2
Worlée, a Family Business
For 160 years now, Worlée has supplied its cus­
tomers reliably with raw materials from Germany
and abroad. The company was founded in 1851
by Emil Heinrich Worlée in Hamburg for the
import and trade of natural resins sold as binders
to the lourishing paint and lacquer industry
during the industrial revolution.
Today 5th
generation descendants manage the
family business. The former trade house has
grown into a modern industrial and service group, operating inter­
nationally, reining and selling spices, dried vegetables, teas etc.
for the food industry as well as producing and distributing important
raw materials for the paint, lacquer and cosmetic industries.
Worlée­Chemie GmbH employs 250 persons in its plants in Lauenburg
and Lübeck/Northern Germany, producing a broad range of different
binders and additives for the paint and lacquer industries on the latest
equipment. The range comprises water­ and solvent­based acrylic and
alkyd resins, polyesters, polyester polyols, polyether polyols, epoxy
esters and numerous additives for a variety of different applications.
In addition, Worlée’s technicans develop tailor­made products for the
speciic requirements of the company’s customers.
Worlée’s scientists and application engineers establish formulations
for modern paints and lacquers, which comply with current and
expected future environmental and safety requirements. Some of
our resins already contain a large part of natural renewable raw
materials, thus contributing to the protection of our resources.
Worlée­Chemie GmbH takes its responsibilities towards its customers,
the society and the environment very seriously. Therefore its produc­
tion plants meet the highest environmental and safety standards.
The processes used are organized professionally and optimized
continuously, to avoid any loss of material and energy.
On several occasions, Worlée has been awarded for its sustainable
management of energy, emissions and resources, the latest award
having been the one as a so­called “Klimaschutz­Unternehmen”
(company protecting our climate). All units are certiied according
to ISO 9001:2008 and ISO 14001. Most of Worlée’s employees stay
with the company for many years, often decades; this fact secures
high competence and continuity.
“Our success is also based on the experience and the commitment of
our employees at home and abroad, most of whom have been trained
within the company.”
With its highly qualiied personnel, its modern production plants and
an internationally operating procurement and sales network, Worlée is
the guarantor for a reliable raw material supply.
Emil Heinrich Worlée

3
Table of Contents
Acrylic Resins solvent based, hydroxyl group, containing WorléeCryl A 4
Acrylic Resins solvent based, thermoplastic WorléeCryl L 4
Acrylic Resins water based emulsions, hydrosoles, solutions WorléeCryl 5
Alkyd Resins acrylated WorléeKyd AC 6
Alkyd Resins solvent based, short oil, airdrying WorléeKyd 6
Alkyd Resins solvent based, medium oil, airdrying WorléeKyd 7–8
Alkyd Resins solvent based, long oil, airdrying WorléeKyd 8–9
Alkyd Resins solvent based, long oil, urethane modiied WorléeKyd 10
Alkyd Resins solvent based, stoving systems, reactive and NC­combination WorléeKyd 11
Alkyd Resins
Acrylic Resins
solvent based, thixotropic WorléeThix 12–13
Alkyd Emulsions PU modiied, water based WorléeSol E 13
Alkyd Emulsions water based WorléeSol NW 13
Alkyd Resins water based, air and forced drying WorléeSol 14
Alkyd Resins water based, for stoving systems WorléeSol 14
Polyesters water based, oil free, saturated WorléePol 15
Polyesterpolyols solvent free, saturated WorléePol 15
Polyesters solvent based, saturated WorléePol 15
Epoxy Esters drying WorléeDur 16
Special Hardeners for epoxy resins WorléeDur H 16
Hard Resins phenol modiied WorléeFen 16
Maleic Resins WorléeSin 17
Adhesion Promoters Special­Primer 17
Additives for paints and lacquers WorléeAdd Resilow 18–20
Defoamers for water and solvent based paints, lacquers, special applications WorléeAdd 20–21
Additives for powder coatings WorléeAdd Resilow 21
Specialities for powder coatings 22
Sales Organisation 23

4
WorléeCryl
Acrylic Resins, solvent based, hydroxyl group containing
Type OH-content
on solids
[%]
Flash point
DIN EN 22719
[°C]
Viscosity 20 °C,,
del.form, Brookf.,
ISO 2555 [mPa·s]
Forms of
delivery
Main uses and principal characteristics
W’Cryl A 1135 3,5 appr. 23 3.000–4.000 60 % in xylene Acrylate copolymer for the manufacture of industrial coatings with very
good resistance against water and other agents.
W’Cryl A 1218 1,8 appr. 26 5.000–7.000 50 % in BAc
98/100
High reactivity and long pot life. For fast drying wood and furniture
lacquers. CAB compatible.
W’Cryl A 1220 2,0 appr. 26 1.000–2.000 60 % in BAc
98/100
acrylate copolymer for the manufacture of high quality plastic coatings.
W’Cryl A 1320 2,0 appr. 26 2.000–3.000 50 % in BAc
98/100
For high quality wood and furniture lacquers, good initial drying.
W’Cryl A 2116 1,6 appr. 47 2.000–2.500 60 % in arom.
HC 155–180
For fast drying industrial paint with good gloss. Also for decorative paints
– in combination with WorléeThix A 2125 – for effect inishes.
W’Cryl A 2130 3,0 appr. 25 3.500–7.000 60 % in X/BAc/
arom. HC
155–180
For two component industrial paints with good mechanical propertties
and high gloss with good outdoor durability.
W’Cryl A 2141 4,1 appr. 26 25.000–35.000 70 % in BAc
98/100
For high quality air and forced drying paints on metal, wood and plastics.
W’Cryl A 2210 1,0 appr. 47 17.000–22.000 60 % in arom.
HC 155–180
For very fast drying primers and illers with very good adhesion properties
on different substates. Also usable as a one component system.
W’Cryl A 2218 1,8 appr. 25 500–2.000 50 % in X/BAc
(9:1)
For air and forced drying 2 pack primers, illers & top coats with excellent
adhesion on steel, aluminium and zinc.
W’Cryl A 2230 W 3,0 50–55 max. 20.000 44 % in water/
solvent blend
Water emulsiied hydroxy­acrylate for the production of exterior resistant
isocyanate cross­linked two component top coats with outstanding drying
properties, ilm hardness and gloss.
W’Cryl A 2241 W 4,1 50–55 max. 25.000 45 % in water/
solvent blend
Water emulsiied hydroxyacrylate for the production of isocyanate cross­
linked exterior resistant two component top coats which exhibit long potlife,
high gloss and good adhesion properties.
W’Cryl A 2335 3,5 25 4.000–.6000 60 % in X/BAc/
Solvesso 100
(2:1:1)
For formulating high quality air and forced drying top and clear coats.
W’Cryl A 2445 4,5 appr. 25
appr. 49
3.000–5.000
8.000–12.000
60 % in X/BAc/
arom. HC
155–180
60 % in arom.
HC 155–180
For high quality industrial and machine paints; also for car repair inishes
with excellent UV­stability.
Type Flash point
DIN EN 22719
[°C]
Flow time 20 °C
DIN 53211-4 [s]
Forms of
delivery
Main uses and principal characteristics
W’Cryl L 241 appr. 60 80–120
(40 % in isop. HC
170–200)
60 % in
isop. HC
170–200
Neutral low odour acrylic resin, mainly for wall and ceiling paints, very good insu­
lating coat for nicotine, chimney and water spots, for chlorine free formulations,
without plasticizer.
W’Cryl L 2380 appr. 500 mPa·s
(del. form, 20 °C, ISO 2555)
50 % in
dearom. HC
160–200
Physically drying thermoplastic acrylic resin for different coating systems impro­
ving hardness and gloss.
W’Cryl L 2580 appr. 68 viscosity, 23 °C, del. form,
Brookield, ISO 2555, 3.000–
7.000 mPa·s
70 % in
isop. HC
170–200
Neutral, soft, low odour acrylic resin mainly used or wall and ceiling paints, low
VOC. Very good insulating coat for nicotine, chimney and water spots.
W’Cryl L 2822 appr. 23 viscosity, Rheom. 23 °C,
C60/2°, 50S­1
, DIN EN ISO
3219, 5.000–10.000 mPa·s
viscosity, 23 °C, del. form,
Brookield, ISO 2555, 8.000–
10.000 mPa·s
70 % in
dearom. HC
160–200
75 % in xylene
Self crosslinking thermoplastic acrylic copolymer to be used as resin of addition
in low VOC industrial paints to improve drying and ilm surface hardness.
WorléeCryl
Acrylic Resins, solvent based, thermoplastic

5
WorléeCryl
Acrylic Resins, water based emulsions, hydrosoles, solutions
Type Monomer Non volat.
content
DIN EN ISO
3251 [%]
pH value
DIN 53785
Density
DIN
51757
[g/cm3]
MFT
[°C]
viscosity
20 °C, del. form
Brookield, ISO
2555 [mPa·s]
Main uses and principal characteristics
W’Cryl 7107 methacrylic
copolymer
emulsion
40 7,2–8,0 1,07 > 95 max. 500 As mixing component universally suitable for improving ilm
hardness, sandability, blocking resistance and stackability.
W’Cryl 7120 styrene acrylic
emulsion
49 8,2–9,0 1,09 15 200–800 Corrosion inhibiting primers on different metals (e.g. iron,
aluminium), good weather resistance.
W’Cryl 7135 styrene acrylic
emulsion
42 7,5–8,5 1,04 39 max. 1.000 Topcoats on metal, wood, plastics (PS, ABS). Also for tem­
porary anti­corrosive primers on metal, can be combined
with water thinnable alkyd resins.
W’Cryl 7137 styrene acrylic
emulsion
42 7,5–8,5 1,04 28 max. 200 Allround emulsion for top coats on plastic, metal, wood
and for corrosion inhibiting primers with very good adhesi­
on on steel and low water absorption.
W’Cryl 7158 styrene acrylic
copolymer
emulsion
49 7,5–8,0 1,06 5 max. 500 Self­crosslinking styrene modiied acrylic emulsion for
primers with excellent results in corrosion protection tests.
W’Cryl 7189 methacrylic
copolymer
emulsion
49 7,0–8,0 1,08 16 max. 200 Flexible binder for wall paints, tiles and building adhesives.
Fast setting, high initial adhesion, highly lexible.
W’Cryl 7410 pure acrylic 45 8,0–9,0 1,06 39 max. 500 Self­crosslinking acrylic polymer for the formu lation of
aqueous furniture lacquers with good resistance against
household chemicals.
W’Cryl 7450 pure acrylic
emulsion
45 7,0–8,0 1,06 0 max. 500 Good blocking stability, in combination with PU­dispersion
wood, parquet lacquers and top coats for wood can be
formulated.
W’Cryl 7461 pure acrylic
emulsion
55 7,0–8,0 1,06 0 max. 500 Self­crosslinking pure acrylic emulsion with high solid
content for formulating block­resistant, high gloss emulsion
paints with very good levelling properties. Low VOC value
in pigmented top coats, solvent free formulations are pos­
sible for glazings and colourless systems.
W’Cryl 7463 pure acrylic
emulsion
55 7,0–8,0 1,06 13 max. 1000 Self­crosslinking pure acrylic emulsion for the formulation
of blocking resistant, high gloss brushable paints with a
low VOC­content.
W’Cryl 7520 acrylic
emulsion
50 8,5–9,0 1,05 14 1.600–2.400 For manufacturing dispersion paints for indoor and outdoor
application and coloured quartz sand plaster
W’Cryl 7712 W pure acrylic
solution, cationic
26 appr. 5,0 1,04 – 300–800 Filler and colourless sealants for wood. Excellent insulating
against bleeding, pigmented and transparent. Nicotine insu­
lating paints.
W’Cryl 7712 H cationic pure
acrylic solution
40 ± 1 4,0–6,0 appr. 1,03 – 5.000–8.000 Excellent suitable as binding agent for illers respectively
as colourless or pigmented sealing primer on wood with
a high content of soluble wood ingredients.
W’Cryl 8025 pure acrylic
solution
25 8,0–9,0 1,02 – 200–800 For production of roller coatings and primers on wood.

6
WorléeKyd
Alkyd Resins, solvent based, short oil, airdrying
Type Oil
[%]
Oil type Phth.
anhyd.
[%]
Color
DIN ISO 4630,
Gardner
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Flow time
20 °C
DIN 53211-4
[s]
Form of
delivery
Main uses and principal characte-
ristics
W’Kyd AC 2550 25 drying veg.
fatty acids
17 max. 5
(50 % in ws
135–175)
max. 5
(50 % in
dearom. HC
140–165)
max. 10 150–210
(50 % in ws
135–175)
200–260
(50 % in
dearom. HC
140–165)
60 % in ws
135–175
60 % in dearom.
HC 140–165
Acrylated alkyd resin for extremely fast
drying primers and top coats.
W’Kyd AC 2551 25 drying veg.
fatty acids
17 max. 5
(50 % in X)
max. 10 90–150
(50 % in X)
60 % in xylene Acrylated alkyd resin for extremely fast
drying primers and top coats.
W’Kyd AC 2943 29 drying veg.
fatty acids
19 max. 5
(50 % in X)
max. 5
(50 % in BAc)
max. 12 30–60
(50 % in X)
30–50
(50 % in BAc)
75 % in xylene
75 % in BAc
Acrylated low viscous alkyd resin for high
solid primers.
W’Kyd L 138 38 linseed and
tung oil
30 max. 10
(50 % in X)
max. 15 250–300
(50 % in X)
60 % in xylene Phenolic mod., for fast drying primers
and top coats, putties and illers.
W’Kyd LH 3702 38 linseed and
tung oil
25 max. 10
(40 % in
dearom. HC
160–200)
max. 20 90–130
(40 % in
dearom. HC
160–200)
50 % in dearom.
HC 160–200
Dearomatic air drying base and top coats.
W’Kyd MH 38 39 mixed fatty acids
and tung oil
38 max. 15
(50 % in X)
max. 25 140–170
(50 % in X)
60 % in xylene Primers and top coats, good elasticity
and resistance properties.
W’Kyd MH 42 42 drying veg.
fatty acids
24 max. 15
(50 % in ws
135–175)
max. 15
(50 % in dea­
rom. HC
140–165)
max. 20 120–150
(50 % in ws
135–175)
50–70
(40 % in dea­
rom. HC 140–
165)
60 % in ws
135–175
60 % in dearom.
HC 140–165
Primers and topcoats, „Larolex“ (BASF)
compatibility.
W’Kyd MH 439 39 mixed fatty acids 32 max. 10
(50 % in X)
max. 10
(50 % in ws
135–175/
Solv. PM)
max. 25 100–130
(50 % in X)
140–170
(50 % in ws
135–175/
Solv. PM)
60 % in xylene
60 % in ws
135–175/
Solv. PM
Phenolic modiied, fast drying primers and
top coats, „Larolex“ (BASF) compatibility.
W’Kyd S 3001 30 drying veg.
fatty acids
35 max. 10
(50 % in
X/Solv. PM
8:2)
max. 12 20–35
(50 % in
X/Solv. PM)
75 % in xylene
Solv. PM (8:2)
Low viscous, fast drying alkyd resin for
manufacturing low VOC industrial primers
and top coats.
W’Kyd SM 340 40 drying veg.
fatty acids
30 max. 10
(50 % in X)
max. 20 130–170
(50 % in X)
60 % in xylene Fast drying primers and top coats, good
elasticity, good resistance properties.
W’Kyd SM 400 34 drying veg.
fatty acids
30 max. 10
(50 % in X)
max. 20 90–110
(50 % in X)
60 % in xylene Fast drying primers and paints with excellent
durability.With amino resins reactive stoving
eTypels with good stability. „Larolex“ (BASF)
compatibility.
W’Kyd SM 426 26 drying veg.
fatty acids
40 max. 10
(50 % in X)
max. 15 90–110
(50 % in X)
60 % in xylene Very fast drying alkyd resin for air and
forced drying primers and top coats.
W’Kyd SM 433 33 drying veg.
fatty acids
38 max. 10
(50 % in X)
max. 15 60–80
(50 % in X)
60 % in xylene Fast drying primers and top coats, high
solids, low thermoplasticity, partial „Laro­
lex“ (BASF) compatibility.
W’Kyd TT 3502 35 drying veg.
fatty acids
24 max. 15
(60 % in X)
max. 20 60–70
(60 % in X)
80 % in xylene Low viscous, fast drying alkyd resin for
low VOC industrial primers.
W’Kyd V 298 38 drying veg.
fatty acids
25 max. 10
(40 % in ws
135–175)
max. 20 90–130
(40 % in ws
135–175)
55 % in ws
135–175
Fast drying primers, very good elasticity
and durability, dilutable with white spirit.

