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Ethanoic acid (found in vinegar)

     CH₃COOH
     CH₃COO¯ (aq)
     H⁺ (aq)

Hydrochloric acid

     HCl
     Cl¯ (aq)
     H⁺ (aq)

Nitric acid

     HNO₃
     NO₃¯ (aq)
     H⁺ (aq)

Sulfuric acid

     H₂SO₄
     SO₄²¯ (aq)
     H⁺(aq)

Metal + acid -> salt + hydrogen

    - Unreactive metal (Copper & Silver) add to dilute acids -> no reaction
    - Concentrated nitric acid + metal (Eg. Copper) -> no hydrogen produced, only nitrate (salt) &
      water & nitrogen gas
    - Lead DO NOT react with dilute HCl & dilute Sulfuric acid
     Layer of lead(II)chloride / lead(II)sulfate formed from initial reaction between lead & dilute
      acid
     layer not soluble in water, quickly form coating around metal
     coating protect metal from further attack from acid



Carbonate + acid -> salt + H₂O + CO₂

Metal oxide / hydroxide + acid -> salt + water (react same way)

Acid                     Uses
Sulfuric                    -      make detergent
                            -      make fertilizers
                            -      found in car batteries
Ethanoic (in vinegar)       -      to preserve food
                            -      In making adhesives (sticky) Eg. glue
Hydrochloric (HCL)          -      in leather processing
                            -      for cleaning metals
Bases are any METAL OXIDE / METAL HYDROXIDE.

    -   contain either oxide ions ( O²¯ ) / hydroxide ions (OH¯)
    -   reacts with acid give salt & water only

Base + acid -> salt & water

    -   oxide / hydroxide ions from bases react with hydrogen ions from acid form water

Alkali is base that is soluble in water.

All alkalis produce hydroxide ions when dissolved in water.

When ammonia gas dissolve in water, ammonium ions & hydroxide ions are formed.
   Ammonia + water -> ammonium ion + hydroxide ion

Alkali + acid -> salt & water (neutralization)
     hydrogen ions from acid + hydroxide ions from alkali react form water

Alkali heated with ammonium salt give off ammonia gas.
     alkali + ammonium salt -> ammonia (alkali, pungent smell) + salt + H₂O

Alkalis react with solution of 1 metal salt to give metal hydroxide + another metal salt
     alkali +salt (metal a ) -> metal hydroxide(appears as precipitate if insoluble in water) + salt
         (metal b)

Uses of bases & alkalis

Ammonia solution

    -   in window cleaning solutions
    -   in fertilizers

Calcium oxide

    -   in neutralizing acidic soil
    -   to make iron, concrete & cement

Magnesium hydroxide

    -   in toothpaste to neutralize acid on teeth
    -   in antacids, relieve indigestion

Sodium hydroxide

    -   in making soaps & detergent
    -   in industrial-cleaning detergents
Concentration can be changed but strength cannot be changed.

  Concentration – how much a substance is dissolved in 1 dm³ of the solution?

  Strength – how easily acid / alkali dissociates when dissolved in water
       strong acid dissociate easily (HCL)
       Weak acid does not fully dissociate (Ethanoic) – much lower concentration of hydrogen ions
          in solution
          HCL strong acid no matter diluted / concentrated
          Ethanoic weak acid no matter diluted / concentrated

  PH value

      -     calculated by no. of hydrogen/ hydroxide ions present in solution
      -     acids with smaller value -> higher concentration of hydrogen ions
      -     alkalis with bigger value -> higher concentration of hydroxide ions

  Soil PH

      - plants grow best in neutral / slightly acidic soil
      - plants do not grow when soil too acidic
       happens when too much fertilizers added / acid rain
      - chemicals added to soil to raise PH
       soil too acidic, treated with base : quicklime (calcium oxide) or slaked lime (calcium
        hydroxide)
       known as “liming” the soil
       but adding too much base will make soil too alkaline and unsuitable for plant growth

Indicator                  Colour in acidic solution   pH range which indicator    Colour in alkaline
                                                       changes colour              solution
Methyl Orange                        Red                           3-5                    Yellow
Screened Methyl                     Violet                         3-5                     Green
Orange
Litmus                              Red                            5-8                     Blue
Bromothymol blue                   Yellow                          6-8                     Blue
Phenolphthalein                   Colorless                        8-10                    Pink
Oxides

