Water-based paint formulations Vol. 4

WATER-BASED
PA1NT FORMULATIONS
Volume 4
by
Ernest W. Flick
NOYES PUBLICATIONS
Inp IWesWood, New Jersey, U.S.A.

Copyright 8 1997 by Ernest W. Flick
No patt of this book may be reproduced or utilized in
any fonn or by any means, electronic or mechanical
including photocopying, recording 01 by any informa-
tion stonge and retrieval system, without permission
in Writing from the Publisher.
Library of Congress Catalog Card Number: 75-2939
Printed in the United States
ISBN 0-8155-1415-8
Published in the United States of America by
Noyes Publications
369 Fairview Avenue
Westwood, New Jersey 07675
10 9 8 7 6 5 4 3 2 1
Library of Congress Cataloging-in-Publications Data
(Revised for vol. 4)
Flick, Ernest W.
Water-based paint formulations.
Vol. 4 published by Noyes Publications.
Includes index.
1. Paint--Patents. II. Title.
TP935.F62 1975 66T.63 75-2939
ISBN 0-8155-0571-X (v. 1)
ISBN 0-8155-1345-3 (v. 3)
ISBN 0-8155-1415-8 (v. 4)

In Memory
of
My Mother and Father

This collection of 232up-to-date water-based trade and industrial formulations
will be of value to technical and managerial personnel in paint manufacturing
companies and firms which supply raw materials or services to these
companies, and to those interested in less hazardous, environmentally safer
formulations. The book will be useful to both those with extensive experience
as well as those new to the field. This book includes new and different
formulations than those included in the previously published Industrial Water-
Based Paint Formulations and Water-Based Paint Formulations.
The data consist of selections of manufacturers' suggested formulations made at
no cost to, nor influence from, the makers or distributors of these materials.
The information given is presented as supplied; the manufacturer should be
contacted if there are any questions. Only the most recent data supplied us has
been included. Any solvent contained is minimal.
The table of contents is organized in such a way as to serve as a subject index.
The formulations described are divided into sections which cover exterior,
interior, and exterior and/or interior water-based paints, enamels, and coatings,
as indicated below:
I. Coatings and Topcoats
11. Coil Coatings
111. Enamels
IV. Enamels-Baking
V. Exterior Paints and Related Products
VI. Interior Paints and Related Products
VII. Lacquers
VIII. Primers
IX. Sealants and Related Compounds
X. Stains
XI. Miscellaneous
Each formula has been placed in the chapter which is most applicable. The
reader, if seeking a formula for a specific end use, should check each chapter
which could possibly apply.
vii

...
viii Preface
In addition to the above, there are two other sections which will be helpful to
the reader:
XI. A chemical trade name section where trade-named raw materials
are listed with a chemical description and the supplier's name. The
specifications which the raw materials meet are included if
applicable.
XIII. Main office addresses of the suppliers of trade-named raw materials
and/or formulations.
Included in the descriptive information for each formulations, where available,
the following properties may be listed: viscosity, solids, content, %
nonvolatiles, pigment volume concentration, density, pH, spatter, leveling, sag
resistance, scrub stability, freeze-thaw stability, ease of application, gloss
foaming, cratering, brightness, opacity, water spotting, adhesion to chalk, brush
clean-up, reflectance, and sheen.
Ernest W. Flick
Notice
To the best of our knowledge the information in this publications is
accurate; however, the Publisher does not assume any responsibility or
liability for the accuracy or completeness of, or consequence arising from,
such information. These formulations do not purport to contain detailed
manufacturing nor user instruction, and by its range and scope could not
possibly do so. Mention of trade names or commercial products does not
constitute endorsement or recommendation for use by the Author or
Publisher.
Water-based paint raw materials could be toxic, and therefore, due caution
should always be exercised in the use of these hazardous materials. Final
determination of the suitability of any information or product for use
contemplated by any user, and the manner of that use, is the sole
responsibility of the user. We strongly recommend that users seek and
adhere to a manufacturer's or supplier's current instructions for handling
each material they use.
The Author and Publisher have used their best efforts to include only the
most recent data available. The reader is cautioned to consult the supplier
in case of questions regarding current availability.

SECTION I: COATINGS AND TOPCOATS .................... 1
Clearcoat Modification ............................... 2
825/Rhoplex CL-104) ................................ 3
Ancamine 2410 High Solids Coating ........................ 4
2410/Ancamide 500 High Solids Coating . . . . . . . . . . . . . . . . . . 5
Cured with HMMM ................................. 6
Phenolic Clear Bake Coating .............................. 8
Clear Bake Coating ..................................... 9
Phenolic Clear Bake Coating .............................. 9
Clear Wood Coating-A & B & C K-Flex UD-320W Modified .... 10
Direct to Metal Acrylic Latex Coating Starting Point
Formulation ...................................... 11
Low Gloss VinyVABS Topcoat ........................... 12
Clear Topcoat for Flexible Substrates ....................... 12
. . . . . . . . . . 13
Lower Adhesion ................................... 13
Polyphobe Rheology Modifiers Formula C Good Leveling . . . . . 14
................................. 14
Acrylic EmulsiodUrea-Formaldehyde Wood
Aliphatic Wood Coating Formulation (Sancure
Exhibit 4 .Starting Formulation Ancamine
Black Single Coat K-Flex XM-4316 PU Dispersion
Clear Bake Coating ..................................... 7
Strippable Coating Sample Formulation A Unmodified
Strippable Coating Sample Formulation B
Strippable Coating Formulations Thickened with Ucar
Formula D High Build
Strippable Coating for Plastic Substrates ..................... 15
Strippable Coating Formulations .......................... 16
Topcoat for Prefinished Hardboard Siding .................... 17
Water-Borne Alkyd/Melamine Wood Clearcoat Modification . . . . . . 18
Waterborne Clear High Gloss Topcoat ...................... 20
White Gloss Maintenance Topcoat ......................... 21
White Gloss Topcoat . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Wood Topcoat Model Formulations ........................ 23
ix