7
WorléeKyd
Alkyd Resins, solvent based, medium oil, airdrying
Type Oil
[%]
Oil type Phth.
anhyd.
[%]
Color
DIN ISO 4630,
Gardner
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Flow time 20 °C
DIN 53211-4
[s]
Forms of
delivery
Main uses and principal
characteristics
W’Kyd B 845 45 special
fatty acids
25 max. 10
(40 % in Ws
145–195)
max. 10
(del. form)
max. 15 80–100
(40 % in Ws
145–195)
5.500–8.000 mPa∙s
(Rheometer 20°C,
C35/1°, 100 s­1)
55 % in Ws
145–195
70 % in xyle­
ne
Fast drying radiator paints, automotive
and machinery reinishing enamels with
good gloss. Larolex (BASF) compatibility.
W’Kyd B 850 U 45 special
fatty acids
17 max. 10
(40 % in Ws
145–195)
max.15 80–120
(40 % in Ws
145–195)
50 % in Ws
145–195/X
Extremely fast drying, urethane modiied,
for primers and topcoats, good
recoatability.
W’Kyd B 4901 49 cotton oil 24 max. 10
(40 % in dearomat.
HC 160–200)
max.12 60–70
(40 % in dearomat.
HC 160–200)
50 % in dea­
romat. HC
160–200
Fast drying, for air and forced drying indus
trial, vehicle and machine paints as well as
dearomat. do­it yourself and radiator paints.
W’Kyd B 4901 nv 49 cotton oil 24 max. 10
(55 % in dearomat.
HC 160–200/
Methoxypropanol
3/1)
max.12 65–75
(55 % in dearomat.
HC 160–200/
Methoxypropanol
3/1)
75 % in dea­
romat. HC
160–200/
Methoxypro­
panol 3/1
Fast drying, for air and forced drying
industrial,vehicle and machine paints as
well as dearomat. do­it yourself and radiator
paints.
W’Kyd BS 830 45 special
fatty acids,
silicone
modiied
17 max. 10
(50 % in Ws
145–195)
max. 10
(50 % in isop. HC
170–200
max. 10
(50 % in dearomat.
HC 160–200)
max.15 55–70
(50 % in Ws
145–195)
170–220
(50 % in isop. HC
170–200)
120–150
(50 % in dearomat.
HC 160–200)
60 % in Ws
145–195
60 % in isop.
HC 170– 200
60 % in dea­
romat. HC
160–200
Silicone modiied alkyd resin for high quality
industrial and maintenance paints with very
good drying properties, high gloss retention
and corrosion resistance.
W’Kyd BS 5005 50 special
veg. fatty
acids
15 max. 5
(50 % in dearomat.
HC 160–200)
max.15 25–40
(50% in dearomat.
HC 160–200)
80 % in dea­
romat. HC
160–200
Low viscous, airdrying, silicone modiied
alkyd resin for industrial and house paints,
low VOC.
W’Kyd BSA 5015 ca.
49
special
veg. fatty
acids
max. 5
(60% in dearomat.
HC 160–200)
max.12 40–60 s 85 % in dea­
romat. HC
160–200
Low viscous, air drying, especially modiied
alkyd resin with good resistance properties
for decorative and house paints, low VOC.
W’Kyd BT 5001 50 special
veg. fatty
acids
24 max. 10
(50% in dearomat.
HC 160–200)
max.12 60–70
(50 % in dearomat.
HC 160–200)
65 % in dea­
romat. HC
160–200
Fast drying alkyd resin for low VOC house
paints and dearomatized machine­, indust­
rial and D.I.Y.­paints.
W’Kyd FC 555 55 special
fatty acids
16
15
max. 10
(40 % in isop. HC
170–200)
max.10 70–100
(40 % in isop. HC
170–200)
50 % in isop.
HC 170–200
Fast drying, low odour and dearomatized
radiator and d.i.y. paints with high gloss
and good yellowing resistance.
W’Kyd S 351 51 soya oil 23 max. 10
(40 % in Ws
180–210)
max. 10
(40 % in isop.
HC 170–200)
max. 10
(40 % in dearomat.
HC 180–220)
max.15 80–100
(40 % in Ws
180–210)
70–100
(40 % in isop. HC
170– 200,
DIN 6 cup)
25–35
(40 % in dearomat.
HC 180–220)
50 % in Ws
180–210
50 % in isop.
HC 170–200
60 % in dea­
romat. HC
180–220
White undercoatings, mat and semi gloss
enamels with good low properties.
W’Kyd S 351 nv nv 51 soya oil 23 max. 10
(del. form)
max.15 9.000–16.000
mPa∙s (Rheometer
20 °C, C35/1°,
100 s­1)
60 % in isop.
HC 170–200
Undercoatings, silkgloss and mat enamels
with good low properties.

8
WorléeKyd
Alkyd Resins, solvent based, medium oil, airdrying
WorléeKyd
Alkyd Resins, solvent based, long oil, airdrying
Type Oil
[%]
Oil type Phth.
anhyd.
[%]
Color
DIN ISO 4630,
Gardner
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Flow time 20 °C
DIN 53211-4
[s]
Forms of
delivery
Main uses and principal
characteristics
W’Kyd S 549 50 soya oil 27 max. 10
(40 % in Ws
145–195)
max. 10
(45 % in Ws
135–175)
max.15 50–65
(40 % in Ws
145–195)
100–130
(45 % in Ws
135–175)
55 % in Ws
145–195
55 % in Ws
135–175
Fast drying automotive and machinery
reinishing enamels.
W’Kyd SO 554 55 soya oil 15 max. 10
(40 % in dearomat.
HC 170–200)
max.10 70–100
(40 % in isop. HC
170–200)
55 % in isop.
HC 170–200
Fast drying, low odour, dearomatized
machinery ind. and d.i.y. paints.
W’Kyd V 162
W’Kyd V 162 nv
41 special
fatty acids
28 max. 10
(40 % in Ws
145–195)
max. 10
(50 % in Ws
135–175)
max. 20
max. 10
40–70
(40 % in Ws
145–195)
130–150
(50 % in Ws
135–175)
55 % in Ws
145–195/X
60 % in Ws
135–175
Extremely fast drying car reinishing,
machinery and industrial paints with high
gloss, good through drying.
W’Kyd V 543 50 special
fatty acids
24 max. 10
(40 % in Ws
145–195)
max. 15 50–70
(40 % in Ws
145–195)
80–120
(40 % in Ws
145–195)
55 % in Ws
145–195/X
55 % in Ws
145–195
Fast drying car reinishing, machinery
and industrial paints with high gloss,
good through­drying.
Type Oil
[%]
Oil type Phth.
anhyd.
[%]
Color
DIN ISO 4630,
Gardner
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Flow time
20 °C
DIN 53211-4
[s]
Forms of
delivery
Main uses and principal
characteristics
W’Kyd B 865
W’Kyd B 865 nv
65 Cotton/
Soya
22 max. 8
(50 % in Ws 45–195)
max. 8
(50 % in dearomat. HC
160–200)
max. 15 70–90
(50 % in Ws
145–195)
40–50
(50 % in dea­
romat. HC
160–200)
60 % in Ws
145–195
65 % in dea­
romat. HC
160–200
High quality house, decorative and d.i.y.
paints with good low, high gloss, good
outdoor resistance.
W’Kyd B 868 68 vegetable
fatty acids
21 max. 10
(50 % in dearomat. HC
160–200)
max. 15 20–40
(50 % in dea­
romat. HC
160–200)
70 % in dea­
romat. HC
160–200
High quality gloss paints, excellent brusha­
bility, gloss retention and good drying pro­
perties.
W’Kyd B 870 69 vegetable
fatty acids
21 max. 10
(60 % in Ws 145–195)
max. 10
(60 % in isop. HC
170–200)
max. 15 60–80
(60 % in Ws
145–195)
90–130
(60 % in isop.
HC 170–200)
75 % in Ws
145–195
75 % in isop.
HC 170–200
House paints with good brushability, high
ilm build, good low and excellent gloss
retention.

9
Type Oil
[%]
Oil type Phth.
anhyd.
[%]
Color
DIN ISO 4630,
Gardner
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Flow time 20 °C
DIN 53211-4
[s]
Forms of
delivery
Main uses and principal
characteristics
W’Kyd B 870 69 special
fatty acids
21 max. 10
(60 % in dearomat.
HC 160–200)
max. 10
(60 % in dearomat.
HC 180–220)
max. 15 60–80
(60 % in dearomat. HC
160–200)
100–125
(60 % in dearomat. HC
180–220)
75 % in dea­
romat. HC
160–200
75 % in dea­
romat. HC
180–220
House paints with good brushability,
high ilm build, good low and excellent
gloss retention.
W’Kyd B 6301 64 special
vegetable
fatty acids
19 max. 10
(70 % in dearomat.
HC 180–220)
max. 10
(70 % in dearomat.
HC 160–200)
max. 18 80–120
(70 % in dearomat. HC
180–220)
60–80
(70 % in dearomat. HC
160–200)
90 % in dea­
romat. HC
180–220
98–100 %
Low viscous, air drying long oil alkyd
resin for decorative and house paints,
low VOC.
W’Kyd E 55 63 special
fatty acids,
urethane
modiied
17 max. 10 (60 % in
Ws 145–195)
max. 10
(55 % in dearomat.
HC 160–200)
max. 10 200–300
(60 % in Ws 145–195)
50–80
(55 % in dearomat. HC
160–200)
70 % in Ws
145–195
70 % in dea­
romat. HC
160–200
In comb. with medium oil alkyds for
high quality car repair inishes and
industrial paints.
W’Kyd L 6800 68 linseed
oil
22 max. 10
(50 % in dearomat.
HC 160–200)
max. 10 Viscosity: 4.500–6.000
mPa·s (del. form, 23 °C,
DIN 53015)
81 % in dea­
romat. HC
160–200
Anticorrosive,d.i.y. and house paints
with high ilm build and good low
properties.
W’Kyd L 7904 79 linseed
oil
18 max. 10
(del. form)
max.15 Viscosity:
8.000–10.000 mPa·s
(20 °C, Haake Rotovisko,
C 35/1, D = 250 s­1)
ca. 100 % High solid clear lacquers, wood
glazings, and high solid primers.
W’Kyd L 8004 80 linseed
oil
max. 10
(del. form)
max.15 30–40 (70 % in dearo­
mat. HC 160–200)
98–100 % Very low viscous alkyd resin for wood
impregnation and wood glazings.
W’Kyd P 151 64 special
fatty
acids
22 max. 10
(80 % in Ws
145–195)
max.10 130–190
(80 % in Ws 145–195)
ca. 100 % Very low viscous, for high conc. pig­
ment preparations. Very good compati­
bility properties.
W’Kyd S 6400 hv 63 soya oil 26 max. 10
(50 % in dearomat.
HC 160–200)
(50 % in dearomat.
HC 180–220)
max.12 120–150
(50 % in dearomat. HC
160– 200)
(50 % in dearomat. HC
180–220)
60 % in dea­
romat. HC
160–200
60 % in dea­
romat. HC
180–220
Consumer, decorative, d.i.y. and anti­
corrosive paints.
W’Kyd S 7304 73 soya oil 20 max. 8
(del. form)
max.11 Viscosity:
47.000–55.000 mPa·s
(20 °C, Haake Rotovisko,
C 35/1, D = 50 s­1)
ca. 100 % Low viscous, air drying long oil alkyd
resin for decorative and house paints,
low VOC.
W’Kyd SB 6401 64 special
fatty acids
19 max. 10
(70 % in dearomat.
HC 180–220)
max. 10
(70 % in dearomat.
HC 160–200)
max. 18 80–120
(70 % in dearomat.HC
180–220)
60–80
(70 % in dearomat.HC
160–200)
90 % in dea­
romat.HC
180–220
98–100 %
Low viscous, air drying, long oil alkyd
resin for decorative and house paints,
low VOC.
W’Kyd SC 965 65 special
vegetable
fatty acids
22 max. 10
(50 % in dearomat.
HC 180–220)
max.15 35–50
(50 % in dearomat. HC
180–220)
70 % in dea­
romat. HC
180–220
High quality house paints, very good
brushability, low and levelling, high
gloss.
W’Kyd SD 7003 70 special
vegetable
fatty acids
max. 10
(60 % in dearomat.
HC 160–200)
max.15 Viscosity:
4.000–12.000 mPa·s
(20 °C, Rheometer,
C 35/1°, 250 s­1)
85 % in dea­
romat. HC
160–200
Low viscous, air drying, long oil alkyd
resin for decorative and house paints,
low VOC.
W’Kyd SD 8300 ca.
83
special
fatty acids
max. 10 max.15 Viscosity, Rheometer,
20 °C, C35/1°, 100 S­1:
3.000–5.000 mPa·s
100 % Low viscous, air drying, long oil alkyd
resin for decorative and house paints,
low VOC. Especially suitable as combi­
nation partner for other alkyd resins.
W’Kyd T 768 68 tall oil
fatty acid
21 max. 10
(60 % in dearomat.
HC 180–220)
max.15 100–150
(60 % in dearomat. HC
180–220)
75 % in dea­
romat. HC
180–220
Long oil alkyd resin for house paints
and anticorrosive coatings, primers
and top coats.
W’Kyd T 7800 78 special
vegetable
fatty acids
max. 10
(70 % in dearomat.
HC 160–200)
max.15 35–55
(70 % in dearomat. HC
160–200)
ca. 100 % Low viscous, air drying, long oil alkyd
resin for house paints, glazings, d.i.y.
and anticorrosive paints

