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Former NAS Moffett Field



Site 26 Eastside Aquifer Treatment System

                Neil Hey, PG
          Shaw Environmental, Inc.

             Valerie Harris, PE
                     Harris
           Navy BRAC PMO West

            September 8, 2011
            S t   b   8
               RAB Meeting



                    1
Presentation Overview



• Treatability Study Update
• Focused Feasibility Study
• Schedule
• Questions




                  2
Site 26 Treatability Study - Location




                     Note – inset location not to scale
                 3
Treatability Study Purpose



Evaluate the applicability and effectiveness of
EHC®, an in situ abiotic/biotic treatment
technology,
technology to reduce the chemicals of concern
(COC; PCE, TCE, DCE, & VC) concentrations in
g
groundwater to levels below the ROD cleanup   p
standards at IR Site 26




                      4
EHC® Treatment Technology




• A product of Adventus Americas, Inc.
• Patented combination of zero-valent iron (ZVI)
                          zero valent
  particles & plant-based carbon

• Combination of chemical (abiotic) and biological
  (biotic) reductive dechlorination processes




                         5
Project Description



• Installed 5
  observation wells

• Injected EHC® at
  16 locations

• Performed 10
  post-injection
  groundwater
  monitoring events
            g

                         6
EHC® Injection
                     Site Location
Total CEs ~80
µg/L

50 ft x 50 ft area

40 to 8 feet bgs

~6,600 gallons
 6,600
hydrant water

~23,000
~23 000 pounds
EHC®                                 Groundwater
                                     Flow

                            7
Treatment Area Results


82 µg/L total




                  4 µg/L total   2 µg/L total




                  8
Treatment Area Results




          9
TS Conclusions


• EHC® easy to prepare but difficult to inject
• EHC® not di t ib t d uniformly due to h t
         t distributed if     l d t heterogeneous
    nature of subsurface
•   Complete reductive dechlorination observed in all
    treatment area wells
•   98% reduction in total COCs concentration in treatment
    area
•   PCE, TCE, & DCE concentrations in treatment area
    reduced below ROD cleanup standards in < 1 year
•   Vinyl hl id
    Vi l chloride concentration in treatment area remains
                            i i                       i
    slightly above ROD cleanup standard but decreasing
•   EHC® continues to treat on-flow of COCs 2 years after
                                               y
    treatment
                             10
Focused Feasibility Study




           11
Site 26 Background


• Chlorinated solvents identified in groundwater near
  Hangar 3 in 1983
• Record of decision (ROD) signed in 1996. Selected
  remedy was groundwater extraction and treatment
  to restore groundwater to cleanup standards.
• Cleanup standards – drinking water
   – Tetrachloroethene (PCE) = 5 g/L
   – Trichloroethene (TCE) = 5 g/L
   –CCis-1,2-dichloroethene = 6 g/L
           2 d hl      h             /
   – Vinyl chloride = 0.5 g/L


                         12
Site 26 Background (continued)


• Eastside Aquifer Treatment System (EATS) began
            q                   y     (    ) g
  operating in 1999.
   – extracted 67 million gallons of water
   – removed 23.7 pounds of chlorinated volatile organic
     compounds (VOCs)
• Shut down in 2003 to evaluate:
   – Evaluate plume stability
   – Chemical rebound
   – Natural attenuation
   – HRC in plume hot spots
   – Treatability study (almost completed)
                          13
2010 Groundwater Plume

                          Combined CVOC concentrations
                            • 85.9 g/L (maximum)
                              located near current treatability
                              study
                              • Max combined CVOC
                              concentration in other areas
                              about 25 g/L
                                b t       /



                  TREATABILITY STUDY AREA


Groundwater
    Flow
                            14
Focused Feasibility Study

Purpose – to evaluate several technologies along with
   the selected remedy
• Identify remedial action objectives and applicable
  regulations
• Identify and screen treatment technologies
   – Monitored Natural Attenuation
   – Abiotic/Biotic Treatment (EHC®)
   – In Situ Biostimulation/Bioaugmentation
• Develop and evaluate remedial alternatives against
  seven of the nine NCP criteria
• Compare the remedial alternatives against each other

                          15
Preliminary Remedial Alternatives


• Alternative 1 – No Action
• Alternative 2 – Monitored Natural Attenuation
                  (MNA)
• Alternative 3 – Optimized Pump and Treat




                      16
Preliminary Remedial Alternatives


• Alternative 4 – Abiotic/biotic Treatment and
                  MNA
• Alternative 5 – In Situ Biostimulation
                  /Bioaugmentation and MNA
                  /Bi          t ti     d
 Biotic     PCE

            TCE
 Cis 1,2‐DCE       Trans 1,2‐DCE

             VC

           Ethene

            Ethane
             α‐elimination         17
             β‐elimination
Conceptual Treatment Areas

                                 •Trend analysis
                                 performed for
                                 each well
                                 •Identify areas
                                 th t could b
                                 that     ld benefit
                                                 fit
                                 from treatment


Natural
processes =
60 years                       Natural
                               processes >
                               60 years
                               (increasing
                               trend/no
                               trend)
                      18
Sustainability

• An evaluation of sustainability will be included
  in the feasibility study (FS)
• FS will use SiteWiseTM
   – Streamlined life cycle analysis tool
                  life-cycle
   – Developed by Navy, Army Corps and Battelle
   – Available at http://www.ert2.org/t2gsrportal
• Sustainability metrics considered are:
   –   Energy and resource consumption
           gy                      p
   –   Greenhouse gas and criteria pollutant emissions
   –   Water and ecological impacts
   –   Worker and community safety
                          19
Schedule


