SlideShare una empresa de Scribd logo
1 de 8
Descargar para leer sin conexión
Safety Data Sheet
Issue Date 09/25/2009 1
Material name: FERROSILICON
* * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * *
Material Name: FERROSILICON
Manufacturer Information
Xining Metals and Minerals IM&Ex(group) Co.,ltd EMERGENCY
CONTACT:
Add: 13/F Yinlong Building, No.36 Huanghe Road,Xining,Qinghai,China
Tel:0086-971-6130129
Fax: 0086-971-6130129
Mobile: 0086-15500621952
E-mail:Export_Trader@outlook.com
Chemical Family
metal, alloy
Synonyms
FERRO SILICON (75% Si); IRON-SILICON; UN 1408; RTECS: LK1400000
Product Use
Ferro Silicon is classed as a non-hazardous item and not subject to UN 1408 provided that it meets
Special Provision 39 and 223 of the Dangerous Goods List. The Dangerous Goods exemption is
valid upon presentation of: A) A signed statement by the supplier that the referenced shipment was
stored under cover, but in the open air, in the size in which it was packed, for not less than 3 days
prior to shipment. B) A certificate from an accredited laboratory stating that the referenced
shipment was tested in accordance with 1) The IMDG Code 2) The United Nations
recommendations on the transport of Dangerous Goods, Manual of Tests and Criteria Part III-
33.4.1.4. Whose Test results indicate that the cargo form which the sampling was done shows that
it is non-dangerous cargo.
* * * Section 2 - HAZARDS IDENTIFICATION * * *
EMERGENCY OVERVIEW
Physical Form: crystals
Odor: odorless
Physical Hazards: Negligible fire and explosion hazard in bulk form. Dust/air mixtures may
ignite or explode.
Reacts violently with water to generate toxic and/or flammable gases.
POTENTIAL HEALTH EFFECTS
Inhalation
Short Term: irritation, metal fume fever
Long Term: difficulty breathing, lung damage
Skin
Short Term: irritation
Long Term: no information is available
Eye
Short Term: irritation, glaucoma
Long Term: same as effects reported in short term exposure
Safety Data Sheet
Issue Date 09/25/2009 2
Ingestion
Short Term: vomiting, diarrhea
Long Term: no information on significant adverse effects
* * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * *
CAS Component Percent Symbol(s) Risk Phrase(s)
8049-17-0 FERROSILICON 100.0 --- ---
* * * Section 4 - FIRST AID MEASURES * * *
Inhalation
If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not
breathing. Get immediate medical attention.
Skin
Wash skin with soap and water for at least 15 minutes while removing contaminated clothing
and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing
and shoes before reuse.
Eyes
Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical
attention.
Ingestion
If a large amount is swallowed, get medical attention.
* * * Section 5 - FIRE FIGHTING MEASURES * * *
See Section 9 for Flammability Properties
NFPA Ratings: Health: 1 Fire: 3 Re-activity : 2
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Flammable Properties
Negligible fire and explosion hazard in bulk form. Dust/air mixtures may ignite or explode.
Extinguishing Media
regular dry chemical, dry sand, lime, soda ash
Large fires: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire
burn.
Fire Fighting Measures
Do not use water. Do not use foam. Move container from fire area if it can be done without
risk. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material
or combustion by-products.
Thermal Decomposition Products
Water or Moisture: arsine, hydrogen, phosphine
* * * Section 6 - ACCIDENTAL RELEASE MEASURES * * *
Occupational spill/release
Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Do
not get water directly on material. Do not get water inside container. Small spills: Collect
spilled material in appropriate container for disposal. Move containers away from spill to a
safe area. Large spills: Dike for later disposal. Cover with plastic sheet or tarp to minimize
Safety Data Sheet
Issue Date 09/25/2009 3
spreading and protect from contact with water. Only personnel trained for the hazards of this
material should perform clean up and disposal. Keep unnecessary people away, isolate hazard area
and deny entry.
* * * Section 7 - HANDLING AND STORAGE * * *
Handling Procedures
Use methods to minimize dust.
Storage Procedures
Store and handle in accordance with all current regulations and standards. Keep separated
from incompatible substances.
* * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * *
Component Exposure Limits
ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of
this product's components.
Ventilation
Ventilation equipment should be explosion-resistant if explosive concentrations of material
are present. Provide local exhaust ventilation system. Ensure compliance with applicable
exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Eyes/Face
Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick
drench shower in the immediate work area.
Protective Clothing
Wear appropriate chemical resistant clothing.
Glove Recommendations
Wear appropriate chemical resistant gloves.
Respiratory Protection
Under conditions of frequent use or heavy exposure, respiratory protection may be needed.
Respiratory protection is ranked in order from minimum to maximum.
Consider warning properties before use.
Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and
P95 filtering facepieces) except quarter-mask respirators. The following filters may also be
used: N99, R99, P99, N100, R100 or P100.
Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The
following filters may also be used: N99, R99, P99, N100, R100 or P100.
Any powered, air-purifying respirator with a high-efficiency particulate filter.
Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency
particulate filter.
Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or
other positive-pressure mode.
For Unknown Concentrations or Immediately Dangerous to Life or Health -
Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or
other positive-pressure mode in combination with an auxiliary self-contained breathing
apparatus operated in pressure-demand or other
positive-pressure mode.
Safety Data Sheet
Issue Date 09/25/2009 4
Any self-contained breathing apparatus that has a full facepiece and is operated in a
pressure-demand or other positive-pressure mode.
* * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * *
Physical State: Solid Appearance: Not available
Physical Form: crystals Odor: odorless
Odor Threshold: Not available Melting Point: Not available
Boiling Point: Not applicable Flash Point: flammable
Vapor Pressure: Not applicable Vapor Density (air = 1): Not applicable
Density: Not available Specific Gravity (water = 1):5.4
Water Solubility:reacts Coeff. Water/Oil Dist: Not available
* * * Section 10 - STABILITY AND REACTIVITY * * *
Chemical Stability
Reacts violently with water to generate toxic and/or flammable gases.
Conditions to Avoid
Dangerous gases may accumulate in confined spaces. Keep out of water supplies and sewers.
Materials to Avoid
acids, bases, oxidizing materials
FERROSILICON:
ACIDS: May evolve highly toxic and flammable arsine, phosphine, and acetylene
gases if impurities present.
ALKALIS: May evolve highly toxic and flammable arsine, phosphine, and
acetylene gases if impurities present.
CAUSTIC SODA: May release flammable hydrogen gas.
OXIDIZING MATERIALS: May react.
Decomposition Products
miscellaneous decomposition products
Thermal Decomposition of Products
Water or Moisture: arsine, hydrogen, phosphine
No data available.
Possibility of Hazardous Reactions
Will not polymerize.
* * * Section 11 - TOXICOLOGICAL INFORMATION * * *
Component Analysis - LD50/LC50
The components of this material have been reviewed in various sources and the following
selected endpoints are published:
FERROSILICON (8049-17-0)
Dermal LD50 Rabbit: >20 g/kg
RTECS Acute Toxicity (selected)
The components of this material have been reviewed, and RTECS publishes the following
endpoints:
FERROSILICON (8049-17-0)
Safety Data Sheet
Issue Date 09/25/2009 5
Skin: >20 gm/kg skin rabbit LD50
Component Carcinogenicity
None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA.
RTECS Irritation
The components of this material have been reviewed and RTECS publishes no data as of the
date on this document.
HEALTH EFFECTS
Inhalation - Acute Exposure
SILICON: Dust may cause respiratory and mucous membrane irritation and cough.
