifera Linn. Requirements cover                            gr. bottle); refractive index;
in the context of increase of fat         physical and chemical properties,                            moisture (by distillation); volatile
related disorders / diseases through      packing, marking, sampling and                               matter (at 105 degree C/1 h);
consumption of highly unsaturated         test.                                                        impurities (filtration and drying);
oils.
                                                                         Table 1. Indian specification for coconut oil (4)
Importance of coconut as oil seed
                                                                                       Expressed                                  Solvent-extracted
    The coconut palm is the most            Characteristics       Refined        Grade        Grade         Grade     Refined          Semi           Grade
                                                                  Grade         1A (Raw)     1B (Raw)      2 (Raw)     grade          refined         1 (raw)
important perennial source of oil,
which is grown in India. The              Moisture & insoluble    0.1           0.25        0.25          0.25        0.1            0.25         1.0
                                          impurities (max) (%)
cultivation of coconut is spread over
                                          Colour Lovibond         2             4           11            30          2              10           30
the entire coastal belt and also some     colour scale in Y+5R
interior tracts. Compared to all other    Refractive index        1.4480 to     1.4480 to   1.4480 to     1.4480 to   1.4480 to      1.4480 to    1.4480 to
oil seed crops coconut has the            at 40 °C                1.4490        1.4490      1.4490        1.4490      1.4490         1.4490       1.4490
highest productivity as well              Specific gravity        0.915 to      0.915 to    0.915 to      0.915 to    0.915 to       0.915 to     0.915 to
as consistency in production.             at 30 °C/30 °C          0.920         0.920       0.920         0.920       0.920          0.920        0.920

Compared to other oil seed crops          Saponification value    250           250         250           250         250            250          250
                                          (min)
coconut is less susceptible to
                                          Iodine value wijs)      7.5 to 10     7.5 to10    7.5 to10      7.5 to10    7.5 to 10      7.5 to10     8.0 to13
abnormal climatic condition.
                                          Acid value (max)        0.5           2.0         6.0           8.0         0.5            1.0          10
 Coconut oil production in India          Unsaponifiable (max)    0.5           0.8         0.8           0.8         0.5            0.8          1.0
                                          Polenske value (min)    13.0          13.0        13.0          -           13.0           -            -
   Rotaries and expellers are used
for crushing the dry coconuts             Flash point, °C (min)   -             -           -             -           225            100          90

(known as copra) for recovery of oil.
The total production of edible grade          Ceylon-Standard; CS 32: 1968                             free fatty acids; I value (modified
coconut oil in the country is about       describes the specification for                              Wij’s); saponification value;
4.0 lakh tons which is 1.5 lakh tons      coconut oil intended for export.                             unsaponifiable matter and mineral
more compared to that produced in         Coconut oil is classified into 4                             acidity (titration with 0.01N NaOH
1980’s (2).                               grades: refined, deodorized                                  to methyl orange) (4).
                                          (neutralized, bleached, final steam
 Specification for coconut oil (3)                                                                     Common methods of production
                                          deodorization); refined (no steam
                                                                                                             of coconut oil
   Indian-Standard; IS: 6220-1971         treatment); white oil (higher free
specifies the quality parameters of       fatty acids); and industrial oil (crude                          Different types of coconut oil for
copra for grading for different uses      oil, not edible without processing).                         edible purposes are available viz,
in India. This standard prescribes        Part I specifies requirement                                 virgin coconut oil from wet coconuts
the methods of grading and the            for chemical and physical                                    (unrefined grade); coconut oil from
requirements of copra for extraction      characteristics, analytical standards,                       dry coconuts (unrefined grade); and
of oil and for table use, together        appearance, freedom from                                     coconut oil by solvent extraction
with methods of sampling and test.        adulterants and suspended matter,                            method (refined from coconut
The 3 types of copra are defined:         packaging and marking. Part II                               expeller cake). Virgin coconut oil is
type 1 (grades 1, 2 and 3), ball copra    describes and illustrates equipment                          claimed to have more health benefits
for table purpose; type 2 (grades 1       for sampling, with special reference                         compared to coconut oil extracted
and 2), cup copra for table purpose;      to large bulk vessels, together with                         from copra.

July 2010                                                                                                                                                  16   l
REVIEW




                                    Table 2. Codex standards for coconut oil (5)                            purposes. Traditionally, virgin coconut
                           Characteristic                                                   Coconut oil     oil is produced by fermentation
       Colour – Platinum cobalt scale (max)                                            50                   method, where coconut milk expelled
       Relative density at 40°C/20° C                                                  0.908-0.921          from freshly harvested coconuts is
       Refractive Index at 40°C                                                        1.448-1.450          fermented for 24-36 hr, and during this
       Moisture & other volatiles at 105°C                                             0.1                  period, the oil phase gets separated
       Free fatty acids, calculated as lauric acid % by mass (max)                     0.3                  from aqueous phase. Further, the
       Peroxide value (millequivalents of active oxygen per kg)                        Not more than 15     resulting wet oil is slightly heated for
       Iodine value                                                                    6.3-10.6             a short time to remove the moisture
       Sap. value                                                                      248-265
                                                                                                            and finally filtered. The main
       Unsaponifiables, % by mass, max g/kg                                            ≤ 15
                                                                                                            disadvantages of this process are low
       Reichert value                                                                  6 – 8.5
                                                                                                            oil recovery and fermented odor,
       Polenske value                                                                  13 –18
                                                                                                            which masks the characteristic coconut
                                                                                                            flavor of the oil.
   Copra milling by traditional                                            Hydraulic presses
            methods                                                                                             In conventional methods for
                                                                      These are used in the large
                                                                                                            virgin coconut oil, freshly extracted
   The extraction of oil from copra                               installations. They are of two main       milk is centrifuged to obtain cream
is one of the oldest seed crushing                                types-open or Anglo-American              which is heated upto 60-80°C before
operations. In India and Sri Lanka                                presses and the closed or cage type       centrifuging to obtain the oil.
copra is still crushed for oil                                    presses. In this the space between the    Systematic research work has been
extraction in the primitive chekkus                               plates above ram and the head is          carried out at CFTRI for the
as well as in rotary ghanis, expellers                            divided by plates between which           production of several value added
and hydraulic presses.                                            copra is put wrapped in press clothes.    products from coconut, one of them
    The chekku is a fixed wooden or                                   The common method is to extract       being virgin coconut oil. In the
stone mortar inside which revolves                                oil from copra or the dry coconuts.       CFTRI process, virgin coconut oil is
on a hard wooden pestle. The pestle                               Conventionally coconut oil is             obtained by ‘wet processing’ without
is attached to a long pole which is                               produced by expelling dry copra,          heat, shear and chemicals with
moved round via bullocks, donkey                                  followed by refining during which         an overall yield of 87.5%.
or by human labor. About 20 – 40                                  oil is exposed to high temperature.       Physicochemical properties and fatty
kg of copra can be handled by a                                   The copra based refined coconut oil       acid compositions were evaluated.
chekku.                                                           or the solvent extracted and refined      Sensory studies are also carried out
                                                                  coconut oil will have a bland taste       and found that virgin coconut oil is
Copra processing by continuous                                                                              superior to the commercial sample.
                                                                  due to the refining processes.
          pressing                                                                                          Scale-up runs were carried out for
                                                                       Wet coconut processing               the production of virgin coconut oil.
   This is done with the help of
expellers. The oil expeller is                                        The wet coconuts are subjected to     The process technology has been
essentially a mechanical screw                                    pressing to ooze the oil out along with   transferred to several user industries
press in which the oil is expelled                                coconut milk. This is processed           through Coconut Development
from the copra by the pressure                                    afterwards without employing heat,        Board, Cochin.
exerted by a continuous rotating                                  shear, chemicals, refining and is         Physico-chemical characteristics
warm shaft in the barrel or cage of                               known as virgin coconut oil. Virgin                of coconut oil
the press. The barrel is built with                               coconut oil has applications in
                                                                  pharmaceuticals and cosmetics. It is                    Solubility
openings to allow the escape of oil
and these can be adjusted                                         colorless with characteristic coconut        Coconut oil is insoluble in water.
according to the type of seed being                               flavor and finds several applications     At temperature above its melting
crushed.                                                          in medicinal, cosmetics and cooking       point it is completely miscible with

l 17                                                                                                                              Indian Coconut Journal
REVIEW




most of the non-hydroxylic solvents                                    high saponification value, high                                Chemistry of fatty acids and
such as light petroleum, benzene,                                      saturated fatty acids content and is a                                triglycerides
carbon tetrachloride etc. In alcohol,                                  liquid at room temperatures of 27°C.
                                                                                                                                       Medium chain triglycerides
coconut oil is more soluble than most                                         Unsaponifiable matter
common fats and oils.                                                                                                                   Medium chain triglycerides
                                                                          All natural fats contain minor                            (MCTs) are a class of lipids in which
            Chemical composition                                       quantities of substance other than                           three saturated fats are bound to a
   Coconut oil contains a high                                         fatty acid glycerides. The                                   glycerol backbone. What distinguishes
proportion of glycerides of lower                                      unsaponified constituent is mostly                           MCTs from other triglycerides is the
chain fatty acids (Tables 3, 4 & 5).                                   sterols. The unsaponifiable                                  fact that each fat molecule is between
The oil is highly stable towards                                       constituent of coconut oil include a                         six and twelve carbons in length (9).
atmospheric oxidation. The oil is                                      small amount of tocopherols and                              MCTs are a component of many foods,
characterized by a low iodine value,                                   phytosterols (Table 3).                                      with coconut and palm oils being the
                                                                                                                                    dietary sources with the highest
                                 Table 3. Physico-chemical Characteristics of coconut oil                                           concentration of MCTs. MCTs are also
                                               Virgin coconut oil             Unrefined coconut               Refined coconut       available as a dietary supplement (10).
                                               from wet coconut                Oil from copra                       oil
        Appearance                                    Colorless                Slight brownish                  Colourless              MCTs have a different pattern of
          Odour                                 Coconut smell                   Coconut smell                   Odourless           absorption and utilization than long-
Melting point °C                                         24                          24                               24            chain triglycerides (LCTs) that make
Moisture (%)                                             <0.1                        <0.1                             <0.1          up 97 percent of dietary fats. For
Iodine value (cg I2/g)                                   12-15                       12-15                            10-12         absorption of LCTs to occur, the fatty
Peroxide value (meq. O2/kg)                              0-1                         0-1                              0-1           acid chains must be separated from
Saponification value(mg KOH/g)                           245-255                     245-255                          250-255       the glycerol backbone by the lipase
Phospholipids(%)                                         0.1                         0.1                              0.0
                                                                                                                                    enzyme. These fatty acids form
Unsaponifiable matter(%)                                 —                           0.42%                            0.19%
                                                                                                                                    micelles, are then absorbed and
Tocopherols mg/kg                                        150-200                     150-200                          4-100
                                                                                                                                    reattached to glycerol, and the
Phytosterols mg/kg                                                                   400-1200
Total phenolics mg/Kg                                    640                         618                              20
                                                                                                                                    resultant triglycerides travel through
Fatty acid composition(relative %)                                                                                                  the lymphatics en route to the
Saturates                                                92.0                        92.0                             92.0          bloodstream. Up to 30 percent of
Monounsaturates                                          6.0                         6.0                              6.0           MCTs are absorbed intact across the
Polyunsaturates                                          2.0                         2.0                              2.0           intestinal barrier and directly enter
                                                                                                                                    the portal vein. This allows for much
                   Table 4. Fatty acid composition of coconut oil and some other vegetable oils                                     quicker absorption and utilization of
Vegetable oils       C8:0   C10:0     C12:0     C14:0 C16:0            C18:0 C18:1 C18:2 C18:3 C20:0 C22:0 Others
                                                                                                                                    MCTs compared to LCTs. MCTs are
                                                                                                                                    transported into the mitochondria
Coconut               7.0    5.4        48.9      20.2          8.4     2.5   6.2         1.4    -      -         -
                                                                                                                                    independent of the carnitine shuttle,
Palm kernel           -      1.2        51.6      22.9          12.2    1.3   10.8        -      -      -         -           -
Sunflower             -      -          -         -             6.3     3.0   43.7        47.0   -      -         -
                                                                                                                                    which is necessary for LCT-
Rice bran             -      -          -         0.4           22.9    1.8   42.5        30.5   1.4    0.5       -                 mitochondrial absorption. Oxidation
Safflower             -      -          -         0.3           11.9    2.3   29.2        55.9   0.4    -         -                 of MCTs provides 8.3 calories per
Sesame                -      -          -         -             10.3    5.8   42.9        41.0   -      -         -                 gram, while LCTs provides 9.2
Groundnut             -      -          -         -             14.0    3.8   41.9        34.7   1.0    1.2       3.4               calories per gram (11).
Palm                  -      -          0.2       1.1           42.6    3.8   41.9        10.4   -      -         -
                                                                                                                                       Coconut Oil as a source of
Olive                 -      -          -         -             12.0    2.5   75.7        7.9    0.5    -         -           1.4
Soybean               -      -          -         -             11.6    4.0   18.8        56.1   8.5    -         -           1.0
                                                                                                                                       medium-chain triglycerides
Grape seed            -      -          -         -             7.2     4.8   19.4        68.1   0.1    -         -           0.4       All fats and oils are composed of
Linseed               -      -          -         -             7.1     2.0   19.9        17.3   53.7   -         -           0.4   triglyceride molecules, which are tri

July 2010                                                                                                                                                              18   l
REVIEW




