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February 2011




                recycling technology takes oFF

                Making the Most oF Mineral Fillers

                nucleators deliver clear beneFits

                rethinking how kneaders work
quantec ® 96 EV-10C
BUSS KNEADER TECHNOLOGY




                          Cutting-Edge Compounding Technology
                          MX and quantec ® BUSS Kneader Series

                                      BUSS innovative 4-flight screw technology sets new benchmarks in the economical
                                      processing of temperature and shear sensitive plastics such as PVC and high grade
                                      cable compounds:

                                      >     2.5 times higher throughputs
                                      >     Enhanced mixing quality and dispersion
                                      >     Energy savings up to 25%




                          Buss AG                      Phone +41 61 825 66 00
                          Hohenrainstrasse 10          Fax +41 61 825 68 58
                          4133 Pratteln                info@busscorp.com
                          Switzerland                  www.busscorp.com
contents
                                      04	 Industry	news
pAge 19




                                      15	 Clariant	colours	in	the	future
                                            Each year, experts from clariant masterbatches predict the plastics colour trends that
                                            lie ahead. we take a first look at their brand new tips for 2012.

                                      16	 Using	carbon	dioxide	as	a	carrier	for	additives
                                            researchers from the Fraunhofer institute are using supercritical carbon dioxide to
                                            impregnate plastics with temperature-sensitive additives.
pAge 2




                                      19	 Bottle	recycler	bounces	back
                                            nadya Anscombe reports on how Eco plastics rebuilt Europe’s biggest plastics bottle
                                            recycling plant after a fire destroyed its sorting facility.

                                      23	 Focus	on	recycling	machinery
                                            we look at the latest technology for sorting, shredding, cleaning, drying and extruding
                                            waste plastics to produce high-quality recycled materials.
pAge 28




                                      28	 Making	the	most	of	minerals
                                            dr chris deArmitt reports from Ami’s recent minerals in compounding conference on
                                            the latest developments in functional fillers for thermoplastics.

                                      41	 Delivering	clear	benefits
                                            lilli Sherman examines how new clarifying and nucleating agents are growing the
                                            market and creating breakthrough applications for polyolefins.
pAge 41




                                      47	 BP	rethinks	kneader	design
                                            we examine Bp process Equipment’s brand new Tri-Kneader, an innovative
                                            reinvention of the reciprocating kneader for demanding applications.

                                      51	 New	products:	polymers	and	additives
                                      54	 New	products:	machinery	and	equipment
pAge 47




                                      56	 Compounder	of	the	Month:	Cromex	of	Brazil
                                      58	 Dates	for	your	diary

coming	next	issue
❙ pelletizing technology ❙ improving wear and friction properties ❙ polymer distribution in north America
                                                                              ➤ Click here to make sure you get your copy

contact	us
   Applied Market Information Ltd     Head	of	business	publishing:   Andy Beevers        E-mail: abe@amiplastics.com
   Ami House, 45-47 Stokes croft,     Contributing	editors:          lilli Sherman       E-mail: editorial@compoundingworld.com
   Bristol, BS1 3Qp, united Kingdom
                                                                     nadya Anscombe      E-mail: editorial@compoundingworld.com
   Tel:+44 (0)117 924 9442
   Fax:+44 (0)117 989 2128            Advertisement	manager:         claire Bishop       E-mail: claire@amimagazines.com
   www.amiplastics.com                                                                   direct tel: +44 (0)20 8686 8139

© Copyright Applied Market Information. No part may be reproduced without the prior written permission of the publisher.

www.compoundingworld.com                                                              February 2011 | compounding world
news



dSm buys into russian
compounding plant
dSm has established two joint        owned by dSm. it will focus on    DSM’s Nico Gerardu
ventures with KuibyshevAzot          growing the market for pA6 in        says that the JVs
(KA) of russia covering the          russia and the ciS. it will          will capitalise on
sales and production of              target both pA6 compounds             anticipated PA 6
polyamide 6 in russia and the        and high-viscosity applica-          growth in Russia
commonwealth of independ-            tions, including film.
ent States (ciS). As part of the        As part of the strategic          nico gerardu, member of         capitalise on this anticipated
agreements, dSm Engineering          agreement, KA is licensing        the dSm board with responsi-       growth.”
plastics will acquire 80% of         dSm’s cyclohexanone technol-      bility for performance                KA is a leading producer of
KA’s compounding plant in            ogy which will allow it to        materials, said: “russia is an     caprolactam and pA in russia
Togliatti, russia.                   increase pA6 capacity at its      increasingly important market      and the ciS, and is among the
    dSm says that this produc-       plant in Togliatti to help meet   for engineering plastics and it    world’s 10 biggest producers
tion JV means that it is the first   the anticipated increase in       is expected that the market for    of these products. it had net
western pA 6 supplier with its       demand created by the new         pA6 will double in the next five   sales of uS$505 million in
own manufacturing presence           JVs. dSm Fibre intermediates      years. with our partnership        2009 and employs around
in russia and the ciS. The           will also have drawing rights     with KA, i expect that dSm         5,500 people.
other JV, which covers sales         for part of the increased         Engineering plastics will be in    ❙ www.dsm.com
and marketing, will be 51%           capacity.                         an excellent position to           ❙ www.kuazot.ru




rhodia acquires pi polymer to                                                                              Spanish toy
                                                                                                           makers add
grow pA compounds in india                                                                                 conductivity
rhodia is acquiring pi                                                                                     Spain’s Toy research
polymer, the engineering                                                 François Hincker says that        institute (AiJu) is leading a
plastics compounding                                                   acquisition will dramatically       research project to examine
business of the indian                                                  accelerate Rhodia’s growth         the use of new conductive
company pi industries. The                                                                     in India    plastics compounds to
deal is expected to be complet-                                                                            control electromagnetic
ed by the end of march 2011.                                                                               interference entering and
    pi polymer forecasts                                                                                   leaving electrical and
revenues of approximately                                                                                  electronic toys.
uS$13 million for the 2010/11                                                                                 The collaborative
fiscal year. its plant in panoli,                                                                          project, called Emitoy, will
gujarat, employs more than 80                                                                              examine the use of carbon
people and produces a range          François Hincker, president of       Following the sale of pi         nano-fibres in polyolefins to
of technical compounds               rhodia Engineering plastics,      polymers, pi industries will        improve electromagnetic
including pA, pc, pBT, ABS           said: “we have identified         focus on the production of          screening, electrostatic
and pp as well as some TpEs.         strong synergies with our         agro-chemicals and the              dissipation and electrostatic
    According to rhodia, the         engineering plastics business     custom synthesis of fine            painting. it is receiving
acquisition is part of its           in terms of product range and     chemicals and pharmaceutical        regional government
strategy to grows it share of        customer portfolio that will      intermediates.                      funding as well as support
india’s pA compounds market          dramatically accelerate our       ❙ www.rhodia.com                    from the European union.
to more than 15% by 2015.            growth in india”.                 ❙ www.piindustries.com              ❙ www.aiju.info

     compounding world | February 2011                                                                     www.compoundingworld.com
news



cereplast and colorTec                                                                                   Eu plans
                                                                                                         13.8% tax
to benefit from bag ban                                                                                  on chinese
cereplast of the uSA has
entered a distribution agree-
                                   natureworks and BASF’s
                                   Ecoflex compostable copolyes-
                                                                      have made the use of bioplas-
                                                                      tic garbage bags mandatory
                                                                                                         glass fibres
ment with the italian master-      ter. it can be processed on        from the start of this year.       The European union (Eu) is
batch marker colorTec              existing blown film lines and is   cereplast already has a deal in    likely to impose import
covering the sale of bio-based     claimed to offer high strength.    place to supply its composta-      duties of 13.8% on glass
and compostable plastics com-         “recent environmental           ble 3000 film grade resin to       fibres imported from china.
pounds in southern italy and       legislation, such as the plastic   another italian masterbatch        if approved later this
Slovenia. The companies            bag ban that went into effect      maker, ri.mE, which is using it    month, the tariffs will be
expect to tap into growing         this year in italy, is driving     to produce colour masterbatch      imposed from 17 march
demand for such materials as       demand for bioplastics,” said      for the European market (see       2011 and will run for a
a result of italy’s highly         cereplast’s cEo Frederic           Compounding World, October         period of five years. glass
controversial ban on non-          Scheer. “we are confident that     2010, page 7).                     yarns will be excluded from
compostable plastic bags.          demand will continue to rise in    l cereplast has also signed a      the import duties.
   under the terms of the          Europe as stores in italy alone    deal with another European            As reported in Com-
agreement, cereplast will          use approximately 20-24            compounder, Euroink                pounding World, Septem-
provide colorTec with its          billion plastic bags a year,       romania. This company will         ber 2010, the Eu imposed
compostable 3000 film grade        which accounts for one-fifth of    use cereplast’s bio-based and      an extra duty of 43.6% on 16
resin for the production of        all European use”.                 compostable resins to produce      September for a period of
masterbatches for the                 colorTec has a strong           colour masterbatch for the         six months, while further
manufacture of shopping and        market position in southern        romanian market.                   investigations into the issue
garbage bags. The resin is a       italy and works closely with the   ❙ www.cereplast.com                were carried out.
blend of ingeo plA from            country’s municipalities that      ❙ www.colortec.it                     The increase has been
                                                                                                         supported by glass fibre
                                                                                                         producers who have

Americhem invests in three                                                                               complained about the
                                                                                                         dumping of chinese


new compounding lines                                                                                    material at illegally low
                                                                                                         prices. However, it has been
                                                                                                         fought by the users of
Americhem has added three                                                                                fibreglass who believe that
compounding lines at its plant                                                                           the increased tariff will lead
in concord, north carolina,                                                                              to material shortages and
uSA, to increase capacity for                                                                            increase their costs.
colour and additive master-                                                                                 The European compos-
batches. The expansion will                                                                              ites industry Association
help to meet growing demand                                                                              (EuciA) welcomes the
from the polyester bulk                                                                                  proposed reduction in the
continuous filament (BcF)                                                                                tariff, but argues that a
market.                             Americhem has added                                                  13.8% duty will still be
   Two of the new lines are set     three compounding lines                                              harmful for European users
up to produce high-quality          at its Concord plant                                                 of glass fibres. it also points
products in large lot sizes for                                                                          out that the tariff was only
the polyester floor covering          “with the floor coverings       our customers grow and gain        supported by four of the 27
industry. The third is optimised   market increasingly shifting to    the competitive edge,” said        Eu member states, with
for the production of small lots   the use of pET BcF fibres over     Jim cook, the company’s plant      most countries abstaining
that meet the critical specifi-    staple and polyolefin-based        manager in concord.                in the vote.
cations of the textile industry.   fibres, Americhem can help         ❙ www.americhem.com                ❙ www.eucia.org

www.compoundingworld.com                                                                     February 2011 | compounding world
news



Foster opens medical plastics lab
Foster corporation has opened          “As the market for medical
its medical plastics innovation     devices evolves, materials of
center at its headquarters in       construction become more
putnam, connecticut, uSA.           critical,” said Foster’s cEo
The facility will be used to        larry Acquarulo. “For
develop advanced polymer            example, within the last 20
formulations for leading edge       years the outside diameter of a
medical devices. it offers          typical angiographic catheter
polymer compounding,                has decreased by 70%, while
materials testing and process       the working pressures have
evaluation for moulding and         increased well over 100%. This
extrusion.                          was made possible by
     particular areas of focus at   improvements in polymer
the new development facility        technologies.”
will include nanocomposites            A subsidiary of the polyme-
and melt-filtered materials, as     dex discovery group, Foster
well as anti-microbial              has been producing thermo-
additives for infection control     plastics compounds for                                                The new facility is built around
materials. Tailored polymers        medical applications for more                                               twin-screw extrusion for
will also be developed for          than 20 years.                                                               compound development
long-term implants.                 ❙ www.fostercomp.com




 Altana buys Kometra Schulman shuts plants
    Altana is to acquire the                                          in italy and Australia
    Kometra, the polymer
    modifier producer based in                                        A. Schulman is closing its           administrative office will
    Schkopau, germany. The                                            manufacturing plants in              remain at Verolanuova.
    company will be integrated                                        Verolanuova, italy, and                 All production at the
    into Altana’s BYK additives                                       Breaside, Australia, with the        Breaside plant, near mel-
    business.                                                         loss of approximately 40 to 60       bourne, Australia, will be
       Kometra’s products                                             jobs. Both facilities produce        moved to other facilities in the
    include specific surface-                                         powders for rotomoulding             region. The company has a
    active copolymers which are                                       applications and were                plant in Brisbane, Australia, as
    used as impact modifiers and    BYK’s Dr Roland Peter says        previously owned by ico              well as facilities in malaysia,
    adhesion promoters. They are    that sales of Kometra’s poly-     polymers which Schulman              indonesia and china.
    marketed under the Scona        mer modifiers will benefit        acquired in April 2010.                 The closure of the Breaside
    brandname and are produced      from his company’s global            production lines from the         facility was primarily the
    using a patented solid-state    sales network                     Verolanuova plant will be            result of the ongoing deterio-
    grafting process originally                                       relocated to Schulman’s site in      ration of the rotomoulding
    developed by dow.               that BYK’s global sales           gorla maggiore, italy, by early      business in Australia. in
       “with Kometra’s technol-     network is well positioned to     2012. The latter facility will be    particular, demand for water
    ogy there are new fields of     open up new market                used to develop and manufac-         tanks has fallen following a
    business which ideally          potential for Kometra’s           ture value-added technical           steady decline in drought
    complement and expand our       polymer modifier technology       powders as well as custom            conditions and government
    existing activities,” said dr   worldwide.                        colour masterbatches and             rebates have been withdrawn,
    roland peter, president of      ❙ www.altana.com                  compounds for the local              says the company.
    the BYK division. He added      ❙ www.kometra.de                  market. A commercial and             ❙ www.aschulman.com

       compounding world | February 2011                                                                     www.compoundingworld.com
news



    lanxess                         clariant spearheads
    starts to
    build plant                     reach registrations
    in india                        clariant has begun work on             “we are delighted to have
    lanxess has started             phase Two of reach legislation      completed the task assigned to
    construction of its new         following its successful            us,” commented Hariolf
    20,000 tonnes/year com-         registration of 152 substances      Kottmann, clariant’s cEo.
    pounding plant in Jhagadia,     under phase one, ahead of the       “our achievement in complet-
    gujarat, india. it is due on    december 2010 deadline. The         ing phase one registration
    line at the start of 2012 and   second phase involves more          inside the deadline required a
    will be used to produce pA      than 300 chemicals and should       lot of long, hard work, and an
    and pBT compounds. A            be completed by 1 June 2013.        intensive use of resources”.
    ground-breaking ceremony           in phase one, clariant was       l if you need to know more
    was held at the site in         the lead registrant for 81 out of   about registering substances
    January. lanxess is investing   the 152 consortia and Sub-          for reach, click here to
    more than E10 million in the    stance information Exchange         download the latest edition of    Clariant’s CEO Hariolf
    facility which will create 60   Forums. The work covered            the EcHA’s 123-page publica-      Kottmann says that Reach
    new jobs.                       finished products, intermedi-       tion, guidance on registration.   registration has required “an
    ❙ www.lanxess.com               ates and raw materials.             ❙ www.clariant.com                intensive use of resources”




