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Introduction to Sedimentary Ore Deposits
Hassan Z. Harraz
hharraz2006@yahoo.com
2012- 2013
22 November 2015 1
Prof. Dr. H.Z. Harraz Presentation
Sed. Ore Deposit Env.
Acknowledgments:
I acknowledge gratefully the extent to which I have leant on the work contained in several good text
books:
Evans, A. M., 1997. An introduction to Economic Geology and its environmental impact. Blackwell
Scientific publications, 376pp.
Pohl, W. L., 2011. Economic Geology: Principles and Practice. Wiley-Blackwell, 680 pp.
Beydoun, Z. R., 1991. Arabian Plate Hydrocarbon Geology and Potential. AAPG, 77 pp.
Guilbert, J. M. and Park, C. F., 1986. The Geology of Ore Deposits. W. H. Freeman & Co, 984 pp.
Boggs, Jr., Sam, 2012, Principles of Sedimentology and Stratigraphy, 5th edition, Prentice Hall, Upper
Saddle River, NJ, 600 pp. ISBN-10: 0321643186
Hussein, A. A. A. 1990. Mineral deposits, In: Said, R. (ed.), The geology of Egypt. A. A.
Balkema/Rotterdam/Brookfield, pp 511-566.
El Gaby, S.; List, F. K., Tehrani, R., 1988. Geology, evolution and metallogenesis of the Pan-African Belt
in Egypt, In: El Gaby, S., Greiling, R. O. (Eds.), The Pan-African Belt of northeast Africa and
adjacent areas. Friedr. Vieweg & Sohn, Braunschweig/Wiesbaden, pp.17-68.
Hunt, J. M., 1996. Petroleum Geochemistry and Geology. W. H. Freeman & Co, 743 pp.
Levorsen, A.I., 1967. Geology of Petroleum. W. H. Freeman & Co. 724 pp.
Selley, Richard C., 1998. Elements of Petroleum Geology. Academic Press. 470 pp.
22 November 2015 2
Prof. Dr. H.Z. Harraz Presentation
Sed. Ore Deposit Env.
Topic 1: Sedimentary Ore Deposit Environments
Topic 2: Calcium Carbonate and Chert Deposits
Topic 3: Manganese and Iron Ore Deposits
Topic 4: Sulfur and Uranium Mineral Deposits
Topic 5: Phosphate Ore Deposits
Topic 6: Evaporate Salt Deposits
Topic 7: Placer Mineral deposits
Topic 8: Residual (eluvial or laterite) Mineral Deposits
Topic 9: Supergene Enrichment
22 November 2015 3
Prof. Dr. H.Z. Harraz Presentation
Sed. Ore Deposit Env.
Outline of lectures:
 An Introduction to Sedimentary Ore Deposits is to geologists.
 This course provides a non-technical introduction to the basic
concepts of:
Introduction
 Surficial Earth processes
 Sedimentary Ore Deposit Environments
 Sedimentary Mineral Deposits
1) Deposits formed by sedimentation
 Ironstone, Calcium carbonate, Chert, Sulfur, Uranium, Copper & Manganese deposits
 Phosphate deposits
 Evaporite deposits
2) Deposits formed by Weathering
 Placer Mineral Deposits
 Residual Mineral Deposits (Laterites and Supergene
 With numerous examples, figures and images of sedimentary ore deposits.
 Also included are some key aspects of the mineral resources from the sedimentary
environments and some ideas about the future of sedimentary mineral resources.
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Prof. Dr. H.Z. Harraz Presentation
Sed. Ore Deposit Env.
Topic 1: Sedimentary Ore Deposit Environments
Hassan Z. Harraz
hharraz2006@yahoo.com
2012- 2013
22 November 2015
Prof. Dr. H.Z. Harraz Presentation
Sed. Ore Deposit Env.
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Outline of Topic 1:
We will explore all of the above in Topic 1
 Mineral Deposits
 Ore Deposit Environments
 Formation of Mineral Deposits
 Introduction
 The Hydrologic Cycle
 The Rock Cycle
 Types of Sedimentary Rocks
 Sediments
 Source of Materials
 Sedimentary Processes
 Hjulstrom’s Diagram
 Weathering & Erosion
 Mechanical Weathering
 Chemical Weathering
 Solution and Transportation
 Deposition
 Depositional Environments
 Sedimentary Ore Deposits
 Exogenous (Surficial) processes
1) Deposits formed by Weathering
2) Deposits formed by sedimentation
 Resources from the Sedimentary Environments
Mineral Deposits
 A mineral deposit is a volume of rock enriched in one or more minerals.
In this sense a mineral refers to a useful material, a definition that is
different from the way we defined a mineral earlier in this unit.
 Mineral deposits can be classified on the basis of the mechanism
responsible for concentrating the valuable substance. Examples
Include:
1) Magmatic Mineral Deposits
2) Hydrothermal Mineral Deposits
3) Metamorphic Mineral Deposits
4) Sedimentary Mineral Deposits
5) Placer Mineral Deposits
6) Residual Mineral Deposits
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Ore Deposit Environments
 Magmatic
 Cumulate deposits – fractional crystallization processes can concentrate metals (Cr, Fe, Pt)
 Pegmatites – late staged crystallization forms pegmatites and many residual elements are
concentrated (Li, Ce, Be, Sn, and U)
 Hydrothermal
 Magmatic fluid - directly associated with magma
 Porphyries - Hot water heated by pluton
 Exhalatives – hot water flowing to surface
 Epigenetic – hot water not directly associated with pluton
 Metamorphic
 Skarn – hot water associated with contact metamorphisms
 Sedimentary
 Sedimentary Mineral Deposits
 Ironstone, Calcium carbonate, Chert, Sulfur, Uranium, Copper & manganese deposits
 Phosphate deposits
 Evaporite deposits – minerals like gypsum, halite deposited this way
 Placer Mineral Deposits :
 Placer – weathering of primary minerals and transport by streams (Gold, diamonds, other)
 Residual Mineral Deposits
 Laterites – leaching of rock leaves residual materials behind (Al, Ni, Fe)
 Supergene – reworking of primary ore deposits remobilizes metals (often over short distances)
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Prof. Dr. H.Z. Harraz
Presentation
Sed. Ore Deposit
Env.
Metallic Mineral Deposits and Geologic Processes
Mineral deposits may be found in a variety of plate tectonic settings.
Mineral resources include reserves = identified deposits from which minerals can
be extracted profitably now or in the future with technological advances.
