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Color and Albedo Heterogeneity of Vesta from Dawn
                               Vishnu Reddy et al.
                               Science 336, 700 (2012);
                               DOI: 10.1126/science.1219088




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Science (print ISSN 0036-8075; online ISSN 1095-9203) is published weekly, except the last week in December, by the
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2012 by the American Association for the Advancement of Science; all rights reserved. The title Science is a
registered trademark of AAAS.
REPORTS
      mass movements, often show associated spec-            evolutionary history, more similar to that of the                     15.   M. C. De Sanctis et al., Space Sci. Rev. (2010).
      tral differences. For example, the Oppia region’s      terrestrial planets than to other asteroids visited                   16.   C. T. Russell et al., Science 336, 684 (2012).
                                                                                                                                   17.   A. Coradini et al., Science 334, 492 (2011).
      surface exhibits variations in albedo and spec-        by spacecraft (17, 18). The occurrence of a greater                   18.   J. Veverka et al., Science 289, 2088 (2000).
      tral slope that indicate differences in surface ma-    proportion of diogenite at depth is a critical finding,               19.   R. G. Burns, Mineralogical Applications of Crystal Field
      terials (Fig. 4A). Moreover, the area around the       not demonstrated by data from the Hubble Space                              Theory (Cambridge Univ. Press, Cambridge, 1993).
      (Fig. 3) fresh Oppia crater (E) and the crater         Telescope or telescopic observations (30, 31),                        20.   L. A. McFadden, T. B. McCord, C. Pieters, Icarus 31, 439
                                                                                                                                         (1977).
      floor (F) have shallower BI depths (Fig. 4B),          and broadly consistent with magma ocean mod-                          21.   P. Schenk et al., Science 336, 694 (2012).
      revealing material poorer in pyroxene. The             els for Vesta’s differentiation. On the other hand,                   22.   R. Jaumann et al., Science 336, 687 (2012).
      cratering process here results in inverted stratig-    the fact that mixtures of diogenite and eucrite                       23.   S. Marchi et al., Science 336, 690 (2012).
      raphy of roughly the upper third of the target         appear ubiquitous in all regions, coupled with the                    24.   P. H. Warren, G. W. Kallemeyn, H. Huber, F. Ulff-Møller,
                                                                                                                                         W. Choe, Geochim. Cosmochim. Acta 73, 5918
      lithology in the ejecta blanket nearest the rim        occurrence of smaller-scale variations in mineralogy,                       (2009).
      [e.g., (29)]. The crater floor and material part-      make it premature to distinguish between a simple                     25.   L. Wilkening, D. Lal, A. M. Reid, Earth Planet. Sci. Lett.
      way up the walls have a reddish hue similar to         layered crust of eucrite and underlying dioge-                              10, 334 (1971).
      the ejecta just outside the rim, consistent with       nite (32) or a complex eucrite crust with                             26.   M. J. Gaffey, J. Geophys. Res. 81, 905 (1976).
                                                                                                                                   27.   L. E. Bowman, M. N. Spilde, J. J. Papike, Meteorit. Planet.
      the lower layers in this crater being composed         intruded diogenitic plutons (14). The Dawn mis-
                                                                                                                                         Sci. 32, 869 (1997).
      of rock poorer in pyroxene. The cyan color in-         sion provides the first spatially detailed view of                    28.   J. S. Delaney, M. Prinz, H. Takeda, J. Geophys. Res. 89,
      dicates that the soils just below the rim (H) have     the distribution of the rock types, allowing insight                        (suppl.), C251 (1984).
      stronger BI absorption and thus have higher            into the magmatic processes that formed the solar                     29.   H. J. Melosh, Impact Cratering: A Geologic Process
      pyroxene content or different grain size (Fig. 4C).    system’s “smallest planet.”                                                 (Oxford Univ. Press, Oxford, 1989).




                                                                                                                                                                                                       Downloaded from www.sciencemag.org on May 10, 2012
                                                                                                                                   30.   Telescopic data suggested a prominent diogenite region.
      The small crater (S) is surrounded by a halo of            References and Notes                                                    In the adopted coordinate system, this diogenite spot was
      bright and green materials, similar to the layer ex-    1. T. B. McCord, J. B. Adams, T. V. Johnson, Science 168,                  moved to the northern hemisphere, where VIR does not
      posed in Oppia (H), suggesting a similar compo-            1445 (1970).                                                            find this evidence.
      sition. VIR thus reveals that the Oppia impact          2. M. A. Feierberg, M. J. Drake, Science 209, 805 (1980).            31.   J. Y. Li et al., Icarus 208, 238 (2010).
                                                              3. G. J. Consolmagno, M. J. Drake, Geochim. Cosmochim.               32.   H. Takeda, Icarus 40, 455 (1979).
      exposed different kinds of materials, suggesting
                                                                 Acta 41, 1271 (1977).
      complex, small-scale crustal stratigraphy on Vesta.     4. M. J. Drake, In Asteroids, T. Gehrels, Ed. (Univ. Arizona         Acknowledgments: VIR is funded by the Italian Space Agency
          At all scales, pyroxene absorptions are the            Press, Tucson, AZ, 1979), pp. 765–782                             and was developed under the leadership of INAF-Istituto
      most prominent spectral features on Vesta and,          5. R. P. Binzel et al., Icarus 128, 95 (1997).                       di Astrofisica e Planetologia Spaziali, Rome, Italy. The
                                                              6. M. C. De Sanctis et al., Astron. Astrophys. 533, A77 (2011).      instrument was built by Selex-Galileo, Florence, Italy. The
      on average, the spectral parameters of Vesta re-                                                                             authors acknowledge the support of the Dawn Science,
                                                              7. N. A. Moscovitz et al., Icarus 208, 773 (2010).
      semble those of howardites (fig. S5). The VIR           8. M. C. De Sanctis et al., Mon. Not. R. Astron. Soc. 412,           Instrument, and Operations Teams. This work was supported
      spectra are thus consistent with a surface covered         2318 (2011).                                                      by the Italian Space Agency, and NASA’s Dawn at Vesta
      by a howardite-like regolith containing varying         9. K. Righter, M. J. Drake, Meteorit. Planet. Sci. 32, 929 (1997).   Participating Scientists Program. A portion of this work was
                                                             10. P. H. Warren, Meteorit. Planet. Sci. 32, 945 (1997).              performed at the Jet Propulsion Laboratory under contract
      proportions of eucrite and diogenite at different
                                                             11. R. C. Greenwood, I. A. Franchi, A. Jambon, P. C. Buchanan,        with NASA.
      locations. This firmly supports the link between           Nature 435, 916 (2005).
      Vesta and the HEDs, providing geologic context         12. D. W. Mittlefehldt et al., in Planetary Materials: Reviews        Supplementary Materials
                                                                                                                                   www.sciencemag.org/cgi/content/full/336/6082/697/DC1
      for these samples, which furthers our understand-          in Mineralogy 36, J. J. Papike, Ed. (Mineralogical
                                                                                                                                   Supplementary Text
      ing of the formation and evolution of Vesta.               Society of America, Chantilly, VA, 1998), pp. 4-1–4-195.
                                                             13. A. Beck, H. Y. McSween Jr., Meteorit. Planet. Sci. 45,            Figs. S1 to S5
          Furthermore, Vesta exhibits large color and            850 (2010).
                                                                                                                                   Table S1
      spectral variations that often reflect geological      14. J.-A. Barrat, A. Yamaguchi, B. Zanda, C. Bollinger,               17 January 2012; accepted 16 April 2012
      structures, indicating a complex geological and            M. Bohn, Geochim. Cosmochim. Acta 74, 6218 (2010).                10.1126/science.1219270