    -    many acids & alkalis form by dissolving oxides in water
    -    compound of oxygen & another element
    -    4 types


     amphoteric oxides
         can behave as both basic / acidic oxide
         Eg. Zinc oxide
         can react with both acids or bases to form salt and water formed only


     neutral oxides
         show neither basic / acidic properties
         Eg. Water, Nitric oxide, carbon monoxide


     acidic oxides (non-metals)
         may dissolve in water form acids
         Carbon dioxide -> carbonic acid
         Sulfur trioxide -> sulfuric acid
         Phosphorous (V) oxide -> phosphorous acid
         does not react with acids
         react with alkalis to form salt & water

Example: Silicon (IV) oxide

         solid at room temperature
         does not dissolve in water
         react with sodium hydroxide form sodium silicate (salt)


     basic oxides (metals)
         mostly insoluble in water
         few oxide dissolve readily in water (called alkalis) (Eg. sodium oxide & potassium oxide)




         PAGE 186 DIAGRAMS!!!
Sulfur dioxide

    -   acidic oxide
    -   important for manufacture of sulfuric acid
    -   Properties & uses

1. as bleaching agent

      decolorize colored compounds, cause them to turn pale/ white
      SD bleach colour compounds by removing oxygen from them
      Substance like SD that remove oxygen from other substances -> called reducing agent
      Eg. Wood pulp to paper
     Wood pulp colored due to dyes containing oxygen

2. as food preservative

        SD poisonous to all organisms (esp. bacteria)
        In food industry, SD added to food in small amt.to prevents growth of mould & bacteria.
        Minute amt. sufficient to kill bacteria not humans but still poisonous so must strictly control
        amt. added

Sulfuric acid

    -   one of most widely used acids
    -   cheapest and most readily available strong acid
    -   Properties & uses of sulfuric acid

1. Manufacture fertilizers (Eg. Ammonium sulfate, superphosphate)

        most important use
        A. S. -> salt formed when sulfuric acid reacted with alkali ammonia
        Super. -> manufactured by reacting raw material calcium phosphate Ca₃(PO₄)₂with
        concentrated sulfuric acid (combi. of 2 calcium salts)

2. Manufacture detergents

3. Battery acid in cars

        dilute s. acid used in batteries for cars
        lead & lead(IV) plates fitted in batteries
        when s. acid, lead & lead(IV) plates react, electrical energy produced -> starts car engine

4. Used for making synthetic fibers & making paint & pigments




SEE PAGE 190 CONCEPT MAP!!!