Australian court dismisses                                                                                 Fox plans to
oxodegradable claims                                                                                       recycle in
                                                                                                           mexico
The Federal court in Adelaide,      the Australian standard. in         of the oxodegradable bags,         Fox petroleum is planning
Australia, has declared that        addition, the bags did not          nupack Australia, had the          to form a plastics recycling
goody Environment engaged in        biodegrade, disintegrate, or        same claims dismissed for the      subsidiary in Tuxtla
misleading and deceptive            compost in accordance with          same reasons.                      gutierrez, southern mexico.
conduct and made false              the standard.                          dr michael Schraper, the        it expects that it will be able
representations about its              According to Justice lander,     Accc’s acting chairman, said:      to process up to 2,300
plastics bags which contain         goody contravened sections 52       “Environmental claims are          tonnes/year of industrial
oxodegradable additives.            and 53 of the Trade practices       powerful selling tools as many     and consumer waste
     in 2009, the company had       Act and the company has been        purchasers want to do the          plastics.
claimed that its goody-             ordered to publish corrective       right thing for the environ-          The city has one million
branded plastic bags were           notices on its website and in       ment. it is important that they    people, but currently there
biodegradable and composta-         The Advertiser newspaper. it        are given accurate information     are no recyclers of plastics.
ble in accordance with the          was also instructed to              and can feel confident in the      “There is an enormous
Australian Standard AS4736-         implement a trade practices         purchasing decisions they          demand for recycling from
2006 and could be legally           compliance and education            make.”                             both the private and public
supplied in South Australia.        programme, and to contribute        l Click here to download the       sectors throughout mexico,
     The court declared that this   AuS$65,000 (E48,000) towards        Accc’s four-page publication       but specifically in Tuxtla
was not the case because the        the costs of the Australian         providing practical guidelines     gutierrez, the leading city in
bags contained the heavy            competition  consumer              on making biodegradable,           the state of chiapas,” said
metal molybdenum in amounts         commission (Accc).                  degradable and recyclable          william lieberman,
that exceeded the maximum              in a previous court decision     claims on plastic bags.            president of Fox petroleum.
concentration prescribed by         in october 2010, the distributor    ❙ www.goody.com.hk                 ❙ www.foxpetro.net

       compounding world | February 2011                                                                   www.compoundingworld.com
Polymers in Cables
                       2011
              The International Conference and Exhibition for the Plastics Cable Industry




                                                                           CliCk Here
                                                                           for more
                                                                            deTailS




                                             March 31- April 1, 2011
                                                Hilton Miami Downtown,
Images courtesy of:                                Miami, Florida, USA
Omya and Imerys
Performance Minerals


                 final reminder – book now!
    Organized by:                      Sponsored by:
    Applied Market
    Information LLC.


              marissa Hann – Conference Coordinator mh@amiplastics-na.com Ph: +1 610 478 0800 fx: +1 610 478 0900
news



 linpac sells                   cabot starts to construct
 recycling
 business
                                chinese masterbatch plant
                                cabot has begun construction          increase masterbatch capacity     already the largest master-
 linpac recycling, one of the   of a new black masterbatch            at the site to 80,000 tonnes/     batch producer in china,
 uK’s largest plastics          facility at its site in the Tianjin   year in the future.               thanks to its plant in Hong
 recyclers, has been bought     Economic development Area                Sean Keohane, vice             Kong. it is also growing in the
 by chamonix private Equity     (TEdA), china. it is investing        president and general             middle East with the opening of
 along with four other          uS$20 million in the com-             manager of cabot’s perform-       its 25,000 tonnes/year facility in
 businesses from the linpac     pounding plant which will have        ance Segment said: “demand        dubai, uAE, in August last year.
 group. They are described      an initial capacity of 45,000         for masterbatch in china and      The latter plant’s capacity can
 as “non-core” to linpac.       tonnes and is scheduled to be         the broader Asia pacific region   be trebled if required.
    linpac recycling, which     completed in mid-2011.                is growing rapidly. Having a         The company’s European
 recycles post-use rigid           in 2009, cabot doubled             local manufacturing facility      masterbatch production is
 plastic into recycled          carbon black production               producing high-quality            being consolidated into its
 compounds for a wide           capacity at its TEdA plant to         products to serve our custom-     loncin and pepinster sites in
 range of moulding applica-     300,000 tonnes/year. The              ers will be a significant         Belgium. it closed its uK
 tions and end-use markets,     company says that the addition        competitive advantage for us”.    compounding plant in dukin-
 will change its name to        of the compounding facility will      Target markets will include the   field in Summer 2009 and it is
 regain polymers.               make it the world’s first fully       pipe, wire, cable and automo-     ending masterbatch production
 ❙ www.linpac.com               integrated black masterbatch          tive sectors.                     in grigno, italy, this month.
 ❙ www.regainpolymers.com       plant. it will be possible to            in volume terms, cabot is      ❙ www.cabot-corp.com




npE 2012 attracts high levels of interest
                                                                      representatives from more         the previous npE show, which
                                                                      than 650 exhibiting companies     was held in chicago in 2009.
                                                                      travelled to orlando, Florida,    After 38 years in chicago, the
                                                                      uSA, last month to take part in   event is being relocated to
                                                                      the draw for stand space at the   orlando in 2012 in a move that
                                                                      npE 2012 exhibition, north        is designed to save costs for
                                                                      America’s leading plastics        exhibitors and visitors.
                                                                      industry event.                      The triennial show is
                                                                         with over a year to go, more   organised by the Spi, the uS
                                                                      than 750 companies have           plastics industry association.
                                                                      contracted almost 62,000 m2 of    its senior vice president of
                                                                      space. This is already equal to   trade shows gene Sanders
                                                                      87% of the occupied area at       said: “The booth selections
                                                                                                        thus far almost completely fill
NPE 2012 exhibitors
                                                                                                        the west Hall of orlando’s
gathered in Orlando
                                                                                                        orange county convention
to select their stand
positions and tour                                                                                      centre, and the South Hall is
the new venue                                                                                           filling up quickly”.
                                                                                                           npE takes place on 1-5
                                                                                                        April 2012. The SpE’s AnTEc
                                                                                                        annual technical conference
                                                                                                        will take place alongside the
                                                                                                        exhibition.
                                                                                                        ❙ www.npe.org

www.compoundingworld.com                                                                     February 2011 | compounding world          11
news




BASF boosts production                                                                                   news in brief

of biodegradable plastics
                                                                                                         ❙ Spartech Polycom is
                                                                                                         restarting production at its
                                                                                                         pp compounds plant in
                                                                                                         lockport, new York, uSA,
The new Ecoflex biodegradable plastics                BASF has started up its expanded Ecoflex           after it was closed in late
plant adds 60,000 tonnes of new capacity              plant in ludwigshafen, germany, increasing         2009 as a result of declining
                                                      production capacity for the biodegradable          demand from the automotive
                                                      polyester from 14,000 to 74,000 tonnes/year. it    market and in particular the
                                                      is also increasing compounding capacity for        delphi Harrison Thermal
                                                      Ecovio, which is a blend of Ecoflex and plA        Systems plant also located in
                                                      bioplastic.                                        the same town.
                                                         Ecoflex is a synthetic plastic that has         www.spartech.com
                                                      properties similar to those of polyethylene, but
                                                      is fully biodegradable under industrial            ❙ Cray Valley has signed an
                                                      composting conditions in accordance with din       agreement with the Grolman
                                                      En 13432. Ecovio is also biodegradable, but        Group for the distribution of
                                                      contains up to 75% renewable raw materials.        its products to the plastics
                                                         Typical applications include shopping bags,     markets in germany,
                                                      mulch films for agricultural applications, bags    Switzerland, Austria and
                                                      for organic waste and food packaging. BASF         Benelux. grolman will focus
                                                      says that demand for biodegradable and bio-        on selling cray valley’s
                                                      based plastics is currently growing at more        specialty low-molecular-
                                                      than 20% per year.                                 weight functional additives to
                                                      ❙ www.basf.com                                     compounders and master-
                                                                                                         batch makers.
                                                                                                         www.grolman-group.com

cytec grows stabilizer capacity                                                                          www.crayvalley.com

                                                                                                         ❙ EnerPlastics of dubai has
cytec industries is increasing    plastics and coatings is            l in a separate move, cytec        begun production of oxode-
production capacity for light     growing,” explained domenico        has sold its building block        gradable additive master-
stabilizers by more than 30%      romanino, global business           chemicals business to an           batch for use in polyolefins.
at its plant in willow island,    director for polymer additives      affiliate of Hg capital for        called Ep oBd, the product
west Virginia, uSA. The           at cytec. “we are expanding our     uS$180 million. The product        is claimed to meet French
expansion is expected to be       manufacturing capabilities for      lines include acrylonitrile,       standards for oxodegradation
completed by the beginning of     several product lines including     sulphuric acid and melamine        and has been certified by the
2012, says the company.           cyasorb THT and cyasorb             which are produced mostly for      centre national d’Evaluation
     “global demand for high-     cynergy Solutions stabilizers to    sale to third parties.             de photoprotection in France.
performance uV protection for     meet customers’ needs.”             ❙ www.cytec.com                    www.enerplastics.com

                                                                                                         ❙ A Schulman has been
Adeka invests in polyester additives for pVc                                                             awarded a 2011 deal maker
                                                                                                         Award from the Association
Adeka is expanding production        The expansion will increase           The polyester additives are   for corporate growth’s
of polyester-based additives      capacity for polyester-based        used as plasticizers, predomi-     cleveland chapter in ohio,
for pVc applications at its       additives at the chiba plant by     nantly in pVc and rubber.          uSA. The company was
plant in chiba, Japan. The        5,600 tonnes/year. Along with       Adeka says that demand is          recognised for its three
company is investing ¥1.5         additional plants in Japan,         expanding for applications in      acquisitions in 2010 – ico
billion (E13 million) in the      china and Thailand, it will take    construction materials and         polymers, mccann color and
project which is scheduled to     Adeka’s total capacity for the      automotive interiors.              mash compostos plasticos.
start production in April 2012.   products to 22,000 tonnes/year.     ❙ www.adeka.co.jp                  www.aschulman.com

12     compounding world | February 2011                                                                   www.compoundingworld.com
M
                                M A S T E R B AT C H

                                                  2 0 1 1
                                              Integrating Colour and Design




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                                                    7-9 June 2011
                                          The Imperial Riding School Vienna,
                                         a Renaissance Hotel, Vienna, Austria




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            Sabine Prack – Conference Coordinator sp@amiplastics.com Ph: +44 117 924 9442 Fax: +44(0)117 311 1534
Colour trends | news




Clariant colours in the future
Each year Clariant’s experts       movement, evolution and             “natural hues that evoke the       dabra that is described as a
predict the global plastics        surprise – bright, lively and       magic of ancient mythologies”.     mysterious violet.
colour trends that lie ahead.      quirky hues and special effects     Examples include: Echo of              Building on the “In-Fusion2”
We take a first look at their      – will prove popular in 2012. At    Silence, a delicate sand colour;   theme from last year, “In-
brand new tips for 2012            the same it predicts that the       Itzamná, a terracotta orange       Fusion3” recognises the
                                   public will be seeking soft,        overlaid with burgundy red ;       blending of the human and the
Global colour trends are being     muted, earthy and organic           and Inner Strength, a deep,        technological through
driven by economic, technologi-    tones that convey introspec-        dark non-black with a tinge of     augmented reality created by
cal, political and philosophical   tion, stability and personal        primal green.                      digital media, 3D entertain-
changes, according to Clariant     responsibility. It says that this      The “Creative Confusion”        ment and motion gaming.
Masterbatches. The rapid           apparent contradiction may be       trend is said to represent the     Colours in this grouping are
changes that are happening in      because confusion is also an        ambiguity and surprise sought      otherworldly. For example,
these areas have been taken        element in some of the major        by people who no longer want       Hyperlight is made up of
into account in its new            societal trends.                    mass-produced sameness and         different glitter colours that
ColorForward 2012 report. This        The four themes for 2012         blandness in their product pur-    can only be reproduced in
is designed to help designers      include “Me... Under Con-           chases or in their lives. The      moulded plastic, while
and brand managers make            struction”, reflecting the need     colours are bright and fun,        StarLED is a purplish blue
successful colour choices for      for introspection and self-         taking advantage of special        colour co-injected with a layer
plastics products and packag-      questioning at times of rapid       effects and combinations.          of silver starburst.
ing that will be marketed a year   change. It also acknowledges        Examples include Bizarre, a            The final trend, “Re-
or more in the future.             the ending of the Mayan             fusion of translucent purple       Volition” is a response to the
    Clariant forecasts that        Calendar on 21 December             and yellow that creates a          negativity that has gripped the
colours that mirror a sense of     2012. The palette incorporates      strange green, and Abraca-         world in the latter part of the
                                                                                                          last decade and the way that
                                                                                                          people look inward to seek a
                                                                                                          resolution. The palette is
                                                                                                          described a pure and unadul-
                                                                                                          terated, featuring solid colours
                                                                                                          without special effects.
                                                                                                          Examples include: Mind
                                                                                                          Switch, a lively yellow/orange;
                                                                                                          Collaboraction, a warm red;
                                                                                                          and New Equilibrium, a stable
                                                                                                          pearlescent brown.
                                                                                                              The colours reproduced
                                                                                                          here are for indication
                                                                                                          purposes only as many use
                                                                                                          special effects that that cannot
                                                                                                          be illustrated accurately on
                                                                                                          screen. The ColorForward
                                                                                                          2012 pack contains moulded
                                                                                                          plaques to accurately repre-
                                                                                                          sent the colours. Click here to
                                                                                                          request one and click here to
                                                                                                          see an animated presentation
                                                                                                          of the ColorForward 2012
                                                                                                          predictions and full details of
                                                                                                          the different colours.
                                                                                                          ❙ www.clariant.masterbatches.com

www.compoundingworld.com                                                                     February 2011 | CoMpouNDING worLD         15
news | Technology



