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Ch11 Solutions  pp
11.1 Solution Composition ,[object Object],[object Object],[object Object],[object Object],[object Object]
Ways of Measuring ,[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],Ways of Measuring
[object Object],[object Object],[object Object],[object Object],[object Object],Given 1.00 g C 2 H 5 OH & 100. g H 2 O and final volume of 101 mL ,[object Object],[object Object],[object Object],[object Object]
11.2 The Energies of Solution Formation  pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
1. Break apart Solvent  pp ,[object Object],[object Object],[object Object]
3. Mixing solvent and solute  pp ,[object Object],[object Object],[object Object],[object Object]
Figure 11.1 The Steps in the Dissolving Process  pp
[object Object],Energy Solute Solution  H 1  H 2  H 3 Solvent Solute and Solvent  H 3 No solution
Types of Solvent and solutes  pp ,[object Object],[object Object],[object Object],[object Object]
Table 11.3 p.521  pp
Energetics of Solutions & Solubility  pp ,[object Object],[object Object],[object Object]
Energetics of Solutions & Solubility  pp ,[object Object],[object Object],[object Object]
Energetics of Solutions & Solubility  pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
11.3 Factors Affecting Solubility  Structure  and Solubility ,[object Object],[object Object],[object Object]
Soap P O - CH 3 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 O - O -
Soap ,[object Object],P O - CH 3 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 O - O -
Soap ,[object Object],P O - CH 3 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 O - O -
Skeletal structure of Soap _ P O - CH 3 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 CH 2 O - O -
[object Object],[object Object],[object Object],[object Object]
[object Object]
[object Object]
[object Object],[object Object]
Figure 23.29 Soap Micelles
Pressure effects ,[object Object],[object Object],[object Object]
Dissolving Gases ,[object Object],[object Object],[object Object]
[object Object],[object Object]
[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object]
Calculations using Henry’s Law  pp ,[object Object],[object Object],[object Object]
Calculations using Henry’s Law  pp ,[object Object],[object Object],[object Object],[object Object]
Calculations using Henry’s Law  pp ,[object Object],[object Object],[object Object],[object Object]
Temperature Effects ,[object Object],[object Object],[object Object]
20 40 60 80 100
Gases are predictable ,[object Object],[object Object],[object Object]
Figure 11.7  The Solubilities of Several Gases in Water
11.4 The Vapor Pressures of Solutions ,[object Object],[object Object]
Raoult’s Law: ,[object Object],[object Object],[object Object],[object Object]
[object Object],Aqueous Solution Pure water
[object Object],Aqueous Solution Pure water
[object Object],Aqueous Solution Pure water
[object Object],[object Object],[object Object],[object Object],Review Question  pp
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Review Question  pp
[object Object],[object Object],[object Object],[object Object],Review Question  pp
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Ideal/Non-ideal solutions
Test-type Question (will be on our test!)  pp ,[object Object],[object Object],[object Object],[object Object]
Test-type Question  pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Test-type Question rf. Z7e #49  pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Test-type Question  pp ,[object Object],[object Object],[object Object]
Test-type Question  pp ,[object Object],[object Object],[object Object],[object Object]
Deviations  to non-ideality ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Colligative Properties ,[object Object],[object Object],[object Object],[object Object],[object Object]
Colligative Properties  pp ,[object Object],[object Object],[object Object],[object Object],[object Object]
Colligative Properties  pp ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
11.5 Boiling point Elevation & Freezing Point Depression ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Freezing point Depression ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
1 atm Vapor Pressure of solution Vapor Pressure of pure water
1 atm Freezing and boiling  points of water
1 atm Freezing and boiling  points of solution
1 atm  T f  T b
Figure 11.14 p. 536 The Development of Osmotic Pressure  pp   AP requires you to diagram the change when adding solute to a solvent   The effect of adding a solute is to extend the range of a solvent.
11.6 Osmotic Pressure ,[object Object],[object Object],[object Object],[object Object]
Figure 11.16 Osmotic Pressure. Net transfer of solvent molecules until hydrostatic pressure equalizes the solvent flow in both directions
Figure 11.18 Osmosis at Equilibrium
[object Object],[object Object]
Figure 11.17 Osmosis  When pressure exceeds this then reverse osmosis occurs.
Review Problems Bp, Fp, π ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
11.7 Colligative Properties of Electrolyte Solutions ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Colligative Properties of Electrolytes ,[object Object],[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object]