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“Ore genesis processes”
I) Endogenous (Internal) processes:
1) Magmatic processes
2) Hydrothermal processes
3) Metamorphic/Metasomatism processes
II) Exogenous (Surficial) processes:
1) Weathering
2) Supergene enrichment
3) Mechanical concentration
4) Chemical deposition (Sedimentation)
5) Evaporation
Formation of Mineral Deposits
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Introduction
The process of sedimentation as distinct from evaporation has resulted not only in the
formation of common sedimentary rocks but also in valuable mineral deposits of iron,
manganese, copper, phosphate, coal, oil shale, carbonates, cement rocks, clay,
diatomaceous earth, bentonite, fuller's earth, magnesite, sulphur, and; less directly,
uranium-vanadium deposits.
Their mode of formation is that of sedimentation with special variations to account for
the special materials. They are composed of inorganic and organic materials; their
source, like that of any sedimentary rock, is from other rocks that have undergone
disintegration, the ultimate source, of course, being the igneous rocks. Some of the
materials, such as oxygen and carbon dioxide, have been obtained from the
atmosphere, and a few have been derived from former deposits.
The formation of sedimentary deposits involves:
1) an adequate source of materials;
2) the gathering of this materials by solution or processes;
3) the transportation of the materials to the site of accumulation if that is
necessary; and
4) the deposition of the materials in the sedimentary basin.
Subsequent compaction, chemical alteration, or other changes may take place.
Water cycle
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The Hydrologic Cycle
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The Rock Cycle
Volcanic Rocks
Soils
Sediments
Sedimentary
Rocks
Weathering
Atmosphere
Biosphere
Hydrosphere
Solar Energy
Metamorphic Rocks
Magma
Melting 1
Melting 2Crust
Mantle
Internal Energy
Subduction
Compaction &
CementationErosion,
Transportation &
Deposition
Tectonic Uplift
Heat &
Pressure
Intrusive Rocks
Cooling &
Crystallization
Sea level
Earth Surface
Endogenous (Internal)
processes
Exogenous (Surficial)
processes
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Sediments and Sedimentary Rocks
make up:
 8% of the Earth’s crust
 75% of the Earth’s surface (principally in the marine environment)
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composed of fragments of pre-existing
rock that have been weathered, eroded
and transported by wind, water, ice, or
mass movement to a site of deposition.
• Sandstones
• Conglomerates
• Breccia
• Shale/mudstones
Types of Sedimentary Rocks
Clastic rocks Chemical rocks
Evaporitic rocks
These rocks are formed
due to evaporation of saline
water (sea water)
e.g. Gypsum, Halit
(rock salt)
Inorganic rocks
Form basically from
CaCO3 – both by
chemical leaching and
by organic source
(biochemical) e.g.
Limestone; dolomite
Organic rocks
Form due to
decomposition of
organic remains
under temperature
and pressure e.g.
phosphate,
Coal/Lignite etc.
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SEDIMENTARY ROCK - Compacted and cemented accumulations of sediment, which
can be of two general types - clastic and chemical.
composed of minerals precipitated from water (usually
ocean water) due to evaporation or to the metabolic
action of organisms (biogenic)
Sediments
Defined:
• unconsolidated organic and
inorganic particles that
accumulate on the ocean floor
• originate from numerous sources:
 weathering and erosion of the
continents (many sizes and types).
 volcanic eruptions
 biological activity
 chemical processes within the
oceanic crust and seawater
 impacts of extra-terrestrial objects
 Space
• classified by size according to the
Wentworth scale
Source of Materials
The materials that enter into sedimentary mineral deposits have been derived
chiefly from the weathering of rocks.
Occasionally, materials have come from the weathering and oxidation of former
mineral deposits such as iron, manganese, and copper. Others have passed through
an intermediate organic stage.
The rocks, however, constitute an adequate source for most of the sedimentary
iron, manganese, and copper.
The iron comes from the weathering of iron-bearing minerals of igneous rocks such
as hornblende, pyroxene, or mica, from the iron-bearing minerals of' sedimentary
and metamorphic rocks, and from the red colouring matter of sedimentary rocks.
Similarly, the manganese of sedimentary deposits has been derived chiefly from the
weathering of manganese-bearing minerals in the rocks and, to a minor extent, from
former sedimentary concentrations and epigenetic lode deposits.
The source of sedimentary phosphate is phosphorus-bearing rock minerals, among
which apatite is the most common. Some is also derived from the weathering of
collophanite and dahllite in sedimentary rocks.
The constituents of sedimentary carbonate deposits such as the industrial
limestones, dolomite, and magnesite are derived from the see or saline waters to
which they are largely supplied by rock weathering; also, the constituents of the
numerous types of industrial clayey deposits such as cl clays, bentonite, and fuller's
earth originate in rock weathering.
Sedimentary Processes
Transportation: Rounding - increases with length of
transportation history.
Sorting: increases with length of transportation
history (weaker minerals broken down).
Deposition: any process that lays down material.
Environment of Deposition: location in which
deposition occurs. Use the Principle of
Uniformitarianism to study ancient environments.
Preservation: deposition and burial in a basin.
Reworking degrades preservation.
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• Average grain size
reflects the energy of
the depositional
environment.
• The smaller the particle is,
the more easily it can be
transported by streams,
waves and currents.
Clays
• can remain suspended
for very long periods
• can be transported very
far by ocean currents
4-1
http://uregina.ca/~sauchyn/geog323/hjulstrom.gif
Hjulstrom’s Diagram graphs the relationship between particle size
and energy for erosion, transportation and deposition
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WEATHERING: Process that transforms high temperature
minerals to low-temperature ones stable at the Earth’s surface.
Dissolves ALL minerals to some extent.
Weathering and erosion as a mechanism of separating
and concentrating chemical constituents:
1) remove specific elements, compounds or
minerals from ordinary rock. Rounding - increases
with length of transportation history.
2) transport these elements, compounds, or
minerals.
3) Sorting: increases with length of transportation history
(weaker minerals broken down).
4) concentrate the elements, compounds, or
minerals preferentially at one spot or zone
where the transport stops.
concentrate
removal
 the primary mechanisms for
concentrating minerals into ores
involves either:
a) sorting by density, or
b) sorting by solubility.
 Weathering and erosion as a
mechanism of separating and
concentrating chemical constituents.
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Fig. 06.01
Transportation: Rounding -
increases with length
of transportation
history.
