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Managing Livestock Ammonia: A
Volatile, Promiscuous, Fugitive in
the Atmosphere?
Jay Ham
Department of Soil and Crop Sciences
Colorado State University
Acknowledgements
 Christina Williams, Joshua
Stratton, Kira Shonkwiler
 Co-PIs and Funding
Agencies
 CSU Department of
Atmospheric Science
 Members of RMNP Agric.
Subcommittee
 Cooperators and Industry
Partners
Outline
 The Global Nitrogen Cycle
 Regional Ammonia
– N deposition in Rocky
Mountain National Park
– What is the contribution from
Livestock ?
 Farm Scale Solutions
– Measurement, Models, &
BMPs
Part 1: The Global Nitrogen Cycle
and Livestock Production
―a small leak will sink
a great ship‖
- Benjamin Franklin
A safe operating space for humanity
Rockström et al. 2009. Nature, 461, 472-475
Galloway et al. 2008. Science, 320,
www.ted.com/talks/johan_rockstrom_let_the_environment_guide_our_development.html
Nitrogen !
Erisman et al., 2008. Nature Geoscience
―Globally around 80% of
harvested nitrogen and
phosphorus is consumed
by livestock rather than
directly by people,
showing how global
nutrient supply and
pollution are dominated
by humans‘ choice to
consume animal
products.‖
Sutton et al., 2013.
United Nations Environment
Programme (UNEP)http://www.gpa.unep.org/gpnm
Sutton et al., 2013. United Nations Environment Programme
(UNEP)
Recommendations from
―Our Nutrient World‖
promotion of the ‗ demitarian ‘
option, which we define as a
meal containing half the
amount of meat or fish
compared with the normal
local amount …,
The Barsac Declaration
Demitarian
Global Nitrogen Fluxes and
Livestock Ammonia
Fluxes Tg N / yr
Nitrogen Fertilizer 120
Nitrogen Fixation 50-70
Crop and Grass Production 122
Crop and Grass for Livestock
Production
100 (81%)
NH3 Emissions from Soils 15
NH3 Emissions from Livestock 22 (59.5 %)
Total NH3 from Agriculture 37
Sutton et al., 2013. United Nations
Environment Programme (UNEP)
Got Beef ? Got Ammonia !
 Retention of fed
nitrogen in feedlot
cattle is typically 13%
 Most fed nitrogen is
excreted in the urine
and feces as urea
 Up to 50% of fed N
can be lost to the
atmosphere as NH3
Map Courtesy of
P.I. Coyne
9.5 million head * 0.31-0.37 lbs N excreted /day
= 2.7 to 3.5 million lbs N/day of excreted N
If 50% is lost to the atmosphere as NH3
1.4 to 1.7 million lbs. of ammonia/day
Satellite Data of NH3 OVER NORTH AMERICA (2009)
Data from Colette L. Heald, CSU
Part 2: Nitrogen deposition in
Rocky Mountain National Park
A "perfect storm" is an
expression that describes an event
where a rare combination of
circumstances will aggravate a
situation drastically
http://en.wikipedia.org/wiki/Perfect_storm
Rocky Mountain National Park
http://vista.cira.colostate.edu/improve/Education/education.htm
NH3SOx NOx
Emissions
Gas-Particle Partitioning (aerosol formation)
NH3
H2SO4
HNO3
NH4
+
SO4
2-
NO3
-
Deposition
Dry Wet
Transport
NH3
(Slide by Luke Schiferl)
http://vista.cira.colostate.edu/improve/Education/education.htm
Wet Deposition Sampling
Wet N Deposition in RMNP
Morris et al., 2012. Natural Resource Report NPS/NRSS/ARD/NRR—2012/562
http://vista.cira.colostate.edu/improve/Education/education.htm
Colorado Ammonia Sources
Rocky Mountain National Park Initiative ‐ Nitrogen Deposition Reduction
Contingency Plan. June 21, 2010
NE Colorado CAFO Map
Malm, W. C., Collett, Jr., J. L., et al. (2009) The Rocky Mountain Airborne Nitrogen and
Sulfur Study (RoMANS), final report to the National Park Service.
strategy taken for apportioning various
aerosol species concentrations and
deposition to source emissions is a
weight-of-evidence approach,
comparing and contrasting results from
multiple analyses.
Wet Nitrogen Deposition
Part 3: Measurements, Modeling,
and BMPs
―What gets measured gets managed ―
- Peter Drucker
CSU Livestock NH3 Research
 Measurement of NH3
Emissions and Regional
Conc. Patterns
 Development of
management BMPs
 Modeling and Software
Tools
 New Technology
Funding Sources:
USDA, EPA, NRCS, and NSF
Best Management Practices to Reduce
Livestock Ammonia Impacts
 Feed Management
 Change Manure Management
 Meteorological Warning
Systems
 NH3 Measurement
Technology
Blue – 13.5% CP
Red – Oscillating
Green – 11.6% CP
Effect of Reduced Crude Protein Diet
on Pen Surface NH3 Emissions
Diet
Galles K., Ham J., Westover E., Stratton J., Wagner J., Engle T., Bryant T.C.
