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Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol. 3, No.9, 2013
208
Assessment of Shallow Aquifers Contamination by Failure of on-
Site Sewage Disposal System in Ughelli, Western Niger Delta,
Nigeria
Ohwoghere –Asuma, O and Adaikpoh, E. O1
Department of Geology, Delta State University, Abraka
1
Corresponding author; adaikpoh_edwino@yahoo.com
Abstract
Hydrochemical quality of shallow groundwater aquifers was investigated to assess the potential of contamination
by on-site sewage disposal systems in Ughelli. The results are; pH(5.47 – 7.45 ), Ec (105-483.2µscm), TDS(
58.95-294.7mg/l), Na+
(1.8-10.95mg/l ), K+
(2.64-9.87mg/l ), Mg2+
( 2.40-9.89mg/l), Ca2+
(3.01-14.90mg/l) and
Fe2+
( 0.02-0.87mg/l). Others include NO3 (0.04-31.24mg/l), NH3
+
(0.015-6.98 mg/l), Cl-
(8.5 - 104mg/l), SO4
-
(2.24-45.75mg/l), PO4
-
(0.21-2.25mg/l). The quality of most groundwater samples from shallow aquifers falls
within the tolerance limits stipulated by the WHO and NSDWQ. However, some groundwater samples revealed
the presence of high microbial population including total coliform bacteria count (1.78 – 25MNP/100ml) and
Escherichia coli (1.35-9.66 MNP/100ml) above the WHO and NSDWQ standards. Interaction between on-site
sewage disposal systems and shallow groundwater aquifers was established by the presence of microbial
population, high concentration of NH3
+
and slightly elevated concentration of NO3, electrical conductivity and
TDS in some the groundwater samples. The extent of contamination of groundwater is strongly influenced by
depth of the aquifers, high recharge rate during the wet seasons and availability of permeable soil beneath on-site
sewage disposal systems. Consequently the paper recommends that groundwater should be sourced from deeper
aquifers and those sourced from shallow aquifer in the area should be disinfected before being used.
Key words; Groundwater, aquifer, coliform, contamination, on-site disposal systems, WHO and NSDWQ
Introduction
Groundwater is an important natural water resource which serves as a source of portable drinking water for
several millions of people in most parts of Nigeria. The quality of groundwater tends to degrade and also become
scarce as the population of any geographical region increases. An increase in population invariably translates
into building of more houses, septic tanks for disposal of domestic sewage and more generation of wastes.
Septic tank disposal systems are constructed in households for disposal of human wastes. The discharge of
sewage into soil overlying groundwater aquifers is often common in Nigeria and many developing countries
which lack centralized sewage disposal systems.
The absence of centralized on-site deposal of sewage system for households has made every household to have
on-site sewage disposal system for disposal of human wastes emanating from toilets, bathrooms, kitchens and
laundries. The effectiveness of on-site sewage system in developing countries is influence by the types of soil
and the ability to remove solids from the effluents. Furthermore, in the case of failure, quality of groundwater
underneath an on-site sewage disposal system depends to a large extent on the soil types overlying it. The failure
of an on- site sewage disposal system affects the quality of groundwater aquifers only when the attenuating
capacity of the soil is absent.
According to USEPA (2002), certain urban areas where on–site sewage disposal systems are sited close to
shallow aquifers, there is the tendency of interaction of the aquifers with the septic tanks in that area. This is
common in karst terrane and in basement rocks (Miller and Ortiz, 2007) and where there is little or absence of
soil covering (Miller, 1980). In the Niger delta, groundwater aquifers are prone to contamination by on-site
sewage due to the presence of permeable aquifers, high water levels, high hydraulic conductivity and porosity.
Thus aquifers of this nature usually enhance the movement of contaminants, not only from septic tanks systems
but also from other sources of contaminants downgradients of groundwater flows.
The consumption of water from wells that interacts with an on-site sewage disposal system has some health
implications as such has resulted in occurrence of epidemic in certain areas. A relationship between health and
quality of water from septic tank that is poorly managed or where high densities of households with septic tanks
has already been established by Groundwater Protection Council (2007). The clusters of high densities of septic
tank system have been linked to endemic diarrheal illness, and other studies have also demonstrated same
relationship between diseases outbreaks and septic tank systems (Craun, 1979, 1984; Bellers et al., 1997 and
Borchardt et al., 2003b). Bacteria and viruses which are waterborne can be transported along groundwater flow
direction from source points to other areas down gradient of flow. The work of DeBorde et al., (1998) has
demonstrated the movement of seeded virus through sandy aquifer for 9 months in the presence of viable seeded
Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol. 3, No.9, 2013
209
virus. Several studies have also shown the susceptibility of shallow water wells to contamination by septic tank
systems (Jin et al., 2004; Francy et al., 2004; Gardner and Vogel, 2005; Panno et al., 2007; Landon et al., 2008
and Brown et al., 2009). More also, high contents of nitrate, orthophosphate, chloride, sodium, calcium,
potassium, dissolved organic carbon, boron and depleted in dissolved oxygen and depressed in pH in
groundwater beneath on-site sewage disposal system have been reported by (Peavy,1978, Robertson et al.,1991
and Panno et al.,2007). Furthermore high concentrations of heavy metals (Fe, Al, Mn and Cr) has been reported
by Robertson and Blowes (1995) to develop under anoxic condition in plumes downgradient of on-site sewage
system in groundwater beneath on-site disposal sewage system.
In recent times Ughelli has experienced massive expansion and as such, one of the fastest developing urban
towns in Delta state. The expansion is adduced to its proximity to Warri; the heart of the hydrocarbon industry in
western Niger Delta; availability of affordable accommodation and couple with its strategic location in the heart
of western Niger delta. Ughelli and its surrounding environs is host to several oil wells, trunk line, oil fields and
flow stations. Consequently, there is rural- urban migration into it, thus increasing the population. Currently, it
has over 80,000 houses and about 160,000 septic tanks. Over 80% of the water abstracted from aquifers for use
in the 80,000 houses finds its way back to the underlying aquifer from septic tanks. The construction of an on-
site sewage system by individuals often lack institutional control and thus quality is compromised, thus
susceptible to failure. The lack of inspection to determine the failure of old septic sewage disposal systems is
potential source of groundwater contamination. Consequently, the groundwater quality beneath Ughelli is
threatened by proliferation of on-site sewage disposal systems emanating from urbanization. This investigation
becomes necessary since the extent of groundwater contamination by on-site sewage disposal in the study area is
unknown.