Table 5. TAG (triacyl glycerols or triglycerides) molecular species in coconut oil from India, Malaysia and    considered essential nutrients for
                                            Indonesia (12 & 13)                                                infants as well as for people with
TAG        Coconut RBDCNO MAL          MAL     MAL      MAL MAL        IND     IND     IND     IND     IND     serious digestive problems like
Species     Oil (I) (MAL)  1            2       3        4   5          1       2       3       4       5
                                                                                                               cystic fibrosis (15, 16). Like other
CaCC        1.1        -        -       -        -       -      -       -       -       -       -       -
                                                                                                               essential nutrients, one must get
CaCLa       3.4        -        -       -        -       -      -       -       -       -       -       -
                                                                                                               them directly from the diet.
CCLa        12.8       13.1     16.6    15.1     16.4    15.9   16.2    14.4    14.3    16.7    14.7    16.1
CpCpLa      -          1.2      0.8     1.1      1.3     1.0    1.4     0.9     1.1     1.3     0.7     0.9        Literature on coconut oil
CpCLa       -          3.5      4.0     3.9      4.2     4.2    4.2     3.3     3.6     4.3     3.7     3.5
                                                                                                                   Philippines, Indonesia, India, Sri
CLaLa       17.8       17.2     21.4    19.8     19.7    19.8   20.0    19.5    19.2    21.1    19.9    20.3
                                                                                                               Lanka, Mexico, West Malaysia, and
LaLaLa      20.7       21.9     25.8    23.3     24.1    22.8   23.6    23.5    23.6    23.5    23.6    23.9
                                                                                                               Papua & New Guinea are the 7
LaLaM       16.1       17.2     15.1    15.6     13.8    14.6   13.6    15.4    16.5    14.2    16.2    14.8
LaLaO       1.8        2.3      1.3     1.5      2.0     1.4    1.6     1.6     1.8     1.8     1.2     1.6
                                                                                                               countries which produce major
LaMM        10.1       10.2     8.6     9.5      7.8     9.1    8.2     9.1     9.4     7.4     9.5     8.6
                                                                                                               quantities of coconut in the world.
LaMO        2.1        2.1      0.9     1.4      1.6     1.3    1.4     1.4     1.5     1.2     1.2     1.2    Coconut is available in two forms
LLO/LaMP    6.2        5.8      4.8     4.8      5.0     4.9    4.8     5.7     5.5     4.8     5.4     4.7    viz., wet and dry materials
LaOO        1.6        1.4      0.3     1.8      1.1     1.0    1.2     0.9     1.0     1.0     0.9     1.1    commonly known as wet coconut
LOO/LaPP    2.9        3.0      0.4     1.3      1.9     2.0    2.0     2.0     1.9     1.7     1.8     2.0    and dry coconut or copra. The oil can
PLO         0.9        -        -       -        -       -      -       -       -       -       -       -      be extracted from both these raw
MOO         -          0.7      -       0.6      0.4     0.6    0.6     0.6     0.3     0.5     0.5     0.5    materials. However, in India and
MPO         0.8        -        -       -        -       -      -       -       -       -       -       -      Srilanka, it is a general practice to
OOO         0.2        -        -       -        -       -      -       -       -       -       -       -      use only copra for oil extraction and
POO         -          0.3      -       0.3      0.4     0.4    0.4     0.5     0.2     0.2     0.4     0.5    the oil is used for food and cosmetic
POP         0.8        -        -       -        -       -      -       -       -       -       -       -      purposes. In Phillippines, the oil is
PPP         0.2        -        -       -        -       -      -       -       -       -       -       -
                                                                                                               extracted from wet coconut also and
                                                                                                               is known as virgin coconut oil. In
esters of glycerol and fatty acids. The                 diet (14). It is the MCT in coconut oil                some countries solvent extraction of
fats upon hydrolysis yield fatty acids                  that make it different from all other fats             the dry coconut followed by refining,
and glycerol. There are two methods                     and for the most part gives it its unique              bleaching and deodorization is
of classifying fatty acids,                             character and healing properties.                      carried out to get the refined
monounsaturated fatty acids, and                        Almost all of the medium-chain                         bleached and deodorized coconut
polyunsaturated fatty acids. The                        triglycerides used in research,                        oil. The technology for the
second method of classification is                      medicine, and food products come                       production of coconut oil through
based on molecular size or length of                    from coconut oil.                                      expellers is well developed and
the carbon chain in the fatty acid.                                                                            many medium scale industries in
                                                             MCT are easily digested,
    The vast majority of the fats and                   absorbed, and put to use nourishing                    India produce oil by this method.
                                                        the body. Unlike other fats, they put                  However, some small scale
oils whether they are saturated or
                                                                                                               industries produce the oil by
unsaturated or from an animal or a                      little strain on the digestive system
                                                                                                               processing fresh coconut also using
plant, are composed of long-chain                       and provide a quick source of energy
                                                                                                               local expeller press. Problems of
triglycerides. All fats we eat consist of               necessary to promote healing. This
                                                                                                               sediments and rancidity persist in
LCT while, coconut oil is unique                        is important for patients who are
                                                                                                               these oils.
because it is composed predominantly                    using every ounce of strength they
of MCT. The size of the fatty acid is                   have to overcome serious illness or                       The literature on coconut oil
extremely important because                             injury. It’s no wonder why MCT are                     which has been reported as
physiological effects of medium-chain                   added to infant formulas. MCT are                      published papers and patents from
fatty acids in coconut oil are distinctly               not only found in coconut oil but also                 1970 onwards were reviewed and
different from the long-chain fatty                     are natural and vital components                       were classified under the following
acids more commonly found in our                        of human breast milk. MCT are                          heads:

l 19                                                                                                                               Indian Coconut Journal
REVIEW




 A. Production Methods and Oil           feeding the expeller presses;             coconut to obtain refined oil and to
             quality                     handling and filtering of crude oil;      simultaneously recover coconut
                                         oil cooling system; and extraction by     products including solid coconut
    A number of reviews are
                                         the solvent method. Loncin et al (20)     products for human consumption
available on the different types of
                                         reviewed the utilization of palm oil      which has also been patented in
extraction and processing methods
                                         and coconut oil in the form of            India. Castellanos and Asturias (26)
for the preparation of coconut oil,
                                         interesterified fat. The utilization of   investigated the wet milling
coconut flour, protein and coconut
                                         transesterified palm oil with 25%         processes for the extraction of oil
cake and meal. Cornelius (17) has
                                         coconut oil for production of cooking     from decorticated fresh coconut
reviewed the aspects of coconut
                                         fat of uniform consistency little         under a variety of experimental
processing such as growing,
                                         affected by temperature. (solid fat       conditions to get oil of better quality
harvesting, handling, storage,
                                         index at 10, 20 and 30 degree C being     and it required less refining.
composition of nut, processing,
                                         45.6, 33.6, 9.2, consistency in 0.1 mm    Hagenmaier et al (27) identified the
primary products (copra, ball copra,
                                         ASTM penetration depth after 9 days’      critical unit operations in the wet
desiccated coconut, fibre and shells),
                                         storage at 15, 21 and 25 degree C was     processing of fresh coconuts for the
coconut oil (extraction methods,
                                         19, 38 and 44). Due to its low            recovery of oil and food grade
composition of coconut oil), uses of
                                         oxidation during heating, liquid oil is   protein.
oil, coconut cake and meal,
                                         suitable for table and frying use.
nutritional aspects, and the coconut                                               Solvent extraction
industry in the 7 major producing        Enzymatic process
                                                                                       Cancel et al (28) has standardized
areas (Philippines, Indonesia, India,        Coconut oil is extracted from         conditions for coconut oil extraction
Sri Lanka, Mexico, West Malaysia,        coconut paste by a new enzymatic          from coconut milk press-cake.
and Papua & New Guinea). Dendy           process (1) and the method used less      Gonzalez et al (29) studied the
and Grimwood (18) have reviewed          energy than the conventional              solvent extraction of residual oil
the various processes for wet            processes. A Sri Lankan inventor (21)     from wet coconut meal using
treatment which have been proposed       has developed a simple method for         isopropanol. Bernardini (30) has
for extraction of oil and protein from   making high quality coconut oil and       described a new single solvent direct
fresh coconut meat: The Chayen,          desiccated coconut. Using more            extraction process (by CMB,
Robledano, ICAIT, Krauss-Maffei,         manpower and little or no electricity,    Pomezia) which obviates the need
Roxas and Sugarman processes,            it involves breaking the coconut,         for pressing. Aliwalas and Buccat
integrated processes, methods used       scraping it and drying in a specially     (31) studied the filtration-extraction
by the Texas A&M University and          designed solar drier. The desiccated      of granulated coconut on a bench
the Tropical Products Institute,         coconut produced can be used for          scale. Claudio et al (32) carried out
London. The problem of obtaining         mechanical extraction of colourless,      laboratory scale studies on the
cheap protein-based food products,       odourless coconut oil suitable for        preparation of a highly nutritious
coconut milk and cream, frozen           direct consumption (22). Mojika (23)      coconut flour from granulated
milk, syrup, etc. is then examined.      developed a simple process for            coconut. Preliminary feeding expt.
A few indications are given              producing coconut oil and food grade      indicate a PER comparable with
regarding the nutritive and chemical     copra cake which has been patented.       casein. Prepared foods (cakes,
aspects of coconut protein. Baltasar     Nambiar (24) developed a method for       doughnuts, cookies, pastries) with
(19) has reviewed the extraction         the production of refined oil from the    20-30% wheat flour replaced by
process of coconut oil by the dry        milk of fresh ripe coconuts and has       coconut flour obtained high taste
processing technology. Coconut oil       been granted an Indian patent.            rating.
extraction employing dry processing
technology is discussed under the        Wet processing of coconut                 Fatty acid composition
following headings: preparation of         Nambiar (25) has developed a               Banzon and Resurreccion (33)
raw material; drying or cooking;         method of processing fresh ripe           carried out a study on the fatty acid
July 2010                                                                                                             20   l
REVIEW




distribution in coconut oil obtained    (CECO). However, high temperatures         coconut oil can be used as a natural
by four processing methods and          used in the hot extraction of coconut      antioxidant through the blending
secured from four Philippine types      oil favor the incorporation of more        process. Bhatnagar et al (37) have
of coconuts. There was no observed      thermally       stable      phenolic       observed that addition of coconut oil
change in the fatty acid distribution   antioxidants into coconut oil.             to either safflower oil, sunflower oil,
in samples of coconut oil obtained      Therefore, the consumption of              rice bran oil increased the oxidative
by 4 methods, namely: solvent           HECO may result in improvement             stability of the resultant blend.
extraction, fermentation, freeze-       of antioxidant related health benefits     Phase separation
thawing and heating. Neither was        compared with the consumption of
there such a change observed in         CECO.                                          Murthi et al (38) studied the
coconut oil samples obtained from                                                  storage stability of edible oils and
                                            Moura (6) studied the changes in       their blends. Among the blends,
4 types of coconuts.
                                        some        components        of     the   sesame oil or groundnut oil blended
Phenolics and antioxidant activity      unsaponifiable fraction of coconut oil     with refined cottonseed oil showed
    Kapila and Dissanayake (34)         during refining. 8 lots of coconut oil     the least increase in FFA. PV of raw
studied the phenolic compounds          were sampled at 5 points in the refining   edible oils and their blends tended
present in the nonsaponifiable          process. The unsaponifiable matter         to rise steadily to a maximum,
fraction of coconut oil by high-        (UNS) comprised hydrocarbons               declining gradually thereafter.
performance liquid chromatography       (including squalene), aliphatic            Acceptability became poor for raw
with florescence detection. Mass        alcohols and triterpenoid alcohols,        edible oils after 120 days, when the
spectra of the phenolic compounds       sterols and a final group containing       PV was between 5.9 and 16 m-
were also obtained separately by        free fatty acids (FFA), campesterol and    equiv./kg, and for refined oils after
LC–MS to confirm the presence of        some unidentified components.              90 days (PV was 4.4-9) and for the
the phenolic compounds. Caffeic         Tocopherols were not detected in the       blends after 90-120 days (PV 4-45).
acid, p-coumaric acid, ferulic acid     coconut samples analysed. Manalac          The consumer preference in various
and catechin were observed in           and Harder (36) analysed the               areas was for oil blends containing
coconut oil. Phenolic acid fraction     tocopherol content of coconut oil from     cottonseed oil with sesame oil or
of the coconut oil prepared by          a commercial processing plant at           groundnut oil, coconut oil with palm
boiling coconut milk (traditional       different stages of refining. One          olein, and rapeseed oil with mustard
coconut oil) was more complex           sample of crude oil containing             oil. Blends containing palm oil were
compared with that of coconut oil       721.06µg/g lost 94.5% resulting in         less acceptable, as a waxy solid mass
prepared by pressing copra              38.9µg/g in the final product.             separates out in these oils.
(commercial coconut oil). Total             It is observed from the above          Coconut oil emulsions
phenol content of traditional coconut   literature reports that there is
oil was nearly seven times higher                                                      Garti and Arkad (39) studied the
                                        variation in the composition of
                                                                                   process of preparation of cloudy
than that of commercial coconut oil     coconut oil with respect to natural
                                                                                   coconut oil emulsions containing
(618 ± 46 vs. 91 ± 11 mg kg )1 ),       antioxidants level with the method         dispersed TiO2 using atomizer.
suggesting that the phenol content      used for its extraction which may          Rogov et al (40) studied the viscosity
varies with the extraction method.      have a bearing on the nutritional          of the fat components of margarine
   Kapila, Chamil and Sagarika (35)     quality of the oil.                        emulsions. Technological procedures
compared the antioxidant activities      B. Blending of coconut oil with           in margarine manufacture (dosage,
of coconut oil extracted under hot             other vegetable oils                transport, mixing) are affected by the
and cold conditions. The coconut oil                                               viscosity of the fat component.
                                        Oxidative stability
extracted under hot conditions                                                     Viscosities of some fats (hardened
(HECO) contained more phenolic             Coconut oil addition to other           fat, qualities 1, 2 and 3, coconut oil,
substances than the coconut oil         vegetable oils improves their              vegetable oil blends, etc.) and of the
extracted under cold conditions         oxidative stability indicating that        fat components used for margarine

l 21                                                                                                    Indian Coconut Journal
REVIEW