• November 30, 2011- Draft FS Report
                                p
• December 1, 2011 to January 29,
  2011 – Agency/RAB Review of draft
          g   y/
• April 30, 2012 - Final FS Report

Next Steps
  – Proposed plan
  – ROD amendment


                      20
Questions?




    21

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Moffett Superfund Site 26 Update to the Moffett Restoration Advisory Board

  • 1. Former NAS Moffett Field Site 26 Eastside Aquifer Treatment System Neil Hey, PG Shaw Environmental, Inc. Valerie Harris, PE Harris Navy BRAC PMO West September 8, 2011 S t b 8 RAB Meeting 1
  • 2. Presentation Overview • Treatability Study Update • Focused Feasibility Study • Schedule • Questions 2
  • 3. Site 26 Treatability Study - Location Note – inset location not to scale 3
  • 4. Treatability Study Purpose Evaluate the applicability and effectiveness of EHC®, an in situ abiotic/biotic treatment technology, technology to reduce the chemicals of concern (COC; PCE, TCE, DCE, & VC) concentrations in g groundwater to levels below the ROD cleanup p standards at IR Site 26 4
  • 5. EHC® Treatment Technology • A product of Adventus Americas, Inc. • Patented combination of zero-valent iron (ZVI) zero valent particles & plant-based carbon • Combination of chemical (abiotic) and biological (biotic) reductive dechlorination processes 5
  • 6. Project Description • Installed 5 observation wells • Injected EHC® at 16 locations • Performed 10 post-injection groundwater monitoring events g 6
  • 7. EHC® Injection Site Location Total CEs ~80 µg/L 50 ft x 50 ft area 40 to 8 feet bgs ~6,600 gallons 6,600 hydrant water ~23,000 ~23 000 pounds EHC® Groundwater Flow 7
  • 8. Treatment Area Results 82 µg/L total 4 µg/L total 2 µg/L total 8
  • 10. TS Conclusions • EHC® easy to prepare but difficult to inject • EHC® not di t ib t d uniformly due to h t t distributed if l d t heterogeneous nature of subsurface • Complete reductive dechlorination observed in all treatment area wells • 98% reduction in total COCs concentration in treatment area • PCE, TCE, & DCE concentrations in treatment area reduced below ROD cleanup standards in < 1 year • Vinyl hl id Vi l chloride concentration in treatment area remains i i i slightly above ROD cleanup standard but decreasing • EHC® continues to treat on-flow of COCs 2 years after y treatment 10
  • 12. Site 26 Background • Chlorinated solvents identified in groundwater near Hangar 3 in 1983 • Record of decision (ROD) signed in 1996. Selected remedy was groundwater extraction and treatment to restore groundwater to cleanup standards. • Cleanup standards – drinking water – Tetrachloroethene (PCE) = 5 g/L – Trichloroethene (TCE) = 5 g/L –CCis-1,2-dichloroethene = 6 g/L 2 d hl h / – Vinyl chloride = 0.5 g/L 12
  • 13. Site 26 Background (continued) • Eastside Aquifer Treatment System (EATS) began q y ( ) g operating in 1999. – extracted 67 million gallons of water – removed 23.7 pounds of chlorinated volatile organic compounds (VOCs) • Shut down in 2003 to evaluate: – Evaluate plume stability – Chemical rebound – Natural attenuation – HRC in plume hot spots – Treatability study (almost completed) 13
  • 14. 2010 Groundwater Plume Combined CVOC concentrations • 85.9 g/L (maximum) located near current treatability study • Max combined CVOC concentration in other areas about 25 g/L b t / TREATABILITY STUDY AREA Groundwater Flow 14
  • 15. Focused Feasibility Study Purpose – to evaluate several technologies along with the selected remedy • Identify remedial action objectives and applicable regulations • Identify and screen treatment technologies – Monitored Natural Attenuation – Abiotic/Biotic Treatment (EHC®) – In Situ Biostimulation/Bioaugmentation • Develop and evaluate remedial alternatives against seven of the nine NCP criteria • Compare the remedial alternatives against each other 15
  • 16. Preliminary Remedial Alternatives • Alternative 1 – No Action • Alternative 2 – Monitored Natural Attenuation (MNA) • Alternative 3 – Optimized Pump and Treat 16
  • 17. Preliminary Remedial Alternatives • Alternative 4 – Abiotic/biotic Treatment and MNA • Alternative 5 – In Situ Biostimulation /Bioaugmentation and MNA /Bi t ti d Biotic PCE TCE Cis 1,2‐DCE       Trans 1,2‐DCE VC Ethene Ethane α‐elimination 17 β‐elimination
  • 18. Conceptual Treatment Areas •Trend analysis performed for each well •Identify areas th t could b that ld benefit fit from treatment Natural processes = 60 years Natural processes > 60 years (increasing trend/no trend) 18
  • 19. Sustainability • An evaluation of sustainability will be included in the feasibility study (FS) • FS will use SiteWiseTM – Streamlined life cycle analysis tool life-cycle – Developed by Navy, Army Corps and Battelle – Available at http://www.ert2.org/t2gsrportal • Sustainability metrics considered are: – Energy and resource consumption gy p – Greenhouse gas and criteria pollutant emissions – Water and ecological impacts – Worker and community safety 19
  • 20. Schedule • November 30, 2011- Draft FS Report p • December 1, 2011 to January 29, 2011 – Agency/RAB Review of draft g y/ • April 30, 2012 - Final FS Report Next Steps – Proposed plan – ROD amendment 20