Geologic setting
Ughelli is underlain by sequence of the known Niger Delta Formations. The formations from the top to the base
are Somebreiro-Warri Deltaic Plain sands, Benin Formation, Agbada Formation and the Akata Formation have
been described in details by (Allen, 1965; Reyment, 1965; Short and Stauble, 1967; Weber and Daukuro, 1975).
According to Wigwe (1975), the Somebreiro-Warri Deltaic Plain sand is about 120 meters thick and it is
Quaternary to Recent. Texturally, the unconsolidated sediments range from fine plastic clay - through- medium-
to -coarsed grained sands and rarely gravelly.
The Benin Formation consists predominantly of unconsolidated sand, gravel and occasionally intercalation of
shales. It is a freshwater bearing formation in the Niger Delta region and it provides all the freshwater need of
the people. Its thickness is about 2000metres and ranges from Oligocene to Pleistocene in age.
The Agbada Formation is the oil bearing formation of the Niger Delta sedimentary basin. It is of Eocene to
Oligocene in age. It consists of alternate sand and shale sequence and about 3000 meters thick. The Akata
Formation is the basal units of the Niger Delta sedimentary basin and overlies the basement complex. This
formation is highly pressured and compositionally it is made up of open marine facies. Its thickness is estimated
to be 1000km and the age is from Eocene to Oligocene.
Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol. 3, No.9, 2013
210
Figure1. Map of the study area showing sample locations
Hydrogeology
The study area consists of unconfined, confined and semi-confined aquifers. They are very productive aquifers,
high yielding and characterized by high specific capacities, as well as high recharge rate. The static water level
of the aquifers is very high; it often ranges from less than 0.2 to 4meters. The water level fluctuates in
accordance with the regimes of the season in a year. It is almost at the ground surface during the wet season and
decreased during the dry season. The town is drained by one major river that flows throughout the season and,
many streams that are perennial in nature, which flow during the raining season and stagnant in the dry season,
these streams are part of wetlands and sometime contribute to the recharge of the aquifers. The aquifers are
characterized by grain sizes that range from fine through medium to coarse grained sand.
Geographical setting
The study area is situated in the centrally part of Delta state and located between Latitude 50
281
39.011
N and
50
581
301
.511
E and longitude 50
301
5311
N and 60
011
04.511
E (Fig 1). It has two climate regimes: the dry season,
which spans from November to March; and the wet season which lasts from April to October. The mean annual
rainfall is above 2500mm with temperature that ranges from 20o
C to 34 o
C; temperatures are usually higher
during the day and lower at night. Relative humidity varies between 55% and 75% throughout the year.
Vegetation of the area is typical of tropical rain forest region, which have been subjected to suffered quantum
deforestation emanating from urbanization, sand dredging, farming and exploration and exploitation of oil and
gas activities.
Materials and Methods
Sampling
About 20 samples of water were collected from shallow hand-dug wells in August, 2012. As a principle of
precaution sample containers were washed with detergent, rinsed with de-ionized water and rinsed with the
sample water prior to collection. Each sample was labeled according to location, preserved at 40
C and
transported to the laboratory for analysis. To determine flow direction, coordinates of position of hand- dug
wells were taken with portable GPS equipment; water levels and depth to water levels from shallow wells were
measured. Surfer -8 was used to plot contours for the depth to water level and water level respectively.
Analytical Method
Laboratory analysis was performed immediately on the samples on arrival at the laboratory in accordance with
the American Public Health Association (APHA, 1994) methods. The various physico-chemical parameters
analyzed include pH, total dissolved solids (TDS), electrical conductivity (Ec), Sulphates (SO4
-
), chlorides (Cl-
),
Journal of Environment and Earth Science www.iiste.org
ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol. 3, No.9, 2013
211
nitrates (NO3
-
), phosphates( PO4
-
), ammonia(NH3
+
), Sodium(Na+
), Magnesium(Mg+
), Calcium( Ca+
),
potassium( K+
). Of the heavy metals only iron (Fe2+
) was the analyzed. Results of laboratory analysis were later
subjected to descriptive statistical analysis.
Results and Discussion
The results of the physio-chemical analyses and microbial composition of groundwater samples collected from
shallow hand-dug wells are summarized in tables 1 and 2. The pH of the groundwater samples analyzed ranged
between 5.4 and 7.4, with a mean of 6.7675 ± 0.508971. All pH values are within the standard stipulated by
World Health Organization (WHO) and the Nigeria Standard for Drinking Water Quality (NSDWQ) for portable
drinking water, except those of Gw3, Gw 4 and Gw 20 (Figure 2), which are below the recommended standards.
According to Robertson and Blowes (1995) the concentration of trace inorganics in sewage plume in
groundwater may be promoted by pH values below 6.0. Consequently, the very low values of 5.45 and 5.55
recorded for Gw3 and Gw4 may have been caused by leakage from on-site disposal system to the groundwater.
The electrical conductivity (EC) values ranged between 105.6 and 483.1us/cm with mean value of 265.0488
±130.0869, while the Total dissolve solid (TDS) varies from 58.95 to 294.7mg/l, with mean value of 155.3325 ±
71.20815. Both the EC and TDS values are below the permissible limit stipulated by WHO and NSDWQ for
portable drinking water (Figure 2).
Human wastes contain sodium (Na+
) and chloride (Cl-
) and they are often disposed in on-site septic systems.
Consequently, elevated concentrations of Na+
and Cl-
in groundwater reflect groundwater which may have been
affected by failure of an on-site sewage disposal system (Fig.2). The obtained Cl-
concentrations ranged between
8.5 and 104mg/l, with mean value of 42.2115± 34.32409 and Na+
ranged between 1.8 and 10.95mg/l and with
mean value of 4.4±2.193705. The concentrations of Na+
ions determined fall below the stipulated standard by
WHO and NSDWQ for portable drinking water.
Table 1: Descriptive statistics of the Physico-chemical qualities of groundwater samples analyzed.
