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Nanotechnology Patents:
What Can Be Learned?
Donald J. Featherstone
Michael D. Specht

Nano Science and Technology Institute
Nanotech 2005
Anaheim, California
May 11, 2005
Top Ten Nanotech Patents


  “Ten Patents that Could Dramatically
       Impact the Development of
           Nanotechnology”

1.2 Nanotechnology Law & Business 225 (2004)




                                               2
Top Ten Nanotech Patents
 Pat No.                     Title                Issue Date

RE 38,233 Field Emission Cathode Having an        08/19/03
          Electrically Conducting Material Shaped
          of Narrow Rod or Knife Edge
5,286,571   Molecular Modification Reagent and    10/21/03
            Method to Functionalize Oxide
            Surfaces
5,424,054   Carbon Fibers and Method for their    6/13/95
            Production
5,505,928   Preparation of III-IV Semiconductor   3/9/96
            Nanocrystals
5,883,705   Atomic Force Microscope for High      3/16/99
            Speed Imaging Including Integral
            Actuator and Sensor


                                                               3
Top Ten Nanotech Patents

 Pat No.                     Title                 Issue Date

5,897,945   Metal Oxide Nanorods                   04/27/99

6,268,041   Narrow Size Distribution Silicon and   07/31/01
            Germanium Nanocrystals
6,322,901   Highly Luminescent Color-Selective     11/27/01
            Nano-Crystalline Materials
6,346,189   Carbon Nanotube Structures Made        02/12/02
            Using Catalyst Islands
6,593,731   Displacement Transducer Utilizing      07/15/03
            Miniatured Magnet and Hall Junction




                                                                4
Issues Impacting Nanotechnology Patents


       Size Considerations

       Nomenclature

       Rigorous Examination

       Speed of Examination


                                          5
Size Considerations

    In 6 patent applications, size considerations
    became fundamentally important to the
    examination.

Examples:
(1) 5,424,054 – prior art teaches hollow carbon tubes of about
     2 nm and a wall several carbon atoms thick.
    SOLUTION: “consisting essentially of” to limit claim to single
     layer of atoms

(2) 6,593,731 – Applicants needed to overcome reference by
     showing critical nature of dimensions.
    SOLUTION: amendment that stated “a gap which is small
     enough to allow direct magnetic flux linkage between the
     magnet and Hall Junction.”


                                                                     6
Nomenclature

Example Lexicography
1. A device comprising: a composite material comprising
   aligned nanowires …. (Patentable features omitted.)

2. The device of claim 1, wherein the nanowires are
   selected from carbon, silicon, and germanium.

3. The device of claim 2, wherein the nanowires are
   carbon nanotubes ….

(USPN 6,741,019)




                                                          7
Definitions Confusing at Best
Definition of Claim Terms from Specification?

•   quot;Carbon nanotubes feature a high aspect ratio (>1,000) and a
    small tip radii of curvature (.about.5-50 nm). These geometric
    characteristics, coupled with the high mechanical strength and
    chemical stability of the tubules, make carbon nanotubes
    attractive as electron field emitters.quot; (Citations omitted.)

•   quot;Other types of nano-scale wires with small diameters also
    exist. Semiconductor or metallic nanowires of silicon or
    germanium, for example, are capable of being fabricated by a
    number of different methods including laser processing, vapor-
    liquid approach or CVD deposition.quot; (Citations omitted.)

•   quot;The first step is to provide nanowires such as carbon
    nanotubes or semiconductor nanowires by any of the known
    synthesis techniques….“



                                                                     8
Nomenclature: Possible Solutions
1. A field-effect transistor, comprising
   a source region;
   a drain region;
   a gate region between said source region and said drain region;
   said gate region containing conductive material having at least
   one through hole formed therein;
   at least one nanoelement disposed in said through hole and
   electrically coupled to said source region and said drain region;
   and
   said nanoelement being arranged and configured such that a
   conductivity thereof is controlled via said gate region, and said
   nanoelement forms a channel region.

2. The field-effect transistor according to claim 1, wherein said
   nanoelement comprises at least one of a nanotube and a
   nanowire.

(USPN 6,740,910)



                                                                       9
Nomenclature
Class 977 – Nanotechnology

The Nanotechnology art collection provides for
   disclosures related to:

(1) Nanostructure and chemical compositions of
    nanostructure;
(2) Devices that include at least one nanostructure;
(3) Mathematical algorithms, e.g., computer software, etc.,
    specifically adapted for modeling configurations or
    properties of nanostructures;
(4) Methods or apparatus for making, detecting, analyzing,
    or treating nanostructures; and
(5) Specified particular uses of nanostructures.

                                                              10
Nomenclature

Class 977 – Nanotechnology

The term “nanostructure” is defined to mean an
   atomic, molecular or macromolecular structure
   that:

(a) Has at least one physical dimension of
    approximately 1-100 nanometers; and
(b) Possesses a special property, provides a
    special function, or produces a special effect
    that is uniquely attributable to the structure’s
    nanoscale size.

