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Oxygen Measurement for Process Analytics Presentation Urdorf, January 2010
Agenda ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Our Group METTLER TOLEDO is a global manufacturer and marketer of precision instruments for  use in the laboratories, manufacturing,  and food retailing. ,[object Object],[object Object],[object Object]
Customer Processes ,[object Object],[object Object],[object Object],[object Object],[object Object],Customer Benefits Laboratory Solutions Industrial Solutions Retail Solutions R&D Drug Discovery Quality Control Retail Logistics Packaging Manufacturing
Divisional Structure Process Analytics Industrial Weighing Laboratory Division Product Inspection Retail Solutions Laboratory Solutions Industrial Solutions Retail Division
Value Proposition Process Analytics Measuring key analytical parameters to control production processes:
Applications Around Customer Processes Plant Water  Source Coagulation / Reverse Osmosis/ Demineralizers Cooling Towers/ Boilers  Waste Water Recycle & Discharge Downstream Processing Preparation Reactions Waste Water Water  Preparation Process Oxygen Gas Phase
Complete Product Offering DO/O 2 /O 3 Housing TOC Turb Cond pH CO 2 High-end Advanced Basic
Service Solutions Service  XXL Customer Benefits Validation methods and protocols ensure process reproducibility, user monitoring and safe data management. Documented equipment qualification ensures compliance with quality assurance systems such as GLP, GMP and ISO. Calibration processes ensure accurate, reliable and traceable results. Proactive maintenance maximizes uptime and productivity. User training ensures equipment knowledge which leads to safer working processes. Maintenance and Support Calibration Regulatory Compliance Vali- dation Maintenance and Support Calibration Qualification Vali- dation Support Improved service tools enhance customer processes
Oxygen Analytics Around Your Process Storage & Environment Upstream & Processing Recovery & Waste Downstream & Purification ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Why METTLER TOLEDO? ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],METTLER TOLEDO Process Analytics is your partner of choice for reliable and innovative Liquid & Gas measurement solutions
Agenda ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Reasons for Gas Measurement ,[object Object],[object Object],[object Object],[object Object],Oxygen control has a direct impact on the quality and the efficiency of your process Quality Safety Environmental  protection ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Drivers for Efficient Oxygen Measurement ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],METTLER TOLEDO: efficient and innovative  in-line  solutions through technology leadership and application expertise Market needs Product requirements
Challenges for In-line Measurement ,[object Object],[object Object],[object Object],[object Object],[object Object],In-Line Measurement Robustness Reliability Accuracy Continuous ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],In-Line Oxygen measurement for your process results into better data transparency and improvement opportunities
Inerting Methods ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],METTLER TOLEDO Approach With Oxygen monitoring, inert gas consumption can be reduced by 70% of  conventional costs Conventional Approach
Which O 2  Level? ,[object Object],[object Object],[object Object],Oxygen control directly into your process is the combination of improved safety with lower operating costs Limiting oxygen concentration (LOC): the lowest oxygen concentration supporting flame propagation
Agenda ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
3-Electrode Polarographic Cell Cathode   :   O 2  + 2H 2 O + 4e - ->  4OH −   Anode 4OH - ->   O 2  + 2H 2 O + 4e - Reference: AgCl ↔   Ag +  + Cl - Electrode reactions InPro 6800 & InPro 6850i Series - Instruction Manual Inner Body Membrane Body O 2 O 2 O 2 R Membrane Cathode Glass  insulator Reference Electrolyte Polarization voltage NTC 22k  Anode - + I Current U
Polarographic Curve ,[object Object],[object Object],A constant polarization voltage (675mV) is applied to the cell that induces the reduction of oxygen at the cathode. PRO-Net Library,  Theory of Polarographic Oxygen Sensors
Amperometric Oxygen Measurement ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Amperometric oxygen measurement is a proven technology in harsh applications
Sensor Design Membrane  body Cap sleeve Retainer nut Replaceable inner body Sensor shaft Connector (IP68) Pg 13.5 sleeve ,[object Object],[object Object],[object Object],Available in: ,[object Object],[object Object],[object Object],Easy and fast maintenance by design