Boulders have
been abraided
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 grain size indicates condition under which sediment is deposited
 high energy environments characteristically yield sediments larger in
size
 small particles (silts, clays) indicate low energy environments
 Sorting: increases with length of transportation history (weaker minerals
broken down).
 considered well-sorted if most particles appear in the same size
classification
 poorly sorted sediments comprised of multiple sizes
 sediment maturity is indicated by several factors
 decreased silt and clay content
 increased sorting
 increased rounding of grains, as a result of weathering and abrasion
 particle transport is controlled by grain size and velocity of transporting
medium
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time
energy
energy
time
Sediment can contain particles of the same size or of different sizes
Sorting is a function of the energy of the environment
wide
narrow
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Erosion
 EROSION: Transport away from weathering site. This process exposes intrusive igneous rocks to weathering
& the process continues. Transport by Wind, Ice, Gravity, Water (solution/ suspension).
 Erosion is the breakdown of materials forming the earth’s crust, otherwise known as weathering.
 The two principle types of weathering include chemical and mechanical weathering.
Chemical weathering:
 involves decomposition of rocks and
their constituent minerals by subjecting
them to generally acidic waters, either
in the form of acid rain or acidic
groundwater.
 Soluble minerals, such as calcite, are
particularly affected, but many other
minerals, including silicates and sulfide
minerals can also be dramatically
affected.
 Chemical reactions (including solution,
oxidation, carbonation and hydration
reactions) separate the constituents of
the minerals themselves.
Mechanical weathering
 involves physical forces which disintegrate rocks
into constituent minerals, but do not dissociate the
minerals into elemental their components.
 Ultimately this process results in the creation of
soil. These forces include the movement of water,
the freezing and thawing action of ice, the prying
action of plant roots, or wind action.
Mechanical erosion loosens and wears away
materials and transports these materials to a new
location. The most pervasive type of mechanical
erosion in temperate climates is that caused by
running water. Rainfall begins the process. The
water then flows down slope or soaks into the
ground.
The washing action of the water on hillsides carries
rocks, and mineral grains formed by rock
decomposition, down the slope where they
eventually become stream sediments.
The turbulence of the water, especially in steeper
areas where the current is faster, continues to carry
the sediments in suspension downstream. These
suspended sediments are called the “stream
load”. Larger rocks which skip along the bottom of
the stream bed due to sheer mass, are called the
“stream bed load”.
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Composed of fragments of pre-existing rock that have
been weathered,...
Mechanical weathering
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Common mineral stability
is the reverse of Bowens
Reaction Series.
Chemical weathering
Increasing
weathering
rates
Olivine [(Mg,Fe)2SiO4] weathers very quickly – it is not present in sediments, soils, or sedimentary
rocks.
Quartz is very resistant to chemical weathering; it is a major constituent of mature sediments.
The main chemical weathering reactions are oxidation and hydration.
Oxidation (addition of oxygen):
2Fe3O4(magnetite) + 0.5 O2 = 3Fe2O3(hematite)
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Chemical weathering
Oxidation (addition of oxygen):
3
3
224
3
2
2
O3Fe0.5OOFe2Fe 

Hydration (addition of H2O):
Magnetite Hematite
OnHOFeOnHOFe 232232 
Hematite Limonite
Carbonization (acidification by addition of CO2):

 33222 HCOHCOHOHCO
Carbonic
Acid
Bicarbonate
Ion
2 H+ + H2O + 2 KAlSi3O8 (K-Feldspar) 
Al2Si2O5(OH)4 (Kaolinite) + 4 SiO2(aq) + 2 K+
H+ + CaCO3 (Calcite)  Ca+2 + HCO3
-
Typical weathering patterns:
Feldspars  clay minerals, salts (change of structure).
Fe-Mg silicates  Fe oxides, Mg salts, clay minerals.
Quartz = stable.
Carbonates… dissolve!
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Chemical weathering
Acids: around volcanoes (HF, H2SO4, HCl);
carbonic (natural), pH 5.5-6. Run off from
mines.
Acid rain – pH down to 2!
Fig. 05.14
Acid Mine Drainage
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Fig. 05.15
Chemical Weathering
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Solution and Transportation
Solution of the constituents of economic sedimentary deposits in large part goes on
during weathering.
This is true of iron, manganese, phosphates, carbonates, copper, and some other
metals, (but, of course, does not apply to clays).
The chief solvents are :
1)Carbonated waters are very effective solvents of limestone, iron, manganese,
and phosphorus. Where iron is present in the ferrous state, its solution offers no
difficulty, since in that form it is unstable and soluble. But ferric iron is almost in
soluble in most surface waters and to underground solution, must first be
changed to the ferrous state organic matter aids his.
1)Humic and other organic acids derived from decomposing vegetation are
considered effective solvents by Harrar. Hyroxal acids dissolve large quantities of
iron, but the weak organic acids dissolve remarkable quantities and are the most
effective of all material solvents.
2)Sulfate solutions are effective solvents of iron and manganese but are rarely
abundant enough to effect large-scale solution and transportation. The oxidation
of pyrite yields sulfuric acid and ferric sulfate.
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H+ + CaCO3 (Calcite)  Ca+2 + HCO3
-
Deposition
 The materials that form economic sedimentary beds are
deposited mechanically, chemically, or biochemically, for
example, whether in the sea or in a swampy basin.
 The study of mineral equilibria under varying pH and Eh
conditions is the only way to understand solution and
deposition at low temperatures.
Conditions of Deposition
 The conditions under which deposition occurs determine in
large part the mineralogical composition of the resulting
deposits; their size; purity; and distribution, both areal and
stratigraphic.
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Fig. 06.04
Deposition: any process that lays down material.
Environment of Deposition: location in which deposition
occurs. Use the Principle of Uniformitarianism to study
ancient environments.
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Depositional Environments
Continental: glaciers, streams (fluvial),
lakes (lacustrine), springs
and groundwater, wind.
Transitional: deltas and beach
deposits.
Marine: shallow (continental shelf)
and deep (abyssal plains)
deposits.
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Continental Depositional Environments
Clastic Sedimentary Rocks
Composed of fragments of pre-existing rock that have been
weathered, eroded, and transported
to a site of deposition
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Examples of Sedimentary Environments
Red – continental environments
Blue – transitional
environments
Black – marine
environments
30
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36
Sedimentary Ore Deposits
 The term sedimentary mineral deposits is applied to any local concentration
of minerals formed through processes of sedimentation.
 One form of sedimentation is the precipitation of substances carried in
solution.
Surficial processes: are the physical and chemical phenomena which cause
concentration of ore material within the regolith, generally by the action of the
environment.
