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Chapter 19 “ Acids, Bases, and Salts ”
Section 19.1 Acid-Base Theories ,[object Object],[object Object]
Section 19.1 Acid-Base Theories ,[object Object],[object Object]
Properties of Acids ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Properties of Acids ,[object Object],[object Object],[object Object],[object Object],[object Object]
Acids Affect Indicators, by changing their color Blue litmus paper turns red in contact with an acid  (and red paper stays red).
Acids have a pH  less   than 7
Acids React with Active Metals Acids react with active metals to form salts and hydrogen gas: HCl (aq)  + Mg (s)   -> MgCl 2(aq)  + H 2(g) This is a single-replacement reaction
Acids React with Carbonates and Bicarbonates HCl  +  NaHCO 3 NaCl + H 2 O + CO 2 Hydrochloric acid + sodium bicarbonate salt + water + carbon dioxide An old-time home remedy for relieving an upset stomach
Effects of  Acid Rain  on Marble (marble is calcium  carbonate ) George Washington: BEFORE acid rain George Washington: AFTER acid rain
Acids  Neutralize  Bases HCl + NaOH  ->  NaCl + H 2 O - Neutralization reactions ALWAYS produce a salt (which is an  ionic compound ) and water. -Of course, it takes the  right proportion  of acid and base to produce a neutral salt
Sulfuric Acid  = H 2 SO 4 ,[object Object],[object Object],[object Object],[object Object]
Nitric Acid  = HNO 3 ,[object Object],[object Object],[object Object],[object Object]
Hydrochloric Acid  = HCl ,[object Object],[object Object],[object Object],[object Object]
Phosphoric Acid  = H 3 PO 4 ,[object Object],[object Object],[object Object],[object Object]
Acetic Acid  = HC 2 H 3 O 2  (also called Ethanoic Acid, CH 3 COOH) ,[object Object],[object Object],[object Object]
Properties of Bases   (metallic hydroxides) ,[object Object],[object Object],[object Object],[object Object],[object Object]
Examples of Bases (metallic hydroxides) ,[object Object],[object Object],[object Object],[object Object]
Bases Affect Indicators Red litmus paper turns blue in contact with a base  (and blue paper stays blue). Phenolphthalein turns purple in a base.
Bases have a pH  greater   than 7
Bases Neutralize Acids Milk of Magnesia contains magnesium hydroxide, Mg(OH) 2 , which neutralizes stomach acid, HCl. 2 HCl + Mg(OH) 2 MgCl 2  + 2 H 2 O Magnesium salts can cause diarrhea (thus they are used as a laxative) and may also cause kidney stones.
Acid-Base Theories
Svante Arrhenius ,[object Object],[object Object],[object Object]
Hubert N. Alyea (1903-1996)
1. Arrhenius Definition - 1887 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Svante Arrhenius (1859-1927)
Polyprotic Acids? ,[object Object],[object Object],[object Object],[object Object],[object Object]
Acids ,[object Object],[object Object],[object Object]
Arrhenius examples... ,[object Object],[object Object],[object Object],[object Object]
Organic Acids  (those with carbon) Organic acids all contain the  carboxyl  group,  (-COOH), sometimes several of them.  CH 3 COOH – of the 4 hydrogen, only 1 ionizable The carboxyl group is a poor proton donor, so  ALL organic acids are  weak acids . (due to being bonded to the highly electronegative  Oxygen )
2. Brønsted-Lowry - 1923 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Johannes Brønsted  Thomas Lowry   (1879-1947)  (1874-1936)   Denmark   England
Why Ammonia is a Base ,[object Object],[object Object],[object Object],[object Object]
Acids and bases come in pairs ,[object Object],[object Object],[object Object],[object Object]
Acids and bases come in pairs ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
3. Lewis Acids and Bases ,[object Object],[object Object],[object Object],[object Object],[object Object]
Gilbert Lewis (1875-1946)
- Page 593
Section 19.2 Hydrogen Ions and Acidity ,[object Object],[object Object]
Section 19.2 Hydrogen Ions and Acidity ,[object Object],[object Object]
Section 19.2 Hydrogen Ions and Acidity ,[object Object],[object Object]
Section 19.2 Hydrogen Ions and Acidity ,[object Object],[object Object]
Hydrogen Ions from Water ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Ion Product Constant ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
- Page 596
The pH concept – from 0 to 14 ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
 
