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Chapter 9
Acids and Bases

Acids and Bases




   LecturePLUS Timberlake   1
Arrhenius Acids and Bases
Acids produce H+ in aqueous solutions
            water
    HCl                H+(aq) + Cl- (aq)

Bases produce OH- in aqueous solutions

            water
    NaOH               Na+(aq) + OH- (aq)
               LecturePLUS Timberlake       2
Acids

 Produce H+ (as H3O+) ions in water
 Produce a negative ion (-) too
 Taste sour
 Corrode metals
 React with bases to form salts and water

                 LecturePLUS Timberlake      3
Bases

Produce OH- ions in water
Taste bitter, chalky
Are electrolytes
Feel soapy, slippery
React with acids to form salts and water
                LecturePLUS Timberlake      4
Learning Check AB1
Describe the solution in each of the
following as: 1) acid 2) base or 3)neutral.
A. ___soda
B. ___soap
C. ___coffee
D. ___ wine
E. ___ water
F. ___ grapefruit
               LecturePLUS Timberlake    5
Solution AB1
Describe each solution as:
1) acid 2) base or 3) neutral.
A. _1_ soda
B. _2_ soap
C. _1_ coffee
D. _1_ wine
E. _3_ water
F. _1_ grapefruit
               LecturePLUS Timberlake   6
Learning Check AB2
Identify each as characteristic of an A) acid
or B) base
____ 1. Sour taste
____ 2.   Produces OH- in aqueous solutions
____ 3.   Chalky taste
____ 4.   Is an electrolyte
____ 5.   Produces H+ in aqueous solutions

                 LecturePLUS Timberlake    7
Solution AB2
Identify each as a characteristic of an A) acid
or B) base
_A_ 1. Sour taste
_B_ 2. Produces OH- in aqueous solutions
_B_ 3. Chalky taste
A, B 4. Is an electrolyte
_A_ 5. Produces H+ in aqueous solutions
                 LecturePLUS Timberlake       8
Some Common Acids

HCl            hydrochloric acid
HNO3           nitric acid

H3PO4          phosphoric acid

H2SO4          sulfuric acid

CH3COOH        acetic acid
          LecturePLUS Timberlake   9
Learning Check AB3

Give the names of the following
A. HBr (aq)      1. bromic acid
                   2. bromous acid
                   3. hydrobromic acid
B. H2CO3           1. carbonic acid
                   2. hydrocarbonic acid
                   3. carbonous acid
               LecturePLUS Timberlake      10
Solution AB3
A. HBr        3. hydrobromic acid
The name of a nonoxy acid begins with the
prefix hydro- and ends with -ic acid. In a
nonoxy acid, the negative anion end in -ide.

B. H2CO31. carbonic acid
The name of an oxyacid is named with the
stem of the anion (carbonate) changed to
-ic acid
                LecturePLUS Timberlake   11
Some Common Bases

NaOH       sodium hydroxide

KOH        potassium hydroxide

Ba(OH)2    ________________________

Mg(OH)2 ________________________

Al(OH)3    aluminum hydroxide
           LecturePLUS Timberlake   12
Learning Check AB4
Match the formulas with the names:

A. ___ HNO2                    1) hydrochloric acid

B. ___ Ca(OH)2                 2) sulfuric acid

C. ___ H2SO4                   3) sodium hydroxide

D. ___ HCl                     4) nitrous acid

E. ___   NaOH                  5) calcium hydroxide
                LecturePLUS Timberlake          13
Solution AB4

Match the formulas with the names:

A. _4__ HNO2         1) hydrochloric acid

B. _5__ Ca(OH)2      2) sulfuric acid

C. _2__ H2SO4        3) sodium hydroxide

D. _1__ HCl          4) nitrous acid
E. _3__ NaOH         5) calcium hydroxide
                LecturePLUS Timberlake      14
Learning Check AB5

          Acid, Base              Name
          or Salt
CaCl2     ______                  _________________
KOH       ______                  _________________
Ba(OH)2   ______                  _________________
HBr       ______                  _________________
H2SO4     ______                  __________________
                   LecturePLUS Timberlake         15
Solution AB5
          Acid, Base              Name
          or Salt
CaCl2     salt          calcium chloride
KOH       base          potassiuim hydroxide
Ba(OH)2   base          barium hydroxide
HBr       acid          hydrobromic acid
H2SO4     acid          sulfuric acid
                  LecturePLUS Timberlake       16
Bronsted-Lowry Acids

Acids are hydrogen ion (H+) donors
Bases are hydrogen ion (H+) acceptors

HCl      +    H2O                 H3O+       +   Cl-
donor         acceptor                   +             -
         +                                   +