emulsion preparation were                 following process for oil extraction      specification for a vegetable oil
determined at 40 degree C. The            from coconut meat: (i) wet method         blend.
viscosities of different fat blend        (using a De Laval centrifuge), (ii)
                                                                                        A.17.24. “Blended Edible
emulsions applied in Russian              hydraulic pressing, (iii) pressing plus
                                                                                    Vegetable Oil” means an admixture
margarine formulations were also          solvent extraction, (iv) filtration
                                                                                    of any two edible vegetable oils
determined and are tabulated.             extraction (direct solvent extraction).
                                                                                    where the proportion by weight of
                                          Oil extraction efficiencies obtained
Nutritional effects of coconut oil                                                  any edible vegetable oil used in the
                                          were: (i) 79.56% (increased to 96.3%
blends                                                                              admixture is not less than 20 per
                                          by subsequent solvent extraction),
    Bellenand et al (41) studied the                                                cent. The individual oils in the blend
                                          (ii) 76.47%, (iii) 99.65%, (iv) 96.58.
effects of coconut oil on heart lipids                                              shall conform to the respective
                                          Protein contents of isolates from (i)
and on fatty acid utilization in                                                    standards prescribed by these rules.
                                          ranged from 59 to 75%. Protein
rapeseed oil. The cardiac lipidosis                                                 The blend shall be clear, free from
                                          efficiency ratio (PER) biological
was proportional to the content of                                                  rancidity, suspended or insoluble
                                          value (BV), true digestibility (TD)
erucic acid in the diet. At 60 days,                                                matter or any other foreign matter,
                                          and net protein utilization (NPU) of
the high level of 22:6 in the cardiac                                               separated water, added colouring
                                          coconut flour from (ii), (iii) and (iv)
phospholipids of rats fed rapeseed oil                                              matter, flavouring substance,
                                          were: PER 2.42, 2.55, 2.42; BV 77,
was reduced by the addition of                                                      mineral oil, hydrocyanic acid, castor
                                          84, 79; TD 76, 74, 72; NPU 68, 64,
sunflower oil but not by coconut oil.                                               oil and tricresyl phosphate. It shall
                                          66. Values for coconut isolate
Thus, the blending of rapeseed oil                                                  also conform to the following
                                          prepared by heat coagulation of
with coconut oil apparently is less                                                 standards, namely;
                                          cream or aqueous portion of fresh
desirable than that of rapeseed oil       coconut milk from (i) were: PER              Based on the PFA specifications,
and sunflower oil. McCutcheon et al       1.50, 2.20; BV 72, 80; TD 88, 92;         a process has been developed at the
(42) studied the cardiopathogenicity      NPU 59, 65. The traditional rural         Central Food Technological
of rapeseed oils and oil blends           method gave an oil extraction             Research Institute, Mysore under
differing in erucic, linoleic and         efficiency of 82.45, and a protein        sponsorship from the Coconut
linolenic acid content on male Wistar     isolate with PER 1.25, BV 62, TD          Development Board, Cochin and is
rats using semipurified diets. Lowest     86 and NPU 58.                            ready for commercialization.
lesion incidence was obtained with
                                              Reena Rao and Lokesh (46, 47),            C. Edible applications of
safflower oil and hydrogenated
                                          Anitha Nagaraju and Lokesh (48, 49)                 coconut oil
coconut oil. It has been postulated
                                          and Reena and Lokesh (50) have
that linolenic acid plays a role in the                                                Coconut oil has a high degree of
                                          used immobilized lipase systems for
etiology of cardiac necrosis observed                                               saturation with a high content of
                                          the synthesis of structured lipids
when rats are fed diets containing                                                  saturated fatty acids. Because of
                                          from coconut oil and omega 6 and
low erucic acid rapeseed oils.                                                      high content of saturated fatty acids
                                          omega 3 fatty acids and carried out
    Theuer (43) developed fat             nutritional evaluation of the same in     coconut oil is highly resistant to
compositions for infant formulas          rats. They found beneficial effects in    oxidative rancidity, coconut oil is
containing vegetable fats with a fatty    the lipid profile after enzymatic         used as a component of infant milk
acid simulating that of human milk.       acidolysis of coconut oil with omega      powders because of its easy
Grandadam (44) developed                  6 and omega 3 fatty acids.                digestibility and stable flavor.
processes to recover the proteins of                                                Coconut oil is extensively used in
                                          Indian Specification for blending         the food industries as a
the coconut from copra cake, or
                                          of vegetable oils                         confectionery fat particularly in the
directly from fresh coconut meat by
different processes. The improved           As per the Prevention of Food           preparation of ice creams. In
Itipat process of double pressing         Adulteration Act 1954 Rules               imitation chocolates coconut oil is
allows recovery of 93.45% of the oil      and Regulations and updated               used in place of cocoa butter along
and 91.9%. Aliwalas (45) studied the      amendments following is the               with cocoa powder.
July 2010                                                                                                             22   l
REVIEW




                         Indian Specification for blending of two oils                                                  materials. These MCTs can also be
a.     Moisture and volatile matter                                             Not more than 0.2 per cent by weight
                                                                                                                        used as a glaze and polishing agent
b.     Acid Value
                                                                                                                        for confectionery products such as
       Nature of oil                                                            Acid value                              gummy- type candies. Solid MCTs
       1. Both raw edible vegetable oils in the blend                           Not more than 6.0                       can help to enhance aeration
       2. One raw edible vegetable oil and one refined edible                                                           properties in bakery products (55,
          vegetable oil in the blend                                            Not more than 5.0                       56).
       3. Both refined edible vegetable oils in the blend                       Not more than 5.0
c.     Unsaponifiable matter:
                                                                                                                        MCT derivatives- structured
       1. Blend with rice bran oil                                              Not more than 3.0 per cent by weight    lipids
       2. Blend with other edible vegetable oils                                Not more than 1.50 per cent by weight      Medium chain triglycerides can
d.     Flash point (Penske Martin closed method)                                Not less than 250ºC
                                                                                                                        be used to custom design fats. MCTs
       1. Test for argemone oil shall be negative for the blend                                                         with conventional long chain fats give
       2. However, blend may contain food additives permitted in these rules and Appendix ‘C’.
                                                                                                                        products with unique physical and
Use in the synthesis of medium                                   Functional benefits of medium                          nutritional products. MCT derivatives
chain triglycerides                                              chain triglycerides                                    show unique properties compared to
                                                                                                                        their corresponding physical blends.
    Medium chain triacylglycerols                                    Medium chain triglycerides are                     They may contribute nutritional and
are unique categories of lipids                                  widely used in the flavor industries                   functional benefits to value added
produced by the esterification of                                as they are more polar and therefore                   foods (57, 58, 59).
glycerol with medium chain fatty                                 more hydrophilic and can dissolve
acids, which come from high lauric                               a variety of polar substances that are                    D. Non-edible applications
oils. Coconut and palm kernel oils                               insoluble in conventional fats and                              of coconut oil
are the only commercially important                              oils. Hydrocarbons, esters and                            One of the major non-edible
sources of medium chain fatty acids                              natural oils as well as alcohols,                      applications of coconut oil is in the
(52). These oils are hydrolyzed to                               ketones and acids are miscible with                    soap industries; one important
liberate their fatty acids from                                  MCTs. These properties make                            chemical derivative of coconut oil
glycerol, and then the fatty acids are                           MCTs superior carrier for flavors,                     is methyl esters of coconut fatty
separated by fractional distillation.                            vitamins and colors when compared                      acids, which are produced by
The lower boiling or top fraction of
                                                                 to conventional oils. MCTs have a                      treating coconut oil with methyl
the fatty acids contains the medium
                                                                 lower molecular weight than                            alcohol. These methyl esters
chain acids (53).The esterification
                                                                 conventional oils. This gives MCTs                     constitutes an important raw
reaction between glycerol and the
                                                                 a lower viscosity than conventional                    material for the chemical industries
medium chain fatty acids is carried
                                                                 oils, even at low temperatures.                        as they are more stable and are
out at high temperatures with or
without use of a catalyst. The water                             MCTs oils have no unsaturated fatty                    easier to separate by fractional
liberated in the reaction is removed                             acids present; therefore they are                      distillation. Coconut oil has many
continuously to drive the reaction to                            exceptionally stable to oxidation.                     other industrial uses in the
completion (54). When the                                        MCTs have excellent keeping                            pharmaceuticals, cosmetics, plastics,
esterification reaction is complete,                             qualities and therefore help to                        rubber substitutes, synthetic resins
excess fatty acids are removed from                              increase shelf- life of finished                       etc. Coconut oil has also been found
the reaction mixture by vacuum                                   products. MCTs are ideal for                           useful for mixing with diesel. These
distillation. To remove the volatile                             treating the surfaces of crackers to                   mixture in the proportion as 30:70
odor and flavor components as well                               act as a moisture barrier. They                        has given excellent road
as any residual fatty acids, the crude                           adhere well to surfaces, including                     performance of diesel vehicles.
MCTs are deodorized to get a final                               metals. They are excellent release                     Methyl esters of coconut oil fatty
product that has a bland flavor and                              agent for surfaces that come into                      acids is also being used as lubricants
is odorless and colorless.                                       contact with food products or raw                      and biodiesel in aviation industry.

l 23                                                                                                                                        Indian Coconut Journal
REVIEW




   E. Clinical Applications of          Healing properties of coconut oil         Saturated fatty acids of coconut oil
 medium chain triglycerides and                                                   having medicinal properties
                                           Coconut oil is antiviral, anti-
      saturated fatty acids                                                           Roughly 45 to 50% of fatty acids
                                        fungal (kills yeast too) and
Malabsorption                           antibacterial. It attacks and kills       of coconut oil form lauric acid.
                                        viruses that have a lipid (fatty)         Lauric acid is known to kill viruses
   Children with cystic fibrosis
                                        coating, such as herpes, HIV,             and bacteria that are enveloped in a
supplemented with up to 75 ml of
                                        hepatitis C, the flu, and                 phospholipid membrane. Examples
MCTs per day experienced greater
                                        mononucleosis. It kills the bacteria      of viruses with a fatty capsule are:
weight gain and reduced fecal fat
                                        that cause pneumonia, sore throats,       influenza viruses and HIV. Coconut
compared to a trial period on a
                                        dental cavities, urinary tract            itself contains about 75% fiber, not
control diet (9). When MCTs are
                                        infections, meningitis, gonorrhea,        bran fiber from wheat and grains
given concurrently with a pancreatic                                              (which contains phytic acid that
enzyme preparation, absorption is       food poisoning and many more
                                        bacterial infections (63). It kills the   absorbs calcium and other mineral
improved (58). MCTs have been                                                     from your body before it is
used in other malabsorption             fungus/yeast infections that cause
                                        candida, ringworm, athletes foot,         excreted), but dietary fiber that feeds
syndromes, including short-bowel                                                  beneficial colon flora. As the fiber
syndrome, celiac disease, and           thrush, jock itch and diaper
                                        rash.                                     is metabolized by the naturally
hepatic disease (15).                                                             occurring bacteria, they by default,
HIV/AIDS                                Use of saturated fats in therapeutic      crowd out other potentially harmful
                                        applications                              pathogens and produce short chain
    MCTs may help with weight
                                           Saturated fatty acids can be           fatty acids (SCFA’s) like acetic acid
maintenance in AIDS patients. An                                                  (minute amounts of vinegar and
enteral formula containing 85           used to: boost the immune system,
                                        for weight management, as                 butyric acid (originally isolate in
percent of fat calories from MCTs                                                 butter) both compounds are known
(35% of total calories from fat) led    antimicrobials, to support the
                                                                                  to have varying degrees of anti
to decreases in stool fat, number of    structure of gut mucosa, and as
                                                                                  microbial activity. These fatty acids
bowel movements, and abdominal          dietary adjuncts in cases of chronic
                                                                                  are absorbed directly into the colon
symptoms, as well as increased fat      degenerative disease, such as
                                                                                  and serve as energy in that way.
absorption compared to baseline         cardiovascular disease, liver
                                                                                  Butyric acid has been shown to have
(59). No improvement was seen in        disease and cancer. As far as the
                                                                                  anti-tumor properties. Many
subjects taking a control LCT-          integrity of the gut mucosa is            researchers have reported that
containing formula. Another             concerned, the use of short and           coconut oil lowers cholesterol. The
controlled trial confirmed these        medium chain fatty acids can              cholesterol-lowering properties of
results (60). MCT-containing            reduce      mucosal       irritation      coconut oil are a direct result of its
caloric supplements do not appear       characteristic of aliments such as:       ability to stimulate thyroid function.
to cause weight gain in AIDS            IBS, ulcerative colitis, and              In the presence of adequate thyroid
patients compared to a control diet.    dysbiosis, to name a few. In              hormone, cholesterol (specifically
In 1978, Kabara and others (61)         particular, short chain fatty acids       LDL-cholesterol) is converted by
reported that certain medium chain      are antihistaminic and may find use       enzymatic processes to the vitally
fatty acids, such as lauric acid have   in the treatment of allergic-type         necessary anti-aging steroids,
adverse effects on other pathogenic     conditions, such as asthma,               pregnenolone, progesterone and
microorganisms, including bacteria,     urticaria and food sensitivities.         DHEA. These substances are
yeast and fungi. These fatty acids      Studies have also shown that short        required to help prevent heart
and their derivatives actually          chain saturated fatty acids can be        disease, senility, obesity, cancer and
disrupt the lipid membranes of the      used in the treatment of dental           other diseases associated with ageing
organisms and thus inactivate them      caries, peptic ulcers, BPH, genital       and chronic degenerative diseases
(62).                                   herpes, and hepatitis (64).               (64).

