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Differential Mobility Analizer



        By Sinelk Berhane
Introduction
               History of electrical mobility studies
•   Erikson (1922) and Zeleny (1929) studied measure of ions in
    gases
•   Rohmann (1929) atmospheric airborne particles
•   Hewitt (1957) two inlet and two outlet flow
•   Whitby and Clack (1966) Unipolar charging by.
•   Liu and Pui (1974) improved Hewitt’s design
•   Knutson & Whitby (1975) designed the modern DMA
Overview
• Nano DMA
• Long DMA
• Process
  – Charging particles
  – Mobility
  – Sizing particles
• Application
Nano DMA
• 2nm<=Dp<=150nm
• Used to optimize performance
• Outer electrode = 0.937cm
Long DMA
• TSI Long DMA
  – 10nm <=Dp<=1000nm
  – Inner electrode (1V-10KV)
Process
1. Particles get charged in the Neutralizer
     •Positively charged are sorted
     •All the others get lost
2. Separated by the Sheath Air flow
Passing down the annulus
3. Influenced by Electric field
• positively charged attracted
• Electrode contact with particles depends on the particle mobility (Zp)
4. Electrical mobility depends on
     •Size
     •Charge




        Note: if particles have the same charge, their mobility will be of the same size
Charging particles
• Uni-polar charging: occurs when only ions of
  one polarity are present.
• Bipolar charging : occurs when a mixture of
  positive and negative ions is present in a
  particle.
Charging particles cont’d
• Radio active ionizers are used to neutralizer
  aerosols.
• Neutralizers are bipolar chargers that use
  unstable elements such as Kr-85, Am-241 and
  Po-210 to charge particles
                    Experimental setup to measure ionization current
Charging particles cont’d
Po-210 source gives nearly eight times the saturation current as Kr-85 source
Midpoint mobility, Diameter &
       concentration
Mobility
Fe=qE = qV/d
                           r1 – radii of outer electrode =0.937cm
E=       V                 r2 – radii of inner electrode = 1.961 cm
     r ln(r2/r1)           q – charge
                           Q - flow rate in cm3/s
Fdrag = 3πμDp*u            μ – gas viscosity
                           C – cunningham slip correction
         C (2λ/Dp)
                           λ – gas mean free path
Z = ieC(Kn)                 L – electrode length
       3πηDp                V - average voltage
                           E – Electric field
Zp = (Qsh+ Qa) ln(r2/r1)   r – radius of the electric field
                           u – particle velocity
        2πLV               Kn – Knudsen number (2λ/Dp)
Dp = ___2neVL___
        3μ Qsh ln(r2/r1)
Sizing




Transfer function for tsi-long DMA operated at flow rate of beta = 0.1
Application
• To Measure Aerosole particle size distribution
  – Determining the concentration of particles in the flow
    entering the CNC (condensation nuclei counter)
• To make Aerosol particles equal size
  – Reagent in an experiment
  – See a change in conditions to see how they can be
    charged
  – Chemical analysis to find their composition
  – Determine the concentration of particles as a function
    of size
Thank you

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Dma ppt

  • 1. Differential Mobility Analizer By Sinelk Berhane
  • 2. Introduction History of electrical mobility studies • Erikson (1922) and Zeleny (1929) studied measure of ions in gases • Rohmann (1929) atmospheric airborne particles • Hewitt (1957) two inlet and two outlet flow • Whitby and Clack (1966) Unipolar charging by. • Liu and Pui (1974) improved Hewitt’s design • Knutson & Whitby (1975) designed the modern DMA
  • 3. Overview • Nano DMA • Long DMA • Process – Charging particles – Mobility – Sizing particles • Application
  • 4. Nano DMA • 2nm<=Dp<=150nm • Used to optimize performance • Outer electrode = 0.937cm
  • 5. Long DMA • TSI Long DMA – 10nm <=Dp<=1000nm – Inner electrode (1V-10KV)
  • 6. Process 1. Particles get charged in the Neutralizer •Positively charged are sorted •All the others get lost 2. Separated by the Sheath Air flow Passing down the annulus 3. Influenced by Electric field • positively charged attracted • Electrode contact with particles depends on the particle mobility (Zp) 4. Electrical mobility depends on •Size •Charge Note: if particles have the same charge, their mobility will be of the same size
  • 7. Charging particles • Uni-polar charging: occurs when only ions of one polarity are present. • Bipolar charging : occurs when a mixture of positive and negative ions is present in a particle.
  • 8. Charging particles cont’d • Radio active ionizers are used to neutralizer aerosols. • Neutralizers are bipolar chargers that use unstable elements such as Kr-85, Am-241 and Po-210 to charge particles Experimental setup to measure ionization current
  • 9. Charging particles cont’d Po-210 source gives nearly eight times the saturation current as Kr-85 source
  • 10.
  • 11. Midpoint mobility, Diameter & concentration
  • 12. Mobility Fe=qE = qV/d r1 – radii of outer electrode =0.937cm E= V r2 – radii of inner electrode = 1.961 cm r ln(r2/r1) q – charge Q - flow rate in cm3/s Fdrag = 3πμDp*u μ – gas viscosity C – cunningham slip correction C (2λ/Dp) λ – gas mean free path Z = ieC(Kn) L – electrode length 3πηDp V - average voltage E – Electric field Zp = (Qsh+ Qa) ln(r2/r1) r – radius of the electric field u – particle velocity 2πLV Kn – Knudsen number (2λ/Dp) Dp = ___2neVL___ 3μ Qsh ln(r2/r1)
  • 13. Sizing Transfer function for tsi-long DMA operated at flow rate of beta = 0.1
  • 14. Application • To Measure Aerosole particle size distribution – Determining the concentration of particles in the flow entering the CNC (condensation nuclei counter) • To make Aerosol particles equal size – Reagent in an experiment – See a change in conditions to see how they can be charged – Chemical analysis to find their composition – Determine the concentration of particles as a function of size