Intratracheal administration of 25 mg in rabbits produced slight pulmonary lesions. IRON:
Dust may cause mucous membrane and respiratory irritation due to mechanical action. Metal
fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed iron
oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns. Symptoms
may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic or
foul taste in the mouth. Other symptoms may include upper respiratory tract irritation
accompanied by coughing and a dryness of the mucous membranes. Lassitude and a
generalized feeling of malaise. Fever, chills, muscular pain, mild to severe headache, nausea,
occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination,
diarrhea and prostration may also occur. Tolerance to fumes develops rapidly, but is quickly
lost. All symptoms usually subside within 24-36 hours.
Inhalation - Chronic Exposure
SILICON: Inert dust may cause excessive production of mucous, mucous gland hypertrophy,
and increased airway resistance and may contribute to chronic bronchitis. IRON: Prolonged
or repeated exposure may cause a mottling of the lungs, a condition called siderosis which is
considered to be a benign pneumoconiosis that does not cause significant physiologic
impairment. Symptoms may include chronic bronchitis, emphysema, and dyspnea on
exertion.
Skin Contact - Acute Exposure
SILICON: May cause mechanical irritation. IRON: Dust may cause irritation. Penetration of
iron particles in the skin may cause an exogenous siderosis which may be characterized by a
red-brown pigmentation of the affected area.
Skin Contact - Chronic Exposure
SILICON: No data available. IRON: May cause same effects as reported in acute exposure.
Eye Contact - Acute Exposure
SILICON: Silicon dust may cause irritation. IRON: May cause irritation due to mechanical
action. Iron particles imbedded in the eye may cause ocular siderosis. Effects may include
discoloration of the cornea and iris, and pupillary effects including poor reaction to light and
accomodation. If a particle enters the lens there may be cataract formation. Glaucoma occurs
rarely in some cases of ocular siderosis.
Eye Contact - Chronic Exposure
SILICON: No data available. IRON: Repeated and prolonged contact may cause
conjunctivitis and other effects reported in acute exposure.
Ingestion - Acute Exposure
SILICON: May cause digestive tract irritation. IRON: There are no reports available on
Safety Data Sheet
Issue Date 09/25/2009 6
poisoning from metallic iron, which is poorly absorbed. The principal manifestations of
poisoning with iron compounds are vomiting, diarrhea, and circulatory collapse.
Ingestion - Chronic Exposure
SILICON: No data available. IRON: Repeated or prolonged exposure may cause
hemosiderosis or hemochromatosis.
* * * Section 12 - ECOLOGICAL INFORMATION * * *
Component Analysis - Aquatic Toxicity
No LOLI ecotoxicity data are available for this product's components.
* * * Section 13 - DISPOSAL CONSIDERATIONS * * *
Disposal Methods
Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S.
EPA 40 CFR 262. Hazardous Waste Number(s): D001. D003.
Component Waste Numbers
The U.S. EPA has not published waste numbers for this product's components.
* * * Section 14 - TRANSPORT INFORMATION * * *
US DOT Information
Shipping Name: Ferrosilicon
UN/NA #: UN1408 Hazard Class: 4.3 Packing Group: III
Required Label(s): 4.3, 6.1
TDG Information
Shipping Name: Ferrosilicon
UN #: UN1408 Hazard Class: 4.3 Packing Group: III
Required Label(s): 4.3, (6.1)
ADR Information
Shipping Name: Ferrosilicon
UN #: UN1408 Hazard Class: 4.3 Packing Group: III
Required Label(s): 4.3, 6.1
ADR Tunnel Code Restrictions
This list contains tunnel restriction codes for those substances and/or chemically related
entries which are found in chapter 3.2 of the ADR regulations.
FERROSILICON (8049-17-0)
RID Information
Shipping Name: Ferrosilicon
UN #: UN1408 Hazard Class: 4.3 Packing Group: III
Required Label(s): 4.3, 6.1
IATA Information
Shipping Name: Ferrosilicon
UN #: UN1408 Hazard Class: 4.3 Packing Group: III
Required Label(s): 4.3, 6.1
ICAO Information
Shipping Name: Ferrosilicon
UN #: UN1408 Hazard Class: 4.3 Packing Group: III
Required Label(s): 4.3, 6.1
IMDG Information
Safety Data Sheet
Issue Date 09/25/2009 7
Shipping Name: Ferrosilicon
UN #: UN1408 Hazard Class: 4.3 Packing Group: III
Required Label(s): 6.1
* * * Section 15 - REGULATORY INFORMATION * * *
U.S. Federal Regulations
None of this products components are listed under SARA Section 302 (40 CFR 355
Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65),
CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan.
SARA Section 311/312 (40 CFR 370 Subparts B and C)
Acute Health: No Chronic Health: No Fire: Yes Pressure: No Reactive: Yes
U.S. State Regulations
The following components appear on one or more of the following state hazardous
substances lists:
Component CAS CA MA MN NJ PA RI
FERROSILICON 8049-17-0 No No No Yes No No
Not regulated under California Proposition 65
Canada
Canada WHMIS
The following components are identified under the Canadian Hazardous Products Act
Ingredient Disclosure List: FERROSILICON (8049-17-0)
1 %
Safety Phrases
S8 Keep container dry. S30 Never add water to this product.
Component Analysis - Inventory
Component CAS US CA EU AU PH JP KR CN NZ
FERROSILICON 8049-17-0 No No No Yes Yes No No No Yes
* * * Section 16 - OTHER INFORMATION * * *
Key / Legend
ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European
Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA -
Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental
Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products
Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of
Transportation; DSL - Domestic Substances List; EEC - European Economic Community;
EINECS - European Inventory of Existing Commercial Chemical Substances; EPA -
Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC -
International Agency for Research on Cancer; IATA - International Air Transport Association;
ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH -
Safety Data Sheet
Issue Date 09/25/2009 8
Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous
Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower
Explosive Limit; LOLI - List Of LIsts. - ChemADVISOR's Regulatory Database; MAK -
Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits;
NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety
and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology
Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH -
Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail
Transport; RTECS - Registry of Toxic Effects of Chemical Substances.; SARA - Superfund
Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG -
Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time
Weighted Average; UEL - Upper Explosive Limit; US - United States
Other Information
Reasonable care has been taken in the preparation of this information, but the manufacturer
makes no warranty of merchantability or any other warranty, expressed or implied, with
respect to this information. The manufacturer makes no representations and assumes no
liability for any direct, incidental or consequential damages resulting from its use.
Disclaimer: Supplier gives no warranty of merchantability or of fitness for a particular
purpose. Any product purchased is sold on the assumption the purchaser will make his own
tests to determine the quality and suitability of the product. Supplier expressly disclaims any
and all liability for incidental and/or consequential property damage arising out of the use of
this product. No information provided shall be deemed to be a recommendation to use any
product in conflict with any existing patent rights. THIS MSDS IS TO BE UTILIZED
SOLEY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY
THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION
STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR).
Read the Material Safety Data Sheet before handling product.
Copyright
Copyright 1984-2009 ChemADVISOR, Inc. All rights reserved.
RTECS is a United States trademark owned and licensed under authority of the U.S.
Government, by and through Symyx Software Inc.
Portions Copyright 2001, U.S. Government. All rights reserved.
End of Sheet

