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Uses of Nuclear Chemistry


         18.3
Radioactive Dating
 Finding the age of an object based on
  the amount of radioactive isotopes in it.
 Example:
  Carbon-14 has a half life of 5715 years.
  Carbon-12 & Carbon-14 amounts remain
   constant while an object is living.
  When an organic artifact is found the
   Carbon-14 can be compared to the
   Carbon-12.
Half-Life
Half-Life
 The amount of time it takes for ½ of an
  unstable element to decay.
Half-Life
 The amount of time it takes for ½ of an
  unstable element to decay.
 Example: carbon-14 half life is 5715. If a
  80mg sample decays over 22860 years, how
  much will remain?
Half-Life
 The amount of time it takes for ½ of an
  unstable element to decay.
 Example: carbon-14 half life is 5715. If a
  80mg sample decays over 22860 years, how
  much will remain?
 22860/5715 = 4 half lives.
Half-Life
 The amount of time it takes for ½ of an
  unstable element to decay.
 Example: carbon-14 half life is 5715. If a
  80mg sample decays over 22860 years, how
  much will remain?
 22860/5715 = 4 half lives.
 80/2=40mg     1st half life
Half-Life
 The amount of time it takes for ½ of an
  unstable element to decay.
 Example: carbon-14 half life is 5715. If a
  80mg sample decays over 22860 years, how
  much will remain?
 22860/5715 = 4 half lives.
 80/2=40mg     1st half life
 40/2=20mg     2nd half-life
Half-Life
 The amount of time it takes for ½ of an
  unstable element to decay.
 Example: carbon-14 half life is 5715. If a
  80mg sample decays over 22860 years, how
  much will remain?
 22860/5715 = 4 half lives.
 80/2=40mg     1st half life
 40/2=20mg     2nd half-life
 20/2=10mg     3rd half-life
Half-Life
 The amount of time it takes for ½ of an
  unstable element to decay.
 Example: carbon-14 half life is 5715. If a
  80mg sample decays over 22860 years, how
  much will remain?
 22860/5715 = 4 half lives.
 80/2=40mg     1st half life
 40/2=20mg     2nd half-life
 20/2=10mg     3rd half-life
 10/2=5mg      4th half-life
Radioactive Dating
Radioactive Dating
 An object was found with 1/8 the ratio of
  carbon-14 to carbon-12. How old is it? (one
  half-life = 5715 years)
Radioactive Dating
 An object was found with 1/8 the ratio of
  carbon-14 to carbon-12. How old is it? (one
  half-life = 5715 years)
Radioactive Dating
 An object was found with 1/8 the ratio of
  carbon-14 to carbon-12. How old is it? (one
  half-life = 5715 years)


 1 divided by 2 = ½ 1st half-life
Radioactive Dating
 An object was found with 1/8 the ratio of
  carbon-14 to carbon-12. How old is it? (one
  half-life = 5715 years)


 1 divided by 2 = ½ 1st half-life
 ½ divided by 2 = ¼ 2nd half-life
Radioactive Dating
 An object was found with 1/8 the ratio of
  carbon-14 to carbon-12. How old is it? (one
  half-life = 5715 years)


 1 divided by 2 = ½ 1st half-life
 ½ divided by 2 = ¼ 2nd half-life
 ¼ divided by 2 = 1/8 3rd half-life
Radioactive Dating
 An object was found with 1/8 the ratio of
  carbon-14 to carbon-12. How old is it? (one
  half-life = 5715 years)


 1 divided by 2 = ½ 1st half-life
 ½ divided by 2 = ¼ 2nd half-life
 ¼ divided by 2 = 1/8 3rd half-life
Radioactive Dating
 An object was found with 1/8 the ratio of
  carbon-14 to carbon-12. How old is it? (one
  half-life = 5715 years)


 1 divided by 2 = ½ 1st half-life
 ½ divided by 2 = ¼ 2nd half-life
 ¼ divided by 2 = 1/8 3rd half-life