July 2010                                                                                                            24   l
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Anti-Cancer Effects of Coconut             effects of the oil has also been                     Section B. Sci. and Engg., 1971 32 (6)
Oil                                        reported especially in cardiovascular                3424-3425 order no. 72-1709.
                                           diseases due to the presence of less            7.   Lucita R Lauretes, Felicito M
    In 1987 Lim-Sylianco (64)                                                                   Rodriguez, Consorcia E. Reano,
                                           of unsaturated fatty acids in the
published a 50-year literature review                                                           Genardo A Santos, Antonio CLaurena,
                                           triglycerides of the oil. It is                      Evelyn Mae Tecson Mendoza.
showing the anti-cancer effects of
                                           hypothesized that due to lower                       Variability in fatty acid and
coconut oil. In chemically induced
                                           amount of PUFA, there is a                           triacylglycerol composition of the oil of
cancers of the colon and breast,                                                                coconut (Cocos nucifera L.) hybrid and
                                           possibility of atherogenecity
Cohen et al (65) showed that coconut                                                            their parental. J. Agric. Food Chem.,
                                           development during long term usage
oil was by far more protective than                                                             (2002) 50 1581-1586.
                                           of the oil. However, more research
unsaturated oils. For example 32%                                                          8.   Frank D Gunstone, John L Harwood,
                                           is needed to clearly understand the                  Albert J Dikstra. The lipid handbook.
of corn oil eaters got colon cancer
                                           many good effects of the oil.                        CRC Press, Taylor and Francis Group.
whereas only 3% of coconut oil
eaters got the cancer. Animals fed                  Acknowledgements                       9.   Babayan, V.K. Medium chain
                                                                                                triglycerides. In dietary fat requirements
unsaturated oils had more tumors.              The authors thank Dr. V. Prakash,                in health and development. (CJ Beare-
This shows the thyroid-suppressive         Director, CFTRI, Mysore and the                      Rogers, ed) AOCS press, Champain,
and hence, immuno-suppressive              Coconut Development Board, Kochi                     Illinois (USA) 1988 73-86.
effect of unsaturated oils.                for enthusing us to write this review           10. J. A. Heydnger, D. K. Nakhasi, Medium
                                                                                               chain Triacylglycerols. J. of Food
            Conclusions                    and Dr. B.R. Lokesh, Head, Dept. of                 Lipids, (3) 1996 251-257.
                                           Lipid Science & Traditional Foods,
    Coconut oil is consumed in                                                             11. Ralph Hoahland,George G. Snider,
                                           for critically going through the                    Digestability of certain higher saturated
tropical countries for thousands of
                                           manuscript.                                         fatty acids and triglycerides. J. Nutri.,
years. Studies done on native diets                                                            1943 26(3) 219-225.
high in coconut oil consumption                           References
                                                                                           12. Malongil B. Reena, Sunki R. Y. Reddy,
show that this population is generally     1.   Thampan, P.K., Glimpses of coconut             Belur R. Lokesh, Changes in
in good health. Coconut oil has a               industry in India,        Coconut              triglyceride molecular species and
                                                Development Board, Cochin 1988.                thermal properties of blended and
long shelf life and is used in baking
                                           2.   http://www.seaofindia.com/. Import             interesterified mixtures of coconut oil
industries, processed foods, infant
                                                of vegetable oils, The Solvent                 or palm oil with rice bran oil or sesame
formulas, pharmaceuticals, cosmetics            Extractors’ Association of India,              oil. Eur. J. of Lipid Sci. and Tech., 2009
and as hair oil. The oil contains 92%           Mumbai, India.                                 111: 346-357.
of saturates consisting of medium          3.   Indian     Standards     Institution       13. A. M. Marina, Y. B. Che Man, S. A. H.
chain fatty acids in the form of                Specification, Grading for copra for           Nasimah, I. Amin, Chemical properties
triglycerides, and about 8% of                  table use and for oil milling. India,          of virgin coconut oil. J. Amer. Oil
                                                Indian- Standard; IS: 6220-1971,               Chem. Soc., 2009 86 301-307.
unsaturates consisting of oleic and             10pp. Methods of sampling and test
linoleic acids as triglycerides. The oil                                                   14. Furman, R.H., Howard R.P., Brusco
                                                for oils and fats, Indian Standard
                                                                                               O.J., Alaupoic P, Effects of Medium
has a small amount of unsaponifiable            specification for coconut oil IS:542-
                                                                                               chain length triglyceride on serum
matter (< 0.5%), is colourless and              1968. Indian Standards Institution
                                                                                               lipids. In medium chain triglyceride. U
                                                New Delhi. 1971.
has a odour typical of the coconuts.                                                           Penn Press Pennysylvania 51-61.
The oil has small amounts of               4.   Specification for coconut oil. Ceylon,
                                                Ceylon-Standard: CS 32: 1968 24pp.         15. Johnson R.C., Cotter R. Metabolism of
tocopherols and tocotrienols and                Bureau of Ceylon Standards. 1968.              medium chain triglyceride lipid
phytosterols. The oil is known to                                                              emulsions. Nutr. Int., 1986 2 150-158.
                                           5.   Codex Alimentarius (FAO/WHO),
have antiviral and antibacterial                Codex Standards for Named Vegetable        16. Marie-Pierre St-Onge, Robert Ross,
effects and excellent healing                   Oils, Codex Stan 210-1999. Codex               William D. Parsons, Peter J.H. Johns,
                                                Alimentarius, V.8-2001. Rome, Italy, p         Medium chain triglycerides increase
properties. It gets easily absorbed in
                                                11-25.                                         energy expenditure and decrease
the body and is a nature mimic of                                                              adiposity in overweight men. Obesity
                                           6.   Moura Fe J de A, Changes in some
the human breast milk fat and hence                                                            Res., 2003 11(3) 395-402.
                                                components of the unsaponifiable
used in infant formulae. With all               fraction of coconut oil during refining.   17. Cornelius J.A., Coconuts: a review.
these good quality attributes, the side         Dissertation Abstracts International.          Trop. Sci., 1973 15 (1) 15-37.

l 25                                                                                                                Indian Coconut Journal
REVIEW




18. Dendy DAY, Grimwood BE, Coconut                  C., Studies on solvent extraction of              atomizer. J. Dispersion Sci. and
    Processing for the production of                 residual oil from wet coconut meal                Technol., 1986 7 (5) 513-523.
    coconut oil and coconut protein food             using isopropanol. Phillip. J. Sci., 1973    40. Rogov B.A., Stetsenko A.V.,
    and feed products. Oleagineux, 1973 28           102 (1/2) 31-43.                                 Kuznetsova N.M., Viscosity of the fat
    (2)93-98.                                    30. Bernardini E., Direct extraction of oil          components of margarine emulsions.
19. Baltasar S.F., Coconut oil extraction            from oilseeds without pressing. Riv.             Maslozhirovaya Promyshlennost, 1984,
    employing the dry processing                     Itali. de. Sost. Gras., 1970 47 (8) 385-         No. 11, 19-20.
    technology. Phillip. J. Coconut Studies,         391                                          41. Bellenand J.F., Baloutch G., Ong N.;
    1977 2 (4) 40-42.                            31. Aliwalas A.R., Buccat C.P., Filtration-          Lecerf J., Effects of coconut oil on heart
20. Loncin M., Palm oil. Fette Seif.                 extraction of granulated coconut on a            lipids and on fatty acid utilization in
    Anstrichm., 1974 76 (3) 104-112.                 bench scale. Phillip. J. Sci., 1970, 96          rapeseed oil. Lipids, 1980 15 (11) 938-
                                                     (3) 215-285.                                     943.
21. Leonard E., Sri Lankan inventor who
                                                 32. Claudio-TR; Capulso S.A., Gonzales           42. McCutcheon J.S., Umermura T;
    makes life easier for his countrymen.
                                                     A.L., Fuente F. S. de la; Manalac G.C.,          Bhatnagar M.K., Walker B.L.,
    1983, Cocomunity, APCC/QS/45/83,
                                                     Laboratory scale studies on the                  Cardiopathogenicity of rapeseed oils
    33-35.
                                                     preparation of coconut flour from                and oil blends differing in erucic,
22. Small-scale oil extraction from                  granulated coconut. Phillip. J. Sci., 1968       linoleic and linolenic acid content.
    groundnuts and copra. International              97 (1) 45-56.                                    Lipids, 1976. 11 (7) 545-552.
    Labour Office; United Nations                                                                 43. Theuer R.C., Fat compositions for
                                                 33. Banzon J.A., Resurreccion A.P., Fatty
    Industrial Development Organization,                                                              infant formulas. 1981 US Patent 4, 282,
                                                     acid distribution in coconut oil obtained
    Technical Memorandum, United                                                                      265.
                                                     by four processing methods and secured
    Nations Industrial Development
                                                     from four Philippine types of coconuts.      44. Grandadam Y., The proteins of the
    Organization; 1983, No. 4, xi + 111pp.           Phillip. J. Coconut Studies, 1979 4 (2)          coconut. Industries Alimentaires et
    ISBN 92 2 103503 4.                              1-8.                                             Agricoles, 1973 90 (9/10) 1253-1268.
23. Mojica I.N. Jr, Process for producing        34. Kapila N. Seneviratne, Dissanayake M.        45. Aliwalas A.R., Gonzales A.L., Claudio
    coconut oil and food grade copra cake.           Sudarshana Dissanayake, Variation of             T.R., Benet R., A study of the wet and
    1978, Philippines-Patent 11661/C.                phenolic content in coconut oil                  dry methods of extracting oil from
24. Nambiar T.V.P., Method for the                   extracted by two conventional methods.           coconut meat. Phillip. J. Sci., 1969 98
    production of refined oil from the milk          International J. Food Sci. and Technol.,         (2) 139-149.
    of fresh ripe coconuts. 1977. Indian-            2008 43 597–602 597.                         46. Reena Rao, Enzymatic synthesis of
    Patent.                                      35. Kapila N. Seneviratne, Chamil D.                 structured lipids by immobilized lipase
25. Nambiar T.V.P., A method of processing           HapuarachchI , Sagarika Ekanayake,               systems in organic solvents. Ph.D.
    fresh ripe coconut to obtain refined oil         Comparison of the phenolic-dependent             Thesis, CFTRI, Mysore, University of
    and to simultaneously recover coconut            antioxidant properties of coconut oil            Mysore 2001.
    products including solid coconut                 extracted under cold and hot conditions.     47. Reena Rao and B.R. Lokesh,
    products for human consumption. 1977,            Food Chem., 2009 114 1444–1449.                  Nutritional evaluation of an omega 6
    Indian-Patent.                               36. Manalac G.C., Harder Soliven A.,                 fatty acid containing structured lipid
26. Castellanos P.S., Asturias C.R.,                 Tocopherol content of coconut oil at             synthesized from coconut oil. Lipids,
    Extraction of oil from fresh coconut.            various stages of processing. Phillip. J.        Mol. and Cell. Biochem., 2003 248 (1-
    Oleagineux, 1969 24 (7) 419-21; 24 (8/           Sci., 1970 96 (3) 239-48.                        2) 25-33.
    9) 505-09.                                   37. Bhatnagar, A.S., Prasanth Kumar P.K.,        48. Anitha Nagaraju, and B.R. Lokesh,
27. Hagenmaier R. D., Cater C. M., Mattil            J. Hemavathy and A.G. Gopala Krishna.            Interesterified coconut oil blends with
    K. F., Identification of the critical unit       Fatty Acid Composition, Oxidative                groundnut oil or olive oil exhibit greater
    operations in the wet processing of fresh        Stability, and Radical Scavenging                hypocholesterolemic effects compared
    coconuts for the recovery of oil and food        Activity of Vegetable Oil Blends with            with their native physical blends in rats.
    grade protein. 1971, Abstr. Papers.              Coconut Oil, J. Amer. Oil Chem.                  Nutri. Res., 2007 27 580-586.
    American Chemical Society, J. Amer.              Soc.,2009 86(10) 991-999.
                                                                                                  49. Anitha Nagaraju, and B.R. Lokesh, Rat
    Chem. Soc., 1971 162: AGFD 8.                38. Murthi T.N., Sharma M., Devdhara V.              fed blended oils containing coconut oil
28. Cancel L.E., Rosario Hernandez J. A.,            D., Chatterjee S., Chakraborty B.K.,             with groundnut oil or olive oil showed
    Hernandez E. R. de, Coconut oil                  Storage stability of edible oils and their       an enhanced activity of hepatic
    extraction from coconut milk press-              blends. J. Food Sci. and Technol.                antioxidant enzymes and a reduction in
    cake. J. Agric. Uni. Puerto Rico, 1976           (India), 1987 24 (2) 84-87.                      LDL oxidation. Food Chem., 2008 108
    60 (3) 281-293.                              39. Garti N., Arkad O. Preparation of                950-957.
29. Gonzalez A.L., Buccat E., Claudio-TR;            cloudy coconut oil emulsions                 50. Malongil B. Reena and Belur R.
    Bueser-NM; Landig R. C., Manalac G.              containing dispersed TiO2 using                  Lokesh, Hypolipidemic effect of oils

July 2010                                                                                                                                   26   l
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                                                                 Copyright (c) by Foxit Software Company, 2004 - 2007
                                                                 For Evaluation Only.                         REVIEW




       with balanced amounts of fatty acids      55. S. Ghosh, D.K. Bhattacharyya, Medium       61. Isaacs C.E., Thomas H., The role of
       obtained       by    blending      and        chain fatty acid-rich glycerides by            milk derived antimicrobial lipids as
       interesterification of coconut oil with       chemical and lipase-catalysed plyester-        antiviral and antibacterial agents. Adv.
       rice bran oil or sesame oil. J. Agric.        monoester interchange reaction. J. Amer.       Exp. Med. Bio, 1991 310 159-165.
       Food Chem., 2007 55: 10461-                   Oil Chem. Soc., 1997 74 (5) 593-595.
                                                                                                62. Bruce Fite, ND, The healing miracle of
       10469.                                    56. Hans Kaunits, Nutritional properties of        coconut oil. Piccadilly Books Ltd.
51. Indian Standard Blended Edible                   coconut oil. J. Amer. Oil Chem. Soc.           Healthwise publications, Colorado
    Vegetable Oils-Specification, BIS. IS:           1970 47(10) 462A-465A.                         Springs, Co. 2000 1-46.
    14309, ICS, 67.200.10 (1995). Babayan        57. Ellen Marie Straarup, Carl-Erik Hoy,
    V. K., Medium chain Triglycerides and                                                       63. Kabara J.J. (Professor Emeritus, Mich
                                                     Structured Lipids Improve Fat
    structured lipids. Lipids, 1987 22(6)                                                           State University and Consut) Health oils
                                                     Absorption       in   Normal        and
    417-420.                                                                                        from the tree of life (Nutrition and
                                                     Malabsorbing Rats 2000 130 (11) 2802-
                                                                                                    health aspects of coconut oil).
52. Babayan V.K., Medium chain                       2808
    Triglycerides-their composition,             58. Dayrit C.S., Coconut oil in health and     64. Lim Sylianco C.Y., Anticarcinogenic
    preparation and application. J. Amer.            desease. Its and monolaurin’s potential        effects of coconut oil. Phillip. J.
    Oil Chem. Soc. 1968 45(1) 23-25.                 as cure for HIV/AIDS. Read at the              Coconut Studies, 1987 12 (2) 89-
53. S. Nandi, S. Gangopadhyay, S. Ghosh,             XXXVIII Cocotech meeting, Chennai,             102.
    Production of medium chain glycerides            India.                                     65. Cohen L. A., Thompson D. O.,
    from coconut and palm kernel fatty acid      59. Gina L. Nick, Coconuts as a functional         Maeura, Choi K., Blank M. E., Rose
    distillates by lipase-catalyzed reactions.       food in the prevention and treatment of        D. P., Dietary fat and mammary cancer.
    Enz. and Microbial Technol. 2005 36              AIDS. Towesnd letter for doctors and           1. Promoting effects of different
    725-728.                                         patients, June, 2006.                          dietary fats on N-nitrosomethylurea-
54. Garfinkel A, Spano M.L. Ditto W.L.,          60. Robert J.J., Pharmacological effects of        induced rat mammary tumorigenesis.
    Weiss J.N., Controlling cardiac chaos.           lipids. AOCS Press, Champaign,                 J. Natl. Cancer Inst., 1986 77 (1) 33-
    Sci., 1992 257 1230-1235.                        Illinois, 1978 1-14.                           42.




