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Redox Reaction Prediction
Important Oxidizers Formed in reaction
MnO4-
(acid solution) Mn(II)
MnO4-
(basic solution) MnO2
MnO2 (acid solution) Mn(II)
Cr2O7
-2
(acid) Cr(III)
CrO4
-2
Cr(III)
HNO3, conc NO2
HNO3, dilute NO
H2SO4, hot conc SO2
Metallic Ions Metallous Ions
Free Halogens Halide ions
HClO4 Cl-
Na2O2 OH-
H2O2 O2
Important Reducers Formed in Reaction
Halide Ions Halogens
Free Metals Metal Ions
Metalous Ions Metallic ions
Nitrite Ions Nitrate Ions
Sulfite Ions SO4
2-
Free Halogens (dil, basic sol) Hypohalite ions
Free Halogens (conc, basic sol) Halate ions
C2O4
2-
CO2
Redox reactions involve the transfer of electrons. The oxidation numbers of at
least two elements must change. Single replacement, some combination and some
decomposition reactions are redox reactions.
To predict the products of a redox reaction, look at the reagents given to see if
there is both an oxidizing agent and a reducing agent. When a problem mentions an
acidic or basic solution, it is probably a redox reaction.

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Redoxhints

  • 1. Redox Reaction Prediction Important Oxidizers Formed in reaction MnO4- (acid solution) Mn(II) MnO4- (basic solution) MnO2 MnO2 (acid solution) Mn(II) Cr2O7 -2 (acid) Cr(III) CrO4 -2 Cr(III) HNO3, conc NO2 HNO3, dilute NO H2SO4, hot conc SO2 Metallic Ions Metallous Ions Free Halogens Halide ions HClO4 Cl- Na2O2 OH- H2O2 O2 Important Reducers Formed in Reaction Halide Ions Halogens Free Metals Metal Ions Metalous Ions Metallic ions Nitrite Ions Nitrate Ions Sulfite Ions SO4 2- Free Halogens (dil, basic sol) Hypohalite ions Free Halogens (conc, basic sol) Halate ions C2O4 2- CO2 Redox reactions involve the transfer of electrons. The oxidation numbers of at least two elements must change. Single replacement, some combination and some decomposition reactions are redox reactions. To predict the products of a redox reaction, look at the reagents given to see if there is both an oxidizing agent and a reducing agent. When a problem mentions an acidic or basic solution, it is probably a redox reaction.