      Color and Albedo Heterogeneity                                                                                               1
                                                                                                                                    Max Planck Institute for Solar System Research, Max-Planck-
                                                                                                                                   Strasse 2, 37191 Katlenburg-Lindau, Germany. 2Department
                                                                                                                                   of Space Studies, University of North Dakota, Grand Forks, ND
      of Vesta from Dawn                                                                                                           58202, USA. 3Department of Astronomy, University of Mary-
                                                                                                                                   land, College Park, MD 20742, USA. 4Planetary Science
      Vishnu Reddy,1,2* Andreas Nathues,1 Lucille Le Corre,1 Holger Sierks,1 Jian-Yang Li,3                                        Institute, 1700 East Fort Lowell, Suite 106, Tucson, AZ 85719,
                                                                                                                                   USA. 5Department of Mineral Sciences, Smithsonian National
      Robert Gaskell,4 Timothy McCoy,5 Andrew W. Beck,5 Stefan E. Schröder,1 Carle M. Pieters,6                                    Museum of Natural History, 10th and Constitution NW,
      Kris J. Becker,7 Bonnie J. Buratti,8 Brett Denevi,9 David T. Blewett,9 Ulrich Christensen,1                                  Washington, DC 20560–0119, USA. 6Department of Geologi-
      Michael J. Gaffey,2 Pablo Gutierrez-Marques,1 Michael Hicks,8 Horst Uwe Keller,10                                            cal Sciences, Brown University, Providence, RI 02912, USA.
                                                                                                                                   7
      Thorsten Maue,1 Stefano Mottola,11 Lucy A. McFadden,12 Harry Y. McSween,13                                                    Astrogeology Science Center, U.S. Geological Survey, Flagstaff,
                                                                                                                                   AZ 86001, USA. 8Jet Propulsion Laboratory, California In-
      David Mittlefehldt,14 David P. O’Brien,4 Carol Raymond,8 Christopher Russell15                                               stitute of Technology, 4800 Oak Grove Drive, Pasadena, CA
                                                                                                                                   91109, USA. 9Johns Hopkins University Applied Physics
      Multispectral images (0.44 to 0.98 mm) of asteroid (4) Vesta obtained by the Dawn Framing Cameras                            Laboratory, Laurel, MD 20723, USA. 10Institut für Geophysik
      reveal global color variations that uncover and help understand the north-south hemispherical                                und extraterrestrische Physik, TU Braunschweig Mendelssohn-
      dichotomy. The signature of deep lithologies excavated during the formation of the Rheasilvia basin on                       strasse 3, DE 38106 Braunschweig, Germany. 11Deutsches
      the south pole has been preserved on the surface. Color variations (band depth, spectral slope, and                          Zentrum für Luft und Raumfahrt (DLR)–German Aerospace Center,
                                                                                                                                   Institute of Planetary Research, Rutherfordstrasse 2, D-12489
      eucrite-diogenite abundance) clearly correlate with distinct compositional units. Vesta displays the                         Berlin, Germany. 12NASA/Goddard Space Flight Center, Mail
      greatest variation of geometric albedo (0.10 to 0.67) of any asteroid yet observed. Four distinct color                      Code 160, Greenbelt, MD 20771, USA. 13Department of Earth
      units are recognized that chronicle processes—including impact excavation, mass wasting, and                                 and Planetary Sciences, University of Tennessee, 1412 Circle
      space weathering—that shaped the asteroid’s surface. Vesta’s color and photometric diversity are                             Drive, Knoxville, TN 37996–1410, USA. 14Astromaterials
                                                                                                                                   Research Office, NASA Johnson Space Center, Mail Code KR,
      indicative of its status as a preserved, differentiated protoplanet.                                                         Houston, TX 77058, USA. 15Institute of Geophysics and Plan-
                                                                                                                                   etary Physics, University of California Los Angeles, Los Angeles,
             he Dawn spacecraft rendezvoused with            in seven colors (0.44 to 0.98 mm) and one broad-

      T
                                                                                                                                   CA 90024–1567, USA.
             the asteroid Vesta on 16 July 2011, and the     band clear filter, mapping the entire sun-lit surface                 *To whom correspondence should be sent. E-mail: reddy@
             Framing Cameras (FCs) (1) acquired images       at a detail of ~9 to ~0.016 km/pixel. We used                         mps.mpg.de


700                                               11 MAY 2012          VOL 336           SCIENCE            www.sciencemag.org
REPORTS
these images to determine the global color               likely formed in the lower crust of the asteroid;    Lambertian disk, photometrically corrected to
characteristics and compositional heterogeneity          and howardites are physical mixtures (regolith)      standard viewing geometry (30° incidence and 0°
of the asteroid’s surface. The diversity of collected    of eucrites and diogenites formed by impact          emergence and 30° phase angles). This was
meteorites indicates that in the early solar system,     processes. Spectroscopic (4) and petrologic evi-     accomplished by using Hapke functions derived
the main asteroid belt held more than 100 large          dence (5) originally suggested a HED-Vesta link,     from disk-integrated ground-based telescopic
asteroids that were partially or totally melted but      and the 3:1 mean-motion resonance with Jupiter       observations of Vesta and Vestoids, as well as
subsequently destroyed by collisions (2). Today,         at 2.5 AU could provide a pathway for pieces         resolved data from the approach phase of the
Vesta is the only surviving silicate-rich differ-        ejected from Vesta to near-Earth space (6). This     mission (8). A fit of the Dawn survey data in the
entiated object (3). Two major goals of the Dawn         connection was further solidified by the detection   wideband clear filter to Hapke’s model yields fits
mission are to help answer why Vesta is the only         of the “Vestoids,” a group of smaller (<10 km)       to the Hapke parameters of 0.52 for the single
remaining member of this class and to use its            asteroids that are spectrally similar to Vesta and   scattering albedo (SSA), –0.29 for the back-
history to understand terrestrial planet formation.      span the orbital region between Vesta and the 3:1    scattering parameter (confirming that Vesta’s
    Vesta is the likely parent body of the howardite-    resonance (7).                                       surface is backscattering as other asteroids are),
eucrite-diogenite (HED) meteorites. Eucrites are             We converted the FC images to reflectance        and 20° for the mean slope angle defining mac-
crustal basalts, petrologically similar to terrestrial   (I/F ) by dividing the observed radiance by the      roscopic roughness. For each color acquisition,
basalts; diogenites are ultramafic cumulates,            solar irradiance from a normally solar-illuminated   subpixel coregistration was accomplished to

Fig. 1. Color mosaics of
Vesta obtained during the




                                                                                                                                                                         Downloaded from www.sciencemag.org on May 10, 2012
approach phase (~480 m/
pixel) in simple cylindrical
projection. (A) Photometrical-
ly corrected 0.75-mm filter
global mosaic showing east-
west and north-south dichoto-
mies in reflectance. (B) Clemen-
tine color ratios mosaic using
CR = R(0.75)/R(0.45), CG =
R(0.75)/R(0.92), and C B =
R(0.45)/R(0.75), where R(l)
is the reflectance in a filter
centered at l(micrometer) and
CR, CG, CB are the colors red,
green, and blue, respectively.
Greener areas have deeper
bands, and redder areas have
steeper visible slopes relative
to bluer areas. (C) Rainbow-color
coded map of R(0.75)/R(0.92)
ratio (proxy for 0.90-mm py-
roxene band depth) showing
areas with deeper bands as
red. (D) Rainbow-color coded
map of R(0.98)/R(0.92) ratio
(Eucrite-Diogenite) showing
diogenite-rich regions as red and
eucrite-rich regions as blue
(8). (E) Color-shaded topo-
graphic map of Vesta with
white corresponding to the
highest elevation and blue the
lowest. Minimum and maxi-
mum elevations are computed
relative to a 285- × 229-km
reference ellipsoid. All maps are
based on the new Claudia co-
ordinate system, which is dif-
ferent from the older Olbers
system used with the Hubble
Space Telescope data. Olbers
reference longitude is located
approximately at 210°E in the
Claudia system.




                                             www.sciencemag.org           SCIENCE       VOL 336      11 MAY 2012                                                   701
REPORTS
      align the seven color frames in order to create          1D). We further confirmed the compositional            Rheasilvia Formation at the south pole also has
      color cubes before analysis.                             identification of specific color units with labora-    higher albedo as compared with that of the north-
          Global maps show variations in 0.75-mm               tory spectra of HED meteorites using several           ern hemisphere (Fig. 2, A and B). In addition,
      albedo (Fig. 1A) and the 0.90-mm pyroxene                spectral criteria (10).                                two distinct lower albedo units are associated
      absorption depth R(0.75)/R(0.92) (Fig. 1C). The              The maps (Fig. 1, A to E) reveal a hemi-           with the ejecta of the Marcia (10°N, 190°) and
      ratio R(0.98)/R(0.92) qualitatively identifies           spherical scale dichotomy on Vesta. The brightest      Oppia (8°S, 309°) impact craters.
      eucrite- and diogenite-rich terrains (Fig. 1D). All of   point (in clear filter) is on a crater wall near the       This dichotomy reflects both Vesta’s com-
      these features show a weak relation to topogra-          south pole that has a SSA of ~0.82 and a geo-          position and regolith processes. Abundance of maf-
      phy (Fig. 1E). A false color composite quantifies        metric albedo of ~0.67; the darkest area has a         ic minerals (iron abundance), space weathering,
      band depth and visible slope (Fig. 1B). Because          SSA of ~0.15 and a geometric albedo of only            grain size, and presence of opaque minerals are
      eucrites have more ferroan pyroxene than                 ~0.10. This range is much higher than is seen in       known to affect the R(0.75)/R(0.92) ratio (8).
      diogenites (fig. S1), their 0.90-mm pyroxene band        other asteroids (8). The global albedo map also        Laboratory study of HED meteorites suggests
      is shifted toward longer wavelength (fig. S2)            exhibits an overall lower reflectance in the           that grain size is a major cause for band depth
      (8, 9), causing the R(0.98)/R(0.92) to be closer         eastern hemisphere as compared with the western        dichotomy (8). Unlike the Moon, where the
      to 1 for eucrites but higher for diogenites (Fig.        (3, 11). The area located between 30°S and the         highland units have higher albedo as compared
                                                                                                                      with those of lower and darker mare, Vesta does
                                                                                                                      not seem to have distinct global correlation be-
                                                                                                                      tween topography and albedo or color.
                                                                                                                          Along with global color dichotomy, we have