Sensor Performance: Response Time 98% Fast Oxygen response time translates into better decision-making  into your process in case of sudden change in process conditions
Agenda ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
O 2  Gas Product Offering Transmitter Housing Sensor AirCheck Enhanced Basic
Technical Facts – Pressure Compensation M400 solution 98% N 2 , 2% O 2  @ 1 bar 2.4 % O 2 1.2 bar 2.0 % O 2 M420 & M700 solution 98% N 2 , 2% O 2  @ 1 bar 2.4 % O 2 1.2 bar 2.0 % O 2 0/4..20 mA 0/4..20 mA 0/4..20 mA 0/4..20 mA Process pressure must be accounted for either in the DCS or in the transmitter
ISM ® : A Future-proof Maintenance Concept ,[object Object],[object Object],[object Object],[object Object],[object Object],Install Configure Calibrate Document Troubleshoot  Replace ISM ®  is METTLER TOLEDO’s solution for Advanced Process Analytics
ISM Maintenance Concept
Key Success Factors ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],The five key differentiators show the clear advantages of INGOLD’s inline gas measurement capability
Robustness ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Typical sampling unit INGOLD’s simple and rugged amperometric solution can be installed in harsh environments
Direct Installation ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Only inline installation offers direct oxygen monitoring in the process
Easy Maintenance ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Permanent system availability due to the easy and fast maintenance or replacement
Enhanced Reliability with AirCheck™ ,[object Object],[object Object],[object Object],[object Object],Unique new “Safety” solution: Check the air current of the oxygen sensor at any time with AirCheck™: Nitrogen Air Coming Q1 10 Vent AirCheck™ allows to regularly check the integrity of the measurement system
Redundancy ,[object Object],[object Object],[object Object],Redundancy ,[object Object],[object Object],The attractive price/performance of a loop allows for cost efficient redundant measurement
Return On Investment (ROI) Payback period 4 Months 80% cost saving
Agenda ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Oxygen Sensor Portfolio ≤ ±[1% +5 ppm] ≤ ±[1% + 3 ppb] ≤ ±[1% + 300ppb] ≤ ±[1% + 0.1 Vol%] Accuracy ,[object Object],[object Object],Certification 0 .. 25% O2 0 .. 100% O2 0 .. 100% O2 0 ..100% O2 Measurement range 5 ppm 50 ppm 300 ppm 300 ppm Detection Limit ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],InPro 6900i G ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Typical Applications ,[object Object],[object Object],[object Object],[object Object],[object Object],InPro 6950i G InPro 6850i G InPro 6800 G ,[object Object],[object Object],[object Object],[object Object],[object Object],Features
Why we do not need Sample Conditioning ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Agenda ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Gas-Phase Oxygen Transmitters Cl1 Div 2 Cl1 Div 1* *pending Pressure input Pressure input Pressure input InPro 6800 G, InPro 6850i G, InPro 6900i G, InPro 6950i G InPro 6800 G, InPro 6850i G, InPro 6900i G, InPro 6950i G InPro 6800 G, InPro 6850i G, InPro 6900i G, InPro 6950i G Single Channel Single Parameter Mixed-mode input 2-Wire, loop powered M420 Single Channel Multi  Parameter Mixed-mode input Dual Channel Multi Parameter Mixed-mode input 4-Wire 4-Wire M400 M700
M400 Feature Overview Password protection (5 digit, numeric) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Quick Setup Mode Large backlit display (4 text lines) USB port M400: Mixed-mode input:   TB3 for conventional sensors (ChA) TB4 for ISM sensor (ChB)  Variable power supply 100..240VAC; 20..30V DC ,[object Object],[object Object],[object Object],[object Object],[object Object],4 x (0) 4-20mA Outputs 6 Relays Multi parameter unit  O2, pH, pH ISFET, Cond, CondInd FM Cl1 Div 2 / Atex Zone 2 (except M400 Type 1 Cond Ind) IP 65 The M400, proven technology for ease of use, ruggedness and advanced ISM diagnostics
M420 Feature Overview 5 x Password protection (4 digit, numeric) FM Cl1 Div 2 (pending) FM Cl1 Div 1 (pending) /ATEX Zone 1 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Wide backlit display (scrolling text line) IrDA service port M420: Mixed-mode input:   conventional sensors OR ISM sensors  ,[object Object],[object Object],[object Object],[object Object],[object Object],pending OUT2 option:  Up to 2 configurable current outputs (primary or secondary value) Key features of the M420 are the integration of ISM ®  functionalities and the unique mixed-mode input feature