                LecturePLUS Timberlake            17

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Acids and bases

  • 1. Chapter 9 Acids and Bases Acids and Bases LecturePLUS Timberlake 1
  • 2. Arrhenius Acids and Bases Acids produce H+ in aqueous solutions water HCl H+(aq) + Cl- (aq) Bases produce OH- in aqueous solutions water NaOH Na+(aq) + OH- (aq) LecturePLUS Timberlake 2
  • 3. Acids  Produce H+ (as H3O+) ions in water  Produce a negative ion (-) too  Taste sour  Corrode metals  React with bases to form salts and water LecturePLUS Timberlake 3
  • 4. Bases Produce OH- ions in water Taste bitter, chalky Are electrolytes Feel soapy, slippery React with acids to form salts and water LecturePLUS Timberlake 4
  • 5. Learning Check AB1 Describe the solution in each of the following as: 1) acid 2) base or 3)neutral. A. ___soda B. ___soap C. ___coffee D. ___ wine E. ___ water F. ___ grapefruit LecturePLUS Timberlake 5
  • 6. Solution AB1 Describe each solution as: 1) acid 2) base or 3) neutral. A. _1_ soda B. _2_ soap C. _1_ coffee D. _1_ wine E. _3_ water F. _1_ grapefruit LecturePLUS Timberlake 6
  • 7. Learning Check AB2 Identify each as characteristic of an A) acid or B) base ____ 1. Sour taste ____ 2. Produces OH- in aqueous solutions ____ 3. Chalky taste ____ 4. Is an electrolyte ____ 5. Produces H+ in aqueous solutions LecturePLUS Timberlake 7
  • 8. Solution AB2 Identify each as a characteristic of an A) acid or B) base _A_ 1. Sour taste _B_ 2. Produces OH- in aqueous solutions _B_ 3. Chalky taste A, B 4. Is an electrolyte _A_ 5. Produces H+ in aqueous solutions LecturePLUS Timberlake 8
  • 9. Some Common Acids HCl hydrochloric acid HNO3 nitric acid H3PO4 phosphoric acid H2SO4 sulfuric acid CH3COOH acetic acid LecturePLUS Timberlake 9
  • 10. Learning Check AB3 Give the names of the following A. HBr (aq) 1. bromic acid 2. bromous acid 3. hydrobromic acid B. H2CO3 1. carbonic acid 2. hydrocarbonic acid 3. carbonous acid LecturePLUS Timberlake 10
  • 11. Solution AB3 A. HBr 3. hydrobromic acid The name of a nonoxy acid begins with the prefix hydro- and ends with -ic acid. In a nonoxy acid, the negative anion end in -ide. B. H2CO31. carbonic acid The name of an oxyacid is named with the stem of the anion (carbonate) changed to -ic acid LecturePLUS Timberlake 11
  • 12. Some Common Bases NaOH sodium hydroxide KOH potassium hydroxide Ba(OH)2 ________________________ Mg(OH)2 ________________________ Al(OH)3 aluminum hydroxide LecturePLUS Timberlake 12
  • 13. Learning Check AB4 Match the formulas with the names: A. ___ HNO2 1) hydrochloric acid B. ___ Ca(OH)2 2) sulfuric acid C. ___ H2SO4 3) sodium hydroxide D. ___ HCl 4) nitrous acid E. ___ NaOH 5) calcium hydroxide LecturePLUS Timberlake 13
  • 14. Solution AB4 Match the formulas with the names: A. _4__ HNO2 1) hydrochloric acid B. _5__ Ca(OH)2 2) sulfuric acid C. _2__ H2SO4 3) sodium hydroxide D. _1__ HCl 4) nitrous acid E. _3__ NaOH 5) calcium hydroxide LecturePLUS Timberlake 14
  • 15. Learning Check AB5 Acid, Base Name or Salt CaCl2 ______ _________________ KOH ______ _________________ Ba(OH)2 ______ _________________ HBr ______ _________________ H2SO4 ______ __________________ LecturePLUS Timberlake 15
  • 16. Solution AB5 Acid, Base Name or Salt CaCl2 salt calcium chloride KOH base potassiuim hydroxide Ba(OH)2 base barium hydroxide HBr acid hydrobromic acid H2SO4 acid sulfuric acid LecturePLUS Timberlake 16
  • 17. Bronsted-Lowry Acids Acids are hydrogen ion (H+) donors Bases are hydrogen ion (H+) acceptors HCl + H2O H3O+ + Cl- donor acceptor + - + + LecturePLUS Timberlake 17