                                                                                                                                                                             Downloaded from www.sciencemag.org on May 10, 2012
                                                                                                                      identified various terrains on Vesta that are fur-
                                                                                                                      ther evidence for surface heterogeneity. We have
                                                                                                                      classified these areas as bright, dark, gray, and
                                                                                                                      orange terrains (Fig. 3, A to H). Fresh impact
                                                                                                                      craters have higher reflectance (30 to 40% in the
                                                                                                                      0.75-mm filter) than that of background surface
                                                                                                                      and are associated with bright terrains (such as
                                                                                                                      the Canuleia crater) (Fig. 3, A and B). They also
                                                                                                                      have deeper 0.90-mm pyroxene absorption band.
                                                                                                                      In the south, several fresh craters appear redder in
                                                                                                                      the eucrite/diogenite (ED) ratio maps, suggesting
                                                                                                                      that diogenite-rich material was excavated within
                                                                                                                      Rheasilvia. By comparing the color spectra of
                                                                                                                      bright material with global average, we find that
                                                                                                                      the R(0.75)/R(0.92) ratio is 16% deeper, and the
      Fig. 2. Stereographic projection centered on the south pole of (A) the color mosaic in Clementine color         visible spectral slope (0.45 to 0.55 mm) is also
      ratios overlaid on a shaded-relief map and of (B) the color-shaded topographic map.                             steeper (Fig. 4, A and B).




      Fig. 3. Examples of diverse color terrains on Vesta in 0.75-mm filter (left) and    Numisia crater located at 7°S, 247°E. (E and F) Gray ejecta blanket of the
      Clementine ratio (right). (A and B) Bright ejecta around the 11.2-km diameter       58-km diameter Marcia crater (top left) located at 10°N, 190°E. (G and H)
      fresh impact crater Canuleia located at 33.7°S, 294.5°E. (C and D) Dark             The 34-km diameter impact crater Oppia located at 8°S, 309°E, with orange
      material on the crater wall and in the surroundings of the 30-km diameter           ejecta blanket.


702                                                11 MAY 2012         VOL 336       SCIENCE        www.sciencemag.org
REPORTS
    Dark material is commonly associated with         slope (redder in Clementine ratios) and a weak          rim. The eastern portion, between ~0 and 130°E,
impact craters (such as the Numisia crater) (Fig.     R(0.75)/R(0.92) ratio; thus, it has a shallower         has higher concentrations of high-band-ratio ma-
3, C and D), but dark deposits are also seen          0.90-mm pyroxene band as compared with the              terial than the western portion (210 to 300°E),
elsewhere in >25 locations. In some cases—            global mean spectrum (Fig. 4, A and B). Several         which is consistent with the western portion con-
Lucaria Tholus—dark material is associated with       lighter “orange patches” are also observed to the       taining relatively more eucritic material. The ori-
a topographic high. In addition, several fresh        west and north around Oppia (Fig. 3, G and H).          gin of this variation is not immediately clear. Given
impact craters exhibit excavation of bright and           Band depth and ED maps (Fig. 1, C and D)            that the western portion of the rim is topograph-
dark material within the crater walls and ejecta      show that areas with deeper R(0.75)/R(0.92)             ically higher (Figs. 1E and 2B), we would expect
blankets (Fig. 3, C and D). They have lower           ratios also tend to have higher R(0.98)/R(0.92)         it to contain higher concentrations of diogenite
reflectance (8 to 13% at 0.75 mm), weaker band        ratios (8). This correlation suggests that diogenite-   material (ejecta), which it does not. This may
depth (Fig. 4, A and B) and have a redder visible     rich material has a deeper R(0.75)/R(0.92) ratio        be an indication that the western portion of the
spectral slope. Either the excavation of a darker     as compared with that of eucrite-rich material.         Rheasilvia ejecta rim sampled previously re-
subsurface layer or the incorporation of dark         Terrains with higher ratios surround Rheasilvia         worked lithologies, which may be linked to the
material by an impactor could explain the             basin in the south, whereas Vesta has lower ra-         large pre-Rheasilvia basin impact (14).
observed morphology of these units. The dark          tios in the north (Fig. 1, C and D). The observed           Two localized concentrations of the highest
material on Vesta may indicate the presence of        variance is consistent with diogenite-rich terrains     R(0.75)/R(0.92) and R(0.98)/R(0.92) ratio material
impact melts and exogenous carbonaceous ma-           (red) in the south and more eucritic terrains (blue)    occur in areas associated with Rheasilvia (Figs. 1,
terial (8), both of which are seen in the HED         in the north, which is in agreement with Visible        C to E, and 2, A and B). The first (43 to 55°S,
meteorites.                                           and Infrared Imaging Spectrometer observations          51 to 87°E) coincides with a large scarp face,




                                                                                                                                                                            Downloaded from www.sciencemag.org on May 10, 2012
    Most of the surface of Vesta is covered with      (12). This north-south dichotomy is disrupted by        possibly indicating diogenite-rich material ex-
gray material (0.75-mm reflectance, ~15 to 30%).      a swath (~0 to 90°E) of relatively higher R(0.75)/      posed along the rim and wall of the basin, and
This material has a moderate R(0.75)/R(0.92)          R(0.92) and R(0.98)/R(0.92) ratio material that         deposited nearby in the ejecta material. The
ratio (Fig. 4, A and B). In craters, downslope        protrudes to the northern extent of Dawn’s ob-          second location (53 to 64°S, 180 to 230°E) is at
movements have unveiled underlying bright ma-         servations (Fig. 1, C and D). This swath is             a topographical low in the Rheasilvia basin
terial. Hence, gray material could correspond to a    probably impact ejecta from the Rheasilvia              floor and corresponds to the Antonia crater and
mixture of bright and dark material or space-         forming event because it is topographically higher      its associated ejecta. Given the likely depth of
weathered bright material. Space weathering           than adjacent terrains (Fig. 1E) and has similar        excavation and the high-band-ratio signature,
affects optical properties of the regolith of plan-   R(0.75)/R(0.92) and R(0.98)/R(0.92) ratios to           this material may be an in situ diogenitic lithol-
etary bodies without an atmosphere. A second          Rheasilvia material (Fig. 1, C and D). Also, me-        ogy that has been exposed by the Rheasilvia
type of gray material is associated with ejecta       teoritical evidence suggests that diogenitic mate-      impact event.
blankets around large impact craters such as the      rial probably formed deep beneath the surface of            In a magma ocean model, a single, deep-
Marcia crater (Fig. 3, E and F) and is possibly       Vesta (13). The central peak of the Rheasilvia          seated layer of diogenitic material is expected
impact melt. This gray material has a 0.75-mm         basin has a strong R(0.75)/R(0.92) ratio (Fig. 2A),     (15), and if this region in the Rheasilvia basin is
reflectance of ~15%, a shallow visible slope, and     implying that it is dominated by material with a        the only region with in situ diogenite material
the second weakest R(0.75)/R(0.92) ratio (Fig. 4,     strong 0.90-mm pyroxene band (diogenite-rich).          identified on Vesta, a magma ocean model may
A and B).                                                 The high rim of Rheasilvia (Figs. 1, C and D,       be favored. Our analyses show that Vesta was
    The Oppia crater displays asymmetric orange       and 2, A and B) is dominated by high R(0.75)/R(0.92)    large enough to accrete material and differentiate
ejecta in the Clementine ratio map (Fig. 3, G and     and R(0.98)/R(0.92) ratio material, which is con-       during the first few million years of Solar System
H) that is spread toward the southeast. The           sistent with diogenite-rich rocks that have been        formation. Although battered by multiple impacts,
morphology of Oppia could be explained by             excavated from depth and deposited as ejecta.           Vesta remains intact today probably because of
an oblique impact or an impact on a slope.            However, the abundance of deeper-band material          its differentiated internal structure. These cata-
This particular unit has a steep visible spectral     is not homogeneous along the entire Rheasilvia          strophic events have not only excavated deeper




Fig. 4. (A) Color spectra of bright (green), dark (black), gray (gray) and        gray, and orange terrains have weaker R(0.75)/R(0.92) ratios, whereas
orange terrains (orange) on Vesta. The red spectrum corresponds to the            bright material has deeper ratio as compared with the global average. The
global average spectrum of Vesta. Errors shown are 1s. (B) Ratios of the          orange ejecta exhibits the steepest visible slope with respect to global
same color spectra divided by the global average spectrum (red). Dark,            average.


