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THE ROLE OF STANDARDISATION IN
  THE FIELD OF BIODEGRADABLE
           MATERIALS

            Francesco Degli Innocenti
      Environmental and sustainability Affairs
              NOVAMONT S.p.A.
               fdi@novamont.com

 2nd Congress on Biodegradable Polymer Packaging
          Milan (Italy), 10-11 May 2012
                                                   1
Short historical notes
• The first discussion on the criteria for biodegradable
  plastics and packaging was developed by the Organic
  Reclamation and Composting Association (ORCA)1.
• Similar discussion and test activities were carried out in
  the USA, at the ASTM Institute for Standards Research,
  within the Degradable Polymers Research Program from
  1991 through 19962


•   1. The ORCA’s Guidelines for the evaluation of feedstock for source separated biowaste
    composting and biogasification (Lemmes, 1994).
•   2. “ASTM-ISR Degradable Polymeric Materials Program” (ASTM/ISR , 1996).

                                                                                         2
• The work was then developed and finalised
  by ASTM D20.96 and by CEN TC 261 SC4
  WG2 (packaging and the Environment)
• More recent is the ISO 17088
  Specifications for compostable plastics.



                                          3
The European legal framework in Europe
       in the field of packaging

• Directive 94/62/EC on packaging and
  packaging waste
• 20 December 1994
•   (Official Journal L 365 , 31/12/1994 p. 0010 – 0023)




                                                           4
• The European Directive      • The meaning of
  on Packaging and              “biodegradable” can be
  Packaging waste               very different in different
  94/62/EC had a very           contexts but, thanks to the
  important role because it     Directive, it is clear what
  clarified the meaning of      a “biodegradable
  “biodegradation”,             packaging” is.
  “organic recycling”,
  “composting” when
  applied to packaging.




                                                          5
• The question of biodegradability is complex and can give
  rise to significant debates. Key points are
• where (environment)
• how fast (time scale)
• how much (final level)
• At academic level even traditional ‘non-biodegradable’
  plastics can be shown to biodegrade, over a very long
  period of time.
• However, such biodegradation rates are clearly unsuited to
  the needs of society.




                                                             6
•   Biodegradable materials are an attempt to find solutions to a problem
    of our society: waste.
•   Waste is produced at a very high rate and therefore the disposal rate
    must be comparable, in order to avoid accumulation.


            Production rate  Waste  Disposal rate

•   Incineration is widely adopted precisely because it is a fast process.
    There would be no interest in a hypothetical ‘slow combustion’
    incinerator because waste does not wait, and quickly builds up.




                                                                             7
A Directive prepared following the ‘New
               Approach’

(1) It limits legislative harmonisation to
  approval of the essential requirements
  through Directives
(2) It delegates the task of drawing up the
  specific techniques to the competent
  industrial standardisation bodies.


                                              8
http://ec.europa.eu/enterprise/policies/single-market-goods/files/blue-guide/guidepublic_en.pdf




                                                                                         9
The “New Approach”




                Laws
Directives      Decrees


                   te
             Manda        EU          NATIONAL
                          NORMS       NORMS



                                  After P.Visintin - UNI
                                                       10
Article 9 of pkg Directive
          Essential requirements
1. Member States shall ensure that….
  packaging may be placed on the market
  only if it complies with all essential
  requirements defined by this Directive
  including Annex II.




                                           11
2. Member States shall, …presume compliance with
   all essential requirements … in the case of
   packaging which complies…. with the relevant
   harmonized standards, the reference numbers of
   which have been published in the Official Journal
   of the European Communities….




                                                  12
Article 10 of pkg Directive
               Standardization

The Commission shall promote, as
 appropriate, the preparation of European
 standards relating to the essential
 requirements referred to in Annex II.
                     ….



                                            13
Definition 9. “organic recycling”

• ‘organic recycling’ shall mean the aerobic
  (composting)          or          anaerobic
  (biomethanization)     treatment,    under
  controlled conditions and using micro-
  organisms, of the biodegradable parts of
  packaging waste, which produces stabilized
  organic residues or methane. Landfill shall
  not be considered a form of organic
  recycling;
                                           14
15
16
Harmonised packaging standards
• EN 13428:2005 – Packaging - Requirements Specific To
  Manufacturing And Composition - Prevention By Source
  Reduction
• EN 13429:2005 – Packaging - Reuse
• EN 13430:2005 – Packaging Requirements For Packaging
  Recoverable By Material Recycling
• EN 13431:2005 – Packaging - Requirements For
  Packaging Recoverable In The Form Of Energy Recovery,
  Including Specification Of Minimum Inferior Calorific
  Value
• EN 13432:2000 – Packaging. Requirements for packaging
  recoverable through composting and biodegradation. Test
  scheme and evaluation criteria for the final acceptance of
  packaging
                                                          17
Final point
• EN 13432:2000 published in the Official Journal
  of the European Communities1
• The standard EN 13432 has been used for 12 years
  and has proven to be reliable.
• Similar approach has been adopted by ISO



