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CHAPTER
3
MEC 451
Thermodynamics
First Law of
Thermodynamics
Lecture Notes:
MOHD HAFIZ MOHD NOH
HAZRAN HUSAIN & MOHD SUHAIRIL
Faculty of Mechanical Engineering
Universiti Teknologi MARA, 40450
Shah Alam, Selangor
For students EM 220 and EM 221 only
1
FacultyofMechanical Engineering, UiTM
2
MEC 451 – THERMODYNAMICS
FIRST LAW OF THERMODYNAMICS
ENERGY ANALYSIS
OF CLOSED SYSTEM
First Law of Thermodynamics
MEC 451 – THERMODYNAMICS
FacultyofMechanical Engineering, UiTM
3
 The First Law is usually referred to as the Law of Conservation
of Energy, i.e. energy can neither be created nor destroyed, but
rather transformed from one state to another.
 The energy balance is maintained within the system being
studied/defined boundary.
 The various energies associated are then being observed as
they cross the boundaries of the system.
FacultyofMechanical Engineering, UiTM
4
MEC 451 – THERMODYNAMICS
Energy Balance for Closed System
Heat
Work
z
Closed
System
Reference Plane, z = 0

V
or
E E E
in out system
  
FacultyofMechanical Engineering, UiTM
5
MEC 451 – THERMODYNAMICS
 According to classical thermodynamics
Q W E
net net system
  
 The total energy of the system, Esystem, is given as
E Internal energy Kinetic energy Potential energy
E U KE PE
= + +
= + +
 The change in stored energy for the system is
   
E U KE PE
  
 The first law of thermodynamics for closed systems then can be
written as
Q W U KE PE
net net
   
  
FacultyofMechanical Engineering, UiTM
6
MEC 451 – THERMODYNAMICS
 If the system does not move with a velocity and has no change in
elevation, the conservation of energy equation is reduced to
Q W U
net net
  
 The first law of thermodynamics can be in the form of
)
(
1000
)
(
2000
1
2
2
1
2
2
1
2 kJ
z
z
g
V
V
u
u
m
W
Q net
net 






 






)
/
(
1000
)
(
2000
1
2
2
1
2
2
1
2 kg
kJ
z
z
g
V
V
u
u
w
q net
net 






 






 For a constant volume process,







 






1000
)
(
2000
1
2
2
1
2
2
1
2
z
z
g
V
V
u
u
m
W
Q net
net







 





1000
)
(
2000
1
2
2
1
2
2
1
2
z
z
g
V
V
u
u
m
Qnet
FacultyofMechanical Engineering, UiTM
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MEC 451 – THERMODYNAMICS
 For a constant pressure process,







 






1000
)
(
2000
1
2
2
1
2
2
1
2
z
z
g
V
V
u
u
m
W
Q net
net







 







1000
)
(
2000
)
( 1
2
2
1
2
2
1
2
1
2
z
z
g
V
V
u
u
m
V
V
P
Qnet







 







1000
)
(
2000
)
( 1
2
2
1
2
2
1
2
1
2
z
z
g
V
V
V
V
P
u
u
m
Qnet







 





1000
)
(
2000
1
2
2
1
2
2
1
2
z
z
g
V
V
h
h
m
Qnet
FacultyofMechanical Engineering, UiTM
8
MEC 451 – THERMODYNAMICS
Rigid tank Piston cylinder
Example of Closed Systems
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MEC 451 – THERMODYNAMICS
A closed system of mass 2 kg
undergoes an adiabatic process.
The work done on the system is
30 kJ. The velocity of the system
changes from 3 m/s to 15 m/s.
During the process, the elevation
of the system increases 45 meters.
Determine the change in internal
energy of the system.
Example 3.1
Solution:
 Energy balance,







 






1000
)
(
2000
1
2
2
1
2
2
1
2
z
z
g
V
V
u
u
m
W
Q net
net
 Rearrange the equation
net
Q
 
 
2 2
2 1 2 1
2 1
2 2
2 1 2 1
2 1
2 2
( )
2000 1000
( )
2000 1000
9.81 45
15 3
30 2 2 2
2000 1000
14.451 ..
net
net
V V g z z
W m u u
V V g z z
W m u u
u
u kJ Ans
 
 
    
 
 
 
 
    
 
 
 
 

       
   
   
 
FacultyofMechanical Engineering, UiTM
10
MEC 451 – THERMODYNAMICS
Steam at 1100 kPa and 92 percent
quality is heated in a rigid container
until the pressure is 2000 kPa. For a
mass of 0.05 kg, calculate the amount
of heat supply (in kJ) and the total
entropy change (in kJ/kg.K).
Example 3.2 Solution:
 
 
 
3
1 1
1 1 1 1
1 1 1 1
1 1 1 1
.
1
1100 , 0.92
0.00113 0.92 0.17753 0.001133
0.1634
780.09 0.92 1806.3
2441.9
2.1792 0.92 4.3744
6.204
f fg
m
kg
f fg
kL
kg
f fg
kJ
kg K
State
at P kPa x
v v x v
u u x u
s s x s
 
 
  

 
 

 
 

kg
m
s
x
s
s
kg
kJ
u
x
u
u
fg,
f,
fg,
f,
3
1
1
1
1
1
1
1
1
20212
.
6
)
3735
.
4
(
92
.
0
1785
.
2
024
.
2441
)
7
.
1805
(
92
.
0
78
.
779










FacultyofMechanical Engineering, UiTM
11
MEC 451 – THERMODYNAMICS
 
3
2 2
2 2
2
2
2
2000 , 0.1634
0.15122 2945.9 7.1292
0.1634
0.17568 3116.9 7.4337
0.1634 0.15122
2945.9 3116.9 2945.9
0.17568 0.15122
3030.42
0.1634 0.15122
7.1292 7.
0.17568 0.15122
m
kg
kJ
kg
State
at P kPa v
v u s
u s
u
s
 

 
  
 

 


 
   

 
 
.
4337 7.1292
7.2790 kJ
kg K


 For a rigid container,
v2=v1=0.1634 m3/kg
g
v
v 
2 superheated
FacultyofMechanical Engineering, UiTM
12
MEC 451 – THERMODYNAMICS
 
 
2 1
0.05 3030.42 2441.9
29.43
Q m u u
kJ
 
 

 Amount of heat supplied, Q
 The change in entropy, Δs
2 1
.
7.2790 6.204
1.075 kJ
kg K
s s s
  
 

FacultyofMechanical Engineering, UiTM
13
MEC 451 – THERMODYNAMICS
Example 3.3
A rigid tank is divided into two equal
parts by a partition. Initially one side
of the tank contains 5 kg water at 200
kPa and 25°C, and the other side is
evacuated. The partition is then
removed, and the water expands into
the entire tank. The water is allowed to
exchange heat with its surroundings
until the temperature in the tank
returns to the initial value of 25°C.
Determine (a) the volume of the tank
(b) the final pressure (c) the heat
transfer for this process.
Solution:
 
3
1
1 @ 25
1
1
3
1
200 ,
0.001003
25
5 0.001003
0.005
m
kg
o f C
State
P kPa
v v
T C
initial volumeof half resevoir
V mv
m
 
 

 


 The initial volume for entire tank
 
3
2 0.005
0.01
resevoir
V
m


sat
T
T 
1 Comp. liquid
FacultyofMechanical Engineering, UiTM
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MEC 451 – THERMODYNAMICS
 
net net
net net
Q W m u ke Pe
Q W
      
 m u ke
    Pe
 
 
 
2 1
net
Q m u m u u
   
 The final pressure
 The heat transfer for this process
3
3
3
2
2
2
2
25 0.001003
0.01
43.34
0.002
5
!
: 3.169
m
f kg
m
m
g kg
kg
f g
sat
saturated m
State
T C v
v
v
ch
ixture
eck region
v v v
then P P kPa

 



  

  
 
 
 