Researchers use carbon dioxide to
impregnate plastics with additives
Researchers in Germany are         conducted with silica and
investigating how compressed       flurbiprofen, the anti-inflam-
CO2 can be impregnated into        matory active pharmaceutical
plastics to act as a carrier for   ingredient, have also been
dyes and additives. The work is    successful.
being carried out at the              At a temperature of 30.1oC
Fraunhofer Institute for           and a pressure of 73.8 bar, CO2
Environmental, Safety and          goes into a supercritical state
Energy Technology (UMSICHT)        that gives the gas solvent-like
in Oberhausen.                     properties. When it is in this
     The researchers say that      state, it can be introduced into
the technology provides a          polymers and used as a carrier
route for impregnating plastics    for dyes, additives, medical
with heat-sensitive additives or   compounds and other
pigments that cannot with-         substances.
stand the high temperatures of        Manfred Renner, a scientist
injection moulding or other        at Fraunhofer UMSICHT,
processes. In addition, the        explains the process: “We
technology can be used to          pump liquid CO2 into a high-
apply expensive additives and      pressure container with the        This phase diagram shows how Co2 beComes
pigments in a thin layer at the    plastic components that are to     superCriTiCal aT CerTain pressures and TemperaTures
part’s surface where they are      be impregnated, then steadily
normally needed, rather than       increase the temperature and          The process takes a few           One potential application
throughout the whole volume        pressure until the gas reaches     minutes – the researchers         highlighted by the researchers
of the component.                  the supercritical state. When      quote five minutes to dye a       is in contact lenses. The
     Early tests have involved     that state is reached, we          plastic part yellow at 90oC and   process could be used to dye
impregnating polycarbonate         increase the pressure further.     200 bar. Once the process is      the products as well as
with nanoparticles that give it    At 170 bar, pigment in powder-     completed, the container is       enriching them with pharma-
antibacterial properties,          form dissolves completely in       opened and the gas escapes        ceutical compounds that would
completely killing off e-coli      the CO2 and then diffuses with     through the surface of the        be slowly released to the eye
placed on its surface. Work        the gas into the plastic”.         plastic, leaving behind the       throughout the day. An
                                                                      pigment or additive.              example would be replacing
                                                       This plastic      According to the UMSICHT       eye drops for treating glau-
                                                     propeller was    researchers, the process is       coma.
                                                    dyed yellow in    suitable for impregnating         l Fraunhofer is Europe’s
                                                      five minutes    partially crystalline and         largest application-oriented
                                                        at 90oC and   amorphous polymers such as        research organisation with
                                                            200 bar   PA, TPE, TPU, PP and PC, but      more than 80 research units,
                                                                      it cannot be applied to           including 60 Fraunhofer
                                                                      crystalline plastics. They        Institutes, at different locations
                                                                      emphasise that CO2 is non-        in Germany. It employs more
                                                                      flammable, non-toxic and inex-    than 18,000 people and has an
                                                                      pensive, and although it          annual research budget of
                                                                      behaves like a solvent, it does   E1.65 billion. UMSICHT
                                                                      not present the health and        focuses on process engineer-
                                                                      environmental issues often        ing technologies.
                                                                      associated with solvents.         ❙ www.umsicht.fraunhofer.de

16     COMPOUndInG WORld | February 2011                                                                  www.compoundingworld.com
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plastics recycling | factory report



                                                                                                        Just over a year after
                                                                                                        a fire destroyed its
                                                                                                        sorting facility, uK
                                                                                                        recycler Eco plastics
                                                                                                        is back, bigger and
                                                                                                        better than ever.
                                                                                                        Nadya Anscombe
                                                                                                        finds out more about
                                                                                                        Europe’s largest
                                                                                                        plastics bottle
                                                                                                        recycling plant




Bottle recycler bounces back
Visitors to a plastics recycling facility expect to see a dirty   when the fire happened,” says Short. A mechanical               The Eco Plastics
environment, especially when the plastics being recycled          failure in a fan in the sorting facility was found to be the    plant processes
are post-consumer waste. But visitors to uK recycler Eco          cause and the sorting facility was burnt to the ground.         around 100,000
plastics (formally AwS Eco plastics) are often surprised          “luckily the processing facility, which houses the bigger       tonnes/year of
how clean and efficient the company’s facility is,                investment, survived,” says Short.                              post-consumer
according to managing director Jonathan Short.                       now, instead of being housed in a 1940s aircraft             plastics bottles
   The company, which built its first sorting plant for           hangar, the sorting facility is in a larger, modern, light      and plans to
plastics waste in 2006, is now by far the largest                 facility which has enabled the company to improve               grow this by 40%
producer of food-grade recycled pET (rpET) in the uK              efficiency. “instead of trying to fit a process into a space,
and also has the largest plastic bottle recycling facility




                                                                                              “
in Europe. “we don’t really see ourselves as plastics
recyclers anymore,” says Short. “But rather as a                                      We don’t really see
manufacturer of food-grade plastics that happens to
use post-consumer waste as its raw material.”                                      ourselves as plastics
   The company has seen a huge rise in demand for
food-grade rpET and has been expanding to meet this
                                                                                   recyclers anymore, but rather
demand. But the brand-new E20 million sorting facility
located in Helmswell, lincolnshire, is not just a result
                                                                                   as a manufacturer of food-
of this increased demand. A year ago a devastating fire
                                                                       grade plastics that happens to use post-

                                                                                                                                          ”
ripped through the old sorting facility and the company
had to work hard to rebuild its business. “we had just                 consumer waste as its raw material
gone through an expansion phase, installing Sorema
hot-wash lines and Erema compounding machinery                         Eco PlAstics’ MD, JoNAthAN short


www.compoundingworld.com                                                                             February 2011 | compounding world           19
factory report | plastics recycling




Left: The          we were able to first design an efficient process and build    and can handle up to 11 streams of plastic material. it is
company’s 17       the building around it,” says Short. For example, because      this ability to deal with many different plastics that has
Titech optical     the new facility is taller, it makes more use of gravity,      resulted in very low waste levels. “most plastic recy-
sorters can        reducing the need for conveyors and cutting maintenance        clers have about 25% process waste,” says Short. “ours
now do their       costs. it also enables more straight process flows which       is around 8% and that is mainly dust and evaporation.
job more           result in improved sorting. Straight process flows mean        we can recover all the different kinds of plastic
effectively as     the product is more spread out and the company’s 17            including bottle tops and other parts.”
the material is    Titech optical sorters can do their job more effectively.         The company is now unrecognizable from the small
spread more        “our new facility is also future-proof,” says Short. “we       sorting facility set up in 2006 which exported all of its
evenly             are already planning our next expansion phase.”                products to the Far East. “Some of our product is still
                      The company currently processes around 100,000              exported, but we want to limit our exposure to the Far
Right: The new     tonnes/year of post-consumer plastic bottles but plans to      East,” says Short. “As china becomes wealthier and its
purpose-built      ramp that up to 140,000 tonnes by 2011. This represents        people consume more, the chinese will have their own
facility has       nearly half of all the post-consumer plastic bottles           waste to deal with and will not need ours any more. This
meant improved     collected in the uK today. in 2006, when Eco plastics was      is why it is so important for countries like the uK to
material flows     first set up as a sorting facility, the uK collected 108,000   build their own infrastructure and recycle their own
                   tonnes of plastic bottles. By 2009 this had risen to nearly    waste plastic.”
                   260,000 tonnes and a recent report by recoup shows                with this, and the increasing amount of plastic being
                   300,000 tonnes will have been collected during 2010.           collected in the uK, in mind, Short expects more
                   “Supply is plentiful,” says Short. “And so is demand. we       companies to jump on the bandwagon. “But the
                   are the largest producer of rpET in the uK, but demand         challenges of recycling post-consumer plastic waste
                   is three or four times what we are producing.”                 into a product suitable for direct food contact are not to
                      This is why the company plans to ramp up its food-          be underestimated,” he says. “Anyone can go and buy
                   grade rpET production from today’s 15,000 tonnes per           the equipment, but having the know-how of how to
                   annum to 40,000 tonnes by mid-2012. This equates to            make the most of that equipment and how to get high-
                   88% of the current uK total.                                   quality product out of it is the key to our success.”
                      This will of course mean more investment in
                   compounding equipment. The company currently has               More information
                   one Vacurema extruder from Erema for pET and is                Click here to see an interactive diagram showing the
                   planning to invest in “at least one more” in order to          layout of Eco plastics’ Helmswell plant along with
                   fulfill these expansion plans.                                 details of each component.
                      As well as food-grade rpET, Eco plastics also sells         ❙ www.ecoplasticsltd.com
                   rpET flake to thermoformers. while pET and HdpE                ❙ www.sorema.it
                   bales are its main products in terms of percentage of          ❙ www.erema.at
                   input, the company processes a very mixed feedstock            ❙ www.titech.com

20   compounding world | February 2011                                                                         www.compoundingworld.com
Ralf Simon
                                                            Managing Director

                                                            „ With steady innovations
                                                              we remain your reliable
                                                              and safe partner.“




                                                                                         BKG pelletizer




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                                                                   barcode reader „i-nigma“               BEST TECHNOLOGY INSIDE !
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compounding  extrusion   materials handling   service



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twin screw extruder is the most productive high performance ZSK of all times. With its specific
torque of 18 Nm/cm3 it stands out for considerable throughput increases with improved product
quality and maximum efficiency. It heralds the next generation of processing technology to pro-
vide you with a unique advantage in technology. That’s what we mean when we say “confidence
through partnership”. www.coperion.com
COMPOUNDING  PROCESSING 2011
       International industry conference on the profitable use of bioplastics

                                                                                                                                                                                      N o va m o nt




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                        Here for
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                                                                                      March 29-30, 2011
                        CAR
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                                                                                      The Hilton Miami Downtown
                          Co




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                                            la n                                                                                                                4 c o ve r m a d e fr o m In g e o
Images courtesy of:                                tL o
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NatureWorks, Novamont                                          m   a d e fro m In g
and Propper



                        final reminder – book now!
   Organized by:                                                                                                  Media Sponsors:
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                    Jessie martin – Conference Coordinator jm@amiplastics-na.com Ph: +1 610 478 0800 fx: +1 610 478 0900
recycling equipment | processing feature




 Focus on plastics recycling machinery
 With growing volumes of plastics being           the recycling process as well as the           market including extruders, shredders,
 recycled, equipment manufacturers                quality of the end product.                    dryers, separators and filtration
 have been responding with new                       On the following pages we look at           systems designed for tough recycling
 technology to improve the efficiency of          some of the latest equipment to hit the        applications.




gneuss wins order for its
largest mrS extruder
The K show proved very              The Gneuss MRS
successful for german               eight-screw
machinery maker gneuss, with        extruder
several orders completed at the     offers very
show including the sale of an       high levels of
mrS 200 extruder to a custom-       devolatizing
er in Brazil. The extruder, which   performance
has a throughput of up to 2
tonnes/hour, is the largest                                                                                  a gneuss rSFgenius 150 melt
gneuss has sold to date and will                                                                             filter and ViS on-line viscom-
be used in the customer’s state-    design, the devolatilizing          direct extrusion into films or       eter. The turn-key system is
of-the-art pET bottle-to-bottle     performance is claimed to be        fibres. The machine also             capable of processing waste
recycling line. The extruder        50 times greater than that of a     provides excellent decontami-        material at 500-700 kg/h to
features gneuss’s multi-            conventional single-screw           nation performance. last year        produce material that is
rotation system (mrS) which         extruder – and this at a            the uS FdA issued a letter of        comparable with virgin
enables the processing of pET       vacuum of only 25 to 40 mbar.       non-objection for using the          polymer according to gneuss.
post-consumer waste without         This eliminates the need for a      extruder for reprocessing                The sales of mrS extruders
pre-drying.                         high vacuum system and pre-         material for the food industry.      have contributed to consider-
   mrS is a drum containing         drying.                                At K 2010 gneuss launched         able growth at gneuss. The
eight satellite single screws,         in the three years since         a complete line for the direct       company has invested heavily
driven by a ring gear and           gneuss introduced its mrS           recycling of pET fibre or film       in new buildings: a new
pinion transmission. The            extruder at K 2007 it has sold      scrap. Built around its mrS          assembly workshop and a new
“barrels” cut into the drum are     more 16 lines for the process-      110 extruder, the system             processing technical centre
approximately 30 % open and         ing of pET post-consumer            features an integrated cutter/       have doubled the production
provide optimum exposure of         flakes without pre-drying,          feeder supplied by ngr               area in order to meet demand.
the melt. Thanks to this            either for repelletizing or for     recycling machines as well as        ❙ www.gneuss.de




