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Particles that substances are
          made up of
Atoms
         Basic building blocks
                    of matter.
                      Element
         Mono-atomic elements
       Metals – giant structures
           Diatomic molecules
  Diatomic molecular elements
Polyatomic molecular elements
Compounds
Two or more atoms of different elements:

                     Molecular compound
             Covalent network structures
                         Ionic compounds
                       Metallic structure

                       Fixed proportions
                      Electrically neutral
Investigating elements and
        compounds
Hydrogen gas
Carbon dioxide gas
Dehydration of copper sulfate
Dehydration of copper sulfate
Electrolysis of water
Representation of elements and compounds

   Molecular formula of a compound
  H2O – actual number and type of atoms
             in the molecule.
   Empirical formula of a compound

      NaCl – the simplest formula.
  Strucutural formula of a compound
O = C = O – shows arrangement between
          atoms in a compound.
Diagrams of elements and compounds
Covalent structures




Electrons shared.
Non-metals.
Form molecules.
Covalent molecular solids


Solids = molecules
  that are bonded in a
  molecular lattice.
Low boiling and
  melting points.
  Often sublimates.
Covalent network structure

When bonds extend throughout the
 structure of the substance to form a giant
 covalent network.
These solids are very stable and have high
 melting and boiling points.
Diamond and graphite are two allotropes of
 carbon. Allotropes are when the same
 element occur in different crystal forms.
Diamond

Colourless transparent crystal.
Hard – strong covalent bonds (4)
Very high M.P. and B.P.
Cannot conduct electricity – no free e- or
 ions.
Graphite

Soft/slippery – form layers held together
 by weak intermolecular forces.
Conduct electricity due to one free e-.
Silica compound

Every silicon atom bonds covalently to four
 oxygen atoms.
Boron compounds

BN share properties similar to graphite and
 diamond, depending on its molecular
 structure.
Uses of diamond, graphite and
             silica
SUBSTANCE   PROPERTIES                 USES
DIAMOND     Hardest known substance In tools to cut and drill
            Very high M.P. and B.P.    Precious stones
            Does not conduct           Jewellery
            electricity
GRAPHITE    Soft and slippery          Lubricants for engines
                                       and locks
            High M.P. and B.P.         Lead of pencils
            Conducts electricity       Electrodes and
                                       connectors in generators
SILICA      Hard, used to sand         On sand paper
            objects
            High M.P. And B.P.         Make glass and lenses
            Does not conduct           In bricks to line furnace
            electricity                ovens.
Properties of covalent
            compounds

    Low melting and boiling points due to weak
                 intermolecular forces.
 Covalent network structures have very high M.P.
and B.P due to the strong covalent bonds between
                        atoms.
    Covalent structures are poor conductors of
 electricity and heat – they are insulators because
              they have no free electrons.
Ionic structures




Electrons transferred
Metal and non-metals
Forms crystal lattice
Complete the ion and metal
          stuff
Chemical bond


                                                         Ionic
              Covalent
                                        Strong electrostatic forces between ions
Forces between atoms inside of
                                        are broken. Requires large amounts of
molecules are broken
                                        energy to break.



    Rearrange atoms/molecules.                     Rearrange ions.


                            Energy is released


         New bond, new                              New bond, new
         substance                                  substance


Only reversible in certain circumstances.

                                                             www.docscientia.co.za
Physical and chemical change
Physical change


         Composition does not change.

Properties – appearance, form and state changes.

  A physical change is a change where no new
chemical compounds are formed. The state may
       change, but the identity does not.
Physical


              Arrangement

              Reversibility

Conservation of mass, atoms and molecules

             Energy involved
Melting                 Evaporation
Absorbs energy             Absorbs energy




Releases energy             Releases energy

 Solidification
             Sublimation

Arrangement of particles
          www.docscientia.co.za
Physical



     Reversibility

Generally easily reversed
Physical


 Conservation of mass, atoms, and molecules

Matter cannot created or destroyed, only changed.
 Therefore mass stays the same after a physical
   change, as does the amount of atoms and
                   molecules.
Physical changes


               Energy involved

  Physical changes can be caused by small
               energy changes.
Only intermolecular forces break during physical
                    changes.
Chemical changes


 Arrangement of the particles

Atoms, molecules or ions regroup.