Más contenido relacionado

La actualidad más candente

Msds ingersoll rand ultra coolant
Msds ingersoll rand ultra coolantMsds ingersoll rand ultra coolant
Msds ingersoll rand ultra coolantKiên Nguyễn
 
Valeo Braking Systems Hydraulic Mineral Fluid LHM+ material safety data sheet...
Valeo Braking Systems Hydraulic Mineral Fluid LHM+ material safety data sheet...Valeo Braking Systems Hydraulic Mineral Fluid LHM+ material safety data sheet...
Valeo Braking Systems Hydraulic Mineral Fluid LHM+ material safety data sheet...Hugo Vallet
 
Valeo Braking Systems Hydraulic Mineral Fluid LHM standard material safety da...
Valeo Braking Systems Hydraulic Mineral Fluid LHM standard material safety da...Valeo Braking Systems Hydraulic Mineral Fluid LHM standard material safety da...
Valeo Braking Systems Hydraulic Mineral Fluid LHM standard material safety da...Hugo Vallet
 
Functionalization of CNTs_SMPA REVISED
Functionalization of CNTs_SMPA REVISEDFunctionalization of CNTs_SMPA REVISED
Functionalization of CNTs_SMPA REVISEDPatrick Warren
 
Energol ic-hfx-404-9389 Liên hệ: Mr Tùng 0987 988 407 website: www.khodaumo.com
Energol ic-hfx-404-9389 Liên hệ: Mr Tùng 0987 988 407  website: www.khodaumo.comEnergol ic-hfx-404-9389 Liên hệ: Mr Tùng 0987 988 407  website: www.khodaumo.com
Energol ic-hfx-404-9389 Liên hệ: Mr Tùng 0987 988 407 website: www.khodaumo.comĐỗ Bá Tùng
 
Pigment dpp orange 71 cas 84632 50-8 safety data sheet msds sds baoxu chemical
Pigment dpp orange 71 cas 84632 50-8 safety data sheet msds sds baoxu chemicalPigment dpp orange 71 cas 84632 50-8 safety data sheet msds sds baoxu chemical
Pigment dpp orange 71 cas 84632 50-8 safety data sheet msds sds baoxu chemicalDongguan Baoxu Chemical Technical Co.,Ltd.
 