Titech opens waste separation test facility
Titech has opened a 1,500 m²        ballistic separator, the test       be accurately simulated.             manager, commented: “The
sensor-based test facility for      facility uses all of Titech’s          during testing, changes can       facility allows us to work with
plastics sorting at its head-       sorting and recycling technolo-     be made which ensure that the        customers to ensure that the
quarters in mülheim-Kärlich in      gies. it has been designed to       sorting systems are calibrated       systems will be deployed to
germany.                            allow several different             to deliver optimum levels of         their sites and immediately
   Set out in a loop which          processes to run concurrently       sorting and recycling for            begin working as efficiently as
prepares the waste by               so that a customer’s facility       specific requirements.               possible.”
screening it and using a            and operating environment can          ralph uepping, test facility      ❙ www.titech.com

www.compoundingworld.com                                                                      February 2011 | compounding world             23
processing feature | Recycling equipment



 Kreyenborg
 builds largest
                                   New Lindner shredder
 infrared dryer                    concept boosts flexibility
 Kreyenborg Plant Technol-         Lindner reSource has              range of different square-         filling capacity ensures a
 ogy has developed a large         launched the Micromat Plus        blade or point-blade rotors can    constantly high material flow.
 infrared drum dryer for           series of variously configura-    be fitted. Easily replaceable      Production waste with different
 drying PET bottle flakes          ble single-shaft shredders for    screens with 10 to 300 mm          material characteristics, such
 with a throughput of 3,500        recycling plastic waste.          hole diameters make for even       as hard plastics, filaments or
 kg/h. The system, with            Available in three sizes, these   greater versatility, while the     films, can therefore be
 drum dimensions of 2,500          units are designed with low       patented maintenance hatch         shredded just as efficiently as
 mm diameter and 5,400             energy consumption and high       facilitates the replacement of     post-consumer plastics such
 mm length, is the largest         productivity in mind.             blades and counter-blades.         as PET bottles, agricultural
 built by the company.                Three different drive             The shredder’s newly            film or carpeting.
      It features 540 kW of        concepts are offered to           developed internal force feeder       Selecting the optimum rotor
 installed radiator output         accommodate specific              can be adapted to a given          and blade types will depend on
 and is designed to dry PET        application needs, while a        application, and an increased      the application. For shredding
 bottle flakes with a bulk                                                                              problematic material such as
 density of about 0.35 kg/          Lindner’s Micromat Plus can                                         big bags, filaments or stretch
 dm³, from maximum 1 %              be configured to shred                                              film, Lindner proposes its
                     ‹
 initial moisture to 0.05%          wide variety of                                                     point-blade rotor providing
 and to crystallize it at the       waste plastics                                                      high cutting precision. The
 same time. Due to the short                                                                            square-blade rotor is optimized
 residence time of 10-15                                                                                for hard plastics and combines
 minutes, there is signifi-                                                                             superior pull-in control with an
 cantly less material in the                                                                            energy-saving power require-
 drying process, eliminating                                                                            ment and RPM level.
 the need for huge drying                                                                                  All rotors are available with
 vessels to process high                                                                                wear protection and can be
 throughputs of low-bulk-                                                                               equipped with cooling
 density flakes.                                                                                        capabilities.
 ❙ www.kreyenborg.de                                                                                    ❙ www.lindner-resource.com




Rapid expands granulator range
Rapid has developed its largest    granulation applications.         operator can gain access to the
‘open hearted’ granulator to          Bengt Rimark, Rapid’s          rotor and cutter at the heart of
date, by adding a 1,500mm          marketing director, said: “The    the machine in three simple
wide model to its 600 series.      600-Series uses the same          steps, without needing any
     The series, which has a 600   patented technology as the        tools. The granulators also
mm diameter rotor, is already      300, 400 and 500 series           come with Rapid’s
available 900 mm and 1200          granulators. The concept is       Mineral Composite
mm widths. It is designed for      completely modular and can        Technology (MCT)
the high volume granulation,       be tailored to any application    base, which is a
and can handle throughputs up      within the plastics processing    vibration-absorbing
to 3,500 kg/h. There are 45        and recycling industry.”          heavy platform that
standard base configurations          The ‘open-hearted’ design of   helps to reduce noise
available, so it can be tailored   the 600 series means that,        levels during operation.
to suit the majority of large      during a production change, the   ❙ www.rapidgranulator.se

24     CoMPouNDINg WoRLD | February 2011                                                                  www.compoundingworld.com
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processing feature | recycling equipment



 conair and
 rajoo work
 together on
 pET project
 At the recent K show, indian
 extrusion machinery


                                                                Screen-changer
 supplier rajoo Engineers
 demonstrated an extrusion
 line running recycled pET
 (rpET) sheet. The line,
 which produced a three-                              meets recycling challenges
 layer clear pET sheet
 intended for thermoforming        The latest generation of            collected in a permanently         backflush filter changes to the
 of disposable containers,         screen-changers from maag           flushed accumulating space         operating mode and starts the
 featured a full range of          now meets all requirements of       and will then clean the dirty      fully automatic cleaning of the
 crystallizing, drying and         direct recycling processes,         screen cloth outside the           screens which is controlled by
 material handling equip-          such as the fabrication of food-    production process by              pressure or time and depends
 ment supplied by conair.          wrapping films from pET bottle      backflushing. in this way,         on the level of dirt accumula-
     The sheet line incorpo-       flakes in one process step.         variations in pressure and         tion. The recycling screen
 rated two extruders – a 90-          maag’s new cSc/BF-pE             volume are largely avoided and     changers are based on the
 mm / 30d / 76-kw unit that        screen-changers feature fully       the effects on the final product   well-proven double-piston
 processes the rpET flake          automated cleaning which can        are minimized.                     design which does not need
 that makes up 90% of the          be adjusted to any kind of             Specific set points can be      any additional seals and
 finished sheet, and a 50-mm       process. The quantity of            programmed into the control        ensures a reliable and leak-
 / 30d / 22-kw unit that runs      material which is needed for        system to suit the process.        proof operation.
 the virgin pET that forms the     backflushing of the screens is      when these are reached, the        ❙ www.maag.com
 outer layers of the sheet.
     conair supplied the
 materials handling and
 conditioning equipment
 upstream from the extrud-
                                   Extricom supplies ringExtruder
 ers, including a cr42             Extricom has delivered a            tion of material taking place in       Extricom is supplying one
 crystallizer, which efficiently   ringExtruder rE7 XpV for            a double helix: around the                of its 12-screw RingEx-
 processes amorphous pET           high-quality bottle-to-bottle       stationary core and around             truders to a PET bottle-to-
 flake at temperatures up to       recycling to a customer in          each screw.                               bottle recycling plant in
 177°c (350°F) with continu-       Eastern Europe. The high-duty       ❙ www.extricom.de                                 Eastern Europe
 ous agitation to prevent          plant has a throughput of 3,500
 agglomeration. conair’s           kg/h pET bottle flakes
 carousel plus dryers were         equating to an annual capacity
 used for processing the           of 27,500 tonnes recycled pET.
 materials, while its drying          The company’s ringExtrud-
 hoppers provided mass             er design features 12 screw
 material flow and uniform         shafts arranged symmetrically
 air/heat distribution.            in a ring. They all rotate in the
     rajoo has supplied more       same direction, each on its
 than half a dozen rpET lines      own axis. The outer barrel
 within the past 12 months.        and the stationary core
 ❙ www.rajoo.com                   enclose the screws with a
 ❙ www.conairgroup.com             narrow gap with transporta-


26   compounding world | February 2011                                                                      www.compoundingworld.com
The international conference and exhibition for
      The international polypropylene film industry
        the bi-oriented conference and exhibition for
                                                           A TURN AHEAD
      The international polypropylene film industry
        the bi-oriented conference and exhibition for
      The international polypropylene film industry
        the bi-oriented conference and exhibition
      The internationalconference and exhibition for for
                                                           TO MORE
        the bi-orientedpolypropylene film industry
         the bi-oriented polypropylene film industry       EFFICIENCY.
                                     SAV
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                                 THE DE T
                                   SASAVT
                               28-E 0 DAE E
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                               28-3E Aune
                                     DJ
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d. AMI’s BOPP Film conference is now well
. AMI’s BOPP Film conference is now well
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   AMI’s BOPP as the leading forum for the
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   established Film conference forum for the
   world industry. the conference is now well
   established as
   AMI’s industry. the leading forum forfor the
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   world’s tonnes of PP resin purchase). over 2
   To viewtonnes of PP resin purchase). here
                  details on this event click
   million moredetails on this event click here
    To view more
   To view more details on this event click here
   To view more details on this event click here
   To view more details on this event click here
                 28 -30 June 2011
                 28 -30 June 2011                          Technology made by Gneuss:
             AustriaTrendJune 2011
                 28 -30 Savoyen Hotel,
                 28 Trend Savoyen Hotel,
             Austria -30 June 2011
             Austria Trend Austria Hotel,
                            Savoyen
                 28Vienna, Austria Hotel,
                    Vienna, Savoyen
             Austria -30 June 2011
                     Trend
                    Vienna, Austria
                    Vienna, Austria
             Austria Trend Savoyen Hotel,
                    Vienna, Austria
      For furtherdetails please contact:
       For further details please contact:                 Thanks to their high performance and constant
                                                           mode of operation, our technologies developed
      Becky Merriott, Conference contact:
       Becky Merriott, Conference  Manager
      For further details please contact:
      For further details please Manager                   for the plastics-processing industry increase the
       E-mail:Merriott, Conference Manager
                 rm@amiplastics.com
      Becky rm@amiplastics.com
      E-mail:Merriott, Conference Manager
      Becky rm@amiplastics.com
      For further details please contact:                  cost efficiency of every production process. Your
      E-mail: 117 924 9442
       Tel: +44
      Tel: +44rm@amiplastics.comManager
      E-mail: 117 924 9442
                                                           production line benefits from maximum availabili-
      Becky Merriott, Conference
      Tel: +44 117 924 9442                                ty while at the same time guaranteeing optimum
      Tel: +44 117 924 9442
      E-mail: rm@amiplastics.com                           product quality, even when using 100 % recycled
      Tel: +44www.amiplastics.com
                  117 924 9442                             material.

                  www.amiplastics.com                      With Gneuss you are always a decisive turn ahead!
                  www.amiplastics.com
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   Organised by:                 Sponsored by:
    Organised by: www.amiplastics.com                      Visit us at CHINAPLAS!
   Applied Market                                          17.05.11 - 20.05.11
    Applied Market
   Organised by:Ltd.                                       Hall 5.1, Stand D 21
   Information
    Information Ltd.
   Organised by:
   Applied Market
   Organised by:
   Applied Market
   Information Ltd.
   Platinum sponsor:
   Applied Market
   Information Ltd.
   Organised by:                                           www.gneuss.com
   Information Ltd.
   Applied Market                                                                                    a turn ahead

   Information Ltd.
additives feature | Mineral fillers




  Dr Chris DeArmitt was chairman for AMI’s recent
  Minerals in Compounding conference in Atlanta,
  Georgia, USA. Here he reports on the wide
  range of presentations covering the latest
  developments in materials and
  processing technologies




Making the most of minerals
                   Interest in fillers is as strong as ever, as illustrated by   hard to understand and complex equations are needed
                   the healthy attendance and the diversity of technologies      to fit the data. In fact it turns out that properties depend
                   presented at the recent AMI Minerals in Compounding           upon the volume percentage of the filler and polymer
                   conference in Atlanta, Georgia, USA. Topics spanned the       phases, not the weight percentage. Plotting data that
                   range from traditional fillers to new entrants and from       way often results in straight lines. Another myth is that
                   additives like dispersants and coupling agents to             fillers have lower specific heat capacities than poly-
                   processing equipment to optimise production through-          mers, thus helping reduce heating and cooling times.
                   put and material properties.                                  Although fillers do indeed speed production through
                      The conference was kicked off by Dr Chris DeArmitt         their high thermal conductivity, it was shown that the
                   of Phantom Plastics who gave an introduction to filled        specific heat capacities of fillers and polymers are
                   plastics including how different types of filler alter the    precisely the same on a per unit volume basis.
                   mechanical and other properties of plastic materials.            Charles-Etienne Houssa of Omya continued with a
                   Each type of filler has its own niche according to the        look at calcium carbonate which is one of the most
Quarzwerke         properties of the filler and the size and shape of the        popular fillers because it is inexpensive and improves
compared a         filler particles. He also emphasized the importance of        several properties of polymers such as modulus and
selection of       dispersants and coupling agents in optimizing compos-         cooling times. In some cases, it can also increase
filler types in    ite processing and properties.                                impact performance and environmental stress cracking
different             He then dispelled some myths about filled plastics.        resistance.
engineering        For example, properties are usually plotted versus the           The price of calcium carbonate is more stable than
plastics           weight % of filler, often resulting in curves which are       polymer prices and has historically increased more




(Left to Right): Muskovite Mica, Phlogopite Mica, Low-aspect-ratio Wollastonite, High-aspect-ratio Wollastonite, Platy Kaolin


28   CoMPoUnDInG worlD | February 2011                                                                        www.compoundingworld.com
Mineral fillers | additives feature




