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Department of University Safety &
           Assurances
Mercury Spill Cleanup
    Procedures
Mercury is a Hazardous Material


                • Mercury (Hg) is a
                  hazardous material
                  as defined by:
                     • U.S. Environmental
                       Protection Agency
                     • Wisconsin
                       Department of
                       Natural Resources
                     • U.S. Dept. of
                       Transportation




    US&A (v. 2/07)
Mercury is a Toxic Substance

• Mercury poisoning can result in
  severe health problems affecting
  the nervous system and other
  organs.
  •   Tremors
  •   Changes in vision or hearing
  •   Insomnia
  •   Weakness
  •   Difficulty with memory
  •   Headaches
  •   Irritability
  •   Shyness and nervousness
  •   Acrodynia (painful extremities), a
      condition caused by chronic exposure to
      mercury
                            US&A (v. 2/07)
Mercury Exposure & Prevention


• Routes of exposure
  • Inhalation
      • Main hazard
      • Evaporates releasing
        hazardous vapors
  • Skin absorption
• Personal Protective
  Equipment Required
  •   Nitrile gloves
  •   Safety glasses
  •   Closed-toed shoes
  •   Lab coat


                           US&A (v. 2/07)
Who do you Contact?



• Questions regarding mercury or
  spill procedures should directed to:
   •   Professor
   •   Laboratory supervisor
   •   Own supervisor
   •   UWM Department of Safety &
       Assurances at x6339
• Note: Any release greater than one
  pound (two tablespoons) to the
  environment is a Reportable
  Quantity.


         US&A (v. 2/07)
Spills

• Prevention is the best
  way to handle mercury
  spills.
• All mercury "spills,"
  including droplets of
  mercury from a broken
  lab thermometer, must
  be cleaned up following
  safe and
  environmentally sound
  procedures.



                      US&A (v. 2/07)
Contain Spill


• Prevent the spread of
  mercury.
  • Trays should be used under
    equipment wherever a
    mercury spill is possible.
  • Mercury beads can splash
    and roll around.
  • Prevent mercury from
    entering cracks, crevices,
    and drains.
  • Do not walk in area of spill.
  • Evacuate room via route
    away from spill.

                           US&A (v. 2/07)
Restricted Area


• Cease activities.
• Secure the area around the
  spill, so the mercury does not
  get "tracked" or "kicked"
  around.
• Keep the area restricted until
  the entire spill is cleaned up.
• Lower room temperature to
  reduce evaporation.



    US&A (v. 2/07)
Temporary Control



• Spill powder may be
  used as a temporary
  control measure.
  • Commercial spill kits.
  • Mix 85 grams of finely
    powdered Sodium
     Thiosulfate with 15
    grams of finely
    powdered EDTA.




                             US&A (v. 2/07)
Temporary Control



• Cover from the perimeter of the spill
  toward the center.
• Do not walk through the spill or spill
  powder.
• Pick-up glass and other large debris,
  then clean up mercury.
  • All debris must be disposed of as
    hazardous waste.



                    US&A (v. 2/07)
Mercury Vacuum




            • A special vacuum
              cleaner, which is
              designed to pick up
              mercury droplets
              safely, is available for
              cleanup.
            • NEVER use a regular
              vacuum.



US&A (v. 2/07)
Location of Mercury Vacuum



• Chemistry Department:
  • Second floor stockroom.
  • Contact the stockroom
    personnel when needed.
• Other departments:
  • Contact University Safety
    & Assurances (x6339) for
    assistance with spill clean-
    up.




                          US&A (v. 2/07)
Use of Mercury Vacuum



         • The stockroom
           personnel will clean up
           the spill.
                 • You may be trained in
                   the proper use of the
                   mercury vacuum.
         • UWM Department of
           Safety & Assurances
           staff may also be
           called for assistance.



US&A (v. 2/07)
Other Cleanup Tools

• A side-arm flask connected to a vacuum pump or
  sink aspirator can be used to vacuum up small
  beads.