Pigment yellow 110 yellow 2rlp cas 5590 18-1 safety data sheet msds sds baox...
Pigment yellow 110  yellow 2rlp cas 5590 18-1 safety data sheet msds sds baox...Pigment yellow 110  yellow 2rlp cas 5590 18-1 safety data sheet msds sds baox...
Pigment yellow 110 yellow 2rlp cas 5590 18-1 safety data sheet msds sds baox...Dongguan Baoxu Chemical Technical Co.,Ltd.
 
Msds aseton
Msds asetonMsds aseton
Msds asetonapril m
 
10365 98-7
10365 98-710365 98-7
10365 98-7MiMi Joy
 
Optical brightener er i 13001-39-3 msds baoxu chemical additivesforpolymer do...
Optical brightener er i 13001-39-3 msds baoxu chemical additivesforpolymer do...Optical brightener er i 13001-39-3 msds baoxu chemical additivesforpolymer do...
Optical brightener er i 13001-39-3 msds baoxu chemical additivesforpolymer do...Dongguan Baoxu Chemical Technical Co.,Ltd.
 
Pigment blue 15:0 phthalo blue 15:0 147-14-8 material safety data sheet msds ...
Pigment blue 15:0 phthalo blue 15:0 147-14-8 material safety data sheet msds ...Pigment blue 15:0 phthalo blue 15:0 147-14-8 material safety data sheet msds ...
Pigment blue 15:0 phthalo blue 15:0 147-14-8 material safety data sheet msds ...Dongguan Baoxu Chemical Technical Co.,Ltd.
 

La actualidad más candente (20)

Msds ingersoll rand ultra coolant
Msds ingersoll rand ultra coolantMsds ingersoll rand ultra coolant
Msds ingersoll rand ultra coolant
 
Paraffin wax Nam Hải
Paraffin wax Nam HảiParaffin wax Nam Hải
Paraffin wax Nam Hải
 
Stone craft Material Safety Data Sheet
Stone craft Material Safety Data SheetStone craft Material Safety Data Sheet
Stone craft Material Safety Data Sheet
 
Stone craft msds-3-25-14
Stone craft msds-3-25-14Stone craft msds-3-25-14
Stone craft msds-3-25-14
 
Valeo Braking Systems Hydraulic Mineral Fluid LHM+ material safety data sheet...
Valeo Braking Systems Hydraulic Mineral Fluid LHM+ material safety data sheet...Valeo Braking Systems Hydraulic Mineral Fluid LHM+ material safety data sheet...
Valeo Braking Systems Hydraulic Mineral Fluid LHM+ material safety data sheet...
 
Valeo Braking Systems Hydraulic Mineral Fluid LHM standard material safety da...
Valeo Braking Systems Hydraulic Mineral Fluid LHM standard material safety da...Valeo Braking Systems Hydraulic Mineral Fluid LHM standard material safety da...
Valeo Braking Systems Hydraulic Mineral Fluid LHM standard material safety da...
 
Functionalization of CNTs_SMPA REVISED
Functionalization of CNTs_SMPA REVISEDFunctionalization of CNTs_SMPA REVISED
Functionalization of CNTs_SMPA REVISED
 
Energol ic-hfx-404-9389 Liên hệ: Mr Tùng 0987 988 407 website: www.khodaumo.com
Energol ic-hfx-404-9389 Liên hệ: Mr Tùng 0987 988 407  website: www.khodaumo.comEnergol ic-hfx-404-9389 Liên hệ: Mr Tùng 0987 988 407  website: www.khodaumo.com
Energol ic-hfx-404-9389 Liên hệ: Mr Tùng 0987 988 407 website: www.khodaumo.com
 
Msds
MsdsMsds
Msds
 
Klip data sheet
Klip data sheetKlip data sheet
Klip data sheet
 
Uv 531 chimassorb 81 cas 1843 05-6 safety data sheet msds sds baoxu chemical
Uv 531 chimassorb 81 cas 1843 05-6 safety data sheet msds sds baoxu chemicalUv 531 chimassorb 81 cas 1843 05-6 safety data sheet msds sds baoxu chemical
Uv 531 chimassorb 81 cas 1843 05-6 safety data sheet msds sds baoxu chemical
 
Pigment dpp orange 71 cas 84632 50-8 safety data sheet msds sds baoxu chemical
Pigment dpp orange 71 cas 84632 50-8 safety data sheet msds sds baoxu chemicalPigment dpp orange 71 cas 84632 50-8 safety data sheet msds sds baoxu chemical
Pigment dpp orange 71 cas 84632 50-8 safety data sheet msds sds baoxu chemical
 
Pigment yellow 110 yellow 2rlp cas 5590 18-1 safety data sheet msds sds baox...
Pigment yellow 110  yellow 2rlp cas 5590 18-1 safety data sheet msds sds baox...Pigment yellow 110  yellow 2rlp cas 5590 18-1 safety data sheet msds sds baox...
Pigment yellow 110 yellow 2rlp cas 5590 18-1 safety data sheet msds sds baox...
 
