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Waste Management
The overall objective of this module is
that participants will show awareness of
waste management and transportation
requirements
Overview
• General principles for safe
acceptance of household hazardous
and/or CESQG waste from the public,
which includes: receiving, sorting,
storing, marking/labeling, packing,
transporting, and final disposal of
waste
• Understand the DOT, CFR, and UN
transportation requirements
Expectations
• List the seven steps in the waste
management process
• List the main classes of hazardous
materials and how they should be
sorted and stored
• Identify the proper selection,
marking/labeling, and handling of
containers of hazardous waste
7 Steps in Waste
Management Process
• Collecting Wastes
• Sorting
• Storing
• Marking/Labeling
• Packing
• Transporting
• Final Disposal
Collecting Wastes
• Minimum standards
– Customer restrictions
– Waste restrictions
– Container restrictions
– Contents identified
– Compatibilities of waste
– Restricted areas
Collecting Wastes
• Guidelines
– Load Inspection
– Unloading
Collecting Wastes
• Inspection
– Visually inspect the containers before
removing to ensure integrity
– Note unusual circumstances such as large
volumes or items not likely to be household
waste
Collecting Wastes
• Identifying and Dealing with
Exceptions
– Commercial wastes
– Universal waste
– Waste oil drums and oil filters
– Open and leaking containers
– Unlabeled / unknown items
– Waste left outside of facility
– Waste from farms
Collecting Wastes
• Identifying and Dealing with
Exceptions
– Infectious waste
– Ammunition and explosives
– Bombs / Unknown Packages
– Critically unstable chemicals
– Asbestos
– Nonhazardous waste
Suspected Commercial
Wastes
• Brought in a commercial vehicle
• Large amounts of the same item
• Items not normally for residential use
• Product of a business; home
business
Collecting Wastes
• Universal Wastes
– Considerations for managing UW under
UWR standards
• Whether state has adopted UWR and
additional waste added to UW list
• Whether want to receive commercial UW
• What quantity of UW you will receive and
manage
Collecting Wastes
• Universal Wastes
– Batteries
– Mercury thermostats
– Pesticides
Collecting Wastes
• Waste Reuse/ Exchange
– Inspect containers for
integrity and contents
– No reuse
• Recalled, canceled or
suspended material
• Material in containers which
are damaged, rusted or
labels are unreadable
Sorting
• Preliminary sorting
• Waste oil
• Testing waste oil for contamination
• Flames test
• Commercial test kits
• Bulking waste oil
• Pumping waste oil from barrels
Sorting
• Preliminary Sorting
– Aerosols
– Antifreeze
– Car batteries
– Unknown waste
– Waste oil
– Testing waste oil for
contamination
– Flame test
– Commercial test kits
Classification Process
• Read the labels
• Clues
– Plastic or plastic-lined containers -used for acids or
bases
– Exotic metals - extremely dangerous
– Single-walled containers - inert gas surrounding
reactive, flammable or explosive material
– Seal - reactive chemical or one which can not be
exposed to air, water, or other chemicals
– Cohesive solid in a liquid - material reactive with air or
water
– “Forbidden” - No transportation unless has been
diluted, stabilized or incorporated into a device
Classification Process
• Color-coded labels and caps
– green - ammonium hydroxide
– brown - acetic acid
– red - nitric acid
– yellow - sulfuric acid
– blue - hydrochloric acid
– black - perchloric acid
Sorting
• Nine DOT hazard classes
– Explosives
– Gases
– Flammable liquids
– Flammable solids
– Oxidizers
– Poisons
– Radioactive
– Corrosives
– Class 9
Sorting
• Precedence of Hazard
– Radioactive
– Poisonous gases
– Flammable gases
– Nonflammable gases
– Poisonous liquids
– Pyrophoric material
– Self-reactive material
Sorting
– Class 3- Flammable liquids
– Class 8- Corrosive materials
– Division 4.1- Flammable solids
– Division 4.2- Spontaneously combustible
materials
– Division 4.3- Dangerous when wet materials
– Division 5.1- Oxidizers
– Division 6.1- Poisonous materials
– Combustible liquids
– Miscellaneous hazardous materials
Storing
• Proper labeling on storage
cabinet, containers
• Compatibilities
• Check reactivity within Hazard
Classes
Marking/Labeling
• Proper Shipping Name (PSN)
• Selecting a Package
• Drum Preparation
• Marking
• Labels
• State Hazardous Waste Stickers
• Drum ID Number
Proper Shipping Name (PSN)
• Priority for selection:
– Chemical Name, e.g., “Methyl Alcohol”
– Generic Name (Chemical Family), e.g.,
“Alcohol’s, n.o.s.”
– End Use of Material, e.g., “Paint Related
Materials”
– The n.o.s. End Use, e.g., “Dyes, Liquid, n.o.s.”