 3 x 5715 = 17145 years
½ Life Example
½ Life Example
 A rock has 4.3mg of Potassium-40. The
  rock was dated 3.84 billion years old.
  How much Potassium-40 was originally
  present? (1 half-life = 1.28 billion years)
½ Life Example
 A rock has 4.3mg of Potassium-40. The
  rock was dated 3.84 billion years old.
  How much Potassium-40 was originally
  present? (1 half-life = 1.28 billion years)
 3.84/1.28 = 3 half lives
½ Life Example
 A rock has 4.3mg of Potassium-40. The
  rock was dated 3.84 billion years old.
  How much Potassium-40 was originally
  present? (1 half-life = 1.28 billion years)
 3.84/1.28 = 3 half lives
 4.3 x 2 = 8.6       1st half-life
½ Life Example
 A rock has 4.3mg of Potassium-40. The
  rock was dated 3.84 billion years old.
  How much Potassium-40 was originally
  present? (1 half-life = 1.28 billion years)
 3.84/1.28 = 3 half lives
 4.3 x 2 = 8.6       1st half-life
 8.6 x 2 = 17.2     2nd half-life
½ Life Example
 A rock has 4.3mg of Potassium-40. The
  rock was dated 3.84 billion years old.
  How much Potassium-40 was originally
  present? (1 half-life = 1.28 billion years)
 3.84/1.28 = 3 half lives
 4.3 x 2 = 8.6       1st half-life
 8.6 x 2 = 17.2     2nd half-life
 17.2 x 2 = 34.4    3rd half-life
½ Life Example
 A rock has 4.3mg of Potassium-40. The
  rock was dated 3.84 billion years old.
  How much Potassium-40 was originally
  present? (1 half-life = 1.28 billion years)
 3.84/1.28 = 3 half lives
 4.3 x 2 = 8.6       1st half-life
 8.6 x 2 = 17.2  2nd half-life
 17.2 x 2 = 34.4 3rd half-life
 Answer = 34.4mg
Uses of Nuclear Chemistry
 Smoke detectors: use Americium-241
 Art forgeries: found through neutron
  activation analysis.
 Medical: to diagnose and treat disease.
  X-rays
  Thallium-201 intravenously
  PET scans
Radiation Exposure
 rem: the unit used to express biological
  effects of radiation.

  0-25 no effect
  25-50 slight decrease in white cell count
  50-100 marked decrease in white cell count
  100-200 nausea and hair loss
  200-500 internal bleeding
  500+ death
Homework




Half-life problems
A New Approach
    All half life problems have 5 parts


1)Length of decay                                 length of decay
                              # of half lives =
2)Length of half life
                                                  length of half life


3)Initial amount    Divide by 2 if finding final amount.
                    Multiply by 2 if finding original amount.
4)Final amount
5)Number of half lives