10
WorléeKyd
Alkyd Resins, long oil, urethane modiied
Type Oil
[%]
Oil type Phth.
anhyd.
[%]
Color
DIN ISO 4630,
Gardner
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Flow time 20 °C
DIN 53211-4
[s]
Forms of
delivery
Main uses and principal
characteristics
W’Kyd B 865 U 62 vegetable
fatty acids
16 max. 10
(50 % in Ws 145–195)
max. 10
(50 % in isop. HC
170–200)
max. 10
(50 % in dearomat. HC
180–220)
max. 10
(50 % in dearomat. HC
160–200)
max. 10 70–100
(50 % in Ws
145–195)
80–100
(50 % in isop. HC
170–200)
80–100
(50 % in dearomat.
HC 180–220)
70–90
(50 % in dearomat.
HC 160–200)
55 % in Ws
145–195
55 % in isop.
HC 170–200
55 % in dea­
romat. HC
180–220
55 % in dea­
romat. HC
160–200
Urethane modiied, for wood varnishes,
loor coatings and industrial primers
and top coats.
W’Kyd B 865 U nv 62 vegetable
fatty acids
16 max. 10
(50 % in dearomat. HC
180–220)
max. 10 45–60
(50 % in dearomat.
HC 180–220)
60 % in dea­
romat. HC
180–220
Urethane modiied, for wood varnishes,
loor coatings and industrial primers
and top coats.
W’Kyd S 5703 57 soya oil
fatty acid
21 max. 5
(50 % in Ws 145–195)
max. 8
(50 % in dearomat. HC
160–200)
max. 10 Viscosity:
5.000–7.000 mPa·s
(del. form, 20 °C,
DIN
53015)
40–55
(45 % in dearomat.
HC 160–200)
55 % in Ws
145–195
55 % in dea­
romat. HC
160–200
Aliphatic urethane modiied alkyd
resin. Use as B 865 U with better
yellowing resistance.
W’Kyd S 6003 60 soya oil
fatty acid
19
16
max. 10
(40 % in dearomat. HC
160–200)
max. 10 (del. form)
max. 5 23–33
(40 % in dearomat.
HC 160–200)
2.500–3.500 mPa·s
(del. form, 20 °C,
DIN 53015)
51 % in dea­
romat. HC
160–200
50 % in isop.
HC 150–180
Use as B 865 U with faster drying and
harder ilm properties.
W’Kyd S 6003 hv 59 soya oil
fatty acid
18 max. 10
(40 % in dearomat. HC
160–200)
max. 5 30–40
(40 % in dearomat.
HC 160–200)
50 % in dea­
romat. HC
160–200
Use as S 6003 with even faster drying.
W’Kyd SD 6403 64 special
fatty acids
12 max. 6
(45 % in dearomat. HC
160–200)
max. 10 55–80
(45 % in dearomat.
HC 160–200)
55 % in dea­
romat. HC
160–200
Special urethane modiied alkyd resin
with good adhesion properties e.g. for
renovation coatings on UV parquet
sealers.
W’Kyd SD 6803 68 special
vegetable
fatty acids
max. 10
(60 % in dearomat. HC
160–200)
max. 15 Viscosity, Rheometer,
20 °C, C35/1°, 250
s–1:
7.000–10.000
mPa·s
75 % in dea­
romat. HC
160–200
Low viscous, urethane alkyd resin for
decorative and house paints, low VOC.
Especially suitable as combination
partner to improve drying, through
drying and hardness.
W’Kyd V 5241 U 81 linseed
oil
max. 10
(del. form)
max. 3 Viscosity:
10.000–15.000
mPa·s (del. form, 20
°C,
DIN 53015)
ca. 100 % Low viscous, oil modiied polyurethane
for high solid environmentally friendly
coating systems.

11
WorléeKyd
Alkyd Resins, solvent based, stoving/reactive/NC­combination
Type Oil
[%]
Oil type Phth.
anhyd.
[%]
Color
DIN ISO 4630,
Gardner
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Flow time 20 °C
DIN 53211-4
[s]
Forms of
delivery
Main uses and principal charac-
teristics
W’Kyd C 628 28 saturated
fatty acids
47 max. 10
(50 % in X)
max. 15 40–60
(50 % in X)
70 % in xylene High quality non yellowing stoving ena­
mels, NC­ and PU­coatings, colourless
and pigmented. OH­cont. (on solids)
2,0–2,4 %.
W’Kyd C 632 M 32 specially
modiied
fatty acids
37 max. 10
(50 % in BAc)
max.18 40–60
(50 % in BAc)
65 % in
Butylacetat
NC­lacquers with properties as acid
curing systems but without formalde­
hyde. Aromatic free. Hydroxyl content
(on solids) 2,7–3,3 %.
W’Kyd C 640 38 saturated
fatty acids
37 max. 10
(50 % in X)
max.15 40–60
(50 % in X)
60 % in xylene NC­lacquers with fast solvent release,
good yellowing resistance and recoata­
bility for paper and wood.
W’Kyd C 641 42 saturated
fatty acids
32 max. 10
(50 % in X)
max.15 60–80
(50 % in BAc)
80 % in BAc High quality NC­lacquers and one
component acid curing inishes with
high ilm build and fast solvent release,
forwood, foil and paper.
W’Kyd C 743 hs 12 synthet.
Fettsäuren
40 max. 10
(60 % in aromat. HC
155–180)
max.20 40–60
(60 % in aromat. HC
155–180)
80 % in aro­
mat. HC
155–180
High solids one component stoving
paints with high reactivity and very
good mechanical properties. OH­cont.
(on solids) 3,0–3,6%.
W’Kyd CD 32 32 special
fatty acids
48 max. 8
(45 % in xylene)
25–40 80–130
(45 % in xylene)
60 % in xylene In combination with suitable amino
resins for very reactive primers and
top coats with good storage stability.
Crosslinking with isocyanate is also
possible. OH content (solids) 2.6– 3.0.
W’Kyd M 932 32 vegetable
fatty acids
38 max. 10
(40 % in X)
max.18 40–60
(40 % in X)
60 % in xylene Stoving primers and topcoats with high
reactivity and good mechanical proper­
ties. Excellent viscosity stability. Sto­
ving cond. 100–140 °C.
W’Kyd RM 232 32 conjug. and
saturated
fatty acids
37 max. 10
(50 % in X)
max.15 100–120
(50 % in X)
60 % in xylene Stoving primers and topcoats with me­
dium reactivity and good mechanical
properties. Stoving conditions: 10 min.
160 °C or 30 min. 130 °C.
W’Kyd SH 380 38 special
fatty acids
34 max. 10
(60 % in BAc)
max.15 90–110
(60 % in BAc)
70 % in BAc
98/100
Acid catalysed inishes, fast curing
with good elasticity and resistance,
suficient potlife. NC­compatible, isocy­
anatecurable.
W’Kyd SM 400 34 drying
vegetable
fatty acids
30 max. 10
(50 % in X)
max.20 90–110
(50 % in X)
60 % in xylene In combination with amino resins for
high reactive stoving primers and top
coats.
W’Kyd SM 426 26 drying
vegetable
fatty acids
40 max. 10
(50 % in X)
max.15 90–110
(50 % in X)
60 % in xylene In combination with amino resins for
high reactive stoving primers and top
coats.
W’Kyd T 735 36 tall oil 35 max. 10
(50 % in X)
max.15 60–70
(50 % in X)
60 % in xylene Stoving primers and topcoats with
medium reactivity and good mechani­
cal properties. Curing conditions:
10 min./160 °C or 30 min./130 °C.

12
WorléeThix
Alkyd Resins, Acrylic Resins, solvent based, thixotropic
Type Oil
[%]
Oil type Phth.
anhyd.
[%]
Color
DIN ISO 4630,
Gardner
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Viscosity, 20 °C
bei Dmax=391/s
DIN 53018,
part 1 [mPa·s]
Forms of
delivery
Main uses and principal characteristics
W’Thix A 1420 2,0 %
OH content
ca. 1 (del. form) max. 12 3.500–5.000 50 % in
Butyl acetate
Thixotropic, hydroxyfunctional pure acrylate
for 2 component inishing lacquers.
W’Thix A 2125 2,5 %
OH content
max. 1 (del. form) 1.000–2.000 50 % in xylene Thixotropic styrene acrylic for thick layer
coatings and textured inishes.
W’Thix A 2242 W 4,2 %
OH content
max. 1 (del. form) 2.500–4.000 58 % in Wa­
ter/BAc/EEP
Thixotropic water thinnable hydroxy acrylate
for formulating high quality 2 component
structure paints. As combination partner
in aqueous 2 component top coats for
improving antisagging properties.
W’Thix A 2313 1,3 %
OH content
ca. 1 (del. form) 4.000–5.000 60 % in aro­
mat. HC
155–180
Thixotropic acrylic resin which can be
crosslinked with isocyanates for air and
forced drying industrial paints.
W’Thix D 46 40 max. 10 (del. form) max. 4 2.000–3.500 50 % in xylene Thixotropic epoxy ester,air­ and oven drying,
for primers, industrial­ and top coats, zinc
dust coatings. Thixotropy is not fully degra­
ded by temperature and polar substances.
W’Thix L 7904 79 linseed oil 18 max. 10 (del. form) max. 15 12.000–22.000
(C35/1, 200/s)
94 % in xylene High solid clear lacquers,wood glazings,
and high solid primers.
W’Thix L 8050 80 linseed oil
fatty acid
max. 10 (del. form) max. 15 thixotropic
soft gel
100 % Thixotropic, long oil alkyd resin, mostly used
for wood glazings. Useable as sole binder
as well.
W’Thix MH 439 39 special
fatty acids
32 max. 10 (del. form) max. 25 4.000–6.000 60 % in xylene Thixotropic short oil alkyd for fast drying
primers, topcoats and textured inishes.
Thixotropy is not fully degraded by tempera­
ture and polar substances.
W’Thix S 2655 26 special
vegetable
fatty acids
40 max. 6 (del. form) max. 15 11.000–15.000 60 % in xylene Thixotropic fast drying short oil alkyd for
primers, top and textured inishes, thick
layer­ and stoving systems. Thixotropy is
not fully degraded by temperature and
polar substances.
W’Thix S 6357 64 soya oil 24 max. 6 (del. form) max. 15 500–1.000
800–12.000
40 % in Ws
180–210
40 % in dea­
romat. HC
180–220
Thixotropic long oil alkyd resin. Combination
resin for house paints, wood glazings/
thicklayer. Thixotropy is not fully degraded
by temperature and polar substances.
W’Thix S 6358 64 soya oil 24 max. 6 (del. form) max. 15 thixotropic
soft gel
50 % in dea­
romat. HC
180–220
Pumpable thixotropic long oil alkyd combina­
tion resin for building paints, wood glazings,
thick layer. Thixotropy is not totally degrada­
ble by temperature and polar solvents.
W’Thix S 6455 64 soya oil
fatty acid
25 max. 6 (del. form) max. 15 thixotropic
strong gel
50 % in Ws
145–195
Strong thixotropic long oil alkyd for thick
layer coatings, wood glazings and clear
coatings. Temperature stable and resistant
against polar solvents.
W’Thix SD 6051 60 special
fatty acids
23 max. 10 (del. form) max. 15 2.500–4.000
3.000–4.500
55 % in dea­
romat. HC
160–200
55 % in dea­
romat. HC
180–220
As V 747, but with improved resistance
against polar substances.
W’Thix 670 hs 61 special
mixed fatty
acids
21 max. 10 (del. form) max. 15 thixotropic gel 70 % in dea­
romat. HC
160–200
70 % in dea­
romat. HC
180–220
Thixotropic long oil alkyd for primers,
illers, gloss and silk gloss coatings, low
VOC.