                                                 Crazy for coconut oil
       For hundreds of years coconut oil has been a staple in the diets of those who live in tropical regions as an important
   source of nutrients. Coconuts that the PCA-Davao Reseach Center conducted a Field play an important role in a total
       The administrator revealed and extra virgin coconut oil are pure foods that can Release Evaluation where a well
   of 1,948 parasitoid adults were released in infested barangays in Region XI and parallel laboratory tests.
   balanced diet.
       "The parasitoids collected in the field inflicted about 30-50 percent parasitism on the pest&apos;s larva or pupa"
       Research has shown that unrefined coconut oil can be very beneficial. Some of its benefits include: nutrient absorption,
   Garin noted adding that laboratory results showed that around 7 to 47 adult parasitoids emerged from one larva/pupa 18
   boosting energy, promoting weight loss, preventing cardiovascular disease, blood glucose levels, hypoglycemia,
   to 26 days from injection for parasitization.
   strengthening of bones, promoting healthy skin and hair, proper digestion and metabolism, skin conditions and moisturizing
   the "With the earwigs, we now have three indigenous species for biological control of this foreign pest" the administrator
       skin.
   enthused as he underscored the need to adopt a long-term integrated pest management system.
       Coconut oil is nature's richest source of medium chain triglycerides. It has antiviral, anti-bacterial and anti-fungal
       The administrator further stressed that use of chemical insecticides through trunk injection or spraying should only be
   properties. Recently, the western world has discovered coconut oil for its ability in promoting weight loss and preventing
   in severe cases and at first treatment, with the long term and sustainable approach to be comprised of biological control,
   premature aging. Coconut oil contains short practices and strict quarantine controls.advantageous in losing weight and
   use of entomophatogen fungi, good farming and medium-chain fatty acids that are
   because it is easy to digest it supports the healthy function of the thyroid and enzymes systems. Its antioxidant properties
       "Our research centers are now mass rearing these parasitoids for immediate use in areas that may suffer recurrence of
   have been shown to slow the aging process. It is safe for cooking at high temperatures. And it is delicious!!
   Brontispa infestation" he concluded.
                                                                                               (http://www.innisfilscope.com)
                                                                                      http://www.pca.da.gov.ph/pr040109.php


l 27                                                                                                                    Indian Coconut Journal

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English article-gopalakrishna-cftri