                     US&A (v. 2/07)
Other Cleanup Tools


• Wet toweling to consolidate small beads into larger
  pieces for vacuuming
• Commercial spill kits
• Disposable
  eyedropper
• Adhesive tape
• Cardboard




                        US&A (v. 2/07)
Special Care



                 • Special attention
                   must be given to
                   cleaning cracks
                   and crevices
                   where the
                   mercury beads
                   may have easily
                   settled.




US&A (v. 2/07)
Mercury Waste


        • Includes the mercury
          and all waste materials
          contaminated with
          mercury.
             • Gloves and other
               contaminated debris.
        • Must be placed in a
          labeled leak-proof,
          polyethylene container.




US&A (v. 2/07)
Disposal


             • No mercury,
               including broken
               thermometers, may
               be disposed of in the
               normal trash or into
               the sewer system.
             • UWM Hazardous
               Waste Manager
               (x4999) will properly
               dispose of all waste.


US&A (v. 2/07)
Assistance After Hours

After Hours:
• If no help is available,
  contact the University
  Police.
   • 9-911 in an emergency
     (229-9911 by cell phone)
   • x4627 if non-emergency.
   • Explain that you have a
     mercury spill.

• Indicate whether the spill
  is small, a broken
  thermometer, or large,
  more than 1 or 2 ml (1/4
  teaspoon).
                         US&A (v. 2/07)
Assistance After Hours

• The police will contact a
  University Safety &
  Assurances staff member for
  assistance.
• If the spill is large or if it
  must be cleaned up right
  away, you will be directed to:
  • Secure the area.
  • Wait until response personnel
    arrive (usually 30 to 60
    minutes).
• The area will be secured/off-
  limits until the next working
  day.

                      US&A (v. 2/07)
Special Consideration

• Large spills, spills in
  confined areas with
  poor ventilation, or
  spills in areas heated
  above room
  temperature must be
  addressed by trained
  personnel with
  protective equipment.
  A risk of high exposure
  to mercury vapors can
  occur in these
  situations.


                       US&A (v. 2/07)
Summary



• Mercury spills are very disruptive.
• Lab personnel are encouraged to use
  extreme caution when using mercury or
  mercury-containing apparatus.
• Thorough decontamination is essential
  to ensure both personal safety and
  protection of the environment.



                US&A (v. 2/07)
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Mercury clean up

