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The chemistry of acids, bases & salts
 
What are acids??? ,[object Object],[object Object],[object Object],[object Object]
Action on litmus paper? Turn  blue  litmus to  red. Acid has a pH range which >7 Some of the weaker acids, however, for example carbonic acid, are so feebly acidic that they can only turn litmus to claret color. Acids contain combined hydrogen. When a sample of zinc, a fairly reactive metal, is dropped into a test tube containing a acid such as HCl m a reaction occurs. The bubbling in the tube indicates that a gas is released. When we test this gas by inserting a burning splint into the test tube, the gas burst into flame and produces a small popping sound. This is the characteristic test for hydrogen gas. In general, when certain acids react with metals, hydrogen gas is released. Metal + acid    metal salt + hydrogen Reaction with carbonates Form salts, water and carbon dioxide gas. Example: Na 2 CO 3  (s) + 2HCl    2NaCl (aq) + CO 2  (g) + H 2 O Properties Of Acids: Taste? Sour. This is true of the three common mineral acid, sulphuric acids, hydrochloric acids, nitric acids and others. The sour taste of many unripe fruits, lemons and sour milk is cause by the acids in them. Corrosive action Most people connect the term acid with the idea of a corrosive, “burning” liquid. Two of the commonest acids- sulphuric acid and nitric acid- are actually corrosive liquids. Acids are not, however, generally corrosive and most of them are solids. Acids release hydrogen in water solutions. When an acid dissolves in water, the acid ionizes, releasing both hydrogen ions and ions of a non-metal or non metallic polyatomic ion. Thus, when hydrochloric acid is dissolved in water, the acid ionizes, forming hydrogen ions and chloride ions, as shown in the following equation: HCl (aq)    H + (aq) + Cl 1-  (aq) other examples: H z SO 4  (aq)    2H + (aq) + SO 4 2-  (aq) H 3 PO 4  (aq)   3H +  (aq) + PO 4 3- (aq) * Thus acids are defined as substances that release hydrogen ions in solution. It is these H  +  (aq)  are responsible for the properties of acids. Reaction with bases: Form salts and water.  Another word: neutralization. Ionic equation: H  +  + OH  -    H 2 O Example: HCl (aq) + NaOH (aq)    NaCl (aq) + H 2  O (l)
The reactions of the three common inorganic acids with various metals.
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Common organic acids: Organic acids????
Inorganic acids???? ,[object Object],[object Object],[object Object],[object Object],Common inorganic acids:
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What is base? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Bases that are soluble usually contain metallic cations from group 1 and group II metals.  Oxides containing transition metals or group III metals are usually insoluble or partially soluble.
Properties of base: Feel slippery/soapy. If you rub a drop or two of household ammonia between your fingers, you may experience the slippery feeling of a base. Wet soap is also slippery because of the presence of a base. Turn red litmus to blue. A common indicator, used to detect the presence of a base, is phenolphthalein which, when mixed with a base, turn pink.  Reaction with ammonium salts: When a mixture of an ammonium salt and an alkali is heated, ammonia gas is given off. The reaction may be briefly summarized as : OH -  + NH 4 +     NH 3  + H 2 O Example: NH 4 Cl (s) + NaOH (aq)    NaCl (aq) + NH 3 (g) + H 2 O(l) Precipitation of metal hydroxides: Solutions of metal hydroxides are used to precipitate insoluble metal hydroxides from solutions of their salts. Example:   2NaOH(aq) +CuSO 4 (aq)   Cu(OH) 2  (S) + Na 4 SO 4 (aq) ,[object Object],[object Object]
Classification of oxides: ,[object Object],[object Object],[object Object],[object Object],[object Object],Metal oxides are basic (e.g. copper (II) Oxide, iron (II) oxide). These oxides have the properties to that of an acid when they dissolve in water. Oxides are formed when metallic and non-metallic elements burn in oxygen. There are some neutral oxides as well.  They are the non-metallic oxides, (e.g. carbon monoxide, water, Nitrogen oxide .) Some oxides are atmospheric in nature (e.g. aluminum oxide, zinc oxide). These oxides show both acidic and basic properties.
[object Object],[object Object],[object Object],[object Object],[object Object]
 