                                           www.sciencemag.org           SCIENCE        VOL 336       11 MAY 2012                                                      703
REPORTS
      compositional units but also delivered exogenous                      7. R. P. Binzel, S. Xu, Science 260, 186 (1993).               financially supported by the Max Planck Society and the
      carbon-rich material to Vesta, a key ingredient for                   8. Materials and methods are available as supplementary        German Space Agency, DLR. We also thank the Dawn at Vesta
                                                                               materials on Science Online.                                Participating Scientist Program for funding the research.
      the formation and evolution of life on Earth.                         9. M. J. Gaffey, J. Geophys. Res. 81, 905 (1976).              A portion of this work was performed at the Jet Propulsion
                                                                           10. L. Le Corre, V. Reddy, A. Nathues, E. A. Cloutis, Icarus    Laboratory, California Institute of Technology, under contract
           References and Notes                                                216, 376 (2011).                                            with NASA. Dawn data are archived with the NASA Planetary
        1. H. Sierks et al., Space Sci. Rev. 163, 263 (2011).              11. J.-Y. Li et al., Icarus 208, 238 (2010).                    Data System.
        2. K. Keil, in Asteroid III, William F. Bottke, Alberto Cellino,   12. M. C. De Sanctis et al., Science 336, 697 (2012).
           Paolo Paolicchi, Richard P. Binzel, Eds. (Univ. of Arizona      13. D. W. Mittlefehldt et al., Planet. Mat. 36, 4-1 (1998).
           Press, Tucson, 2002), pp. 573–584.                              14. P. Schenk et al., Science 336, 694 (2012).
                                                                                                                                           Supplementary Materials
                                                                           15. A. Ruzicka, G. A. Snyder, Meteor. Planet. Sci. 32, 825      www.sciencemag.org/cgi/content/full/336/6082/700/DC1
        3. P. C. Thomas et al., Icarus 128, 88 (1997).
                                                                                                                                           Materials and Methods
        4. T. B. McCord, J. B. Adams, T. V. Johnson, Science 168,              (1997).
                                                                                                                                           Figs. S1 and S2
           1445 (1970).
                                                                           Acknowledgments: We thank the Dawn team for the                 References (16–31)
        5. G. J. Consolmagno, M. J. Drake, Geochim. Cosmochim.
           Acta 41, 1271 (1977).                                           development, cruise, orbital insertion, and operations of the   13 January 2012; accepted 13 April 2012
        6. J. Wisdom, Nature 315, 731 (1985).                              Dawn spacecraft at Vesta. The Framing Camera project is         10.1126/science.1219088



                                                                                                                                           pole moment oriented randomly in the QW
      Coupling Quantum Tunneling                                                                                                           plane. The indirect exciton jIX 〉 has the hole in
                                                                                                                                           the left QW and the electron in the right QW—
      with Cavity Photons                                                                                                                  thus possessing an additional static dipole mo-




                                                                                                                                                                                                            Downloaded from www.sciencemag.org on May 10, 2012
                                                                                                                                           ment aligned perpendicularly to the plane—and
                                                                                                                                           has a very small overlap of electron and hole wave
      Peter Cristofolini,1 Gabriel Christmann,1 Simeon I. Tsintzos,1,2 George Deligeorgis,2*                                               functions, hence low oscillator strength. When a
      George Konstantinidis,2 Zacharias Hatzopoulos,2 Pavlos G. Savvidis,2,3 Jeremy J. Baumberg1†                                          bias voltage is applied to bring the electron levels
                                                                                                                                           into resonance, the electron states in the two QWs
      Tunneling of electrons through a potential barrier is fundamental to chemical reactions, electronic                                  mix to give symmetric and antisymmetric elec-
      transport in semiconductors and superconductors, magnetism, and devices such as terahertz oscillators.                               tron wave functions (red in Fig. 1A), which, to-
      Whereas tunneling is typically controlled by electric fields, a completely different approach is to bind                             gether with the low-energy hole states (blue)
      electrons into bosonic quasiparticles with a photonic component. Quasiparticles made of such light-matter                            in pffiffiffi left QW, produce the exciton modes
                                                                                                                                               the
      microcavity polaritons have recently been demonstrated to Bose-condense into superfluids, whereas                                    ð1= 2ÞfjIX 〉 T jDX 〉g, split by the tunneling
      spatially separated Coulomb-bound electrons and holes possess strong dipole interactions. We use                                     energy ħJ (where ħ is Planck’s constant divided
      tunneling polaritons to connect these two realms, producing bosonic quasiparticles with static dipole                                by 2p). These modes combine the large os-
      moments. Our resulting three-state system yields dark polaritons analogous to those in atomic systems or                             cillator strength of the DX with the large static
      optical waveguides, thereby offering new possibilities for electromagnetically induced transparency,                                 dipole moment of the IX (Fig. 1B, bottom).
      room-temperature condensation, and adiabatic photon-to-electron transfer.                                                                Embedding DX and IX excitons in the mi-
                                                                                                                                           crocavity with cavity mode C now forms a
             trong coupling of photons to the interband                    ficient in-plane electrostatic traps (9, 10) and the            three-state system similar to the atomic L-scheme

      S      exciton transition in a semiconductor mi-
             crocavity leads to the formation of polar-
      itons, bosonic quasiparticles whose properties are
                                                                           coherent control of electron spins (11). By em-
                                                                           bedding double quantum wells inside a conven-
                                                                           tional microcavity in the strong coupling regime,
                                                                                                                                           (14, 15), which is coupled optically by the vac-
                                                                                                                                           uum Rabi frequency W and electronically by the
                                                                                                                                           electron tunneling rate J (Fig. 1C). Although J
      governed by their mixed light-matter composi-                        we unite the concepts of indirect excitons and                  and W are intrinsic to the microcavity design,
      tion. Owing to their quantum indistinguishability                    microcavity polaritons to produce optically active              full control of the dipolariton modes is possible
      and the interplay of their Coulomb interactions,                     quasiparticles with transport properties, named                 through bias voltage control of tunneling and
      microcavity polaritons show unusually strong                         dipolaritons. These offer the advantages of both                angle tuning of the cavity mode. In the strong
      light-matter interactions and many-body quan-                        systems: electrical trapping and tuning of ex-                  coupling regime, when J is larger than the carrier
      tum effects. In particular, their small effective mass               citons, strong optical coupling to low-mass quasi-              escape rate from the coupled QWs and W is faster
      allows observation of quantum degeneracy ef-                         particles with large de Broglie wavelength, and                 than the photon decay rate, the system displays
      fects at temperatures from 10 to 300 K, such as                      excellent control over the dipole properties and                three distinct eigenmodes: the lower (LP), middle
      Bose condensation (1–4) and superfluidity flow                       interactions (12, 13).                                          (MP), and upper (UP) dipolaritons. Thus, a con-
      dynamics (5), and their tunable interactions make                        Microcavities are formed from p-i-n semi-                   ventional microcavity polariton (Fig. 1D, black)
      them ideal candidates for future quantum opto-                       conductor multilayers surrounded by doped                       can be simply bias-tuned to yield the dipolariton
      electronic devices (6) working at room temper-                       multilayer mirrors (7) (Fig. 1A; details in the sup-            spectrum (red) in the strong tunneling regime.
      ature (7). By contrast, spatially separating the                     porting online material) and pumped with a non-                     The bias dependence of the photolumines-
      electrons and holes in coupled double quantum                        resonant laser. Quantum wells (QWs) of InGaAs                   cence (PL) of a mesa with barrier width LB =
      wells yields indirect excitons with sufficiently                     inside the cavity are arranged in asymmetric pairs              4 nm (Fig. 2) clearly reveals these three dipolar-
      long lifetimes for thermalization and a large static                 separated by a thin barrier (of width LB) that                  iton modes. Because in-plane wave vectors k are
      dipole moment (8). These properties enable ef-                       allows electrons to tunnel between the two wells                conserved, photons emitted at an angle q directly
                                                                           (Fig. 1A). Because of the large effective hole mass             measure dipolaritons at k. At normal incidence
      1
        NanoPhotonics Centre, Cavendish Laboratory, University of          and the wide energy separation of hole levels in                (Fig. 2, A and C) the narrow cavity mode is de-
      Cambridge, Cambridge CB3 0HE, UK. 2FORTH‑IESL, Post Office           neighboring QWs, hole tunneling is negligible,                  tuned below the excitons, whereas at 35° (Fig. 2,
      Box 1527, 71110 Heraklion, Crete, Greece. 3Department of Ma-         and only the low-energy left QW (LQW) hole                      B and D) the uncoupled modes are all degen-
      terials Science and Technology, University of Crete, Post Office     state is considered. Without tunneling, there are               erate. For higher electric fields, the PL emission
      Box 2208, 71003 Heraklion, Greece.
                                                                           two types of exciton in this system. The direct                 weakens because electrons escape the coupled
      *Present address: CNRS, LAAS, 7 avenue de Colonel Roche,
      F-31077 Toulouse Cedex 4, France.
                                                                           exciton jDX 〉 has both electron and hole in the                 QW system before they can recombine radia-
      †To whom correspondence should be addressed. E-mail:                 left QW (Fig. 1B, top) and therefore strongly                   tively with a left QW hole, and eventually two of
      jjb12@cam.ac.uk                                                      couples to the cavity mode, with its induced di-                the modes vanish, leaving only the most cavity-