  • 1. REVIEW Coconut Oil: Chemistry, Production and Its Applications - A Review Gopala Krishna A.G.,* Gaurav Raj, Ajit Singh Bhatnagar, Prasanth Kumar P.K. and Preeti Chandrashekar Abstract chemistry, MCT and its applications taking a holistic approach on the good C oconut oil is produced by crushing copra, the dried kernel, which contains about 60- and bad effects of coconut oil reported in the literature. 65% of the oil. The oil has the natural Introduction Coconut oil is consumed in sweet taste of coconut and contains tropical countries for 92% of saturated fatty acids(in the Coconut oil is an edible oil that thousands of years. Studies form of triglycerides), most of them has been consumed in tropical done on native diets high in (about 70%) are lower chain countries for thousands of years. As coconut oil consumption show saturated fatty acids known as it has a long shelf life and a melting medium chain fatty acids (MCFAs). point of 76 °F, it is used in baking that this population is MCFAs are not common to different industries. A negative campaign generally in good health. vegetable oils with lauric acid at 45- against saturated fats in general, and Coconut oil has a long shelf 56%. Various fractions of coconut oil the tropical oils in particular, led to life and is used in baking have medium chain triglycerides and most food manufacturers abandoning industries, processed foods, are excellent solvent for flavours, coconut oil in recent years in favor infant formulae, essences, emulsifiers etc. These fatty of hydrogenated polyunsaturated pharmaceuticals, cosmetics acids are used in the preparation of oils, particularly soy, which contain and as hair oil. emulsifiers, as drugs and also in trans fatty acids. Studies done on cosmetics. Its metabolism is different populations consuming diets high in from that of the normal vegetable oils coconut oil show no adverse effects containing long chain fatty acids. on the health of the population (1). Hence, it cannot be generalized as an oil similar in properties to that of a Coconut oil has >90% saturated 92% long chain saturated fatty acids fatty acids, hence is less attractive containing oil/fat. More studies are to consumers. Saturated fat is one required to prove the good effects of that has no unsaturation or double coconut oil, medium chain bonds and tends to be solid at room triglycerides (MCT) and the fatty temperature. Coconut oil is rich in acids on humans especially on the ill short and medium chain fatty acids. effects on cardiovascular and other Shorter chain length allows fatty diseases. The review covers the acids to be metabolized without use production of coconut oil, its of the carnitine transport system. Department of Lipid Science & Traditional Foods, Central Food Technological Research Institute (CSIR), Mysore - 570020 l 15 Indian Coconut Journal
  • 2. REVIEW Various fractions of coconut oil are and type 3 (grades 1, 2 and 3), manipulative methods. Part III used as drugs. Butyric acid is used milling copra for oil extraction. The prescribes detailed laboratory to treat cancer, while lauric acid is material shall be the kernels techniques for determination of: effective in treating viral infections. obtained from the fruits of Cocos colour (lovibond scale); sp. gr. (sp. Hence, the literature is reviewed nucifera Linn. Requirements cover gr. bottle); refractive index; in the context of increase of fat physical and chemical properties, moisture (by distillation); volatile related disorders / diseases through packing, marking, sampling and matter (at 105 degree C/1 h); consumption of highly unsaturated test. impurities (filtration and drying); oils. Table 1. Indian specification for coconut oil (4) Importance of coconut as oil seed Expressed Solvent-extracted The coconut palm is the most Characteristics Refined Grade Grade Grade Refined Semi Grade Grade 1A (Raw) 1B (Raw) 2 (Raw) grade refined 1 (raw) important perennial source of oil, which is grown in India. The Moisture & insoluble 0.1 0.25 0.25 0.25 0.1 0.25 1.0 impurities (max) (%) cultivation of coconut is spread over Colour Lovibond 2 4 11 30 2 10 30 the entire coastal belt and also some colour scale in Y+5R interior tracts. Compared to all other Refractive index 1.4480 to 1.4480 to 1.4480 to 1.4480 to 1.4480 to 1.4480 to 1.4480 to oil seed crops coconut has the at 40 °C 1.4490 1.4490 1.4490 1.4490 1.4490 1.4490 1.4490 highest productivity as well Specific gravity 0.915 to 0.915 to 0.915 to 0.915 to 0.915 to 0.915 to 0.915 to as consistency in production. at 30 °C/30 °C 0.920 0.920 0.920 0.920 0.920 0.920 0.920 Compared to other oil seed crops Saponification value 250 250 250 250 250 250 250 (min) coconut is less susceptible to Iodine value wijs) 7.5 to 10 7.5 to10 7.5 to10 7.5 to10 7.5 to 10 7.5 to10 8.0 to13 abnormal climatic condition. Acid value (max) 0.5 2.0 6.0 8.0 0.5 1.0 10 Coconut oil production in India Unsaponifiable (max) 0.5 0.8 0.8 0.8 0.5 0.8 1.0 Polenske value (min) 13.0 13.0 13.0 - 13.0 - - Rotaries and expellers are used for crushing the dry coconuts Flash point, °C (min) - - - - 225 100 90 (known as copra) for recovery of oil. The total production of edible grade Ceylon-Standard; CS 32: 1968 free fatty acids; I value (modified coconut oil in the country is about describes the specification for Wij’s); saponification value; 4.0 lakh tons which is 1.5 lakh tons coconut oil intended for export. unsaponifiable matter and mineral more compared to that produced in Coconut oil is classified into 4 acidity (titration with 0.01N NaOH 1980’s (2). grades: refined, deodorized to methyl orange) (4). (neutralized, bleached, final steam Specification for coconut oil (3) Common methods of production deodorization); refined (no steam of coconut oil Indian-Standard; IS: 6220-1971 treatment); white oil (higher free specifies the quality parameters of fatty acids); and industrial oil (crude Different types of coconut oil for copra for grading for different uses oil, not edible without processing). edible purposes are available viz, in India. This standard prescribes Part I specifies requirement virgin coconut oil from wet coconuts the methods of grading and the for chemical and physical (unrefined grade); coconut oil from requirements of copra for extraction characteristics, analytical standards, dry coconuts (unrefined grade); and of oil and for table use, together appearance, freedom from coconut oil by solvent extraction with methods of sampling and test. adulterants and suspended matter, method (refined from coconut The 3 types of copra are defined: packaging and marking. Part II expeller cake). Virgin coconut oil is type 1 (grades 1, 2 and 3), ball copra describes and illustrates equipment claimed to have more health benefits for table purpose; type 2 (grades 1 for sampling, with special reference compared to coconut oil extracted and 2), cup copra for table purpose; to large bulk vessels, together with from copra. July 2010 16 l
  • 3. REVIEW Table 2. Codex standards for coconut oil (5) purposes. Traditionally, virgin coconut Characteristic Coconut oil oil is produced by fermentation Colour – Platinum cobalt scale (max) 50 method, where coconut milk expelled Relative density at 40°C/20° C 0.908-0.921 from freshly harvested coconuts is Refractive Index at 40°C 1.448-1.450 fermented for 24-36 hr, and during this Moisture & other volatiles at 105°C 0.1 period, the oil phase gets separated Free fatty acids, calculated as lauric acid % by mass (max) 0.3 from aqueous phase. Further, the Peroxide value (millequivalents of active oxygen per kg) Not more than 15 resulting wet oil is slightly heated for Iodine value 6.3-10.6 a short time to remove the moisture Sap. value 248-265 and finally filtered. The main Unsaponifiables, % by mass, max g/kg ≤ 15 disadvantages of this process are low Reichert value 6 – 8.5 oil recovery and fermented odor, Polenske value 13 –18 which masks the characteristic coconut flavor of the oil. Copra milling by traditional Hydraulic presses methods In conventional methods for These are used in the large virgin coconut oil, freshly extracted The extraction of oil from copra installations. They are of two main milk is centrifuged to obtain cream is one of the oldest seed crushing types-open or Anglo-American which is heated upto 60-80°C before operations. In India and Sri Lanka presses and the closed or cage type centrifuging to obtain the oil. copra is still crushed for oil presses. In this the space between the Systematic research work has been extraction in the primitive chekkus plates above ram and the head is carried out at CFTRI for the as well as in rotary ghanis, expellers divided by plates between which production of several value added and hydraulic presses. copra is put wrapped in press clothes. products from coconut, one of them The chekku is a fixed wooden or The common method is to extract being virgin coconut oil. In the stone mortar inside which revolves oil from copra or the dry coconuts. CFTRI process, virgin coconut oil is on a hard wooden pestle. The pestle Conventionally coconut oil is obtained by ‘wet processing’ without is attached to a long pole which is produced by expelling dry copra, heat, shear and chemicals with moved round via bullocks, donkey followed by refining during which an overall yield of 87.5%. or by human labor. About 20 – 40 oil is exposed to high temperature. Physicochemical properties and fatty kg of copra can be handled by a The copra based refined coconut oil acid compositions were evaluated. chekku. or the solvent extracted and refined Sensory studies are also carried out coconut oil will have a bland taste and found that virgin coconut oil is Copra processing by continuous superior to the commercial sample. due to the refining processes. pressing Scale-up runs were carried out for Wet coconut processing the production of virgin coconut oil. This is done with the help of expellers. The oil expeller is The wet coconuts are subjected to The process technology has been essentially a mechanical screw pressing to ooze the oil out along with transferred to several user industries press in which the oil is expelled coconut milk. This is processed through Coconut Development from the copra by the pressure afterwards without employing heat, Board, Cochin. exerted by a continuous rotating shear, chemicals, refining and is Physico-chemical characteristics warm shaft in the barrel or cage of known as virgin coconut oil. Virgin of coconut oil the press. The barrel is built with coconut oil has applications in pharmaceuticals and cosmetics. It is Solubility openings to allow the escape of oil and these can be adjusted colorless with characteristic coconut Coconut oil is insoluble in water. according to the type of seed being flavor and finds several applications At temperature above its melting crushed. in medicinal, cosmetics and cooking point it is completely miscible with l 17 Indian Coconut Journal
  • 4. REVIEW most of the non-hydroxylic solvents high saponification value, high Chemistry of fatty acids and such as light petroleum, benzene, saturated fatty acids content and is a triglycerides carbon tetrachloride etc. In alcohol, liquid at room temperatures of 27°C. Medium chain triglycerides coconut oil is more soluble than most Unsaponifiable matter common fats and oils. Medium chain triglycerides All natural fats contain minor (MCTs) are a class of lipids in which Chemical composition quantities of substance other than three saturated fats are bound to a Coconut oil contains a high fatty acid glycerides. The glycerol backbone. What distinguishes proportion of glycerides of lower unsaponified constituent is mostly MCTs from other triglycerides is the chain fatty acids (Tables 3, 4 & 5). sterols. The unsaponifiable fact that each fat molecule is between The oil is highly stable towards constituent of coconut oil include a six and twelve carbons in length (9). atmospheric oxidation. The oil is small amount of tocopherols and MCTs are a component of many foods, characterized by a low iodine value, phytosterols (Table 3). with coconut and palm oils being the dietary sources with the highest Table 3. Physico-chemical Characteristics of coconut oil concentration of MCTs. MCTs are also Virgin coconut oil Unrefined coconut Refined coconut available as a dietary supplement (10). from wet coconut Oil from copra oil Appearance Colorless Slight brownish Colourless MCTs have a different pattern of Odour Coconut smell Coconut smell Odourless absorption and utilization than long- Melting point °C 24 24 24 chain triglycerides (LCTs) that make Moisture (%) <0.1 <0.1 <0.1 up 97 percent of dietary fats. For Iodine value (cg I2/g) 12-15 12-15 10-12 absorption of LCTs to occur, the fatty Peroxide value (meq. O2/kg) 0-1 0-1 0-1 acid chains must be separated from Saponification value(mg KOH/g) 245-255 245-255 250-255 the glycerol backbone by the lipase Phospholipids(%) 0.1 0.1 0.0 enzyme. These fatty acids form Unsaponifiable matter(%) — 0.42% 0.19% micelles, are then absorbed and Tocopherols mg/kg 150-200 150-200 4-100 reattached to glycerol, and the Phytosterols mg/kg 400-1200 Total phenolics mg/Kg 640 618 20 resultant triglycerides travel through Fatty acid composition(relative %) the lymphatics en route to the Saturates 92.0 92.0 92.0 bloodstream. Up to 30 percent of Monounsaturates 6.0 6.0 6.0 MCTs are absorbed intact across the Polyunsaturates 2.0 2.0 2.0 intestinal barrier and directly enter the portal vein. This allows for much Table 4. Fatty acid composition of coconut oil and some other vegetable oils quicker absorption and utilization of Vegetable oils C8:0 C10:0 C12:0 C14:0 C16:0 C18:0 C18:1 C18:2 C18:3 C20:0 C22:0 Others MCTs compared to LCTs. MCTs are transported into the mitochondria Coconut 7.0 5.4 48.9 20.2 8.4 2.5 6.2 1.4 - - - independent of the carnitine shuttle, Palm kernel - 1.2 51.6 22.9 12.2 1.3 10.8 - - - - - Sunflower - - - - 6.3 3.0 43.7 47.0 - - - which is necessary for LCT- Rice bran - - - 0.4 22.9 1.8 42.5 30.5 1.4 0.5 - mitochondrial absorption. Oxidation Safflower - - - 0.3 11.9 2.3 29.2 55.9 0.4 - - of MCTs provides 8.3 calories per Sesame - - - - 10.3 5.8 42.9 41.0 - - - gram, while LCTs provides 9.2 Groundnut - - - - 14.0 3.8 41.9 34.7 1.0 1.2 3.4 calories per gram (11). Palm - - 0.2 1.1 42.6 3.8 41.9 10.4 - - - Coconut Oil as a source of Olive - - - - 12.0 2.5 75.7 7.9 0.5 - - 1.4 Soybean - - - - 11.6 4.0 18.8 56.1 8.5 - - 1.0 medium-chain triglycerides Grape seed - - - - 7.2 4.8 19.4 68.1 0.1 - - 0.4 All fats and oils are composed of Linseed - - - - 7.1 2.0 19.9 17.3 53.7 - - 0.4 triglyceride molecules, which are tri July 2010 18 l
  • 5. REVIEW Table 5. TAG (triacyl glycerols or triglycerides) molecular species in coconut oil from India, Malaysia and considered essential nutrients for Indonesia (12 & 13) infants as well as for people with TAG Coconut RBDCNO MAL MAL MAL MAL MAL IND IND IND IND IND serious digestive problems like Species Oil (I) (MAL) 1 2 3 4 5 1 2 3 4 5 cystic fibrosis (15, 16). Like other CaCC 1.1 - - - - - - - - - - - essential nutrients, one must get CaCLa 3.4 - - - - - - - - - - - them directly from the diet. CCLa 12.8 13.1 16.6 15.1 16.4 15.9 16.2 14.4 14.3 16.7 14.7 16.1 CpCpLa - 1.2 0.8 1.1 1.3 1.0 1.4 0.9 1.1 1.3 0.7 0.9 Literature on coconut oil CpCLa - 3.5 4.0 3.9 4.2 4.2 4.2 3.3 3.6 4.3 3.7 3.5 Philippines, Indonesia, India, Sri CLaLa 17.8 17.2 21.4 19.8 19.7 19.8 20.0 19.5 19.2 21.1 19.9 20.3 Lanka, Mexico, West Malaysia, and LaLaLa 20.7 21.9 25.8 23.3 24.1 22.8 23.6 23.5 23.6 23.5 23.6 23.9 Papua & New Guinea are the 7 LaLaM 16.1 17.2 15.1 15.6 13.8 14.6 13.6 15.4 16.5 14.2 16.2 14.8 LaLaO 1.8 2.3 1.3 1.5 2.0 1.4 1.6 1.6 1.8 1.8 1.2 1.6 countries which produce major LaMM 10.1 10.2 8.6 9.5 7.8 9.1 8.2 9.1 9.4 7.4 9.5 8.6 quantities of coconut in the world. LaMO 2.1 2.1 0.9 1.4 1.6 1.3 1.4 1.4 1.5 1.2 1.2 1.2 Coconut is available in two forms LLO/LaMP 6.2 5.8 4.8 4.8 5.0 4.9 4.8 5.7 5.5 4.8 5.4 4.7 viz., wet and dry materials LaOO 1.6 1.4 0.3 1.8 1.1 1.0 1.2 0.9 1.0 1.0 0.9 1.1 commonly known as wet coconut LOO/LaPP 2.9 3.0 0.4 1.3 1.9 2.0 2.0 2.0 1.9 1.7 1.8 2.0 and dry coconut or copra. The oil can PLO 0.9 - - - - - - - - - - - be extracted from both these raw MOO - 0.7 - 0.6 0.4 0.6 0.6 0.6 0.3 0.5 0.5 0.5 materials. However, in India and MPO 0.8 - - - - - - - - - - - Srilanka, it is a general practice to OOO 0.2 - - - - - - - - - - - use only copra for oil extraction and POO - 0.3 - 0.3 0.4 0.4 0.4 0.5 0.2 0.2 0.4 0.5 the oil is used for food and cosmetic POP 0.8 - - - - - - - - - - - purposes. In Phillippines, the oil is PPP 0.2 - - - - - - - - - - - extracted from wet coconut also and is known as virgin coconut oil. In esters of glycerol and fatty acids. The diet (14). It is the MCT in coconut oil some countries solvent extraction of fats upon hydrolysis yield fatty acids that make it different from all other fats the dry coconut followed by refining, and glycerol. There are two methods and for the most part gives it its unique bleaching and deodorization is of classifying fatty acids, character and healing properties. carried out to get the refined monounsaturated fatty acids, and Almost all of the medium-chain bleached and deodorized coconut polyunsaturated fatty acids. The triglycerides used in research, oil. The technology for the second method of classification is medicine, and food products come production of coconut oil through based on molecular size or length of from coconut oil. expellers is well developed and the carbon chain in the fatty acid. many medium scale industries in MCT are easily digested, The vast majority of the fats and absorbed, and put to use nourishing India produce oil by this method. the body. Unlike other fats, they put However, some small scale oils whether they are saturated or industries produce the oil by unsaturated or from an animal or a little strain on the digestive system processing fresh coconut also using plant, are composed of long-chain and provide a quick source of energy local expeller press. Problems of triglycerides. All fats we eat consist of necessary to promote healing. This sediments and rancidity persist in LCT while, coconut oil is unique is important for patients who are these oils. because it is composed predominantly using every ounce of strength they of MCT. The size of the fatty acid is have to overcome serious illness or The literature on coconut oil extremely important because injury. It’s no wonder why MCT are which has been reported as physiological effects of medium-chain added to infant formulas. MCT are published papers and patents from fatty acids in coconut oil are distinctly not only found in coconut oil but also 1970 onwards were reviewed and different from the long-chain fatty are natural and vital components were classified under the following acids more commonly found in our of human breast milk. MCT are heads: l 19 Indian Coconut Journal