1 @ 25
2 2
2
2
5
5
2
104.88
2.3 10
104.88 2.3 10 2304.9
104.93
:
5 104.93 104.88
0.25
kJ
kg
f C
f fg
f
fg
kJ
kg
net
u u
u u x u
v v
x
v
u
Then
Q
kJ


 
 


 
   

 

 +ve sign indicates heat transfer
into the system.
kg
kJ
83
.
104

104.83 (2304.3)
(104.88-104.83)
104.88
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MEC 451 – THERMODYNAMICS
Supplementary Problems 1
1. Two tanks are connected by a valve. Tank A contains 2 kg of carbon
monoxide gas at 77°C and 0.7 bar. Tank B holds 8 kg of the same gas
at 27°C and 1.2 bar. Then the valve is opened and the gases are allowed
to mix while receiving energy via heat transfer from the surrounding.
The final equilibrium temperature is found to be 42°C. Determine (a)
the final pressure (b) the amount of heat transfer. Also state your
assumption. [P2=105 kPa, Q = +37.25 kJ]
2. A piston cylinder device contains 0.2 kg of water initially at 800 kPa
and 0.06 m3. Now 200 kJ of heat is transferred to the water while its
pressure is held constant. Determine the final temperature of the water.
Also, show the process on a T-V diagram with respect to saturation
lines. [ 721.1oC]
FacultyofMechanical Engineering, UiTM
16
MEC 451 – THERMODYNAMICS
Supplementary Problems 1
3. A piston-cylinder device contains 6 kg of refrigerant-134a at 800 kPa
and 50oC. The refrigerant is now cooled at constant pressure until it
exist as a liquid at 24oC. Show the process on T-v diagram and
determine the heat loss from the system. State any assumption made.
[1210.26 kJ]
4. A 0.5 m3 rigid tank contains refrigerant-134a initially at 200 kPa and 40
percent quality. Heat is now transferred to the refrigerant until the
pressure reaches 800 kPa. Determine (a) the mass of the refrigerant in
the tank and (b) the amount of heat transferred. Also, show the process
on a P-v diagram with respect to saturation lines.
[12.3 kg, 2956.2 kJ]
5. An insulated tank is divided into two parts by a partition. One part of
the tank contains 6 kg of an ideal gas at 50°C and 800 kPa while the
other part is evacuated. The partition is now removed, and the gas
expands to fill the entire tank. Determine the final temperature and the
pressure in the tank.
[50°C, 400 kPa]
FacultyofMechanical Engineering, UiTM
17
MEC 451 – THERMODYNAMICS
 Some thermodynamic cycle composes of processes in which
the working fluid undergoes a series of state changes such
that the final and initial states are identical.
 For such system the change in internal energy of the
working fluid is zero.
 The first law for a closed system operating in a
thermodynamic cycle becomes
Closed System First Law of a Cycle
Q W U
Q W
net net cycle
net net
 


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MEC 451 – THERMODYNAMICS
Boundary Works
3
2
4
5
1
P
V
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MEC 451 – THERMODYNAMICS
No Value of n Process Description Result of IGL
1 ∞ isochoric constant volume (V1 = V2)
2 0 isobaric constant pressure (P1 = P2)
3 1 isothermal constant temperature
(T1 = T2)
4 1<n< γ polytropic -none-
5 γ isentropic constant entropy (S1 = S2)
According to a law of constant

n
V
P
2
2
1
1
T
P
T
P

2
2
1
1
T
V
T
V

2
2
1
1 V
P
V
P 
1
2
1
1
2
2
1



















n
n
n
T
T
V
V
P
P
FacultyofMechanical Engineering, UiTM
20
MEC 451 – THERMODYNAMICS
 Various forms of work are expressed as follows
Process Boundary Work
isochoric
isobaric
isothermal
polytropic
isentropic
0
)
( 1
2
12 

 V
V
P
W
)
( 1
2
12 V
V
P
W 

1
2
1
1
12 ln
V
V
V
P
W 
n
V
P
V
P
W



1
1
1
2
2
12
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21
MEC 451 – THERMODYNAMICS
Example 3.4
Sketch a P-V diagram showing the following processes in a cycle
Process 1-2: isobaric work output of 10.5 kJ from an initial volume of 0.028
m3 and pressure 1.4 bar,
Process 2-3: isothermal compression, and
Process 3-1: isochoric heat transfer to its original volume of 0.028 m3 and
pressure 1.4 bar.
Calculate (a) the maximum volume in the cycle, in m3, (b) the isothermal work,
in kJ, (c) the net work, in kJ, and (d) the heat transfer during isobaric expansion,
in kJ.
FacultyofMechanical Engineering, UiTM
22
MEC 451 – THERMODYNAMICS
Solution:
 Process by process analysis,
 
 
 
12 2 1
2
3
2
10.5
140 0.028 10.5
1
0.1 3
2
0
W P V V
V
Section isobari
V m
c
  




 The isothermal work
 
 
 
2 2 3 3
3
3
23 2 2
2
0.103
140 515
0.028
ln
0.028
140 0.103 ln
0.103
18.78
2 3
PV PV
P kPa
V
W PV
Section isothermal
V
kJ

 
 
 
 
 
 
  


 

FacultyofMechanical Engineering, UiTM
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MEC 451 – THERMODYNAMICS
 The net work
 
31
12 23 31
0
10.5 18.78
8.2
1
8
3
net
W
W W
Section isochoric
W W
kJ

   
 
 

FacultyofMechanical Engineering, UiTM
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MEC 451 – THERMODYNAMICS
Example 3.5
A fluid at 4.15 bar is expanded reversibly according to a law PV = constant to
a pressure of 1.15 bar until it has a specific volume of 0.12 m3/kg. It is then
cooled reversibly at a constant pressure, then is cooled at constant volume until
the pressure is 0.62 bar; and is then allowed to compress reversibly according
to a law PVn = constant back to the initial conditions. The work done in the
constant pressure is 0.525 kJ, and the mass of fluid present is 0.22 kg.
Calculate the value of n in the fourth process, the net work of the cycle and
sketch the cycle on a P-V diagram.
FacultyofMechanical Engineering, UiTM
25
MEC 451 – THERMODYNAMICS
Solution:
 Process by process analysis,
 
 
 
1 1 2 2
1
3
2
12 1 1
1
115
0.22 0.12
415
0.00732
ln
0.0264
415 0.00732 l
1
n
0.00732
3.8 5
2
9
Section isothe
PV PV
V
m
V
W PV
V
k
rm l
J
a

 
  
 





FacultyofMechanical Engineering, UiTM
26
MEC 451 – THERMODYNAMICS
 
 
23 3 2
3
3
0.525
0.525
0.0264
115
0.03
2 3
097
Sec
W P V V
tion iso
kJ
V
m
baric




 

 
34
3
0
4
Section iso
W
choric


 
   
4 1
1 4
1 1 4 4
41
62 0.00732
415 0.03097
ln 0.1494 ln 0.2364
1.3182
1
415 0.0072 62 0.03097
1 1.3182
3. 2
1
51 4
4
n
n
P V
P V
n
n
PV PV
W
n
k
Section PolytroPic
J
 
  
 
 
  
 








 