                                                       11
Nomenclature

Class 977 – Nanotechnology

Nanotube: A fullerene molecule having a cylindrical or toroidal shape.

Fullerene: Any of various cage-like, hollow molecules composed of
     hexagonal and pentagonal groups of atoms, and especially those
     formed from carbon, that constitute the third form of carbon after
     diamond and graphite. Alternatively, a class of cage-like carbon
     compounds composed of fused, pentagonal, or hexagonal sp2 carbon
     rings.

Graphene: Two-dimensional sheet form of fullerene.

Single Walled Nanotube (SWNT): Formed from one layer of graphene
     wrapped in cylindrical form.

Multi-Walled Nanotube (MWNT): Formed of multiple layers of graphene
     wrapped in cylindrical form.

                                                                          12
Rigorous Examination
  Rejections generally well thought out.

  In nine of ten applications, applicants made
  narrowing amendments.

  In at least half of the applications, applicants
  cancelled claims.

  Examiners requiring showing of criticality of
  dimensions.

  Misleading conclusions – perhaps – more on
  this later.
                                                     13
Speed of Examination

                                              Class 977 Patent Average Pendancy
                                                  (Filing Date to Issue Date)
               50
               45

                                                                                           AVE: 26.3
               40
               35
  M o n th s




               30
               25
               20
               15
               10
                5
                0
                    78
                         80
                              81
                                   82
                                        84
                                             85
                                                  86
                                                       87
                                                            88
                                                                 89
                                                                      90
                                                                           91
                                                                                92
                                                                                     93
                                                                                          94
                                                                                               95
                                                                                                    96
                                                                                                         97
                                                                                                              98
                                                                                                                   99
                                                                                                                        00
                                                                                                                             01
                                                                                                                                  02
                                                                                                                                       03
                                                                                                                                            04
                                                                                                                                                 05
               19
                     19
                          19
                               19
                                    19
                                         19
                                              19
                                                   19
                                                        19
                                                             19
                                                                  19
                                                                       19
                                                                            19
                                                                                 19
                                                                                      19
                                                                                           19
                                                                                                19
                                                                                                     19
                                                                                                          19
                                                                                                               19
                                                                                                                    20
                                                                                                                         20
                                                                                                                              20
                                                                                                                                   20
                                                                                                                                        20
                                                                                                                                             20
                                                                                 Year


Source: United States Patent and Trademark Office                                                                                                     14
Disclaimers & Contact Information

        These materials are not intended and should not be used as legal advice.
  If you need legal advice or an opinion on a specific issue or factual situation, please
 consult an attorney. Answering questions or the use of this material does not form or
 constitute an attorney-client relationship. These material are for information purposes
           only and should not be relied upon as a substitute for legal advice

  The presentation reflects only the current considerations and views of the authors,
which should not be attributed to Sterne, Kessler, Goldstein & Fox P.L.L.C. or any of its
                                current or former clients.

                     For More Information, please contact

                             Donald J. Featherstone
                         202-772-8629 or donf@skgf.com

                              Michael D. Specht
                      202-772-8756 or mspecht@skgf.com



                                                                                            15

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SKGF_Presentation_Nanotechnology Patents: What Can Be Learned?_2005