  • 2. Department of University Safety & Assurances Mercury Spill Cleanup Procedures
  • 3. Mercury is a Hazardous Material • Mercury (Hg) is a hazardous material as defined by: • U.S. Environmental Protection Agency • Wisconsin Department of Natural Resources • U.S. Dept. of Transportation US&A (v. 2/07)
  • 4. Mercury is a Toxic Substance • Mercury poisoning can result in severe health problems affecting the nervous system and other organs. • Tremors • Changes in vision or hearing • Insomnia • Weakness • Difficulty with memory • Headaches • Irritability • Shyness and nervousness • Acrodynia (painful extremities), a condition caused by chronic exposure to mercury US&A (v. 2/07)
  • 5. Mercury Exposure & Prevention • Routes of exposure • Inhalation • Main hazard • Evaporates releasing hazardous vapors • Skin absorption • Personal Protective Equipment Required • Nitrile gloves • Safety glasses • Closed-toed shoes • Lab coat US&A (v. 2/07)
  • 6. Who do you Contact? • Questions regarding mercury or spill procedures should directed to: • Professor • Laboratory supervisor • Own supervisor • UWM Department of Safety & Assurances at x6339 • Note: Any release greater than one pound (two tablespoons) to the environment is a Reportable Quantity. US&A (v. 2/07)
  • 7. Spills • Prevention is the best way to handle mercury spills. • All mercury "spills," including droplets of mercury from a broken lab thermometer, must be cleaned up following safe and environmentally sound procedures. US&A (v. 2/07)
  • 8. Contain Spill • Prevent the spread of mercury. • Trays should be used under equipment wherever a mercury spill is possible. • Mercury beads can splash and roll around. • Prevent mercury from entering cracks, crevices, and drains. • Do not walk in area of spill. • Evacuate room via route away from spill. US&A (v. 2/07)
  • 9. Restricted Area • Cease activities. • Secure the area around the spill, so the mercury does not get "tracked" or "kicked" around. • Keep the area restricted until the entire spill is cleaned up. • Lower room temperature to reduce evaporation. US&A (v. 2/07)
  • 10. Temporary Control • Spill powder may be used as a temporary control measure. • Commercial spill kits. • Mix 85 grams of finely powdered Sodium Thiosulfate with 15 grams of finely powdered EDTA. US&A (v. 2/07)
  • 11. Temporary Control • Cover from the perimeter of the spill toward the center. • Do not walk through the spill or spill powder. • Pick-up glass and other large debris, then clean up mercury. • All debris must be disposed of as hazardous waste. US&A (v. 2/07)
  • 12. Mercury Vacuum • A special vacuum cleaner, which is designed to pick up mercury droplets safely, is available for cleanup. • NEVER use a regular vacuum. US&A (v. 2/07)
  • 13. Location of Mercury Vacuum • Chemistry Department: • Second floor stockroom. • Contact the stockroom personnel when needed. • Other departments: • Contact University Safety & Assurances (x6339) for assistance with spill clean- up. US&A (v. 2/07)
  • 14. Use of Mercury Vacuum • The stockroom personnel will clean up the spill. • You may be trained in the proper use of the mercury vacuum. • UWM Department of Safety & Assurances staff may also be called for assistance. US&A (v. 2/07)
  • 15. Other Cleanup Tools • A side-arm flask connected to a vacuum pump or sink aspirator can be used to vacuum up small beads. US&A (v. 2/07)
  • 16. Other Cleanup Tools • Wet toweling to consolidate small beads into larger pieces for vacuuming • Commercial spill kits • Disposable eyedropper • Adhesive tape • Cardboard US&A (v. 2/07)
  • 17. Special Care • Special attention must be given to cleaning cracks and crevices where the mercury beads may have easily settled. US&A (v. 2/07)
  • 18. Mercury Waste • Includes the mercury and all waste materials contaminated with mercury. • Gloves and other contaminated debris. • Must be placed in a labeled leak-proof, polyethylene container. US&A (v. 2/07)
  • 19. Disposal • No mercury, including broken thermometers, may be disposed of in the normal trash or into the sewer system. • UWM Hazardous Waste Manager (x4999) will properly dispose of all waste. US&A (v. 2/07)
  • 20. Assistance After Hours After Hours: • If no help is available, contact the University Police. • 9-911 in an emergency (229-9911 by cell phone) • x4627 if non-emergency. • Explain that you have a mercury spill. • Indicate whether the spill is small, a broken thermometer, or large, more than 1 or 2 ml (1/4 teaspoon). US&A (v. 2/07)
  • 21. Assistance After Hours • The police will contact a University Safety & Assurances staff member for assistance. • If the spill is large or if it must be cleaned up right away, you will be directed to: • Secure the area. • Wait until response personnel arrive (usually 30 to 60 minutes). • The area will be secured/off- limits until the next working day. US&A (v. 2/07)
  • 22. Special Consideration • Large spills, spills in confined areas with poor ventilation, or spills in areas heated above room temperature must be addressed by trained personnel with protective equipment. A risk of high exposure to mercury vapors can occur in these situations. US&A (v. 2/07)
  • 23. Summary • Mercury spills are very disruptive. • Lab personnel are encouraged to use extreme caution when using mercury or mercury-containing apparatus. • Thorough decontamination is essential to ensure both personal safety and protection of the environment. US&A (v. 2/07)