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by Steven S. Zumdahl   & Donald J. DeCoste University of Illinois Introductory Chemistry:  A Foundation, 6 th  Ed.  Introductory Chemistry, 6 th  Ed.  Basic Chemistry, 6 th  Ed.
Chapter 16 Acids and Bases
Properties of Acids ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Properties of Bases ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Bubbles (CO 2 ) NR Limestone CaCO 3 Bubbles (H 2 ) NR Magnesium Yellow Blue Bromothymol Stayed clear (cloudy) Clear  Pink  (Fuschia) Phenolphthalein Blue  Red Red  Blue Litmus (blue or red) <7 >7 pH (# from the key) Not slippery Slippery Feel (choose slippery or not slippery) Sour Bitter Taste Acids ( H +  + A - ) Bases (X +  +  OH - ) Lab Results
Mnemonic Device ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],pH = litmus
Arrhenius Theory ,[object Object],[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],Arrhenius Theory  (cont.)
Brønsted-Lowery Theory ,[object Object],[object Object],[object Object],[object Object]
Brønsted-Lowery Theory  (cont.) ,[object Object],[object Object],[object Object],[object Object],[object Object]
Complete the following table
Complete the following table Produces H+  ions in solution  Produces OH-  ions in solution  Proton donor Proton acceptor
Example #1: ,[object Object],[object Object],[object Object],Write the conjugate base for the acid H 3 PO 4
Brønsted-Lowery Theory  (cont.) ,[object Object],[object Object],[object Object],[object Object]
Brønsted-Lowery Theory  (cont.) ,[object Object],[object Object],[object Object]
Acids in Water
Identify the acid and base in the following reaction acid base Conjugate acid (hydronium ion) Conjugate base Conjugate acid-base pair Conjugate acid-base pair
Bases in Water acid base Conjugate acid (hydronium ion) Conjugate base Conjugate acid-base pair Conjugate acid-base pair
Identify the conjugate acid-base pairs ,[object Object],[object Object],[object Object],[object Object]
Identify the conjugate acid-base pairs ,[object Object],[object Object],[object Object],[object Object]
Complete the following tables
Complete the following tables NO 3 - H 2 O OH - H 2 SO 4 Br - OH - H 3 O + HCO 3 - HSO 4 - ClO 4 -
Strength of Acids & Bases ,[object Object]
Strength of Acids & Bases  (cont.) ,[object Object],[object Object],[object Object],[object Object]
Multiprotic Acids ,[object Object],[object Object],[object Object],[object Object],[object Object]
What new words describe H 2 SO 4 ?
What new words describe H 2 SO 4 ? ,[object Object],[object Object],[object Object],[object Object]
Water As an Acid and a Base ,[object Object],[object Object],[object Object],[object Object],[object Object]
Autoionization of Water ,[object Object],[object Object],[object Object]
* Acidic and Basic Solutions * ,[object Object],[object Object],[object Object],[object Object],[H + ] =  1 x 10 -14 [OH - ] [OH - ] =  1 x 10 -14 [H + ]
pH scale
Example #2 Determine the [H + ] and [OH - ] in a  10.0 M H +  solution
Example #2  (cont.) ,[object Object],[object Object]
[object Object],[object Object],Example #2  (cont.)
pH & pOH ,[object Object],[object Object],[object Object],[object Object]
pH & pOH  (cont.) ,[object Object],[object Object],[object Object],[object Object]
Example #3 Calculate the pH of a solution with a  [OH - ] = 1.0 x 10 -6  M
Example #3  (cont.) ,[object Object]
[object Object],[object Object],[object Object],[object Object],Example #3  (cont.)
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Example #4 Calculate the pH and pOH of a solution with a [OH - ] = 1.0 x 10 -3  M
[object Object],[object Object],Example #5 Calculate the [OH - ] of a solution with a pH of 7.41
Example #5  (cont.) ,[object Object],[object Object],[object Object],[object Object],[object Object]
Calculating the pH of a Strong, Monoprotic Acid ,[object Object],[object Object],[object Object],[object Object],[object Object]
Example #6 Calculate the pH of a 0.10 M HNO 3  solution. pH means – log of [H+] pH = - log [0.10] pH = - log [ 1 x 10 -1 ] pH = 1  note the exponent!
Example #6  (cont.) ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Practice Problems ,[object Object],[object Object],[object Object],[object Object],[object Object]
Practice Problems ,[object Object],[object Object],[object Object],[object Object],[object Object]
Practice Problems ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Practice Problems ,[object Object],[object Object],[object Object],[object Object],[object Object]
Practice Problems ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Practice Problems ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Challenge Questions ,[object Object],[object Object],[object Object]
Challenge Questions ,[object Object],[object Object],[object Object],[object Object]
Challenge Questions ,[object Object],[object Object],[object Object]
Challenge Questions ,[object Object],[object Object],[object Object],[object Object],[object Object]
Titration ,[object Object],[object Object],[object Object],[object Object]
Practice Problems ,[object Object],[object Object]
Buffered Solutions ,[object Object],[object Object],[object Object]
Buffered Solutions  (cont.) ,[object Object],[object Object],[object Object]
Challenge Question ,[object Object],[object Object],[object Object]