Variables n = 20
Parameters Min Max Mean+STD WHO Recommended standard
(1996)
pH 5.4 7.4 6.7675 ± 0.508971 6.5-8.5
EC (µs/cm) 105.6 483.1 265.0485 ± 130.0869
TDS(mg/l) 58.95 294.7 155.3325 ± 71.20815 500
Na+
(mg/l) 1.8 10.95 4.4 ± 2.193705 200
K+
(mg/l) 2.64 9.87 5.85 ± 2.250534 12
Mg++
(mg/l) 2.4 9.89 5.4375 ± 2.205674 50
Ca++
(mg/l) 3.01 14.90 7.405 ± 2.894511 200
Fe2
++
(mg/l) 0.02 0.87 0.276 ± 0.326886 0.03
NO3
-
(mg/l) 0.04 31.24 4.981 ± 7,119029 50
NH3
+
(mg/l) 0.015 6.96 0.9123 ± 1.599319 0.5
SO4
-
(mg/l) 2.24 45.78 16.12 ± 13.99089 250
CL-
(mg/l) 8.5 104 42.2115± 34,32409 250
PO4
-
(mg/l) 0.21 2.25 0.7985± 2.508791 5.0
Of all the samples of groundwater analyzed, 40 percent has concentrations of Cl-
above the mean value of
42.111mg/l, while 60 percent is below it. Also, 50 percent of the groundwater samples analyzed have
concentrations of Na+
below the mean value of 4.4mg/l and the other above it. The groundwater is regarded as
fresh but observed variation in the concentrations of Cl-
and Na+
did indicate minute level of contamination by
on-site sewage disposal systems. The content of K+
varies from 2.64 to 9.87mg/l and mean value of 5.85mg/l
(Table 1). Greater proportion of samples has their concentrations above the mean concentration, which
represents 65 percent of the entire samples. The concentration of K+
is relatively high and close to the limit of
12mg/l stipulated by WHO and NSDWQ for drinking water quality. The spatial distribution in the
concentrations of K+
in the groundwater samples is a clear evidence of the effect of on-site deposal systems
failure. The mean content of Mg+
concentration is 5.4375mg/l and also ranges between 2.4 and 9.89mg/l, 60% of
the entire samples have concentration that is below the mean. Furthermore, the concentration of Mg+
is lower
that the allowable limit recommended by WHO and NSDWQ for drinking water quality. The presence of Ca+
in
groundwater is a good indicator of its contamination by sewage. The measured concentration of Ca+
varies from
3.01 to 14.90mg/l, with a mean of 7.405mg/l. Of all the samples analyzed, 35 % of them have concentration
above the mean and 65% lesser than it. These concentrations of Ca+
however fall below the standard stipulated
by WHO and NSDWQ for drinking water quality. It is clear from Table 1 that the concentration of ions of
calcium is higher in that order; Ca++
> Na+
> Mg++
> K+
. The concentration of Fe2+
ranges between 0.02 to
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ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
Vol. 3, No.9, 2013
212
0.87mg/l, with mean value of 0.276mg/l. The majority of the groundwater samples (65%) have Fe2+
concentrations higher than the 0.03mg/l stipulated by WHO and NSDWQ for drinking water. The high
preponderance of Fe2+
in the groundwater samples measured is similar to those obtained by Ophori et al., (2007).
The source of Fe2+
in shallow water aquifer is yet to be ascertained in most parts of the Niger Delta. It is
suggested that the preponderance of Fe2+
, which characterized some shallow groundwater aquifer, is probably
due to leakage from on-site septic disposal systems failure. This suggestion is supported by the results of Chilton
et al., (1999), who demonstrated that under anaerobic condition, iron sulphide is usually precipitated from the
seepage of sewage through the subsurface underneath failed on-site disposal systems. In addition, Fe2+
may have
been transported in suspension form weathering of sources rich in iron and subsequently deposited along with
clays and sediments in the coastal plains of the Niger Delta. The Fe2+
is subsequently released into the porewater
when the Eh become negative.
Table2: Statistical summary of Microbial composition of groundwater from shallow aquifer in Ughelli.
n=20
Parameters Min Max Mean WHO (1996)
Guideline
Total Coliform 1.78 25 6.5685±7.119734823 0.05 (MNP)/100ml
E.Coli 1.35 9.66 3.7215±3.136275 0(MNP)/100ml
The availability of nitrogen and phosphorus compounds in groundwater is a reflection of contamination by on-
site disposal systems (Miller, 1980). Of these compounds, NO3
-
, NH3+
and PO4
-
were determined (Fig.2). The
results revealed that NO3
-
concentration vary from 0.04 to 31.24mg/l, with mean of 4.981mg/l, 65 and 35 percent
of the samples concentrations are lower and higher than the mean concentration respectively. The low
concentrations of NO3
-
ions measured in groundwater samples may be attributed to gradual attenuation of NO3
-
due to mixing of recharge water and dispersion in the aquifer (Groundwater and assessment programme, 1999).
From the total 20 samples of groundwater analyzed, 60 and 40 percent of the samples have concentration of
NH3+
lower and higher than the mean of 0.912mg/l respectively. While the concentration of NO3
-
is less than the
allowable limits, NH3+
is more than WHO and NSDWQ for portable drinking water. The elevated concentration
of NH3+
in the groundwater above the recommended standard indicates that the quality of groundwater has been
affected by on-site disposal systems. Sulphate (SO4
-
) was detected in all samples but in low concentrations,
however, all were within the required tolerance limits of WHO and NSDWQ for drinking water (Table.1). The
obtained concentration of SO4
-
varies from 2.24 to 45.78mg/l and mean value of 16.12mg/l. 65 percent of the
samples have their SO4
-
concentrations below the mean, while 35 percent above the mean. The low
concentration of SO4
-
values determined in the study area may be adduced to sulfurization process in the
anaerobic groundwater according to Chilton (1999).
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ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
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Figure 2: Indicators of septic tank disposal system failure in groundwater (elevated level of A- K in groundwater
reflects contamination by sewage system) the presence of F, I, J and K strongly indicate water quality that has
been impacted upon by septic tank failure.
Furthermore, phosphate (Po4
-
) has a mean concentration of 0.93mg/l. Of all 20 samples analyzed, 80 percent has
concentrations of PO4
-
lower and 20 percent is higher than mean respectively. These concentrations of PO4
-
ions
are below the standard stipulated by WHO and NSDWQ drinking water quality. Small amount of PO4
-
as small
as to 0.1mg/l in water can leads to the development of slimes and algal growths (Adekunle et al., 2007). In a
poorly buffered system higher concentration of PO4
-
should be of concerned due its detrimental effects on food
preparation (Longe and Balogun, 2009).The low concentrations of PO4
-
ions observed in the groundwater
samples was caused by the attenuation of PO4
-
in the unsaturated zones. The Groundwater and assessment
program (1999) has shown that low concentration of PO4
-
in urban groundwater is due to attenuation of PO4
-
in
the unsaturated zones, which retards its movement into groundwater. Once PO4
-
reached the saturated zones, it
cannot be attenuated (Noss and Billa, 1988; Kaplan, 1987).