13
Type Oil
[%]
Oil type Phth.
anhyd.
[%]
Color
DIN ISO 4630,
Gardner
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Viscosity, 20 °C
bei Dmax=391/s
DIN 53018, Teil 1
[mPa·s]
Forms of
delivery
Main uses and principal characte-
ristics
W’Thix V 727 63 special
mixed fatty
acid
23 max. 10 (del.
form)
max. 15 3.000–4.000
(52 % in Ws
180–210)
4.000–6.000
(52 % in isop. HC
170–200)
4.200–4.800
(52 % in dearomat.
HC 180–220)
52 % inWs
180–210
52 % in isop.
HC 170–200
52 % in dea­
romat. HC
180–220
Thixotropic long oil alkyd for semi gloss
house paints, primers, wood stains and
anticorrosive paints.
W’Thix V 747 64 special
fatty acids
23 max. 7 (del.
form)
max. 15 5.000–7.000
(52 % in isop. HC
170–200)
5.000–7.000
(52 % in dearomat.
HC 180–220)
52 % in iso.
HC 170–200
52 % in dea­
romat. HC
180–220
Thixotropic long oil alkyd for primers,
mat wall and silk gloss paints and thixo­
tropic glossy decorative and protective
house paints.
W’Thix V 800 62 special
mixed fatty
acid
18 max. 10 (del.
form)
max. 6 (del.
form)
max. 10 1.000–2.000
250–450
50 % in dea­
romat. HC
160–200
40 % in isop.
HC 170–200
Thixotropic, urethane modiied long oil
alkyd for thick layer coatings, wood gla­
zings and lacquers. Temperature stable
and resistant against polar solvents.
Type Oil
[%]
Acid value
DIN EN
ISO 3682
[mgKOH/g]
pH value
DIN 53785
Viscosity 20 °C, del.
form Brookield,
ISO 2555 [mPa·s]
Forms of deli-
very
Main uses and principal characteristics
W’Sol E 150 W 44 max. 30 7,0–8,0 50–1.500 40 % in water Medium oil alkyd emulsion for high gloss decorative, DIY and indust­
rial paints. Most versatile type.
W’Sol E 280 W 28 20–30 6,9–7,2 max. 10.000 38 % in water
co­solvent free
Short oil coconut modiied alkyd emulsion for non­yellowing paint
systems.
W’Sol E 330 W 33 15–20 7,5–8,5 max. 10.000 42 % in water Short oil alkyd emulsion for (drier­free based) anticorrosive primers
and top coats.
W’Sol E 530 W 53 max. 38 7,0–8,5 max. 10.000 30 % in water Medium oil alkyd emulsion for fast drying wood paints and lacquers.
W’Sol E 927 W 28 max. 30 6,8–7,5 max. 10.000 40 % in water Short oil alkyd emulsion for fast curing wood coatings of all types
(also drier­free).
W’Sol SE 420 W 42 max. 30 7,0–8,5 max. 5.000 40 % in water Medium oil silicone modiied alkyd emulsion for high gloss paint
systems (also decorative) with excellent outdoor resistance.
Type Oil
[%]
Density
DIN 51757
[g/cm3]
Viscosity 20
°C, del. form
Brookield, ISO
2555 [mPa·s]
Forms of deli-
very
Main uses and principal characteristics
W’Sol NW 410 40 1,050 max. 3.000 46 % in water Solvent free medium oil special modiied alkyd emulsion for water thinnable decorative
and d.i.y. paints with good brushability, low and illing properties. For high gloss top
coats and wood protection stains.
W’Sol NW 474 74 1,013 max. 1.500 60 % in water Amine and co­solvent free alkyd emulsion for wood im preg nations and wood protec­
ting paints. Also suitable as a co­binder to improve open time and illing properties of
decorative paints.
WorléeSol E
PU modiied Alkyd Emulsions, water thinnable
WorléeSol NW
Alkyd Emulsions, water soluble

14
WorléeSol
Alkyd Resins, water thinnable, airdrying and low bake
Type Oil
[%]
Color
DIN ISO 4630,
Gardner
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Density
DIN 51757
[g/cm3]
Flow time 20 °C
DIN 53211-4
[s]
Forms of delivery Main uses and principal characteristics
W’Sol 07 A 37 max. 10 35–45
(50 % in BG)
1,03 80–140
(50 % in BG)
75 % in BG/sec.
Butanol 1:1
Air drying and low bake industrial primers and top­
coats. Low viscous, very fast dust free drying, early
water resistance.
W’Sol 30 max. 15 max. 20
(pH 4–5)
(50 % in
water)
1,02 50–100
(85 % in BG)
100 % Water soluble modiied linseed oil type. Readily
reducible with water, for printing inks, as additive
for latex paints, tinting and artist colours and pig­
ment pastes.
W’Sol 31 A
31 C
90 max. 10 (del.
form)
85–105
(pH 7,5–8,5)
0,99
1,00
120–200 (del. form)
Dowanol
45 % in water/
BG 80:20
45 % in water/
PnB 8:2
Water dispersible linseed oil polymer. Readily redu­
cible with water for in­ and outdoor stains and
wood preservatives. Extremely good penetration
and outdoor resistance.
W’Sol 37 90 max. 15 55–80 0,998 230 59 % in water/BG Modiied linseed oil polymer for wood protection
systems. Excellent penetration and weather resis­
tance on different woods and long term elasticity.
W’Sol 61 A
61 E
61 F
61 P
30 max. 10
(50 % in BG)
max. 10
(50 % in BG)
max. 10
(50 % in PnB)
max. 10 (del.
form)
35–45
35–45
40–50
35–45
1,06
1,07
1,05
1,06
70–90
(50 % in BG)
50–70
(50 % in BG)
70–90
(50 % in PnB)
6.000–20.000
m∙Pas (del. form
Brookield)
75 % in BG/sec.
Butanol 1:1
75 % in Ethoxypro­
panol
70 % in Dowanol
PnB
60 % in water/
BG/sec. Butanol
Air drying and low bake industrial primers and top
coats, very fast drying, excellent corrosion resis­
tance.
61 version fully neutralized with ammonia.
W’Sol 64 E 30 max. 10
(50 % in BG)
35–45 1,06 50–70
(50 % in BG)
75 % in Ethoxypro­
panol
For air drying and low bake industrial primers and
top coats, very fast drying, good corrosion resis­
tance.
W’Sol 65 A
65 E
30 max. 10
(45 % in BG)
max. 10
(45 % in BG)
30–40
30–40
1,05
1,05
50–70
(45 % in BG)
30–60
(45 % in BG)
70 % in Lsm­
Gemisch: BG/sec.
Butanol/Dowanol
PnB
70 % in
Ethoxipropanol
Air drying and low bake industrial primers and top­
coats, very fast drying, early water resistance,
suitable for agricultural machinery paints.
W’Sol 68 A 32 max. 10
(50 % in BG)
35–45 1,07 50–100
(50 % in BG)
75 % in BG Silicone modiied alkyd resin for air drying and
stoving systems with excellent weather, heat and
humidity resistance.
WorléeSol
Alkyd Resins, water thinnable, for stoving systems
Type Oil
[%]
Color
DIN ISO 4630,
Gardner
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Density
DIN 51757
[g/cm3]
Flow time
20 °C
DIN 53211-4
[s]
Forms of delivery Main uses and principal characteristics
W’Sol 84 C 30 max. 10 (del.
form)
6,7–8,5 1,06 4.000–20.000 44 % in water/BG
(1,0 %) (DMEA
neutr.)
For waterborne stoving systems, high gloss, good
mechanical properties, total cosolvent content
< 1 %.
W’Sol 85 A 30 max. 10 (del.
form)
6,7–8,5 1,06 6.000–20.000 43 % in water/BG
(5,5 %) (DMEA neutr.)
As WorléeSol 84, but more reactive.

15
Type Acid value
DIN EN
ISO 3682
[mgKOH/g]
Color DIN
ISO 4630,
Gardner
OH con-
tent auf
Festharz
[%]
Density
DIN
51757
[g/cm3]
Viscosity
20 °C, del. form
Forms of
delivery
Main uses and principal characteristics
W’Pol 191 45–60 max. 10
(50 % in BG)
approx.
4,3
1,10 45–70 s
(50 % in BG, DIN
53211­4/ 20 °C
80 % in BG Branched saturated polyester resin for waterborne
industrial stoving systems.
W’Pol 194 clear to
slightly
opaque
1,075 < 20.000* 40 % in water
+ BG (2,1%)
Branched saturated polyester resin for waterborne
stoving primers, illers and top coats with low voc.
pH =7,5­8,5, very reactive.
W’Pol 808 max. 25 max. 3 (del.
form)
approx.
7,0
1,20 15.000–25.000**
( 25 °C)
100 % Low viscous, with high reactivity. For amine free water
based stoving paints on metal, aluminium foil, paper and
plastics. Also suitable for printing inks.
W’Pol V 450 max. 15 max. 3 (del.
form)
approx.
8,5
1,18 500–700**
(25 °C)
90 % in water Similar to WorléePol 808 but higher reactivity, better sta­
bility, higher water tolerance and lower viscosity. Also sui­
table for printing inks.
Type Viscosity
23 °C, del.
form
DIN 53015
[mPa·s]
OH value
DIN EN ISO
4629
[mgKOH/g]
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Water
content DIN
51777, Teil 1
Karl Fischer
[%]
Main uses and principal characteristics
W’Pol 165 3.000–4.000 150–170 max. 2 max. 0,2 WorléePol 165 is a low viscous and solvent free branched polyol with ester and ether
groups and is mainly used for the formulation of solvent free coatings, sealings and
adhesives in combination with modiied polyisocyanates.
W’Pol 230 2.500–3.500 220–240 max. 2 max. 0,2 WorléePol 230 is a low viscous and solvent free branched polyol with ester and ether
groups and is mainly used for the formulation of solvent free coatings, sealings and ad­
hesives in combination with modiied polyisocyanates
W’Pol 1181/03 2.000–3.000
(25 °C)
310–350 max. 2 max. 0,1 Saturated low viscous polyester resin, due to its wide compatibility suitable for various
systems, e.g. as modifying component for solvent and water based isocyanate and ami­
no resin crosslinking coatings to improve lexibility, low, chemical and mechanical resis­
tance and to increase solids content. Corresponds to FDA § 175.300.
W’Pol 1181/09 1.500–3.000
(25 °C)
310–350 max. 2 max. 0,1 Saturated low viscous polyester resin, due to its wide compatibility suitable for various
systems, e.g. as modifying component for solvent and water based isocyanate and ami­
no resin crosslinking coatings to improve lexibility, low, chemical and mechanical resis­
tance and to increase solids content. Excellent weather resistance.
WorléePol
Polyester, water thinnable, oil free, saturated
WorléePol
Polyester/ether­polyols, solvent free, saturated
*Brookield, ISO 2555 **DIN 53015 [mPa·s]
Type OH content
auf Fest-
harz [%]
Flow time
20 °C
DIN 3211-4
[s]
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Color DIN
ISO 4630,
Gardner
Forms of
delivery
Main uses and principal characteristics
W’Pol 6631 ca. 8,0 20.000–30.000
mPa·s (Lff, Brook­
ield, ISO 2555)
max. 3 max. 3 67 % in Methoxy­
propylacetate
Saturated type for air drying 2 pack PU coatings.
W’Pol 6741 ca. 4,1 10.000–20.000
mPa·s (Lff, Brook­
ield, ISO 2555)
max. 2 80 % in Bac Saturated, hydroxy functional polyester resin for the manufacture
of solvent based „ultra high solids“ 2 component PUR systems.
W’Pol 6756 5,6 20.000–50.000
mPa·s (Lff, Brook­
ield, ISO 2555)
max. 2 78 % in Bac Saturated, hydroxy functional polyester resin for the manufacture
of solvent based „ultra high solids“ 2 component PUR systems for
industrial and car repair coatings with good mechanical properties
and excellent chemical and weather resistance.
WorléePol
Polyester, water thinnable, oil free, saturated

16
WorléeDur
Epoxy Esters, drying
Type Oil
[%]
Oil type EP-
resin
[%]
Color
DIN ISO 4630,
Gardner
Acid value
DIN EN
ISO 3682
[mgKOH/g]
Flow time 20 °C
DIN 53211-4
[s]
Forms of
delivery
Main uses and principal characteristics
W’Dur D 46 40 conj. fatty
acids
60 max. 10
(50 % in X)
max. 4 200–250
(50 % in X)
60 % in xylene High quality zinc rich and anti corrosive paints,
airdrying and stoving primers and top coats,
fast drying and excellent water resistance.
W’Dur MF 45 40 tall oil/
tung oil
60 max. 20
(50 % in X)
max. 6 200–250
(50 % in X)
60 % in xylene Zinc rich and anti corrosive paints with excel­
lent water resistant and rust preventing, good
brushability.
W’Dur D 6311 63 special
modiied
max. 10 (del.
form)
max. 2 3.000–4.000
mPa·s (del. form,
20°C, DIN 53015)
3.500–5.000
60 % in dea­
romat. HC
140–165
60 % in
Teswsenzin
145–195
60 % in dea­
romat. HC
160–200
Universal adhesion and anti corrosion primer
and one coat paints. Very good adhesion even
on dificult substrates.
Type H equi-
valent
Viscosity 20 °C,
del. form DIN
53015
[mPa·s]
Amine
value
DIN 53176
[mgKOH/g]
Color
DIN ISO
4630,
Gardner
Medium
potlife
Main uses and principal characteristics
W’Dur H 60 90 50–100 400 ± 50 max. 2 (del.
form)
ca. 25 Min. Modiied polycondensated polyamine system for sellevelling loorings,
very good levelling and deairating properties, tough and resilent.
W’Dur H 90 90 175–325 375 ± 50 max. 4 (del.
form)
ca. 40 Min. Modiied cycloaliphatic polyamine adduct for self­levelling loorings,
good levelling properties, low carbamation.
W’Dur H 100 50 300–600 700 ± 75 max. 2 (del.
form)
ca. 50 Min. Polycondensated polyamine free of benzylic alcohol. Special hardener
system to modify standard hardeners.
W’Dur H 380 M 380 8.000–12.000
(Brookield, ISO 2555)
190 ± 30 max. 2 (del.
form)
ca. 6 Std. Aliphatic polyamine adduct 55% in xylene/isobutanol for solvent based
epoxy primers and top coats.
WorléeDur
Special Hardeners for epoxy resins
Type Melting point
Capillary
method[°C]
Acid value
DIN EN ISO
3682
[mgKOH/g]
Flow time
20 °C
DIN 53211-4
[s]
Color
DIN ISO 4630,
Gardner
M.O.T. [%] Main uses and principal characteristics
W’Fen F 105 90–110 15–25 20–30
(50 % in Ws
145–195)
max. 10
(50 % in Ws
145–195)
300 General purpose type for alkyd based paints and primers.
Low viscous resin giving excellent gloss and rub resis­
tance on cold set inks.
W’Fen F 120 110–130 10–20 80–120
(50 % in Ws
145–195)
max. 10
(50 % in Ws
145–195)
225 General purpose type for alkyd based paints and primers
and for cooking with alkyds. Fast setting, high gloss resin
for sheetfed inks. Compatible with alkyds and natural inks.
W’Fen F 130 120–140 15–25 120–170
(60 % in X)
max. 10
(60 % in X)
Cold cut modifying resin for paints with good drying
properties and high gloss.
WorléeFen
Rosin based hard resins, phenol modiied