M700 Feature Overview Optional selectable software functions FDA 21CFR Part11 compliance Data logger FM Cl1 Div 2 FM Cl1 Div 1 / ATEX Zone 1 IP65/NEMA 4X ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Wide backlit display (scrolling text line) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Key features of the M700 are the integration of ISM ®  and the unique dual channel mixed-mode input features
Communication Capabilities HART and FOUNDATION Fieldbus Integration Open Architecture with PROFIBUS METTLER TOLEDO integrates your analytical measurement into your control system
Agenda ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Housing Overview for Oxygen Systems Q1 10 ,[object Object],[object Object],InFit 761e ,[object Object],[object Object],[object Object],AirCheck™ InTrac 777e INGOLD offers a wide range of application solutions, customizable for all process adaptions
The TRI-LOCK TM  System ,[object Object],[object Object],[object Object],Patented  immersion tube 100 mm & 200 mm Sensor detector Positive position rod for InTrac 7X7 & 7x9 (enclosed) Maintenance and sensor replacement without process interruption
1) Patented Immersion Tube ,[object Object],[object Object],Increased operational safety  and reliable operation due to the safety TRI-LOCK system.
2) Sensor Detection ,[object Object],[object Object],Increased operational safety  and reliable operation due to the safety TRI-LOCK system.
3) Positive Position Rod ,[object Object],[object Object],Increased operational safety  and reliable operation due to the safety TRI-LOCK system.
Agenda ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Applications N2 blanketing Inertization Off-gas Monitoring & Vapor recovery ,[object Object],[object Object],[object Object],Background gas: Background gases: Background gases:
Add customer-specific slides from Application Presentation Portfolio !
Agenda ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Summary and Outlook ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],METTLER TOLEDO – an unique choice of measurement solutions for gas and liquid analytics

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GPO Customer Presentation

  • 1. Oxygen Measurement for Process Analytics Presentation Urdorf, January 2010
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  • 5. Divisional Structure Process Analytics Industrial Weighing Laboratory Division Product Inspection Retail Solutions Laboratory Solutions Industrial Solutions Retail Division
  • 6. Value Proposition Process Analytics Measuring key analytical parameters to control production processes:
  • 7. Applications Around Customer Processes Plant Water Source Coagulation / Reverse Osmosis/ Demineralizers Cooling Towers/ Boilers Waste Water Recycle & Discharge Downstream Processing Preparation Reactions Waste Water Water Preparation Process Oxygen Gas Phase
  • 8. Complete Product Offering DO/O 2 /O 3 Housing TOC Turb Cond pH CO 2 High-end Advanced Basic
  • 9. Service Solutions Service XXL Customer Benefits Validation methods and protocols ensure process reproducibility, user monitoring and safe data management. Documented equipment qualification ensures compliance with quality assurance systems such as GLP, GMP and ISO. Calibration processes ensure accurate, reliable and traceable results. Proactive maintenance maximizes uptime and productivity. User training ensures equipment knowledge which leads to safer working processes. Maintenance and Support Calibration Regulatory Compliance Vali- dation Maintenance and Support Calibration Qualification Vali- dation Support Improved service tools enhance customer processes
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  • 19. 3-Electrode Polarographic Cell Cathode : O 2 + 2H 2 O + 4e - -> 4OH − Anode 4OH - -> O 2 + 2H 2 O + 4e - Reference: AgCl ↔ Ag + + Cl - Electrode reactions InPro 6800 & InPro 6850i Series - Instruction Manual Inner Body Membrane Body O 2 O 2 O 2 R Membrane Cathode Glass insulator Reference Electrolyte Polarization voltage NTC 22k  Anode - + I Current U
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  • 23. Sensor Performance: Response Time 98% Fast Oxygen response time translates into better decision-making into your process in case of sudden change in process conditions
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  • 25. O 2 Gas Product Offering Transmitter Housing Sensor AirCheck Enhanced Basic
  • 26. Technical Facts – Pressure Compensation M400 solution 98% N 2 , 2% O 2 @ 1 bar 2.4 % O 2 1.2 bar 2.0 % O 2 M420 & M700 solution 98% N 2 , 2% O 2 @ 1 bar 2.4 % O 2 1.2 bar 2.0 % O 2 0/4..20 mA 0/4..20 mA 0/4..20 mA 0/4..20 mA Process pressure must be accounted for either in the DCS or in the transmitter