Figure 3: water level contour plot of the study area, water level in some shallow hand-dug wells are less
than 1metre especially during the wet season
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ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online)
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On-site disposal system is repository for human wastes. Apart from the laundries and bathrooms wastes, there
are those generated from the gastrointestinal tracks of humans. The gastrointestinal tracks of human contain
bacterial such as Coliforms. The presence of feacal coliforms in groundwater aquifers signifies effluents from
on-site disposal systems. The bacterial composition of the groundwater analyzed ranged from not-detected (ND)
to 25MNP/100ml and ND to 9.66 for the total coliform counts and Escherichia coli, with mean value for 6.5685
and 3.7215MNP/100ml respectively (Table 2). The obtained values for the total coliform counts and Escherichia
coli in the groundwater samples are significantly higher than the WHO, 1996 guidelines, which indicates that 75
percent of shallow groundwater samples are hydraulically connected to on-site disposal systems and as such not
fit for drinking. The observed contaminations of groundwater by pathogens may be attributable to the existence
of high water table (Figure 3), flow by-passing the clogging mats, which is common during higher recharge
period of the year and the shallowness of the aquifers (Figure 4). When the clogging mat is by-passed by
percolation of wastewater from septic tanks, it may results in the introduction of microbes into aquifers (Ground
water and assessment program, 1999). The reason for this is that attenuation of pathogens usually takes place at
the clogging mats, which is often situated between the soils and the drainfield media.
Figure 4: Depth to water level contour
The contribution of soils to the attenuation of contaminants and effluents from on-site disposal systems cannot
be overemphasized. They assist in the reduction of effluents from septic tanks by way of absorption, dispersion
and retardation of the migration of contaminants within the vadose zone, thereby reducing the degree of
groundwater contamination. The characteristics of soils (Figure 5) in the study area may have played significant
roles in attenuation of effluents from septic tank disposal systems, thus most of the groundwater samples were
not affected by failure of septic tanks.
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Figure 3; Lithologies description of some boreholes and water levels in study area
Conclusion
The slightly elevated concentration of NO-
3, electrical conductivity and TDS, the spatial distribution of other
anions and cations and, coupled with strong evidence of the presence of feacal coliform and E-coli as well as
concentrations of NH3+
that were above the tolerance limit of the standard recommended by WHO and NSDWQ,
suggest that the groundwater samples may have been contaminated by on-site sewage disposal systems.
Therefore, the hydrogeochemical investigation of shallow groundwater aquifers has demonstrated hydraulic
connection between on–site sewage disposal systems and some of the shallow groundwater aquifers in the study
area. This is reflected more among the shallowest of the shallow aquifers, which are more hydraulically
connected to the on-site sewage disposal system than the deeper shallow aquifers, especially during the wet
seasons.
The few contaminations recorded in groundwater samples may have emanated from the inability of soils in the
unsaturated zones to attenuate the effluents, as result of the presence of permeable soils below septic tank and
high aquifers recharge rate common during the wet seasons. During the wet seasons the clogging mats that
usually help in natural attenuation are often by-pass by groundwater percolation. However, the low concentration
of anions and cations measured in the hydrogeochemical investigation also shows that naturally attenuation by
the unsaturated zone may have contributed significantly in causing the reduction in the measured concentrations,
which are below the WHO and NSDWQ standards. The conclusion therefore is that some of the shallow aquifers
are not fit for drinking and it is recommended that drinking water in Ughelli area should be sourced from deeper
aquifer by drilling rather than hand-dug wells, which are often prone to contamination by effluent from on-site
sewage disposal systems as demonstrated in the study.
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This academic article was published by The International Institute for Science,
Technology and Education (IISTE). The IISTE is a pioneer in the Open Access
Publishing service based in the U.S. and Europe. The aim of the institute is
Accelerating Global Knowledge Sharing.
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Assessment of shallow aquifer contamination

  • 1. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol. 3, No.9, 2013 208 Assessment of Shallow Aquifers Contamination by Failure of on- Site Sewage Disposal System in Ughelli, Western Niger Delta, Nigeria Ohwoghere –Asuma, O and Adaikpoh, E. O1 Department of Geology, Delta State University, Abraka 1 Corresponding author; adaikpoh_edwino@yahoo.com Abstract Hydrochemical quality of shallow groundwater aquifers was investigated to assess the potential of contamination by on-site sewage disposal systems in Ughelli. The results are; pH(5.47 – 7.45 ), Ec (105-483.2µscm), TDS( 58.95-294.7mg/l), Na+ (1.8-10.95mg/l ), K+ (2.64-9.87mg/l ), Mg2+ ( 2.40-9.89mg/l), Ca2+ (3.01-14.90mg/l) and Fe2+ ( 0.02-0.87mg/l). Others include NO3 (0.04-31.24mg/l), NH3 + (0.015-6.98 mg/l), Cl- (8.5 - 104mg/l), SO4 - (2.24-45.75mg/l), PO4 - (0.21-2.25mg/l). The quality of most groundwater samples from shallow aquifers falls within the tolerance limits stipulated by the WHO and NSDWQ. However, some groundwater samples revealed the presence of high microbial population including total coliform bacteria count (1.78 – 25MNP/100ml) and Escherichia coli (1.35-9.66 MNP/100ml) above the WHO and NSDWQ standards. Interaction between on-site sewage disposal systems and shallow groundwater aquifers was established by the presence of microbial population, high concentration of NH3 + and slightly elevated concentration of NO3, electrical conductivity and TDS in some the groundwater samples. The extent of contamination of groundwater is strongly influenced by depth of the aquifers, high recharge rate during the wet seasons and availability of permeable soil beneath on-site sewage disposal systems. Consequently the paper recommends that groundwater should be sourced from deeper aquifers and those sourced from shallow aquifer in the area should be disinfected before being used. Key