  • 6. REVIEW A. Production Methods and Oil feeding the expeller presses; coconut to obtain refined oil and to quality handling and filtering of crude oil; simultaneously recover coconut oil cooling system; and extraction by products including solid coconut A number of reviews are the solvent method. Loncin et al (20) products for human consumption available on the different types of reviewed the utilization of palm oil which has also been patented in extraction and processing methods and coconut oil in the form of India. Castellanos and Asturias (26) for the preparation of coconut oil, interesterified fat. The utilization of investigated the wet milling coconut flour, protein and coconut transesterified palm oil with 25% processes for the extraction of oil cake and meal. Cornelius (17) has coconut oil for production of cooking from decorticated fresh coconut reviewed the aspects of coconut fat of uniform consistency little under a variety of experimental processing such as growing, affected by temperature. (solid fat conditions to get oil of better quality harvesting, handling, storage, index at 10, 20 and 30 degree C being and it required less refining. composition of nut, processing, 45.6, 33.6, 9.2, consistency in 0.1 mm Hagenmaier et al (27) identified the primary products (copra, ball copra, ASTM penetration depth after 9 days’ critical unit operations in the wet desiccated coconut, fibre and shells), storage at 15, 21 and 25 degree C was processing of fresh coconuts for the coconut oil (extraction methods, 19, 38 and 44). Due to its low recovery of oil and food grade composition of coconut oil), uses of oxidation during heating, liquid oil is protein. oil, coconut cake and meal, suitable for table and frying use. nutritional aspects, and the coconut Solvent extraction industry in the 7 major producing Enzymatic process Cancel et al (28) has standardized areas (Philippines, Indonesia, India, Coconut oil is extracted from conditions for coconut oil extraction Sri Lanka, Mexico, West Malaysia, coconut paste by a new enzymatic from coconut milk press-cake. and Papua & New Guinea). Dendy process (1) and the method used less Gonzalez et al (29) studied the and Grimwood (18) have reviewed energy than the conventional solvent extraction of residual oil the various processes for wet processes. A Sri Lankan inventor (21) from wet coconut meal using treatment which have been proposed has developed a simple method for isopropanol. Bernardini (30) has for extraction of oil and protein from making high quality coconut oil and described a new single solvent direct fresh coconut meat: The Chayen, desiccated coconut. Using more extraction process (by CMB, Robledano, ICAIT, Krauss-Maffei, manpower and little or no electricity, Pomezia) which obviates the need Roxas and Sugarman processes, it involves breaking the coconut, for pressing. Aliwalas and Buccat integrated processes, methods used scraping it and drying in a specially (31) studied the filtration-extraction by the Texas A&M University and designed solar drier. The desiccated of granulated coconut on a bench the Tropical Products Institute, coconut produced can be used for scale. Claudio et al (32) carried out London. The problem of obtaining mechanical extraction of colourless, laboratory scale studies on the cheap protein-based food products, odourless coconut oil suitable for preparation of a highly nutritious coconut milk and cream, frozen direct consumption (22). Mojika (23) coconut flour from granulated milk, syrup, etc. is then examined. developed a simple process for coconut. Preliminary feeding expt. A few indications are given producing coconut oil and food grade indicate a PER comparable with regarding the nutritive and chemical copra cake which has been patented. casein. Prepared foods (cakes, aspects of coconut protein. Baltasar Nambiar (24) developed a method for doughnuts, cookies, pastries) with (19) has reviewed the extraction the production of refined oil from the 20-30% wheat flour replaced by process of coconut oil by the dry milk of fresh ripe coconuts and has coconut flour obtained high taste processing technology. Coconut oil been granted an Indian patent. rating. extraction employing dry processing technology is discussed under the Wet processing of coconut Fatty acid composition following headings: preparation of Nambiar (25) has developed a Banzon and Resurreccion (33) raw material; drying or cooking; method of processing fresh ripe carried out a study on the fatty acid July 2010 20 l
  • 7. REVIEW distribution in coconut oil obtained (CECO). However, high temperatures coconut oil can be used as a natural by four processing methods and used in the hot extraction of coconut antioxidant through the blending secured from four Philippine types oil favor the incorporation of more process. Bhatnagar et al (37) have of coconuts. There was no observed thermally stable phenolic observed that addition of coconut oil change in the fatty acid distribution antioxidants into coconut oil. to either safflower oil, sunflower oil, in samples of coconut oil obtained Therefore, the consumption of rice bran oil increased the oxidative by 4 methods, namely: solvent HECO may result in improvement stability of the resultant blend. extraction, fermentation, freeze- of antioxidant related health benefits Phase separation thawing and heating. Neither was compared with the consumption of there such a change observed in CECO. Murthi et al (38) studied the coconut oil samples obtained from storage stability of edible oils and Moura (6) studied the changes in their blends. Among the blends, 4 types of coconuts. some components of the sesame oil or groundnut oil blended Phenolics and antioxidant activity unsaponifiable fraction of coconut oil with refined cottonseed oil showed Kapila and Dissanayake (34) during refining. 8 lots of coconut oil the least increase in FFA. PV of raw studied the phenolic compounds were sampled at 5 points in the refining edible oils and their blends tended present in the nonsaponifiable process. The unsaponifiable matter to rise steadily to a maximum, fraction of coconut oil by high- (UNS) comprised hydrocarbons declining gradually thereafter. performance liquid chromatography (including squalene), aliphatic Acceptability became poor for raw with florescence detection. Mass alcohols and triterpenoid alcohols, edible oils after 120 days, when the spectra of the phenolic compounds sterols and a final group containing PV was between 5.9 and 16 m- were also obtained separately by free fatty acids (FFA), campesterol and equiv./kg, and for refined oils after LC–MS to confirm the presence of some unidentified components. 90 days (PV was 4.4-9) and for the the phenolic compounds. Caffeic Tocopherols were not detected in the blends after 90-120 days (PV 4-45). acid, p-coumaric acid, ferulic acid coconut samples analysed. Manalac The consumer preference in various and catechin were observed in and Harder (36) analysed the areas was for oil blends containing coconut oil. Phenolic acid fraction tocopherol content of coconut oil from cottonseed oil with sesame oil or of the coconut oil prepared by a commercial processing plant at groundnut oil, coconut oil with palm boiling coconut milk (traditional different stages of refining. One olein, and rapeseed oil with mustard coconut oil) was more complex sample of crude oil containing oil. Blends containing palm oil were compared with that of coconut oil 721.06µg/g lost 94.5% resulting in less acceptable, as a waxy solid mass prepared by pressing copra 38.9µg/g in the final product. separates out in these oils. (commercial coconut oil). Total It is observed from the above Coconut oil emulsions phenol content of traditional coconut literature reports that there is oil was nearly seven times higher Garti and Arkad (39) studied the variation in the composition of process of preparation of cloudy than that of commercial coconut oil coconut oil with respect to natural coconut oil emulsions containing (618 ± 46 vs. 91 ± 11 mg kg )1 ), antioxidants level with the method dispersed TiO2 using atomizer. suggesting that the phenol content used for its extraction which may Rogov et al (40) studied the viscosity varies with the extraction method. have a bearing on the nutritional of the fat components of margarine Kapila, Chamil and Sagarika (35) quality of the oil. emulsions. Technological procedures compared the antioxidant activities B. Blending of coconut oil with in margarine manufacture (dosage, of coconut oil extracted under hot other vegetable oils transport, mixing) are affected by the and cold conditions. The coconut oil viscosity of the fat component. Oxidative stability extracted under hot conditions Viscosities of some fats (hardened (HECO) contained more phenolic Coconut oil addition to other fat, qualities 1, 2 and 3, coconut oil, substances than the coconut oil vegetable oils improves their vegetable oil blends, etc.) and of the extracted under cold conditions oxidative stability indicating that fat components used for margarine l 21 Indian Coconut Journal
  • 8. REVIEW emulsion preparation were following process for oil extraction specification for a vegetable oil determined at 40 degree C. The from coconut meat: (i) wet method blend. viscosities of different fat blend (using a De Laval centrifuge), (ii) A.17.24. “Blended Edible emulsions applied in Russian hydraulic pressing, (iii) pressing plus Vegetable Oil” means an admixture margarine formulations were also solvent extraction, (iv) filtration of any two edible vegetable oils determined and are tabulated. extraction (direct solvent extraction). where the proportion by weight of Oil extraction efficiencies obtained Nutritional effects of coconut oil any edible vegetable oil used in the were: (i) 79.56% (increased to 96.3% blends admixture is not less than 20 per by subsequent solvent extraction), Bellenand et al (41) studied the cent. The individual oils in the blend (ii) 76.47%, (iii) 99.65%, (iv) 96.58. effects of coconut oil on heart lipids shall conform to the respective Protein contents of isolates from (i) and on fatty acid utilization in standards prescribed by these rules. ranged from 59 to 75%. Protein rapeseed oil. The cardiac lipidosis The blend shall be clear, free from efficiency ratio (PER) biological was proportional to the content of rancidity, suspended or insoluble value (BV), true digestibility (TD) erucic acid in the diet. At 60 days, matter or any other foreign matter, and net protein utilization (NPU) of the high level of 22:6 in the cardiac separated water, added colouring coconut flour from (ii), (iii) and (iv) phospholipids of rats fed rapeseed oil matter, flavouring substance, were: PER 2.42, 2.55, 2.42; BV 77, was reduced by the addition of mineral oil, hydrocyanic acid, castor 84, 79; TD 76, 74, 72; NPU 68, 64, sunflower oil but not by coconut oil. oil and tricresyl phosphate. It shall 66. Values for coconut isolate Thus, the blending of rapeseed oil also conform to the following prepared by heat coagulation of with coconut oil apparently is less standards, namely; cream or aqueous portion of fresh desirable than that of rapeseed oil coconut milk from (i) were: PER Based on the PFA specifications, and sunflower oil. McCutcheon et al 1.50, 2.20; BV 72, 80; TD 88, 92; a process has been developed at the (42) studied the cardiopathogenicity NPU 59, 65. The traditional rural Central Food Technological of rapeseed oils and oil blends method gave an oil extraction Research Institute, Mysore under differing in erucic, linoleic and efficiency of 82.45, and a protein sponsorship from the Coconut linolenic acid content on male Wistar isolate with PER 1.25, BV 62, TD Development Board, Cochin and is rats using semipurified diets. Lowest 86 and NPU 58. ready for commercialization. lesion incidence was obtained with Reena Rao and Lokesh (46, 47), C. Edible applications of safflower oil and hydrogenated Anitha Nagaraju and Lokesh (48, 49) coconut oil coconut oil. It has been postulated and Reena and Lokesh (50) have that linolenic acid plays a role in the Coconut oil has a high degree of used immobilized lipase systems for etiology of cardiac necrosis observed saturation with a high content of the synthesis of structured lipids when rats are fed diets containing saturated fatty acids. Because of from coconut oil and omega 6 and low erucic acid rapeseed oils. high content of saturated fatty acids omega 3 fatty acids and carried out Theuer (43) developed fat nutritional evaluation of the same in coconut oil is highly resistant to compositions for infant formulas rats. They found beneficial effects in oxidative rancidity, coconut oil is containing vegetable fats with a fatty the lipid profile after enzymatic used as a component of infant milk acid simulating that of human milk. acidolysis of coconut oil with omega powders because of its easy Grandadam (44) developed 6 and omega 3 fatty acids. digestibility and stable flavor. processes to recover the proteins of Coconut oil is extensively used in Indian Specification for blending the food industries as a the coconut from copra cake, or of vegetable oils confectionery fat particularly in the directly from fresh coconut meat by different processes. The improved As per the Prevention of Food preparation of ice creams. In Itipat process of double pressing Adulteration Act 1954 Rules imitation chocolates coconut oil is allows recovery of 93.45% of the oil and Regulations and updated used in place of cocoa butter along and 91.9%. Aliwalas (45) studied the amendments following is the with cocoa powder. July 2010 22 l
  • 9. REVIEW Indian Specification for blending of two oils materials. These MCTs can also be a. Moisture and volatile matter Not more than 0.2 per cent by weight used as a glaze and polishing agent b. Acid Value for confectionery products such as Nature of oil Acid value gummy- type candies. Solid MCTs 1. Both raw edible vegetable oils in the blend Not more than 6.0 can help to enhance aeration 2. One raw edible vegetable oil and one refined edible properties in bakery products (55, vegetable oil in the blend Not more than 5.0 56). 3. Both refined edible vegetable oils in the blend Not more than 5.0 c. Unsaponifiable matter: MCT derivatives- structured 1. Blend with rice bran oil Not more than 3.0 per cent by weight lipids 2. Blend with other edible vegetable oils Not more than 1.50 per cent by weight Medium chain triglycerides can d. Flash point (Penske Martin closed method) Not less than 250ºC be used to custom design fats. MCTs 1. Test for argemone oil shall be negative for the blend with conventional long chain fats give 2. However, blend may contain food additives permitted in these rules and Appendix ‘C’. products with unique physical and Use in the synthesis of medium Functional benefits of medium nutritional products. MCT derivatives chain triglycerides chain triglycerides show unique properties compared to their corresponding physical blends. Medium chain triacylglycerols Medium chain triglycerides are They may contribute nutritional and are unique categories of lipids widely used in the flavor industries functional benefits to value added produced by the esterification of as they are more polar and therefore foods (57, 58, 59). glycerol with medium chain fatty more hydrophilic and can dissolve acids, which come from high lauric a variety of polar substances that are D. Non-edible applications oils. Coconut and palm kernel oils insoluble in conventional fats and of coconut oil are the only commercially important oils. Hydrocarbons, esters and One of the major non-edible sources of medium chain fatty acids natural oils as well as alcohols, applications of coconut oil is in the (52). These oils are hydrolyzed to ketones and acids are miscible with soap industries; one important liberate their fatty acids from MCTs. These properties make chemical derivative of coconut oil glycerol, and then the fatty acids are MCTs superior carrier for flavors, is methyl esters of coconut fatty separated by fractional distillation. vitamins and colors when compared acids, which are produced by The lower boiling or top fraction of to conventional oils. MCTs have a treating coconut oil with methyl the fatty acids contains the medium lower molecular weight than alcohol. These methyl esters chain acids (53).The esterification conventional oils. This gives MCTs constitutes an important raw reaction between glycerol and the a lower viscosity than conventional material for the chemical industries medium chain fatty acids is carried oils, even at low temperatures. as they are more stable and are out at high temperatures with or without use of a catalyst. The water MCTs oils have no unsaturated fatty easier to separate by fractional liberated in the reaction is removed acids present; therefore they are distillation. Coconut oil has many continuously to drive the reaction to exceptionally stable to oxidation. other industrial uses in the completion (54). When the MCTs have excellent keeping pharmaceuticals, cosmetics, plastics, esterification reaction is complete, qualities and therefore help to rubber substitutes, synthetic resins excess fatty acids are removed from increase shelf- life of finished etc. Coconut oil has also been found the reaction mixture by vacuum products. MCTs are ideal for useful for mixing with diesel. These distillation. To remove the volatile treating the surfaces of crackers to mixture in the proportion as 30:70 odor and flavor components as well act as a moisture barrier. They has given excellent road as any residual fatty acids, the crude adhere well to surfaces, including performance of diesel vehicles. MCTs are deodorized to get a final metals. They are excellent release Methyl esters of coconut oil fatty product that has a bland flavor and agent for surfaces that come into acids is also being used as lubricants is odorless and colorless. contact with food products or raw and biodiesel in aviation industry. l 23 Indian Coconut Journal