Msds hcl
Msds hclMsds hcl
Msds hcl
 
Msds aseton
Msds asetonMsds aseton
Msds aseton
 
Msds na cl
Msds na clMsds na cl
Msds na cl
 
10365 98-7
10365 98-710365 98-7
10365 98-7
 
Optical brightener er i 13001-39-3 msds baoxu chemical additivesforpolymer do...
Optical brightener er i 13001-39-3 msds baoxu chemical additivesforpolymer do...Optical brightener er i 13001-39-3 msds baoxu chemical additivesforpolymer do...
Optical brightener er i 13001-39-3 msds baoxu chemical additivesforpolymer do...
 
Pigment blue 15:0 phthalo blue 15:0 147-14-8 material safety data sheet msds ...
Pigment blue 15:0 phthalo blue 15:0 147-14-8 material safety data sheet msds ...Pigment blue 15:0 phthalo blue 15:0 147-14-8 material safety data sheet msds ...
Pigment blue 15:0 phthalo blue 15:0 147-14-8 material safety data sheet msds ...
 
MSDS Cosmesome Containing Alcohol
MSDS Cosmesome Containing AlcoholMSDS Cosmesome Containing Alcohol
MSDS Cosmesome Containing Alcohol
 

Similar a MSDS Fesi75

Upol safety data sheet
Upol safety data sheetUpol safety data sheet
Upol safety data sheetPatrick Alford
 
Buy customized variations of Acetic Acid Sds
Buy customized variations of Acetic Acid SdsBuy customized variations of Acetic Acid Sds
Buy customized variations of Acetic Acid SdsAlexCarter68
 
Buy customized variations of Acetic Acid Sds
Buy customized variations of Acetic Acid SdsBuy customized variations of Acetic Acid Sds
Buy customized variations of Acetic Acid SdsApolloOpticalSystems1
 
100.00.10.21 msds nitrogen, compressed gas
100.00.10.21 msds nitrogen, compressed gas100.00.10.21 msds nitrogen, compressed gas
100.00.10.21 msds nitrogen, compressed gasrickkaun
 
White Petroleum Jelly MSDS | Elchemy
White Petroleum Jelly MSDS | ElchemyWhite Petroleum Jelly MSDS | Elchemy
White Petroleum Jelly MSDS | ElchemyElchemy
 
Centurion max msds
Centurion max msdsCenturion max msds
Centurion max msdsarysta123
 
Antioxidant 1098 irganox 1098 23128-74-7 safety data sheet msds sds baoxu che...
Antioxidant 1098 irganox 1098 23128-74-7 safety data sheet msds sds baoxu che...Antioxidant 1098 irganox 1098 23128-74-7 safety data sheet msds sds baoxu che...
Antioxidant 1098 irganox 1098 23128-74-7 safety data sheet msds sds baoxu che...Dongguan Baoxu Chemical Technical Co.,Ltd.
 
MSDS-Petron-Industrial-Diesel-Fuel.pdf
MSDS-Petron-Industrial-Diesel-Fuel.pdfMSDS-Petron-Industrial-Diesel-Fuel.pdf
MSDS-Petron-Industrial-Diesel-Fuel.pdfCatherineLasco1
 
MATERIAL SAFETY DATA SHEET FOR HALON.
MATERIAL SAFETY DATA SHEET FOR HALON.MATERIAL SAFETY DATA SHEET FOR HALON.
MATERIAL SAFETY DATA SHEET FOR HALON.Halon Us
 
Sáp nến công nghiệp
Sáp nến công nghiệpSáp nến công nghiệp
Sáp nến công nghiệpHoangMinhDuong1
 
Fly Ash - Safety Data Sheet
Fly Ash - Safety Data SheetFly Ash - Safety Data Sheet
Fly Ash - Safety Data SheetLilyShubina
 
100.00.10.23 msds oxygen, compressed gas
100.00.10.23 msds oxygen, compressed gas100.00.10.23 msds oxygen, compressed gas
100.00.10.23 msds oxygen, compressed gasrickkaun
 

Similar a MSDS Fesi75 (20)

22711.pdf
22711.pdf22711.pdf
22711.pdf
 
Upol safety data sheet
Upol safety data sheetUpol safety data sheet
Upol safety data sheet
 
Buy customized variations of Acetic Acid Sds
Buy customized variations of Acetic Acid SdsBuy customized variations of Acetic Acid Sds
Buy customized variations of Acetic Acid Sds
 
Buy customized variations of Acetic Acid Sds
Buy customized variations of Acetic Acid SdsBuy customized variations of Acetic Acid Sds
Buy customized variations of Acetic Acid Sds
 
100.00.10.21 msds nitrogen, compressed gas
100.00.10.21 msds nitrogen, compressed gas100.00.10.21 msds nitrogen, compressed gas
100.00.10.21 msds nitrogen, compressed gas
 
White Petroleum Jelly MSDS | Elchemy
White Petroleum Jelly MSDS | ElchemyWhite Petroleum Jelly MSDS | Elchemy
White Petroleum Jelly MSDS | Elchemy
 
Benzoic acid
Benzoic acidBenzoic acid
Benzoic acid
 
Centurion max msds
Centurion max msdsCenturion max msds
Centurion max msds
 
Cp lmodus400-gb1
Cp lmodus400-gb1Cp lmodus400-gb1
Cp lmodus400-gb1
 
00064500.pdf
00064500.pdf00064500.pdf
00064500.pdf
 
Antioxidant 1098 irganox 1098 23128-74-7 safety data sheet msds sds baoxu che...
Antioxidant 1098 irganox 1098 23128-74-7 safety data sheet msds sds baoxu che...Antioxidant 1098 irganox 1098 23128-74-7 safety data sheet msds sds baoxu che...
Antioxidant 1098 irganox 1098 23128-74-7 safety data sheet msds sds baoxu che...
 