2011. Influence of Reduced Nitrogen Diets on Ammonia Emissions from Cattle
Feedlot Pens. Atmosphere. 2(4):655-670.
New Measurement Technology
 Identification of NH3
―Hot Spots‖
 Tracking and Trend
Detection of NH3
emissions
 Information for Decision
Making
 Meeting future
regulatory requirements
Robotics for Managing Air Emissions of Ammonia at
Livestock Operations
Ham et al., 2012.National Robotics Initiative (NSF/USDA-NIFA)
Goal: Develop a robotic air-quality management system for dairies and
cattle feedlots that will help managers reduce ammonia emissions
Design new low-cost Laser for
real-time NH3 monitoring
Laser Det.
Sample Gas
Develop a wireless
NH3 sensor network
Design weather
forecast retrieval
system to predict NH3
emissions and
transport in advance.
Conditional Passive Samplers
Conditional Passive Samplers
``
Linear Actcuator
Acrylic Tube
Cap
Spacer
Vertical Adapter
Radiello Diffusive
Sampler
Foam
Acrylic Disc
Hall Effect Sensor
Control Cable
Spacer
Clevis
Clevis
Plunger
Magnet
Hall Effect Cable
Arduino
Northern Colorado Dairy
Beef Feedlot NH3
Concentrations
http://sensemake.rs/portfolio-item/air-quality-egg/
http://aircasting.org/
http://aircasting.org/
http://www.guardian.co.uk/local-government-
network/2011/aug/18/internet-of-things-local-
government
http://www.economist.com/node/17388368
https://www.farmeron.com/
Conclusions
 Livestock NH3 is becoming
a dominant global and
regional environmental
issue – and linkages
between N pollution,
livestock, and food choice
will gain more attention
over time.
Contact Information: jay.ham@colostate.edu; 970-491-4112
Conclusions
 The Front Range of
Colorado and RMNP has
emerged as a test case for
how science, policy, and
cooperation among
stakeholders can address a
regional NH3 issue.
Contact Information: jay.ham@colostate.edu; 970-491-4112
Conclusions
 New measurement
technologies, IoT, and
M2M communications will
likely greatly help livestock
managers reducer NH3
losses.
Contact Information: jay.ham@colostate.edu; 970-491-4112
Questions ?
Contact Information: jay.ham@colostate.edu; 970-491-4112

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Managing Livestock Ammonia: A Volatile, Promiscuous Fugitive in the Atmosphere

  • 1. Managing Livestock Ammonia: A Volatile, Promiscuous, Fugitive in the Atmosphere? Jay Ham Department of Soil and Crop Sciences Colorado State University
  • 2. Acknowledgements  Christina Williams, Joshua Stratton, Kira Shonkwiler  Co-PIs and Funding Agencies  CSU Department of Atmospheric Science  Members of RMNP Agric. Subcommittee  Cooperators and Industry Partners
  • 3. Outline  The Global Nitrogen Cycle  Regional Ammonia – N deposition in Rocky Mountain National Park – What is the contribution from Livestock ?  Farm Scale Solutions – Measurement, Models, & BMPs
  • 4. Part 1: The Global Nitrogen Cycle and Livestock Production ―a small leak will sink a great ship‖ - Benjamin Franklin
  • 5. A safe operating space for humanity Rockström et al. 2009. Nature, 461, 472-475 Galloway et al. 2008. Science, 320, www.ted.com/talks/johan_rockstrom_let_the_environment_guide_our_development.html Nitrogen !
  • 6. Erisman et al., 2008. Nature Geoscience
  • 7. ―Globally around 80% of harvested nitrogen and phosphorus is consumed by livestock rather than directly by people, showing how global nutrient supply and pollution are dominated by humans‘ choice to consume animal products.‖ Sutton et al., 2013. United Nations Environment Programme (UNEP)http://www.gpa.unep.org/gpnm
  • 8. Sutton et al., 2013. United Nations Environment Programme (UNEP) Recommendations from ―Our Nutrient World‖
  • 9. promotion of the ‗ demitarian ‘ option, which we define as a meal containing half the amount of meat or fish compared with the normal local amount …, The Barsac Declaration Demitarian
  • 10. Global Nitrogen Fluxes and Livestock Ammonia Fluxes Tg N / yr Nitrogen Fertilizer 120 Nitrogen Fixation 50-70 Crop and Grass Production 122 Crop and Grass for Livestock Production 100 (81%) NH3 Emissions from Soils 15 NH3 Emissions from Livestock 22 (59.5 %) Total NH3 from Agriculture 37 Sutton et al., 2013. United Nations Environment Programme (UNEP)
  • 11. Got Beef ? Got Ammonia !  Retention of fed nitrogen in feedlot cattle is typically 13%  Most fed nitrogen is excreted in the urine and feces as urea  Up to 50% of fed N can be lost to the atmosphere as NH3
  • 12. Map Courtesy of P.I. Coyne 9.5 million head * 0.31-0.37 lbs N excreted /day = 2.7 to 3.5 million lbs N/day of excreted N If 50% is lost to the atmosphere as NH3 1.4 to 1.7 million lbs. of ammonia/day
  • 13. Satellite Data of NH3 OVER NORTH AMERICA (2009) Data from Colette L. Heald, CSU
  • 14. Part 2: Nitrogen deposition in Rocky Mountain National Park A "perfect storm" is an expression that describes an event where a rare combination of circumstances will aggravate a situation drastically http://en.wikipedia.org/wiki/Perfect_storm
  • 15.