     Decomposition reaction
       Synthesis reaction
Chemical changes



                 Reversible

A few are reversible, but most are difficult to
                  reverse.
Chemical changes



Conservation of mass, atoms and molecules

    The quantity of a specific subsance can
change, but total amount of atoms stay the same.
Chemical changes


               Energy involved

Absorbed or released during chemical reactions.
         Much more energy involved.
 Intramolecular forces have to be broken and
                   re-formed.
Decompostion and synthesis
       reactions
Decompostion reactions




       AB → A + B
Decompostion reactions
Synthesis reactions




     A + B → AB
Synthesis reactions
Energy changes in chemical
         reactions


Total energy absorbed to break bonds are less
 than the energy required to form new bonds.
     Heat is given off to the environment.

         EXOTHERMIC REACTION
Energy changes in chemical
        reactions
Energy changes in chemical
         reactions


Total energy absorbed to break bonds are more
 than the energy released to form new bonds.
    Heat is absorbed from the environment.

         ENDOTHERMIC REACTION
Total energy           Total energy released
 Energy transferred
                            absorbed to break        when new bonds form
                                  bonds


Product:          warmer –=exothermic reaction           -
                  colder – endothermic reaction
                                 Chemical reaction

           Exothermic                                         Endothermic
            reaction                                            reaction


To calculate the 'energy required', you need the following:
• Amount of Ep that is necessary to break bonds, as well as
• Amount of Ep that is released after bonds form.
 
Energy values shown as kJ⋅mol-1.




                                                                www.docscientia.co.za
Conservation of atoms and
          mass
Law of conservation of mass


Laviosier: Matter cannot be created or destroyed.
         Reactant mass = Product mass
 
During a chemical reaction or a physical change the sum of the reactants are
 
equal to the sum of the mass of the products.
 


Atoms in reactants    = Atoms in products
Amount of atoms (reactants) = Amounts of atoms
  (products)
Mass before      = Mass after
 

Consider the following balanced equation:
                                                →
             2SO2
      2(32 + 16 + 16)
                              +     O2
                              + (16 + 16)
                                                          2SO3
                                                → 2(32 + 16 + 16 + 16)

Ar    128                      + 32             → 160
      Voor:                     160             = Na: 160

                                                            www.docscientia.co.za
Law of conservation of atoms but non-
conservation of molecule in a chemical reaction




During a chemical reaction the number of atoms of
            each element stays intact.
Law of constant composition
Balanced equation:
Everyting in front of the arrow, is still to be found at the back of the
         arrow.
Left side has the same amount of matter as the right side.

 A specific chemical reaction always has the same elements in the same ratios.


Any amount:
•        Carbon dioxide: carbon and oxygen contains 1 C for every 2 O's.
•        Ammonia: nitrogen and hydrogen contains 1 N for every 3 H’s.
•        Dinitrogen tetraoxide: nitrogen and oxygen contains 2 N's for
         every 4 O's.
Multiple compounds are sometimes possible:
For example: :         H2O en H2O2
                        CO en CO2



                                                              www.docscientia.co.za
A specific amount of particles of any gas occupies the
same volume at a fixed temperature and pressure.


                2SO2(g) + O2(g) → 2SO3(g)



       2SO2          +        O2        →         2SO3
2 particles SO2      + 1 particle O2    → 2 particle SO3
2 volume-units SO2   + 1 volume-units   → 2 volume-units
                       O2                 SO3
2 dm3 SO2            + 1 dm3 O2         → 2 dm3 SO3
2 cm3 SO2            + 1 cm3 O2         → 2 cm3 SO3
6 cm3 SO2            + 3 cm3 O2         → 6 cm3 SO3



                                              www.docscientia.co.za
Balancing of equations
Balancing of equations
Calculating mass
          So, we have learned that:
Mass stays the same before and after a
chemical reaction.
The amount of atoms on the left hand side is
the same as the amount of atoms on the
right hand side – they are simply arranged
differently.
All of this led us to balance our chemical
equations.
Calculating mass


  The balanced equations show us that:
Mass stays the same on the left ans right.
The volumes of gas reactants are the same as
the balanced equations.
All of these facts can help us calculate the
actual mass of the reactants.
Calculating mass

          So, we can say that:

Mass of reactants and products can be
calculated.
Volume of gas reactions can be calculated.
Actual mass of reactants or products can be
calculated.
Calculating mass –               proving the
        law of conservation of mass

        Step 1: Balanced equation
 Pb(NO3)2(aq) + 2NaI(ag) → PbI2 + 2NaNO3(aq)
         Step 2: Relative mass
               REACTANTS
 Mr[Pb(NO3)2] = 207 + 2(14 + (16·3)) = 331
          Mr(NaI) = 23 + 127 = 150
                PRODUCTS
       Mr(PbI2) = 207 + (2·127) = 461
     Mr(NaNO3) = 23 + 14 + (3·16) = 85
Calculating mass –                proving the
         law of conservation of mass




Step 3: Determine total mass before and after
 Pb(NO3)2(aq) + 2NaI(ag) → PbI2 + 2NaNO3(aq)
   331      + 150     →    461 + 85
           631        →    631
Calculating mass –                                 Using the law of
 conservation of mass to determine the actual mass of substances.