17
Type Melting point
Capillary
method[°C]
Acid value
DIN EN ISO
3682
[mgKOH/g]
Flow time
20 °C
DIN 53211-4
[s]
Color
DIN ISO 4630,
Gardner
Main uses and principal characteristics
W’Sin GM 201 95–120 20–25 25–50
(50 % in Ws
145–195)
max. 8
(50 % in Ws
145–195)
General purpose resin for modiication of oil, alkyds and paints based up on
them. As a cold cut or to be polymerised with oils and alkyds.
W’Sin GM 203 100–125 20–25 25–50
(50 % in Ws
145–195)
max. 8
(50 % in Ws
145–195)
General purpose resin for oil and alkyd based paints and for NC­lacquers.
For modiication of oil and paints based up on them. As a cold cut or to be
polymerised with oils and alkyds.
W’Sin PM 200 95–115 15–25 20–40
(50 % in Ws
145–195)
max. 8
(50 % in Ws
145–195)
Low viscosity penta esteriied resin for gloss improvement for house and
industrial paints and dispersing media for pigment pastes and preparations.
W’Sin PM 202 100–125 15–20 30–60 (50 %
in Ws 145–195)
max. 8
(50 % in Ws
145–195)
Penta esteriied general purpose resin for decorative, do­it­yourself and
industrial paints. Also used for furniture adhesives.
W’Sin MK 223 90–110 40–50 80–120
(60 % in BAc)
max. 8
(60 % in BAc)
With castor oil plasticized, for NC­lacquers with very good solvent release
and sandability.
W’Sin MS 235 125–155 180–200 10–20
(50 % in Ethanol)
max. 15
(50 % in Ethanol)
For alcohol and water based paints and lacquers, lexo and gravure inks,
overprint varnishes. Compatible with acrylic polymers and NC. Soluble in
water after neutralisation. FDA 175.105, 175.300
W’Sin MS 265 155–190 190–220 15–25
(50 % in Ethanol)
max. 8 For alcohol and water based paints and lacquers, lexo and gravure inks,
overprint varnishes. Compatible with acrylic polymers and NC. Soluble in
water after neutralization. FDA 175.105, 175.300
WorléeSin
Rosin based maleic resins and rosin esters
Type Appearance Forms of
delivery
Application Main uses and principal characteristics
Special-Primer
AP 1010
white
(pigmented)
4,0 % in xylene undiluted: spraying,
dipping, rolling, printing
Adhesion promoter for EPDM, PP and blends of these as used for the automotive industry
for spoilers, bumpers, dashboards etc. for subsequent painting, printing and sticking.
Special­Primer AP 1010 can be used in aerosol cans.
Special-Primer
AP 1030
white
(pigmented)
4,0 % in xylene undiluted: spraying,
dipping, low coating,
rolling, printing
Adhesion promoter for EPDM, PP and blends of these as used for the automotive industry
for spoilers, bumpers, dashboards etc. for subsequent painting, printing, sticking and
coating.
Special-Primer
PE 6800
colourless to
yellowish, clear
5,0 % in xylene application as
2.5 % solution
Adhesion promoter for untreated polyethylene for subsequent coating or printing.
Special-Primer
PP 3200 W
low viscous,
beige cream
coloured liquid
30 % in water application diluted with
water to 10 % solids
con tent by spraying,
dipping or printing
Aqueous adhesion promoter based on especially modiied, low hlorinated polypropylene
for PP, polyoleinic blends and with restrictions for PE.
Special-Primer
PP 4400 W
brownish,
turbid liquid
40 % in water application diluted with
water to 10 % solids
content by spraying,
dipping or printing
Chlorine­free primer and adhesion promoter based on special modiied polypropylene
used for polypropylene and polyoleinic blends.
Special-Primer
PP 5130
colourless to
yellowish,clear
2,5 % in xylene
5,0 % in xylene
application as
2.5 % solution
Adhesion promoter for untreated polypropylene for subsequent painting, printing, sticking.
Batteries, packaging ilm, heels, toyes, foils etc.
Special-Primer
PP 7550
colourless to
yellowish,clear
5,0 % in xylene application as
2.5 % solution
Same as PP 5130, with improved adhesion promotion on different PP substrates and
aluminium.
Special-Primer
PP 7560
colourless to
yellowish,clear
10 % in xylene application as
2.5 % solution
Same as PP 5130, with improved adhesion promotion on different PP substrates and
aluminium.
Special-Primer
PP 7580
colourless to
yellowish,clear
2,5 % in xylene application as
2.5 % solution
Adhesion promoter for untreated polypropylene for subsequent painting, printing, sticking.
For batteries, heels, toys, foils, garden furniture etc. Best adhesion properties.
Special-Primer
Adhesion promoters

18
Type Appearance Forms of
delivery
Addition* Main uses and principal characteristics
W’Add 100 colourless, high
viscous liquid
min. 98 % 0,1–1,0 % Polymeric, silicone free low control agent for solvent based and solvent free coatings, UV­
resistant, good recoatability, avoids surface imperfections. Corresponds to FDA § 175.300.
W’Add 101 colourless, high
viscous liquid
min. 98 % 0,1–1,0 % Silicone free acrylic low control agent for solvent based and freecoatings and printing
inks of different composition. Avoids also surface imperfections. Corresponds to FDA
§ 175.300.
W’Add 311, 10 %
W’Add 311, 30 %
clear to slightly turbid,
low viscous liquids
10 % in xylene
30 % in xylene
0,1–1,0 %
0,03–0,3 %
Silicone based, for paints, lacquers and leather inishes. Improve mar resistance, slip, low,
gloss, reduce foaming, pinholing and orange peel.
W’Add 312 clear, low viscous
liquid
10 % in isop.
HC 170–200
0,1–1,0 % Silicone based additive, especially for decorative paints. Eliminates cell structure and
brush marks, improves low, mar resistance and slip. Specially designed for aromatic free
decorative paints.
W’Add 315 clear, colourless,
low viscous liquid
10 % in iso­
Propanol
0,5–1,0 % Silicone based additive, for water and solvent based paints, improving mar resistance and
slip, low and gloss.
W’Add 317 transparent
yellowish liquid
100 % 0,01–0,3 % Silicone based additive, for solvent based coatings, improves deairing, levelling, mar resis­
tance, slip and gloss, reduces orange peel and cratering. Also suitable for curtain coatings.
Thermostable in stoving systems.
W’Add 327 clear, low viscous
liquid
20 % in iso­
Propanol
0,1–1,5 % Silicone based, mainly for water thinnable lacquers and paints, improves wetting of plastic
and aluminium substrates, increases mar resistance and slip, avoids cratering.
W’Add 330
W’Add 333
clear, slightly yel­
lowish, low viscous
liquid
clear, low viscous
liquid
10 % in BG
10 % in water
0,3–0,5 %
0,3–0,5 %
Silicone based, reduce surface tension of water thinnable systems, improve levelling,
reduce edge pulling, eliminate surface imperfections.
W’Add 340 clear to slightly hazy,
yellowish liquid
100 % 0,1–1,0 % Especially modiied silicone polyether for substrate wetting of aqueous systems on dificult
substrates.
W’Add 342 clear to slightly hazy,
yellow coloured liquid
60 % in Dipropy­
lenglykolmonom­
ethylether
0,1–1,0 % Excellent substrate wetting additive for aqueous systems, reduces surface tension, low
tendency to stabilize foam.
W’Add 345 clear to slightly turbid
yellowish liquid
71 % in solvent
blend/water
0,3–1,5 % Special modiied silicone polyether for aqueous systems for improving subtrate wetting
and penetration on absorbend substrates.
W’Add 351 turby, creamy liquid 70 % in water/BG 0,5–1,0 % High molecular silicone additive to improve slip, mar resistance and antiblocking,
for aqueous systems.
W’Add 352 turby, creamy liquid 70 % in water/
1,2­Propylen
glycol
0,5–3,0 % High molecular silicone additive to improve slip, mar resistance and antiblocking,
for aqueous systems.
W’Add 355 milky liquid 40 % in water 0,3–2,0 % Silicone emulsion, improves substrate wetting, low, smoothness, mar resistance and
water resistance.
W’Add 356 colourless liquid 30 % in xylene 0,2–1,0 % Silicone based additive, for solvent based coatings, improves deairing, levelling, mar resis­
tance, slip and gloss, reduces orange peel and cratering. Also suitable for curtain coatings.
Thermostable in stoving systems.
W’Add 380 F clear, brown liquid 30 % in water 0,01–0,2 % Anionic luorinate additive for aqueous coatings. Strong reduction of surface tension,
considerably improving substrate wetting and low.
W’Add 386 F clear to slightly
turbid liquid
10 % in water/
Dowanol PnB/Iso­
propanol
0,01–0,2 % Anionic luorinate additive for aqueous coatings. Strong reduction of surface tension,
considerably improving substrate wetting and low.
W’Add 410 N clear to slightly
turbid liquid
0,5–2,0 % Viscosity stabilizer, anti skinning and anti­gelling agent for solvent based air drying and
stoving paints.
W’Add 411 N clear, slightly turbid,
yellowish, low
viscous liquid
0,5–2,0 % Like WorléeAdd 410 N, but aromatic free.
W’Add 412 transparent liquid 65 % in water 0,5–1,0 % Solvent free compatibility agent for easier incorporation of driers into water based alkyd
emulsion paints.
W’Add 422 50 % in iso­Pro­
panol/Methoxy­
propanol
0,2–0,8 % Cationic surface active additive for increasing the conductivity of electrostatic sprayable
paint systems, low addition.
*calculated on total form.
WorléeAdd
Resilow – Additives for paints and lacquers

19
Type Appearance Forms of
delivery
Addition* Main uses and principal characteristics
W’Add 425 clear, yellowish
liquid
51 % in solvent
blend
0,2–1,5 % Silicone free additive, imparts an equal structure to coil coatings which contains wax.
Improves degassing, reduces popping, also for clear coats.
W’Add 428 clear liquid 10 % in solvent
blend
3,0–6,0 % Silicone free additive for structured coil coatings without wax addition, for achieving
orange peel effect. Improves degassing.
W’Add 429 colourless liqud 10 % 0,5–1,5 % For improving the eficiency of matting agents in solvent based silk gloss decorative
paints. Additionally improvement of low and scratch resistance, deairing.
W’Add 456 colourless liqud 30 % in water 0,5–3,0 % Nitrit­free anti­lash rust agent and corrosion inhibitor for aqueous paints and lacquers.
W’Add 458 colourless liqud 38 % in water 0,2–2,0 % Nitrit­free anti­lash rust agent for aqueous paints and lacquers.
W’Add 483 colourless to light
yelllow liquid
76 % 1,0–3,0 % Special polyester resin for improving adhesion of solvent based 2 component PU and
stoving paints on metals substrates. Improves elasticity and low. Corresponds to FDA
§ 175.300
W’Add 486 colourless to light
yelllow liquid
75 % in solvent
blend
1,0–3,0 % Special adhesion promoter for solvent based systems for air drying and oven cured
systems.
W’Add 487 colourless to light
yelllow liquid
78 % in solvent
blend
1,0–3,0 % Like W’Add 486. Does not contain n­methyl­2­pyrrolidone.
W’Add 700 milky liquid 60 % in water 2,0–5,0 % Silicone based, for aqueous systems to increase water resistance, gloss, adhesion and
weather resistance. Best effect after more than 16 hours of addition into the ready made
product.
W’Add 710 colourless, clear to
slightly turbid liquid
50 % aliphatische
HC/iso­propanol
0,5–2,0 % Amino functional polydimethyl siloxane used in leather coatings, leather care products and
car polishes. Improves resistance, smoothness and polishing ability. For solvent based as
well as aqueous systems.
W’Add 720 colourless, clear to
slightly turbid liquid
50 % in solvent
blend
1,5–3,0 % Special modiied polydimethyl siloxane for the manufacture of aqueous and solvent based
antrigrafiti coatings.
W’Add 781 clear, medium
viscous liquid
solvent free 0,1–2,0 % Silicone free additive for solvent based, solvent free and water based systems to improve
levelling, lexibility and adhesion. 2 component­PUR­coatings of high ilm thickness show
reduced blistering.
W’Add 1400 clear to slightly
turbid liquid
100 % 0,5–1,0 % Silicone based additive for water thinnable and solvent based coatings and printing inks
including UV­curing systems to improve deairing, low out, levelling, gloss, slip, mar resis­
tance and to eliminate cratering and orange peel.
W’Add 1500 viscous liquid 100 % 0,2–2,0 % Silicone based additive for solvent based coatings and inks to increase abrasion resis­
tance, smoothness and anti­blocking. FDA 175.300 approved. Corresponds to FDA
§ 175.300.
W’Add 2000 clear, yellowish
liquid
30 % in BAc/
Poly glycol
0,5–1,2 % Catalyst for solvent based and aqueous isocyanate crosslinking systems.
W’Add 2030 clear, amber
coloured liquid
28 % in iso­
Butanol/MPA
0,4–2,0 % Catalyst for solvent and water based stoving inishes. Improves water, salt spray and
detergent resistance.
Resilow FK 70 colourless liquid 70 % in PGME 0,3–2,0 % Silicone free anti­loating and low control agent e.g. for polyester/melamine resin based
stoving paints. Eliminates craters, pinholes and isheyes. Corresponds to FDA § 175.300
and AP (2004) 1.
Resilow FL 2 colourless, high
viscous liquid
min. 98 % 0,2–2,0 % Silicone free acrylic low control agent for solvent based and solvent free coatings based
on alkyd, polyester, acrylic, vinyl, epoxy and polyurethane resin. Corresponds to FDA
§ 175.300 and AP (2004) 1.
Resilow FL 9 colourless, high
viscous liquid
min. 98 % 0,2–1,5 % As Resilow FL 2, but often better compatibility.
Resilow FM 4
FM 4-50
colourless, high
viscous liquid
min. 98 %
50 % in xylene
0,2–2,0 %
0,4–4,0 %
As Resilow FL 2, but with improved eficiency.
Corresponds to FDA § 175.300 and AP (2004) 1.
Resilow L 3075
Resilow LH-240 viscous liquid min. 98 % 0,2–1,5 % Flow control and degassing additive for solvent based and solvent free formulations of
different composition, including gel coats.
Resilow LH 241 clear, viscous liquid min. 98,5 % 0,2–2,0 % Silicone free acrylic low control agent for solvent based and solvent free coatings based
on alkyd, polyester, acrylic, epoxy, polyurethane resins etc. Excellent compatibility, espe­
cially suitable for clear coats.
Resilow LW colourless to slightly
yellow, low viscous
liquid
min. 98,5 % 0,2–1,5 % Silicone free acrylic low control agent for solvent based and solvent free coatings, similar
to Resilow FL 2 but lower in viscosity.
Resilow W 51 colourless, medium
viscous liquid
50 % in BG
/iso­Propanol
0,5–3,0 % Silicone free acrylic low control agent for mainly water based coating systems as well as
solvent based stoving systems (very good compatibility). Effective pigment wetting agent.
Corresponds to FDA § FDA § 175.105, 175.300 and AP (2004) 1.
*calculated on total form.

