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PLUSS®
www.pluss.co.in
Synergism at work
PLUSS®
Recycling of Engineering Polymers-
Nylons/ PET&PBT/ PC
Kailash Pandey
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
Outline
About PLUSS®
Recycling Nylons
Recycling Polyesters
Recycling Polycarbonates
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
PLUSS®
Polymers …CONTINUED
A TECHNOLOGY DRIVEN COMPANY SPECIALIZING IN
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
WE
 Our Strengths:
 Indigenous “home grown” technologies
 Cost effectiveness
 Technology Providers:
 Thermal Energy Storage
 Polymer Technology
 We believe in:
 Consistent development
 Pragmatic development
…CONTINUED
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
…CONTINUED
 The Stakeholders
 Tata Capital Innovation fund
 Private Equity fund that has invested INR 15 crores.
 Promoters
 Founded by Mr. Devendra Jain and Mr. A.K. Mehta
 Employees
 A family of 70, and growing.
 Customers
 International
 Domestic
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
Achievements
1998: Grafted Polymers developed for the first time in India.
2000: Nylon Alloys - first time for the Cable Industry in India.
2003: Technology Day Award – Grafted Polymers.
2004: HDPE Profiles for the Telecom Industry.
2004: Successful development of Wood-Plastics Composites.
2005: Development of Phase Change Materials and encapsulation methods.
2006: BryAir–ISHRAE/ASHRAE Award for HS29 development.
2007: IIT-Delhi & DST, Govt. of India project on PCM use in textiles.
2008: Development of Ultra High MFI PP – first time in India
2010: Development of OPTIPET for Film Recycling
2012: Development of Polymers based Phase Change Materials
2012: TATA capital Innovation Fund invests INR 15 crores
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
Speciality Polymers- OPTIM®
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
Speciality Polymers- OPTIM®
And……
you can OPTIMise your recycled polymers
by using OPTIM®
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
Polymer Recycling
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
Engineering Polymers
MAJOR CLASSIFICATION*
* Scrap Generation wise
SOURCES OF SCRAP
1.NYLONS: film, fiber, automotive parts,
appliance housings, bearings, cable ties,
gear wheels, cam, slides etc.
2.POLYESTERS (PET&PBT): food
processor blades, vacuum cleaner parts,
fans, hair dryer housings, coffee makers,
switches, motor housings, fuse cases, key
caps for computer keyboards, connectors,
fiber optic buffer tubing etc.
3.POLYCARBONATES: computer parts,
connectors, etc., food processors,
refrigerator drawers, headlights, taillights,
instrument panels, etc.
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
Nylons
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
PROPERTIES OF IMPORTANCE
1. Good mechanical strength and rigidity.
Applications: Gear wheels for water meters,
slides, cams, bearings etc.
2. High impact strength and toughness.
Applications: Appliance housings etc.
Nylon Scrap
But NYLON SCRAP lacks these!
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
Use LLD based Additives for:
Improving impact properties.
Imparting desired toughness.
Compatibilizing foreign particulates like
mineral fillers and polymers like PE, PP etc.
E.g.: OPTIM®
E-126
Use Elastomer based Additives for:
Impact properties at sub zero temperatures.
Super toughness properties.
 Dispersion of both mineral fillers and glass
fillers in the polymer matrix.
E.g.: OPTIM®
E-131
Recycling Nylon scrap
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
 Most commonly used OPTIM®
Compatibilizing agents for Nylon Alloys
are OPTIM®
E-131 & E-126
Properties Unit Nylon 6 OPTIM®
E-131
5-15%
OPTIM®
E-126
2-10%
Tensile Strength MPa 80 53-70 60-70
Elongation @ Break % 50 40-120 150-250
Flexural Strength MPa 110 80-110 80-110
Notched Impact
Strength
J/m 55 90-850 100-500
Nylon Alloys
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
Polyesters (PET & PBT)
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
1. PET scrap lack sufficient mechanical strength
and impact properties.
Applications: head lamp reflectors and various
structural automotive components etc.
2. PBT scrap lacks desired abrasion resistance
and toughness.
Applications: electrical connectors, switches, key
caps for computer keyboards, motor housings
etc.
Polyester Scrap
So, PET/PBT scrap needs to be upgraded!
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
Using Additives such as
OPTIPET™ 213M
Improves impact properties.
Impart desired toughness.
Compatibilize foreign particulates like
mineral fillers and polymers like PE or PP
etc.
 Compatibilize PET/PBT scrap.
Recycling Polyester scrap
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
Polycarbonates
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
PROPERTIES OF IMPORTANCE
1. Good dimensional stability and superior
mechanical strength.
Applications: instrument panels, computer parts
etc.
2. High heat and impact resistance.
Applications: headlights, taillights, refrigerator
drawer etc.
Polycarbonate Scrap
But Polycarbonate scrap lacks these!
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
Use additives such as OPTIM®
GE-344
Improves impact properties.
Impart desired toughness.
Compatibilize foreign particulates like
mineral fillers and polymers like PE or PP
etc.
 Compatibilize PET/PBT scrap.
Recycling Polycarbonate scrap
PLUSS®
www.pluss.co.in
Factors Affecting Polymer Recycling
 Identification and Segregation of Polymer waste
 Shear Rate in the Compounding Machine used
 Temperature
 Composition of the mix
 Residence Time
 Additives Package
 Equipments & Conditions for Subsequent Processing
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
PLUSS®
in Recycling
 CONSULTANCY: Provides
solutions for recycling of
engineering polymers:
Nylons, PET/PBT, PC
 ADDITIVES: Provides
speciality polymers to
improve the properties of
polymer scrap.
 VALUE ADDITION:
Identifying applications and
uses for your polymer waste
PLUSS®
www.pluss.co.inPLUSS®
www.pluss.co.in
PLUSS®
in Recycling
Almost All Polymer Waste is Recyclable.
The bottleneck is proper collection and segregation
and
Professional Recycling Organizations need to be set up!
PLUSS®
www.pluss.co.in
SYNERGISM AT WORK
PLUSS®
and YOU
Kailash Pandey
kailash@pluss.co.in

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Recycling of engineering polymers

Editor's Notes

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