– DOT Class of Hazard, e.g., “Flammable
Liquids, n.o.s.”
Selecting a Package
• Package must meet design and
performance standards-
“performance-based packaging”
• Limited quantity (LMTD QTY)
Drum Preparation
• New or reconditioned and acceptable to DOT
• Empty
• Cover, securing ring and / or bung and gaskets
• Drums used for lab packs must be lined with a
6 ml polyethylene liner
• Drums with liquids inside containers must be
marked on two opposite vertical sides of the
package with the arrows pointing in the correct
upright direction
• Marked on 2 sides - This side up
Marking
• Proper shipping name
• ID number
• Address of the shipper or
recipient
• English
• Durable
• Of contrasting color with
background
• Away from other markings
• Easy to see
Labels
• Diamond shaped
• Indicate the hazard class and
division of a material
• Placed near proper shipping name
and ID#s
State Hazardous Waste
Stickers
• “Accumulation Start Date”
• “Hazard Class”
• “Hazardous Waste” - upper one-third
of the drum
• Labels on two sides (upper third) and
the top of the drum
Drum ID Number
• Assign a serial number
Packing
• Lab Pack
• Incompatible material
• Drum inventory
• Loose Pack
• Consolidation
Packing
• Lab pack
– Extensive training
– Nonleaking containers
– Compatible with waste it is holding
– Appropriately placed in the lab pack
protecting them from breakage, rupture or
leaks
Packing
• Incompatible Material
– Nitric acid should not be placed in a drum with acetic
acid
– Cyanides and sulfides should never be placed with
acids
– Acids and bases should not be packed in the same
drum
– Ammonia solutions should never be packed with
bleach
– Oxidizers should not be placed with flammables or
corrosives
Packing
• Drum Inventory
–Inventory sheets
• Trade name or major chemical
ingredient
• List liquids by volume
• List solids by weight
Packing
• Loose Pack
– Packed for short-term transport
– Aerosols packed without absorbents
– Nonleaking and tightly sealed containers
– Leaking and damaged containers - Placed
in a nonleaking container
Packing
• Consolidation
– Oil-Based Paint for Energy Recovery
• Flammable liquid label
• Hazardous waste sticker
• Grounding
• Secure to structure
Packing
• Consolidation
– Pesticides
• Same generic name and chemical constituents
• Appropriate personal protective equipment
• Containers emptied and disposed of properly
Transporting
• Shipping papers
• Emergency response
information
• Emergency response
guidebook (1996)
• Placards
• Loading, moving, and
Shipping Papers
• Shipper and receiver identification
– Package type and count
– Hazard material description (proper shipping
name, hazard class, ID number, other
information)
– Total quantity
– Emergency response information
– Shipper’s certification
– Signature
Emergency Response
Information
• 24-hr contact number operated by
knowledgeable person
• Description and technical name of
the hazardous material
• Immediate hazards to health
• Risks of fire or explosion
Emergency Response
Information
• Immediate precautions to be taken in
the event of an accident or incident
• Immediate methods for handling fires
• Initial methods for handling spill or
leaks in the absence of fire
• Preliminary first aid measures
Emergency Response
Information
• Review Emergency Response
Guidebook
• Familiarize yourself with your
facilities emergency procedures
• Emergency Management process
Placards
• Large 12” diamond shape
• Contain
– Hazard class or division
number
– Placard name
– Placard design section
references
• Placed on all four sides of
transport vehicle
Loading, Moving and
Unloading
• Responsibility of the carrier
• Segregation and separation
Training
• Refresher every two years
• Increases awareness of safety
considerations
Final Disposal
• Registered Transporter
• Know where your waste is going
• Recycling/TSD Facility
• Evaluate disposal facility
Monitoring
• Maintenance
• Inspections
Maintenance
• Drums
– Kept closed during storage except when items
are added
– Maintain empty space to ensure unobstructed
movement
– Label waste-containing drums
– Empty drums must be label free
– Good housekeeping
– Routine inspection checklists
Inspections
• Daily inspection of containers in the
facility
– Leakage or damage
– Liquid around base of drum
– Signs of rust or corrosion around base, top seal or
bung of drum
– Bulges or depressions
– Leaks or spills of hazardous materials
• Weekly inspection of facility by
supervisor
Safety
• Proper hygiene
• Safety meetings
• Security
• Visitors
Proper Hygiene
• Protective should be removed:
– Prior to taking breaks
– Entering the office area
– Leaving the sites
• Remove gloves last
Proper Hygiene
• Wash hands before:
– Eating
– Drinking
– Smoking
– Using the restroom
Safety Meetings
• Monthly
• Provide:
– Results of the inspections
– Review hazards identified
– Answer safety-related questions from
workers
Security
• Inform visitors of hazards and egress
routes
• Preapprove tours
• No tours during bulking, packing,