 The net work of the cycle
12 23 34 41
0.9076
net
W W W W W
kJ
   

FacultyofMechanical Engineering, UiTM
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MEC 451 – THERMODYNAMICS
Supplementary Problems 2
1. A mass of 0.15 kg of air is initially exists at 2 MPa and 350oC. The air is
first expanded isothermally to 500 kPa, then compressed polytropically
with a polytropic exponent of 1.2 to the initial state. Determine the
boundary work for each process and the net work of the cycle.
2. 0.078 kg of a carbon monoxide initially exists at 130 kPa and 120oC. The
gas is then expanded polytropically to a state of 100 kPa and 100oC.
Sketch the P-V diagram for this process. Also determine the value of n
(index) and the boundary work done during this process.
[1.248,1.855 kJ]
FacultyofMechanical Engineering, UiTM
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MEC 451 – THERMODYNAMICS
3. Two kg of air experiences the three-
process cycle shown in Fig. 3-14.
Calculate the net work.
4. A system contains 0.15 m3 of air pressure of 3.8 bars and 150⁰ C. It is
expanded adiabatically till the pressure falls to 1.0 bar. The air is then
heated at a constant pressure till its enthalpy increases by 70 kJ.
Sketch the process on a P-V diagram and determine the total work
done.
Use cp=1.005 kJ/kg.K and cv=0.714 kJ/kg.K
FacultyofMechanical Engineering, UiTM
29
MEC 451 – THERMODYNAMICS
FIRST LAW OF THERMODYNAMICS
MASS & ENERGY ANALYSIS
OF CONTROL VOLUME
FacultyofMechanical Engineering, UiTM
30
MEC 451 – THERMODYNAMICS
Conservation of Mass
 Conservation of mass is one of the most fundamental
principles in nature. We are all familiar with this
principle, and it is not difficult to understand it!
 For closed system, the conservation of mass principle is
implicitly used since the mass of the system remain
constant during a process.
 However, for control volume, mass can cross the
boundaries. So the amount of mass entering and leaving
the control volume must be considered.
FacultyofMechanical Engineering, UiTM
31
MEC 451 – THERMODYNAMICS
Mass and Volume Flow Rates
 Mass flow through a cross-sectional area per unit time is called the
mass flow rate. Note the dot over the mass symbol indicates a time
rate of change. It is expressed as

 dA
V
m .


 If the fluid density and velocity are constant over the flow cross-
sectional area, the mass flow rate is
voulme
specific
called
is
where
AV
AV
m





1




FacultyofMechanical Engineering, UiTM
32
MEC 451 – THERMODYNAMICS
Principal of Conservation of Mass
 The conservation of mass principle for a control volume can be
expressed as
in out CV
m m m
 
 For a steady state, steady flow process the conservation of mass
principle becomes
(kg/s)
in out
m m

FacultyofMechanical Engineering, UiTM
33
MEC 451 – THERMODYNAMICS
 As the fluid upstream pushes mass across the control volume, work
done on that unit of mass is
flow
flow
flow
A
W FdL FdL PdV Pv m
A
W
w Pv
m
 



   
 
Flow Work & The Energy of a Flowing Fluid
FacultyofMechanical Engineering, UiTM
34
MEC 451 – THERMODYNAMICS
 The total energy carried by a unit of mass as it crosses the control
surface is the sum of the internal energy + flow work + potential
energy + kinetic energy
 





 gz
V
h
gz
V
P
u
energy
2
2
2
2

 The first law for a control volume can be written as

 






















in
in
in
in
in
out
out
out
out
out
net
net gz
V
h
m
gz
V
h
m
W
Q
2
2
2
.
2
.
.
.
Total Energy of a Flowing Fluid
FacultyofMechanical Engineering, UiTM
35
MEC 451 – THERMODYNAMICS
Total Energy of a Flowing Fluid
 The steady state, steady flow conservation of mass and first law of
thermodynamics can be expressed in the following forms
)
(
1000
)
(
2000
1
2
2
1
2
2
1
2
.
.
.
kW
z
z
g
V
V
h
h
m
W
Q net
net 






 






)
(
1000
)
(
2000
1
2
2
1
2
2
1
2 kJ
z
z
g
V
V
h
h
m
W
Q net
net 






 






)
/
(
1000
)
(
2000
1
2
2
1
2
2
1
2 kg
kJ
z
z
g
V
V
h
h
w
q net
net 






 






FacultyofMechanical Engineering, UiTM
36
MEC 451 – THERMODYNAMICS
Steady-flow Engineering Devices
FacultyofMechanical Engineering, UiTM
37
MEC 451 – THERMODYNAMICS
Nozzle & Diffuser
 Nozzle - device that increases
the velocity fluid at the expense
of pressure.
 Diffuser - device that increases
pressure of a fluid by slowing it
down.
 Commonly utilized in jet
engines, rockets, space-craft
and even garden hoses.
 Q = 0 (heat transfer from the
fluid to surroundings very
small
 W = 0 and ΔPE = 0
FacultyofMechanical Engineering, UiTM
38
MEC 451 – THERMODYNAMICS
 Energy balance (nozzle & diffuser):

 
























out
out
out
out
out
out
out
in
in
in
in
in
in
in gz
V
h
m
W
Q
gz
V
h
m
W
Q
2
2
2
.
.
.
2
.
.
.



















2
2
2
.
2
.
out
out
out
in
in
in
V
h
m
V
h
m



















2
2
2
2
2
2
1
1
V
h
V
h
FacultyofMechanical Engineering, UiTM
39
MEC 451 – THERMODYNAMICS
Example 3.6
Steam at 0.4 MPa, 300ºC,
enters an adiabatic nozzle with
a low velocity and leaves at 0.2
MPa with a quality of 90%.
Find the exit velocity.
Solution:
 Simplified energy balance:
2
1
1
V
h 
 
2
2
2
1
1
1
2 2
2
2
2
2 2
1
3067.1
0.4
300 sup
2
0.2
2486.1
0.9
kJ
kg
o
f fg
kJ
kg
V
h
State
h
P MPa
T C erheated
State
h h x h
P MPa
h
x
   
   
 
   
 

 

 
 
 


 
1 2
1 2
1
0.4 0.2
300 0.
1 2
9
0
o
P MPa P MPa
T C x
State S te
V
ta
 
 
 Exit velocity:
 
2 2000 3067.1 2486.1
1078 /
V
m s
 

FacultyofMechanical Engineering, UiTM
40
MEC 451 – THERMODYNAMICS
Example 3.7
Air at 10°C and 80 kPa enters the
diffuser of a jet engine steadily
with a velocity of 200 m/s. The
inlet area of the diffuser is 0.4 m2.
The air leaves the diffuser with a
velocity that is very small
compared with the inlet velocity.
Determine (a) the mass flow rate
of the air and (b) the temperature
of the air leaving the diffuser.
1 2
1
1
2
1
80 0
1
1
0
200 /
0.
2
4
o
P kPa V
T C
V m s
St
A
ate State
m




Solution:
2
2
2
1
1 2
2
V
V
h h
 
  
 
 
0
2
 
 
 
 
 Simplified energy balance:
 From Ideal Gas Law:
3
1
1
1
1.015 m
kg
RT
v
P
 
FacultyofMechanical Engineering, UiTM
41
MEC 451 – THERMODYNAMICS
 Mass flow rate
  
1 1
1
1
1
200 0.4
1.015
78.8 kg
s
m V A
v

 
  
 

 Enthalpy at state 1
 
1 1 1.005 283
284.42
p
kJ
kg
h C T
 

 From energy balance:
2
1
2 1
2
2
2
2000
200
284.42
2000
304.42
304.42
1.005
302.9
kJ
kg
p
V
h h
h
T
C
K
 
 




FacultyofMechanical Engineering, UiTM
42
MEC 451 – THERMODYNAMICS
Turbine & Compressor
 Turbine – a work producing device through the expansion of a
fluid.
 Compressor (as well as pump and fan) - device used to increase
pressure of a fluid and involves work input.
 Q = 0 (well insulated), ΔPE = 0, ΔKE = 0 (very small compare to
Δenthalpy).
FacultyofMechanical Engineering, UiTM
43
MEC 451 – THERMODYNAMICS
 Energy balance: for turbine

 
























out
out
out
out
out
out
out
in
in
in
in
in
in
in gz
V
h
m
W
Q
gz
V
h
m
W
Q
2
2
2
.
.
.
2
.
.
.
   
out
out
out
in
in h
m
W
h
m
.
.
.