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Zum notes (09) acids and bases

  • 1. by Steven S. Zumdahl & Donald J. DeCoste University of Illinois Introductory Chemistry: A Foundation, 6 th Ed. Introductory Chemistry, 6 th Ed. Basic Chemistry, 6 th Ed.
  • 2. Chapter 16 Acids and Bases
  • 3.
  • 4.
  • 5. Bubbles (CO 2 ) NR Limestone CaCO 3 Bubbles (H 2 ) NR Magnesium Yellow Blue Bromothymol Stayed clear (cloudy) Clear  Pink (Fuschia) Phenolphthalein Blue  Red Red  Blue Litmus (blue or red) <7 >7 pH (# from the key) Not slippery Slippery Feel (choose slippery or not slippery) Sour Bitter Taste Acids ( H + + A - ) Bases (X + + OH - ) Lab Results
  • 6.
  • 7.
  • 8.
  • 9.
  • 10.
  • 12. Complete the following table Produces H+ ions in solution Produces OH- ions in solution Proton donor Proton acceptor
  • 13.
  • 14.
  • 15.
  • 17. Identify the acid and base in the following reaction acid base Conjugate acid (hydronium ion) Conjugate base Conjugate acid-base pair Conjugate acid-base pair
  • 18. Bases in Water acid base Conjugate acid (hydronium ion) Conjugate base Conjugate acid-base pair Conjugate acid-base pair
  • 19.
  • 20.
  • 22. Complete the following tables NO 3 - H 2 O OH - H 2 SO 4 Br - OH - H 3 O + HCO 3 - HSO 4 - ClO 4 -
  • 23.
  • 24.
  • 25.
  • 26. What new words describe H 2 SO 4 ?
  • 27.
  • 28.
  • 29.
  • 30.
  • 32. Example #2 Determine the [H + ] and [OH - ] in a 10.0 M H + solution
  • 33.
  • 34.
  • 35.
  • 36.
  • 37. Example #3 Calculate the pH of a solution with a [OH - ] = 1.0 x 10 -6 M
  • 38.
  • 39.
  • 40.
  • 41.
  • 42.
  • 43.
  • 44. Example #6 Calculate the pH of a 0.10 M HNO 3 solution. pH means – log of [H+] pH = - log [0.10] pH = - log [ 1 x 10 -1 ] pH = 1 note the exponent!
  • 45.
  • 46.
  • 47.
  • 48.
  • 49.
  • 50.
  • 51.
  • 52.
  • 53.
  • 54.
  • 55.
  • 56.
  • 57.
  • 58.
  • 59.
  • 60.

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