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Ch11 z5e solutions

Notas del editor

  1. Section 11.1 Solution Compositions Z5e 514
  2. Z5e 514 Section 11.1 Solution Composition
  3. Z5e 514.
  4. SE 11.1 Z5e 514 Molarity = 0.215 M Mass % = 0.990% Mole fraction = 0.00389 Molality - 0.217 m
  5. SE 11.1 Z5e 514 Molarity = 0.101 L Mass % = 0.990% Mole fraction = 0.00389 Molality - 0.217 m
  6. Section 11.2 The Energies of Solution Formation 5e 518
  7. Fig. 11.1 Z5e 519
  8. Rf. Fig. 11-2 Z5e 519
  9. Rf. Z553 #35.
  10. Rf. Z553 #35.
  11. Rf. Z553 #35.
  12. Section 11.3 Factors Affecting Solubility Z5e 522
  13. Bottom diagram shows skeletal structure of soap with nonpolar and polar ends
  14. Z5e 1133 Fig. 23.29.
  15. Z5e 523.
  16. Rf. Fig. 11.5 Z5e 523
  17. Z5e 524 SE 11.4
  18. Z5e 524 SE 11.4
  19. Z5e 524 SE 11.4
  20. Z5e 525.
  21. Rf. Fig. 11.6 Z5e 525 Note: most become more soluble with higher temperature, but note cerium sulfate
  22. Rf. Z5e 526 Warmer water on lakes blocks oxygen getting to older water below and the warmer water contains less oxygen.
  23. Fig. 11.7 Z5e 527
  24. Section 11.4 The Vapor Pressures of Solutions Z5e 538
  25. Z5e 529
  26. This is because the dissolved nonvolatile solute decreases the number of solvent molecules at the surface, and so proportionately lowers the escaping tendency of the solvent molecules. Rf. Z5e 528 and Fig. 11.9
  27. Note: all substances are molecules (so no colligative property problem) Use mole fraction        77 b. 
  28. Note: all substances are molecules (so no colligative property problem) Use mole fraction        77 b. 
  29. Note: all substances are molecules (so no colligative property problem) Use mole fraction        77 b. 
  30. Z5e 532
  31. Z5e 554 # 51. Use density to get number of moles. Then find  of liquid pentane & hexane. Then use Raoult’s law to get P in torr of both partial and total pressure. b. Since partial pressure of gas is proportional to number of moles of gas present use mol pentane in vapor/total mol vapor to get  See solutions guide p. 267
  32. Z5e 554 # 51. Use density to get number of moles. Then find  of liquid pentane & hexane. Then use Raoult’s law to get P in torr of both partial and total pressure. b. Since partial pressure of gas is proportional to number of moles of gas present use mol pentane in vapor/total mol vapor to get  See solutions guide p. 267
  33. Use density to get number of moles. Then find  of liquid pentane & hexane. Then use Raoult’s law to get P in torr of both partial and total pressure. b. Since partial pressure of gas is proportional to number of moles of gas present use mol pentane in vapor/total mol vapor to get  See solutions guide p. 267
  34. Z5e 554 # 51. Use density to get number of moles. Then find  of liquid pentane & hexane. Then use Raoult’s law to get P in torr of both partial and total pressure. b. Since partial pressure of gas is proportional to number of moles of gas present use mol pentane in vapor/total mol vapor to get  See solutions guide p. 267
  35. Use density to get number of moles. Then find  of liquid pentane & hexane. Then use Raoult’s law to get P in torr of both partial and total pressure. b. Since partial pressure of gas is proportional to number of moles of gas present use mol pentane in vapor/total mol vapor to get  See solutions guide p. 267
  36. Z5e 532
  37. Z5e 532
  38. Z5e 532 SE 11.6
  39. Z5e 532
  40. Section 11.5 Bp elevation & Fp depression Stays liquid longer because intermolecular forces between solute/solvent help hold the liquid together.
  41. Stays liquid longer (before freezing) because IMF of solute/solution prevents forming orderly crystal
  42. Fig. 11.14 Z5e 536 AP question will require you to diagram the change of addition of a solute to a solvent. The effect of adding a solute is to extend the range of a solvent.
  43. Section 11.6 Osmotic Pressure Z5e 540
  44. Z5e 540 fig. 11.16
  45. Z5e 540 Fig. 11.17
  46. Z5e 546 Section 11.7 Colligative Properties of Electrolyte Solutions