The physical processes of ore deposit formation in the surficial realm include:
erosion
Density Differences deposition by sedimentary processes, including winnowing, Sorting
due to gravity, density separation (e.g.; Placers: gold , Ti, Sn, and Diamonds placers)
weathering via oxidation or chemical attack of a rock, either liberating rock fragments or
creating chemically deposited clays, laterites or manto ore deposits(Example: Bauxite and
other laterites, supergene)
Deposition in low-energy environments in beach environments
Chemical Precipitation (Example: Banded Iron Formations, Evaporites, Salt, Gypsum).
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Exogenous (Surficial) processes: (solar, external heat driven largely)
1) Weathering:
 Climate, pH, Eh, T (effect of H+ on feldspar stability)
2KAlSi3O8 + 2H+ + 9H2O = H4Al2Si2O9 (kaolinite) + 4H4SiO4 (silicic acid) + 2K+
(direction of reaction when decrease pH, increase H+)
 Leaching, chelating agents, secondary concentration processes (redox,
Cu, U), Clays common product, also bauxite from Easterbrook.
Note: that this is also important for pollutants, solubility determines mobility.
Comment on bauxite (Al -rich) versus laterite (typical red tropical soil, Fe rich)
2) Sedimentation:
 Sorting, river, wind, energy/density, sometimes Eh! (U in pC), placer
deposits.
 Crystallization from surface water, usually evaporation, can also be
mixing zone where activities of components change. NaCl (mined for
salt), CaSO4*2H2O, KCl (mined for fertilizer).
 Flux of sea water to produce concentrations (such as onto shallow
continental shelf or restricted basin), phosphorous from teeth bones on
continental shelfs, Often perception is biologically enhanced (e.g.
manganese nodules probably related to microbe activity).
 Complex reactions where polluted stream encounters other water.
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1) Deposits formed by Weathering
 Placer Mineral Deposits:
 Formed by mechanical weathering of primary minerals and transport by streams .
 Minerals are concentrated by flowing surface waters depositing high density minerals either in streams or along
coastlines
 Sorted and distributed by flow of transporting media such as water, wind and ice .
 when the velocity of the water slows, minerals with a higher density are deposited. Heavy minerals like gold, diamond,
and magnetite will be concentrated in areas where water current velocity is low. The lighter minerals (quartz) are carried
away.
 Gold originally formed in hydrothermal veins, is eroded out of the veins and carried in streams where it was deposited in
placer deposits. The California gold rush in 1849 began when someone discovered rich placer deposits of gold in
streams.
 Gold, Ti, diamonds, other
 Residual (eluvial or laterite) Mineral Deposits :
 Formed by chemical weathering reactions at the earth’s surface.
 Leaching of rock leaves residual materials behind (i.e., Form by the removal of soluble minerals (leaching)
 Insoluble minerals (residues) get concentrated at the weathering site
 Intense chemical weathering is favored by tropical climate
 iron-rich Limonite , aluminum-rich Bauxite, Nickeliferous-laterite; Jamaica, Cuba, Arkansas.
 Al, Ni, Fe.
 Supergene Secondary Enrichment Deposits:
 In addition, an existing mineral deposit can be turned in to a more highly concentrated mineral deposit
by weathering in a process called secondary enrichment.
 Reworking of primary ore deposits remobilizes metals (often over short distances)
 Helps the low grade deposit to become high grade
 Leaching of sulphides (Cu) close to the surface and depositing them at depth forming rich blankets of
copper
 Examples: Chilean Andes, Southwestern US
 Copper and other sulfides.
Mechanical
Weathering
Chemical
Weathering
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Residual Concentration by Mechanical Weathering
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Placer deposits occur in any area where
current velocity is low, such as;
1) between ripple marks
Placer
Deposit
Stream Direction
3) on the inside of meandering streams
Placer
Deposit
2) behind rock bars
Stream Direction
Placer
Deposit
4) in holes on the bottom of a stream
Stream Direction
Placer
Deposit
Secondary enrichment process
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Sed. Ore Deposit Env.
40
2) Deposits formed by sedimentation
 Ironstone, Calcium carbonate, Chert, Sulfur, uranium, Copper &
manganese Deposits
 Direct precipitated as sediments
 Precipitated from a solution, typically sea water
 Manganese nodules
 Evaporite Salt Deposits
 Minerals like gypsum, halite deposited this way
 Evaporation of lake water or sea water results in the loss of water and
thus concentrates dissolved minerals in the remaining water.
 When the water becomes saturated with dissolved minerals, they
precipitate from the water. Deposits of halite (table salt) and gypsum
(used in plaster and wall board), result from this process.
 Phosphate Deposits
 Minerals are concentrated by chemical precipitation from lake or sea water.
 These mineral deposits form as a result of chemical sedimentation, where minerals are precipitated
directly out of water.
22 November 2015
Prof. Dr. H.Z. Harraz Presentation
Sed. Ore Deposit Env.
41
Resources from the Sedimentary Environments
Energy resources
•Oil and Gas
•Gas hydrates
•Coal Deposits
•Oil Shale
•Gas Shale
•Tar Sand
•Uranium Placer Deposits
•Uranium Sedimentary deposits
 Non-Metallic Resources:
• Natural aggregate (crushed stone,
sand, and gravel
• Sandstone
• Limestone and dolomite
• Shale
• Placer Deposits (Diamond, Garnet ,
Ruby and Sapphire)
• Phosphate deposits
• Chert
• Evaporative salts (Potash minerals,
Sodium minerals, Borate, Nitrates)
• Sulfur
• Clay mineral (Kaolinite)
Metallic Resources:
• Copper deposits
• Supergene Secondary Enrichment
Deposits (Cu, Pb, Zn, Ag)
• Manganese deposits
• Manganese nodules deposits
• Sedimentary Iron Deposits
• Laterite (Bauxite (Al ore), iron, nickel, cobalt,
chromium, titanium, copper, gold )
• Placer Deposits:
Gold (Au), Platinum (Pt), Cassiterite
(for Sn), Chromite (Cr), Columbite (for
Nb), Cu, Ilmenite (for Ti), Magnetite
and Hematite (for Fe), black sand,
Monazite (for rare earth elements),
Rutile (for Ti), zircon (for Zr), and
xenotime (for Y)
22 November 2015
Prof. Dr. H.Z. Harraz Presentation
Sed. Ore Deposit Env.
42
Non-metallic Resources
• Non-metallic resources - not mined to
extract a metal or an energy source
 construction materials
• sand, gravel, limestone, and gypsum
 agriculture
• phosphate, nitrate and potassium compounds.
 industrial uses
• rock salt, sulfur
 gemstones
• diamonds, rubies, etc.
 household and business products
• glass sand, diatomite
22 November 2015
Prof. Dr. H.Z. Harraz Presentation
Sed. Ore Deposit Env.