704                                                          11 MAY 2012            VOL 336          SCIENCE           www.sciencemag.org

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Vesta's Color and Albedo from Dawn Mission

  • 1. Color and Albedo Heterogeneity of Vesta from Dawn Vishnu Reddy et al. Science 336, 700 (2012); DOI: 10.1126/science.1219088 This copy is for your personal, non-commercial use only. If you wish to distribute this article to others, you can order high-quality copies for your colleagues, clients, or customers by clicking here. Downloaded from www.sciencemag.org on May 10, 2012 Permission to republish or repurpose articles or portions of articles can be obtained by following the guidelines here. The following resources related to this article are available online at www.sciencemag.org (this information is current as of May 10, 2012 ): Updated information and services, including high-resolution figures, can be found in the online version of this article at: http://www.sciencemag.org/content/336/6082/700.full.html Supporting Online Material can be found at: http://www.sciencemag.org/content/suppl/2012/05/09/336.6082.700.DC1.html A list of selected additional articles on the Science Web sites related to this article can be found at: http://www.sciencemag.org/content/336/6082/700.full.html#related This article cites 26 articles, 6 of which can be accessed free: http://www.sciencemag.org/content/336/6082/700.full.html#ref-list-1 This article has been cited by 2 articles hosted by HighWire Press; see: http://www.sciencemag.org/content/336/6082/700.full.html#related-urls This article appears in the following subject collections: Planetary Science http://www.sciencemag.org/cgi/collection/planet_sci Science (print ISSN 0036-8075; online ISSN 1095-9203) is published weekly, except the last week in December, by the American Association for the Advancement of Science, 1200 New York Avenue NW, Washington, DC 20005. Copyright 2012 by the American Association for the Advancement of Science; all rights reserved. The title Science is a registered trademark of AAAS.
  • 2. REPORTS mass movements, often show associated spec- evolutionary history, more similar to that of the 15. M. C. De Sanctis et al., Space Sci. Rev. (2010). tral differences. For example, the Oppia region’s terrestrial planets than to other asteroids visited 16. C. T. Russell et al., Science 336, 684 (2012). 17. A. Coradini et al., Science 334, 492 (2011). surface exhibits variations in albedo and spec- by spacecraft (17, 18). The occurrence of a greater 18. J. Veverka et al., Science 289, 2088 (2000). tral slope that indicate differences in surface ma- proportion of diogenite at depth is a critical finding, 19. R. G. Burns, Mineralogical Applications of Crystal Field terials (Fig. 4A). Moreover, the area around the not demonstrated by data from the Hubble Space Theory (Cambridge Univ. Press, Cambridge, 1993). (Fig. 3) fresh Oppia crater (E) and the crater Telescope or telescopic observations (30, 31), 20. L. A. McFadden, T. B. McCord, C. Pieters, Icarus 31, 439 (1977). floor (F) have shallower BI depths (Fig. 4B), and broadly consistent with magma ocean mod- 21. P. Schenk et al., Science 336, 694 (2012). revealing material poorer in pyroxene. The els for Vesta’s differentiation. On the other hand, 22. R. Jaumann et al., Science 336, 687 (2012). cratering process here results in inverted stratig- the fact that mixtures of diogenite and eucrite 23. S. Marchi et al., Science 336, 690 (2012). raphy of roughly the upper third of the target appear ubiquitous in all regions, coupled with the 24. P. H. Warren, G. W. Kallemeyn, H. Huber, F. Ulff-Møller, W. Choe, Geochim. Cosmochim. Acta 73, 5918 lithology in the ejecta blanket nearest the rim occurrence of smaller-scale variations in mineralogy, (2009). [e.g., (29)]. The crater floor and material part- make it premature to distinguish between a simple 25. L. Wilkening, D. Lal, A. M. Reid, Earth Planet. Sci. Lett. way up the walls have a reddish hue similar to layered crust of eucrite and underlying dioge- 10, 334 (1971). the ejecta just outside the rim, consistent with nite (32) or a complex eucrite crust with 26. M. J. Gaffey, J. Geophys. Res. 81, 905 (1976). 27. L. E. Bowman, M. N. Spilde, J. J. Papike, Meteorit. Planet. the lower layers in this crater being composed intruded diogenitic plutons (14). The Dawn mis- Sci. 32, 869 (1997). of rock poorer in pyroxene. The cyan color in- sion provides the first spatially detailed view of 28. J. S. Delaney, M. Prinz, H. Takeda, J. Geophys. Res. 89, dicates that the soils just below the rim (H) have the distribution of the rock types, allowing insight (suppl.), C251 (1984). stronger BI absorption and thus have higher into the magmatic processes that formed the solar 29. H. J. Melosh, Impact Cratering: A Geologic Process pyroxene content or different grain size (Fig. 4C). system’s “smallest planet.” (Oxford Univ. Press, Oxford, 1989). Downloaded from www.sciencemag.org on May 10, 2012 30. Telescopic data suggested a prominent diogenite region. The small crater (S) is surrounded by a halo of References and Notes In the adopted coordinate system, this diogenite spot was bright and green materials, similar to the layer ex- 1. T. B. McCord, J. B. Adams, T. V. Johnson, Science 168, moved to the northern hemisphere, where VIR does not posed in Oppia (H), suggesting a similar compo- 1445 (1970). find this evidence. sition. VIR thus reveals that the Oppia impact 2. M. A. Feierberg, M. J. Drake, Science 209, 805 (1980). 31. J. Y. Li et al., Icarus 208, 238 (2010). 3. G. J. Consolmagno, M. J. Drake, Geochim. Cosmochim. 32. H. Takeda, Icarus 40, 455 (1979). exposed different kinds of materials, suggesting Acta 41, 1271 (1977). complex, small-scale crustal stratigraphy on Vesta. 4. M. J. Drake, In Asteroids, T. Gehrels, Ed. (Univ. Arizona Acknowledgments: VIR is funded by the Italian Space Agency At all scales, pyroxene absorptions are the Press, Tucson, AZ, 1979), pp. 765–782 and was developed under the leadership of INAF-Istituto most prominent spectral features on Vesta and, 5. R. P. Binzel et al., Icarus 128, 95 (1997). di Astrofisica e Planetologia Spaziali, Rome, Italy. The 6. M. C. De Sanctis et al., Astron. Astrophys. 533, A77 (2011). instrument was built by Selex-Galileo, Florence, Italy. The on average, the spectral parameters of Vesta re- authors acknowledge the support of the Dawn Science, 7. N. A. Moscovitz et al., Icarus 208, 773 (2010). semble those of howardites (fig. S5). The VIR 8. M. C. De Sanctis et al., Mon. Not. R. Astron. Soc. 412, Instrument, and Operations Teams. This work was supported spectra are thus consistent with a surface covered 2318 (2011). by the Italian Space Agency, and NASA’s Dawn at Vesta by a howardite-like regolith containing varying 9. K. Righter, M. J. Drake, Meteorit. Planet. Sci. 32, 929 (1997). Participating Scientists Program. A portion of this work was 10. P. H. Warren, Meteorit. Planet. Sci. 32, 945 (1997). performed at the Jet Propulsion Laboratory under contract proportions of eucrite and diogenite at different 11. R. C. Greenwood, I. A. Franchi, A. Jambon, P. C. Buchanan, with NASA. locations. This firmly supports the link between Nature 435, 916 (2005). Vesta and the HEDs, providing geologic context 12. D. W. Mittlefehldt et al., in Planetary Materials: Reviews Supplementary Materials www.sciencemag.org/cgi/content/full/336/6082/697/DC1 for these samples, which furthers our understand- in Mineralogy 36, J. J. Papike, Ed. (Mineralogical Supplementary Text ing of the formation and evolution of Vesta. Society of America, Chantilly, VA, 1998), pp. 4-1–4-195. 13. A. Beck, H. Y. McSween Jr., Meteorit. Planet. Sci. 45, Figs. S1 to S5 Furthermore, Vesta exhibits large color and 850 (2010). Table S1 spectral variations that often reflect geological 14. J.-A. Barrat, A. Yamaguchi, B. Zanda, C. Bollinger, 17 January 2012; accepted 16 April 2012 structures, indicating a complex geological and M. Bohn, Geochim. Cosmochim. Acta 74, 6218 (2010). 10.1126/science.1219270 Color and Albedo Heterogeneity 1 Max Planck Institute for Solar System Research, Max-Planck- Strasse 2, 37191 Katlenburg-Lindau, Germany. 