MSDS-Petron-Industrial-Diesel-Fuel.pdf
MSDS-Petron-Industrial-Diesel-Fuel.pdfMSDS-Petron-Industrial-Diesel-Fuel.pdf
MSDS-Petron-Industrial-Diesel-Fuel.pdf
 
MATERIAL SAFETY DATA SHEET FOR HALON.
MATERIAL SAFETY DATA SHEET FOR HALON.MATERIAL SAFETY DATA SHEET FOR HALON.
MATERIAL SAFETY DATA SHEET FOR HALON.
 
Sáp nến công nghiệp
Sáp nến công nghiệpSáp nến công nghiệp
Sáp nến công nghiệp
 
Fly Ash - Safety Data Sheet
Fly Ash - Safety Data SheetFly Ash - Safety Data Sheet
Fly Ash - Safety Data Sheet
 
100.00.10.23 msds oxygen, compressed gas
100.00.10.23 msds oxygen, compressed gas100.00.10.23 msds oxygen, compressed gas
100.00.10.23 msds oxygen, compressed gas
 
Hals 944 chimassorb 944 70624-18-9 safety data sheet msds sds baoxu chemical
Hals 944 chimassorb 944 70624-18-9 safety data sheet msds sds baoxu chemicalHals 944 chimassorb 944 70624-18-9 safety data sheet msds sds baoxu chemical
Hals 944 chimassorb 944 70624-18-9 safety data sheet msds sds baoxu chemical
 
Yubase4 eng
Yubase4 engYubase4 eng
Yubase4 eng
 
Msdsu ksunfood hf 32
Msdsu ksunfood hf 32Msdsu ksunfood hf 32
Msdsu ksunfood hf 32
 
white-cement MSDS.pdf
white-cement MSDS.pdfwhite-cement MSDS.pdf
white-cement MSDS.pdf
 