•   1
        L 190 12/07/2001 P.0021-0023




                                                18
Points that have been debated lately

• Q. EN 13432 does not consider “biodegradable
  packaging” that can degrade in the
  environment. This gap must be filled.
• R. A “biodegradable packaging” with
  properties different from the packaging that
  can be recovered through organic recycling
  (composting and anaerobic digestion) in
  compliance with the EN 13432 is not foreseen

                                             19
20
EN 13432:2000 – Packaging. Requirements for packaging
recoverable through composting and biodegradation. Test
scheme and evaluation criteria for the final acceptance of
                      packaging

• “Biodegradable” packaging is a packaging
  that can be recovered by means of organic
  recycling. Other forms of disposal are not
  defined by the Directive.
• Controlled landfills, unlicensed landfills or
  litter are not part of the European agenda
  that rules packaging.

                                                        21
Position of European Bioplastics

• The bioplastics industry is committed to organic
  recycling as a controlled and beneficial way of
  recovery. Disposal of packaging material in the
  environment is not a way of recovery of material –
  regardless of material properties.
• Encouraging any form of littering will add to the
  problem and further weaken the existing recovery
  streams (e.g. recycling and organic recovery).

                                                  22
• Q. Harmonised standards (such as EN 13432) are not
  obligatory and adherence is voluntary. May I use
  different standard specifications to show
  biodegradability?
• R. Yes, EN 13432 is not obligatory. Other industrial
  standard specifications are available worldwide and
  can be applied. However, they do not automatically
  provide presumption of conformity to the essential
  requirements. Economic operators thus have the
  obligation to prove that their products are in
  conformity with the mandatory legal requirements.

                                                         23
Other specifications about compostable
                  materials
ISO 17088 - Specifications for Compostable Plastics The ISO
   (International Organization for Standardization) has drawn up a
   standard which specifies the procedures and requirements for
   identifying and marking plastics and plastic products suitable for
   recovery by aerobic composting.
ASTM D6400 - Standard Specification for Compostable Plastics
   ASTM International is a very well known standardisation body,
   particularly in the United States. ASTM D 6400 was the first standard
   to specify the requirements of plastics and plastic products designed to
   be composted in municipal or industrial aerobic composting plants.
EN 14995 - Plastic materials - Assessment of compostability - Test
   and specification system It is not an alternative to EN 13432.
   Indeed, EN 13432 specifies the characteristics of packaging that can
   be recycled through organic recovery (composting and anaerobic
   digestion). EN 14995 covers compostable plastic materials not used as
   packaging
                                                                         24
Technical content of EN 13432




                                25
Criteria of the EN 13432

• Biodegradability
• Disintegrability
• Absence of ecotoxicological and negative
  effects




                                             26
Biodegradability
•   Organic carbon  CO2 + water
•   Test method: ISO 14855
•   Duration: 6 months
•   Level: 90%
                          100
                          90
                          80
                          70
       biodegradation %




                          60
                          50
                          40
                          30
                          20
                          10
                           0
                                0   1      2   3           4   5   6   7
                                               Time (months)
                                                                           27
• Q. the biodegradation rate is too fast, the final level is
  too high. Composting of plastics is a sort of “cold
  incineration” that does not produce any compost and
  release CO2, a GHG.

•   R. The laboratory approach, used to show inherent
    biodegradability, shall not be confused with behaviour on a real
    composting process.
•   Lab test conditions do not favour biomass but rather catabolic
    reactions
•   Real composting requires the mixing of different starting
    materials, in a "balanced” recipe. Fast, medium, slow
    biodegradable compounds are needed.
•   No composting expert would consider composting as a "cold
    incineration" of vegetable or fruit residues, only because they are
    the most biodegradable in the bio-waste mixture.
•   Bioplastics can be considered as a constituent of the mixture,
    similar in behaviour to cellulose.

                                                                      28
Disintegrability (EN 14045)




                              < 10%


                              >90%
                               29
• Q. Will products disintegrate efficiently in a
  composting cycle shorter than 3 months?
• R. Trials carried out by the ISR (ASTM/ISR , 1996)
  clearly showed that the disintegration test at pilot scale
  was conservative in comparison with the real
  composting process .
• Therefore, the fact that the testing period is 90 days
  does not imply that a compostable plastic will behave in
  a unsatisfactory way in a shorter cycle.
• The pilot scale is less aggressive than the full scale. In
  case of doubts a specific trial can be carried out.