20
WorléeAdd
Defoamers for solvent based and solvent free systems
Type Appearance Forms of delivery Addition* Main uses and principal characteristics
W’Add 317 clear, yellowish
liquid
100 % 0,01–0,3 % Silicone based additive, multifunctional, aids defoaming and deairing, improves as well
levelling and mar resistance.
W’Add 370 colourless liquid 10 % in X/BAc/
Cyclohexanon 4:4:1
0,03–0,5 % Fluor silicone based defoamer and deairing agent for solvent based paints and inks
of different compositions as well as EP­coatings.
W’Add 371 colourless liquid 1 % in MPA 0,1–1,0 % Fluor silicone based defoamer and deairing agent for solvent based and high solid
coatings. Especially for decorative paints.
W’Add 372 colourless liquid 5 % in MPA 0,05–0,8 % Fluor silicone based defoamer and deairing agent for solvent based and high solid
coatings. Especially for decorative paints.
W’Add 373 N colourless liquid 3 % in isop. HC
150–180
0,2–1,0 % Silicone based additive with multifunctional properties. Used in solvent based coatings
mainly to achieve surface smoothness and mar resistance. At the same time it works as
antifoam agent and avoids surface imperfections.
W’Add 425 clear, yellowish
liquid
51 % in solvent
blend
0,2–1,5 % Silicone free antifoam agent and defoamer, especially suitable for wax containing coil
coating structure paints and 2 component EP loor coatings.
W’Add 602 clear liquid 1,3 % in isop. HC
170–200
0,4–2,0 % Silicone based antifoam agent mainly for 2 component­PU and EPcoatings.
W’Add 603 clear liquid 13,2 % in isop. HC 0,2–1,5 % Polyacrylate modiied silicone defoamer for solvent based and solvent free coatings of
different compositions, approved under FDA regulation 175.300.
W’Add 635 clear to slightly
turbid, yellowish
liquid
8,5 % in solvent
blend
0,5–2,0 % Defoamer based on silicone­acrylic­mod. Especially for solvent based and solvent free
EP­loor coatings.
W’Add 636 low viscous liquid 16 % in isop.
HC 170–200/
xylene 49:35
0,2–3,0 % Silicone based antifoam agent and defoamer for solvent based systems, especially
suitable for solvent free PU coatings.
W’Add 677 clear to slightly
yellowish liquid
20% in isop. HC,
aromatenfrei
0,05–0,6 % Silicone free antifoam and defoaming additive for solvent based and solvent free
formulations of different composition.
W’Add 678 clear liquid 10 % in solvent
blend
1,0–3,0 % Silicone free antifoam agent and defoamer mainly for solvent based and solvent free
2 comp.­PU coatings.
*calculated on total form.
Type Appearance Forms of
delivery
Addition* Main uses and principal characteristics
Resilow W 52 colourless, medium
viscous liquid
50 % in BG
/iso­Propanol
0,5–3,0 % Silicone free acrylic low control agent for mainly water based coating systems as well as
solvent based stoving systems (very good compatibility). Effective pigment wetting agent.
Corresponds to FDA § 175.105 and AP (2004) 1.
Resilow W 5200 colourless, high
viscous liquid
min. 96 % 0,2–1,5 % Silicone free polymer low control agent, especially for aqueous coatings but also for
solvent based systems.
Resilow UV-10 colourless, medium
viscous liquid
min. 98 % 0,1–3,0 % Silicone free acrylic low control agent for UV curing as well as solvent based coatings and
printing inks. Improves also substrate wetting and deairing, avoids surface imperfections.
Often synergistic effects in combination with silicone additives.
*calculated on total form.

21
Type Appearance Activity Density
DIN
51757
[g/cm3]
Addition* Main uses and principal characteristics
W’Add 604 N low viscous liquid 25 % 0,86 1,0–4,0 % Silicone containing defoamer and antifoam additive mainly for water thinnable wood
and parquet lacquers, wall paints etc. based on acrylic emulsions.
W’Add 614 clear liquid 25 % 0,858 0,5–3,0 % Silicone based, APEO free defoaming solution for water based systems of different
composition.
W’Add 624 clear liquid 25 % 0,960 0,5–3,0 % Silicone based, aromatic and APEO free defoaming solution for water based systems
of different composition.
W’Add 626 colourless, viscous
liquid
100 % 0,05–1,0 % Silicone based silica containing defoamer concentrate for aqueous formulations.
Very good defoaming in pigment mill bases
W’Add 659 milky liquid 10 % 1,0 0,1–0,5 % Silicone foam control agent, effective in non­ionic, anionic and cationic systems.
W’Add 685 milky liquid ca. 10 % 1,0 0,1–0,5 % Silicone based, very eficient defoaming emulsion for water thinnable paints and
lacquers, approved under FDA regulation 175.300.
W’Add 695 milky liquid 10 % 1,0 0,1–0,5 % Silicone based, non­ionic antifoam emulsion for water­borne paints and lacquers.
*calculated on total form.
WorléeAdd
Defoamers for water based systems
WorléeAdd
Resilow – Additives for powder coatings
Type Appearance Addition* Main uses and principal characteristics
W’Add 18 white powder 0,5–1,5 % Silicone free powder low control agent for general industrial applications.
W’Add 101 P white powder 0,5–1,5 % Silicone free powder low control agent for high gloss powder coatings and clear coats.
W’Add 360 laked solid 0,5–2,0 % Low molecular weight, hydroxy functional polymeric silicone additive for better mar resistance, slip and low.
W’Add 902 white powder 0,5–1,5 % For reducing the melt viscosity, thus improving deairing and degassing. Best results in combination with very
low amounts of benzoine (0,1­0,2 %). Especially suitable for non­yellowing powder coatings, for instance when
cured in gas ired ovens.
W’Add 904 white granulate 0,5–4,0 % For reducing the melt viscosity, thus improving deairing and degassing. Best results in combination with very
low amounts of benzoine (0,1­0,2 %). Raw materials 21 CFR 175.300 FDA listed.
W’Add 915 white powder 1,5–2,5 % Catalyst for better mechanical properties of GMA­acrylic powder systems based e.g. on Isocryl EP­570.
W’Add 1200 white powder 0,3–6,0 % Micronized synthetic wax improving slip properties and mar resistance of powder coatings. Excellent deairing
effect. At higher concentrations it may also function as a latting agent
W’Add ST-70 white powder 0,1–0,5 % Stannous octoate catalyst for PU powder coatings.
Resilow CP 77 white powder 0,7–1,5 % Silicone free powder anti­cratering agent. Also suitable for powder clear coats and UV systems.
Resilow L 66 F clear, viscous liquid 0,2–2,0 % Liquid functional low control agent. Excellent transparency in TGIC­powder clear coats. Use via a master
batch production.
Resilow P 64 F white powder 0,2–2,0 % Powder functional low control agent for powder clear coats of all types, especially for GMA acrylate systems.
Due to the compatibility the transparency is hardly reduced.
Resilow P 65 F white powder 0,2–2,0 % Powder functional low control agent for powder clear coats of all types, especially based on epoxy.
Raw materials 21 CFR 175.300 FDA listed.
Resilow P 67 white powder 0,7–1,5 % Silicone free powder low control agent with good allround properties.
Resilow PH 240 white powder 0,5–2,0 % Powder functional low control agent with excellent low without increasing „pill low“; especially suitable
for PU powder systems and PUR clear coats.
Resilow PL 200 white powder 0,7–1,5 % Silicone free powder low control agent with good intercoat adhesion when recoated with powder or liquid paints.
Resilow PV 5 white powder 0,5–1,5 % Silicone free powder low control agent for powder coatings of all types. Very freelowing and yellowing resistant.
Resilow PV 88 white powder 0,5–1,5 % As Resilow PV 5, but on another silicate carrier.
*calculated on total form.

22
Specialities for powder coatings
Type Appearance Addition* additional
information
Main uses and principal characteristics
Acrylharzvernetzer
GMA-300
water bright
granulates
1,0–7,0 % 105–120 °C
softening range
High reactive acrylic crosslinker for increasing crosslinking density, e.g. in Hybrid­, Primid and PU
systems. Also as binder component for UV systems.
Epomatt G-151 granulate 2,0–10,0 % 115–125 °C
softening range
Matting agent for epoxy powder coatings, especially in combination with OTB­epoxy hardeners.
Non­yellowing. Also for NIR­application.
Epomatt G-152 granulate 2,0–10,0 % 115–125 °C
softening range
Matting agent for matt and dead matt epoxy and hybrid powder coatings. Matting of low temperature
curing epoxy powders in combination with Epoxy Hardner G­91 and of low temperature curing
(140 °C) hybride powders with suitable poyester type. Also for NIR application.
Epoxidhärter G-91 granulate 2,0–4,0 % 92–106 °C
softening range
Imidazole adduct for curing epoxy powder coatings at low baking temperature (130 °C) with still good
mechanical properties.
Epoxidhärter G-92 granulate 6,0–24,0 % 80–100 °C
softening point
Catalysed phenolic curing agent for epoxy resins. Imparts excellent chemical resistance and mechani­
cal properties at fast cure (200 °C) or low temperature cure (120 °C).
Escat 50 off­white
granulates
0,3–0,6 % Substituted Imidazole/wax blend to improve curing of powder coatings; easily dispersible.
Isocryl EP-570 G lakes 17–20 % 140–155 °C
softening point
GMA­matting resin for one­shoot matt outdoor powder coatings with good abrasion resistance and
surface levelling, also suitable for matt clear coats.
*calculated on total form.
Sales Organisation
Germany
Hamburg Worlée­Chemie G.m.b.H., Headquarters, Traded Products Division handel@worlee.de 040­73333­0
Central and East Europe Administration
Lauenburg Worlée­Chemie G.m.b.H., Resin Plant / Sales service@worlee.de 04153­596­0
Lübeck Worlée­Chemie G.m.b.H., Polymer Plant service@worlee.de 0451­61 97 4­0
Regional German Sales Ofices
Sales Area North-East Worlée­Chemie G.m.b.H. Sales Ofice North­East SHandt@worlee.de 040­7333­2650
Sales Area West Worlée­Chemie G.m.b.H. Sales Ofice West vbwest@worlee.de 02102­5 97 98 0
Sales Area South-West Worée­Chemie G.m.b.H. Sales Ofice South­West fw_sengewald@t­online.de 06202­6 59 92
Sales Area South-East Worée­Chemie G.m.b.H. Sales Ofice South­East doebelin@lacktip.de 09372­134 790
Europe
Austria Worlée­Chemie G.m.b.H., VB Süd­Ost doebelin@lacktip.de 09372­134 790
Baltic States IMCD Baltics UAB dsa@imcd.lt +370­5­236 36 62
Belgium E.H. Worlée & Co. B. V. worlee@worlee.nl +31­35­6 56 14 24
Bulgaria Petrex – E Ltd spetrov@petrex­e.com +359­2­958 28 72
Croatia/Slovenia/Serbia Kemoteks d.o.o. nenad.kostic@zg.t­com.hr +385­1­383 0067
Czech Republic/Slovakia Ing. Petr Torma ptorma@seznam.cz +420­37­793 23 33
Finland Brenntag Nordic OY main@brenntag­nordic.com +358­9­54 95 64 11
France Worlée­Chemie G.m.b.H. Lauenburg mhderansart@worlee.de +49(0)4153­ 596­4700
Great Britain E.H. Worlée & Co. (UK) Ltd. sales@worlee.co.uk +44­17 82­71 46 14
Greece Worlée­Chemie G.m.b.H. c/o Papadimitracopoulos Brothers pan­theos@forthnet.gr +30­6944­149802
Hungary Béla Vorös vrsbl@freemail.hu +36­30­858 9976
Ireland E.H. Worlée & Co. (UK) Ltd. sales@worlee.co.uk +44­17 82­71 46 15
Italy Worlée Italia S.R. L. worlee@worleeitalia.it +39­02­28 04 03 79
Luxemburg E.H. Worlée & Co. B. V. worlee@worlee.nl +31­35­6 56 14 24
The Netherlands E.H. Worlée & Co. B. V. worlee@worlee.nl +31­35­6 56 14 25
Norway Harald Mathisen A/S ingar.strand@mathisen.no +47­22­40 59 40
Poland Worlée Polska Sp.z.o.o legierski@poczta.onet.pl +48­32­401 1460
Portugal Mapril S.A. tintas@mapril.com +351­22­030 43 00
Romania M.R. Chimtrade S.R.L. mircea.radulescu@mrchimtrade.ro +40­317­11 03 92