 
2
1
.
.
h
h
m
W out 

FacultyofMechanical Engineering, UiTM
44
MEC 451 – THERMODYNAMICS
 Energy balance: for compressor, pump and fan

 
























out
out
out
out
out
out
out
in
in
in
in
in
in
in gz
V
h
m
W
Q
gz
V
h
m
W
Q
2
2
2
.
.
.
2
.
.
.
   
out
out
in
in
in h
m
h
m
W
.
.
.


 
1
2
.
.
h
h
m
W in 

FacultyofMechanical Engineering, UiTM
45
MEC 451 – THERMODYNAMICS
Example 3.8
The power output of an adiabatic steam turbine is 5 MW. Compare
the magnitudes of Δh, Δke, and Δpe. Then determine the work done
per unit mass of the steam flowing through the turbine and calculate
the mass flow rate of the steam.
Data : Inlet (P = 2 MPa, T = 400ºC,v = 50 m/s, z = 10 m)
Exit (P = 15 kPa, x = 90%, v = 180 m/s, z = 6m)
FacultyofMechanical Engineering, UiTM
46
MEC 451 – THERMODYNAMICS
Solution:
 
1
1
1
2
2
2 2 2 2
1
sup
2
3247.6
400
2
15
.
0.9
225.94 0.9 2373.1
2361.73
o kJ
kg
f fg
kJ
kg
State
erheated
p MPa
h
T C
State
P kPa
sat mixture
x
h h x h
 


 
 

 
 
 

.
in
Q
.
in
W

2
.
2
. . .
2
2
in
in in in
in
out
out out out out
out
out
V
m h gz
V
Q W m h gz
 
   
 
 
 
   
 
 


 From energy balance:
 
2 1
2 2
2 1
2 1
885.87
14.95
2000
0.04
1000
kJ
kg
kJ
kg
kJ
kg
h h h
V V
KE
g z z
PE
    

  

   
 Solve the equation:
3248.4
(2372.3)
2361.01
-887.39
FacultyofMechanical Engineering, UiTM
47
MEC 451 – THERMODYNAMICS
 the work done per unit mass
 
 
2 2
1 2
1 2
1 2
2000 1000
885.87 14.95 0.04
870.96
out
kJ
kg
g z z
V V
W h h
 
 

 

   
 
 
 
 
   
 
  

 The mass flow rate
5000
5.74
870.96
kg
out
s
out
W
m
W
  
887.39
872.48
872.48
5.73
FacultyofMechanical Engineering, UiTM
48
MEC 451 – THERMODYNAMICS
Example 3.9
Air at 100 kPa and 280 K is
compressed steadily to 600
kPa and 400 K. The mass
flow rate of the air is 0.02
kg/s, and a heat loss of 16
kJ/kg occurs during the
process. Assuming the
changes in kinetic and
potential energies are
negligible, determine the
necessary power input to the
compressor.
Solution:
 simplified energy balance:
 
 
2 1
2 1
in out
out
W m h h Q
m h h mq
  
  
1
1
1
2
2
2
1
100
280.13
280
2
600
400.98
400
kJ
kg
kJ
kg
State
air
P kPa
h
T K
State
air
P kPa
h
T K
 


 
 


 
FacultyofMechanical Engineering, UiTM
49
MEC 451 – THERMODYNAMICS
 Thus
 
0.02 400.98 280.13 16
2.74
in
W
kW
 
  
 

FacultyofMechanical Engineering, UiTM
50
MEC 451 – THERMODYNAMICS
Throttling Valve
Flow-restricting devices that
cause a significant pressure drop
in the fluid.
Some familiar examples are
ordinary adjustable valves and
capillary tubes.
FacultyofMechanical Engineering, UiTM
51
MEC 451 – THERMODYNAMICS
Steam enters a throttling valve at
8000 kPa and 300°C and leaves
at a pressure of 1600 kPa.
Determine the final temperature
and specific volume of the
steam.
Example 3.10
   
1
1
1
2
2 1
2 2 2 2 2
1
sup
8000
2786.5
300
2
1600
int
1500 198.29 0.001154 0.131710 844.55 2791
1600
1750 205.72 0.001166 0.113440 878.16 2795.2
o kJ
kg
o
f g f g
f g f g
State
erheated
P kPa
h
T C
State
P kPa
make erpolation
h h
v v h h
P kPa T C
T v v h h
 


 
 

 
FacultyofMechanical Engineering, UiTM
52
MEC 451 – THERMODYNAMICS
2 201.3o
sat
T T C
 
 At state 2, the region is sat.
mixture
 Getting the quality at state 2
2 2
2
2 2
2786.5 857.994
2792.68 857.994
0.997
f
g f
h h
x
h h







 Specific volume at state 2
 
3
2 2 2 2
0.0011588
0.997 0.124402 0.0011588
0.1240
f fg
m
kg
v v x v
 
 


FacultyofMechanical Engineering, UiTM
53
MEC 451 – THERMODYNAMICS
The section where the mixing process
takes place.
An ordinary T-elbow or a Y-elbow in
a shower, for example, serves as the
mixing chamber for the cold- and
hot-water streams.
Mixing Chamber
FacultyofMechanical Engineering, UiTM
54
MEC 451 – THERMODYNAMICS
Mixing Chamber
 Energy Balance:
 
   
1 1 2 2 3 3
1 1 3 1 2 3 3
1 1 2 3 3 2
3 2
1 3
1 2
m h m h m h
m h m m h m h
m h h m h h
h h
m m
h h
 
  
  
 

  

 
FacultyofMechanical Engineering, UiTM
55
MEC 451 – THERMODYNAMICS
Devices where two moving fluid
streams exchange heat without
mixing.
Heat exchangers typically involve
no work interactions (w = 0) and
negligible kinetic and potential
energy changes for each fluid
stream.
Heat Exchanger
FacultyofMechanical Engineering, UiTM
56
MEC 451 – THERMODYNAMICS
Liquid sodium, flowing at 100
kg/s, enters a heat exchanger at
450°C and exits at 350°C. The
specific heat of sodium is 1.25
kJ/kg.oC. Water enters at 5000
kPa and 20oC. Determine the
minimum mass flux of the water
so that the water does not
completely vaporize. Neglect the
pressure drop through the
exchanger. Also, calculate the
rate of heat transfer.
Example 3.11 Solution:
 simplified energy balance:
   
   
1 1 2 2
1 2 2 1
, 1 2 2 1
s s w w s s w w
s s s w w w
s p s s s w w w
m h m h m h m h
m h h m h h
m C T T m h h
  
  
  
1
1
1
2
2
1:
.
5000
88.61
20
2:
5000
2794.2
o kJ
w kg
kJ
w kg
State water
comp liquid
P kPa
h
T C
State water
P kPa
h
 


 


Assume a sat. vapor
state to obtain the
max. allowable exiting
enthalpy.
FacultyofMechanical Engineering, UiTM
57
MEC 451 – THERMODYNAMICS
 the minimum mass flux of the water
so that the water does not
completely vaporize
 
 
  
, 1 2
2 1
100 1.25 450 350
2794.2 88.61
4.62
s p s s s
w
w w
kg
s
m C T T
m
h h







 the rate of heat transfer
 
 
2 1
4.62 2794.2 88.61
12.5
w w w w
Q m h h
MW
 
 