43
Sample Problem
Answer:
 Distinguish between weathering and depositional methods of the formation of economic mineral
deposits.
 Distinguish between depositional methods of the formation of economic mineral deposits in arid and
tropical (or semi-tropical) environments.
 Distinguish between different residual methods of the formation of economic mineral deposits.
 Distinguish between evaporation and depositional methods of the formation of economic mineral
deposits.
22 November 2015
Prof. Dr. H.Z. Harraz Presentation
Sed. Ore Deposit Env.
44
2-5 Geophysical SurveyingEND OF LECTURE 1

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Sedimentary ore deposit environments

  • 1. Introduction to Sedimentary Ore Deposits Hassan Z. Harraz hharraz2006@yahoo.com 2012- 2013 22 November 2015 1 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env.
  • 2. Acknowledgments: I acknowledge gratefully the extent to which I have leant on the work contained in several good text books: Evans, A. M., 1997. An introduction to Economic Geology and its environmental impact. Blackwell Scientific publications, 376pp. Pohl, W. L., 2011. Economic Geology: Principles and Practice. Wiley-Blackwell, 680 pp. Beydoun, Z. R., 1991. Arabian Plate Hydrocarbon Geology and Potential. AAPG, 77 pp. Guilbert, J. M. and Park, C. F., 1986. The Geology of Ore Deposits. W. H. Freeman & Co, 984 pp. Boggs, Jr., Sam, 2012, Principles of Sedimentology and Stratigraphy, 5th edition, Prentice Hall, Upper Saddle River, NJ, 600 pp. ISBN-10: 0321643186 Hussein, A. A. A. 1990. Mineral deposits, In: Said, R. (ed.), The geology of Egypt. A. A. Balkema/Rotterdam/Brookfield, pp 511-566. El Gaby, S.; List, F. K., Tehrani, R., 1988. Geology, evolution and metallogenesis of the Pan-African Belt in Egypt, In: El Gaby, S., Greiling, R. O. (Eds.), The Pan-African Belt of northeast Africa and adjacent areas. Friedr. Vieweg & Sohn, Braunschweig/Wiesbaden, pp.17-68. Hunt, J. M., 1996. Petroleum Geochemistry and Geology. W. H. Freeman & Co, 743 pp. Levorsen, A.I., 1967. Geology of Petroleum. W. H. Freeman & Co. 724 pp. Selley, Richard C., 1998. Elements of Petroleum Geology. Academic Press. 470 pp. 22 November 2015 2 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env.
  • 3. Topic 1: Sedimentary Ore Deposit Environments Topic 2: Calcium Carbonate and Chert Deposits Topic 3: Manganese and Iron Ore Deposits Topic 4: Sulfur and Uranium Mineral Deposits Topic 5: Phosphate Ore Deposits Topic 6: Evaporate Salt Deposits Topic 7: Placer Mineral deposits Topic 8: Residual (eluvial or laterite) Mineral Deposits Topic 9: Supergene Enrichment 22 November 2015 3 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. Outline of lectures:
  • 4.  An Introduction to Sedimentary Ore Deposits is to geologists.  This course provides a non-technical introduction to the basic concepts of: Introduction  Surficial Earth processes  Sedimentary Ore Deposit Environments  Sedimentary Mineral Deposits 1) Deposits formed by sedimentation  Ironstone, Calcium carbonate, Chert, Sulfur, Uranium, Copper & Manganese deposits  Phosphate deposits  Evaporite deposits 2) Deposits formed by Weathering  Placer Mineral Deposits  Residual Mineral Deposits (Laterites and Supergene  With numerous examples, figures and images of sedimentary ore deposits.  Also included are some key aspects of the mineral resources from the sedimentary environments and some ideas about the future of sedimentary mineral resources. 22 November 2015 4 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env.
  • 5. Topic 1: Sedimentary Ore Deposit Environments Hassan Z. Harraz hharraz2006@yahoo.com 2012- 2013 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 5
  • 6. 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 6 Outline of Topic 1: We will explore all of the above in Topic 1  Mineral Deposits  Ore Deposit Environments  Formation of Mineral Deposits  Introduction  The Hydrologic Cycle  The Rock Cycle  Types of Sedimentary Rocks  Sediments  Source of Materials  Sedimentary Processes  Hjulstrom’s Diagram  Weathering & Erosion  Mechanical Weathering  Chemical Weathering  Solution and Transportation  Deposition  Depositional Environments  Sedimentary Ore Deposits  Exogenous (Surficial) processes 1) Deposits formed by Weathering 2) Deposits formed by sedimentation  Resources from the Sedimentary Environments
  • 7. Mineral Deposits  A mineral deposit is a volume of rock enriched in one or more minerals. In this sense a mineral refers to a useful material, a definition that is different from the way we defined a mineral earlier in this unit.  Mineral deposits can be classified on the basis of the mechanism responsible for concentrating the valuable substance. Examples Include: 1) Magmatic Mineral Deposits 2) Hydrothermal Mineral Deposits 3) Metamorphic Mineral Deposits 4) Sedimentary Mineral Deposits 5) Placer Mineral Deposits 6) Residual Mineral Deposits 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 7
  • 8. Ore Deposit Environments  Magmatic  Cumulate deposits – fractional crystallization processes can concentrate metals (Cr, Fe, Pt)  Pegmatites – late staged crystallization forms pegmatites and many residual elements are concentrated (Li, Ce, Be, Sn, and U)  Hydrothermal  Magmatic fluid - directly associated with magma  Porphyries - Hot water heated by pluton  Exhalatives – hot water flowing to surface  Epigenetic – hot water not directly associated with pluton  Metamorphic  Skarn – hot water associated with contact metamorphisms  Sedimentary  Sedimentary Mineral Deposits  Ironstone, Calcium carbonate, Chert, Sulfur, Uranium, Copper & manganese deposits  Phosphate deposits  Evaporite deposits – minerals like gypsum, halite deposited this way  Placer Mineral Deposits :  Placer – weathering of primary minerals and transport by streams (Gold, diamonds, other)  Residual Mineral Deposits  Laterites – leaching of rock leaves residual materials behind (Al, Ni, Fe)  Supergene – reworking of primary ore deposits remobilizes metals (often over short distances) 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 8