  • 1. Nanotechnology Patents: What Can Be Learned? Donald J. Featherstone Michael D. Specht Nano Science and Technology Institute Nanotech 2005 Anaheim, California May 11, 2005
  • 2. Top Ten Nanotech Patents “Ten Patents that Could Dramatically Impact the Development of Nanotechnology” 1.2 Nanotechnology Law & Business 225 (2004) 2
  • 3. Top Ten Nanotech Patents Pat No. Title Issue Date RE 38,233 Field Emission Cathode Having an 08/19/03 Electrically Conducting Material Shaped of Narrow Rod or Knife Edge 5,286,571 Molecular Modification Reagent and 10/21/03 Method to Functionalize Oxide Surfaces 5,424,054 Carbon Fibers and Method for their 6/13/95 Production 5,505,928 Preparation of III-IV Semiconductor 3/9/96 Nanocrystals 5,883,705 Atomic Force Microscope for High 3/16/99 Speed Imaging Including Integral Actuator and Sensor 3
  • 4. Top Ten Nanotech Patents Pat No. Title Issue Date 5,897,945 Metal Oxide Nanorods 04/27/99 6,268,041 Narrow Size Distribution Silicon and 07/31/01 Germanium Nanocrystals 6,322,901 Highly Luminescent Color-Selective 11/27/01 Nano-Crystalline Materials 6,346,189 Carbon Nanotube Structures Made 02/12/02 Using Catalyst Islands 6,593,731 Displacement Transducer Utilizing 07/15/03 Miniatured Magnet and Hall Junction 4
  • 5. Issues Impacting Nanotechnology Patents Size Considerations Nomenclature Rigorous Examination Speed of Examination 5
  • 6. Size Considerations In 6 patent applications, size considerations became fundamentally important to the examination. Examples: (1) 5,424,054 – prior art teaches hollow carbon tubes of about 2 nm and a wall several carbon atoms thick. SOLUTION: “consisting essentially of” to limit claim to single layer of atoms (2) 6,593,731 – Applicants needed to overcome reference by showing critical nature of dimensions. SOLUTION: amendment that stated “a gap which is small enough to allow direct magnetic flux linkage between the magnet and Hall Junction.” 6
  • 7. Nomenclature Example Lexicography 1. A device comprising: a composite material comprising aligned nanowires …. (Patentable features omitted.) 2. The device of claim 1, wherein the nanowires are selected from carbon, silicon, and germanium. 3. The device of claim 2, wherein the nanowires are carbon nanotubes …. (USPN 6,741,019) 7
  • 8. Definitions Confusing at Best Definition of Claim Terms from Specification? • quot;Carbon nanotubes feature a high aspect ratio (>1,000) and a small tip radii of curvature (.about.5-50 nm). These geometric characteristics, coupled with the high mechanical strength and chemical stability of the tubules, make carbon nanotubes attractive as electron field emitters.quot; (Citations omitted.) • quot;Other types of nano-scale wires with small diameters also exist. Semiconductor or metallic nanowires of silicon or germanium, for example, are capable of being fabricated by a number of different methods including laser processing, vapor- liquid approach or CVD deposition.quot; (Citations omitted.) • quot;The first step is to provide nanowires such as carbon nanotubes or semiconductor nanowires by any of the known synthesis techniques….“ 8
  • 9. Nomenclature: Possible Solutions 1. A field-effect transistor, comprising a source region; a drain region; a gate region between said source region and said drain region; said gate region containing conductive material having at least one through hole formed therein; at least one nanoelement disposed in said through hole and electrically coupled to said source region and said drain region; and said nanoelement being arranged and configured such that a conductivity thereof is controlled via said gate region, and said nanoelement forms a channel region. 2. The field-effect transistor according to claim 1, wherein said nanoelement comprises at least one of a nanotube and a nanowire. (USPN 6,740,910) 9
  • 10. Nomenclature Class 977 – Nanotechnology The Nanotechnology art collection provides for disclosures related to: (1) Nanostructure and chemical compositions of nanostructure; (2) Devices that include at least one nanostructure; (3) Mathematical algorithms, e.g., computer software, etc., specifically adapted for modeling configurations or properties of nanostructures; (4) Methods or apparatus for making, detecting, analyzing, or treating nanostructures; and (5) Specified particular uses of nanostructures. 10
  • 11. Nomenclature Class 977 – Nanotechnology The term “nanostructure” is defined to mean an atomic, molecular or macromolecular structure that: (a) Has at least one physical dimension of approximately 1-100 nanometers; and (b) Possesses a special property, provides a special function, or produces a special effect that is uniquely attributable to the structure’s nanoscale size. 11
  • 12. Nomenclature Class 977 – Nanotechnology Nanotube: A fullerene molecule having a cylindrical or toroidal shape. Fullerene: Any of various cage-like, hollow molecules composed of hexagonal and pentagonal groups of atoms, and especially those formed from carbon, that constitute the third form of carbon after diamond and graphite. Alternatively, a class of cage-like carbon compounds composed of fused, pentagonal, or hexagonal sp2 carbon rings. Graphene: Two-dimensional sheet form of fullerene. Single Walled Nanotube (SWNT): Formed from one layer of graphene wrapped in cylindrical form. Multi-Walled Nanotube (MWNT): Formed of multiple layers of graphene wrapped in cylindrical form. 12
  • 13. Rigorous Examination Rejections generally well thought out. In nine of ten applications, applicants made narrowing amendments. In at least half of the applications, applicants cancelled claims. Examiners requiring showing of criticality of dimensions. Misleading conclusions – perhaps – more on this later. 13
  • 14. Speed of Examination Class 977 Patent Average Pendancy (Filing Date to Issue Date) 50 45 AVE: 26.3 40 35 M o n th s 30 25 20 15 10 5 0 78 80 81 82 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 00 01 02 03 04 05 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 19 20 20 20 20 20 20 Year Source: United States Patent and Trademark Office 14
  • 15. Disclaimers & Contact Information These materials are not intended and should not be used as legal advice. If you need legal advice or an opinion on a specific issue or factual situation, please consult an attorney. Answering questions or the use of this material does not form or constitute an attorney-client relationship. These material are for information purposes only and should not be relied upon as a substitute for legal advice The presentation reflects only the current considerations and views of the authors, which should not be attributed to Sterne, Kessler, Goldstein & Fox P.L.L.C. or any of its current or former clients. For More Information, please contact Donald J. Featherstone 202-772-8629 or donf@skgf.com Michael D. Specht 202-772-8756 or mspecht@skgf.com 15