MSDS Fesi75

  • 1. Safety Data Sheet Issue Date 09/25/2009 1 Material name: FERROSILICON * * * Section 1 - PRODUCT AND COMPANY IDENTIFICATION * * * Material Name: FERROSILICON Manufacturer Information Xining Metals and Minerals IM&Ex(group) Co.,ltd EMERGENCY CONTACT: Add: 13/F Yinlong Building, No.36 Huanghe Road,Xining,Qinghai,China Tel:0086-971-6130129 Fax: 0086-971-6130129 Mobile: 0086-15500621952 E-mail:Export_Trader@outlook.com Chemical Family metal, alloy Synonyms FERRO SILICON (75% Si); IRON-SILICON; UN 1408; RTECS: LK1400000 Product Use Ferro Silicon is classed as a non-hazardous item and not subject to UN 1408 provided that it meets Special Provision 39 and 223 of the Dangerous Goods List. The Dangerous Goods exemption is valid upon presentation of: A) A signed statement by the supplier that the referenced shipment was stored under cover, but in the open air, in the size in which it was packed, for not less than 3 days prior to shipment. B) A certificate from an accredited laboratory stating that the referenced shipment was tested in accordance with 1) The IMDG Code 2) The United Nations recommendations on the transport of Dangerous Goods, Manual of Tests and Criteria Part III- 33.4.1.4. Whose Test results indicate that the cargo form which the sampling was done shows that it is non-dangerous cargo. * * * Section 2 - HAZARDS IDENTIFICATION * * * EMERGENCY OVERVIEW Physical Form: crystals Odor: odorless Physical Hazards: Negligible fire and explosion hazard in bulk form. Dust/air mixtures may ignite or explode. Reacts violently with water to generate toxic and/or flammable gases. POTENTIAL HEALTH EFFECTS Inhalation Short Term: irritation, metal fume fever Long Term: difficulty breathing, lung damage Skin Short Term: irritation Long Term: no information is available Eye Short Term: irritation, glaucoma Long Term: same as effects reported in short term exposure
  • 2. Safety Data Sheet Issue Date 09/25/2009 2 Ingestion Short Term: vomiting, diarrhea Long Term: no information on significant adverse effects * * * Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS * * * CAS Component Percent Symbol(s) Risk Phrase(s) 8049-17-0 FERROSILICON 100.0 --- --- * * * Section 4 - FIRST AID MEASURES * * * Inhalation If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. Get immediate medical attention. Skin Wash skin with soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention, if needed. Thoroughly clean and dry contaminated clothing and shoes before reuse. Eyes Flush eyes with plenty of water for at least 15 minutes. Then get immediate medical attention. Ingestion If a large amount is swallowed, get medical attention. * * * Section 5 - FIRE FIGHTING MEASURES * * * See Section 9 for Flammability Properties NFPA Ratings: Health: 1 Fire: 3 Re-activity : 2 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe Flammable Properties Negligible fire and explosion hazard in bulk form. Dust/air mixtures may ignite or explode. Extinguishing Media regular dry chemical, dry sand, lime, soda ash Large fires: Keep unnecessary people away, isolate hazard area and deny entry. Let the fire burn. Fire Fighting Measures Do not use water. Do not use foam. Move container from fire area if it can be done without risk. Use extinguishing agents appropriate for surrounding fire. Avoid inhalation of material or combustion by-products. Thermal Decomposition Products Water or Moisture: arsine, hydrogen, phosphine * * * Section 6 - ACCIDENTAL RELEASE MEASURES * * * Occupational spill/release Avoid heat, flames, sparks and other sources of ignition. Do not touch spilled material. Do not get water directly on material. Do not get water inside container. Small spills: Collect spilled material in appropriate container for disposal. Move containers away from spill to a safe area. Large spills: Dike for later disposal. Cover with plastic sheet or tarp to minimize
  • 3. Safety Data Sheet Issue Date 09/25/2009 3 spreading and protect from contact with water. Only personnel trained for the hazards of this material should perform clean up and disposal. Keep unnecessary people away, isolate hazard area and deny entry. * * * Section 7 - HANDLING AND STORAGE * * * Handling Procedures Use methods to minimize dust. Storage Procedures Store and handle in accordance with all current regulations and standards. Keep separated from incompatible substances. * * * Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION * * * Component Exposure Limits ACGIH, NIOSH, EU, OSHA (US) and Mexico have not developed exposure limits for any of this product's components. Ventilation Ventilation equipment should be explosion-resistant if explosive concentrations of material are present. Provide local exhaust ventilation system. Ensure compliance with applicable exposure limits. PERSONAL PROTECTIVE EQUIPMENT Eyes/Face Wear splash resistant safety goggles. Provide an emergency eye wash fountain and quick drench shower in the immediate work area. Protective Clothing Wear appropriate chemical resistant clothing. Glove Recommendations Wear appropriate chemical resistant gloves. Respiratory Protection Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked in order from minimum to maximum. Consider warning properties before use. Any particulate respirator equipped with an N95, R95, or P95 filter (including N95, R95, and P95 filtering facepieces) except quarter-mask respirators. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any air-purifying full-facepiece respirator equipped with an N95, R95, or P95 filter. The following filters may also be used: N99, R99, P99, N100, R100 or P100. Any powered, air-purifying respirator with a high-efficiency particulate filter. Any powered, air-purifying respirator with a tight-fitting facepiece and a high-efficiency particulate filter. Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode. For Unknown Concentrations or Immediately Dangerous to Life or Health - Any supplied-air respirator with a full facepiece that is operated in a pressure-demand or other positive-pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive-pressure mode.
  • 4. Safety Data Sheet Issue Date 09/25/2009 4 Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive-pressure mode. * * * Section 9 - PHYSICAL AND CHEMICAL PROPERTIES * * * Physical State: Solid Appearance: Not available Physical Form: crystals Odor: odorless Odor Threshold: Not available Melting Point: Not available Boiling Point: Not applicable Flash Point: flammable Vapor Pressure: Not applicable Vapor Density (air = 1): Not applicable Density: Not available Specific Gravity (water = 1):5.4 Water Solubility:reacts Coeff. Water/Oil Dist: Not available * * * Section 10 - STABILITY AND REACTIVITY * * * Chemical Stability Reacts violently with water to generate toxic and/or flammable gases. Conditions to Avoid Dangerous gases may accumulate in confined spaces. Keep out of water supplies and sewers. Materials to Avoid acids, bases, oxidizing materials FERROSILICON: ACIDS: May evolve highly toxic and flammable arsine, phosphine, and acetylene gases if impurities present. ALKALIS: May evolve highly toxic and flammable arsine, phosphine, and acetylene gases if impurities present. CAUSTIC SODA: May release flammable hydrogen gas. OXIDIZING MATERIALS: May react. Decomposition Products miscellaneous decomposition products Thermal Decomposition of Products Water or Moisture: arsine, hydrogen, phosphine No data available. Possibility of Hazardous Reactions Will not polymerize. * * * Section 11 - TOXICOLOGICAL INFORMATION * * * Component Analysis - LD50/LC50 The components of this material have been reviewed in various sources and the following selected endpoints are published: FERROSILICON (8049-17-0) Dermal LD50 Rabbit: >20 g/kg RTECS Acute Toxicity (selected) The components of this material have been reviewed, and RTECS publishes the following endpoints: FERROSILICON (8049-17-0)