                QUESTION:
Determine the mass of oxygen that is released
When 29,4 g potassium chlorate is heated and
 Completely decomposed into potassium and
                 Oxygen.

  Step 1: What is asked, and what is given?
           29,4 g KClO3 → ? g O2
Calculating mass –                                Using the law of
conservation of mass to determine the actual mass of substances.




            Step 2: Balanced equation
              2KClO3 → 2KCl + 3O2

Step 3: Relative mass of substances in step 1
2[39 + 35,5 + (3·16) →         3(2·16)
               245    →        96
Calculating mass –                                Using the law of
conservation of mass to determine the actual mass of substances.


Step 4: Use ratios to caculate the mass of O2
                245 g KClO3 : 96 g O2
         245 g/245 KClO3 : 96 g/245 O2
              Which is the same as...
              1 g KClO3 : 96/245 g O2
              So, we can say that
       29,4 g KClO3 : (29,4·96)/245 g O2
                      = 11,52 g O2
        A mass of 11,52 g O2 is formed.
Calculating mass                               – Using the law of
   conservation of mass to determine the actual mass of subst ances.




                          QUESTION:

Determine what mass of sodium will fully react with
        chlorine to form 25 g of table salt.
Calculating mass                               – Using the law of
conservation of mass to determine the actual mass of subst ances.




              BALANCED EQUATION:
                2Na + Cl2 → 2NaCl

               WHAT DO WE HAVE?
               Na - ?  25 g NaCl

            RELATIVE MOLAR MASS
           Na – 46  :   NaCl – 117
Calculating mass                               – Using the law of
conservation of mass to determine the actual mass of subst ances.




           Na – 46   :     NaCl – 117
              46 g Na : 117 g NaCl

               46/117 g Na : 1 g NaCl

            25·46/117 g Na : 25 g NaCl

          9,83 g Na will yield 25 g NaCl.
Calculating volume

Calculate the volume of nitrogen oxide that forms,
    should 3 dm3 nitrogen react with oxygen.

           Step 1: Balanced equation
                N2 + O2 → 2NO

   Step 2: substitute particles for volume units
       1 dm3 N2 + 1 dm3 O2 → 2 dm3 NO
Calculating volume

Calculate the volume of nitrogen oxide that forms,
    should 3 dm3 nitrogen react with oxygen.

           Step 1: Balanced equation
                N2 + O2 → 2NO

   Step 2: substitute particles for volume units
       1 dm3 N2 + 1 dm3 O2 → 2 dm3 NO

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Matter and materials (II) Paticles that substances are made up of

