This is from awhile back and has limited value out side of a simple inventory without demos. However, I still see many developers who don't take advantage of these features that have been with us since VS 2010 was released. I hope this helps with some awareness.

1. What’s New in VS 2010
Debugging
Presented by
Gregory M. Sohl

2. VS 2010 Debugging Enhancements
Breakpoints
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Searching
Labeling
Import / Export
Data Tips / Pinning
Thread Window
Redesign
Loading of Dump
Files
IntelliTrace
Symbol Loading
Enhancements
Parallel Stacks
Parallel Tasks
64 bit debugging
WPF Tree Visualizer

3. Breakpoints
Labels
Searching
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Toolbar buttons affect displayed breakpoints
Import / Export

4. Data Tips
Pinning
Add additional values
Comments
Pin to source
Remember last value
Import / Export

5. Thread Window
Search
Grouping
Filter
Call Stack Expansion / Search
Breakpoint Memory

6. Dump File Loading
File Association
Dump Summary
Action Links
Debug with mixed (CLR 4 only)

7. IntelliTrace
Black Box Recorder
On by default!
IntelliTrace Windows
Options
Call information option
Works with .NET 3.5 Code too

8. Symbol Loading
MS Symbol Server provided
Auto Loading Exceptions
Only load specified
Paste functionality (not obvious)

9. Resources
Scott Gu Blog Post: http://bit.ly/9a9kHt
Online Doc: http://bit.ly/cuEiPp
Debugger Enhancements
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Channel9 Video: http://bit.ly/9ee4bW
Debugging Crash Dumps with VS 2010
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Channel9 Video with Tess: http://bit.ly/ct5Dw5
Debugger Team Blog: http://bit.ly/blUSyW