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Molybdenum-on-Chromium Dual Coating on Steel www.utsi.edu   Center for Laser Applications University of Tennessee  Space Institute 411 B. H. Goethert Parkway  Tullahoma, TN 37388  Surface & Coatings Technology (2009), 203 (9), pp 1281-1287 Implementation of fast scanning diode pumped fiber laser to surface modification Deepak Rajput  [email_address]   /  http://drajput.com
Molybdenum coating on steel ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Molybdenum coating on steel ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Direct alloying of Mo on Steel: Problems ,[object Object],[object Object]
Dilution Precursor mixture Substrate  Laser beam Pores  Capillary action fills up the pores with the molten metal from the substrate
Dilution Substrate Substrate 1) Composite coating: unmelted precursor particles embedded in the substrate 1 2 T p  >> T s T p  > T s  or not enough Laser power 2) Partial melting of the precursor: coating contains alloy and unmelted particles
Fe-Mo phase diagram
Problems & Solution ,[object Object],Mo Fe Mo Fe IML intermetallics No intermetallics No intermetallics Phase diagrams show that  Cr , V and Nb are the best intermediate layers (IML)
Fe-Cr phase diagram
Cr-Mo phase diagram
Cr-B phase diagram 1630 o C
Mo-B phase diagram 2180 o C
Chemistry & Stoichiometry ,[object Object],[object Object],[object Object],temperature Cr CrB 2 CrB 2 Cr % CrB 2 Cr + 10.5% CrB 2
Process: LISI TM ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Precursor Deposition Precursor mixture = Metal Powders + Binder Precursor mixture steel air Spray gun
Laser Deposition Cr* = 165W, 25mm/s, Hatch 0.1mm @ 355mm Mo* = 180W, 25mm/s, Hatch 0.1mm @355mm Steel Cr IML Mo Layer
Fiber laser processing Scan head Fiber Water-cooled chamber View port Hopper
Fiber laser results Substrate: AISI 4130 steel
Fiber laser results Cr* layer at high magnification
Fiber laser – two coatings
Fiber laser – two coatings Mo* layer at high magnification
Cr* coating Microhardness test of chromium layer
X-ray Cr* layer X-ray diffractogram of chromium layer
Mo* on Cr* coating Microhardness test of molybdenum coating
Mo* on Cr* x-rays X-ray diffractogram of molybdenum coating
Block-on-ring wear tester ASTM G77  (4 lb load)
Block-on-ring sliding wear Sliding wear performance
PLINT TE68 Gas Jet Erosion Rig ASTM G76  (silica 2 gm/min at 52 m/s)
ASTM G76 dry sand erosion wear Solid particle erosion performance
Summary ,[object Object],[object Object],[object Object],[object Object]
[object Object]

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Molybdenum-on-Chromium Dual Coating on Steel