                                                          30
• Biodegradability, bio-based content, carbon-footprint etc.
  cannot be noted directly by consumers. However, the
  commercial success of bioproducts rests precisely on
  claims of this kind.
• In order to guarantee market transparency, normative
  instruments are needed to link declarations, which are
  used as advertising messages, and the actual
  characteristics and benefits of the products.
                                                           31
• Many thanks for your attention…




                                    32

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THE ROLE OF STANDARDISATION IN THE FIELD OF BIODEGRADABLE MATERIALS

  • 1. THE ROLE OF STANDARDISATION IN THE FIELD OF BIODEGRADABLE MATERIALS Francesco Degli Innocenti Environmental and sustainability Affairs NOVAMONT S.p.A. fdi@novamont.com 2nd Congress on Biodegradable Polymer Packaging Milan (Italy), 10-11 May 2012 1
  • 2. Short historical notes • The first discussion on the criteria for biodegradable plastics and packaging was developed by the Organic Reclamation and Composting Association (ORCA)1. • Similar discussion and test activities were carried out in the USA, at the ASTM Institute for Standards Research, within the Degradable Polymers Research Program from 1991 through 19962 • 1. The ORCA’s Guidelines for the evaluation of feedstock for source separated biowaste composting and biogasification (Lemmes, 1994). • 2. “ASTM-ISR Degradable Polymeric Materials Program” (ASTM/ISR , 1996). 2
  • 3. • The work was then developed and finalised by ASTM D20.96 and by CEN TC 261 SC4 WG2 (packaging and the Environment) • More recent is the ISO 17088 Specifications for compostable plastics. 3
  • 4. The European legal framework in Europe in the field of packaging • Directive 94/62/EC on packaging and packaging waste • 20 December 1994 • (Official Journal L 365 , 31/12/1994 p. 0010 – 0023) 4
  • 5. • The European Directive • The meaning of on Packaging and “biodegradable” can be Packaging waste very different in different 94/62/EC had a very contexts but, thanks to the important role because it Directive, it is clear what clarified the meaning of a “biodegradable “biodegradation”, packaging” is. “organic recycling”, “composting” when applied to packaging. 5
  • 6. • The question of biodegradability is complex and can give rise to significant debates. Key points are • where (environment) • how fast (time scale) • how much (final level) • At academic level even traditional ‘non-biodegradable’ plastics can be shown to biodegrade, over a very long period of time. • However, such biodegradation rates are clearly unsuited to the needs of society. 6
  • 7. Biodegradable materials are an attempt to find solutions to a problem of our society: waste. • Waste is produced at a very high rate and therefore the disposal rate must be comparable, in order to avoid accumulation. Production rate  Waste  Disposal rate • Incineration is widely adopted precisely because it is a fast process. There would be no interest in a hypothetical ‘slow combustion’ incinerator because waste does not wait, and quickly builds up. 7
  • 8. A Directive prepared following the ‘New Approach’ (1) It limits legislative harmonisation to approval of the essential requirements through Directives (2) It delegates the task of drawing up the specific techniques to the competent industrial standardisation bodies. 8
  • 10. The “New Approach” Laws Directives Decrees te Manda EU NATIONAL NORMS NORMS After P.Visintin - UNI 10
  • 11. Article 9 of pkg Directive Essential requirements 1. Member States shall ensure that…. packaging may be placed on the market only if it complies with all essential requirements defined by this Directive including Annex II. 11
  • 12. 2. Member States shall, …presume compliance with all essential requirements … in the case of packaging which complies…. with the relevant harmonized standards, the reference numbers of which have been published in the Official Journal of the European Communities…. 12
  • 13. Article 10 of pkg Directive Standardization The Commission shall promote, as appropriate, the preparation of European standards relating to the essential requirements referred to in Annex II. …. 13
  • 14. Definition 9. “organic recycling” • ‘organic recycling’ shall mean the aerobic (composting) or anaerobic (biomethanization) treatment, under controlled conditions and using micro- organisms, of the biodegradable parts of packaging waste, which produces stabilized organic residues or methane. Landfill shall not be considered a form of organic recycling; 14
  • 15. 15
  • 16. 16
  • 17. Harmonised packaging standards • EN 13428:2005 – Packaging - Requirements Specific To Manufacturing And Composition - Prevention By Source Reduction • EN 13429:2005 – Packaging - Reuse • EN 13430:2005 – Packaging Requirements For Packaging Recoverable By Material Recycling • EN 13431:2005 – Packaging - Requirements For Packaging Recoverable In The Form Of Energy Recovery, Including Specification Of Minimum Inferior Calorific Value • EN 13432:2000 – Packaging. Requirements for packaging recoverable through composting and biodegradation. Test scheme and evaluation criteria for the final acceptance of packaging 17