FacultyofMechanical Engineering, UiTM
58
MEC 451 – THERMODYNAMICS
Supplementary Problems 3
1. Air flows through the supersonic nozzle . The inlet conditions are 7 kPa
and 420°C. The nozzle exit diameter is adjusted such that the exiting
velocity is 700 m/s. Calculate ( a ) the exit temperature, ( b )the mass flux,
and ( c ) the exit diameter. Assume an adiabatic quasiequilibrium flow.
2. Steam at 5 MPa and 400°C enters a nozzle steadily velocity of 80 m/s,
and it leaves at 2 MPa and 300°C. The inlet area of the nozzle is 50 cm2,
and heat is being lost at a rate of 120 kJ/s. Determine (a) the mass flow
rate of the steam, (b) the exit velocity of the steam, and (c) the exit area
nozzle.
3. Steam enters a turbine at 4000 kPa and 500oC and leaves as shown in Fig
A below. For an inlet velocity of 200 m/s, calculate the turbine power
output. ( a )Neglect any heat transfer and kinetic energy change ( b )Show
that the kinetic energy change is negligible.
FacultyofMechanical Engineering, UiTM
59
MEC 451 – THERMODYNAMICS
Figure A
4. Consider an ordinary shower where hot water at 60°C is mixed with cold
water at 10°C. If it is desired that a steady stream of warm water at 45°C
be supplied, determine the ratio of the mass flow rates of the hot to cold
water. Assume the heat losses from the mixing chamber to be negligible
and the mixing to take place at a pressure of 150 kPa.
5. Refrigerant-134a is to be cooled by water in a condenser. The refrigerant
enters the condenser with a mass flow rate of 6 kg/min at 1 MPa and 70ºC
and leaves at 35°C. The cooling water enters at 300 kPa and 15°C and
leaves at 25ºC. Neglecting any pressure drops, determine (a) the mass
flow rate of the cooling water required and (b) the heat transfer rate from
the refrigerant to water.

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chap3firstlawthermodynamics-130703012634-phpapp02.ppt