words; Groundwater, aquifer, coliform, contamination, on-site disposal systems, WHO and NSDWQ Introduction Groundwater is an important natural water resource which serves as a source of portable drinking water for several millions of people in most parts of Nigeria. The quality of groundwater tends to degrade and also become scarce as the population of any geographical region increases. An increase in population invariably translates into building of more houses, septic tanks for disposal of domestic sewage and more generation of wastes. Septic tank disposal systems are constructed in households for disposal of human wastes. The discharge of sewage into soil overlying groundwater aquifers is often common in Nigeria and many developing countries which lack centralized sewage disposal systems. The absence of centralized on-site deposal of sewage system for households has made every household to have on-site sewage disposal system for disposal of human wastes emanating from toilets, bathrooms, kitchens and laundries. The effectiveness of on-site sewage system in developing countries is influence by the types of soil and the ability to remove solids from the effluents. Furthermore, in the case of failure, quality of groundwater underneath an on-site sewage disposal system depends to a large extent on the soil types overlying it. The failure of an on- site sewage disposal system affects the quality of groundwater aquifers only when the attenuating capacity of the soil is absent. According to USEPA (2002), certain urban areas where on–site sewage disposal systems are sited close to shallow aquifers, there is the tendency of interaction of the aquifers with the septic tanks in that area. This is common in karst terrane and in basement rocks (Miller and Ortiz, 2007) and where there is little or absence of soil covering (Miller, 1980). In the Niger delta, groundwater aquifers are prone to contamination by on-site sewage due to the presence of permeable aquifers, high water levels, high hydraulic conductivity and porosity. Thus aquifers of this nature usually enhance the movement of contaminants, not only from septic tanks systems but also from other sources of contaminants downgradients of groundwater flows. The consumption of water from wells that interacts with an on-site sewage disposal system has some health implications as such has resulted in occurrence of epidemic in certain areas. A relationship between health and quality of water from septic tank that is poorly managed or where high densities of households with septic tanks has already been established by Groundwater Protection Council (2007). The clusters of high densities of septic tank system have been linked to endemic diarrheal illness, and other studies have also demonstrated same relationship between diseases outbreaks and septic tank systems (Craun, 1979, 1984; Bellers et al., 1997 and Borchardt et al., 2003b). Bacteria and viruses which are waterborne can be transported along groundwater flow direction from source points to other areas down gradient of flow. The work of DeBorde et al., (1998) has demonstrated the movement of seeded virus through sandy aquifer for 9 months in the presence of viable seeded
  • 2. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol. 3, No.9, 2013 209 virus. Several studies have also shown the susceptibility of shallow water wells to contamination by septic tank systems (Jin et al., 2004; Francy et al., 2004; Gardner and Vogel, 2005; Panno et al., 2007; Landon et al., 2008 and Brown et al., 2009). More also, high contents of nitrate, orthophosphate, chloride, sodium, calcium, potassium, dissolved organic carbon, boron and depleted in dissolved oxygen and depressed in pH in groundwater beneath on-site sewage disposal system have been reported by (Peavy,1978, Robertson et al.,1991 and Panno et al.,2007). Furthermore high concentrations of heavy metals (Fe, Al, Mn and Cr) has been reported by Robertson and Blowes (1995) to develop under anoxic condition in plumes downgradient of on-site sewage system in groundwater beneath on-site disposal sewage system. In recent times Ughelli has experienced massive expansion and as such, one of the fastest developing urban towns in Delta state. The expansion is adduced to its proximity to Warri; the heart of the hydrocarbon industry in western Niger Delta; availability of affordable accommodation and couple with its strategic location in the heart of western Niger delta. Ughelli and its surrounding environs is host to several oil wells, trunk line, oil fields and flow stations. Consequently, there is rural- urban migration into it, thus increasing the population. Currently, it has over 80,000 houses and about 160,000 septic tanks. Over 80% of the water abstracted from aquifers for use in the 80,000 houses finds its way back to the underlying aquifer from septic tanks. The construction of an on- site sewage system by individuals often lack institutional control and thus quality is compromised, thus susceptible to failure. The lack of inspection to determine the failure of old septic sewage disposal systems is potential source of groundwater contamination. Consequently, the groundwater quality beneath Ughelli is threatened by proliferation of on-site sewage disposal systems emanating from urbanization. This investigation becomes necessary since the extent of groundwater contamination by on-site sewage disposal in the study area is unknown. Geologic setting Ughelli is underlain by sequence of the known Niger Delta Formations. The formations from the top to the base are Somebreiro-Warri Deltaic Plain sands, Benin Formation, Agbada Formation and the Akata Formation have been described in details by (Allen, 1965; Reyment, 1965; Short and Stauble, 1967; Weber and Daukuro, 1975). According to Wigwe (1975), the Somebreiro-Warri Deltaic Plain sand is about 120 meters thick and it is Quaternary to Recent. Texturally, the unconsolidated sediments range from fine plastic clay - through- medium- to -coarsed grained sands and rarely gravelly. The Benin Formation consists predominantly of unconsolidated sand, gravel and occasionally intercalation of shales. It is a freshwater bearing formation in the Niger Delta region and it provides all the freshwater need of the people. Its thickness is about 2000metres and ranges from Oligocene to Pleistocene in age. The Agbada Formation is the oil bearing formation of the Niger Delta sedimentary basin. It is of Eocene to Oligocene in age. It consists of alternate sand and shale sequence and about 3000 meters thick. The Akata Formation is the basal units of the Niger Delta sedimentary basin and overlies the basement complex. This formation is highly pressured and compositionally it is made up of open marine facies. Its thickness is estimated to be 1000km and the age is from Eocene to Oligocene.