Calculating pOH ,[object Object],[object Object],[object Object],[object Object],[object Object]
pH and Significant Figures ,[object Object],[object Object],[object Object]
- Page 599
- Page 600
Measuring pH ,[object Object],[object Object],[object Object]
How to measure pH with wide-range paper 1. Moisten the pH indicator paper strip with a few drops of solution, by using a stirring rod. 2.Compare the color to the chart on the vial – then read the pH value.
Some of the many pH Indicators  and their pH range
Acid-Base Indicators ,[object Object],[object Object],[object Object],[object Object]
Acid-Base Indicators ,[object Object],[object Object],[object Object],[object Object],[object Object]
Section 19.3 Strengths of Acids and Bases ,[object Object],[object Object]
Section 19.3 Strengths of Acids and Bases ,[object Object],[object Object]
Section 19.3 Strengths of Acids and Bases ,[object Object],[object Object]
Section 19.3 Strengths of Acids and Bases ,[object Object],[object Object]
Section 19.3 Strengths of Acids and Bases ,[object Object],[object Object]
Strength ,[object Object],[object Object],[object Object],[object Object]
Strength ,[object Object],[object Object],[object Object]
Strong Acid Dissociation   (makes 100 % ions)
Weak Acid Dissociation (only partially ionizes)
Measuring strength ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],(Note that water is  NOT  shown, because its concentration is constant, and built into K a ) (Note that the arrow goes both directions.)
What about bases? ,[object Object],[object Object],[object Object],[object Object],[object Object]
Strength vs. Concentration ,[object Object],[object Object],[object Object]
Practice ,[object Object],[object Object],[object Object],[object Object]
- Page 610
Section 19.4 Neutralization Reactions ,[object Object],[object Object]
Section 19.4 Neutralization Reactions ,[object Object],[object Object]
Section 19.4 Neutralization Reactions ,[object Object],[object Object]
Section 19.4 Neutralization Reactions ,[object Object],[object Object]
Acid-Base Reactions ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Acid-Base Reactions ,[object Object],[object Object],[object Object],[object Object]
Titration ,[object Object],[object Object],[object Object]
- Page 614
Titration ,[object Object],[object Object],[object Object]
Steps - Neutralization reaction ,[object Object],[object Object],[object Object],[object Object]
Neutralization ,[object Object],[object Object],[object Object],[object Object],[object Object]
Section 19.5 Salts in Solution ,[object Object],[object Object]
Section 19.5 Salts in Solution ,[object Object],[object Object]
Salt Hydrolysis ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Salt Hydrolysis ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Salt Hydrolysis ,[object Object],[object Object],[object Object],[object Object],NaCl, a  neutral  salt (NH 4 ) 2 SO 4 ,  acidic  salt CH 3 COOK,  basic  salt
Buffers ,[object Object],[object Object]
Buffers ,[object Object],[object Object],[object Object],[object Object]
Buffers ,[object Object],[object Object],[object Object]
Buffers ,[object Object],[object Object],[object Object],[object Object],[object Object]
Aspirin (which is a type of acid) sometimes causes stomach upset; thus by adding a “buffer”, it does not cause the acid irritation. Bufferin  is one brand of a buffered aspirin that is sold in stores.  What about the cost compared to plain aspirin?
End of Chapter 19

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Chemistry - Chp 19 - Acids, Bases, and Salt - PowerPoints

  • 1. Chapter 19 “ Acids, Bases, and Salts ”
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  • 6. Acids Affect Indicators, by changing their color Blue litmus paper turns red in contact with an acid (and red paper stays red).
  • 7. Acids have a pH less than 7
  • 8. Acids React with Active Metals Acids react with active metals to form salts and hydrogen gas: HCl (aq) + Mg (s) -> MgCl 2(aq) + H 2(g) This is a single-replacement reaction
  • 9. Acids React with Carbonates and Bicarbonates HCl + NaHCO 3 NaCl + H 2 O + CO 2 Hydrochloric acid + sodium bicarbonate salt + water + carbon dioxide An old-time home remedy for relieving an upset stomach
  • 10. Effects of Acid Rain on Marble (marble is calcium carbonate ) George Washington: BEFORE acid rain George Washington: AFTER acid rain
  • 11. Acids Neutralize Bases HCl + NaOH -> NaCl + H 2 O - Neutralization reactions ALWAYS produce a salt (which is an ionic compound ) and water. -Of course, it takes the right proportion of acid and base to produce a neutral salt
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  • 19. Bases Affect Indicators Red litmus paper turns blue in contact with a base (and blue paper stays blue). Phenolphthalein turns purple in a base.
  • 20. Bases have a pH greater than 7
  • 21. Bases Neutralize Acids Milk of Magnesia contains magnesium hydroxide, Mg(OH) 2 , which neutralizes stomach acid, HCl. 2 HCl + Mg(OH) 2 MgCl 2 + 2 H 2 O Magnesium salts can cause diarrhea (thus they are used as a laxative) and may also cause kidney stones.
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  • 24. Hubert N. Alyea (1903-1996)
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  • 30. Organic Acids (those with carbon) Organic acids all contain the carboxyl group, (-COOH), sometimes several of them. CH 3 COOH – of the 4 hydrogen, only 1 ionizable The carboxyl group is a poor proton donor, so ALL organic acids are weak acids . (due to being bonded to the highly electronegative Oxygen )
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  • 32. Johannes Brønsted Thomas Lowry (1879-1947) (1874-1936) Denmark England
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  • 53. How to measure pH with wide-range paper 1. Moisten the pH indicator paper strip with a few drops of solution, by using a stirring rod. 2.Compare the color to the chart on the vial – then read the pH value.
  • 54. Some of the many pH Indicators and their pH range
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  • 64. Strong Acid Dissociation (makes 100 % ions)
  • 65. Weak Acid Dissociation (only partially ionizes)
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  • 91. Aspirin (which is a type of acid) sometimes causes stomach upset; thus by adding a “buffer”, it does not cause the acid irritation. Bufferin is one brand of a buffered aspirin that is sold in stores. What about the cost compared to plain aspirin?