  • 1. CHAPTER 3 MEC 451 Thermodynamics First Law of Thermodynamics Lecture Notes: MOHD HAFIZ MOHD NOH HAZRAN HUSAIN & MOHD SUHAIRIL Faculty of Mechanical Engineering Universiti Teknologi MARA, 40450 Shah Alam, Selangor For students EM 220 and EM 221 only 1
  • 2. FacultyofMechanical Engineering, UiTM 2 MEC 451 – THERMODYNAMICS FIRST LAW OF THERMODYNAMICS ENERGY ANALYSIS OF CLOSED SYSTEM
  • 3. First Law of Thermodynamics MEC 451 – THERMODYNAMICS FacultyofMechanical Engineering, UiTM 3  The First Law is usually referred to as the Law of Conservation of Energy, i.e. energy can neither be created nor destroyed, but rather transformed from one state to another.  The energy balance is maintained within the system being studied/defined boundary.  The various energies associated are then being observed as they cross the boundaries of the system.
  • 4. FacultyofMechanical Engineering, UiTM 4 MEC 451 – THERMODYNAMICS Energy Balance for Closed System Heat Work z Closed System Reference Plane, z = 0  V or E E E in out system   
  • 5. FacultyofMechanical Engineering, UiTM 5 MEC 451 – THERMODYNAMICS  According to classical thermodynamics Q W E net net system     The total energy of the system, Esystem, is given as E Internal energy Kinetic energy Potential energy E U KE PE = + + = + +  The change in stored energy for the system is     E U KE PE     The first law of thermodynamics for closed systems then can be written as Q W U KE PE net net       
  • 6. FacultyofMechanical Engineering, UiTM 6 MEC 451 – THERMODYNAMICS  If the system does not move with a velocity and has no change in elevation, the conservation of energy equation is reduced to Q W U net net     The first law of thermodynamics can be in the form of ) ( 1000 ) ( 2000 1 2 2 1 2 2 1 2 kJ z z g V V u u m W Q net net                ) / ( 1000 ) ( 2000 1 2 2 1 2 2 1 2 kg kJ z z g V V u u w q net net                 For a constant volume process,                1000 ) ( 2000 1 2 2 1 2 2 1 2 z z g V V u u m W Q net net               1000 ) ( 2000 1 2 2 1 2 2 1 2 z z g V V u u m Qnet
  • 7. FacultyofMechanical Engineering, UiTM 7 MEC 451 – THERMODYNAMICS  For a constant pressure process,                1000 ) ( 2000 1 2 2 1 2 2 1 2 z z g V V u u m W Q net net                 1000 ) ( 2000 ) ( 1 2 2 1 2 2 1 2 1 2 z z g V V u u m V V P Qnet                 1000 ) ( 2000 ) ( 1 2 2 1 2 2 1 2 1 2 z z g V V V V P u u m Qnet               1000 ) ( 2000 1 2 2 1 2 2 1 2 z z g V V h h m Qnet
  • 8. FacultyofMechanical Engineering, UiTM 8 MEC 451 – THERMODYNAMICS Rigid tank Piston cylinder Example of Closed Systems
  • 9. FacultyofMechanical Engineering, UiTM 9 MEC 451 – THERMODYNAMICS A closed system of mass 2 kg undergoes an adiabatic process. The work done on the system is 30 kJ. The velocity of the system changes from 3 m/s to 15 m/s. During the process, the elevation of the system increases 45 meters. Determine the change in internal energy of the system. Example 3.1 Solution:  Energy balance,                1000 ) ( 2000 1 2 2 1 2 2 1 2 z z g V V u u m W Q net net  Rearrange the equation net Q     2 2 2 1 2 1 2 1 2 2 2 1 2 1 2 1 2 2 ( ) 2000 1000 ( ) 2000 1000 9.81 45 15 3 30 2 2 2 2000 1000 14.451 .. net net V V g z z W m u u V V g z z W m u u u u kJ Ans                                                 
  • 10. FacultyofMechanical Engineering, UiTM 10 MEC 451 – THERMODYNAMICS Steam at 1100 kPa and 92 percent quality is heated in a rigid container until the pressure is 2000 kPa. For a mass of 0.05 kg, calculate the amount of heat supply (in kJ) and the total entropy change (in kJ/kg.K). Example 3.2 Solution:       3 1 1 1 1 1 1 1 1 1 1 1 1 1 1 . 1 1100 , 0.92 0.00113 0.92 0.17753 0.001133 0.1634 780.09 0.92 1806.3 2441.9 2.1792 0.92 4.3744 6.204 f fg m kg f fg kL kg f fg kJ kg K State at P kPa x v v x v u u x u s s x s                   kg m s x s s kg kJ u x u u fg, f, fg, f, 3 1 1 1 1 1 1 1 1 20212 . 6 ) 3735 . 4 ( 92 . 0 1785 . 2 024 . 2441 ) 7 . 1805 ( 92 . 0 78 . 779          
  • 11. FacultyofMechanical Engineering, UiTM 11 MEC 451 – THERMODYNAMICS   3 2 2 2 2 2 2 2 2000 , 0.1634 0.15122 2945.9 7.1292 0.1634 0.17568 3116.9 7.4337 0.1634 0.15122 2945.9 3116.9 2945.9 0.17568 0.15122 3030.42 0.1634 0.15122 7.1292 7. 0.17568 0.15122 m kg kJ kg State at P kPa v v u s u s u s                           . 4337 7.1292 7.2790 kJ kg K    For a rigid container, v2=v1=0.1634 m3/kg g v v  2 superheated
  • 12. FacultyofMechanical Engineering, UiTM 12 MEC 451 – THERMODYNAMICS     2 1 0.05 3030.42 2441.9 29.43 Q m u u kJ       Amount of heat supplied, Q  The change in entropy, Δs 2 1 . 7.2790 6.204 1.075 kJ kg K s s s      
  • 13. FacultyofMechanical Engineering, UiTM 13 MEC 451 – THERMODYNAMICS Example 3.3 A rigid tank is divided into two equal parts by a partition. Initially one side of the tank contains 5 kg water at 200 kPa and 25°C, and the other side is evacuated. The partition is then removed, and the water expands into the entire tank. The water is allowed to exchange heat with its surroundings until the temperature in the tank returns to the initial value of 25°C. Determine (a) the volume of the tank (b) the final pressure (c) the heat transfer for this process. Solution:   3 1 1 @ 25 1 1 3 1 200 , 0.001003 25 5 0.001003 0.005 m kg o f C State P kPa v v T C initial volumeof half resevoir V mv m           The initial volume for entire tank   3 2 0.005 0.01 resevoir V m   sat T T  1 Comp. liquid
  • 14. FacultyofMechanical Engineering, UiTM 14 MEC 451 – THERMODYNAMICS   net net net net Q W m u ke Pe Q W         m u ke     Pe       2 1 net Q m u m u u      The final pressure  The heat transfer for this process 3 3 3 2 2 2 2 25 0.001003 0.01 43.34 0.002 5 ! : 3.169 m f kg m m g kg kg f g sat saturated m State T C v v v ch ixture eck region v v v then P P kPa                    1 @ 25 2 2 2 2 5 5 2 104.88 2.3 10 104.88 2.3 10 2304.9 104.93 : 5 104.93 104.88 0.25 kJ kg f C f fg f fg kJ kg net u u u u x u v v x v u Then Q kJ                    +ve sign indicates heat transfer into the system. kg kJ 83 . 104  104.83 (2304.3) (104.88-104.83) 104.88
  • 15. FacultyofMechanical Engineering, UiTM 15 MEC 451 – THERMODYNAMICS Supplementary Problems 1 1. Two tanks are connected by a valve. Tank A contains 2 kg of carbon monoxide gas at 77°C and 0.7 bar. Tank B holds 8 kg of the same gas at 27°C and 1.2 bar. Then the valve is opened and the gases are allowed to mix while receiving energy via heat transfer from the surrounding. The final equilibrium temperature is found to be 42°C. Determine (a) the final pressure (b) the amount of heat transfer. Also state your assumption. [P2=105 kPa, Q = +37.25 kJ] 2. A piston cylinder device contains 0.2 kg of water initially at 800 kPa and 0.06 m3. Now 200 kJ of heat is transferred to the water while its pressure is held constant. Determine the final temperature of the water. Also, show the process on a T-V diagram with respect to saturation lines. [ 721.1oC]
  • 16. FacultyofMechanical Engineering, UiTM 16 MEC 451 – THERMODYNAMICS Supplementary Problems 1 3. A piston-cylinder device contains 6 kg of refrigerant-134a at 800 kPa and 50oC. The refrigerant is now cooled at constant pressure until it exist as a liquid at 24oC. Show the process on T-v diagram and determine the heat loss from the system. State any assumption made. [1210.26 kJ] 4. A 0.5 m3 rigid tank contains refrigerant-134a initially at 200 kPa and 40 percent quality. Heat is now transferred to the refrigerant until the pressure reaches 800 kPa. Determine (a) the mass of the refrigerant in the tank and (b) the amount of heat transferred. Also, show the process on a P-v diagram with respect to saturation lines. [12.3 kg, 2956.2 kJ] 5. An insulated tank is divided into two parts by a partition. One part of the tank contains 6 kg of an ideal gas at 50°C and 800 kPa while the other part is evacuated. The partition is now removed, and the gas expands to fill the entire tank. Determine the final temperature and the pressure in the tank. [50°C, 400 kPa]
  • 17. FacultyofMechanical Engineering, UiTM 17 MEC 451 – THERMODYNAMICS  Some thermodynamic cycle composes of processes in which the working fluid undergoes a series of state changes such that the final and initial states are identical.  For such system the change in internal energy of the working fluid is zero.  The first law for a closed system operating in a thermodynamic cycle becomes Closed System First Law of a Cycle Q W U Q W net net cycle net net    
  • 18. FacultyofMechanical Engineering, UiTM 18 MEC 451 – THERMODYNAMICS Boundary Works 3 2 4 5 1 P V