  • 3. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol. 3, No.9, 2013 210 Figure1. Map of the study area showing sample locations Hydrogeology The study area consists of unconfined, confined and semi-confined aquifers. They are very productive aquifers, high yielding and characterized by high specific capacities, as well as high recharge rate. The static water level of the aquifers is very high; it often ranges from less than 0.2 to 4meters. The water level fluctuates in accordance with the regimes of the season in a year. It is almost at the ground surface during the wet season and decreased during the dry season. The town is drained by one major river that flows throughout the season and, many streams that are perennial in nature, which flow during the raining season and stagnant in the dry season, these streams are part of wetlands and sometime contribute to the recharge of the aquifers. The aquifers are characterized by grain sizes that range from fine through medium to coarse grained sand. Geographical setting The study area is situated in the centrally part of Delta state and located between Latitude 50 281 39.011 N and 50 581 301 .511 E and longitude 50 301 5311 N and 60 011 04.511 E (Fig 1). It has two climate regimes: the dry season, which spans from November to March; and the wet season which lasts from April to October. The mean annual rainfall is above 2500mm with temperature that ranges from 20o C to 34 o C; temperatures are usually higher during the day and lower at night. Relative humidity varies between 55% and 75% throughout the year. Vegetation of the area is typical of tropical rain forest region, which have been subjected to suffered quantum deforestation emanating from urbanization, sand dredging, farming and exploration and exploitation of oil and gas activities. Materials and Methods Sampling About 20 samples of water were collected from shallow hand-dug wells in August, 2012. As a principle of precaution sample containers were washed with detergent, rinsed with de-ionized water and rinsed with the sample water prior to collection. Each sample was labeled according to location, preserved at 40 C and transported to the laboratory for analysis. To determine flow direction, coordinates of position of hand- dug wells were taken with portable GPS equipment; water levels and depth to water levels from shallow wells were measured. Surfer -8 was used to plot contours for the depth to water level and water level respectively. Analytical Method Laboratory analysis was performed immediately on the samples on arrival at the laboratory in accordance with the American Public Health Association (APHA, 1994) methods. The various physico-chemical parameters analyzed include pH, total dissolved solids (TDS), electrical conductivity (Ec), Sulphates (SO4 - ), chlorides (Cl- ),
  • 4. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol. 3, No.9, 2013 211 nitrates (NO3 - ), phosphates( PO4 - ), ammonia(NH3 + ), Sodium(Na+ ), Magnesium(Mg+ ), Calcium( Ca+ ), potassium( K+ ). Of the heavy metals only iron (Fe2+ ) was the analyzed. Results of laboratory analysis were later subjected to descriptive statistical analysis. Results and Discussion The results of the physio-chemical analyses and microbial composition of groundwater samples collected from shallow hand-dug wells are summarized in tables 1 and 2. The pH of the groundwater samples analyzed ranged between 5.4 and 7.4, with a mean of 6.7675 ± 0.508971. All pH values are within the standard stipulated by World Health Organization (WHO) and the Nigeria Standard for Drinking Water Quality (NSDWQ) for portable drinking water, except those of Gw3, Gw 4 and Gw 20 (Figure 2), which are below the recommended standards. According to Robertson and Blowes (1995) the concentration of trace inorganics in sewage plume in groundwater may be promoted by pH values below 6.0. Consequently, the very low values of 5.45 and 5.55 recorded for Gw3 and Gw4 may have been caused by leakage from on-site disposal system to the groundwater. The electrical conductivity (EC) values ranged between 105.6 and 483.1us/cm with mean value of 265.0488 ±130.0869, while the Total dissolve solid (TDS) varies from 58.95 to 294.7mg/l, with mean value of 155.3325 ± 71.20815. Both the EC and TDS values are below the permissible limit stipulated by WHO and NSDWQ for portable drinking water (Figure 2). Human wastes contain sodium (Na+ ) and chloride (Cl- ) and they are often disposed in on-site septic systems. Consequently, elevated concentrations of Na+ and Cl- in groundwater reflect groundwater which may have been affected by failure of an on-site sewage disposal system (Fig.2). The obtained Cl- concentrations ranged between 8.5 and 104mg/l, with mean value of 42.2115± 34.32409 and Na+ ranged between 1.8 and 10.95mg/l and with mean value of 4.4±2.193705. The concentrations of Na+ ions determined fall below the stipulated standard by WHO and NSDWQ for portable drinking water. Table 1: Descriptive statistics of the Physico-chemical qualities of groundwater samples analyzed. Variables n = 20 Parameters Min Max Mean+STD WHO Recommended standard (1996) pH 5.4 7.4 6.7675 ± 0.508971 6.5-8.5 EC (µs/cm) 105.6 483.1 265.0485 ± 130.0869 TDS(mg/l) 58.95 294.7 155.3325 ± 71.20815 500 Na+ (mg/l) 1.8 10.95 4.4 ± 2.193705 200 K+ (mg/l) 2.64 9.87 5.85 ± 2.250534 12 Mg++ (mg/l) 2.4 9.89 5.4375 ± 2.205674 50 Ca++ (mg/l) 3.01 14.90 7.405 ± 2.894511 200 Fe2 ++ (mg/l) 0.02 0.87 0.276 ± 0.326886 0.03 NO3 - (mg/l) 0.04 31.24 4.981 ± 7,119029 50 NH3 + (mg/l) 0.015 6.96 0.9123 ± 1.599319 0.5 SO4 - (mg/l) 2.24 45.78 16.12 ± 13.99089 250 CL- (mg/l) 8.5 104 42.2115± 34,32409 250 PO4 - (mg/l) 0.21 2.25 0.7985± 2.508791 5.0 Of all the samples of groundwater analyzed, 40 percent has concentrations of Cl- above the mean value of 42.111mg/l, while 60 percent is below it. Also, 50 percent of the groundwater samples analyzed have concentrations of Na+ below the mean value of 4.4mg/l and the other above it. The groundwater is regarded as fresh but observed variation in the concentrations of Cl- and Na+ did indicate minute level of contamination by on-site sewage disposal systems. The content of K+ varies from 2.64 to 9.87mg/l and mean value of 5.85mg/l (Table 1). Greater proportion of samples has their concentrations above the mean concentration, which represents 65 percent of the entire samples. The concentration of K+ is relatively high and close to the limit of 12mg/l stipulated by WHO and NSDWQ for drinking water quality. The spatial distribution in the concentrations of K+ in the groundwater samples is a clear evidence of the effect of on-site deposal systems failure. The mean content of Mg+ concentration is 5.4375mg/l and also ranges between 2.4 and 9.89mg/l, 60% of the entire samples have concentration that is below the mean. Furthermore, the concentration of Mg+ is lower that the allowable limit recommended by WHO and NSDWQ for drinking water quality. The presence of Ca+ in groundwater is a good indicator of its contamination by sewage. The measured concentration of Ca+ varies from 3.01 to 14.90mg/l, with a mean of 7.405mg/l. Of all the samples analyzed, 35 % of them have concentration above the mean and 65% lesser than it. These concentrations of Ca+ however fall below the standard stipulated by WHO and NSDWQ for drinking water quality. It is clear from Table 1 that the concentration of ions of calcium is higher in that order; Ca++ > Na+ > Mg++ > K+ . The concentration of Fe2+ ranges between 0.02 to
  • 5. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol. 3, No.9, 2013 212 0.87mg/l, with mean value of 0.276mg/l. The majority of the groundwater samples (65%) have Fe2+ concentrations higher than the 0.03mg/l stipulated by WHO and NSDWQ for drinking water. The high preponderance of Fe2+ in the groundwater samples measured is similar to those obtained by Ophori et al., (2007). The source of Fe2+ in shallow water aquifer is yet to be ascertained in most parts of the Niger Delta. It is suggested that the preponderance of Fe2+ , which characterized some shallow groundwater aquifer, is probably due to leakage from on-site septic disposal systems failure. This suggestion is supported by the results of Chilton et al., (1999), who demonstrated that under anaerobic condition, iron sulphide is usually precipitated from the seepage of sewage through the subsurface underneath failed on-site disposal systems. In addition, Fe2+ may have been transported in suspension form weathering of sources rich in iron and subsequently deposited along with clays and sediments in the coastal plains of the Niger Delta. The Fe2+ is subsequently released into the porewater when the Eh become negative. Table2: Statistical summary of Microbial composition of groundwater from shallow aquifer in Ughelli. n=20 Parameters Min Max Mean WHO (1996) Guideline Total Coliform 1.78 25 6.5685±7.119734823 0.05 (MNP)/100ml E.Coli 1.35 9.66 3.7215±3.136275 0(MNP)/100ml The availability of nitrogen and phosphorus compounds in groundwater is a reflection of contamination by on- site disposal systems (Miller, 1980). Of these compounds, NO3 - , NH3+ and PO4 - were determined (Fig.2). The results revealed that NO3 - concentration vary from 0.04 to 31.24mg/l, with mean of 4.981mg/l, 65 and 35 percent of the samples concentrations are lower and higher than the mean concentration respectively. The low concentrations of NO3 - ions measured in groundwater samples may be attributed to gradual attenuation of NO3 - due to mixing of recharge water and dispersion in the aquifer (Groundwater and assessment programme, 1999). From the total 20 samples of groundwater analyzed, 60 and 40 percent of the samples have concentration of NH3+ lower and higher than the mean of 0.912mg/l respectively. While the concentration of NO3 - is less than the allowable limits, NH3+ is more than WHO and NSDWQ for portable drinking water. The elevated concentration of NH3+ in the groundwater above the recommended standard indicates that the quality of groundwater has been affected by on-site disposal systems. Sulphate (SO4 - ) was detected in all samples but in low concentrations, however, all were within the required tolerance limits of WHO and NSDWQ for drinking water (Table.1). The obtained concentration of SO4 - varies from 2.24 to 45.78mg/l and mean value of 16.12mg/l. 65 percent of the samples have their SO4 - concentrations below the mean, while 35 percent above the mean. The low concentration of SO4 - values determined in the study area may be adduced to sulfurization process in the anaerobic groundwater according to Chilton (1999).