                                                             cooling and therefore higher production output. In PP                 Mondo
                                                             and PA, talc also helps nucleated crystallization leading     produces very
                                                             to a further increase in production output.                   high purity talc
                                                                Dr Jörg Zilles of HPF The Mineral Engineers, which is      using a super-
                                                             a division of Quarzwerke, presented studies on mica               conducting
                                                             (Phlogopite and Muscovite variants), Wollastonite (low-        magnet and a
                                                             aspect-ratio and high-aspect-ratio) and platy Kaolin all             flotation
slowly than that of polymers. For example HDPE prices        at 20 weight % in PA6, PBT, ABS, PPS and PSU. Mechani-               process
increased 125% from 2000 to 2010. In contrast CaCO3          cal properties were measured comprehensively as well
increased just 50% over the same period. This gives the      as the difference in shrinkage parallel and perpendicular
expectation that more and more filler will be used in        to the injection direction. The latter measurement gives
future years.                                                an indication of the tendency to warp.
                                                                Overall, the fillers tended to increase modulus,
Natural born fillers                                         strength and HDT while reducing warpage. The only
Calcium carbonate filler is formed through a process         downside was some loss in impact resistance commonly
known as diagenesis whereby sea organisms are                found when adding fillers to polymers. For each plastic
deposited on the sea bed and then converted to calcium       there was a filler which provided the best property
carbonate sedimentary rock. It turns out that 300            balance. Phlogopite was found to be the preferable filler
million metric tonnes are deposited in the oceans per        for PA 6, while high-aspect Wollastonite showed the best
year but only 75 million tonnes are quarried, making         balance of properties in ABS if anisotropy can be
calcium carbonate a sustainable filler.                      tolerated. Low-aspect Wollastonite gave remarkable
   Omya showed some new particle morphologies,               increases in modulus coupled with excellent impact
namely microplatelets agglomerated to make spheres.          strength in PBT, PPS and PPU. Kaolin and Muscovite
Potential applications were not mentioned but one can        mica gave increases in modulus, tensile strength and
imagine that such high surface area particles would be       heat deflection temperature, while shrinkage of the
effective for nucleating foam cell growth and for catalyst   polymer is decreased in an isotropic way.
supports.
   The next presentation by Frans Venema of Mondo            Added strength
Minerals focused on talc which has a higher aspect           Milliken is well known as the market leader for
ratio than calcium carbonate, leading to improved            clarifying agents for PP and nucleating agents for PE
stiffness, HDT and barrier properties. Talc also             and PP. However, Normand Niron’s talk focused on its
increases polymer strength and reduces creep (slow           new product Hyperform HPR-803 which is marketed as
flow) of polymers. One caveat is that impurities are         a filler to replace talc in applications where density and
common, so Mondo performs a flotation process to             surface finish are paramount.
remove other minerals. This process is combined with a          The push for hybrid cars has added complexity and,
special superconducting magnet to remove magnetic            ironically weight to the vehicles. Similarly, the continual
impurities like iron.                                        addition of new features and devices also pushes up the
   As with other mineral fillers, talc increases thermal     weight of vehicles. The manufacturers therefore seek
conductivity substantially, leading to faster heating and    new ways to reinforce automotive plastics to bring the


www.compoundingworld.com                                                                      February 2011 | COMPOUNDING WORLD         29
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Compounding World Feb-2011

