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1/11/13
CHM 101

          Chapter 1: Matter & Measurement
                      Part B
Scientific Notation

  Scientific notation is used to write very large or very small numbers.

      A number in scientific notation contains a coefficient and a power of 10.

           coefficient power of ten            coefficient   power of ten
                    1.5 x 102                7.35     x 10-4


      To write a number in scientific notation, the decimal point is moved so it will lie after
         the first digit.
      All significant figures are written.

         52 000. = 5.2000 x 10 4               0.00378 = 3.78 x 10-3
           4 spaces left                      3 spaces right (use negative exponent)
          (use positive exponent)


See Section 1.6 in your text for a detailed treatment of scientific notation (ASK FOR HELP!)
Units of Measurement

             You MUST know the prefixes below and be able to use them
                            as conversion factors.




 Used to
represent
  large
quantities


 Used to
represent
  small
quantities
Equalities
An equality states the same measurement in two different units, or in the same unit
with two different prefixes.

   1 km = 1 x 103 m           1 cm = 1 x 10-2           1 mg = 1 x 10-3 g
   1 m = 1 x 10-3 km          m
                                                        1 x 103 mg = 1 g
                              1 m = 100 cm
   1000 m = 1 km                                        1000 mg = 1 g



 Equalities are also written for relationships between units of the metric
   system, U.S. units, or between metric and U.S. units.



      1 in. = 2.54 cm                              454 g = 1 lb
Conversion Factors
A conversion factor is a fraction obtained from an equality.

         Equality: 1 in. = 2.54 cm

The conversion factor is written as a ratio with a numerator and denominator.



It can be inverted to give two conversion factors for every equality.

                              1 in.            2.54 cm
                                         or
                            2.54 cm              1 in.



         Equality: 1 m = 1 x 106 mm

                                                     6
                              1m               1 × 10 μ m
                                6        or
                          1 × 10 μ m              1m
Factor-Label Method for Conversions

How many minutes are 2.5 hours?
Given unit =     2.5 hr
Needed unit = min
Unit Plan   = hr            min




Setup problem to cancel hours (hr).
Given Conversion Needed
unit factor         unit
2.5 hr x 60 min = 150 min (2 SF)
          1 hr

      **Always write out the conversion factor with units. Cross through
       the units that cancel and make sure you end with the desired unit.
Factor-Label Method for Conversions

How many minutes are 2.5 hours?
Given unit =     2.5 hr
Needed unit = min
Unit Plan   = hr              min




Setup problem to cancel hours (hr).
Given Conversion Needed
unit factor         unit
2.5 hr x 60 min = 150 min (2 SF)
          1 hr

      **Always write out the conversion factor with units. Cross through
       the units that cancel and make sure you end with the desired unit.
Units & Conversion Factors

The diameter of an average sodium atom is 186 nm. What is the diameter in cm?
In inches?




A man weighs 83.95 kg. What is his weight in pounds?




       Do you know how to enter scientific notation on your calculator?
Density
   Density – physical property, ratio of the mass of a substance to its
   volume.
                                               mass
                                  density =
                                              volume

   Common units of density
   include g/mL, kg/L, etc.



Ice floats in water because the
density of ice is less than the
density of water.


Aluminum sinks because its
density is greater than the
density of water.
Density




        The mass and volume of a substance can be used to calculate
         density, which can then be used to identify the substance.



Answer the following questions without doing calculations:
1. Which has a larger mass: 1.0 mL gasoline or 1.0 mL water?
2. Which has a greater volume: 1 g bone or 1 g table sugar?
Density
Density can be written as an equality and used as a conversion factor.

     For a substance with a density of 3.8 g/mL, the equality is
              3.8 g = 1 mL

     From this equality, two conversion factors can be written for density.
              3.8 g     or      1 mL
              1 mL              3.8 g




*Calculate the volume of a 25.7 g sample of iron. Iron has a density of 7.86 g/mL.



*Calculate the mass 150. mL of ethanol (d = 0.789 g/mL).
Density
Specific Gravity – ratio of the density of a substance to the density of water.


                                         density   of a substance   (g/mL)
                specific   gravity   =
                                            density   of water (g/mL)


                                                             Specific gravity has no units.



*The specific gravity of a urine sample is measured to be 1.020. What volume of this
urine sample would have a mass of 35 g?
Temperature
   Temperature is a measure of how hot or cold an object is compared to
   another object. Common temperature scales include Celsius,
   Fahrenheit, and Kelvin.



  TF  9       (TC )  32
                                 
           5

  TC  5
           9
             T   F
                       32
                             
                                 

   T K  TC  273 . 15


 You MUST be able to convert
   between the 3 temperature
scales: Celsius, Fahrenheit, and
             Kelvin.
Record the temperatures on the thermometers
      below as accurately as possible.