What is salt? Many chemical compounds may classified as salt. The most familiar to all of us is the table salt. In general, salts are ionic compounds that are composed of metallic ions and non-metallic ions. For example, sodium chloride is composed of metallic sodium ions and non metallic chloride ions.  Salts can be considered to be formed by the reaction of an acid with a base. Salts are classified into neutral, basic or acidic according to the effect they have on pH when dissolved in water. Strong acid + strong base    neutral solution Weak acid+ strong base    base solution Strong acid +weak base   acidic solution
[object Object],[object Object],[object Object],[object Object],Color? Exist in all different colors. For examples: sodium chloride =transparent Nickel oxide=green Potassium dichromate=orange  Taste? Different salts can elicit all the five basic tastes. Odor? Depend on the acid and base which make up the salt.
Methods of preparing salts: ,[object Object],[object Object],[object Object]
Examples and uses of salts: ,[object Object],[object Object],Sodium bicarbonate: Used in baking powder, in manufacture of glass. Sodium chloride: Used for seasoning and preserving food, essential in life processes Calcium chloride: Used as a drying agent to absorb moisture, in freezing mixtures. Silver bromide: Used in making photographic film. Potassium nitrate: Used in manufacture of explosives, fertilizers Sodium nitrate: Used in fertilizers ; source of nitric acid
 
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Chemistry’S Project1

  • 1. The chemistry of acids, bases & salts
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  • 4. Action on litmus paper? Turn blue litmus to red. Acid has a pH range which >7 Some of the weaker acids, however, for example carbonic acid, are so feebly acidic that they can only turn litmus to claret color. Acids contain combined hydrogen. When a sample of zinc, a fairly reactive metal, is dropped into a test tube containing a acid such as HCl m a reaction occurs. The bubbling in the tube indicates that a gas is released. When we test this gas by inserting a burning splint into the test tube, the gas burst into flame and produces a small popping sound. This is the characteristic test for hydrogen gas. In general, when certain acids react with metals, hydrogen gas is released. Metal + acid  metal salt + hydrogen Reaction with carbonates Form salts, water and carbon dioxide gas. Example: Na 2 CO 3 (s) + 2HCl  2NaCl (aq) + CO 2 (g) + H 2 O Properties Of Acids: Taste? Sour. This is true of the three common mineral acid, sulphuric acids, hydrochloric acids, nitric acids and others. The sour taste of many unripe fruits, lemons and sour milk is cause by the acids in them. Corrosive action Most people connect the term acid with the idea of a corrosive, “burning” liquid. Two of the commonest acids- sulphuric acid and nitric acid- are actually corrosive liquids. Acids are not, however, generally corrosive and most of them are solids. Acids release hydrogen in water solutions. When an acid dissolves in water, the acid ionizes, releasing both hydrogen ions and ions of a non-metal or non metallic polyatomic ion. Thus, when hydrochloric acid is dissolved in water, the acid ionizes, forming hydrogen ions and chloride ions, as shown in the following equation: HCl (aq)  H + (aq) + Cl 1- (aq) other examples: H z SO 4 (aq)  2H + (aq) + SO 4 2- (aq) H 3 PO 4 (aq)  3H + (aq) + PO 4 3- (aq) * Thus acids are defined as substances that release hydrogen ions in solution. It is these H + (aq) are responsible for the properties of acids. Reaction with bases: Form salts and water. Another word: neutralization. Ionic equation: H + + OH -  H 2 O Example: HCl (aq) + NaOH (aq)  NaCl (aq) + H 2 O (l)
  • 5. The reactions of the three common inorganic acids with various metals.
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  • 7. Common organic acids: Organic acids????
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  • 16. What is salt? Many chemical compounds may classified as salt. The most familiar to all of us is the table salt. In general, salts are ionic compounds that are composed of metallic ions and non-metallic ions. For example, sodium chloride is composed of metallic sodium ions and non metallic chloride ions. Salts can be considered to be formed by the reaction of an acid with a base. Salts are classified into neutral, basic or acidic according to the effect they have on pH when dissolved in water. Strong acid + strong base  neutral solution Weak acid+ strong base  base solution Strong acid +weak base  acidic solution
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