  • 1. Particles that substances are made up of
  • 2. Atoms Basic building blocks of matter. Element Mono-atomic elements Metals – giant structures Diatomic molecules Diatomic molecular elements Polyatomic molecular elements
  • 3. Compounds Two or more atoms of different elements: Molecular compound Covalent network structures Ionic compounds Metallic structure Fixed proportions Electrically neutral
  • 10. Representation of elements and compounds Molecular formula of a compound H2O – actual number and type of atoms in the molecule. Empirical formula of a compound NaCl – the simplest formula. Strucutural formula of a compound O = C = O – shows arrangement between atoms in a compound.
  • 11. Diagrams of elements and compounds
  • 13. Covalent molecular solids Solids = molecules that are bonded in a molecular lattice. Low boiling and melting points. Often sublimates.
  • 14. Covalent network structure When bonds extend throughout the structure of the substance to form a giant covalent network. These solids are very stable and have high melting and boiling points. Diamond and graphite are two allotropes of carbon. Allotropes are when the same element occur in different crystal forms.
  • 15. Diamond Colourless transparent crystal. Hard – strong covalent bonds (4) Very high M.P. and B.P. Cannot conduct electricity – no free e- or ions.
  • 16. Graphite Soft/slippery – form layers held together by weak intermolecular forces. Conduct electricity due to one free e-.
  • 17. Silica compound Every silicon atom bonds covalently to four oxygen atoms.
  • 18. Boron compounds BN share properties similar to graphite and diamond, depending on its molecular structure.
  • 19. Uses of diamond, graphite and silica SUBSTANCE PROPERTIES USES DIAMOND Hardest known substance In tools to cut and drill Very high M.P. and B.P. Precious stones Does not conduct Jewellery electricity GRAPHITE Soft and slippery Lubricants for engines and locks High M.P. and B.P. Lead of pencils Conducts electricity Electrodes and connectors in generators SILICA Hard, used to sand On sand paper objects High M.P. And B.P. Make glass and lenses Does not conduct In bricks to line furnace electricity ovens.
  • 20. Properties of covalent compounds Low melting and boiling points due to weak intermolecular forces. Covalent network structures have very high M.P. and B.P due to the strong covalent bonds between atoms. Covalent structures are poor conductors of electricity and heat – they are insulators because they have no free electrons.
  • 21. Ionic structures Electrons transferred Metal and non-metals Forms crystal lattice
  • 22. Complete the ion and metal stuff
  • 23. Chemical bond Ionic Covalent Strong electrostatic forces between ions Forces between atoms inside of are broken. Requires large amounts of molecules are broken energy to break. Rearrange atoms/molecules. Rearrange ions. Energy is released New bond, new New bond, new substance substance Only reversible in certain circumstances. www.docscientia.co.za
  • 25. Physical change Composition does not change. Properties – appearance, form and state changes. A physical change is a change where no new chemical compounds are formed. The state may change, but the identity does not.
  • 26. Physical Arrangement Reversibility Conservation of mass, atoms and molecules Energy involved
  • 27. Melting Evaporation Absorbs energy Absorbs energy Releases energy Releases energy Solidification Sublimation Arrangement of particles www.docscientia.co.za
  • 28. Physical Reversibility Generally easily reversed
  • 29. Physical Conservation of mass, atoms, and molecules Matter cannot created or destroyed, only changed. Therefore mass stays the same after a physical change, as does the amount of atoms and molecules.
  • 30. Physical changes Energy involved Physical changes can be caused by small energy changes. Only intermolecular forces break during physical changes.
  • 31. Chemical changes Arrangement of the particles Atoms, molecules or ions regroup. Decomposition reaction Synthesis reaction
  • 32. Chemical changes Reversible A few are reversible, but most are difficult to reverse.
  • 33. Chemical changes Conservation of mass, atoms and molecules The quantity of a specific subsance can change, but total amount of atoms stay the same.
  • 34. Chemical changes Energy involved Absorbed or released during chemical reactions. Much more energy involved. Intramolecular forces have to be broken and re-formed.
  • 36. Decompostion reactions AB → A + B
  • 38. Synthesis reactions A + B → AB
  • 40. Energy changes in chemical reactions Total energy absorbed to break bonds are less than the energy required to form new bonds. Heat is given off to the environment. EXOTHERMIC REACTION
  • 41. Energy changes in chemical reactions
  • 42. Energy changes in chemical reactions Total energy absorbed to break bonds are more than the energy released to form new bonds. Heat is absorbed from the environment. ENDOTHERMIC REACTION
