This is short presentation on Energy Harvesting Materials that was held in July 2009 at Frost & Sullivan Analyst Briefing event

1. Thermal and Mechanical Energy Harvesting Materials Krzysztof Grzybowski

2. Smart Energy Management–Global Level of energy utilization was increasing in European countries during the last few years. New and efficient technologies allowed for significant reduction of our dependence on energy. Development of new energy harvesting technology is a key solution in this regard.

3. are the potential energy sources ? to harvest wasted energy ? is necessary for energy harvester design? materials should be used for energy harvesting? How Where What Which

4. are potential energy sources ? Where

5. Piezoelectric E nergy H arvesting Mechanical stress Vibrations

6. Thermoelectric E nergy H arvesting dT>0 q>0

8. to harvest wasted energy ? How

9. Piezoelectric S olutions Frequent vibrations are capable of power ing any kind of energy - dependent wireless sensors . (Microstrain, Cedrat)

10. Thermoelectric M iniaturized H arvester Nextreme Thermal Solutions, Micropelt

11. Energy S treams in a C ar BSST with BMW, Visteon, Marlow, Virginia Tech, Purdue, UC-Santa Cruz · GM with GE, U of Michigan, U of South Florida, ORNL, RTI · Michigan State with Cummins, Tellurex, NASA-JPL, Iowa State · United Technologies with Pratt & Whitney, Hi-Z, Pacific Northwest National Lab., and Caterpillar Research groups

12. Waste H eat R ecovery S ystems BMW Series 5 , Model Year 2010, 3.0 Liter Gasoline Engine with Thermoelectric Generator US D O E planned decrease of fuel consumption by 10 %

13. Unused I ndustrial H eat S ources Many heat energy sources are currenlty well re - used via traditional heat exchangers and accumulators. This is one of the main quidelines of process engineering. However, some of the heat sources could be utilized even more deeper. Industrial P rocessing H eat Unused and E mitted H eat S treams

14. Self powered sensors/actuators The application of self- powering wireless network systems takes place in various scales. Due to their elastic architecture, they can easily incorporate various energy harvesters. IMEC Morgan ElectroCeramics Ferrotec, EnOcean Human Machine Complex systems

15. Self powered systems. Comparison of battery and piezoelectric energy harvester Energy harvesters provide various useful features that make them more attractive than batteries for self-powered solutions. Battery replacement: Advanced Cerametrics, Advanced Linear Devices

16. is necessary for the energy harvester design? What

19. materials should be used for energy harvesting? Which

20. Applicability in harsh environments Energy harvesting materials – Drivers Small size Note: Size of the ball indicates importance or weight of the factor Small dimensions of most of the energy harvesters allow for their easy and noninvasive application in varioussolutions. Popular batteries cannot operate at high temperatures. Thus energy harvesters are good candidate to be used instead of them. Applied energy harvesters providing easy to use and maintain solutions. Energy harvesters can operate for long times. Despite of their high inital costs they exclude the need of frequent system maintanace or replacement. Demand for reliable powering devices with long lifetimes Market need for quiet solutions with no moving parts.

21. Energy Harvesting T hermoelectric S ystems Key Challenges TE systems Low conversion efficiency Necessity of accurate module design Need of power management systems Relatively high price Parasitic thermal conduction Size of the bubble describes the strength of the factor

22. Energy Harvesting Piezoelectric S ystems Key Challenges Piezoelectric systems Brittleness Relatively High Cost Unidirectional operation Difficult deposition Low energy transfer Size of the bubble describes the strength of the factor

23. Influence of the BixSb2–xTe3 constituent elements on total alloy price(*) Absolute Numbers Percentage Share Trend 100% 100% (*) note that the price of the whole alloy is not directly the sum of constituent elements Bismuth Antimony Tellurium The price of the tellurium is mostly impacting bismuth telluride alloys’ price. The influence of antimony is neglectable.

24. Energy H arvesting S ystems Piezoelectrics Human source Piezoelectrics Environment Photovoltaic Outdoor RF - GSM 1E-3 microWatts/cm 2 1E4 1 Photovoltaic Indoor RF - WiFi Thermoelectric Environment Thermoelectric Human Energy Harvested Development stage Early Advanced

25. Top Market Impact of Top 10 Developed Piezoelectrics Projected Impact on the Industry High Impact Low Impact Certainty Low High Bi4Ti3O12 KxNa1-xNbO3 modified KNN PbTiO3 PZT BaTiO3 Quartz High Growth Impact Low Growth Impact Medium Growth Impact Source Frost & Sullivan. KNN stands forKxNa1-xNbO3

26. Thank you