  • 6. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol. 3, No.9, 2013 213 Figure 2: Indicators of septic tank disposal system failure in groundwater (elevated level of A- K in groundwater reflects contamination by sewage system) the presence of F, I, J and K strongly indicate water quality that has been impacted upon by septic tank failure. Furthermore, phosphate (Po4 - ) has a mean concentration of 0.93mg/l. Of all 20 samples analyzed, 80 percent has concentrations of PO4 - lower and 20 percent is higher than mean respectively. These concentrations of PO4 - ions are below the standard stipulated by WHO and NSDWQ drinking water quality. Small amount of PO4 - as small as to 0.1mg/l in water can leads to the development of slimes and algal growths (Adekunle et al., 2007). In a poorly buffered system higher concentration of PO4 - should be of concerned due its detrimental effects on food preparation (Longe and Balogun, 2009).The low concentrations of PO4 - ions observed in the groundwater samples was caused by the attenuation of PO4 - in the unsaturated zones. The Groundwater and assessment program (1999) has shown that low concentration of PO4 - in urban groundwater is due to attenuation of PO4 - in the unsaturated zones, which retards its movement into groundwater. Once PO4 - reached the saturated zones, it cannot be attenuated (Noss and Billa, 1988; Kaplan, 1987). Figure 3: water level contour plot of the study area, water level in some shallow hand-dug wells are less than 1metre especially during the wet season
  • 7. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol. 3, No.9, 2013 214 On-site disposal system is repository for human wastes. Apart from the laundries and bathrooms wastes, there are those generated from the gastrointestinal tracks of humans. The gastrointestinal tracks of human contain bacterial such as Coliforms. The presence of feacal coliforms in groundwater aquifers signifies effluents from on-site disposal systems. The bacterial composition of the groundwater analyzed ranged from not-detected (ND) to 25MNP/100ml and ND to 9.66 for the total coliform counts and Escherichia coli, with mean value for 6.5685 and 3.7215MNP/100ml respectively (Table 2). The obtained values for the total coliform counts and Escherichia coli in the groundwater samples are significantly higher than the WHO, 1996 guidelines, which indicates that 75 percent of shallow groundwater samples are hydraulically connected to on-site disposal systems and as such not fit for drinking. The observed contaminations of groundwater by pathogens may be attributable to the existence of high water table (Figure 3), flow by-passing the clogging mats, which is common during higher recharge period of the year and the shallowness of the aquifers (Figure 4). When the clogging mat is by-passed by percolation of wastewater from septic tanks, it may results in the introduction of microbes into aquifers (Ground water and assessment program, 1999). The reason for this is that attenuation of pathogens usually takes place at the clogging mats, which is often situated between the soils and the drainfield media. Figure 4: Depth to water level contour The contribution of soils to the attenuation of contaminants and effluents from on-site disposal systems cannot be overemphasized. They assist in the reduction of effluents from septic tanks by way of absorption, dispersion and retardation of the migration of contaminants within the vadose zone, thereby reducing the degree of groundwater contamination. The characteristics of soils (Figure 5) in the study area may have played significant roles in attenuation of effluents from septic tank disposal systems, thus most of the groundwater samples were not affected by failure of septic tanks.
  • 8. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol. 3, No.9, 2013 215 Figure 3; Lithologies description of some boreholes and water levels in study area Conclusion The slightly elevated concentration of NO- 3, electrical conductivity and TDS, the spatial distribution of other anions and cations and, coupled with strong evidence of the presence of feacal coliform and E-coli as well as concentrations of NH3+ that were above the tolerance limit of the standard recommended by WHO and NSDWQ, suggest that the groundwater samples may have been contaminated by on-site sewage disposal systems. Therefore, the hydrogeochemical investigation of shallow groundwater aquifers has demonstrated hydraulic connection between on–site sewage disposal systems and some of the shallow groundwater aquifers in the study area. This is reflected more among the shallowest of the shallow aquifers, which are more hydraulically connected to the on-site sewage disposal system than the deeper shallow aquifers, especially during the wet seasons. The few contaminations recorded in groundwater samples may have emanated from the inability of soils in the unsaturated zones to attenuate the effluents, as result of the presence of permeable soils below septic tank and high aquifers recharge rate common during the wet seasons. During the wet seasons the clogging mats that usually help in natural attenuation are often by-pass by groundwater percolation. However, the low concentration of anions and cations measured in the hydrogeochemical investigation also shows that naturally attenuation by the unsaturated zone may have contributed significantly in causing the reduction in the measured concentrations, which are below the WHO and NSDWQ standards. The conclusion therefore is that some of the shallow aquifers are not fit for drinking and it is recommended that drinking water in Ughelli area should be sourced from deeper aquifer by drilling rather than hand-dug wells, which are often prone to contamination by effluent from on-site sewage disposal systems as demonstrated in the study. References Adekunle, I.M., M.T. Adetunji, A.M. Gbadebo and O.B. Banjoko, 2007. Assessment of groundwater quality in a typical rural settlement in Southwest, Nigeria. Int. J. Environ. Res. Public Health, 4(4): 307-318. Allen, J.R.L., 1965. Late Quaternary Niger delta and adjacent areas: sedimentary environments and lithofacies. Bull.AAPG 49, 547-600. APHA, 1994. Standard Methods for Examination of Water and Wastewater. 18th Edn., American Public Health Association. Beller, M., Ellis, A., Lee, S.H., Drebot, M.A., Jenkerson, S.A., Funk, E., Sobsey, M.D., Simmons III., O.D., Monroe, S.S., Ando, T., Noel, J., Petric, M., Middaugh, J.P., Spika, J.S., 1997. Outbreak of viral gastroenteritis due to a contaminated well: International consequences. Journal of the American Medical Association 278(7), 563–568.