  • 9. Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. Metallic Mineral Deposits and Geologic Processes Mineral deposits may be found in a variety of plate tectonic settings. Mineral resources include reserves = identified deposits from which minerals can be extracted profitably now or in the future with technological advances. 22 November 2015 9
  • 10. “Ore genesis processes” I) Endogenous (Internal) processes: 1) Magmatic processes 2) Hydrothermal processes 3) Metamorphic/Metasomatism processes II) Exogenous (Surficial) processes: 1) Weathering 2) Supergene enrichment 3) Mechanical concentration 4) Chemical deposition (Sedimentation) 5) Evaporation Formation of Mineral Deposits 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 10
  • 11. Introduction The process of sedimentation as distinct from evaporation has resulted not only in the formation of common sedimentary rocks but also in valuable mineral deposits of iron, manganese, copper, phosphate, coal, oil shale, carbonates, cement rocks, clay, diatomaceous earth, bentonite, fuller's earth, magnesite, sulphur, and; less directly, uranium-vanadium deposits. Their mode of formation is that of sedimentation with special variations to account for the special materials. They are composed of inorganic and organic materials; their source, like that of any sedimentary rock, is from other rocks that have undergone disintegration, the ultimate source, of course, being the igneous rocks. Some of the materials, such as oxygen and carbon dioxide, have been obtained from the atmosphere, and a few have been derived from former deposits. The formation of sedimentary deposits involves: 1) an adequate source of materials; 2) the gathering of this materials by solution or processes; 3) the transportation of the materials to the site of accumulation if that is necessary; and 4) the deposition of the materials in the sedimentary basin. Subsequent compaction, chemical alteration, or other changes may take place. Water cycle 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 11
  • 12. The Hydrologic Cycle 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 12
  • 13. The Rock Cycle Volcanic Rocks Soils Sediments Sedimentary Rocks Weathering Atmosphere Biosphere Hydrosphere Solar Energy Metamorphic Rocks Magma Melting 1 Melting 2Crust Mantle Internal Energy Subduction Compaction & CementationErosion, Transportation & Deposition Tectonic Uplift Heat & Pressure Intrusive Rocks Cooling & Crystallization Sea level Earth Surface Endogenous (Internal) processes Exogenous (Surficial) processes 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 13
  • 14. Sediments and Sedimentary Rocks make up:  8% of the Earth’s crust  75% of the Earth’s surface (principally in the marine environment) 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 14
  • 15. composed of fragments of pre-existing rock that have been weathered, eroded and transported by wind, water, ice, or mass movement to a site of deposition. • Sandstones • Conglomerates • Breccia • Shale/mudstones Types of Sedimentary Rocks Clastic rocks Chemical rocks Evaporitic rocks These rocks are formed due to evaporation of saline water (sea water) e.g. Gypsum, Halit (rock salt) Inorganic rocks Form basically from CaCO3 – both by chemical leaching and by organic source (biochemical) e.g. Limestone; dolomite Organic rocks Form due to decomposition of organic remains under temperature and pressure e.g. phosphate, Coal/Lignite etc. 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 15 SEDIMENTARY ROCK - Compacted and cemented accumulations of sediment, which can be of two general types - clastic and chemical. composed of minerals precipitated from water (usually ocean water) due to evaporation or to the metabolic action of organisms (biogenic)
  • 16. Sediments Defined: • unconsolidated organic and inorganic particles that accumulate on the ocean floor • originate from numerous sources:  weathering and erosion of the continents (many sizes and types).  volcanic eruptions  biological activity  chemical processes within the oceanic crust and seawater  impacts of extra-terrestrial objects  Space • classified by size according to the Wentworth scale
  • 17. Source of Materials The materials that enter into sedimentary mineral deposits have been derived chiefly from the weathering of rocks. Occasionally, materials have come from the weathering and oxidation of former mineral deposits such as iron, manganese, and copper. Others have passed through an intermediate organic stage. The rocks, however, constitute an adequate source for most of the sedimentary iron, manganese, and copper. The iron comes from the weathering of iron-bearing minerals of igneous rocks such as hornblende, pyroxene, or mica, from the iron-bearing minerals of' sedimentary and metamorphic rocks, and from the red colouring matter of sedimentary rocks. Similarly, the manganese of sedimentary deposits has been derived chiefly from the weathering of manganese-bearing minerals in the rocks and, to a minor extent, from former sedimentary concentrations and epigenetic lode deposits. The source of sedimentary phosphate is phosphorus-bearing rock minerals, among which apatite is the most common. Some is also derived from the weathering of collophanite and dahllite in sedimentary rocks. The constituents of sedimentary carbonate deposits such as the industrial limestones, dolomite, and magnesite are derived from the see or saline waters to which they are largely supplied by rock weathering; also, the constituents of the numerous types of industrial clayey deposits such as cl clays, bentonite, and fuller's earth originate in rock weathering.