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18.3 Half-Life

  • 1. Uses of Nuclear Chemistry 18.3
  • 2. Radioactive Dating  Finding the age of an object based on the amount of radioactive isotopes in it.  Example: Carbon-14 has a half life of 5715 years. Carbon-12 & Carbon-14 amounts remain constant while an object is living. When an organic artifact is found the Carbon-14 can be compared to the Carbon-12.
  • 4. Half-Life  The amount of time it takes for ½ of an unstable element to decay.
  • 5. Half-Life  The amount of time it takes for ½ of an unstable element to decay.  Example: carbon-14 half life is 5715. If a 80mg sample decays over 22860 years, how much will remain?
  • 6. Half-Life  The amount of time it takes for ½ of an unstable element to decay.  Example: carbon-14 half life is 5715. If a 80mg sample decays over 22860 years, how much will remain?  22860/5715 = 4 half lives.
  • 7. Half-Life  The amount of time it takes for ½ of an unstable element to decay.  Example: carbon-14 half life is 5715. If a 80mg sample decays over 22860 years, how much will remain?  22860/5715 = 4 half lives.  80/2=40mg 1st half life
  • 8. Half-Life  The amount of time it takes for ½ of an unstable element to decay.  Example: carbon-14 half life is 5715. If a 80mg sample decays over 22860 years, how much will remain?  22860/5715 = 4 half lives.  80/2=40mg 1st half life  40/2=20mg 2nd half-life
  • 9. Half-Life  The amount of time it takes for ½ of an unstable element to decay.  Example: carbon-14 half life is 5715. If a 80mg sample decays over 22860 years, how much will remain?  22860/5715 = 4 half lives.  80/2=40mg 1st half life  40/2=20mg 2nd half-life  20/2=10mg 3rd half-life
  • 10. Half-Life  The amount of time it takes for ½ of an unstable element to decay.  Example: carbon-14 half life is 5715. If a 80mg sample decays over 22860 years, how much will remain?  22860/5715 = 4 half lives.  80/2=40mg 1st half life  40/2=20mg 2nd half-life  20/2=10mg 3rd half-life  10/2=5mg 4th half-life
  • 12. Radioactive Dating  An object was found with 1/8 the ratio of carbon-14 to carbon-12. How old is it? (one half-life = 5715 years)
  • 13. Radioactive Dating  An object was found with 1/8 the ratio of carbon-14 to carbon-12. How old is it? (one half-life = 5715 years)
  • 14. Radioactive Dating  An object was found with 1/8 the ratio of carbon-14 to carbon-12. How old is it? (one half-life = 5715 years)  1 divided by 2 = ½ 1st half-life
  • 15. Radioactive Dating  An object was found with 1/8 the ratio of carbon-14 to carbon-12. How old is it? (one half-life = 5715 years)  1 divided by 2 = ½ 1st half-life  ½ divided by 2 = ¼ 2nd half-life
  • 16. Radioactive Dating  An object was found with 1/8 the ratio of carbon-14 to carbon-12. How old is it? (one half-life = 5715 years)  1 divided by 2 = ½ 1st half-life  ½ divided by 2 = ¼ 2nd half-life  ¼ divided by 2 = 1/8 3rd half-life
  • 17. Radioactive Dating  An object was found with 1/8 the ratio of carbon-14 to carbon-12. How old is it? (one half-life = 5715 years)  1 divided by 2 = ½ 1st half-life  ½ divided by 2 = ¼ 2nd half-life  ¼ divided by 2 = 1/8 3rd half-life
  • 18. Radioactive Dating  An object was found with 1/8 the ratio of carbon-14 to carbon-12. How old is it? (one half-life = 5715 years)  1 divided by 2 = ½ 1st half-life  ½ divided by 2 = ¼ 2nd half-life  ¼ divided by 2 = 1/8 3rd half-life  3 x 5715 = 17145 years
  • 20. ½ Life Example  A rock has 4.3mg of Potassium-40. The rock was dated 3.84 billion years old. How much Potassium-40 was originally present? (1 half-life = 1.28 billion years)
  • 21. ½ Life Example  A rock has 4.3mg of Potassium-40. The rock was dated 3.84 billion years old. How much Potassium-40 was originally present? (1 half-life = 1.28 billion years)  3.84/1.28 = 3 half lives
  • 22. ½ Life Example  A rock has 4.3mg of Potassium-40. The rock was dated 3.84 billion years old. How much Potassium-40 was originally present? (1 half-life = 1.28 billion years)  3.84/1.28 = 3 half lives  4.3 x 2 = 8.6 1st half-life
  • 23. ½ Life Example  A rock has 4.3mg of Potassium-40. The rock was dated 3.84 billion years old. How much Potassium-40 was originally present? (1 half-life = 1.28 billion years)  3.84/1.28 = 3 half lives  4.3 x 2 = 8.6 1st half-life  8.6 x 2 = 17.2 2nd half-life
  • 24. ½ Life Example  A rock has 4.3mg of Potassium-40. The rock was dated 3.84 billion years old. How much Potassium-40 was originally present? (1 half-life = 1.28 billion years)  3.84/1.28 = 3 half lives  4.3 x 2 = 8.6 1st half-life  8.6 x 2 = 17.2 2nd half-life  17.2 x 2 = 34.4 3rd half-life
  • 25. ½ Life Example  A rock has 4.3mg of Potassium-40. The rock was dated 3.84 billion years old. How much Potassium-40 was originally present? (1 half-life = 1.28 billion years)  3.84/1.28 = 3 half lives  4.3 x 2 = 8.6 1st half-life  8.6 x 2 = 17.2 2nd half-life  17.2 x 2 = 34.4 3rd half-life  Answer = 34.4mg
  • 26. Uses of Nuclear Chemistry  Smoke detectors: use Americium-241  Art forgeries: found through neutron activation analysis.  Medical: to diagnose and treat disease. X-rays Thallium-201 intravenously PET scans
  • 27. Radiation Exposure  rem: the unit used to express biological effects of radiation. 0-25 no effect 25-50 slight decrease in white cell count 50-100 marked decrease in white cell count 100-200 nausea and hair loss 200-500 internal bleeding 500+ death
  • 29. A New Approach All half life problems have 5 parts 1)Length of decay length of decay # of half lives = 2)Length of half life length of half life 3)Initial amount Divide by 2 if finding final amount. Multiply by 2 if finding original amount. 4)Final amount 5)Number of half lives

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