2Department of Space Studies, University of North Dakota, Grand Forks, ND of Vesta from Dawn 58202, USA. 3Department of Astronomy, University of Mary- land, College Park, MD 20742, USA. 4Planetary Science Vishnu Reddy,1,2* Andreas Nathues,1 Lucille Le Corre,1 Holger Sierks,1 Jian-Yang Li,3 Institute, 1700 East Fort Lowell, Suite 106, Tucson, AZ 85719, USA. 5Department of Mineral Sciences, Smithsonian National Robert Gaskell,4 Timothy McCoy,5 Andrew W. Beck,5 Stefan E. Schröder,1 Carle M. Pieters,6 Museum of Natural History, 10th and Constitution NW, Kris J. Becker,7 Bonnie J. Buratti,8 Brett Denevi,9 David T. Blewett,9 Ulrich Christensen,1 Washington, DC 20560–0119, USA. 6Department of Geologi- Michael J. Gaffey,2 Pablo Gutierrez-Marques,1 Michael Hicks,8 Horst Uwe Keller,10 cal Sciences, Brown University, Providence, RI 02912, USA. 7 Thorsten Maue,1 Stefano Mottola,11 Lucy A. McFadden,12 Harry Y. McSween,13 Astrogeology Science Center, U.S. Geological Survey, Flagstaff, AZ 86001, USA. 8Jet Propulsion Laboratory, California In- David Mittlefehldt,14 David P. O’Brien,4 Carol Raymond,8 Christopher Russell15 stitute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109, USA. 9Johns Hopkins University Applied Physics Multispectral images (0.44 to 0.98 mm) of asteroid (4) Vesta obtained by the Dawn Framing Cameras Laboratory, Laurel, MD 20723, USA. 10Institut für Geophysik reveal global color variations that uncover and help understand the north-south hemispherical und extraterrestrische Physik, TU Braunschweig Mendelssohn- dichotomy. The signature of deep lithologies excavated during the formation of the Rheasilvia basin on strasse 3, DE 38106 Braunschweig, Germany. 11Deutsches the south pole has been preserved on the surface. Color variations (band depth, spectral slope, and Zentrum für Luft und Raumfahrt (DLR)–German Aerospace Center, Institute of Planetary Research, Rutherfordstrasse 2, D-12489 eucrite-diogenite abundance) clearly correlate with distinct compositional units. Vesta displays the Berlin, Germany. 12NASA/Goddard Space Flight Center, Mail greatest variation of geometric albedo (0.10 to 0.67) of any asteroid yet observed. Four distinct color Code 160, Greenbelt, MD 20771, USA. 13Department of Earth units are recognized that chronicle processes—including impact excavation, mass wasting, and and Planetary Sciences, University of Tennessee, 1412 Circle space weathering—that shaped the asteroid’s surface. Vesta’s color and photometric diversity are Drive, Knoxville, TN 37996–1410, USA. 14Astromaterials Research Office, NASA Johnson Space Center, Mail Code KR, indicative of its status as a preserved, differentiated protoplanet. Houston, TX 77058, USA. 15Institute of Geophysics and Plan- etary Physics, University of California Los Angeles, Los Angeles, he Dawn spacecraft rendezvoused with in seven colors (0.44 to 0.98 mm) and one broad- T CA 90024–1567, USA. the asteroid Vesta on 16 July 2011, and the band clear filter, mapping the entire sun-lit surface *To whom correspondence should be sent. E-mail: reddy@ Framing Cameras (FCs) (1) acquired images at a detail of ~9 to ~0.016 km/pixel. We used mps.mpg.de 700 11 MAY 2012 VOL 336 SCIENCE www.sciencemag.org
  • 3. REPORTS these images to determine the global color likely formed in the lower crust of the asteroid; Lambertian disk, photometrically corrected to characteristics and compositional heterogeneity and howardites are physical mixtures (regolith) standard viewing geometry (30° incidence and 0° of the asteroid’s surface. The diversity of collected of eucrites and diogenites formed by impact emergence and 30° phase angles). This was meteorites indicates that in the early solar system, processes. Spectroscopic (4) and petrologic evi- accomplished by using Hapke functions derived the main asteroid belt held more than 100 large dence (5) originally suggested a HED-Vesta link, from disk-integrated ground-based telescopic asteroids that were partially or totally melted but and the 3:1 mean-motion resonance with Jupiter observations of Vesta and Vestoids, as well as subsequently destroyed by collisions (2). Today, at 2.5 AU could provide a pathway for pieces resolved data from the approach phase of the Vesta is the only surviving silicate-rich differ- ejected from Vesta to near-Earth space (6). This mission (8). A fit of the Dawn survey data in the entiated object (3). Two major goals of the Dawn connection was further solidified by the detection wideband clear filter to Hapke’s model yields fits mission are to help answer why Vesta is the only of the “Vestoids,” a group of smaller (<10 km) to the Hapke parameters of 0.52 for the single remaining member of this class and to use its asteroids that are spectrally similar to Vesta and scattering albedo (SSA), –0.29 for the back- history to understand terrestrial planet formation. span the orbital region between Vesta and the 3:1 scattering parameter (confirming that Vesta’s Vesta is the likely parent body of the howardite- resonance (7). surface is backscattering as other asteroids are), eucrite-diogenite (HED) meteorites. Eucrites are We converted the FC images to reflectance and 20° for the mean slope angle defining mac- crustal basalts, petrologically similar to terrestrial (I/F ) by dividing the observed radiance by the roscopic roughness. For each color acquisition, basalts; diogenites are ultramafic cumulates, solar irradiance from a normally solar-illuminated subpixel coregistration was accomplished to Fig. 1. Color mosaics of Vesta obtained during the Downloaded from www.sciencemag.org on May 10, 2012 approach phase (~480 m/ pixel) in simple cylindrical projection. (A) Photometrical- ly corrected 0.75-mm filter global mosaic showing east- west and north-south dichoto- mies in reflectance. (B) Clemen- tine color ratios mosaic using CR = R(0.75)/R(0.45), CG = R(0.75)/R(0.92), and C B = R(0.45)/R(0.75), where R(l) is the reflectance in a filter centered at l(micrometer) and CR, CG, CB are the colors red, green, and blue, respectively. Greener areas have deeper bands, and redder areas have steeper visible slopes relative to bluer areas. (C) Rainbow-color coded map of R(0.75)/R(0.92) ratio (proxy for 0.90-mm py- roxene band depth) showing areas with deeper bands as red. (D) Rainbow-color coded map of R(0.98)/R(0.92) ratio (Eucrite-Diogenite) showing diogenite-rich regions as red and eucrite-rich regions as blue (8). (E) Color-shaded topo- graphic map of Vesta with white corresponding to the highest elevation and blue the lowest. Minimum and maxi- mum elevations are computed relative to a 285- × 229-km reference ellipsoid. All maps are based on the new Claudia co- ordinate system, which is dif- ferent from the older Olbers system used with the Hubble Space Telescope data. Olbers reference longitude is located approximately at 210°E in the Claudia system. www.sciencemag.org SCIENCE VOL 336 11 MAY 2012 701
  • 4. REPORTS align the seven color frames in order to create 1D). We further confirmed the compositional Rheasilvia Formation at the south pole also has color cubes before analysis. identification of specific color units with labora- higher albedo as compared with that of the north- Global maps show variations in 0.75-mm tory spectra of HED meteorites using several ern hemisphere (Fig. 2, A and B). In addition, albedo (Fig. 1A) and the 0.90-mm pyroxene spectral criteria (10). two distinct lower albedo units are associated absorption depth R(0.75)/R(0.92) (Fig. 1C). The The maps (Fig. 1, A to E) reveal a hemi- with the ejecta of the Marcia (10°N, 190°) and ratio R(0.98)/R(0.92) qualitatively identifies spherical scale dichotomy on Vesta. The brightest Oppia (8°S, 309°) impact craters. eucrite- and diogenite-rich terrains (Fig. 1D). All of point (in clear filter) is on a crater wall near the This dichotomy reflects both Vesta’s com- these features show a weak relation to topogra- south pole that has a SSA of ~0.82 and a geo- position and regolith processes. Abundance of maf- phy (Fig. 1E). A false color composite quantifies metric albedo of ~0.67; the darkest area has a ic minerals (iron abundance), space weathering, band depth and visible slope (Fig. 1B). Because SSA of ~0.15 and a geometric albedo of only grain size, and presence of opaque minerals are eucrites have more ferroan pyroxene than ~0.10. This range is much higher than is seen in known to affect the R(0.75)/R(0.92) ratio (8). diogenites (fig. S1), their 0.90-mm pyroxene band other asteroids (8). The global albedo map also Laboratory study of HED meteorites suggests is shifted toward longer wavelength (fig. S2) exhibits an overall lower reflectance in the that grain size is a major cause for band depth (8, 9), causing the R(0.98)/R(0.92) to be closer