            28°C                                     28°C


            27°C                                     27°C


            26°C                                     26°C


            25°C                                     25°C




 °C                                       °C




      Always estimate one digit beyond the last marking.
Now Let’s Practice Measuring and Converting
   Units using the Factor-Label Method

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Scientific Notation and Unit Conversions

  • 1. 1/11/13 CHM 101 Chapter 1: Matter & Measurement Part B
  • 2. Scientific Notation Scientific notation is used to write very large or very small numbers. A number in scientific notation contains a coefficient and a power of 10. coefficient power of ten coefficient power of ten 1.5 x 102 7.35 x 10-4 To write a number in scientific notation, the decimal point is moved so it will lie after the first digit. All significant figures are written. 52 000. = 5.2000 x 10 4 0.00378 = 3.78 x 10-3 4 spaces left 3 spaces right (use negative exponent) (use positive exponent) See Section 1.6 in your text for a detailed treatment of scientific notation (ASK FOR HELP!)
  • 3. Units of Measurement You MUST know the prefixes below and be able to use them as conversion factors. Used to represent large quantities Used to represent small quantities
  • 4. Equalities An equality states the same measurement in two different units, or in the same unit with two different prefixes. 1 km = 1 x 103 m 1 cm = 1 x 10-2 1 mg = 1 x 10-3 g 1 m = 1 x 10-3 km m 1 x 103 mg = 1 g 1 m = 100 cm 1000 m = 1 km 1000 mg = 1 g Equalities are also written for relationships between units of the metric system, U.S. units, or between metric and U.S. units. 1 in. = 2.54 cm 454 g = 1 lb
  • 5. Conversion Factors A conversion factor is a fraction obtained from an equality. Equality: 1 in. = 2.54 cm The conversion factor is written as a ratio with a numerator and denominator. It can be inverted to give two conversion factors for every equality. 1 in. 2.54 cm or 2.54 cm 1 in. Equality: 1 m = 1 x 106 mm 6 1m 1 × 10 μ m 6 or 1 × 10 μ m 1m
  • 6. Factor-Label Method for Conversions How many minutes are 2.5 hours? Given unit = 2.5 hr Needed unit = min Unit Plan = hr min Setup problem to cancel hours (hr). Given Conversion Needed unit factor unit 2.5 hr x 60 min = 150 min (2 SF) 1 hr **Always write out the conversion factor with units. Cross through the units that cancel and make sure you end with the desired unit.
  • 7. Factor-Label Method for Conversions How many minutes are 2.5 hours? Given unit = 2.5 hr Needed unit = min Unit Plan = hr min Setup problem to cancel hours (hr). Given Conversion Needed unit factor unit 2.5 hr x 60 min = 150 min (2 SF) 1 hr **Always write out the conversion factor with units. Cross through the units that cancel and make sure you end with the desired unit.
  • 8. Units & Conversion Factors The diameter of an average sodium atom is 186 nm. What is the diameter in cm? In inches? A man weighs 83.95 kg. What is his weight in pounds? Do you know how to enter scientific notation on your calculator?
  • 9. Density Density – physical property, ratio of the mass of a substance to its volume. mass density = volume Common units of density include g/mL, kg/L, etc. Ice floats in water because the density of ice is less than the density of water. Aluminum sinks because its density is greater than the density of water.
  • 10. Density The mass and volume of a substance can be used to calculate density, which can then be used to identify the substance. Answer the following questions without doing calculations: 1. Which has a larger mass: 1.0 mL gasoline or 1.0 mL water? 2. Which has a greater volume: 1 g bone or 1 g table sugar?
  • 11. Density Density can be written as an equality and used as a conversion factor. For a substance with a density of 3.8 g/mL, the equality is 3.8 g = 1 mL From this equality, two conversion factors can be written for density. 3.8 g or 1 mL 1 mL 3.8 g *Calculate the volume of a 25.7 g sample of iron. Iron has a density of 7.86 g/mL. *Calculate the mass 150. mL of ethanol (d = 0.789 g/mL).
  • 12. Density Specific Gravity – ratio of the density of a substance to the density of water. density of a substance (g/mL) specific gravity = density of water (g/mL) Specific gravity has no units. *The specific gravity of a urine sample is measured to be 1.020. What volume of this urine sample would have a mass of 35 g?
  • 13. Temperature Temperature is a measure of how hot or cold an object is compared to another object. Common temperature scales include Celsius, Fahrenheit, and Kelvin. TF  9 (TC )  32  5 TC  5 9 T F  32   T K  TC  273 . 15 You MUST be able to convert between the 3 temperature scales: Celsius, Fahrenheit, and Kelvin.
  • 14. Record the temperatures on the thermometers below as accurately as possible. 28°C 28°C 27°C 27°C 26°C 26°C 25°C 25°C °C °C Always estimate one digit beyond the last marking.
  • 15. Now Let’s Practice Measuring and Converting Units using the Factor-Label Method