  • 18. Sedimentary Processes Transportation: Rounding - increases with length of transportation history. Sorting: increases with length of transportation history (weaker minerals broken down). Deposition: any process that lays down material. Environment of Deposition: location in which deposition occurs. Use the Principle of Uniformitarianism to study ancient environments. Preservation: deposition and burial in a basin. Reworking degrades preservation. 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 18
  • 19. • Average grain size reflects the energy of the depositional environment. • The smaller the particle is, the more easily it can be transported by streams, waves and currents. Clays • can remain suspended for very long periods • can be transported very far by ocean currents 4-1 http://uregina.ca/~sauchyn/geog323/hjulstrom.gif Hjulstrom’s Diagram graphs the relationship between particle size and energy for erosion, transportation and deposition 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 19
  • 20. WEATHERING: Process that transforms high temperature minerals to low-temperature ones stable at the Earth’s surface. Dissolves ALL minerals to some extent. Weathering and erosion as a mechanism of separating and concentrating chemical constituents: 1) remove specific elements, compounds or minerals from ordinary rock. Rounding - increases with length of transportation history. 2) transport these elements, compounds, or minerals. 3) Sorting: increases with length of transportation history (weaker minerals broken down). 4) concentrate the elements, compounds, or minerals preferentially at one spot or zone where the transport stops. concentrate removal  the primary mechanisms for concentrating minerals into ores involves either: a) sorting by density, or b) sorting by solubility.  Weathering and erosion as a mechanism of separating and concentrating chemical constituents. 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 20
  • 21. Fig. 06.01 Transportation: Rounding - increases with length of transportation history. Boulders have been abraided 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 21
  • 22.  grain size indicates condition under which sediment is deposited  high energy environments characteristically yield sediments larger in size  small particles (silts, clays) indicate low energy environments  Sorting: increases with length of transportation history (weaker minerals broken down).  considered well-sorted if most particles appear in the same size classification  poorly sorted sediments comprised of multiple sizes  sediment maturity is indicated by several factors  decreased silt and clay content  increased sorting  increased rounding of grains, as a result of weathering and abrasion  particle transport is controlled by grain size and velocity of transporting medium 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 22
  • 23. time energy energy time Sediment can contain particles of the same size or of different sizes Sorting is a function of the energy of the environment wide narrow 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 23
  • 24. Erosion  EROSION: Transport away from weathering site. This process exposes intrusive igneous rocks to weathering & the process continues. Transport by Wind, Ice, Gravity, Water (solution/ suspension).  Erosion is the breakdown of materials forming the earth’s crust, otherwise known as weathering.  The two principle types of weathering include chemical and mechanical weathering. Chemical weathering:  involves decomposition of rocks and their constituent minerals by subjecting them to generally acidic waters, either in the form of acid rain or acidic groundwater.  Soluble minerals, such as calcite, are particularly affected, but many other minerals, including silicates and sulfide minerals can also be dramatically affected.  Chemical reactions (including solution, oxidation, carbonation and hydration reactions) separate the constituents of the minerals themselves. Mechanical weathering  involves physical forces which disintegrate rocks into constituent minerals, but do not dissociate the minerals into elemental their components.  Ultimately this process results in the creation of soil. These forces include the movement of water, the freezing and thawing action of ice, the prying action of plant roots, or wind action. Mechanical erosion loosens and wears away materials and transports these materials to a new location. The most pervasive type of mechanical erosion in temperate climates is that caused by running water. Rainfall begins the process. The water then flows down slope or soaks into the ground. The washing action of the water on hillsides carries rocks, and mineral grains formed by rock decomposition, down the slope where they eventually become stream sediments. The turbulence of the water, especially in steeper areas where the current is faster, continues to carry the sediments in suspension downstream. These suspended sediments are called the “stream load”. Larger rocks which skip along the bottom of the stream bed due to sheer mass, are called the “stream bed load”. 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 24
  • 25. Composed of fragments of pre-existing rock that have been weathered,... Mechanical weathering 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 25
  • 26. Common mineral stability is the reverse of Bowens Reaction Series. Chemical weathering Increasing weathering rates Olivine [(Mg,Fe)2SiO4] weathers very quickly – it is not present in sediments, soils, or sedimentary rocks. Quartz is very resistant to chemical weathering; it is a major constituent of mature sediments. The main chemical weathering reactions are oxidation and hydration. Oxidation (addition of oxygen): 2Fe3O4(magnetite) + 0.5 O2 = 3Fe2O3(hematite) 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 26
  • 27. Chemical weathering Oxidation (addition of oxygen): 3 3 224 3 2 2 O3Fe0.5OOFe2Fe   Hydration (addition of H2O): Magnetite Hematite OnHOFeOnHOFe 232232  Hematite Limonite Carbonization (acidification by addition of CO2):   33222 HCOHCOHOHCO Carbonic Acid Bicarbonate Ion 2 H+ + H2O + 2 KAlSi3O8 (K-Feldspar)  Al2Si2O5(OH)4 (Kaolinite) + 4 SiO2(aq) + 2 K+ H+ + CaCO3 (Calcite)  Ca+2 + HCO3 - Typical weathering patterns: Feldspars  clay minerals, salts (change of structure). Fe-Mg silicates  Fe oxides, Mg salts, clay minerals. Quartz = stable. Carbonates… dissolve! 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 27
  • 28. Chemical weathering Acids: around volcanoes (HF, H2SO4, HCl); carbonic (natural), pH 5.5-6. Run off from mines. Acid rain – pH down to 2! Fig. 05.14 Acid Mine Drainage 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 28
  • 29. Fig. 05.15 Chemical Weathering 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 29
  • 30. Solution and Transportation Solution of the constituents of economic sedimentary deposits in large part goes on during weathering. This is true of iron, manganese, phosphates, carbonates, copper, and some other metals, (but, of course, does not apply to clays). The chief solvents are : 1)Carbonated waters are very effective solvents of limestone, iron, manganese, and phosphorus. Where iron is present in the ferrous state, its solution offers no difficulty, since in that form it is unstable and soluble. But ferric iron is almost in soluble in most surface waters and to underground solution, must first be changed to the ferrous state organic matter aids his. 1)Humic and other organic acids derived from decomposing vegetation are considered effective solvents by Harrar. Hyroxal acids dissolve large quantities of iron, but the weak organic acids dissolve remarkable quantities and are the most effective of all material solvents. 2)Sulfate solutions are effective solvents of iron and manganese but are rarely abundant enough to effect large-scale solution and transportation. The oxidation of pyrite yields sulfuric acid and ferric sulfate. 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 30 H+ + CaCO3 (Calcite)  Ca+2 + HCO3 -
  • 31. Deposition  The materials that form economic sedimentary beds are deposited mechanically, chemically, or biochemically, for example, whether in the sea or in a swampy basin.  The study of mineral equilibria under varying pH and Eh conditions is the only way to understand solution and deposition at low temperatures. Conditions of Deposition  The conditions under which deposition occurs determine in large part the mineralogical composition of the resulting deposits; their size; purity; and distribution, both areal and stratigraphic. 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 31
  • 32. Fig. 06.04 Deposition: any process that lays down material. Environment of Deposition: location in which deposition occurs. Use the Principle of Uniformitarianism to study ancient environments. 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 32
  • 33. Depositional Environments Continental: glaciers, streams (fluvial), lakes (lacustrine), springs and groundwater, wind. Transitional: deltas and beach deposits. Marine: shallow (continental shelf) and deep (abyssal plains) deposits. 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 33
  • 34. Continental Depositional Environments Clastic Sedimentary Rocks Composed of fragments of pre-existing rock that have been weathered, eroded, and transported to a site of deposition 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 34
  • 35. Examples of Sedimentary Environments Red – continental environments Blue – transitional environments Black – marine environments 30 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 35
  • 36. 36 Sedimentary Ore Deposits  The term sedimentary mineral deposits is applied to any local concentration of minerals formed through processes of sedimentation.  One form of sedimentation is the precipitation of substances carried in solution. Surficial processes: are the physical and chemical phenomena which cause concentration of ore material within the regolith, generally by the action of the environment. The physical processes of ore deposit formation in the surficial realm include: erosion Density Differences deposition by sedimentary processes, including winnowing, Sorting due to gravity, density separation (e.g.; Placers: gold , Ti, Sn, and Diamonds placers) weathering via oxidation or chemical attack of a rock, either liberating rock fragments or creating chemically deposited clays, laterites or manto ore deposits(Example: Bauxite and other laterites, supergene) Deposition in low-energy environments in beach environments Chemical Precipitation (Example: Banded Iron Formations, Evaporites, Salt, Gypsum). 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env.