eastern hemisphere as compared with the western dichotomy (8). Unlike the Moon, where the to 1 for eucrites but higher for diogenites (Fig. (3, 11). The area located between 30°S and the highland units have higher albedo as compared with those of lower and darker mare, Vesta does not seem to have distinct global correlation be- tween topography and albedo or color. Along with global color dichotomy, we have Downloaded from www.sciencemag.org on May 10, 2012 identified various terrains on Vesta that are fur- ther evidence for surface heterogeneity. We have classified these areas as bright, dark, gray, and orange terrains (Fig. 3, A to H). Fresh impact craters have higher reflectance (30 to 40% in the 0.75-mm filter) than that of background surface and are associated with bright terrains (such as the Canuleia crater) (Fig. 3, A and B). They also have deeper 0.90-mm pyroxene absorption band. In the south, several fresh craters appear redder in the eucrite/diogenite (ED) ratio maps, suggesting that diogenite-rich material was excavated within Rheasilvia. By comparing the color spectra of bright material with global average, we find that the R(0.75)/R(0.92) ratio is 16% deeper, and the Fig. 2. Stereographic projection centered on the south pole of (A) the color mosaic in Clementine color visible spectral slope (0.45 to 0.55 mm) is also ratios overlaid on a shaded-relief map and of (B) the color-shaded topographic map. steeper (Fig. 4, A and B). Fig. 3. Examples of diverse color terrains on Vesta in 0.75-mm filter (left) and Numisia crater located at 7°S, 247°E. (E and F) Gray ejecta blanket of the Clementine ratio (right). (A and B) Bright ejecta around the 11.2-km diameter 58-km diameter Marcia crater (top left) located at 10°N, 190°E. (G and H) fresh impact crater Canuleia located at 33.7°S, 294.5°E. (C and D) Dark The 34-km diameter impact crater Oppia located at 8°S, 309°E, with orange material on the crater wall and in the surroundings of the 30-km diameter ejecta blanket. 702 11 MAY 2012 VOL 336 SCIENCE www.sciencemag.org
  • 5. REPORTS Dark material is commonly associated with slope (redder in Clementine ratios) and a weak rim. The eastern portion, between ~0 and 130°E, impact craters (such as the Numisia crater) (Fig. R(0.75)/R(0.92) ratio; thus, it has a shallower has higher concentrations of high-band-ratio ma- 3, C and D), but dark deposits are also seen 0.90-mm pyroxene band as compared with the terial than the western portion (210 to 300°E), elsewhere in >25 locations. In some cases— global mean spectrum (Fig. 4, A and B). Several which is consistent with the western portion con- Lucaria Tholus—dark material is associated with lighter “orange patches” are also observed to the taining relatively more eucritic material. The ori- a topographic high. In addition, several fresh west and north around Oppia (Fig. 3, G and H). gin of this variation is not immediately clear. Given impact craters exhibit excavation of bright and Band depth and ED maps (Fig. 1, C and D) that the western portion of the rim is topograph- dark material within the crater walls and ejecta show that areas with deeper R(0.75)/R(0.92) ically higher (Figs. 1E and 2B), we would expect blankets (Fig. 3, C and D). They have lower ratios also tend to have higher R(0.98)/R(0.92) it to contain higher concentrations of diogenite reflectance (8 to 13% at 0.75 mm), weaker band ratios (8). This correlation suggests that diogenite- material (ejecta), which it does not. This may depth (Fig. 4, A and B) and have a redder visible rich material has a deeper R(0.75)/R(0.92) ratio be an indication that the western portion of the spectral slope. Either the excavation of a darker as compared with that of eucrite-rich material. Rheasilvia ejecta rim sampled previously re- subsurface layer or the incorporation of dark Terrains with higher ratios surround Rheasilvia worked lithologies, which may be linked to the material by an impactor could explain the basin in the south, whereas Vesta has lower ra- large pre-Rheasilvia basin impact (14). observed morphology of these units. The dark tios in the north (Fig. 1, C and D). The observed Two localized concentrations of the highest material on Vesta may indicate the presence of variance is consistent with diogenite-rich terrains R(0.75)/R(0.92) and R(0.98)/R(0.92) ratio material impact melts and exogenous carbonaceous ma- (red) in the south and more eucritic terrains (blue) occur in areas associated with Rheasilvia (Figs. 1, terial (8), both of which are seen in the HED in the north, which is in agreement with Visible C to E, and 2, A and B). The first (43 to 55°S, meteorites. and Infrared Imaging Spectrometer observations 51 to 87°E) coincides with a large scarp face, Downloaded from www.sciencemag.org on May 10, 2012 Most of the surface of Vesta is covered with (12). This north-south dichotomy is disrupted by possibly indicating diogenite-rich material ex- gray material (0.75-mm reflectance, ~15 to 30%). a swath (~0 to 90°E) of relatively higher R(0.75)/ posed along the rim and wall of the basin, and This material has a moderate R(0.75)/R(0.92) R(0.92) and R(0.98)/R(0.92) ratio material that deposited nearby in the ejecta material. The ratio (Fig. 4, A and B). In craters, downslope protrudes to the northern extent of Dawn’s ob- second location (53 to 64°S, 180 to 230°E) is at movements have unveiled underlying bright ma- servations (Fig. 1, C and D). This swath is a topographical low in the Rheasilvia basin terial. Hence, gray material could correspond to a probably impact ejecta from the Rheasilvia floor and corresponds to the Antonia crater and mixture of bright and dark material or space- forming event because it is topographically higher its associated ejecta. Given the likely depth of weathered bright material. Space weathering than adjacent terrains (Fig. 1E) and has similar excavation and the high-band-ratio signature, affects optical properties of the regolith of plan- R(0.75)/R(0.92) and R(0.98)/R(0.92) ratios to this material may be an in situ diogenitic lithol- etary bodies without an atmosphere. A second Rheasilvia material (Fig. 1, C and D). Also, me- ogy that has been exposed by the Rheasilvia type of gray material is associated with ejecta teoritical evidence suggests that diogenitic mate- impact event. blankets around large impact craters such as the rial probably formed deep beneath the surface of In a magma ocean model, a single, deep- Marcia crater (Fig. 3, E and F) and is possibly Vesta (13). The central peak of the Rheasilvia seated layer of diogenitic material is expected impact melt. This gray material has a 0.75-mm basin has a strong R(0.75)/R(0.92) ratio (Fig. 2A), (15), and if this region in the Rheasilvia basin is reflectance of ~15%, a shallow visible slope, and implying that it is dominated by material with a the only region with in situ diogenite material the second weakest R(0.75)/R(0.92) ratio (Fig. 4, strong 0.90-mm pyroxene band (diogenite-rich). identified on Vesta, a magma ocean model may A and B). The high rim of Rheasilvia (Figs. 1, C and D, be favored. Our analyses show that Vesta was The Oppia crater displays asymmetric orange and 2, A and B) is dominated by high R(0.75)/R(0.92) large enough to accrete material and differentiate ejecta in the Clementine ratio map (Fig. 3, G and and R(0.98)/R(0.92) ratio material, which is con- during the first few million years of Solar System H) that is spread toward the southeast. The sistent with diogenite-rich rocks that have been formation. Although battered by multiple impacts, morphology of Oppia could be explained by excavated from depth and deposited as ejecta. Vesta remains intact today probably because of an oblique impact or an impact on a slope. However, the abundance of deeper-band material its differentiated internal structure. These cata- This particular unit has a steep visible spectral is not homogeneous along the entire Rheasilvia strophic events have not only excavated deeper Fig. 4. (A) Color spectra of bright (green), dark (black), gray (gray) and gray, and orange terrains have weaker R(0.75)/R(0.92) ratios, whereas orange terrains (orange) on Vesta. The red spectrum corresponds to the bright material has deeper ratio as compared with the global average. The global average spectrum of Vesta. Errors shown are 1s. (B) Ratios of the orange ejecta exhibits the steepest visible slope with respect to global same color spectra divided by the global average spectrum (red). Dark, average. www.sciencemag.org SCIENCE VOL 336 11 MAY 2012 703