  • 19. FacultyofMechanical Engineering, UiTM 19 MEC 451 – THERMODYNAMICS No Value of n Process Description Result of IGL 1 ∞ isochoric constant volume (V1 = V2) 2 0 isobaric constant pressure (P1 = P2) 3 1 isothermal constant temperature (T1 = T2) 4 1<n< γ polytropic -none- 5 γ isentropic constant entropy (S1 = S2) According to a law of constant  n V P 2 2 1 1 T P T P  2 2 1 1 T V T V  2 2 1 1 V P V P  1 2 1 1 2 2 1                    n n n T T V V P P
  • 20. FacultyofMechanical Engineering, UiTM 20 MEC 451 – THERMODYNAMICS  Various forms of work are expressed as follows Process Boundary Work isochoric isobaric isothermal polytropic isentropic 0 ) ( 1 2 12    V V P W ) ( 1 2 12 V V P W   1 2 1 1 12 ln V V V P W  n V P V P W    1 1 1 2 2 12
  • 21. FacultyofMechanical Engineering, UiTM 21 MEC 451 – THERMODYNAMICS Example 3.4 Sketch a P-V diagram showing the following processes in a cycle Process 1-2: isobaric work output of 10.5 kJ from an initial volume of 0.028 m3 and pressure 1.4 bar, Process 2-3: isothermal compression, and Process 3-1: isochoric heat transfer to its original volume of 0.028 m3 and pressure 1.4 bar. Calculate (a) the maximum volume in the cycle, in m3, (b) the isothermal work, in kJ, (c) the net work, in kJ, and (d) the heat transfer during isobaric expansion, in kJ.
  • 22. FacultyofMechanical Engineering, UiTM 22 MEC 451 – THERMODYNAMICS Solution:  Process by process analysis,       12 2 1 2 3 2 10.5 140 0.028 10.5 1 0.1 3 2 0 W P V V V Section isobari V m c         The isothermal work       2 2 3 3 3 3 23 2 2 2 0.103 140 515 0.028 ln 0.028 140 0.103 ln 0.103 18.78 2 3 PV PV P kPa V W PV Section isothermal V kJ                     
  • 23. FacultyofMechanical Engineering, UiTM 23 MEC 451 – THERMODYNAMICS  The net work   31 12 23 31 0 10.5 18.78 8.2 1 8 3 net W W W Section isochoric W W kJ          
  • 24. FacultyofMechanical Engineering, UiTM 24 MEC 451 – THERMODYNAMICS Example 3.5 A fluid at 4.15 bar is expanded reversibly according to a law PV = constant to a pressure of 1.15 bar until it has a specific volume of 0.12 m3/kg. It is then cooled reversibly at a constant pressure, then is cooled at constant volume until the pressure is 0.62 bar; and is then allowed to compress reversibly according to a law PVn = constant back to the initial conditions. The work done in the constant pressure is 0.525 kJ, and the mass of fluid present is 0.22 kg. Calculate the value of n in the fourth process, the net work of the cycle and sketch the cycle on a P-V diagram.
  • 25. FacultyofMechanical Engineering, UiTM 25 MEC 451 – THERMODYNAMICS Solution:  Process by process analysis,       1 1 2 2 1 3 2 12 1 1 1 115 0.22 0.12 415 0.00732 ln 0.0264 415 0.00732 l 1 n 0.00732 3.8 5 2 9 Section isothe PV PV V m V W PV V k rm l J a             
  • 26. FacultyofMechanical Engineering, UiTM 26 MEC 451 – THERMODYNAMICS     23 3 2 3 3 0.525 0.525 0.0264 115 0.03 2 3 097 Sec W P V V tion iso kJ V m baric          34 3 0 4 Section iso W choric         4 1 1 4 1 1 4 4 41 62 0.00732 415 0.03097 ln 0.1494 ln 0.2364 1.3182 1 415 0.0072 62 0.03097 1 1.3182 3. 2 1 51 4 4 n n P V P V n n PV PV W n k Section PolytroPic J                           The net work of the cycle 12 23 34 41 0.9076 net W W W W W kJ     
  • 27. FacultyofMechanical Engineering, UiTM 27 MEC 451 – THERMODYNAMICS Supplementary Problems 2 1. A mass of 0.15 kg of air is initially exists at 2 MPa and 350oC. The air is first expanded isothermally to 500 kPa, then compressed polytropically with a polytropic exponent of 1.2 to the initial state. Determine the boundary work for each process and the net work of the cycle. 2. 0.078 kg of a carbon monoxide initially exists at 130 kPa and 120oC. The gas is then expanded polytropically to a state of 100 kPa and 100oC. Sketch the P-V diagram for this process. Also determine the value of n (index) and the boundary work done during this process. [1.248,1.855 kJ]
  • 28. FacultyofMechanical Engineering, UiTM 28 MEC 451 – THERMODYNAMICS 3. Two kg of air experiences the three- process cycle shown in Fig. 3-14. Calculate the net work. 4. A system contains 0.15 m3 of air pressure of 3.8 bars and 150⁰ C. It is expanded adiabatically till the pressure falls to 1.0 bar. The air is then heated at a constant pressure till its enthalpy increases by 70 kJ. Sketch the process on a P-V diagram and determine the total work done. Use cp=1.005 kJ/kg.K and cv=0.714 kJ/kg.K
  • 29. FacultyofMechanical Engineering, UiTM 29 MEC 451 – THERMODYNAMICS FIRST LAW OF THERMODYNAMICS MASS & ENERGY ANALYSIS OF CONTROL VOLUME
  • 30. FacultyofMechanical Engineering, UiTM 30 MEC 451 – THERMODYNAMICS Conservation of Mass  Conservation of mass is one of the most fundamental principles in nature. We are all familiar with this principle, and it is not difficult to understand it!  For closed system, the conservation of mass principle is implicitly used since the mass of the system remain constant during a process.  However, for control volume, mass can cross the boundaries. So the amount of mass entering and leaving the control volume must be considered.
  • 31. FacultyofMechanical Engineering, UiTM 31 MEC 451 – THERMODYNAMICS Mass and Volume Flow Rates  Mass flow through a cross-sectional area per unit time is called the mass flow rate. Note the dot over the mass symbol indicates a time rate of change. It is expressed as   dA V m .    If the fluid density and velocity are constant over the flow cross- sectional area, the mass flow rate is voulme specific called is where AV AV m      1    
  • 32. FacultyofMechanical Engineering, UiTM 32 MEC 451 – THERMODYNAMICS Principal of Conservation of Mass  The conservation of mass principle for a control volume can be expressed as in out CV m m m    For a steady state, steady flow process the conservation of mass principle becomes (kg/s) in out m m 
  • 33. FacultyofMechanical Engineering, UiTM 33 MEC 451 – THERMODYNAMICS  As the fluid upstream pushes mass across the control volume, work done on that unit of mass is flow flow flow A W FdL FdL PdV Pv m A W w Pv m            Flow Work & The Energy of a Flowing Fluid
  • 34. FacultyofMechanical Engineering, UiTM 34 MEC 451 – THERMODYNAMICS  The total energy carried by a unit of mass as it crosses the control surface is the sum of the internal energy + flow work + potential energy + kinetic energy         gz V h gz V P u energy 2 2 2 2   The first law for a control volume can be written as                          in in in in in out out out out out net net gz V h m gz V h m W Q 2 2 2 . 2 . . . Total Energy of a Flowing Fluid
  • 35. FacultyofMechanical Engineering, UiTM 35 MEC 451 – THERMODYNAMICS Total Energy of a Flowing Fluid  The steady state, steady flow conservation of mass and first law of thermodynamics can be expressed in the following forms ) ( 1000 ) ( 2000 1 2 2 1 2 2 1 2 . . . kW z z g V V h h m W Q net net                ) ( 1000 ) ( 2000 1 2 2 1 2 2 1 2 kJ z z g V V h h m W Q net net                ) / ( 1000 ) ( 2000 1 2 2 1 2 2 1 2 kg kJ z z g V V h h w q net net               
  • 36. FacultyofMechanical Engineering, UiTM 36 MEC 451 – THERMODYNAMICS Steady-flow Engineering Devices
  • 37. FacultyofMechanical Engineering, UiTM 37 MEC 451 – THERMODYNAMICS Nozzle & Diffuser  Nozzle - device that increases the velocity fluid at the expense of pressure.  Diffuser - device that increases pressure of a fluid by slowing it down.  Commonly utilized in jet engines, rockets, space-craft and even garden hoses.  Q = 0 (heat transfer from the fluid to surroundings very small  W = 0 and ΔPE = 0
  • 38. FacultyofMechanical Engineering, UiTM 38 MEC 451 – THERMODYNAMICS  Energy balance (nozzle & diffuser):                            out out out out out out out in in in in in in in gz V h m W Q gz V h m W Q 2 2 2 . . . 2 . . .                    2 2 2 . 2 . out out out in in in V h m V h m                    2 2 2 2 2 2 1 1 V h V h
  • 39. FacultyofMechanical Engineering, UiTM 39 MEC 451 – THERMODYNAMICS Example 3.6 Steam at 0.4 MPa, 300ºC, enters an adiabatic nozzle with a low velocity and leaves at 0.2 MPa with a quality of 90%. Find the exit velocity. Solution:  Simplified energy balance: 2 1 1 V h    2 2 2 1 1 1 2 2 2 2 2 2 2 1 3067.1 0.4 300 sup 2 0.2 2486.1 0.9 kJ kg o f fg kJ kg V h State h P MPa T C erheated State h h x h P MPa h x                               1 2 1 2 1 0.4 0.2 300 0. 1 2 9 0 o P MPa P MPa T C x State S te V ta      Exit velocity:   2 2000 3067.1 2486.1 1078 / V m s   