testing
• Use needed PPE

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waste_management.ppt

  • 1. Waste Management The overall objective of this module is that participants will show awareness of waste management and transportation requirements
  • 2. Overview • General principles for safe acceptance of household hazardous and/or CESQG waste from the public, which includes: receiving, sorting, storing, marking/labeling, packing, transporting, and final disposal of waste • Understand the DOT, CFR, and UN transportation requirements
  • 3. Expectations • List the seven steps in the waste management process • List the main classes of hazardous materials and how they should be sorted and stored • Identify the proper selection, marking/labeling, and handling of containers of hazardous waste
  • 4. 7 Steps in Waste Management Process • Collecting Wastes • Sorting • Storing • Marking/Labeling • Packing • Transporting • Final Disposal
  • 5. Collecting Wastes • Minimum standards – Customer restrictions – Waste restrictions – Container restrictions – Contents identified – Compatibilities of waste – Restricted areas
  • 6. Collecting Wastes • Guidelines – Load Inspection – Unloading
  • 7. Collecting Wastes • Inspection – Visually inspect the containers before removing to ensure integrity – Note unusual circumstances such as large volumes or items not likely to be household waste
  • 8. Collecting Wastes • Identifying and Dealing with Exceptions – Commercial wastes – Universal waste – Waste oil drums and oil filters – Open and leaking containers – Unlabeled / unknown items – Waste left outside of facility – Waste from farms
  • 9. Collecting Wastes • Identifying and Dealing with Exceptions – Infectious waste – Ammunition and explosives – Bombs / Unknown Packages – Critically unstable chemicals – Asbestos – Nonhazardous waste
  • 10. Suspected Commercial Wastes • Brought in a commercial vehicle • Large amounts of the same item • Items not normally for residential use • Product of a business; home business
  • 11. Collecting Wastes • Universal Wastes – Considerations for managing UW under UWR standards • Whether state has adopted UWR and additional waste added to UW list • Whether want to receive commercial UW • What quantity of UW you will receive and manage
  • 12. Collecting Wastes • Universal Wastes – Batteries – Mercury thermostats – Pesticides
  • 13. Collecting Wastes • Waste Reuse/ Exchange – Inspect containers for integrity and contents – No reuse • Recalled, canceled or suspended material • Material in containers which are damaged, rusted or labels are unreadable
  • 14. Sorting • Preliminary sorting • Waste oil • Testing waste oil for contamination • Flames test • Commercial test kits • Bulking waste oil • Pumping waste oil from barrels
  • 15. Sorting • Preliminary Sorting – Aerosols – Antifreeze – Car batteries – Unknown waste – Waste oil – Testing waste oil for contamination – Flame test – Commercial test kits
  • 16. Classification Process • Read the labels • Clues – Plastic or plastic-lined containers -used for acids or bases – Exotic metals - extremely dangerous – Single-walled containers - inert gas surrounding reactive, flammable or explosive material – Seal - reactive chemical or one which can not be exposed to air, water, or other chemicals – Cohesive solid in a liquid - material reactive with air or water – “Forbidden” - No transportation unless has been diluted, stabilized or incorporated into a device
  • 17. Classification Process • Color-coded labels and caps – green - ammonium hydroxide – brown - acetic acid – red - nitric acid – yellow - sulfuric acid – blue - hydrochloric acid – black - perchloric acid
  • 18. Sorting • Nine DOT hazard classes – Explosives – Gases – Flammable liquids – Flammable solids – Oxidizers – Poisons – Radioactive – Corrosives – Class 9
  • 19. Sorting • Precedence of Hazard – Radioactive – Poisonous gases – Flammable gases – Nonflammable gases – Poisonous liquids – Pyrophoric material – Self-reactive material
  • 20. Sorting – Class 3- Flammable liquids – Class 8- Corrosive materials – Division 4.1- Flammable solids – Division 4.2- Spontaneously combustible materials – Division 4.3- Dangerous when wet materials – Division 5.1- Oxidizers – Division 6.1- Poisonous materials – Combustible liquids – Miscellaneous hazardous materials
  • 21. Storing • Proper labeling on storage cabinet, containers • Compatibilities • Check reactivity within Hazard Classes
  • 22. Marking/Labeling • Proper Shipping Name (PSN) • Selecting a Package • Drum Preparation • Marking • Labels • State Hazardous Waste Stickers • Drum ID Number
  • 23. Proper Shipping Name (PSN) • Priority for selection: – Chemical Name, e.g., “Methyl Alcohol” – Generic Name (Chemical Family), e.g., “Alcohol’s, n.o.s.” – End Use of Material, e.g., “Paint Related Materials” – The n.o.s. End Use, e.g., “Dyes, Liquid, n.o.s.” – DOT Class of Hazard, e.g., “Flammable Liquids, n.o.s.”