  • 6. REPORTS compositional units but also delivered exogenous 7. R. P. Binzel, S. Xu, Science 260, 186 (1993). financially supported by the Max Planck Society and the carbon-rich material to Vesta, a key ingredient for 8. Materials and methods are available as supplementary German Space Agency, DLR. We also thank the Dawn at Vesta materials on Science Online. Participating Scientist Program for funding the research. the formation and evolution of life on Earth. 9. M. J. Gaffey, J. Geophys. Res. 81, 905 (1976). A portion of this work was performed at the Jet Propulsion 10. L. Le Corre, V. Reddy, A. Nathues, E. A. Cloutis, Icarus Laboratory, California Institute of Technology, under contract References and Notes 216, 376 (2011). with NASA. Dawn data are archived with the NASA Planetary 1. H. Sierks et al., Space Sci. Rev. 163, 263 (2011). 11. J.-Y. Li et al., Icarus 208, 238 (2010). Data System. 2. K. Keil, in Asteroid III, William F. Bottke, Alberto Cellino, 12. M. C. De Sanctis et al., Science 336, 697 (2012). Paolo Paolicchi, Richard P. Binzel, Eds. (Univ. of Arizona 13. D. W. Mittlefehldt et al., Planet. Mat. 36, 4-1 (1998). Press, Tucson, 2002), pp. 573–584. 14. P. Schenk et al., Science 336, 694 (2012). Supplementary Materials 15. A. Ruzicka, G. A. Snyder, Meteor. Planet. Sci. 32, 825 www.sciencemag.org/cgi/content/full/336/6082/700/DC1 3. P. C. Thomas et al., Icarus 128, 88 (1997). Materials and Methods 4. T. B. McCord, J. B. Adams, T. V. Johnson, Science 168, (1997). Figs. S1 and S2 1445 (1970). Acknowledgments: We thank the Dawn team for the References (16–31) 5. G. J. Consolmagno, M. J. Drake, Geochim. Cosmochim. Acta 41, 1271 (1977). development, cruise, orbital insertion, and operations of the 13 January 2012; accepted 13 April 2012 6. J. Wisdom, Nature 315, 731 (1985). Dawn spacecraft at Vesta. The Framing Camera project is 10.1126/science.1219088 pole moment oriented randomly in the QW Coupling Quantum Tunneling plane. The indirect exciton jIX 〉 has the hole in the left QW and the electron in the right QW— with Cavity Photons thus possessing an additional static dipole mo- Downloaded from www.sciencemag.org on May 10, 2012 ment aligned perpendicularly to the plane—and has a very small overlap of electron and hole wave Peter Cristofolini,1 Gabriel Christmann,1 Simeon I. Tsintzos,1,2 George Deligeorgis,2* functions, hence low oscillator strength. When a George Konstantinidis,2 Zacharias Hatzopoulos,2 Pavlos G. Savvidis,2,3 Jeremy J. Baumberg1† bias voltage is applied to bring the electron levels into resonance, the electron states in the two QWs Tunneling of electrons through a potential barrier is fundamental to chemical reactions, electronic mix to give symmetric and antisymmetric elec- transport in semiconductors and superconductors, magnetism, and devices such as terahertz oscillators. tron wave functions (red in Fig. 1A), which, to- Whereas tunneling is typically controlled by electric fields, a completely different approach is to bind gether with the low-energy hole states (blue) electrons into bosonic quasiparticles with a photonic component. Quasiparticles made of such light-matter in pffiffiffi left QW, produce the exciton modes the microcavity polaritons have recently been demonstrated to Bose-condense into superfluids, whereas ð1= 2ÞfjIX 〉 T jDX 〉g, split by the tunneling spatially separated Coulomb-bound electrons and holes possess strong dipole interactions. We use energy ħJ (where ħ is Planck’s constant divided tunneling polaritons to connect these two realms, producing bosonic quasiparticles with static dipole by 2p). These modes combine the large os- moments. Our resulting three-state system yields dark polaritons analogous to those in atomic systems or cillator strength of the DX with the large static optical waveguides, thereby offering new possibilities for electromagnetically induced transparency, dipole moment of the IX (Fig. 1B, bottom). room-temperature condensation, and adiabatic photon-to-electron transfer. Embedding DX and IX excitons in the mi- crocavity with cavity mode C now forms a trong coupling of photons to the interband ficient in-plane electrostatic traps (9, 10) and the three-state system similar to the atomic L-scheme S exciton transition in a semiconductor mi- crocavity leads to the formation of polar- itons, bosonic quasiparticles whose properties are coherent control of electron spins (11). By em- bedding double quantum wells inside a conven- tional microcavity in the strong coupling regime, (14, 15), which is coupled optically by the vac- uum Rabi frequency W and electronically by the electron tunneling rate J (Fig. 1C). Although J governed by their mixed light-matter composi- we unite the concepts of indirect excitons and and W are intrinsic to the microcavity design, tion. Owing to their quantum indistinguishability microcavity polaritons to produce optically active full control of the dipolariton modes is possible and the interplay of their Coulomb interactions, quasiparticles with transport properties, named through bias voltage control of tunneling and microcavity polaritons show unusually strong dipolaritons. These offer the advantages of both angle tuning of the cavity mode. In the strong light-matter interactions and many-body quan- systems: electrical trapping and tuning of ex- coupling regime, when J is larger than the carrier tum effects. In particular, their small effective mass citons, strong optical coupling to low-mass quasi- escape rate from the coupled QWs and W is faster allows observation of quantum degeneracy ef- particles with large de Broglie wavelength, and than the photon decay rate, the system displays fects at temperatures from 10 to 300 K, such as excellent control over the dipole properties and three distinct eigenmodes: the lower (LP), middle Bose condensation (1–4) and superfluidity flow interactions (12, 13). (MP), and upper (UP) dipolaritons. Thus, a con- dynamics (5), and their tunable interactions make Microcavities are formed from p-i-n semi- ventional microcavity polariton (Fig. 1D, black) them ideal candidates for future quantum opto- conductor multilayers surrounded by doped can be simply bias-tuned to yield the dipolariton electronic devices (6) working at room temper- multilayer mirrors (7) (Fig. 1A; details in the sup- spectrum (red) in the strong tunneling regime. ature (7). By contrast, spatially separating the porting online material) and pumped with a non- The bias dependence of the photolumines- electrons and holes in coupled double quantum resonant laser. Quantum wells (QWs) of InGaAs cence (PL) of a mesa with barrier width LB = wells yields indirect excitons with sufficiently inside the cavity are arranged in asymmetric pairs 4 nm (Fig. 2) clearly reveals these three dipolar- long lifetimes for thermalization and a large static separated by a thin barrier (of width LB) that iton modes. Because in-plane wave vectors k are dipole moment (8). These properties enable ef- allows electrons to tunnel between the two wells conserved, photons emitted at an angle q directly (Fig. 1A). Because of the large effective hole mass measure dipolaritons at k. At normal incidence 1 NanoPhotonics Centre, Cavendish Laboratory, University of and the wide energy separation of hole levels in (Fig. 2, A and C) the narrow cavity mode is de- Cambridge, Cambridge CB3 0HE, UK. 2FORTH‑IESL, Post Office neighboring QWs, hole tunneling is negligible, tuned below the excitons, whereas at 35° (Fig. 2, Box 1527, 71110 Heraklion, Crete, Greece. 3Department of Ma- and only the low-energy left QW (LQW) hole B and D) the uncoupled modes are all degen- terials Science and Technology, University of Crete, Post Office state is considered. Without tunneling, there are erate. For higher electric fields, the PL emission Box 2208, 71003 Heraklion, Greece. two types of exciton in this system. The direct weakens because electrons escape the coupled *Present address: CNRS, LAAS, 7 avenue de Colonel Roche, F-31077 Toulouse Cedex 4, France. exciton jDX 〉 has both electron and hole in the QW system before they can recombine radia- †To whom correspondence should be addressed. E-mail: left QW (Fig. 1B, top) and therefore strongly tively with a left QW hole, and eventually two of jjb12@cam.ac.uk couples to the cavity mode, with its induced di- the modes vanish, leaving only the most cavity- 704 11 MAY 2012 VOL 336 SCIENCE www.sciencemag.org