  • 1. February 2011 recycling technology takes oFF Making the Most oF Mineral Fillers nucleators deliver clear beneFits rethinking how kneaders work
  • 2. quantec ® 96 EV-10C BUSS KNEADER TECHNOLOGY Cutting-Edge Compounding Technology MX and quantec ® BUSS Kneader Series BUSS innovative 4-flight screw technology sets new benchmarks in the economical processing of temperature and shear sensitive plastics such as PVC and high grade cable compounds: > 2.5 times higher throughputs > Enhanced mixing quality and dispersion > Energy savings up to 25% Buss AG Phone +41 61 825 66 00 Hohenrainstrasse 10 Fax +41 61 825 68 58 4133 Pratteln info@busscorp.com Switzerland www.busscorp.com
  • 3. contents 04 Industry news pAge 19 15 Clariant colours in the future Each year, experts from clariant masterbatches predict the plastics colour trends that lie ahead. we take a first look at their brand new tips for 2012. 16 Using carbon dioxide as a carrier for additives researchers from the Fraunhofer institute are using supercritical carbon dioxide to impregnate plastics with temperature-sensitive additives. pAge 2 19 Bottle recycler bounces back nadya Anscombe reports on how Eco plastics rebuilt Europe’s biggest plastics bottle recycling plant after a fire destroyed its sorting facility. 23 Focus on recycling machinery we look at the latest technology for sorting, shredding, cleaning, drying and extruding waste plastics to produce high-quality recycled materials. pAge 28 28 Making the most of minerals dr chris deArmitt reports from Ami’s recent minerals in compounding conference on the latest developments in functional fillers for thermoplastics. 41 Delivering clear benefits lilli Sherman examines how new clarifying and nucleating agents are growing the market and creating breakthrough applications for polyolefins. pAge 41 47 BP rethinks kneader design we examine Bp process Equipment’s brand new Tri-Kneader, an innovative reinvention of the reciprocating kneader for demanding applications. 51 New products: polymers and additives 54 New products: machinery and equipment pAge 47 56 Compounder of the Month: Cromex of Brazil 58 Dates for your diary coming next issue ❙ pelletizing technology ❙ improving wear and friction properties ❙ polymer distribution in north America ➤ Click here to make sure you get your copy contact us Applied Market Information Ltd Head of business publishing: Andy Beevers E-mail: abe@amiplastics.com Ami House, 45-47 Stokes croft, Contributing editors: lilli Sherman E-mail: editorial@compoundingworld.com Bristol, BS1 3Qp, united Kingdom nadya Anscombe E-mail: editorial@compoundingworld.com Tel:+44 (0)117 924 9442 Fax:+44 (0)117 989 2128 Advertisement manager: claire Bishop E-mail: claire@amimagazines.com www.amiplastics.com direct tel: +44 (0)20 8686 8139 © Copyright Applied Market Information. No part may be reproduced without the prior written permission of the publisher. www.compoundingworld.com February 2011 | compounding world
  • 4. news dSm buys into russian compounding plant dSm has established two joint owned by dSm. it will focus on DSM’s Nico Gerardu ventures with KuibyshevAzot growing the market for pA6 in says that the JVs (KA) of russia covering the russia and the ciS. it will will capitalise on sales and production of target both pA6 compounds anticipated PA 6 polyamide 6 in russia and the and high-viscosity applica- growth in Russia commonwealth of independ- tions, including film. ent States (ciS). As part of the As part of the strategic nico gerardu, member of capitalise on this anticipated agreements, dSm Engineering agreement, KA is licensing the dSm board with responsi- growth.” plastics will acquire 80% of dSm’s cyclohexanone technol- bility for performance KA is a leading producer of KA’s compounding plant in ogy which will allow it to materials, said: “russia is an caprolactam and pA in russia Togliatti, russia. increase pA6 capacity at its increasingly important market and the ciS, and is among the dSm says that this produc- plant in Togliatti to help meet for engineering plastics and it world’s 10 biggest producers tion JV means that it is the first the anticipated increase in is expected that the market for of these products. it had net western pA 6 supplier with its demand created by the new pA6 will double in the next five sales of uS$505 million in own manufacturing presence JVs. dSm Fibre intermediates years. with our partnership 2009 and employs around in russia and the ciS. The will also have drawing rights with KA, i expect that dSm 5,500 people. other JV, which covers sales for part of the increased Engineering plastics will be in ❙ www.dsm.com and marketing, will be 51% capacity. an excellent position to ❙ www.kuazot.ru rhodia acquires pi polymer to Spanish toy makers add grow pA compounds in india conductivity rhodia is acquiring pi Spain’s Toy research polymer, the engineering François Hincker says that institute (AiJu) is leading a plastics compounding acquisition will dramatically research project to examine business of the indian accelerate Rhodia’s growth the use of new conductive company pi industries. The in India plastics compounds to deal is expected to be complet- control electromagnetic ed by the end of march 2011. interference entering and pi polymer forecasts leaving electrical and revenues of approximately electronic toys. uS$13 million for the 2010/11 The collaborative fiscal year. its plant in panoli, project, called Emitoy, will gujarat, employs more than 80 examine the use of carbon people and produces a range François Hincker, president of Following the sale of pi nano-fibres in polyolefins to of technical compounds rhodia Engineering plastics, polymers, pi industries will improve electromagnetic including pA, pc, pBT, ABS said: “we have identified focus on the production of screening, electrostatic and pp as well as some TpEs. strong synergies with our agro-chemicals and the dissipation and electrostatic According to rhodia, the engineering plastics business custom synthesis of fine painting. it is receiving acquisition is part of its in terms of product range and chemicals and pharmaceutical regional government strategy to grows it share of customer portfolio that will intermediates. funding as well as support india’s pA compounds market dramatically accelerate our ❙ www.rhodia.com from the European union. to more than 15% by 2015. growth in india”. ❙ www.piindustries.com ❙ www.aiju.info compounding world | February 2011 www.compoundingworld.com
  • 5. news cereplast and colorTec Eu plans 13.8% tax to benefit from bag ban on chinese cereplast of the uSA has entered a distribution agree- natureworks and BASF’s Ecoflex compostable copolyes- have made the use of bioplas- tic garbage bags mandatory glass fibres ment with the italian master- ter. it can be processed on from the start of this year. The European union (Eu) is batch marker colorTec existing blown film lines and is cereplast already has a deal in likely to impose import covering the sale of bio-based claimed to offer high strength. place to supply its composta- duties of 13.8% on glass and compostable plastics com- “recent environmental ble 3000 film grade resin to fibres imported from china. pounds in southern italy and legislation, such as the plastic another italian masterbatch if approved later this Slovenia. The companies bag ban that went into effect maker, ri.mE, which is using it month, the tariffs will be expect to tap into growing this year in italy, is driving to produce colour masterbatch imposed from 17 march demand for such materials as demand for bioplastics,” said for the European market (see 2011 and will run for a a result of italy’s highly cereplast’s cEo Frederic Compounding World, October period of five years. glass controversial ban on non- Scheer. “we are confident that 2010, page 7). yarns will be excluded from compostable plastic bags. demand will continue to rise in l cereplast has also signed a the import duties. under the terms of the Europe as stores in italy alone deal with another European As reported in Com- agreement, cereplast will use approximately 20-24 compounder, Euroink pounding World, Septem- provide colorTec with its billion plastic bags a year, romania. This company will ber 2010, the Eu imposed compostable 3000 film grade which accounts for one-fifth of use cereplast’s bio-based and an extra duty of 43.6% on 16 resin for the production of all European use”. compostable resins to produce September for a period of masterbatches for the colorTec has a strong colour masterbatch for the six months, while further manufacture of shopping and market position in southern romanian market. investigations into the issue garbage bags. The resin is a italy and works closely with the ❙ www.cereplast.com were carried out. blend of ingeo plA from country’s municipalities that ❙ www.colortec.it The increase has been supported by glass fibre producers who have Americhem invests in three complained about the dumping of chinese new compounding lines material at illegally low prices. However, it has been fought by the users of Americhem has added three fibreglass who believe that compounding lines at its plant the increased tariff will lead in concord, north carolina, to material shortages and uSA, to increase capacity for increase their costs. colour and additive master- The European compos- batches. The expansion will ites industry Association help to meet growing demand (EuciA) welcomes the from the polyester bulk proposed reduction in the continuous filament (BcF) tariff, but argues that a market. Americhem has added 13.8% duty will still be Two of the new lines are set three compounding lines harmful for European users up to produce high-quality at its Concord plant of glass fibres. it also points products in large lot sizes for out that the tariff was only the polyester floor covering “with the floor coverings our customers grow and gain supported by four of the 27 industry. The third is optimised market increasingly shifting to the competitive edge,” said Eu member states, with for the production of small lots the use of pET BcF fibres over Jim cook, the company’s plant most countries abstaining that meet the critical specifi- staple and polyolefin-based manager in concord. in the vote. cations of the textile industry. fibres, Americhem can help ❙ www.americhem.com ❙ www.eucia.org www.compoundingworld.com February 2011 | compounding world
  • 6. news Foster opens medical plastics lab Foster corporation has opened “As the market for medical its medical plastics innovation devices evolves, materials of center at its headquarters in construction become more putnam, connecticut, uSA. critical,” said Foster’s cEo The facility will be used to larry Acquarulo. “For develop advanced polymer example, within the last 20 formulations for leading edge years the outside diameter of a medical devices. it offers typical angiographic catheter polymer compounding, has decreased by 70%, while materials testing and process the working pressures have evaluation for moulding and increased well over 100%. This extrusion. was made possible by particular areas of focus at improvements in polymer the new development facility technologies.” will include nanocomposites A subsidiary of the polyme- and melt-filtered materials, as dex discovery group, Foster well as anti-microbial has been producing thermo- additives for infection control plastics compounds for The new facility is built around materials. Tailored polymers medical applications for more twin-screw extrusion for will also be developed for than 20 years. compound development long-term implants. ❙ www.fostercomp.com Altana buys Kometra Schulman shuts plants Altana is to acquire the in italy and Australia Kometra, the polymer modifier producer based in A. Schulman is closing its administrative office will Schkopau, germany. The manufacturing plants in remain at Verolanuova. company will be integrated Verolanuova, italy, and All production at the into Altana’s BYK additives Breaside, Australia, with the Breaside plant, near mel- business. loss of approximately 40 to 60 bourne, Australia, will be Kometra’s products jobs. Both facilities produce moved to other facilities in the include specific surface- powders for rotomoulding region. The company has a active copolymers which are applications and were plant in Brisbane, Australia, as used as impact modifiers and BYK’s Dr Roland Peter says previously owned by ico well as facilities in malaysia, adhesion promoters. They are that sales of Kometra’s poly- polymers which Schulman indonesia and china. marketed under the Scona mer modifiers will benefit acquired in April 2010. The closure of the Breaside brandname and are produced from his company’s global production lines from the facility was primarily the using a patented solid-state sales network Verolanuova plant will be result of the ongoing deterio- grafting process originally relocated to Schulman’s site in ration of the rotomoulding developed by dow. that BYK’s global sales gorla maggiore, italy, by early business in Australia. in “with Kometra’s technol- network is well positioned to 2012. The latter facility will be particular, demand for water ogy there are new fields of open up new market used to develop and manufac- tanks has fallen following a business which ideally potential for Kometra’s ture value-added technical steady decline in drought complement and expand our polymer modifier technology powders as well as custom conditions and government existing activities,” said dr worldwide. colour masterbatches and rebates have been withdrawn, roland peter, president of ❙ www.altana.com compounds for the local says the company. the BYK division. He added ❙ www.kometra.de market. A commercial and ❙ www.aschulman.com compounding world | February 2011 www.compoundingworld.com
  • 7.
  • 8. news lanxess clariant spearheads starts to build plant reach registrations in india clariant has begun work on “we are delighted to have lanxess has started phase Two of reach legislation completed the task assigned to construction of its new following its successful us,” commented Hariolf 20,000 tonnes/year com- registration of 152 substances Kottmann, clariant’s cEo. pounding plant in Jhagadia, under phase one, ahead of the “our achievement in complet- gujarat, india. it is due on december 2010 deadline. The ing phase one registration line at the start of 2012 and second phase involves more inside the deadline required a will be used to produce pA than 300 chemicals and should lot of long, hard work, and an and pBT compounds. A be completed by 1 June 2013. intensive use of resources”. ground-breaking ceremony in phase one, clariant was l if you need to know more was held at the site in the lead registrant for 81 out of about registering substances January. lanxess is investing the 152 consortia and Sub- for reach, click here to more than E10 million in the stance information Exchange download the latest edition of Clariant’s CEO Hariolf facility which will create 60 Forums. The work covered the EcHA’s 123-page publica- Kottmann says that Reach new jobs. finished products, intermedi- tion, guidance on registration. registration has required “an ❙ www.lanxess.com ates and raw materials. ❙ www.clariant.com intensive use of resources” Australian court dismisses Fox plans to oxodegradable claims recycle in mexico The Federal court in Adelaide, the Australian standard. in of the oxodegradable bags, Fox petroleum is planning Australia, has declared that addition, the bags did not nupack Australia, had the to form a plastics recycling goody Environment engaged in biodegrade, disintegrate, or same claims dismissed for the subsidiary in Tuxtla misleading and deceptive compost in accordance with same reasons. gutierrez, southern mexico. conduct and made false the standard. dr michael Schraper, the it expects that it will be able representations about its According to Justice lander, Accc’s acting chairman, said: to process up to 2,300 plastics bags which contain goody contravened sections 52 “Environmental claims are tonnes/year of industrial oxodegradable additives. and 53 of the Trade practices powerful selling tools as many and consumer waste in 2009, the company had Act and the company has been purchasers want to do the plastics. claimed that its goody- ordered to publish corrective right thing for the environ- The city has one million branded plastic bags were notices on its website and in ment. it is important that they people, but currently there biodegradable and composta- The Advertiser newspaper. it are given accurate information are no recyclers of plastics. ble in accordance with the was also instructed to and can feel confident in the “There is an enormous Australian Standard AS4736- implement a trade practices purchasing decisions they demand for recycling from 2006 and could be legally compliance and education make.” both the private and public supplied in South Australia. programme, and to contribute l Click here to download the sectors throughout mexico, The court declared that this AuS$65,000 (E48,000) towards Accc’s four-page publication but specifically in Tuxtla was not the case because the the costs of the Australian providing practical guidelines gutierrez, the leading city in bags contained the heavy competition consumer on making biodegradable, the state of chiapas,” said metal molybdenum in amounts commission (Accc). degradable and recyclable william lieberman, that exceeded the maximum in a previous court decision claims on plastic bags. president of Fox petroleum. concentration prescribed by in october 2010, the distributor ❙ www.goody.com.hk ❙ www.foxpetro.net compounding world | February 2011 www.compoundingworld.com
  • 9.
  • 10. Polymers in Cables 2011 The International Conference and Exhibition for the Plastics Cable Industry CliCk Here for more deTailS March 31- April 1, 2011 Hilton Miami Downtown, Images courtesy of: Miami, Florida, USA Omya and Imerys Performance Minerals final reminder – book now! Organized by: Sponsored by: Applied Market Information LLC. marissa Hann – Conference Coordinator mh@amiplastics-na.com Ph: +1 610 478 0800 fx: +1 610 478 0900
  • 11. news linpac sells cabot starts to construct recycling business chinese masterbatch plant cabot has begun construction increase masterbatch capacity already the largest master- linpac recycling, one of the of a new black masterbatch at the site to 80,000 tonnes/ batch producer in china, uK’s largest plastics facility at its site in the Tianjin year in the future. thanks to its plant in Hong recyclers, has been bought Economic development Area Sean Keohane, vice Kong. it is also growing in the by chamonix private Equity (TEdA), china. it is investing president and general middle East with the opening of along with four other uS$20 million in the com- manager of cabot’s perform- its 25,000 tonnes/year facility in businesses from the linpac pounding plant which will have ance Segment said: “demand dubai, uAE, in August last year. group. They are described an initial capacity of 45,000 for masterbatch in china and The latter plant’s capacity can as “non-core” to linpac. tonnes and is scheduled to be the broader Asia pacific region be trebled if required. linpac recycling, which completed in mid-2011. is growing rapidly. Having a The company’s European recycles post-use rigid in 2009, cabot doubled local manufacturing facility masterbatch production is plastic into recycled carbon black production producing high-quality being consolidated into its compounds for a wide capacity at its TEdA plant to products to serve our custom- loncin and pepinster sites in range of moulding applica- 300,000 tonnes/year. The ers will be a significant Belgium. it closed its uK tions and end-use markets, company says that the addition competitive advantage for us”. compounding plant in dukin- will change its name to of the compounding facility will Target markets will include the field in Summer 2009 and it is regain polymers. make it the world’s first fully pipe, wire, cable and automo- ending masterbatch production ❙ www.linpac.com integrated black masterbatch tive sectors. in grigno, italy, this month. ❙ www.regainpolymers.com plant. it will be possible to in volume terms, cabot is ❙ www.cabot-corp.com npE 2012 attracts high levels of interest representatives from more the previous npE show, which than 650 exhibiting companies was held in chicago in 2009. travelled to orlando, Florida, After 38 years in chicago, the uSA, last month to take part in event is being relocated to the draw for stand space at the orlando in 2012 in a move that npE 2012 exhibition, north is designed to save costs for America’s leading plastics exhibitors and visitors. industry event. The triennial show is with over a year to go, more organised by the Spi, the uS than 750 companies have plastics industry association. contracted almost 62,000 m2 of its senior vice president of space. This is already equal to trade shows gene Sanders 87% of the occupied area at said: “The booth selections thus far almost completely fill NPE 2012 exhibitors the west Hall of orlando’s gathered in Orlando orange county convention to select their stand positions and tour centre, and the South Hall is the new venue filling up quickly”. npE takes place on 1-5 April 2012. The SpE’s AnTEc annual technical conference will take place alongside the exhibition. ❙ www.npe.org www.compoundingworld.com February 2011 | compounding world 11