23
Russia/GUS Stoelck Aussenhandel AG stoelck@wtt.ru +7­495­258 2475, 76
Interchemmet Company Limited msm@int­chemmet.spb.ru +7­812­449 2195
Spain Montse Solà msola@worlee.es +34­93 778 11 86
Sweden Brenntag Nordic AB niklas.ekman@brenntag­nordic.com +46­40­28 73 23
Switzerland Varistor AG Bereich Worlée Chemie info@varistor.ch +41­56­266 5075
Turkey Kar Kimya San.ve Tec. Ltd. Sti. kgbakan@karkimya.com.tr +90­216­317 65 30
Africa
Egypt African Chemicals S.A.E. info@africanchemicals.com +202­2378 4301
+202­2750 8641
+202­2750 8740
Morocco Graphichimie industries@graphichimie.net +212­5223 20 830, 37
South Africa Lionheart (PTY) LTD. Lionhartl@global.co.za +27­11917­9661/62/63
America
Brazil Adexim S/C tecnica@adexim­comexim.com.br +55­11­39 66 31 55
Canada Ferguson Chemical Innovation coatings@fergusonchemical.com +905 453 7131
USA Eastern Region J.H.Calo Company Inc. sales@jhcalo.com +1 516 832­7750
USA Mid- and Western
Region, British Columbia
The Tryline Group sales@tryline.com +1 425 450­8822
Asia
Regional Ofice Asia Paciic Worlée­Chemie GmbH
Regional Ofice Asia Paciic worlee@streamyx.com +60­3­7118 2001­3
China Worlée (Shanghai) Trading Co., Ltd. worlee@worlee.cn +86­21­6247 2546
Worlée­Chemie GmbH worlee@worlee.cn +86­216496 0533
Shanghai Technical Center
India Worlée­Chemie India Private Limited service@worlee.in +91­22­2778 1042
Victor Agencies info@victoragencies.com +91­112­923 2907
Indonesia PT Indoresksa Lokamandiri marketing@indoreksa.com +62­21­5694 1665 / 7 / 9
United Chemicals unichem1@indosat.net.id +62­21­380 3805
Iran Chemie Yaran Co. Ltd. cy@chyaran.com +98­21­2205 9909
Israel Shiran Representatives 2008 Ltd. gabi.golan@shiran­2008.co.il +972­9 74 30 411
Japan Worlée­Chemie GmbH
Yashuhiro Watanabe ben1943@isis.ocn.ne.jp mobile +81­08054 13 30 51
Jordan Target Chemicals Est. target@wanadoo.jo +962­6­55 30 771
Korea Hasang Interchem Co. Ltd. hstcl@unitel.co.ko +82­2­48 78 08 6/7
Rexchem Corporation hycho@rexchem.com +82­31­929 6210
Lebanon Meditrade indecchem@live.com +961­1­89 47 22/25
Malaysia Entire Concept SDN. BHD ec_chem@myjaring.net +60­3­5122 1335 / 1615
Philippines Omya Chemical Merchants Inc. chmer@chemicalmerchants.com +632­813­0301
Kingdom of Saudi Arabia Chemtec sales@chemtecinc.com +9662­2843432 / 284 34 33
Singapore Segachemie Pte. Ltd. jeremy@segachemie.com +65­6846 09 33
Sri Lanka Tradekem (Pvt.) Ltd. tradekem@panlanka.net +94­112­578060/114­54 18 89
Taiwan/R.O.C. Best Sincerity Co., Ltd. best.sincerity@gmail.com +886­22­7­65 98 89
Neoway Chemicals Co. Ltd. neoway.chem@msa.hinet.net +886­7 616 7719
Thailand Alphani International Co. Ltd. alphani@loxinfo.co.th +662­21656 57
Vietnam An Thanh Pte phong2005@hcm.fpt.vn +84­8­38060785
UAE Applied Technology +971­6­48 19 679
Australia
Endeavour C&P darren.spies@optusnet.com.au +61­7­3315 6496
New Zealand
Rebain International (NZ) Ltd. sales@rebain.co.nz +64­9­966 2445
The information and speciications contained in this document are based on careful investigations and examinations by us . They do however not relieve from examining the
described products as to their suitability for the intended process and purpose and as to the risk of infringement of third party industrial property rights. A liability on our part for the
correctness and completeness of the information and speciications in this booklet as well as other advice concerning the application methods is excluded. Any liability on our part is
subject solely to our General Standard Terms and Conditions (GSTC), which can also be viewed under www.worlee.de/GSTC. If required we will forward a copy to you.

02.12.2009 M. Rehfeld2
• Part I:
Bruno Bock and Evans Chemetics: The companies and
their products.
• Part II:
The production line Polythiols: Multifunctional mercapto
compounds based on Mercaptocarboxylic Acids.

!

02.12.2009 M. Rehfeld4
" "
• May 1937: Founded by Bruno Bock as a trading company.
• 1948/50: Start of the production of Thioglycolic Acid in Hamburg1Billbrook.
• 1967/68: Relocation to Marschacht (south1east of Hamburg)
• June 2004: DIN EN ISO 9001, 14001 and OHSAS 18001.
• September 2005: Acquisition of Dow‘s business unit Evans Chemetics
The company is 100 % privately owned and occupies a global leading position
in the field of Mercaptocarboxylic Acids.

02.12.2009 M. Rehfeld5
" "
• 1938: Founded by Ralph L. Evans in Hoboken, NJ
• 1943: Relocation to Waterloo, NY
• 1978: Evans Chemetics was sold to W.R. Grace
• 1992: The Organic Chemicals Division of W.R. Grace including Evans
Chemetics was acquired by Vestar Capital Partners forming Hampshire
Chemical Corporation
• 1995: Hampshire Chemical Corporation was purchased by Sentrachem,SA
• 1998: DOW acquired Sentrachem
• 2005: Bruno Bock acquired the Evans Chemetics business including the
Waterloo production site from DOW through its fully owned subsidiary Evans
Chemetics LP located in Iselin, NJ
• Evans Chemetics LP is ISO 9000:2000 certified

02.12.2009 M. Rehfeld6
" # # "

02.12.2009 M. Rehfeld7
" $ %

02.12.2009 M. Rehfeld8
" "
Glenpointe Center, Teaneck, NJ Production site in Waterloo, NY

02.12.2009 M. Rehfeld9
" # & "

02.12.2009 M. Rehfeld10
" "
' ( ' ) $
Thioglycolic Acid (TGA) 31Mercaptopropionic Acid (31MPA)
( (
Thiolactic Acid (TLA or 21MPA) Thiodiglycolic Acid (TDGA)
( (
Dithiodiglycolic Acid (DTDGA)
( * + ,

02.12.2009 M. Rehfeld11
" ' $ "
1 St = Stabilizers
1 C = Cosmetic ( erms, traighteners, epilatories)
1 L = Leather
1 R = Rubber
1 A = Secondary antioxidant (Polyolefins, ABS, SBR rubber)
1 o = others (water treatment, oil field, synthesis: pharma,
conductive polymers, Bisphenol A, surface cleaners e.g. wheel
cleaners)

02.12.2009 M. Rehfeld12
" $ "
A
A
A
- $
StSt/C/PGlycerine
PPPolyols
PSt/PEthylene Glycol
oStearyl
StStC121C14
StSt/Pi1Tridecyl
StLauryl
StSt/Pi1Octyl
RStSt/PEthylhexyl
oPButyl
-.$/"( $.$$

02.12.2009 M. Rehfeld13
" $ + 0 + " "
11C1d
11L, o+
11C1d
C1p/sC1pC1p/s$
C1p/s1C1p/s(
1$- -.$.$

02.12.2009 M. Rehfeld14
" "
Monoethanolamine (low iron)Trading Goods
# 2 213 1+
Plasticizer in automotive rubber applicationsDi1n1butyl1methylene1bis1
thioglycolate
Oilfield applications, chain transfer agent in
polymerization applications, detergent in
cleaning solutions
TGA
Co1catalyst used in the production of
Bisphenol A, chain transfer agent in
polymerization reactions
31MPA

02.12.2009 M. Rehfeld15
" "
Chelating agent for photo processing1,31Diaminopropane121ol1tetraacetic
acid (Hampronol)
Functional monomer or
polymerizable surfactant in aqueous
polymer applications e.g. PVDC
(Polyvinyliden chloride)
21Sulfoethyl Methacrylate
(21SEM)
phamaceutical intermediate,
polymers
11Thioglycerine
Chemical structures from: http://ecb.jrc.ec.europa.eu/esis/

02.12.2009 M. Rehfeld16
" ' 4 ' *5667, "
• Globally active
• Turnover 2008: ~50 Mio. EUR
• Number of employees: app. 97 full time employees
( ' $
47%
28%
14%
2%3% 6% 0%
Stabilizer Cosmetic Polymer Rubber
Leather Other Agents
( # #
25%
25%
1%6%
6%
36%
1%
Germany Rest EU Rest Europe NA
LA Asia/Pac. Arab

( '
( ' ) $

02.12.2009 M. Rehfeld18
• Fields of application
• Chemical variability
• Properties, advantages and disadvantages
• Raw materials: Mercaptocarboxylic Acids
• Types of Polythiols
• Formulations
• Summary

02.12.2009 M. Rehfeld19
8
' #
$ 2 +
• Fast epoxies (classic)
• Optical lenses (classic)
• Floor coatings
• Sealants(Polysulfides)
• Adhesives
#
• UV1cure coating systems: Clearcoat Automotiv from Akzo Nobel
• Decorative Coatings
• Coating of electronic circuit boards
• Special applications

02.12.2009 M. Rehfeld20
'
: Epoxies, isocyanates, unsaturated compounds.

02.12.2009 M. Rehfeld21
2 # 0 #
$ #
• Applicable in many systems
• EB1 and UV1curing always possible
• High but variable reactivity ⇒ Mercaptopropionate vs. Mercaptoacetate
• Low viscosities between 0,12 Pas and 0,45 Pas
• Mostly colourless liquids with high refractive index
• Modular composition kit for varying hardness / flexibility and reactivity
• Thiol1Ene systems: Low shrinkage and low oxygen inhibition. High conversion of the
double bonds.
- #
• Hydrolytic stability (depends on system and application)
• Smell. But clear improvement with PETMP l.o.
• Exothermal heat generation during the reaction with epoxies and isocyanates be a
disadvantage

02.12.2009 M. Rehfeld22
9 (
" ( ' ) $ "
' ( ' ) $
$ !
# $
* .$,
/"( $
*/"( $,

02.12.2009 M. Rehfeld23
" $ ' "
1+Pentaerythritol Tetra131Mercaptopropionate sl, csPETMP sl, cs
1+Pentaerythritol Tetra131Mercaptopropionate l.o.PETMP l.o.
1+Propylene Glycol131Mercaptopropionate 2200PPGMP 2200
1+Propylene Glycol131Mercaptopropionate 800PPGMP 800
1+Ethoxylated Trimethylolpropane Tri131Mercapto1
propionate 1300
ETTMP 1300
1+Ethoxylated Trimethylolpropane Tri131Mercapto1
propionate 700
ETTMP 700
++Glycol DimercaptoacetateGDMA
1+Trimethylolpropane TrimercaptoacetateTMPMA
1+Pentaerythritol TetramercaptoacetatePETMA
1+Glycol Di131MercaptopropionateGDMP
++Trimethylolpropane Tri131MercaptopropionateTMPMP
++Pentaerythritol Tetra131MercaptopropionatePETMP
4$''
' 9
# !

02.12.2009 M. Rehfeld24
" + "
245104413
Pre1reg.
2250415013
Yes
not miscible
~ 1,51
unknown
~ 26,8
238,3
2
Glycol Di1
31Mercapto1
propionate
.-(
204165314
Pre1reg.
12318119
Yes
not miscible
~ 1,519
unknown
~ 30,5
210,2
2
Glycol
Dimercapto1
acetate
.-($
233148017
Pre1reg.
1019319611
Yes
233148218
Pre1reg.
1019319914
Yes
251133611
Pre1reg.
3300718319
Yes
231147218
Pre1reg.
757512317
Yes
4 +
$
$+
+ $
not misciblenot misciblenot misciblenot miscible'
9 9
~ 1,531~ 1,547~ 1,52~ 1,532
)
0,145crystallize at
RT
0,1240,45
At RT [Pas]
~ 26,5~ 29~ 24~ 26+ "
[w/w%]
356,5432,5398,6488,2
9 # [g/mol]
3434+ "
Trimethylol1
propane Tri1
mercapto1
acetate
Pentaerythri1
tol Tetramer1
captoacetate
Trimethylol1
propane Tri1
31Mercapto1
propionate
Pentaerythri1
tol Tetra1
31Mercapto1
propionate
( ($($( ((
! !2 2

02.12.2009 M. Rehfeld25
" - "
Polymer
Pre1reg.
903912310
No
Polymer
Pre1reg.
903912310
No
Polymer
Pre1reg.
34535211914
No
Polymer
Pre1reg.
67478618315
No
4 +
$
$+
+ $
not misciblenot misciblemisciblemiscible within
limits
' 9
9
~ 1,457~ 1,465~ 1,485~ 1,495)
unknownunknown0,357unknown: at RT [Pas]
~ 2.9~ 8,0~ 7,8~ 13,5+ " [w/w%]
2176776 g/mol1274 g/mol708 g/mol#
9 # (calculated)
2233
Propylene
Glycol1
31Mercapto1
propionate
2200
Propylene
Glycol1
31Mercapto1
propionate
800
Ethoxylated
Trimethylol1
propane Tri1
31Mercapto1
propionate
Ethoxylated
Trimethylol1
propane Tri1
31Mercapto1
propionate
.(
5566
.(
766
(
;/66
( <66

02.12.2009 M. Rehfeld26
" + "
.-( *5, .-($ *5,
( *=, ($ *=,
+ "
( ( */, ( ($ */,

02.12.2009 M. Rehfeld27
" + "
( */, .( *5,
+ "

02.12.2009 M. Rehfeld28
" 4 9 '' "
+ 8 ' 566> 9 # 9
''
THIOCURE GDMPGD131MP
THIOCURE TMPMATTMA
THIOCURE TMPMPTT131MP
THIOCURE PETMPPET131MP; PTM
4 9 ''''
THIOCURE is a registrated trademark of Bruno Bock and Evans Chemetics LP

02.12.2009 M. Rehfeld29
8
1. Epoxies: Use of a amine or a latent base (Ciba) as an activator.
2. Isocyanate: Reaction is faster; Addition of a amine or a latent
base (Ciba) as an activator.
3. Michael1Addition: Addition of a amine or a latent base (Ciba).
4. Unsaturated compounds: Radical initiator.
The direct use of primary and secondary amines is not possible, because these
amines reacts with the esterfunction of the polythiols.
Activator = Generally tertiary amine; latent base; radical initiator.
An increase in temperature also leads to a speeding up of the reaction.

02.12.2009 M. Rehfeld30
8
" 1 ' "
+ :

02.12.2009 M. Rehfeld31
8
+ " " ?
122 1 125119GDMP1)
979 1 10341088PPGMP 2200
241 1 247235ETTMP 700
349 1 369388PPGMP 800
435 1 448426ETTMP 1300
107 1 108
122 1 125
136 1 140
111 1 114
125 1 128
Typical values
122PETMP1) l.o., sl
105GDMA1)
119TMPMA1)
133TMPMP1)
108PETMA1)
Theoretical values
+ " " ? $;,
SH1active1equivalent = theoretical value * 100 % / (Content %)

02.12.2009 M. Rehfeld32
8 :
Epikote 8281): 100
TMPMA: 52,88
ETTMP 1300: 47,32
Versamine EH 503): 10
Potlife4): 3,5 min
Epikote 8281): 100
PETMP: 32,3
ETTMP 1300: 112,7
DMP 302): 10
Potlife4): 2,5 h
Epikote 8281): 100
TMPMA: 5,5
PETMP: 16,95
DMP 302): 10
Potlife4): 4,0 min
/7@7=
8
1) Resolution; 2) 2,4,61tris(dimethylaminomethyl)phenol; 3) Cognis; 4) wooden paddle will not further be moistened
→ product is hard.