  • 40. FacultyofMechanical Engineering, UiTM 40 MEC 451 – THERMODYNAMICS Example 3.7 Air at 10°C and 80 kPa enters the diffuser of a jet engine steadily with a velocity of 200 m/s. The inlet area of the diffuser is 0.4 m2. The air leaves the diffuser with a velocity that is very small compared with the inlet velocity. Determine (a) the mass flow rate of the air and (b) the temperature of the air leaving the diffuser. 1 2 1 1 2 1 80 0 1 1 0 200 / 0. 2 4 o P kPa V T C V m s St A ate State m     Solution: 2 2 2 1 1 2 2 V V h h          0 2          Simplified energy balance:  From Ideal Gas Law: 3 1 1 1 1.015 m kg RT v P  
  • 41. FacultyofMechanical Engineering, UiTM 41 MEC 451 – THERMODYNAMICS  Mass flow rate    1 1 1 1 1 200 0.4 1.015 78.8 kg s m V A v           Enthalpy at state 1   1 1 1.005 283 284.42 p kJ kg h C T     From energy balance: 2 1 2 1 2 2 2 2000 200 284.42 2000 304.42 304.42 1.005 302.9 kJ kg p V h h h T C K        
  • 42. FacultyofMechanical Engineering, UiTM 42 MEC 451 – THERMODYNAMICS Turbine & Compressor  Turbine – a work producing device through the expansion of a fluid.  Compressor (as well as pump and fan) - device used to increase pressure of a fluid and involves work input.  Q = 0 (well insulated), ΔPE = 0, ΔKE = 0 (very small compare to Δenthalpy).
  • 43. FacultyofMechanical Engineering, UiTM 43 MEC 451 – THERMODYNAMICS  Energy balance: for turbine                            out out out out out out out in in in in in in in gz V h m W Q gz V h m W Q 2 2 2 . . . 2 . . .     out out out in in h m W h m . . .     2 1 . . h h m W out  
  • 44. FacultyofMechanical Engineering, UiTM 44 MEC 451 – THERMODYNAMICS  Energy balance: for compressor, pump and fan                            out out out out out out out in in in in in in in gz V h m W Q gz V h m W Q 2 2 2 . . . 2 . . .     out out in in in h m h m W . . .     1 2 . . h h m W in  
  • 45. FacultyofMechanical Engineering, UiTM 45 MEC 451 – THERMODYNAMICS Example 3.8 The power output of an adiabatic steam turbine is 5 MW. Compare the magnitudes of Δh, Δke, and Δpe. Then determine the work done per unit mass of the steam flowing through the turbine and calculate the mass flow rate of the steam. Data : Inlet (P = 2 MPa, T = 400ºC,v = 50 m/s, z = 10 m) Exit (P = 15 kPa, x = 90%, v = 180 m/s, z = 6m)
  • 46. FacultyofMechanical Engineering, UiTM 46 MEC 451 – THERMODYNAMICS Solution:   1 1 1 2 2 2 2 2 2 1 sup 2 3247.6 400 2 15 . 0.9 225.94 0.9 2373.1 2361.73 o kJ kg f fg kJ kg State erheated p MPa h T C State P kPa sat mixture x h h x h                 . in Q . in W  2 . 2 . . . 2 2 in in in in in out out out out out out out V m h gz V Q W m h gz                        From energy balance:   2 1 2 2 2 1 2 1 885.87 14.95 2000 0.04 1000 kJ kg kJ kg kJ kg h h h V V KE g z z PE                Solve the equation: 3248.4 (2372.3) 2361.01 -887.39
  • 47. FacultyofMechanical Engineering, UiTM 47 MEC 451 – THERMODYNAMICS  the work done per unit mass     2 2 1 2 1 2 1 2 2000 1000 885.87 14.95 0.04 870.96 out kJ kg g z z V V W h h                                The mass flow rate 5000 5.74 870.96 kg out s out W m W    887.39 872.48 872.48 5.73
  • 48. FacultyofMechanical Engineering, UiTM 48 MEC 451 – THERMODYNAMICS Example 3.9 Air at 100 kPa and 280 K is compressed steadily to 600 kPa and 400 K. The mass flow rate of the air is 0.02 kg/s, and a heat loss of 16 kJ/kg occurs during the process. Assuming the changes in kinetic and potential energies are negligible, determine the necessary power input to the compressor. Solution:  simplified energy balance:     2 1 2 1 in out out W m h h Q m h h mq       1 1 1 2 2 2 1 100 280.13 280 2 600 400.98 400 kJ kg kJ kg State air P kPa h T K State air P kPa h T K            
  • 49. FacultyofMechanical Engineering, UiTM 49 MEC 451 – THERMODYNAMICS  Thus   0.02 400.98 280.13 16 2.74 in W kW        
  • 50. FacultyofMechanical Engineering, UiTM 50 MEC 451 – THERMODYNAMICS Throttling Valve Flow-restricting devices that cause a significant pressure drop in the fluid. Some familiar examples are ordinary adjustable valves and capillary tubes.
  • 51. FacultyofMechanical Engineering, UiTM 51 MEC 451 – THERMODYNAMICS Steam enters a throttling valve at 8000 kPa and 300°C and leaves at a pressure of 1600 kPa. Determine the final temperature and specific volume of the steam. Example 3.10     1 1 1 2 2 1 2 2 2 2 2 1 sup 8000 2786.5 300 2 1600 int 1500 198.29 0.001154 0.131710 844.55 2791 1600 1750 205.72 0.001166 0.113440 878.16 2795.2 o kJ kg o f g f g f g f g State erheated P kPa h T C State P kPa make erpolation h h v v h h P kPa T C T v v h h           
  • 52. FacultyofMechanical Engineering, UiTM 52 MEC 451 – THERMODYNAMICS 2 201.3o sat T T C    At state 2, the region is sat. mixture  Getting the quality at state 2 2 2 2 2 2 2786.5 857.994 2792.68 857.994 0.997 f g f h h x h h         Specific volume at state 2   3 2 2 2 2 0.0011588 0.997 0.124402 0.0011588 0.1240 f fg m kg v v x v      
  • 53. FacultyofMechanical Engineering, UiTM 53 MEC 451 – THERMODYNAMICS The section where the mixing process takes place. An ordinary T-elbow or a Y-elbow in a shower, for example, serves as the mixing chamber for the cold- and hot-water streams. Mixing Chamber
  • 54. FacultyofMechanical Engineering, UiTM 54 MEC 451 – THERMODYNAMICS Mixing Chamber  Energy Balance:       1 1 2 2 3 3 1 1 3 1 2 3 3 1 1 2 3 3 2 3 2 1 3 1 2 m h m h m h m h m m h m h m h h m h h h h m m h h                 
  • 55. FacultyofMechanical Engineering, UiTM 55 MEC 451 – THERMODYNAMICS Devices where two moving fluid streams exchange heat without mixing. Heat exchangers typically involve no work interactions (w = 0) and negligible kinetic and potential energy changes for each fluid stream. Heat Exchanger
  • 56. FacultyofMechanical Engineering, UiTM 56 MEC 451 – THERMODYNAMICS Liquid sodium, flowing at 100 kg/s, enters a heat exchanger at 450°C and exits at 350°C. The specific heat of sodium is 1.25 kJ/kg.oC. Water enters at 5000 kPa and 20oC. Determine the minimum mass flux of the water so that the water does not completely vaporize. Neglect the pressure drop through the exchanger. Also, calculate the rate of heat transfer. Example 3.11 Solution:  simplified energy balance:         1 1 2 2 1 2 2 1 , 1 2 2 1 s s w w s s w w s s s w w w s p s s s w w w m h m h m h m h m h h m h h m C T T m h h          1 1 1 2 2 1: . 5000 88.61 20 2: 5000 2794.2 o kJ w kg kJ w kg State water comp liquid P kPa h T C State water P kPa h         Assume a sat. vapor state to obtain the max. allowable exiting enthalpy.
  • 57. FacultyofMechanical Engineering, UiTM 57 MEC 451 – THERMODYNAMICS  the minimum mass flux of the water so that the water does not completely vaporize        , 1 2 2 1 100 1.25 450 350 2794.2 88.61 4.62 s p s s s w w w kg s m C T T m h h         the rate of heat transfer     2 1 4.62 2794.2 88.61 12.5 w w w w Q m h h MW     
  • 58. FacultyofMechanical Engineering, UiTM 58 MEC 451 – THERMODYNAMICS Supplementary Problems 3 1. Air flows through the supersonic nozzle . The inlet conditions are 7 kPa and 420°C. The nozzle exit diameter is adjusted such that the exiting velocity is 700 m/s. Calculate ( a ) the exit temperature, ( b )the mass flux, and ( c ) the exit diameter. Assume an adiabatic quasiequilibrium flow. 2. Steam at 5 MPa and 400°C enters a nozzle steadily velocity of 80 m/s, and it leaves at 2 MPa and 300°C. The inlet area of the nozzle is 50 cm2, and heat is being lost at a rate of 120 kJ/s. Determine (a) the mass flow rate of the steam, (b) the exit velocity of the steam, and (c) the exit area nozzle. 3. Steam enters a turbine at 4000 kPa and 500oC and leaves as shown in Fig A below. For an inlet velocity of 200 m/s, calculate the turbine power output. ( a )Neglect any heat transfer and kinetic energy change ( b )Show that the kinetic energy change is negligible.
  • 59. FacultyofMechanical Engineering, UiTM 59 MEC 451 – THERMODYNAMICS Figure A 4. Consider an ordinary shower where hot water at 60°C is mixed with cold water at 10°C. If it is desired that a steady stream of warm water at 45°C be supplied, determine the ratio of the mass flow rates of the hot to cold water. Assume the heat losses from the mixing chamber to be negligible and the mixing to take place at a pressure of 150 kPa. 5. Refrigerant-134a is to be cooled by water in a condenser. The refrigerant enters the condenser with a mass flow rate of 6 kg/min at 1 MPa and 70ºC and leaves at 35°C. The cooling water enters at 300 kPa and 15°C and leaves at 25ºC. Neglecting any pressure drops, determine (a) the mass flow rate of the cooling water required and (b) the heat transfer rate from the refrigerant to water.