  • 10. REVIEW E. Clinical Applications of Healing properties of coconut oil Saturated fatty acids of coconut oil medium chain triglycerides and having medicinal properties Coconut oil is antiviral, anti- saturated fatty acids Roughly 45 to 50% of fatty acids fungal (kills yeast too) and Malabsorption antibacterial. It attacks and kills of coconut oil form lauric acid. viruses that have a lipid (fatty) Lauric acid is known to kill viruses Children with cystic fibrosis coating, such as herpes, HIV, and bacteria that are enveloped in a supplemented with up to 75 ml of hepatitis C, the flu, and phospholipid membrane. Examples MCTs per day experienced greater mononucleosis. It kills the bacteria of viruses with a fatty capsule are: weight gain and reduced fecal fat that cause pneumonia, sore throats, influenza viruses and HIV. Coconut compared to a trial period on a dental cavities, urinary tract itself contains about 75% fiber, not control diet (9). When MCTs are infections, meningitis, gonorrhea, bran fiber from wheat and grains given concurrently with a pancreatic (which contains phytic acid that enzyme preparation, absorption is food poisoning and many more bacterial infections (63). It kills the absorbs calcium and other mineral improved (58). MCTs have been from your body before it is used in other malabsorption fungus/yeast infections that cause candida, ringworm, athletes foot, excreted), but dietary fiber that feeds syndromes, including short-bowel beneficial colon flora. As the fiber syndrome, celiac disease, and thrush, jock itch and diaper rash. is metabolized by the naturally hepatic disease (15). occurring bacteria, they by default, HIV/AIDS Use of saturated fats in therapeutic crowd out other potentially harmful applications pathogens and produce short chain MCTs may help with weight Saturated fatty acids can be fatty acids (SCFA’s) like acetic acid maintenance in AIDS patients. An (minute amounts of vinegar and enteral formula containing 85 used to: boost the immune system, for weight management, as butyric acid (originally isolate in percent of fat calories from MCTs butter) both compounds are known (35% of total calories from fat) led antimicrobials, to support the to have varying degrees of anti to decreases in stool fat, number of structure of gut mucosa, and as microbial activity. These fatty acids bowel movements, and abdominal dietary adjuncts in cases of chronic are absorbed directly into the colon symptoms, as well as increased fat degenerative disease, such as and serve as energy in that way. absorption compared to baseline cardiovascular disease, liver Butyric acid has been shown to have (59). No improvement was seen in disease and cancer. As far as the anti-tumor properties. Many subjects taking a control LCT- integrity of the gut mucosa is researchers have reported that containing formula. Another concerned, the use of short and coconut oil lowers cholesterol. The controlled trial confirmed these medium chain fatty acids can cholesterol-lowering properties of results (60). MCT-containing reduce mucosal irritation coconut oil are a direct result of its caloric supplements do not appear characteristic of aliments such as: ability to stimulate thyroid function. to cause weight gain in AIDS IBS, ulcerative colitis, and In the presence of adequate thyroid patients compared to a control diet. dysbiosis, to name a few. In hormone, cholesterol (specifically In 1978, Kabara and others (61) particular, short chain fatty acids LDL-cholesterol) is converted by reported that certain medium chain are antihistaminic and may find use enzymatic processes to the vitally fatty acids, such as lauric acid have in the treatment of allergic-type necessary anti-aging steroids, adverse effects on other pathogenic conditions, such as asthma, pregnenolone, progesterone and microorganisms, including bacteria, urticaria and food sensitivities. DHEA. These substances are yeast and fungi. These fatty acids Studies have also shown that short required to help prevent heart and their derivatives actually chain saturated fatty acids can be disease, senility, obesity, cancer and disrupt the lipid membranes of the used in the treatment of dental other diseases associated with ageing organisms and thus inactivate them caries, peptic ulcers, BPH, genital and chronic degenerative diseases (62). herpes, and hepatitis (64). (64). July 2010 24 l
  • 11. REVIEW Anti-Cancer Effects of Coconut effects of the oil has also been Section B. Sci. and Engg., 1971 32 (6) Oil reported especially in cardiovascular 3424-3425 order no. 72-1709. diseases due to the presence of less 7. Lucita R Lauretes, Felicito M In 1987 Lim-Sylianco (64) Rodriguez, Consorcia E. Reano, of unsaturated fatty acids in the published a 50-year literature review Genardo A Santos, Antonio CLaurena, triglycerides of the oil. It is Evelyn Mae Tecson Mendoza. showing the anti-cancer effects of hypothesized that due to lower Variability in fatty acid and coconut oil. In chemically induced amount of PUFA, there is a triacylglycerol composition of the oil of cancers of the colon and breast, coconut (Cocos nucifera L.) hybrid and possibility of atherogenecity Cohen et al (65) showed that coconut their parental. J. Agric. Food Chem., development during long term usage oil was by far more protective than (2002) 50 1581-1586. of the oil. However, more research unsaturated oils. For example 32% 8. Frank D Gunstone, John L Harwood, is needed to clearly understand the Albert J Dikstra. The lipid handbook. of corn oil eaters got colon cancer many good effects of the oil. CRC Press, Taylor and Francis Group. whereas only 3% of coconut oil eaters got the cancer. Animals fed Acknowledgements 9. Babayan, V.K. Medium chain triglycerides. In dietary fat requirements unsaturated oils had more tumors. The authors thank Dr. V. Prakash, in health and development. (CJ Beare- This shows the thyroid-suppressive Director, CFTRI, Mysore and the Rogers, ed) AOCS press, Champain, and hence, immuno-suppressive Coconut Development Board, Kochi Illinois (USA) 1988 73-86. effect of unsaturated oils. for enthusing us to write this review 10. J. A. Heydnger, D. K. Nakhasi, Medium chain Triacylglycerols. J. of Food Conclusions and Dr. B.R. Lokesh, Head, Dept. of Lipids, (3) 1996 251-257. Lipid Science & Traditional Foods, Coconut oil is consumed in 11. Ralph Hoahland,George G. Snider, for critically going through the Digestability of certain higher saturated tropical countries for thousands of manuscript. fatty acids and triglycerides. J. Nutri., years. Studies done on native diets 1943 26(3) 219-225. high in coconut oil consumption References 12. Malongil B. Reena, Sunki R. Y. Reddy, show that this population is generally 1. Thampan, P.K., Glimpses of coconut Belur R. Lokesh, Changes in in good health. Coconut oil has a industry in India, Coconut triglyceride molecular species and Development Board, Cochin 1988. thermal properties of blended and long shelf life and is used in baking 2. http://www.seaofindia.com/. Import interesterified mixtures of coconut oil industries, processed foods, infant of vegetable oils, The Solvent or palm oil with rice bran oil or sesame formulas, pharmaceuticals, cosmetics Extractors’ Association of India, oil. Eur. J. of Lipid Sci. and Tech., 2009 and as hair oil. The oil contains 92% Mumbai, India. 111: 346-357. of saturates consisting of medium 3. Indian Standards Institution 13. A. M. Marina, Y. B. Che Man, S. A. H. chain fatty acids in the form of Specification, Grading for copra for Nasimah, I. Amin, Chemical properties triglycerides, and about 8% of table use and for oil milling. India, of virgin coconut oil. J. Amer. Oil Indian- Standard; IS: 6220-1971, Chem. Soc., 2009 86 301-307. unsaturates consisting of oleic and 10pp. Methods of sampling and test linoleic acids as triglycerides. The oil 14. Furman, R.H., Howard R.P., Brusco for oils and fats, Indian Standard O.J., Alaupoic P, Effects of Medium has a small amount of unsaponifiable specification for coconut oil IS:542- chain length triglyceride on serum matter (< 0.5%), is colourless and 1968. Indian Standards Institution lipids. In medium chain triglyceride. U New Delhi. 1971. has a odour typical of the coconuts. Penn Press Pennysylvania 51-61. The oil has small amounts of 4. Specification for coconut oil. Ceylon, Ceylon-Standard: CS 32: 1968 24pp. 15. Johnson R.C., Cotter R. Metabolism of tocopherols and tocotrienols and Bureau of Ceylon Standards. 1968. medium chain triglyceride lipid phytosterols. The oil is known to emulsions. Nutr. Int., 1986 2 150-158. 5. Codex Alimentarius (FAO/WHO), have antiviral and antibacterial Codex Standards for Named Vegetable 16. Marie-Pierre St-Onge, Robert Ross, effects and excellent healing Oils, Codex Stan 210-1999. Codex William D. Parsons, Peter J.H. Johns, Alimentarius, V.8-2001. Rome, Italy, p Medium chain triglycerides increase properties. It gets easily absorbed in 11-25. energy expenditure and decrease the body and is a nature mimic of adiposity in overweight men. Obesity 6. Moura Fe J de A, Changes in some the human breast milk fat and hence Res., 2003 11(3) 395-402. components of the unsaponifiable used in infant formulae. With all fraction of coconut oil during refining. 17. Cornelius J.A., Coconuts: a review. these good quality attributes, the side Dissertation Abstracts International. Trop. Sci., 1973 15 (1) 15-37. l 25 Indian Coconut Journal
  • 12. REVIEW 18. Dendy DAY, Grimwood BE, Coconut C., Studies on solvent extraction of atomizer. J. Dispersion Sci. and Processing for the production of residual oil from wet coconut meal Technol., 1986 7 (5) 513-523. coconut oil and coconut protein food using isopropanol. Phillip. J. Sci., 1973 40. Rogov B.A., Stetsenko A.V., and feed products. Oleagineux, 1973 28 102 (1/2) 31-43. Kuznetsova N.M., Viscosity of the fat (2)93-98. 30. Bernardini E., Direct extraction of oil components of margarine emulsions. 19. Baltasar S.F., Coconut oil extraction from oilseeds without pressing. Riv. Maslozhirovaya Promyshlennost, 1984, employing the dry processing Itali. de. Sost. Gras., 1970 47 (8) 385- No. 11, 19-20. technology. Phillip. J. Coconut Studies, 391 41. Bellenand J.F., Baloutch G., Ong N.; 1977 2 (4) 40-42. 31. Aliwalas A.R., Buccat C.P., Filtration- Lecerf J., Effects of coconut oil on heart 20. Loncin M., Palm oil. Fette Seif. extraction of granulated coconut on a lipids and on fatty acid utilization in Anstrichm., 1974 76 (3) 104-112. bench scale. Phillip. J. Sci., 1970, 96 rapeseed oil. Lipids, 1980 15 (11) 938- (3) 215-285. 943. 21. Leonard E., Sri Lankan inventor who 32. Claudio-TR; Capulso S.A., Gonzales 42. McCutcheon J.S., Umermura T; makes life easier for his countrymen. A.L., Fuente F. S. de la; Manalac G.C., Bhatnagar M.K., Walker B.L., 1983, Cocomunity, APCC/QS/45/83, Laboratory scale studies on the Cardiopathogenicity of rapeseed oils 33-35. preparation of coconut flour from and oil blends differing in erucic, 22. Small-scale oil extraction from granulated coconut. Phillip. J. Sci., 1968 linoleic and linolenic acid content. groundnuts and copra. International 97 (1) 45-56. Lipids, 1976. 11 (7) 545-552. Labour Office; United Nations 43. Theuer R.C., Fat compositions for 33. Banzon J.A., Resurreccion A.P., Fatty Industrial Development Organization, infant formulas. 1981 US Patent 4, 282, acid distribution in coconut oil obtained Technical Memorandum, United 265. by four processing methods and secured Nations Industrial Development from four Philippine types of coconuts. 44. Grandadam Y., The proteins of the Organization; 1983, No. 4, xi + 111pp. Phillip. J. Coconut Studies, 1979 4 (2) coconut. Industries Alimentaires et ISBN 92 2 103503 4. 1-8. Agricoles, 1973 90 (9/10) 1253-1268. 23. Mojica I.N. Jr, Process for producing 34. Kapila N. Seneviratne, Dissanayake M. 45. Aliwalas A.R., Gonzales A.L., Claudio coconut oil and food grade copra cake. Sudarshana Dissanayake, Variation of T.R., Benet R., A study of the wet and 1978, Philippines-Patent 11661/C. phenolic content in coconut oil dry methods of extracting oil from 24. Nambiar T.V.P., Method for the extracted by two conventional methods. coconut meat. Phillip. J. Sci., 1969 98 production of refined oil from the milk International J. Food Sci. and Technol., (2) 139-149. of fresh ripe coconuts. 1977. Indian- 2008 43 597–602 597. 46. Reena Rao, Enzymatic synthesis of Patent. 35. Kapila N. Seneviratne, Chamil D. structured lipids by immobilized lipase 25. Nambiar T.V.P., A method of processing HapuarachchI , Sagarika Ekanayake, systems in organic solvents. Ph.D. fresh ripe coconut to obtain refined oil Comparison of the phenolic-dependent Thesis, CFTRI, Mysore, University of and to simultaneously recover coconut antioxidant properties of coconut oil Mysore 2001. products including solid coconut extracted under cold and hot conditions. 47. Reena Rao and B.R. Lokesh, products for human consumption. 1977, Food Chem., 2009 114 1444–1449. Nutritional evaluation of an omega 6 Indian-Patent. 36. Manalac G.C., Harder Soliven A., fatty acid containing structured lipid 26. Castellanos P.S., Asturias C.R., Tocopherol content of coconut oil at synthesized from coconut oil. Lipids, Extraction of oil from fresh coconut. various stages of processing. Phillip. J. Mol. and Cell. Biochem., 2003 248 (1- Oleagineux, 1969 24 (7) 419-21; 24 (8/ Sci., 1970 96 (3) 239-48. 2) 25-33. 9) 505-09. 37. Bhatnagar, A.S., Prasanth Kumar P.K., 48. Anitha Nagaraju, and B.R. Lokesh, 27. Hagenmaier R. D., Cater C. M., Mattil J. Hemavathy and A.G. Gopala Krishna. Interesterified coconut oil blends with K. F., Identification of the critical unit Fatty Acid Composition, Oxidative groundnut oil or olive oil exhibit greater operations in the wet processing of fresh Stability, and Radical Scavenging hypocholesterolemic effects compared coconuts for the recovery of oil and food Activity of Vegetable Oil Blends with with their native physical blends in rats. grade protein. 1971, Abstr. Papers. Coconut Oil, J. Amer. Oil Chem. Nutri. Res., 2007 27 580-586. American Chemical Society, J. Amer. Soc.,2009 86(10) 991-999. 49. Anitha Nagaraju, and B.R. Lokesh, Rat Chem. Soc., 1971 162: AGFD 8. 38. Murthi T.N., Sharma M., Devdhara V. fed blended oils containing coconut oil 28. Cancel L.E., Rosario Hernandez J. A., D., Chatterjee S., Chakraborty B.K., with groundnut oil or olive oil showed Hernandez E. R. de, Coconut oil Storage stability of edible oils and their an enhanced activity of hepatic extraction from coconut milk press- blends. J. Food Sci. and Technol. antioxidant enzymes and a reduction in cake. J. Agric. Uni. Puerto Rico, 1976 (India), 1987 24 (2) 84-87. LDL oxidation. Food Chem., 2008 108 60 (3) 281-293. 39. Garti N., Arkad O. Preparation of 950-957. 29. Gonzalez A.L., Buccat E., Claudio-TR; cloudy coconut oil emulsions 50. Malongil B. Reena and Belur R. Bueser-NM; Landig R. C., Manalac G. containing dispersed TiO2 using Lokesh, Hypolipidemic effect of oils July 2010 26 l
  • 13. Edited by Foxit PDF Editor Copyright (c) by Foxit Software Company, 2004 - 2007 For Evaluation Only. REVIEW with balanced amounts of fatty acids 55. S. Ghosh, D.K. Bhattacharyya, Medium 61. Isaacs C.E., Thomas H., The role of obtained by blending and chain fatty acid-rich glycerides by milk derived antimicrobial lipids as interesterification of coconut oil with chemical and lipase-catalysed plyester- antiviral and antibacterial agents. Adv. rice bran oil or sesame oil. J. Agric. monoester interchange reaction. J. Amer. Exp. Med. Bio, 1991 310 159-165. Food Chem., 2007 55: 10461- Oil Chem. Soc., 1997 74 (5) 593-595. 62. Bruce Fite, ND, The healing miracle of 10469. 56. Hans Kaunits, Nutritional properties of coconut oil. Piccadilly Books Ltd. 51. Indian Standard Blended Edible coconut oil. J. Amer. Oil Chem. Soc. Healthwise publications, Colorado Vegetable Oils-Specification, BIS. IS: 1970 47(10) 462A-465A. Springs, Co. 2000 1-46. 14309, ICS, 67.200.10 (1995). Babayan 57. Ellen Marie Straarup, Carl-Erik Hoy, V. K., Medium chain Triglycerides and 63. Kabara J.J. (Professor Emeritus, Mich Structured Lipids Improve Fat structured lipids. Lipids, 1987 22(6) State University and Consut) Health oils Absorption in Normal and 417-420. from the tree of life (Nutrition and Malabsorbing Rats 2000 130 (11) 2802- health aspects of coconut oil). 52. Babayan V.K., Medium chain 2808 Triglycerides-their composition, 58. Dayrit C.S., Coconut oil in health and 64. Lim Sylianco C.Y., Anticarcinogenic preparation and application. J. Amer. desease. Its and monolaurin’s potential effects of coconut oil. Phillip. J. Oil Chem. Soc. 1968 45(1) 23-25. as cure for HIV/AIDS. Read at the Coconut Studies, 1987 12 (2) 89- 53. S. Nandi, S. Gangopadhyay, S. Ghosh, XXXVIII Cocotech meeting, Chennai, 102. Production of medium chain glycerides India. 65. Cohen L. A., Thompson D. O., from coconut and palm kernel fatty acid 59. Gina L. Nick, Coconuts as a functional Maeura, Choi K., Blank M. E., Rose distillates by lipase-catalyzed reactions. food in the prevention and treatment of D. P., Dietary fat and mammary cancer. Enz. and Microbial Technol. 2005 36 AIDS. Towesnd letter for doctors and 1. Promoting effects of different 725-728. patients, June, 2006. dietary fats on N-nitrosomethylurea- 54. Garfinkel A, Spano M.L. Ditto W.L., 60. Robert J.J., Pharmacological effects of induced rat mammary tumorigenesis. Weiss J.N., Controlling cardiac chaos. lipids. AOCS Press, Champaign, J. Natl. Cancer Inst., 1986 77 (1) 33- Sci., 1992 257 1230-1235. Illinois, 1978 1-14. 42. Crazy for coconut oil For hundreds of years coconut oil has been a staple in the diets of those who live in tropical regions as an important source of nutrients. Coconuts that the PCA-Davao Reseach Center conducted a Field play an important role in a total The administrator revealed and extra virgin coconut oil are pure foods that can Release Evaluation where a well of 1,948 parasitoid adults were released in infested barangays in Region XI and parallel laboratory tests. balanced diet. "The parasitoids collected in the field inflicted about 30-50 percent parasitism on the pest&apos;s larva or pupa" Research has shown that unrefined coconut oil can be very beneficial. Some of its benefits include: nutrient absorption, Garin noted adding that laboratory results showed that around 7 to 47 adult parasitoids emerged from one larva/pupa 18 boosting energy, promoting weight loss, preventing cardiovascular disease, blood glucose levels, hypoglycemia, to 26 days from injection for parasitization. strengthening of bones, promoting healthy skin and hair, proper digestion and metabolism, skin conditions and moisturizing the "With the earwigs, we now have three indigenous species for biological control of this foreign pest" the administrator skin. enthused as he underscored the need to adopt a long-term integrated pest management system. Coconut oil is nature's richest source of medium chain triglycerides. It has antiviral, anti-bacterial and anti-fungal The administrator further stressed that use of chemical insecticides through trunk injection or spraying should only be properties. Recently, the western world has discovered coconut oil for its ability in promoting weight loss and preventing in severe cases and at first treatment, with the long term and sustainable approach to be comprised of biological control, premature aging. Coconut oil contains short practices and strict quarantine controls.advantageous in losing weight and use of entomophatogen fungi, good farming and medium-chain fatty acids that are because it is easy to digest it supports the healthy function of the thyroid and enzymes systems. Its antioxidant properties "Our research centers are now mass rearing these parasitoids for immediate use in areas that may suffer recurrence of have been shown to slow the aging process. It is safe for cooking at high temperatures. And it is delicious!! Brontispa infestation" he concluded. (http://www.innisfilscope.com) http://www.pca.da.gov.ph/pr040109.php l 27 Indian Coconut Journal