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1.
2.
3.
4.
The E1 Reaction
The alkyl halide dissociate, forming a carbocation The base removes a proton The mechanism shows that an E1 reaction is a two-step reaction
5.
6.
7.
Energy Diagram for
E1
8.
Transition States Rate
= k [A] See SN1 and E1 Reaction Mechanisms And Radical Chain Reaction
9.
10.
Here are four
characteristics that the E1 / SN1 mechanisms have in common.
11.
Dehydration of Alcohols
Acid assisted reactions are always E1
12.
The E2 Mechanism
13.
Energy Diagram for
the E2 Mechanism
14.
Transition States Rate
= k [A][B] See SN2 and E2 Reaction Mechanisms
15.
16.
17.
18.
Here are four
characteristics that the E2 / SN2 mechanisms have in common.
19.
Effect of the
Substrate on E2 Reactivity
20.
Bulky leaving groups:
Hofmann Elimination This give the anti-Saytzeff product (least substituted product is formed)!
21.
22.
23.
24.
25.
26.
The Saytzeff) Rule
(Z-rule) According to the Z-rule , the major product in a dehydrohalgenation is the most stable product .
27.
28.
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