  • 37. Exogenous (Surficial) processes: (solar, external heat driven largely) 1) Weathering:  Climate, pH, Eh, T (effect of H+ on feldspar stability) 2KAlSi3O8 + 2H+ + 9H2O = H4Al2Si2O9 (kaolinite) + 4H4SiO4 (silicic acid) + 2K+ (direction of reaction when decrease pH, increase H+)  Leaching, chelating agents, secondary concentration processes (redox, Cu, U), Clays common product, also bauxite from Easterbrook. Note: that this is also important for pollutants, solubility determines mobility. Comment on bauxite (Al -rich) versus laterite (typical red tropical soil, Fe rich) 2) Sedimentation:  Sorting, river, wind, energy/density, sometimes Eh! (U in pC), placer deposits.  Crystallization from surface water, usually evaporation, can also be mixing zone where activities of components change. NaCl (mined for salt), CaSO4*2H2O, KCl (mined for fertilizer).  Flux of sea water to produce concentrations (such as onto shallow continental shelf or restricted basin), phosphorous from teeth bones on continental shelfs, Often perception is biologically enhanced (e.g. manganese nodules probably related to microbe activity).  Complex reactions where polluted stream encounters other water. 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 37
  • 38. 1) Deposits formed by Weathering  Placer Mineral Deposits:  Formed by mechanical weathering of primary minerals and transport by streams .  Minerals are concentrated by flowing surface waters depositing high density minerals either in streams or along coastlines  Sorted and distributed by flow of transporting media such as water, wind and ice .  when the velocity of the water slows, minerals with a higher density are deposited. Heavy minerals like gold, diamond, and magnetite will be concentrated in areas where water current velocity is low. The lighter minerals (quartz) are carried away.  Gold originally formed in hydrothermal veins, is eroded out of the veins and carried in streams where it was deposited in placer deposits. The California gold rush in 1849 began when someone discovered rich placer deposits of gold in streams.  Gold, Ti, diamonds, other  Residual (eluvial or laterite) Mineral Deposits :  Formed by chemical weathering reactions at the earth’s surface.  Leaching of rock leaves residual materials behind (i.e., Form by the removal of soluble minerals (leaching)  Insoluble minerals (residues) get concentrated at the weathering site  Intense chemical weathering is favored by tropical climate  iron-rich Limonite , aluminum-rich Bauxite, Nickeliferous-laterite; Jamaica, Cuba, Arkansas.  Al, Ni, Fe.  Supergene Secondary Enrichment Deposits:  In addition, an existing mineral deposit can be turned in to a more highly concentrated mineral deposit by weathering in a process called secondary enrichment.  Reworking of primary ore deposits remobilizes metals (often over short distances)  Helps the low grade deposit to become high grade  Leaching of sulphides (Cu) close to the surface and depositing them at depth forming rich blankets of copper  Examples: Chilean Andes, Southwestern US  Copper and other sulfides. Mechanical Weathering Chemical Weathering 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 38
  • 39. Residual Concentration by Mechanical Weathering 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 39
  • 40. Placer deposits occur in any area where current velocity is low, such as; 1) between ripple marks Placer Deposit Stream Direction 3) on the inside of meandering streams Placer Deposit 2) behind rock bars Stream Direction Placer Deposit 4) in holes on the bottom of a stream Stream Direction Placer Deposit Secondary enrichment process 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 40
  • 41. 2) Deposits formed by sedimentation  Ironstone, Calcium carbonate, Chert, Sulfur, uranium, Copper & manganese Deposits  Direct precipitated as sediments  Precipitated from a solution, typically sea water  Manganese nodules  Evaporite Salt Deposits  Minerals like gypsum, halite deposited this way  Evaporation of lake water or sea water results in the loss of water and thus concentrates dissolved minerals in the remaining water.  When the water becomes saturated with dissolved minerals, they precipitate from the water. Deposits of halite (table salt) and gypsum (used in plaster and wall board), result from this process.  Phosphate Deposits  Minerals are concentrated by chemical precipitation from lake or sea water.  These mineral deposits form as a result of chemical sedimentation, where minerals are precipitated directly out of water. 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 41
  • 42. Resources from the Sedimentary Environments Energy resources •Oil and Gas •Gas hydrates •Coal Deposits •Oil Shale •Gas Shale •Tar Sand •Uranium Placer Deposits •Uranium Sedimentary deposits  Non-Metallic Resources: • Natural aggregate (crushed stone, sand, and gravel • Sandstone • Limestone and dolomite • Shale • Placer Deposits (Diamond, Garnet , Ruby and Sapphire) • Phosphate deposits • Chert • Evaporative salts (Potash minerals, Sodium minerals, Borate, Nitrates) • Sulfur • Clay mineral (Kaolinite) Metallic Resources: • Copper deposits • Supergene Secondary Enrichment Deposits (Cu, Pb, Zn, Ag) • Manganese deposits • Manganese nodules deposits • Sedimentary Iron Deposits • Laterite (Bauxite (Al ore), iron, nickel, cobalt, chromium, titanium, copper, gold ) • Placer Deposits: Gold (Au), Platinum (Pt), Cassiterite (for Sn), Chromite (Cr), Columbite (for Nb), Cu, Ilmenite (for Ti), Magnetite and Hematite (for Fe), black sand, Monazite (for rare earth elements), Rutile (for Ti), zircon (for Zr), and xenotime (for Y) 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 42
  • 43. Non-metallic Resources • Non-metallic resources - not mined to extract a metal or an energy source  construction materials • sand, gravel, limestone, and gypsum  agriculture • phosphate, nitrate and potassium compounds.  industrial uses • rock salt, sulfur  gemstones • diamonds, rubies, etc.  household and business products • glass sand, diatomite 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 43
  • 44. Sample Problem Answer:  Distinguish between weathering and depositional methods of the formation of economic mineral deposits.  Distinguish between depositional methods of the formation of economic mineral deposits in arid and tropical (or semi-tropical) environments.  Distinguish between different residual methods of the formation of economic mineral deposits.  Distinguish between evaporation and depositional methods of the formation of economic mineral deposits. 22 November 2015 Prof. Dr. H.Z. Harraz Presentation Sed. Ore Deposit Env. 44