02.12.2009 M. Rehfeld33
8 :
8 9 " Different SH1contents from ETTMP 1300
1) Leuna1Harze; 2) Rhein Chemie: Triethylenediamine in Dipropylenglycol; 3) wooden paddle will not further
be moistened → product is hard.
EPILOX A 191001): 100
PETMP: 32,3
ETTMP 1300: 112,7
Addocat 1052): 5
Potlife3): 28 min
EPILOX A 191001): 100
PETMP: 51,7
ETTMP 1300: 45,1
Addocat 1052): 5
Potlife3): 8 min
EPILOX A 191001): 100
PETMP: 65,2
Addocat 1052): 1
Potlife3): 6,5 min
A57A7<

02.12.2009 M. Rehfeld34
8 :
* " , + " ( ;/66
In this equimolar formulation the SH1content from PETMP is stepwise substituted (10 % steps) by
ETTMP1300. With an increase of the amount of ETTMP 1300 the potlife and the flexibility increase. The
content of the catalyst, Addocat 105, is similar in all formulations.

02.12.2009 M. Rehfeld35
8 :
* " , *$ ;6@,
The amounts of PETMP and ETTMP 1300 are constant. The amount of the catalyst, Addocat 105,
will change. It shows that the potlife varies by the amount of the catalyst.

02.12.2009 M. Rehfeld36
8 :
;66 # $ ' ( ($
@A 100 parts Epikote 828; 22,75 parts PETMP; 10 parts DMP 30
>6 100 parts Epikote 828; 16,95 parts PETMP; 5,5 parts TMPMA; 10 parts DMP 30

02.12.2009 M. Rehfeld37
8 B
;66 # $ ' ( ($
All raw materials where stored at start temperature 5 °C or 22 °C: 100 parts Epikote 828, 69,2 parts
PETMP; 10 parts DMP 30.

02.12.2009 M. Rehfeld38
8 B
8 4 " Different SH1contents from ETTMP 1300
1)Bayer; 2) Rhein Chemie: Triethylendiamine in Dipropyleneglycol; 3) wooden paddle will not further be
moistened → product is hard.
DESMODUR XP 24101):
100
PETMP: 35,5
ETTMP 1300: 119,6
Addocat 1052): 0,33
Potlife3): ~ 15 h
DESMODUR XP 24101):
100
PETMP: 70,9
Addocat 1052): 0,02
Potlife3): 60 min
;@;/

02.12.2009 M. Rehfeld39
8 B
• Speeding up of the hardening by addition of TMPMA.
• Flexibilisation of the system by addition of ETTMP 1300. But the chemical
and light durability can decrease hereby which depends on the system.

02.12.2009 M. Rehfeld40
+
9
• High variety of reactions: Epoxies, Isocyanates and unsaturated Molecules.
• Low Viscosity, colourless and high refractive index.
• Good mechanical properties as crosslinking agent.
A variety of Polyols and Polyesterpolyols are available for esterification with
Mercaptocarboxylic acids.
Special polymer1polythiols can be made on demand of the customer.

Solutions for Coatings, Inks,
Adhesives, Elastomers
and Sealants
NACURE®
& K-CURE®
Acid & Blocked Acid Catalysts
K-KAT®
Non-tin Catalysts for Urethanes
K-PURE®
Catalysts for Epoxies
K-FLEX®
Polyols and Reactive Diluents
NACORR®
Rust & Corrosion Inhibitors
K-SPERSE®
Dispersants
K-STAY®
Rheology Modifiers

King Industries Coatings Additives Division
Technology Overview
Since 1932, King Industries has been supplying specialty chemical products to a variety of
industries that are performance driven with ever changing requirements. This is especially true for
the coatings, inks, adhesives and sealant markets, the audience for this product guide. While the
brochure covers our standard products, this overview has been designed to give you a summary of
our areas of technical expertise and to urge you to contact us if you feel we may be of assistance for
your specific product needs.
CROSSLINKING CATALYSTS
With over four decades of experience in catalysis, King offers the industry’s broadest spectrum of
catalysts including:
 Acid and blocked acid (latent) catalysts for amino thermoset systems
 Non-tin, mercury-free catalysts for urethanes
 Latent and super acid catalysts for the cationic cure of epoxies
 Hydrophobic catalysts for the moisture cure of siloxane functional polymers
POLYOLS & REACTIVE DILUENTS
 Unique polyester polyols based upon low molecular weight, linear, saturated aliphatic structures
with pendent hydroxyl groups
 Novel, low molecular weight diols with an all urethane backbone
 Acetoacetate functional reactive diluents
CORROSION INHIBITION
King offers ferrous and non-ferrous protection for a wide variety of metals and systems based on
several unique platforms:
 Sulfonate based rust and corrosion inhibitors
 Modified trialzole compounds and amino acid derivatives
DISPERSANT TECHNOLOGY
Whether organic or inorganic pigments/fillers, King offers a variety of dispersant technologies
including:
 Solvent free polymeric wetting and dispersing agents for solventless and epoxy systems
 Sulfonate based dispersants for non-aqueous, solvent-free and powder systems
 Organic wetting/dispersing agents for highly viscous systems such as ceramics, metal pastes
and sand-filled epoxies.
RHEOLOGY MODIFIERS
 Unique sulfonate based modifiers for non-aqueous systems
 Polyamide based thixotropes for aqueous and non-aqueous systems
 Hydrophobically modified ethoxylated urethane thickeners for waterborne systems
SURFACE CONTROL ADDITIVES & SILANES
In addition to King’s internally developed products, the Disparlon®
product line represents over 30
years of a technology alliance with Kusumoto Chemical Ltd. of Japan. The Disparlon line offers a
broad range of leveling, defoaming, anti-popping and anti-cratering additives for aqueous, solvent,
solventless, UV and powder systems. Similarly, King represents D.O.G Deutsche Oelfabrik of
Hamburg, Germany in North America for the technical sales of their products for coatings including
DEOLINK®
silanes and DEOGRIP®
soft feel/matting/anti-slip additives.
© All materials copyrighted 2012, King Industries, Inc., Norwalk, CT, USA
Solutions Through
Chemistry
Since 1932
KING FACILITIES
USA
World Headquarters
King Industries, Inc.
Science Road
Norwalk, CT 06852
Phone: 203-866-5551
Fax: 203-866-1268
E-mail: coatings@kingindustries.com
EUROPE
Technical Sales Office
King Industries International, Inc.
Noordkade 64
2741 EZ Waddinxveen
The Netherlands
Phone: +31 182-631360
Fax: +31 182-621002
E-mail: mg@kingintl.nl
ASIA/PACIFIC
Technical Service Lab
Dr. Zhiqiang He
Synlico Tech (Zhongshan) Co., Ltd.
106 Chuangye Building, Kang Le Ave.
Torch Development Zone,
Zhongshan, China
Phone: +760-88229866
Fax: +760-88229896
E-mail: alex.he@kingindustries.com

NACURE®
&K-CURE®
ACID&BLOCKEDACIDCATALYSTS
NACURE®
& K-CURE®
Acid & Blocked Acid Catalysts
Catalyst By Acid Type
Acid
Type
Acid
Catalysts
Blocked
Catalysts
NACURE 155 NACURE 3327
NACURE 3525
NACURE X49-110
NACURE 1051 NACURE 1323
NACURE 1419
NACURE 1492
NACURE 1557
NACURE 1953
NACURE 5076 NACURE 5225
NACURE 5414
NACURE 5528
NACURE 5925
K-CURE 1040
K-CURE 1040W
NACURE 4000
NACURE 4054
NACURE XC-235
NACURE 4167
NACURE 4575
NACURE 2107
NACURE 2500
NACURE 2501
NACURE 2522
NACURE 2530
NACURE 2547
K-CURE 129B NACURE 8924
NACURE XC-194K
SO3H
C9H19HO3S
H19C9
DNNDSA
Dinonylnaphthalene
Disulfonic Acid
DNNSA
Dinonylnaphthalene
Sulfonic Acid
C9H19
SO3H
H19C9
DDBSA
Dodecylbenzene
Sulfonic Acid
SO3H
C12H25
p-TSA
p-Toluene
Sulfonic Acid
CH3
SO3H
Phosphates
AAP/PAP
Alkyl Acid Phosphates
Phenyl Acid Phosphates
Today’s need for
high solids and
waterborne
coatings requires
greater use of high
reactivity, low
viscosity resins
and crosslinkers.
Conversion of
these systems into
tough, chemically
resistant, high
performance coat-
ings at reduced cure temperatures can be accomplished
with the use of a catalyst.
Acrylics, alkyds, epoxies and polyesters with reactive
functional groups, such as hydroxyl carbamate, siloxane
or amide can be reacted with melamine, urea and ben-
zoguanamine crosslinkers. The proper use of catalysts
can facilitate the crosslinking reaction resulting in the
following benefits:
 Shorter cure schedules
 Lower cure temperatures for thermoset high
solids and waterborne coatings
 Energy savings
 Improved hardness, gloss, humidity and
corrosion resistance
 Improved mechanical properties
King Industries continues to develop catalysts to meet
the ever expanding needs of a rapidly changing market.
Free Acid Or Latent Catalyst?
While acid catalysts provide the fastest cure and lower
curing temperatures, blocked or latent catalysts are
typically chosen for systems requiring greater package
stability. In addition, troublesome catalyst-pigment
interaction can be reduced or eliminated with the use
of blocked catalysts.
As can be seen in the table which follows, King’s
catalyst line is based upon a variety of acids. The
middle column denotes the free acid versions while the
far right column shows amine blocked or covalently
bonded derivatives for applications requiring extended
package stability.
E
Energy
Required
Without
Catalyst
ECAT
Energy Required
With Catalyst
Why Use Catalysts?
Other & Mixed
Acids

NACURE®
&K-CURE®
ACID&BLOCKEDACIDCATALYSTS
The chemical structure of the catalyst, as well as the
quantity used, can have a profound impact on film prop-
erties such as adhesion, corrosion resistance, flexibility
and impact resistance. These observations are appar-
ent not only among varying acid types but also among
different products within the same chemical family.
The type of crosslinker used will also affect the choice of
catalyst. High solids and waterborne coatings are typi-
cally formulated with monomeric crosslinkers such as
hexa(methoxymethyl)melamine (HMMM) or mixed ether
melamine; reaction of these crosslinkers with hydroxy
or carbamate functional groups is best achieved with
strong acid catalysts like DNNDSA or p-TSA.
More reactive crosslinkers, which are more polymeric
but contain high levels of -NH groups, respond better to
a weaker acid such as acid phosphates or low dosages
of amine blocked sulfonic acids.
The table to the right, matches the type of crosslinking
agent and the acid catalyst most suitable for each class.
King offers a broad selection of catalysts to satisfy
Product Offerings
Crosslinking Agent General
Acid
Category
Acid
Types
Fully alkylated
monomeric M/F resins:
Fully methylated
Fully butylated
Mixed ethers
Urea formaldehyde res-
ins
Benzoguanamine resins
Glycoluril resins
Strong Acids
pKa<1
P-TSA
DNNDSA
DDBSA
DNNSA
Highly alkylated, high
imino M/F resins
Partially alkylated
polymeric M/F resins
Weak Acids
pKa 1-3
Phosphates
Metal Salts
Carboxylic
Acid
RELATIVE ACID STRENGTH:
p-TSA>DNNDSA>DDBSA>DNNSA>Phosphates>Carboxylates
almost every possible curing parameter. Relative
cure profiles for NACURE Blocked Catalysts are
shown below.
Pages 3 & 4
Relative Cure Profiles for NACURE Blocked Catalysts
for Amino Crosslinked Systems
N-8924
N-2530
N-2500
N-2558
N-2107
N-3327
X49-110
N-5225
N-3525
N-5925
N-4575
N-5414
N-4167
N-1323 N-1953
N-1419
N-2547
N-5528
0
5
10
15
20
25
30
35
85 90 95 100 105 110 115 120 125 130 135 140 145 150 155 160 165 170 175
Cure Temperature,
o
C
CureTime,Minutes
Coil conditions up to 220C
N-1323, N-1953, N-1419, N-1557
Cure Profiles - Blocked Catalysts

NACURE®
&K-CURE®
ACID&BLOCKEDACIDCATALYSTS
Metal Substrates
Solventborne Waterborne Can
NACURE
3525
Adhesion &
Stability
Solventborne
NACURE
X49-110
Package
Stability
NACURE
2107
Textured
Finish
Waterborne Solventborne Waterborne WaterborneSolventborne
General IndustrialCoil, Appliance
TopcoatsPrimers
NACURE
3525
Solubility
NACURE
1051
Corrosion
Resistance
NACURE
3525 &
X49-110
Package
Stability
NACURE
5925*
Package
Stability
NACURE
155
Moisture
Resistance
NACURE
2500
Best Overall
NACURE
155
Moisture
Resistance
NACURE
1323
High
Temperatures
NACURE
1419
Best Overall
NACURE
155
Best Overall
NACURE
5076*
Best Overall
NACURE
2500
Best Overall
NACURE
2500
Best Overall
NACURE
2547
Best Overall
NACURE
2558
Blister
Resistance
NACURE
3525
Adhesion
NACURE
3525
Adhesion
NACURE
X49-110 &
3525
Adhesion
NACURE
2500
Rapid Cure
* Complaint FDA 21 CFR, Sec. 175.300 (b) (3) xii & Xiii (a&b)
NACURE
1051
Best Overall
NACURE
X49-110
Package
Stability
NACURE
1323 & 1953
High Bake
Systems
NACURE
1419
Corrosion
Resistance
Catalyst Selection Chart by Application
PRODUCT SELECTION: The application charts that follow can be used to arrive at good starting point product recom-
mendations based upon King’ s decades of experience in catalysis. However, we strongly recommend given the
complexity of the selection process and the subtle nuances of each individual product that you take advantage of our
Technical Service Department who will be more than happy to assist you. They can be quickly reached either by email:
coatings@kingindustries.com or phone: (203) 866-5551 for assistance.
DNNDSA (7) DNNSA (8) DDBSA & OTHER (9) p-TSA (10KEY TO CATALYST TYPE - (PAGE #)