  • 18. NH3SOx NOx Emissions Gas-Particle Partitioning (aerosol formation) NH3 H2SO4 HNO3 NH4 + SO4 2- NO3 - Deposition Dry Wet Transport NH3 (Slide by Luke Schiferl)
  • 21. Wet N Deposition in RMNP Morris et al., 2012. Natural Resource Report NPS/NRSS/ARD/NRR—2012/562
  • 23. Colorado Ammonia Sources Rocky Mountain National Park Initiative ‐ Nitrogen Deposition Reduction Contingency Plan. June 21, 2010
  • 25. Malm, W. C., Collett, Jr., J. L., et al. (2009) The Rocky Mountain Airborne Nitrogen and Sulfur Study (RoMANS), final report to the National Park Service. strategy taken for apportioning various aerosol species concentrations and deposition to source emissions is a weight-of-evidence approach, comparing and contrasting results from multiple analyses.
  • 27. Part 3: Measurements, Modeling, and BMPs ―What gets measured gets managed ― - Peter Drucker
  • 28. CSU Livestock NH3 Research  Measurement of NH3 Emissions and Regional Conc. Patterns  Development of management BMPs  Modeling and Software Tools  New Technology Funding Sources: USDA, EPA, NRCS, and NSF
  • 29. Best Management Practices to Reduce Livestock Ammonia Impacts  Feed Management  Change Manure Management  Meteorological Warning Systems  NH3 Measurement Technology
  • 30. Blue – 13.5% CP Red – Oscillating Green – 11.6% CP Effect of Reduced Crude Protein Diet on Pen Surface NH3 Emissions Diet Galles K., Ham J., Westover E., Stratton J., Wagner J., Engle T., Bryant T.C. 2011. Influence of Reduced Nitrogen Diets on Ammonia Emissions from Cattle Feedlot Pens. Atmosphere. 2(4):655-670.
  • 31. New Measurement Technology  Identification of NH3 ―Hot Spots‖  Tracking and Trend Detection of NH3 emissions  Information for Decision Making  Meeting future regulatory requirements
  • 32. Robotics for Managing Air Emissions of Ammonia at Livestock Operations Ham et al., 2012.National Robotics Initiative (NSF/USDA-NIFA) Goal: Develop a robotic air-quality management system for dairies and cattle feedlots that will help managers reduce ammonia emissions Design new low-cost Laser for real-time NH3 monitoring Laser Det. Sample Gas Develop a wireless NH3 sensor network Design weather forecast retrieval system to predict NH3 emissions and transport in advance.
  • 34. Conditional Passive Samplers `` Linear Actcuator Acrylic Tube Cap Spacer Vertical Adapter Radiello Diffusive Sampler Foam Acrylic Disc Hall Effect Sensor Control Cable Spacer Clevis Clevis Plunger Magnet Hall Effect Cable Arduino
  • 39. Conclusions  Livestock NH3 is becoming a dominant global and regional environmental issue – and linkages between N pollution, livestock, and food choice will gain more attention over time. Contact Information: jay.ham@colostate.edu; 970-491-4112
  • 40. Conclusions  The Front Range of Colorado and RMNP has emerged as a test case for how science, policy, and cooperation among stakeholders can address a regional NH3 issue. Contact Information: jay.ham@colostate.edu; 970-491-4112
  • 41. Conclusions  New measurement technologies, IoT, and M2M communications will likely greatly help livestock managers reducer NH3 losses. Contact Information: jay.ham@colostate.edu; 970-491-4112
  • 42. Questions ? Contact Information: jay.ham@colostate.edu; 970-491-4112

Notas del editor

  1. Although complicated, this system can be broken into 3 main processes: Emissions of SOx from power production, NH3 from catalytic conversion and NOx from fossil fuel combustion in urban areas and NH3 from agriculture in rural areas; the partitioning of oxidized versions of SOx and NOx in the forms of sulfuric acid and nitric acid during their reaction with NH3 into particle ion species, and the loss of these species through dry and wet deposition. This deposition can affect the nitrogen balance of ecosystems, causing degredation. and particles which are present at the surface can negatively affect human health. It is important to understand all three of these processes in order to understand the system as a whole.
  2. Over the next four years (2009-2012), Weld County is growing rapidly with a projected population increase in the state at 13.8%, which will result in increased NOx emissions and possibly decreasing ammonia emissions as farmland is converted to urban use.