  • 12. news BASF boosts production news in brief of biodegradable plastics ❙ Spartech Polycom is restarting production at its pp compounds plant in lockport, new York, uSA, The new Ecoflex biodegradable plastics BASF has started up its expanded Ecoflex after it was closed in late plant adds 60,000 tonnes of new capacity plant in ludwigshafen, germany, increasing 2009 as a result of declining production capacity for the biodegradable demand from the automotive polyester from 14,000 to 74,000 tonnes/year. it market and in particular the is also increasing compounding capacity for delphi Harrison Thermal Ecovio, which is a blend of Ecoflex and plA Systems plant also located in bioplastic. the same town. Ecoflex is a synthetic plastic that has www.spartech.com properties similar to those of polyethylene, but is fully biodegradable under industrial ❙ Cray Valley has signed an composting conditions in accordance with din agreement with the Grolman En 13432. Ecovio is also biodegradable, but Group for the distribution of contains up to 75% renewable raw materials. its products to the plastics Typical applications include shopping bags, markets in germany, mulch films for agricultural applications, bags Switzerland, Austria and for organic waste and food packaging. BASF Benelux. grolman will focus says that demand for biodegradable and bio- on selling cray valley’s based plastics is currently growing at more specialty low-molecular- than 20% per year. weight functional additives to ❙ www.basf.com compounders and master- batch makers. www.grolman-group.com cytec grows stabilizer capacity www.crayvalley.com ❙ EnerPlastics of dubai has cytec industries is increasing plastics and coatings is l in a separate move, cytec begun production of oxode- production capacity for light growing,” explained domenico has sold its building block gradable additive master- stabilizers by more than 30% romanino, global business chemicals business to an batch for use in polyolefins. at its plant in willow island, director for polymer additives affiliate of Hg capital for called Ep oBd, the product west Virginia, uSA. The at cytec. “we are expanding our uS$180 million. The product is claimed to meet French expansion is expected to be manufacturing capabilities for lines include acrylonitrile, standards for oxodegradation completed by the beginning of several product lines including sulphuric acid and melamine and has been certified by the 2012, says the company. cyasorb THT and cyasorb which are produced mostly for centre national d’Evaluation “global demand for high- cynergy Solutions stabilizers to sale to third parties. de photoprotection in France. performance uV protection for meet customers’ needs.” ❙ www.cytec.com www.enerplastics.com ❙ A Schulman has been Adeka invests in polyester additives for pVc awarded a 2011 deal maker Award from the Association Adeka is expanding production The expansion will increase The polyester additives are for corporate growth’s of polyester-based additives capacity for polyester-based used as plasticizers, predomi- cleveland chapter in ohio, for pVc applications at its additives at the chiba plant by nantly in pVc and rubber. uSA. The company was plant in chiba, Japan. The 5,600 tonnes/year. Along with Adeka says that demand is recognised for its three company is investing ¥1.5 additional plants in Japan, expanding for applications in acquisitions in 2010 – ico billion (E13 million) in the china and Thailand, it will take construction materials and polymers, mccann color and project which is scheduled to Adeka’s total capacity for the automotive interiors. mash compostos plasticos. start production in April 2012. products to 22,000 tonnes/year. ❙ www.adeka.co.jp www.aschulman.com 12 compounding world | February 2011 www.compoundingworld.com
  • 13.
  • 14. M M A S T E R B AT C H 2 0 1 1 Integrating Colour and Design CLICK HERE FOR DETAILS HEADLINE SPONSOR 7-9 June 2011 The Imperial Riding School Vienna, a Renaissance Hotel, Vienna, Austria Organised by: Also sponsored by: Media sponsor: Applied Market Information Ltd. Sabine Prack – Conference Coordinator sp@amiplastics.com Ph: +44 117 924 9442 Fax: +44(0)117 311 1534
  • 15. Colour trends | news Clariant colours in the future Each year Clariant’s experts movement, evolution and “natural hues that evoke the dabra that is described as a predict the global plastics surprise – bright, lively and magic of ancient mythologies”. mysterious violet. colour trends that lie ahead. quirky hues and special effects Examples include: Echo of Building on the “In-Fusion2” We take a first look at their – will prove popular in 2012. At Silence, a delicate sand colour; theme from last year, “In- brand new tips for 2012 the same it predicts that the Itzamná, a terracotta orange Fusion3” recognises the public will be seeking soft, overlaid with burgundy red ; blending of the human and the Global colour trends are being muted, earthy and organic and Inner Strength, a deep, technological through driven by economic, technologi- tones that convey introspec- dark non-black with a tinge of augmented reality created by cal, political and philosophical tion, stability and personal primal green. digital media, 3D entertain- changes, according to Clariant responsibility. It says that this The “Creative Confusion” ment and motion gaming. Masterbatches. The rapid apparent contradiction may be trend is said to represent the Colours in this grouping are changes that are happening in because confusion is also an ambiguity and surprise sought otherworldly. For example, these areas have been taken element in some of the major by people who no longer want Hyperlight is made up of into account in its new societal trends. mass-produced sameness and different glitter colours that ColorForward 2012 report. This The four themes for 2012 blandness in their product pur- can only be reproduced in is designed to help designers include “Me... Under Con- chases or in their lives. The moulded plastic, while and brand managers make struction”, reflecting the need colours are bright and fun, StarLED is a purplish blue successful colour choices for for introspection and self- taking advantage of special colour co-injected with a layer plastics products and packag- questioning at times of rapid effects and combinations. of silver starburst. ing that will be marketed a year change. It also acknowledges Examples include Bizarre, a The final trend, “Re- or more in the future. the ending of the Mayan fusion of translucent purple Volition” is a response to the Clariant forecasts that Calendar on 21 December and yellow that creates a negativity that has gripped the colours that mirror a sense of 2012. The palette incorporates strange green, and Abraca- world in the latter part of the last decade and the way that people look inward to seek a resolution. The palette is described a pure and unadul- terated, featuring solid colours without special effects. Examples include: Mind Switch, a lively yellow/orange; Collaboraction, a warm red; and New Equilibrium, a stable pearlescent brown. The colours reproduced here are for indication purposes only as many use special effects that that cannot be illustrated accurately on screen. The ColorForward 2012 pack contains moulded plaques to accurately repre- sent the colours. Click here to request one and click here to see an animated presentation of the ColorForward 2012 predictions and full details of the different colours. ❙ www.clariant.masterbatches.com www.compoundingworld.com February 2011 | CoMpouNDING worLD 15
  • 16. news | Technology Researchers use carbon dioxide to impregnate plastics with additives Researchers in Germany are conducted with silica and investigating how compressed flurbiprofen, the anti-inflam- CO2 can be impregnated into matory active pharmaceutical plastics to act as a carrier for ingredient, have also been dyes and additives. The work is successful. being carried out at the At a temperature of 30.1oC Fraunhofer Institute for and a pressure of 73.8 bar, CO2 Environmental, Safety and goes into a supercritical state Energy Technology (UMSICHT) that gives the gas solvent-like in Oberhausen. properties. When it is in this The researchers say that state, it can be introduced into the technology provides a polymers and used as a carrier route for impregnating plastics for dyes, additives, medical with heat-sensitive additives or compounds and other pigments that cannot with- substances. stand the high temperatures of Manfred Renner, a scientist injection moulding or other at Fraunhofer UMSICHT, processes. In addition, the explains the process: “We technology can be used to pump liquid CO2 into a high- apply expensive additives and pressure container with the This phase diagram shows how Co2 beComes pigments in a thin layer at the plastic components that are to superCriTiCal aT CerTain pressures and TemperaTures part’s surface where they are be impregnated, then steadily normally needed, rather than increase the temperature and The process takes a few One potential application throughout the whole volume pressure until the gas reaches minutes – the researchers highlighted by the researchers of the component. the supercritical state. When quote five minutes to dye a is in contact lenses. The Early tests have involved that state is reached, we plastic part yellow at 90oC and process could be used to dye impregnating polycarbonate increase the pressure further. 200 bar. Once the process is the products as well as with nanoparticles that give it At 170 bar, pigment in powder- completed, the container is enriching them with pharma- antibacterial properties, form dissolves completely in opened and the gas escapes ceutical compounds that would completely killing off e-coli the CO2 and then diffuses with through the surface of the be slowly released to the eye placed on its surface. Work the gas into the plastic”. plastic, leaving behind the throughout the day. An pigment or additive. example would be replacing This plastic According to the UMSICHT eye drops for treating glau- propeller was researchers, the process is coma. dyed yellow in suitable for impregnating l Fraunhofer is Europe’s five minutes partially crystalline and largest application-oriented at 90oC and amorphous polymers such as research organisation with 200 bar PA, TPE, TPU, PP and PC, but more than 80 research units, it cannot be applied to including 60 Fraunhofer crystalline plastics. They Institutes, at different locations emphasise that CO2 is non- in Germany. It employs more flammable, non-toxic and inex- than 18,000 people and has an pensive, and although it annual research budget of behaves like a solvent, it does E1.65 billion. UMSICHT not present the health and focuses on process engineer- environmental issues often ing technologies. associated with solvents. ❙ www.umsicht.fraunhofer.de 16 COMPOUndInG WORld | February 2011 www.compoundingworld.com
  • 17. Nanocyl SA , Rue de l’Essor, 4, 5060 Sambreville, Belgium N anocyl provides easy-to-use carbon nanotube powder and masterbatches for ESD and conductive plastics. Our carbon nanotube solutions exhibit easier processing conditions, better surface quality and retention of the intrinsic mechanical properties. Our products meet the most stringent requirements of the automotive and the electronics industries such as weight reduction, dimensional stability, high cleanliness and abrasion resistance. Such a versatile technology provides also a direct cost advantage ! Call our global technical support today at +32 71 750 385 or email us at techsupport@nanocyl.com and let us know how we can assist you. SUPERIOR CARBON NANOTUBE (CNT) TECHNOLOGIES FOR IMPROVING THE PROPERTIES OF YOUR APPLICATION Conductive Plastics : Thermoplastic Concentrates / Industrial Research Grade CNTs Composites : Epoxy Resins Sizing Agents Prepreg Materials Coatings : Anti-fouling / Flame Barrier Aqueous Dispersions
  • 18.
  • 19. plastics recycling | factory report Just over a year after a fire destroyed its sorting facility, uK recycler Eco plastics is back, bigger and better than ever. Nadya Anscombe finds out more about Europe’s largest plastics bottle recycling plant Bottle recycler bounces back Visitors to a plastics recycling facility expect to see a dirty when the fire happened,” says Short. A mechanical The Eco Plastics environment, especially when the plastics being recycled failure in a fan in the sorting facility was found to be the plant processes are post-consumer waste. But visitors to uK recycler Eco cause and the sorting facility was burnt to the ground. around 100,000 plastics (formally AwS Eco plastics) are often surprised “luckily the processing facility, which houses the bigger tonnes/year of how clean and efficient the company’s facility is, investment, survived,” says Short. post-consumer according to managing director Jonathan Short. now, instead of being housed in a 1940s aircraft plastics bottles The company, which built its first sorting plant for hangar, the sorting facility is in a larger, modern, light and plans to plastics waste in 2006, is now by far the largest facility which has enabled the company to improve grow this by 40% producer of food-grade recycled pET (rpET) in the uK efficiency. “instead of trying to fit a process into a space, and also has the largest plastic bottle recycling facility “ in Europe. “we don’t really see ourselves as plastics recyclers anymore,” says Short. “But rather as a We don’t really see manufacturer of food-grade plastics that happens to use post-consumer waste as its raw material.” ourselves as plastics The company has seen a huge rise in demand for food-grade rpET and has been expanding to meet this recyclers anymore, but rather demand. But the brand-new E20 million sorting facility located in Helmswell, lincolnshire, is not just a result as a manufacturer of food- of this increased demand. A year ago a devastating fire grade plastics that happens to use post- ” ripped through the old sorting facility and the company had to work hard to rebuild its business. “we had just consumer waste as its raw material gone through an expansion phase, installing Sorema hot-wash lines and Erema compounding machinery Eco PlAstics’ MD, JoNAthAN short www.compoundingworld.com February 2011 | compounding world 19
  • 20. factory report | plastics recycling Left: The we were able to first design an efficient process and build and can handle up to 11 streams of plastic material. it is company’s 17 the building around it,” says Short. For example, because this ability to deal with many different plastics that has Titech optical the new facility is taller, it makes more use of gravity, resulted in very low waste levels. “most plastic recy- sorters can reducing the need for conveyors and cutting maintenance clers have about 25% process waste,” says Short. “ours now do their costs. it also enables more straight process flows which is around 8% and that is mainly dust and evaporation. job more result in improved sorting. Straight process flows mean we can recover all the different kinds of plastic effectively as the product is more spread out and the company’s 17 including bottle tops and other parts.” the material is Titech optical sorters can do their job more effectively. The company is now unrecognizable from the small spread more “our new facility is also future-proof,” says Short. “we sorting facility set up in 2006 which exported all of its evenly are already planning our next expansion phase.” products to the Far East. “Some of our product is still The company currently processes around 100,000 exported, but we want to limit our exposure to the Far Right: The new tonnes/year of post-consumer plastic bottles but plans to East,” says Short. “As china becomes wealthier and its purpose-built ramp that up to 140,000 tonnes by 2011. This represents people consume more, the chinese will have their own facility has nearly half of all the post-consumer plastic bottles waste to deal with and will not need ours any more. This meant improved collected in the uK today. in 2006, when Eco plastics was is why it is so important for countries like the uK to material flows first set up as a sorting facility, the uK collected 108,000 build their own infrastructure and recycle their own tonnes of plastic bottles. By 2009 this had risen to nearly waste plastic.” 260,000 tonnes and a recent report by recoup shows with this, and the increasing amount of plastic being 300,000 tonnes will have been collected during 2010. collected in the uK, in mind, Short expects more “Supply is plentiful,” says Short. “And so is demand. we companies to jump on the bandwagon. “But the are the largest producer of rpET in the uK, but demand challenges of recycling post-consumer plastic waste is three or four times what we are producing.” into a product suitable for direct food contact are not to This is why the company plans to ramp up its food- be underestimated,” he says. “Anyone can go and buy grade rpET production from today’s 15,000 tonnes per the equipment, but having the know-how of how to annum to 40,000 tonnes by mid-2012. This equates to make the most of that equipment and how to get high- 88% of the current uK total. quality product out of it is the key to our success.” This will of course mean more investment in compounding equipment. The company currently has More information one Vacurema extruder from Erema for pET and is Click here to see an interactive diagram showing the planning to invest in “at least one more” in order to layout of Eco plastics’ Helmswell plant along with fulfill these expansion plans. details of each component. As well as food-grade rpET, Eco plastics also sells ❙ www.ecoplasticsltd.com rpET flake to thermoformers. while pET and HdpE ❙ www.sorema.it bales are its main products in terms of percentage of ❙ www.erema.at input, the company processes a very mixed feedstock ❙ www.titech.com 20 compounding world | February 2011 www.compoundingworld.com
  • 21. Ralf Simon Managing Director „ With steady innovations we remain your reliable and safe partner.“ BKG pelletizer Download the mobile barcode reader „i-nigma“ BEST TECHNOLOGY INSIDE ! and follow us to the internet! www.kreyenborg-group.com compounding extrusion materials handling service The advance into a new performance dimension of processing technology. The new ZSK Mc18 twin screw extruder is the most productive high performance ZSK of all times. With its specific torque of 18 Nm/cm3 it stands out for considerable throughput increases with improved product quality and maximum efficiency. It heralds the next generation of processing technology to pro- vide you with a unique advantage in technology. That’s what we mean when we say “confidence through partnership”. www.coperion.com
  • 22. COMPOUNDING PROCESSING 2011 International industry conference on the profitable use of bioplastics N o va m o nt CliCk Here for deTailS g eo ™ pe a In n ne i ol S til P ro p p er G m b H March 29-30, 2011 CAR GO The Hilton Miami Downtown Co Miami, Florida, USA B io sm ser t ic ie iP e sP hone ™ la n 4 c o ve r m a d e fr o m In g e o Images courtesy of: tL o ve ™ eo™ NatureWorks, Novamont m a d e fro m In g and Propper final reminder – book now! Organized by: Media Sponsors: Applied Market Information LLC. Jessie martin – Conference Coordinator jm@amiplastics-na.com Ph: +1 610 478 0800 fx: +1 610 478 0900