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  • 35. Return On Investment (ROI) Payback period 4 Months 80% cost saving
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  • 40. Gas-Phase Oxygen Transmitters Cl1 Div 2 Cl1 Div 1* *pending Pressure input Pressure input Pressure input InPro 6800 G, InPro 6850i G, InPro 6900i G, InPro 6950i G InPro 6800 G, InPro 6850i G, InPro 6900i G, InPro 6950i G InPro 6800 G, InPro 6850i G, InPro 6900i G, InPro 6950i G Single Channel Single Parameter Mixed-mode input 2-Wire, loop powered M420 Single Channel Multi Parameter Mixed-mode input Dual Channel Multi Parameter Mixed-mode input 4-Wire 4-Wire M400 M700
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  • 44. Communication Capabilities HART and FOUNDATION Fieldbus Integration Open Architecture with PROFIBUS METTLER TOLEDO integrates your analytical measurement into your control system
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  • 53. Add customer-specific slides from Application Presentation Portfolio !
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Notas del editor

  1. Solutions: Sensor Software / system integration Services LAB (blue): laboratories in many different industries products used for research, DD, QC has become much more sizeable in recent years IND (green) same customer base – however on the manufacturing und e.g. pharma production side. cover solutions across the plant: production, packaging, logistics RET (red): in food retail – provide solutions for the management of fresh goods Important value propositions to your customers: Accelerate processes (DD) Increase efficiency (LAB) Improve product quality (IND) Comply with regulations
  2. Aside from offering instruments and related software, we offer also an increasing array of services . We are in the midst of a successful transition from a traditional service definition to one of value added services. The foundation is our traditional service business with a significant contract / maintenance business / repair / calibration Now, we are moving decisively into regulatory compliance services, e.g. pharma FDA: IQ, EQ, OQ, PQ Also, we have validation specialists that can assist in all aspects of process validation. Validation methods ensure 21 CFR part 11 conformity . Validation protocols guarantee monitored user management and safe data management. Service is 20% of sales. Many years good growth , slowed down as a result of economy  bring it back to good growth.
  3. ISM is a system for the future and for today., Today ISM gives you a lot of benefits by making all the handling operations much simpler, more error-free and more efficient. Starting with the installation of the sensor. After connecting the sensor to the instrument the ISM system will perform it own configuration. Calibration can be done in a lab or maintenance shop, much easier than at the measuring point.. The ISM will also help you to reduce the amount trouble shootings. In all this steps the ISM function will guide you, save costs and a lot of valuable time. For the future ISM gives our customers a system that is flexible for and expendable.
  4. Lets take a look at how iSense works.
  5. Where have the amperometric systems been successful in industrial applications? I would like to group the applications after the background gases that are present in the gas mixture. In the first group, we have blanketing applications where the only other gas present in the gas mixture next to Oxygen is Nitrogen. In these applications, mainly storage and packaging, long term signal stability is key. Here, the important feature of the one-point air calibration is relevant. With only air necessary as calibration gas, the whole characteristic line of the sensor can be quickly verified, and with the AirCheck solution, this can be even done automatically. In the second group, we have Inertization applications, with may be flammable solvents in the background composition. There, safety is a key issue, and this is where the ATEX zone 0 and FM class 1 Div 1 hazardous area certifications are necessary. Both the InPro 6850i G and InPro 6900i G have these certification so centrifuge inertization with oxygen measurement directly in the centrifuge is possible In the third group, Background gas composition is changing with the process conditions. This can be the case in vent collect headers for example. In off-gas monitoring, process conditions are sometimes changing fast. For these applications, the high membrane selectivity and fast response time of the sensor is key.