  • 9. Journal of Environment and Earth Science www.iiste.org ISSN 2224-3216 (Paper) ISSN 2225-0948 (Online) Vol. 3, No.9, 2013 216 Borchardt, M.A., Chyou, P., DeVries, E.O., Belongia, E.A., 2003b. Septic system density and infectious diarrhea in a defined population of children. Environmental Health Perspectives 111 (5), 742–748. Brown, C.L., Starn, J.J., Stollenwerk, K., Mondazzi, R.A., Trombley, T.J., 2009. Aquifer Chemistry and Transport Processes in the Zone of Contribution to a Public-Supply Well in Woodbury, Connecticut, 2002–06. US Geological Survey Scientific Investigations Report 2009-5051, 158pp. Chilton, J., (1999), (ed), Groundwater in the urban environment, International Contributions to Hydrogeology Vol. 21, 342 p, IAH, A.A. Balkema, Rotterdam. Craun, G.F., 1979. Waterborne disease – a status report emphasizing outbreaks in ground-water systems. Ground Water 17, 183–191. Craun, G.F., 1984. Health aspects of groundwater pollution. In: Bitton, G., Gerba, C.P.(Eds.), Groundwater Pollution Microbiology. John Wiley and Sons, New York, pp. 135–179. DeBorde, D.C., Woessner, W.W., Lauerman, B., Ball, P.N., 1998. Virus occurrence and transport INA school septic system and unconfined aquifer. Ground Water 36 (5), 825–834. Francy, D.S., Bushon, R.N., Stopar, Julie, Luzano, E.J., Fout, G.S., 2004. Environmental Factors and Chemical and Microbiological Water-Quality Constituents Related to the Presence of Enteric Viruses in Ground Water from Small Public Water Supplies in Southeastern Michigan. US Geological Survey Scientific Investigations Report 2004-5219, 54pp. Gardner, K.K., Vogel, R.M., 2005. Predicting ground water nitrate concentration from land use. Ground Water 43, 343–352. Ground Water Protection Council, 2007. Ground Water Report to the Nation: A Call to Action, Ground Water Protection Council, Oklahoma City, Oklahoma, 156pp Jin, Z., Chen, Y., Wang, F., Ogura, N., 2004. Detection of nitrate sources in urban groundwater by isotopic and chemical indicators, Hangzhou City, China. Environmental Geology 45 (7), 1017–1024. Kaplan, B.O. 1987. Septic Systems Handbook. Lewis Publishers. Chelsea, Michigan.290 p. Landon, M.K., Clark, B.R., McMahon, P.B., McGuire, V.L., Turco, M.J., 2008, Hydrogeology, Chemical- Characteristics, and Transport Processes in the Zone of Contribution of a Public-Supply Well in York, Nebraska. US Geological Survey Scientific Investigations Report 2008-5050, 149pp. Longe, E.O., Balogun, M.R., (2009). Groundwater Quality Assessment near a Municipal Landfill, Lagos, Nigeria, Research Journal of Applied Sciences, Engineering and Technology 2(1): 39-44, 2010 Miller, L.D., Ortiz, R.F., 2007. Ground-Water Quality and Potential Effects of Individual Sewage Disposal System Effluent on Ground-Water Quality in Park County, Colorado, 2001–2004. US Geological Survey Scientific Investigations Report 2007-5220, 48p. Miller, D.W., 1980. Waste-disposal effects on ground water: BerkIey, Calif., Premier Press, 512 p. Noss, R.R., M. Billa. 1988. Septic System Maintenance Management. Journal of Urban Planning and Development. 114:73-90. Ophori, D.U. (2007). A Simulation of large-scale groundwater flow in the Niger Delta, Nigeria. Environmental Geosciences, 14, No. 4. 1-15 Panno, S.V., Kelley, W.R., Hackley, K.C., Weibel, C.P., 2007. Chemical and bacterial quality of aeration-type wastewater treatment system discharge. Ground Water Monitoring and Remediation 27 (2), 71–76. Peavy, H.S., 1978. Groundwater Pollution From Septic Tank Drainfields—A Report to the Blue Ribbons of the Big Sky Country Areawide Planning Organization. Bozeman, Mont., Dept. of Civil Engineering and Engineering Mechanics, Montana State University. Reyment, R.A. 1965. Aspects of the Geology of Nigeria. University Press: Ibadan, Nigeria. Robertson, W.D., Cherry, J.A., Sudicky, E.A., 1991. Ground-water contamination from two small septic systems on sand aquifers. Ground Water 29 (1), 82–92. Robertson, W.D., Blowes, D.W., 1995. Major ion and trace metal geochemistry of an acidic septic-system plume in silt. Ground Water 33, 275–283. Short, KC; Stauble, AJ (1967). Outline of geology of Niger Delta. American Assoc. Petroleum Geologists Bull. 51: 761-779. USEPA, 2002. Onsite Wastewater Treatment Systems Manual. Environmental Protection Agency Report EPA625/R-00/008, 175pp. Weber, K.J., E. Daukoru, 1975, Petroleum geology of the Niger Delta: 9th World Petroleum Congress Proceedings 2, 209-221. Wigwe, G.A. (1975). The Niger Delta: Physical. In G.E.K. Ofomata (ed). Nigeria in maps: Eastern States. Pp380 –400. Ethiope Publ. House, Benin City World Health Organization (1996). Guidelines for drinking water quality. 2nd ed.: Health criteria and other supporting information. Geneva.
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