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Acids n bases

  • 1. Ethanoic acid (found in vinegar)  CH₃COOH  CH₃COO¯ (aq)  H⁺ (aq) Hydrochloric acid  HCl  Cl¯ (aq)  H⁺ (aq) Nitric acid  HNO₃  NO₃¯ (aq)  H⁺ (aq) Sulfuric acid  H₂SO₄  SO₄²¯ (aq)  H⁺(aq) Metal + acid -> salt + hydrogen - Unreactive metal (Copper & Silver) add to dilute acids -> no reaction - Concentrated nitric acid + metal (Eg. Copper) -> no hydrogen produced, only nitrate (salt) & water & nitrogen gas - Lead DO NOT react with dilute HCl & dilute Sulfuric acid  Layer of lead(II)chloride / lead(II)sulfate formed from initial reaction between lead & dilute acid  layer not soluble in water, quickly form coating around metal  coating protect metal from further attack from acid Carbonate + acid -> salt + H₂O + CO₂ Metal oxide / hydroxide + acid -> salt + water (react same way) Acid Uses Sulfuric - make detergent - make fertilizers - found in car batteries Ethanoic (in vinegar) - to preserve food - In making adhesives (sticky) Eg. glue Hydrochloric (HCL) - in leather processing - for cleaning metals
  • 2. Bases are any METAL OXIDE / METAL HYDROXIDE. - contain either oxide ions ( O²¯ ) / hydroxide ions (OH¯) - reacts with acid give salt & water only Base + acid -> salt & water - oxide / hydroxide ions from bases react with hydrogen ions from acid form water Alkali is base that is soluble in water. All alkalis produce hydroxide ions when dissolved in water. When ammonia gas dissolve in water, ammonium ions & hydroxide ions are formed.  Ammonia + water -> ammonium ion + hydroxide ion Alkali + acid -> salt & water (neutralization)  hydrogen ions from acid + hydroxide ions from alkali react form water Alkali heated with ammonium salt give off ammonia gas.  alkali + ammonium salt -> ammonia (alkali, pungent smell) + salt + H₂O Alkalis react with solution of 1 metal salt to give metal hydroxide + another metal salt  alkali +salt (metal a ) -> metal hydroxide(appears as precipitate if insoluble in water) + salt (metal b) Uses of bases & alkalis Ammonia solution - in window cleaning solutions - in fertilizers Calcium oxide - in neutralizing acidic soil - to make iron, concrete & cement Magnesium hydroxide - in toothpaste to neutralize acid on teeth - in antacids, relieve indigestion Sodium hydroxide - in making soaps & detergent - in industrial-cleaning detergents
  • 3. Concentration can be changed but strength cannot be changed. Concentration – how much a substance is dissolved in 1 dm³ of the solution? Strength – how easily acid / alkali dissociates when dissolved in water  strong acid dissociate easily (HCL)  Weak acid does not fully dissociate (Ethanoic) – much lower concentration of hydrogen ions in solution HCL strong acid no matter diluted / concentrated Ethanoic weak acid no matter diluted / concentrated PH value - calculated by no. of hydrogen/ hydroxide ions present in solution - acids with smaller value -> higher concentration of hydrogen ions - alkalis with bigger value -> higher concentration of hydroxide ions Soil PH - plants grow best in neutral / slightly acidic soil - plants do not grow when soil too acidic  happens when too much fertilizers added / acid rain - chemicals added to soil to raise PH  soil too acidic, treated with base : quicklime (calcium oxide) or slaked lime (calcium hydroxide)  known as “liming” the soil  but adding too much base will make soil too alkaline and unsuitable for plant growth Indicator Colour in acidic solution pH range which indicator Colour in alkaline changes colour solution Methyl Orange Red 3-5 Yellow Screened Methyl Violet 3-5 Green Orange Litmus Red 5-8 Blue Bromothymol blue Yellow 6-8 Blue Phenolphthalein Colorless 8-10 Pink
  • 4. Oxides - many acids & alkalis form by dissolving oxides in water - compound of oxygen & another element - 4 types  amphoteric oxides can behave as both basic / acidic oxide Eg. Zinc oxide can react with both acids or bases to form salt and water formed only  neutral oxides show neither basic / acidic properties Eg. Water, Nitric oxide, carbon monoxide  acidic oxides (non-metals) may dissolve in water form acids Carbon dioxide -> carbonic acid Sulfur trioxide -> sulfuric acid Phosphorous (V) oxide -> phosphorous acid does not react with acids react with alkalis to form salt & water Example: Silicon (IV) oxide solid at room temperature does not dissolve in water react with sodium hydroxide form sodium silicate (salt)  basic oxides (metals) mostly insoluble in water few oxide dissolve readily in water (called alkalis) (Eg. sodium oxide & potassium oxide) PAGE 186 DIAGRAMS!!!
  • 5. Sulfur dioxide - acidic oxide - important for manufacture of sulfuric acid - Properties & uses 1. as bleaching agent decolorize colored compounds, cause them to turn pale/ white SD bleach colour compounds by removing oxygen from them Substance like SD that remove oxygen from other substances -> called reducing agent Eg. Wood pulp to paper  Wood pulp colored due to dyes containing oxygen 2. as food preservative SD poisonous to all organisms (esp. bacteria) In food industry, SD added to food in small amt.to prevents growth of mould & bacteria. Minute amt. sufficient to kill bacteria not humans but still poisonous so must strictly control amt. added Sulfuric acid - one of most widely used acids - cheapest and most readily available strong acid - Properties & uses of sulfuric acid 1. Manufacture fertilizers (Eg. Ammonium sulfate, superphosphate) most important use A. S. -> salt formed when sulfuric acid reacted with alkali ammonia Super. -> manufactured by reacting raw material calcium phosphate Ca₃(PO₄)₂with concentrated sulfuric acid (combi. of 2 calcium salts) 2. Manufacture detergents 3. Battery acid in cars dilute s. acid used in batteries for cars lead & lead(IV) plates fitted in batteries when s. acid, lead & lead(IV) plates react, electrical energy produced -> starts car engine 4. Used for making synthetic fibers & making paint & pigments SEE PAGE 190 CONCEPT MAP!!!