  • 18. Final point • EN 13432:2000 published in the Official Journal of the European Communities1 • The standard EN 13432 has been used for 12 years and has proven to be reliable. • Similar approach has been adopted by ISO • 1 L 190 12/07/2001 P.0021-0023 18
  • 19. Points that have been debated lately • Q. EN 13432 does not consider “biodegradable packaging” that can degrade in the environment. This gap must be filled. • R. A “biodegradable packaging” with properties different from the packaging that can be recovered through organic recycling (composting and anaerobic digestion) in compliance with the EN 13432 is not foreseen 19
  • 20. 20
  • 21. EN 13432:2000 – Packaging. Requirements for packaging recoverable through composting and biodegradation. Test scheme and evaluation criteria for the final acceptance of packaging • “Biodegradable” packaging is a packaging that can be recovered by means of organic recycling. Other forms of disposal are not defined by the Directive. • Controlled landfills, unlicensed landfills or litter are not part of the European agenda that rules packaging. 21
  • 22. Position of European Bioplastics • The bioplastics industry is committed to organic recycling as a controlled and beneficial way of recovery. Disposal of packaging material in the environment is not a way of recovery of material – regardless of material properties. • Encouraging any form of littering will add to the problem and further weaken the existing recovery streams (e.g. recycling and organic recovery). 22
  • 23. • Q. Harmonised standards (such as EN 13432) are not obligatory and adherence is voluntary. May I use different standard specifications to show biodegradability? • R. Yes, EN 13432 is not obligatory. Other industrial standard specifications are available worldwide and can be applied. However, they do not automatically provide presumption of conformity to the essential requirements. Economic operators thus have the obligation to prove that their products are in conformity with the mandatory legal requirements. 23
  • 24. Other specifications about compostable materials ISO 17088 - Specifications for Compostable Plastics The ISO (International Organization for Standardization) has drawn up a standard which specifies the procedures and requirements for identifying and marking plastics and plastic products suitable for recovery by aerobic composting. ASTM D6400 - Standard Specification for Compostable Plastics ASTM International is a very well known standardisation body, particularly in the United States. ASTM D 6400 was the first standard to specify the requirements of plastics and plastic products designed to be composted in municipal or industrial aerobic composting plants. EN 14995 - Plastic materials - Assessment of compostability - Test and specification system It is not an alternative to EN 13432. Indeed, EN 13432 specifies the characteristics of packaging that can be recycled through organic recovery (composting and anaerobic digestion). EN 14995 covers compostable plastic materials not used as packaging 24
  • 25. Technical content of EN 13432 25
  • 26. Criteria of the EN 13432 • Biodegradability • Disintegrability • Absence of ecotoxicological and negative effects 26
  • 27. Biodegradability • Organic carbon  CO2 + water • Test method: ISO 14855 • Duration: 6 months • Level: 90% 100 90 80 70 biodegradation % 60 50 40 30 20 10 0 0 1 2 3 4 5 6 7 Time (months) 27
  • 28. • Q. the biodegradation rate is too fast, the final level is too high. Composting of plastics is a sort of “cold incineration” that does not produce any compost and release CO2, a GHG. • R. The laboratory approach, used to show inherent biodegradability, shall not be confused with behaviour on a real composting process. • Lab test conditions do not favour biomass but rather catabolic reactions • Real composting requires the mixing of different starting materials, in a "balanced” recipe. Fast, medium, slow biodegradable compounds are needed. • No composting expert would consider composting as a "cold incineration" of vegetable or fruit residues, only because they are the most biodegradable in the bio-waste mixture. • Bioplastics can be considered as a constituent of the mixture, similar in behaviour to cellulose. 28
  • 30. • Q. Will products disintegrate efficiently in a composting cycle shorter than 3 months? • R. Trials carried out by the ISR (ASTM/ISR , 1996) clearly showed that the disintegration test at pilot scale was conservative in comparison with the real composting process . • Therefore, the fact that the testing period is 90 days does not imply that a compostable plastic will behave in a unsatisfactory way in a shorter cycle. • The pilot scale is less aggressive than the full scale. In case of doubts a specific trial can be carried out. 30
  • 31. • Biodegradability, bio-based content, carbon-footprint etc. cannot be noted directly by consumers. However, the commercial success of bioproducts rests precisely on claims of this kind. • In order to guarantee market transparency, normative instruments are needed to link declarations, which are used as advertising messages, and the actual characteristics and benefits of the products. 31
  • 32. • Many thanks for your attention… 32