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Lattice Energy LLC

  Growth of conductive metallic “tin whiskers” and random electrical shorting
events implicated in Toyota’s uncontrollable vehicle acceleration safety problems
   Whisker shorting issue analogous to metallic dendrite shorting events that can cause
LENRs which can then trigger super-hot, fast-burning metal oxidation fires in Li-ion batteries
 Other major difference from Li-ion batteries is frequency of occurrence: looks like potential
for LENR triggering is 1 out of every ~5 million cells (battery manufacturer estimate) vs. est.
  of 140 whisker-related shorting failures per 1 million (= 700 per 5 million) Toyota vehicles
       Note: micron-scale LENRs very likely do not often occur in Toyota whisker micro-arcs


References:

“Lattice Energy LLC - Could LENRs be involved in some Li-ion battery fires? LENRs in advanced
batteries”
Lewis Larsen, Lattice Energy LLC, July 16, 2010 [68 slides – not refereed]
Discusses possibility that LENRs may be occurring in some indeterminate subset of Li-ion battery fires
http://www.slideshare.net/lewisglarsen/cfakepathlattice-energy-llc-len-rs-in-liion-battery-firesjuly-16-2010

“Toyota's Sudden Acceleration Problem May Have Been Triggered By Tin Whiskers”
Sharon Carty, Reporter
Huffington Post - first Posted: 01/22/2012 7:07 pm Updated: 01/23/2012 5:26 pm
http://www.huffingtonpost.com/2012/01/21/toyota-sudden-acceleration-tin-whiskers_n_1221076.html

“Toyota accelerations revisited—hanging by a (tin) whisker”
Rick DeMeis, Editor of Automotive Designline
EE Times - News and Analysis 1/10/2012 8:39 AM EST
http://www.eetimes.com/electronics-news/4234309/Toyota-accelerations-revisited-hanging-by-a--tin--
whisker

“Electrical Failure of an Accelerator Pedal Position Sensor Caused by a Tin Whisker and Discussion of
Investigative Techniques Used for Whisker Detection”
H. Leidecker (NASA Goddard), L. Panashchenko (NASA Goddard), & J. Brusse (Dell Federal Govt Svcs)
September 14, 2011 NASA
http://nepp.nasa.gov/whisker/reference/tech_papers/2011-NASA-GSFC-whisker-failure-app-sensor.pdf

                                            Caught in the act!




 Image credit and source:
 above-cited NASA report                                                             Note electrical arc (spark)
      on Slide #17                                                                   emitted from the sharp tip
                                                                                         of the tin whisker




January 24, 2012                      Copyright 2012, All Rights reserved                              Page 1
Lattice Energy LLC

          Example of lithium metal dendrites growing in Li-ion battery electrolyte




               Source: Lawrence Berkeley National Laboratory, APS March 17, 2010




                    Example of zinc whiskers growing on top of substrate

January 24, 2012                 Copyright 2012, All Rights reserved                 Page 2

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Lattice Energy LLC- Tin Whisker Shorting Problems Analogous to Li-ion Batteries-Jan 24 2012

  • 1. Lattice Energy LLC Growth of conductive metallic “tin whiskers” and random electrical shorting events implicated in Toyota’s uncontrollable vehicle acceleration safety problems Whisker shorting issue analogous to metallic dendrite shorting events that can cause LENRs which can then trigger super-hot, fast-burning metal oxidation fires in Li-ion batteries Other major difference from Li-ion batteries is frequency of occurrence: looks like potential for LENR triggering is 1 out of every ~5 million cells (battery manufacturer estimate) vs. est. of 140 whisker-related shorting failures per 1 million (= 700 per 5 million) Toyota vehicles Note: micron-scale LENRs very likely do not often occur in Toyota whisker micro-arcs References: “Lattice Energy LLC - Could LENRs be involved in some Li-ion battery fires? LENRs in advanced batteries” Lewis Larsen, Lattice Energy LLC, July 16, 2010 [68 slides – not refereed] Discusses possibility that LENRs may be occurring in some indeterminate subset of Li-ion battery fires http://www.slideshare.net/lewisglarsen/cfakepathlattice-energy-llc-len-rs-in-liion-battery-firesjuly-16-2010 “Toyota's Sudden Acceleration Problem May Have Been Triggered By Tin Whiskers” Sharon Carty, Reporter Huffington Post - first Posted: 01/22/2012 7:07 pm Updated: 01/23/2012 5:26 pm http://www.huffingtonpost.com/2012/01/21/toyota-sudden-acceleration-tin-whiskers_n_1221076.html “Toyota accelerations revisited—hanging by a (tin) whisker” Rick DeMeis, Editor of Automotive Designline EE Times - News and Analysis 1/10/2012 8:39 AM EST http://www.eetimes.com/electronics-news/4234309/Toyota-accelerations-revisited-hanging-by-a--tin-- whisker “Electrical Failure of an Accelerator Pedal Position Sensor Caused by a Tin Whisker and Discussion of Investigative Techniques Used for Whisker Detection” H. Leidecker (NASA Goddard), L. Panashchenko (NASA Goddard), & J. Brusse (Dell Federal Govt Svcs) September 14, 2011 NASA http://nepp.nasa.gov/whisker/reference/tech_papers/2011-NASA-GSFC-whisker-failure-app-sensor.pdf Caught in the act! Image credit and source: above-cited NASA report Note electrical arc (spark) on Slide #17 emitted from the sharp tip of the tin whisker January 24, 2012 Copyright 2012, All Rights reserved Page 1
  • 2. Lattice Energy LLC Example of lithium metal dendrites growing in Li-ion battery electrolyte Source: Lawrence Berkeley National Laboratory, APS March 17, 2010 Example of zinc whiskers growing on top of substrate January 24, 2012 Copyright 2012, All Rights reserved Page 2