  • 23. recycling equipment | processing feature Focus on plastics recycling machinery With growing volumes of plastics being the recycling process as well as the market including extruders, shredders, recycled, equipment manufacturers quality of the end product. dryers, separators and filtration have been responding with new On the following pages we look at systems designed for tough recycling technology to improve the efficiency of some of the latest equipment to hit the applications. gneuss wins order for its largest mrS extruder The K show proved very The Gneuss MRS successful for german eight-screw machinery maker gneuss, with extruder several orders completed at the offers very show including the sale of an high levels of mrS 200 extruder to a custom- devolatizing er in Brazil. The extruder, which performance has a throughput of up to 2 tonnes/hour, is the largest a gneuss rSFgenius 150 melt gneuss has sold to date and will filter and ViS on-line viscom- be used in the customer’s state- design, the devolatilizing direct extrusion into films or eter. The turn-key system is of-the-art pET bottle-to-bottle performance is claimed to be fibres. The machine also capable of processing waste recycling line. The extruder 50 times greater than that of a provides excellent decontami- material at 500-700 kg/h to features gneuss’s multi- conventional single-screw nation performance. last year produce material that is rotation system (mrS) which extruder – and this at a the uS FdA issued a letter of comparable with virgin enables the processing of pET vacuum of only 25 to 40 mbar. non-objection for using the polymer according to gneuss. post-consumer waste without This eliminates the need for a extruder for reprocessing The sales of mrS extruders pre-drying. high vacuum system and pre- material for the food industry. have contributed to consider- mrS is a drum containing drying. At K 2010 gneuss launched able growth at gneuss. The eight satellite single screws, in the three years since a complete line for the direct company has invested heavily driven by a ring gear and gneuss introduced its mrS recycling of pET fibre or film in new buildings: a new pinion transmission. The extruder at K 2007 it has sold scrap. Built around its mrS assembly workshop and a new “barrels” cut into the drum are more 16 lines for the process- 110 extruder, the system processing technical centre approximately 30 % open and ing of pET post-consumer features an integrated cutter/ have doubled the production provide optimum exposure of flakes without pre-drying, feeder supplied by ngr area in order to meet demand. the melt. Thanks to this either for repelletizing or for recycling machines as well as ❙ www.gneuss.de Titech opens waste separation test facility Titech has opened a 1,500 m² ballistic separator, the test be accurately simulated. manager, commented: “The sensor-based test facility for facility uses all of Titech’s during testing, changes can facility allows us to work with plastics sorting at its head- sorting and recycling technolo- be made which ensure that the customers to ensure that the quarters in mülheim-Kärlich in gies. it has been designed to sorting systems are calibrated systems will be deployed to germany. allow several different to deliver optimum levels of their sites and immediately Set out in a loop which processes to run concurrently sorting and recycling for begin working as efficiently as prepares the waste by so that a customer’s facility specific requirements. possible.” screening it and using a and operating environment can ralph uepping, test facility ❙ www.titech.com www.compoundingworld.com February 2011 | compounding world 23
  • 24. processing feature | Recycling equipment Kreyenborg builds largest New Lindner shredder infrared dryer concept boosts flexibility Kreyenborg Plant Technol- Lindner reSource has range of different square- filling capacity ensures a ogy has developed a large launched the Micromat Plus blade or point-blade rotors can constantly high material flow. infrared drum dryer for series of variously configura- be fitted. Easily replaceable Production waste with different drying PET bottle flakes ble single-shaft shredders for screens with 10 to 300 mm material characteristics, such with a throughput of 3,500 recycling plastic waste. hole diameters make for even as hard plastics, filaments or kg/h. The system, with Available in three sizes, these greater versatility, while the films, can therefore be drum dimensions of 2,500 units are designed with low patented maintenance hatch shredded just as efficiently as mm diameter and 5,400 energy consumption and high facilitates the replacement of post-consumer plastics such mm length, is the largest productivity in mind. blades and counter-blades. as PET bottles, agricultural built by the company. Three different drive The shredder’s newly film or carpeting. It features 540 kW of concepts are offered to developed internal force feeder Selecting the optimum rotor installed radiator output accommodate specific can be adapted to a given and blade types will depend on and is designed to dry PET application needs, while a application, and an increased the application. For shredding bottle flakes with a bulk problematic material such as density of about 0.35 kg/ Lindner’s Micromat Plus can big bags, filaments or stretch dm³, from maximum 1 % be configured to shred film, Lindner proposes its ‹ initial moisture to 0.05% wide variety of point-blade rotor providing and to crystallize it at the waste plastics high cutting precision. The same time. Due to the short square-blade rotor is optimized residence time of 10-15 for hard plastics and combines minutes, there is signifi- superior pull-in control with an cantly less material in the energy-saving power require- drying process, eliminating ment and RPM level. the need for huge drying All rotors are available with vessels to process high wear protection and can be throughputs of low-bulk- equipped with cooling density flakes. capabilities. ❙ www.kreyenborg.de ❙ www.lindner-resource.com Rapid expands granulator range Rapid has developed its largest granulation applications. operator can gain access to the ‘open hearted’ granulator to Bengt Rimark, Rapid’s rotor and cutter at the heart of date, by adding a 1,500mm marketing director, said: “The the machine in three simple wide model to its 600 series. 600-Series uses the same steps, without needing any The series, which has a 600 patented technology as the tools. The granulators also mm diameter rotor, is already 300, 400 and 500 series come with Rapid’s available 900 mm and 1200 granulators. The concept is Mineral Composite mm widths. It is designed for completely modular and can Technology (MCT) the high volume granulation, be tailored to any application base, which is a and can handle throughputs up within the plastics processing vibration-absorbing to 3,500 kg/h. There are 45 and recycling industry.” heavy platform that standard base configurations The ‘open-hearted’ design of helps to reduce noise available, so it can be tailored the 600 series means that, levels during operation. to suit the majority of large during a production change, the ❙ www.rapidgranulator.se 24 CoMPouNDINg WoRLD | February 2011 www.compoundingworld.com
  • 25. TPEI Compounding Lines Featuring Free Rotor™ Continuous Mixers J-Block™ Extruders For over 25 years TPEI has been in the forefront of innovation in the design and manufacture of state-of-the- art compounding machinery for the plastics and rubber processing industries. High Output, Low Maintenance Compounding Lines • E-mixer™ designs for hard to feed and fluffy materials. • Patented sealing arrangement for mixer. • Fully automated grease lubricated and water cooled bearing blocks. • Proprietary J-Block™ extruder technology. • T-orientation of mixer to extruder. • Ubangi™ flow channels used in extruder dies and adaptors. • Compounding rates from 50lbs/h to 15,000 lbs/h. 24/7 Service Technical Support Whatever your needs, if we don’t stock it, we’ll build it! 892 Blakeslee Blvd. Drive West Lehighton, PA 18235 Ph: (570) 386-4777 Fax: (570) 386-4120 Email: tpeguest@ptd.net www.tpei.com
  • 26. processing feature | recycling equipment conair and rajoo work together on pET project At the recent K show, indian extrusion machinery Screen-changer supplier rajoo Engineers demonstrated an extrusion line running recycled pET (rpET) sheet. The line, which produced a three- meets recycling challenges layer clear pET sheet intended for thermoforming The latest generation of collected in a permanently backflush filter changes to the of disposable containers, screen-changers from maag flushed accumulating space operating mode and starts the featured a full range of now meets all requirements of and will then clean the dirty fully automatic cleaning of the crystallizing, drying and direct recycling processes, screen cloth outside the screens which is controlled by material handling equip- such as the fabrication of food- production process by pressure or time and depends ment supplied by conair. wrapping films from pET bottle backflushing. in this way, on the level of dirt accumula- The sheet line incorpo- flakes in one process step. variations in pressure and tion. The recycling screen rated two extruders – a 90- maag’s new cSc/BF-pE volume are largely avoided and changers are based on the mm / 30d / 76-kw unit that screen-changers feature fully the effects on the final product well-proven double-piston processes the rpET flake automated cleaning which can are minimized. design which does not need that makes up 90% of the be adjusted to any kind of Specific set points can be any additional seals and finished sheet, and a 50-mm process. The quantity of programmed into the control ensures a reliable and leak- / 30d / 22-kw unit that runs material which is needed for system to suit the process. proof operation. the virgin pET that forms the backflushing of the screens is when these are reached, the ❙ www.maag.com outer layers of the sheet. conair supplied the materials handling and conditioning equipment upstream from the extrud- Extricom supplies ringExtruder ers, including a cr42 Extricom has delivered a tion of material taking place in Extricom is supplying one crystallizer, which efficiently ringExtruder rE7 XpV for a double helix: around the of its 12-screw RingEx- processes amorphous pET high-quality bottle-to-bottle stationary core and around truders to a PET bottle-to- flake at temperatures up to recycling to a customer in each screw. bottle recycling plant in 177°c (350°F) with continu- Eastern Europe. The high-duty ❙ www.extricom.de Eastern Europe ous agitation to prevent plant has a throughput of 3,500 agglomeration. conair’s kg/h pET bottle flakes carousel plus dryers were equating to an annual capacity used for processing the of 27,500 tonnes recycled pET. materials, while its drying The company’s ringExtrud- hoppers provided mass er design features 12 screw material flow and uniform shafts arranged symmetrically air/heat distribution. in a ring. They all rotate in the rajoo has supplied more same direction, each on its than half a dozen rpET lines own axis. The outer barrel within the past 12 months. and the stationary core ❙ www.rajoo.com enclose the screws with a ❙ www.conairgroup.com narrow gap with transporta- 26 compounding world | February 2011 www.compoundingworld.com
  • 27. The international conference and exhibition for The international polypropylene film industry the bi-oriented conference and exhibition for A TURN AHEAD The international polypropylene film industry the bi-oriented conference and exhibition for The international polypropylene film industry the bi-oriented conference and exhibition The internationalconference and exhibition for for TO MORE the bi-orientedpolypropylene film industry the bi-oriented polypropylene film industry EFFICIENCY. SAV THE AVE S TH SDAE A 28-3E V VE E THE DE T SASAVT 28-E 0 DAE E TTHH 0 J AT 28-3E Aune DJ 8 2 30 DTE E 22 -2011 une 8-30u AT 301 Jun E 0 J1 une 221 11ne e 0 J . 201 11 . . d. AMI’s BOPP Film conference is now well . AMI’s BOPP Film conference is now well established as theconference is now well AMI’s BOPP as the leading forum for the AMI’s BOPP Film leading is now well established Film conference forum for the world industry. the conference is now well established as AMI’s industry. the leading forum forfor the established Film leading forum the world BOPP as world industry. world industry. established as the leading forum for the The conference usually attracts over 200 world industry. usually attracts over 200 The conferenceover 30 attracts over 200 delegates from usually countries. over 200 The conferenceover 30 countries. Delegate The conference usually attracts delegates from over 30 countries. Delegatethe delegates from Delegate companies represent30 countries. over 200 The conferenceover more than 50% of the delegates from usually attracts50% of companies represent more than 50%Delegate world’s output of BOPP film than 50% over 2 companies represent more (equal of the companies represent30 countries. to over 2 delegates fromof BOPP film than Delegate world’s tonnes ofoverresin purchase). of2the world’s output more (equal million output ofBOPPmore than to to over 2 PP film (equal 50% of the over world’s tonnesof PP resin purchase). companies represent film (equal to output of PP resin purchase). million tonnes million of BOPP million output BOPP film (equal to world’s tonnes of PP resin purchase). over 2 To viewtonnes of PP resin purchase). here details on this event click million moredetails on this event click here To view more To view more details on this event click here To view more details on this event click here To view more details on this event click here 28 -30 June 2011 28 -30 June 2011 Technology made by Gneuss: AustriaTrendJune 2011 28 -30 Savoyen Hotel, 28 Trend Savoyen Hotel, Austria -30 June 2011 Austria Trend Austria Hotel, Savoyen 28Vienna, Austria Hotel, Vienna, Savoyen Austria -30 June 2011 Trend Vienna, Austria Vienna, Austria Austria Trend Savoyen Hotel, Vienna, Austria For furtherdetails please contact: For further details please contact: Thanks to their high performance and constant mode of operation, our technologies developed Becky Merriott, Conference contact: Becky Merriott, Conference Manager For further details please contact: For further details please Manager for the plastics-processing industry increase the E-mail:Merriott, Conference Manager rm@amiplastics.com Becky rm@amiplastics.com E-mail:Merriott, Conference Manager Becky rm@amiplastics.com For further details please contact: cost efficiency of every production process. Your E-mail: 117 924 9442 Tel: +44 Tel: +44rm@amiplastics.comManager E-mail: 117 924 9442 production line benefits from maximum availabili- Becky Merriott, Conference Tel: +44 117 924 9442 ty while at the same time guaranteeing optimum Tel: +44 117 924 9442 E-mail: rm@amiplastics.com product quality, even when using 100 % recycled Tel: +44www.amiplastics.com 117 924 9442 material. www.amiplastics.com With Gneuss you are always a decisive turn ahead! www.amiplastics.com www.amiplastics.com Organised by: Sponsored by: Organised by: www.amiplastics.com Visit us at CHINAPLAS! Applied Market 17.05.11 - 20.05.11 Applied Market Organised by:Ltd. Hall 5.1, Stand D 21 Information Information Ltd. Organised by: Applied Market Organised by: Applied Market Information Ltd. Platinum sponsor: Applied Market Information Ltd. Organised by: www.gneuss.com Information Ltd. Applied Market a turn ahead Information Ltd.
  • 28. additives feature | Mineral fillers Dr Chris DeArmitt was chairman for AMI’s recent Minerals in Compounding conference in Atlanta, Georgia, USA. Here he reports on the wide range of presentations covering the latest developments in materials and processing technologies Making the most of minerals Interest in fillers is as strong as ever, as illustrated by hard to understand and complex equations are needed the healthy attendance and the diversity of technologies to fit the data. In fact it turns out that properties depend presented at the recent AMI Minerals in Compounding upon the volume percentage of the filler and polymer conference in Atlanta, Georgia, USA. Topics spanned the phases, not the weight percentage. Plotting data that range from traditional fillers to new entrants and from way often results in straight lines. Another myth is that additives like dispersants and coupling agents to fillers have lower specific heat capacities than poly- processing equipment to optimise production through- mers, thus helping reduce heating and cooling times. put and material properties. Although fillers do indeed speed production through The conference was kicked off by Dr Chris DeArmitt their high thermal conductivity, it was shown that the of Phantom Plastics who gave an introduction to filled specific heat capacities of fillers and polymers are plastics including how different types of filler alter the precisely the same on a per unit volume basis. mechanical and other properties of plastic materials. Charles-Etienne Houssa of Omya continued with a Each type of filler has its own niche according to the look at calcium carbonate which is one of the most Quarzwerke properties of the filler and the size and shape of the popular fillers because it is inexpensive and improves compared a filler particles. He also emphasized the importance of several properties of polymers such as modulus and selection of dispersants and coupling agents in optimizing compos- cooling times. In some cases, it can also increase filler types in ite processing and properties. impact performance and environmental stress cracking different He then dispelled some myths about filled plastics. resistance. engineering For example, properties are usually plotted versus the The price of calcium carbonate is more stable than plastics weight % of filler, often resulting in curves which are polymer prices and has historically increased more (Left to Right): Muskovite Mica, Phlogopite Mica, Low-aspect-ratio Wollastonite, High-aspect-ratio Wollastonite, Platy Kaolin 28 CoMPoUnDInG worlD | February 2011 www.compoundingworld.com
  • 29. Mineral fillers | additives feature cooling and therefore higher production output. In PP Mondo and PA, talc also helps nucleated crystallization leading produces very to a further increase in production output. high purity talc Dr Jörg Zilles of HPF The Mineral Engineers, which is using a super- a division of Quarzwerke, presented studies on mica conducting (Phlogopite and Muscovite variants), Wollastonite (low- magnet and a aspect-ratio and high-aspect-ratio) and platy Kaolin all flotation slowly than that of polymers. For example HDPE prices at 20 weight % in PA6, PBT, ABS, PPS and PSU. Mechani- process increased 125% from 2000 to 2010. In contrast CaCO3 cal properties were measured comprehensively as well increased just 50% over the same period. This gives the as the difference in shrinkage parallel and perpendicular expectation that more and more filler will be used in to the injection direction. The latter measurement gives future years. an indication of the tendency to warp. Overall, the fillers tended to increase modulus, Natural born fillers strength and HDT while reducing warpage. The only Calcium carbonate filler is formed through a process downside was some loss in impact resistance commonly known as diagenesis whereby sea organisms are found when adding fillers to polymers. For each plastic deposited on the sea bed and then converted to calcium there was a filler which provided the best property carbonate sedimentary rock. It turns out that 300 balance. Phlogopite was found to be the preferable filler million metric tonnes are deposited in the oceans per for PA 6, while high-aspect Wollastonite showed the best year but only 75 million tonnes are quarried, making balance of properties in ABS if anisotropy can be calcium carbonate a sustainable filler. tolerated. Low-aspect Wollastonite gave remarkable Omya showed some new particle morphologies, increases in modulus coupled with excellent impact namely microplatelets agglomerated to make spheres. strength in PBT, PPS and PPU. Kaolin and Muscovite Potential applications were not mentioned but one can mica gave increases in modulus, tensile strength and imagine that such high surface area particles would be heat deflection temperature, while shrinkage of the effective for nucleating foam cell growth and for catalyst polymer is decreased in an isotropic way. supports. The next presentation by Frans Venema of Mondo Added strength Minerals focused on talc which has a higher aspect Milliken is well known as the market leader for ratio than calcium carbonate, leading to improved clarifying agents for PP and nucleating agents for PE stiffness, HDT and barrier properties. Talc also and PP. However, Normand Niron’s talk focused on its increases polymer strength and reduces creep (slow new product Hyperform HPR-803 which is marketed as flow) of polymers. One caveat is that impurities are a filler to replace talc in applications where density and common, so Mondo performs a flotation process to surface finish are paramount. remove other minerals. This process is combined with a The push for hybrid cars has added complexity and, special superconducting magnet to remove magnetic ironically weight to the vehicles. Similarly, the continual impurities like iron. addition of new features and devices also pushes up the As with other mineral fillers, talc increases thermal weight of vehicles. The manufacturers therefore seek conductivity substantially, leading to faster heating and new ways to reinforce automotive plastics to bring the www.compoundingworld.com February 2011 | COMPOUNDING WORLD 29