  • 24. Selecting a Package • Package must meet design and performance standards- “performance-based packaging” • Limited quantity (LMTD QTY)
  • 25. Drum Preparation • New or reconditioned and acceptable to DOT • Empty • Cover, securing ring and / or bung and gaskets • Drums used for lab packs must be lined with a 6 ml polyethylene liner • Drums with liquids inside containers must be marked on two opposite vertical sides of the package with the arrows pointing in the correct upright direction • Marked on 2 sides - This side up
  • 26. Marking • Proper shipping name • ID number • Address of the shipper or recipient • English • Durable • Of contrasting color with background • Away from other markings • Easy to see
  • 27. Labels • Diamond shaped • Indicate the hazard class and division of a material • Placed near proper shipping name and ID#s
  • 28. State Hazardous Waste Stickers • “Accumulation Start Date” • “Hazard Class” • “Hazardous Waste” - upper one-third of the drum • Labels on two sides (upper third) and the top of the drum
  • 29. Drum ID Number • Assign a serial number
  • 30. Packing • Lab Pack • Incompatible material • Drum inventory • Loose Pack • Consolidation
  • 31. Packing • Lab pack – Extensive training – Nonleaking containers – Compatible with waste it is holding – Appropriately placed in the lab pack protecting them from breakage, rupture or leaks
  • 32. Packing • Incompatible Material – Nitric acid should not be placed in a drum with acetic acid – Cyanides and sulfides should never be placed with acids – Acids and bases should not be packed in the same drum – Ammonia solutions should never be packed with bleach – Oxidizers should not be placed with flammables or corrosives
  • 33. Packing • Drum Inventory –Inventory sheets • Trade name or major chemical ingredient • List liquids by volume • List solids by weight
  • 34. Packing • Loose Pack – Packed for short-term transport – Aerosols packed without absorbents – Nonleaking and tightly sealed containers – Leaking and damaged containers - Placed in a nonleaking container
  • 35. Packing • Consolidation – Oil-Based Paint for Energy Recovery • Flammable liquid label • Hazardous waste sticker • Grounding • Secure to structure
  • 36. Packing • Consolidation – Pesticides • Same generic name and chemical constituents • Appropriate personal protective equipment • Containers emptied and disposed of properly
  • 37. Transporting • Shipping papers • Emergency response information • Emergency response guidebook (1996) • Placards • Loading, moving, and
  • 38. Shipping Papers • Shipper and receiver identification – Package type and count – Hazard material description (proper shipping name, hazard class, ID number, other information) – Total quantity – Emergency response information – Shipper’s certification – Signature
  • 39. Emergency Response Information • 24-hr contact number operated by knowledgeable person • Description and technical name of the hazardous material • Immediate hazards to health • Risks of fire or explosion
  • 40. Emergency Response Information • Immediate precautions to be taken in the event of an accident or incident • Immediate methods for handling fires • Initial methods for handling spill or leaks in the absence of fire • Preliminary first aid measures
  • 41. Emergency Response Information • Review Emergency Response Guidebook • Familiarize yourself with your facilities emergency procedures • Emergency Management process
  • 42. Placards • Large 12” diamond shape • Contain – Hazard class or division number – Placard name – Placard design section references • Placed on all four sides of transport vehicle
  • 43. Loading, Moving and Unloading • Responsibility of the carrier • Segregation and separation
  • 44. Training • Refresher every two years • Increases awareness of safety considerations
  • 45. Final Disposal • Registered Transporter • Know where your waste is going • Recycling/TSD Facility • Evaluate disposal facility
  • 47. Maintenance • Drums – Kept closed during storage except when items are added – Maintain empty space to ensure unobstructed movement – Label waste-containing drums – Empty drums must be label free – Good housekeeping – Routine inspection checklists
  • 48. Inspections • Daily inspection of containers in the facility – Leakage or damage – Liquid around base of drum – Signs of rust or corrosion around base, top seal or bung of drum – Bulges or depressions – Leaks or spills of hazardous materials • Weekly inspection of facility by supervisor
  • 49. Safety • Proper hygiene • Safety meetings • Security • Visitors
  • 50. Proper Hygiene • Protective should be removed: – Prior to taking breaks – Entering the office area – Leaving the sites • Remove gloves last
  • 51. Proper Hygiene • Wash hands before: – Eating – Drinking – Smoking – Using the restroom
  • 52. Safety Meetings • Monthly • Provide: – Results of the inspections – Review hazards identified – Answer safety-related questions from workers
  • 53. Security • Inform visitors of hazards and egress routes • Preapprove tours • No tours during bulking, packing, testing • Use needed PPE