  • 43. Total energy Total energy released Energy transferred absorbed to break when new bonds form bonds Product: warmer –=exothermic reaction - colder – endothermic reaction Chemical reaction Exothermic Endothermic reaction reaction To calculate the 'energy required', you need the following: • Amount of Ep that is necessary to break bonds, as well as • Amount of Ep that is released after bonds form.   Energy values shown as kJ⋅mol-1. www.docscientia.co.za
  • 45. Law of conservation of mass Laviosier: Matter cannot be created or destroyed. Reactant mass = Product mass
  • 46.   During a chemical reaction or a physical change the sum of the reactants are   equal to the sum of the mass of the products.   Atoms in reactants = Atoms in products Amount of atoms (reactants) = Amounts of atoms (products) Mass before = Mass after   Consider the following balanced equation: →   2SO2 2(32 + 16 + 16) + O2 + (16 + 16) 2SO3 → 2(32 + 16 + 16 + 16) Ar 128 + 32 → 160 Voor:   160 = Na: 160 www.docscientia.co.za
  • 47. Law of conservation of atoms but non- conservation of molecule in a chemical reaction During a chemical reaction the number of atoms of each element stays intact.
  • 48. Law of constant composition Balanced equation: Everyting in front of the arrow, is still to be found at the back of the arrow. Left side has the same amount of matter as the right side. A specific chemical reaction always has the same elements in the same ratios. Any amount: • Carbon dioxide: carbon and oxygen contains 1 C for every 2 O's. • Ammonia: nitrogen and hydrogen contains 1 N for every 3 H’s. • Dinitrogen tetraoxide: nitrogen and oxygen contains 2 N's for every 4 O's. Multiple compounds are sometimes possible: For example: : H2O en H2O2 CO en CO2 www.docscientia.co.za
  • 49. A specific amount of particles of any gas occupies the same volume at a fixed temperature and pressure. 2SO2(g) + O2(g) → 2SO3(g) 2SO2 + O2 → 2SO3 2 particles SO2 + 1 particle O2 → 2 particle SO3 2 volume-units SO2 + 1 volume-units → 2 volume-units O2 SO3 2 dm3 SO2 + 1 dm3 O2 → 2 dm3 SO3 2 cm3 SO2 + 1 cm3 O2 → 2 cm3 SO3 6 cm3 SO2 + 3 cm3 O2 → 6 cm3 SO3 www.docscientia.co.za
  • 52. Calculating mass So, we have learned that: Mass stays the same before and after a chemical reaction. The amount of atoms on the left hand side is the same as the amount of atoms on the right hand side – they are simply arranged differently. All of this led us to balance our chemical equations.
  • 53. Calculating mass The balanced equations show us that: Mass stays the same on the left ans right. The volumes of gas reactants are the same as the balanced equations. All of these facts can help us calculate the actual mass of the reactants.
  • 54. Calculating mass So, we can say that: Mass of reactants and products can be calculated. Volume of gas reactions can be calculated. Actual mass of reactants or products can be calculated.
  • 55. Calculating mass – proving the law of conservation of mass Step 1: Balanced equation Pb(NO3)2(aq) + 2NaI(ag) → PbI2 + 2NaNO3(aq) Step 2: Relative mass REACTANTS Mr[Pb(NO3)2] = 207 + 2(14 + (16·3)) = 331 Mr(NaI) = 23 + 127 = 150 PRODUCTS Mr(PbI2) = 207 + (2·127) = 461 Mr(NaNO3) = 23 + 14 + (3·16) = 85
  • 56. Calculating mass – proving the law of conservation of mass Step 3: Determine total mass before and after Pb(NO3)2(aq) + 2NaI(ag) → PbI2 + 2NaNO3(aq) 331 + 150 → 461 + 85 631 → 631
  • 57. Calculating mass – Using the law of conservation of mass to determine the actual mass of substances. QUESTION: Determine the mass of oxygen that is released When 29,4 g potassium chlorate is heated and Completely decomposed into potassium and Oxygen. Step 1: What is asked, and what is given? 29,4 g KClO3 → ? g O2
  • 58. Calculating mass – Using the law of conservation of mass to determine the actual mass of substances. Step 2: Balanced equation 2KClO3 → 2KCl + 3O2 Step 3: Relative mass of substances in step 1 2[39 + 35,5 + (3·16) → 3(2·16) 245 → 96
  • 59. Calculating mass – Using the law of conservation of mass to determine the actual mass of substances. Step 4: Use ratios to caculate the mass of O2 245 g KClO3 : 96 g O2 245 g/245 KClO3 : 96 g/245 O2 Which is the same as... 1 g KClO3 : 96/245 g O2 So, we can say that 29,4 g KClO3 : (29,4·96)/245 g O2 = 11,52 g O2 A mass of 11,52 g O2 is formed.
  • 60. Calculating mass – Using the law of conservation of mass to determine the actual mass of subst ances. QUESTION: Determine what mass of sodium will fully react with chlorine to form 25 g of table salt.
  • 61. Calculating mass – Using the law of conservation of mass to determine the actual mass of subst ances. BALANCED EQUATION: 2Na + Cl2 → 2NaCl WHAT DO WE HAVE? Na - ? 25 g NaCl RELATIVE MOLAR MASS Na – 46 : NaCl – 117
  • 62. Calculating mass – Using the law of conservation of mass to determine the actual mass of subst ances. Na – 46 : NaCl – 117 46 g Na : 117 g NaCl 46/117 g Na : 1 g NaCl 25·46/117 g Na : 25 g NaCl 9,83 g Na will yield 25 g NaCl.
  • 63. Calculating volume Calculate the volume of nitrogen oxide that forms, should 3 dm3 nitrogen react with oxygen. Step 1: Balanced equation N2 + O2 → 2NO Step 2: substitute particles for volume units 1 dm3 N2 + 1 dm3 O2 → 2 dm3 NO
  • 64. Calculating volume Calculate the volume of nitrogen oxide that forms, should 3 dm3 nitrogen react with oxygen. Step 1: Balanced equation N2 + O2 → 2NO Step 2: substitute particles for volume units 1 dm3 N2 + 1 dm3 O2 → 2 dm3 NO