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Commercially Available Rheology Modifiers

                    Contents
                                      Page

   Introduction                        72
   1. Acrylic Polymers                 74
   2. Cross-linked Acrylic Polymers    81
   3. Alginates                        89
   4. Associative Thickeners           94
   5. Carrageenan                      99
   6. Microcrystalline Cellulose      106
   7. Carboxymethylcellulose Sodium   109
   8. Hydroxyethylcellulose           114
   9. Hydroxypropylcellulose          119
   10. Hydroxypropylmethylcellulose   121
   11. Methylcellulose                128
   12. Guar & Guar Derivatives        132
   13. Locust Bean Gum                138
   14. Organoclays                    141
   15. Polyethylene                   151
   16. Polyethylene Oxide             157
   17. Polyvinylpyrrolidone           161
   18. Silica                         167
   19. Water-swellable Clay           174
   20. Xanthan Gum                    184




                        71
72 Rheology Modifier Handbook


                            Introduction

This part of the handbook presents the commercially available product
lines of the 26 rheology modifier suppliers who have provided technical
information for this work. Over 1000 products are included herein. It is
also probable that there are other suppliers that the authors are not aware
of, especially in the “Pacific Rim” or South America. Handbook users in
those areas should consult local manufacturer directories to determine if
other suppliers exist in their area.

The term “commercially available” is intended to indicate that the
products listed are available to any customer in any quantity, from as
little as 50 lbs. to 50 tons or more. Many suppliers also produce other
grades of product that are classified as experimental or proprietary.
These are grades that are specially manufactured for specific large-
volume applications or customers. These grades are not included in this
handbook.

Twenty different chemical types of rheology modifiers are included in
this part of the handbook. They differ in chemical structure and
performance. Each Section begins with a brief description of the
chemical type and some key features and recommended applications for
the particular type of rheology modifier. This information is obtained
from the supplier’s technical literature and is not intended to be an
exhaustive treatise on the subject. In-depth technical information is
usually available in the supplier’s technical literature. Reference to this
technical literature is also included in the introduction to each Section.

It does not contain information on the supplier’s recommended handling
procedures for his products. This is because it may vary for different
suppliers and may, in fact, vary for different products from the same
supplier. The supplier’s technical literature is always the best source of
information on the recommended handling procedure to use.
Commercially Available Rheology Modifiers 73


In each section the product lines are presented alphabetically by
supplier’s name. Each product line is arranged according to the suppliers
recommended application area for the products, i.e., food,
pharmaceutical, personal care or household/institutional.

The product line data are believed to be complete and accurate as of
mid-1999. But suppliers are continually adding new and improved
products to their lines. The handbook user is urged to contact suppliers
(see Appendix C for contact information) to learn about new products
that might also be candidates for the intended application.

Note:
These tables also contain the following less common abbreviations:

cSt = centistoke                            n/a = not available or not
                                            applicable
mPas = milliPascal•second = centipoise      ppm = parts per million
INCI = International Nomenclature           soln = solution
Cosmetic Ingredient
µm = micrometer or micron (10-6 meter)
nm = nanometer (10-9 meter)

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Capitulo 1 a

  • 1. Part 2 Commercially Available Rheology Modifiers Contents Page Introduction 72 1. Acrylic Polymers 74 2. Cross-linked Acrylic Polymers 81 3. Alginates 89 4. Associative Thickeners 94 5. Carrageenan 99 6. Microcrystalline Cellulose 106 7. Carboxymethylcellulose Sodium 109 8. Hydroxyethylcellulose 114 9. Hydroxypropylcellulose 119 10. Hydroxypropylmethylcellulose 121 11. Methylcellulose 128 12. Guar & Guar Derivatives 132 13. Locust Bean Gum 138 14. Organoclays 141 15. Polyethylene 151 16. Polyethylene Oxide 157 17. Polyvinylpyrrolidone 161 18. Silica 167 19. Water-swellable Clay 174 20. Xanthan Gum 184 71
  • 2. 72 Rheology Modifier Handbook Introduction This part of the handbook presents the commercially available product lines of the 26 rheology modifier suppliers who have provided technical information for this work. Over 1000 products are included herein. It is also probable that there are other suppliers that the authors are not aware of, especially in the “Pacific Rim” or South America. Handbook users in those areas should consult local manufacturer directories to determine if other suppliers exist in their area. The term “commercially available” is intended to indicate that the products listed are available to any customer in any quantity, from as little as 50 lbs. to 50 tons or more. Many suppliers also produce other grades of product that are classified as experimental or proprietary. These are grades that are specially manufactured for specific large- volume applications or customers. These grades are not included in this handbook. Twenty different chemical types of rheology modifiers are included in this part of the handbook. They differ in chemical structure and performance. Each Section begins with a brief description of the chemical type and some key features and recommended applications for the particular type of rheology modifier. This information is obtained from the supplier’s technical literature and is not intended to be an exhaustive treatise on the subject. In-depth technical information is usually available in the supplier’s technical literature. Reference to this technical literature is also included in the introduction to each Section. It does not contain information on the supplier’s recommended handling procedures for his products. This is because it may vary for different suppliers and may, in fact, vary for different products from the same supplier. The supplier’s technical literature is always the best source of information on the recommended handling procedure to use.
  • 3. Commercially Available Rheology Modifiers 73 In each section the product lines are presented alphabetically by supplier’s name. Each product line is arranged according to the suppliers recommended application area for the products, i.e., food, pharmaceutical, personal care or household/institutional. The product line data are believed to be complete and accurate as of mid-1999. But suppliers are continually adding new and improved products to their lines. The handbook user is urged to contact suppliers (see Appendix C for contact information) to learn about new products that might also be candidates for the intended application. Note: These tables also contain the following less common abbreviations: cSt = centistoke n/a = not available or not applicable mPas = milliPascal•second = centipoise ppm = parts per million INCI = International Nomenclature soln = solution Cosmetic Ingredient µm = micrometer or micron (10-6 meter) nm = nanometer (10-9 meter)