  • 5. Safety Data Sheet Issue Date 09/25/2009 5 Skin: >20 gm/kg skin rabbit LD50 Component Carcinogenicity None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA. RTECS Irritation The components of this material have been reviewed and RTECS publishes no data as of the date on this document. HEALTH EFFECTS Inhalation - Acute Exposure SILICON: Dust may cause respiratory and mucous membrane irritation and cough. Intratracheal administration of 25 mg in rabbits produced slight pulmonary lesions. IRON: Dust may cause mucous membrane and respiratory irritation due to mechanical action. Metal fume fever, an influenza-like illness, may occur due to the inhalation of freshly formed iron oxide particles sized below 1.5 microns and usually between 0.02-0.05 microns. Symptoms may be delayed 4-12 hours and begin with a sudden onset of thirst, and a sweet, metallic or foul taste in the mouth. Other symptoms may include upper respiratory tract irritation accompanied by coughing and a dryness of the mucous membranes. Lassitude and a generalized feeling of malaise. Fever, chills, muscular pain, mild to severe headache, nausea, occasional vomiting, exaggerated mental activity, profuse sweating, excessive urination, diarrhea and prostration may also occur. Tolerance to fumes develops rapidly, but is quickly lost. All symptoms usually subside within 24-36 hours. Inhalation - Chronic Exposure SILICON: Inert dust may cause excessive production of mucous, mucous gland hypertrophy, and increased airway resistance and may contribute to chronic bronchitis. IRON: Prolonged or repeated exposure may cause a mottling of the lungs, a condition called siderosis which is considered to be a benign pneumoconiosis that does not cause significant physiologic impairment. Symptoms may include chronic bronchitis, emphysema, and dyspnea on exertion. Skin Contact - Acute Exposure SILICON: May cause mechanical irritation. IRON: Dust may cause irritation. Penetration of iron particles in the skin may cause an exogenous siderosis which may be characterized by a red-brown pigmentation of the affected area. Skin Contact - Chronic Exposure SILICON: No data available. IRON: May cause same effects as reported in acute exposure. Eye Contact - Acute Exposure SILICON: Silicon dust may cause irritation. IRON: May cause irritation due to mechanical action. Iron particles imbedded in the eye may cause ocular siderosis. Effects may include discoloration of the cornea and iris, and pupillary effects including poor reaction to light and accomodation. If a particle enters the lens there may be cataract formation. Glaucoma occurs rarely in some cases of ocular siderosis. Eye Contact - Chronic Exposure SILICON: No data available. IRON: Repeated and prolonged contact may cause conjunctivitis and other effects reported in acute exposure. Ingestion - Acute Exposure SILICON: May cause digestive tract irritation. IRON: There are no reports available on
  • 6. Safety Data Sheet Issue Date 09/25/2009 6 poisoning from metallic iron, which is poorly absorbed. The principal manifestations of poisoning with iron compounds are vomiting, diarrhea, and circulatory collapse. Ingestion - Chronic Exposure SILICON: No data available. IRON: Repeated or prolonged exposure may cause hemosiderosis or hemochromatosis. * * * Section 12 - ECOLOGICAL INFORMATION * * * Component Analysis - Aquatic Toxicity No LOLI ecotoxicity data are available for this product's components. * * * Section 13 - DISPOSAL CONSIDERATIONS * * * Disposal Methods Dispose in accordance with all applicable regulations. Subject to disposal regulations: U.S. EPA 40 CFR 262. Hazardous Waste Number(s): D001. D003. Component Waste Numbers The U.S. EPA has not published waste numbers for this product's components. * * * Section 14 - TRANSPORT INFORMATION * * * US DOT Information Shipping Name: Ferrosilicon UN/NA #: UN1408 Hazard Class: 4.3 Packing Group: III Required Label(s): 4.3, 6.1 TDG Information Shipping Name: Ferrosilicon UN #: UN1408 Hazard Class: 4.3 Packing Group: III Required Label(s): 4.3, (6.1) ADR Information Shipping Name: Ferrosilicon UN #: UN1408 Hazard Class: 4.3 Packing Group: III Required Label(s): 4.3, 6.1 ADR Tunnel Code Restrictions This list contains tunnel restriction codes for those substances and/or chemically related entries which are found in chapter 3.2 of the ADR regulations. FERROSILICON (8049-17-0) RID Information Shipping Name: Ferrosilicon UN #: UN1408 Hazard Class: 4.3 Packing Group: III Required Label(s): 4.3, 6.1 IATA Information Shipping Name: Ferrosilicon UN #: UN1408 Hazard Class: 4.3 Packing Group: III Required Label(s): 4.3, 6.1 ICAO Information Shipping Name: Ferrosilicon UN #: UN1408 Hazard Class: 4.3 Packing Group: III Required Label(s): 4.3, 6.1 IMDG Information
  • 7. Safety Data Sheet Issue Date 09/25/2009 7 Shipping Name: Ferrosilicon UN #: UN1408 Hazard Class: 4.3 Packing Group: III Required Label(s): 6.1 * * * Section 15 - REGULATORY INFORMATION * * * U.S. Federal Regulations None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section 311/312 (40 CFR 370.21), SARA Section 313 (40 CFR 372.65), CERCLA (40 CFR 302.4), TSCA 12(b), or require an OSHA process safety plan. SARA Section 311/312 (40 CFR 370 Subparts B and C) Acute Health: No Chronic Health: No Fire: Yes Pressure: No Reactive: Yes U.S. State Regulations The following components appear on one or more of the following state hazardous substances lists: Component CAS CA MA MN NJ PA RI FERROSILICON 8049-17-0 No No No Yes No No Not regulated under California Proposition 65 Canada Canada WHMIS The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List: FERROSILICON (8049-17-0) 1 % Safety Phrases S8 Keep container dry. S30 Never add water to this product. Component Analysis - Inventory Component CAS US CA EU AU PH JP KR CN NZ FERROSILICON 8049-17-0 No No No Yes Yes No No No Yes * * * Section 16 - OTHER INFORMATION * * * Key / Legend ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD - Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CN - China; CPR - Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F - Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO - International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH -
  • 8. Safety Data Sheet Issue Date 09/25/2009 8 Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LOLI - List Of LIsts. - ChemADVISOR's Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH - National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; RID - European Rail Transport; RTECS - Registry of Toxic Effects of Chemical Substances.; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US - United States Other Information Reasonable care has been taken in the preparation of this information, but the manufacturer makes no warranty of merchantability or any other warranty, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental or consequential damages resulting from its use. Disclaimer: Supplier gives no warranty of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the purchaser will make his own tests to determine the quality and suitability of the product. Supplier expressly disclaims any and all liability for incidental and/or consequential property damage arising out of the use of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights. THIS MSDS IS TO BE UTILIZED SOLEY AS A REFERENCE DOCUMENT AND IT IS NOT TO BE USED TO SATISFY THE DISTRIBUTION REQUIREMENTS OF OSHA'S HAZARD COMMUNICATION STANDARD (HCS) NOR CANADA'S CONTROLLED PRODUCT REGULATION (CPR). Read the Material Safety Data Sheet before handling product. Copyright Copyright 1984-2009 ChemADVISOR, Inc. All rights reserved. RTECS is a United States trademark owned and licensed under authority of the U.S. Government, by and through Symyx Software Inc. Portions Copyright 2001, U.S. Government. All rights reserved. End of Sheet