x Contents and Subject Index
SECTION 11: COIL COATINGS ............................ 24
Chromate Coil-Coating Primer ........................... 25
Low-Sheen Coil-Coating Topcoat ......................... 26
Medium-Gloss Coil-Coating Topcoat ...................... 27
Strippable Coil Coating ................................. 28
SECTION LII: ENAMELS ................................. 29
Acrylic Emulsion Enamel-B&C K-Flex UD-320W Modified . . . . . 30
Synergistic Effects of Combining Nacorr with Anti-
Corrosive Pigment in an Air Dry Water Reducible
Alkyd Modified Acrylic Enamel ....................... 31
Ancamide 2353 Fast Drying White Gloss Enamel . . . . . . . . . . . . . . 32
Ancamide 2353 Low VOC White Gloss Enamel . . . . . . . . . . . . . . . 33
Cary Gloss White Enamel ............................... 34
Clear Enamel (For Maximum Solvent and Abrasion
Resistance) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Gloss Safety Red Enamel ............................... 37
Gloss Safety Yellow Enamel ............................. 38
Gloss White Enamel ................................... 39
Gloss White Enamel (Maximum Solvent and Abrasion
Resistance) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
Green Air Dry Enamel for Flexible Substrates . . . . . . . . . . . . . . . . . 42
High-Hiding Eggshell Enamel ............................ 43
MacGregor Gloss Black Enamel .......................... 44
Pinehurst Gloss Green Enamel ............................ 45
Self-Priming Interior Semi-Gloss Enamel . . . . . . . . . . . . . . . . . . . 46
Exterior Maintenance-Type Coating ........................ 46
Semigloss Enamel ..................................... 47
Southern Pines Gloss White Enamel ........................ 49
Spensol I54 Orange Enamel ............................. 50
Waterborne Black Enamel Based on Epotuf 37-143/37-680
(Formula No. 3019-28A) ............................ 51
Waterborne Blue Enamel Based on Epotuf 37-143/37-680
(Formula No.3019-316) ............................ 52
Waterborne Dark Blue Enamel Based on Epotuf
37-143/37-680 (Formula No.3019-31D) . . . . . . . . . . . . . . . . . 53
Waterborne Green Enamel Based on Epotuf 37-143/37-680
(Formula No. 3019-3lF) ............................. 54
Waterborne Orange Enamel Based on Epotuf 37-143/37-680
(Formula 3019-310 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
Waterborne Red Enamel Based on Epotuf 37-143/37-680
(Formula No. 3019-31B) ............................ 56
Waterborne Red Orange Enamel Based on Epotuf
37-143/37-680 (Formula No. 3019-31E) . . . . . . . . . . . . . . . . . 57

Contents and Subject Index xi
Waterborne Yellow Epoxy Enamel Based on Epotuf
37-143/37-680 (Formula No.3019-31C) . . . . . . . . . . . . . . . . . 58
Whispering Pines Semigloss White Enamel . . . . . . . . . . . . . . . . . . . 59
Anquamine 401 1:l White Gloss Enamel .................... 60
Gloss Enamel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
Anquamine 401/Solid Resin Dispersion 2:l White
SECTION IV: ENAMELS-BAKING ........................ 62
Clear Bake Coating .................................... 63
Phenolic Clear Bake Coating ............................. 63
Clear High Gloss. Baking Finish .......................... 64
Blue Metallic Urethane Enamel ........................... 64
Experimental Water-Reducible Polyester Gloss White
Baking Enamel Using Halox SZP-391 . . . . . . . . . . . . . . . . . . . 65
Waterborne Acrylic Bake Enamel
Water Reducible Polyester Baking Enamel
Spensol L54 White Baking Enamel
2-Component Waterborne System ......................... 69
......................... 66
. . . . . . . . . . . . . . . . . . . 67
........................ 68
SECTION V: EXTERIOR PAINTS AND RELATED PRODUCTS . . . 70
Exterior Flat House Paint with ZnO ........................ 71
Exterior Gloss White . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
Exterior House Paint . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
Exterior House Paint .Tint Base .......................... 75
Exterior Semigloss Formulation ........................... 77
Exterior Tint Base Formulation ........................... 78
Exterior Trim Formulation Modified Vinyl Acrylic Paint . . . . . . . . . 79
Exterior Trim Formulation ............................... 80
Exterior White Flat House Paint ........................... 82
Exterior White Trim house Paint .......................... 83
Good Quality White Exterior Flat Paint for Masonry . . . . . . . . . . . . 84
Good Quality White Exterior Flat Paint for Wood . . . . . . . . . . . . . . 85
Gregson Drive Gloss White .............................. 86
High Quality Exterior Semi Gloss Paint ..................... 87
High Sheen White House Paint ........................... 88
Low VOC Exterior House Paint ........................... 89
Quality Exterior Flat Formulation .......................... 90
Quality Exterior Flat Paint ............................... 91
Quality White Exterior Trim Paint ......................... 92
Quality White House Paint with ZnO ....................... 94
Urethane Fortified Porch & Deck Enamel .................... 95
Weather Barrier Formulation ............................. 96
White Exterior Flat House Paint with Zinc Oxide . . . . . . . . . . . . . . 97
Exterior Semigloss .................................... 76

xii Contents and Subject Index
White Roof Coating ................................... 99
SECI'ION VI: INTERIOR PAINTS AND RELATED PRODUCTS . 100
Clear High Gloss Varnish .............................. 101
Fast-Dry Sealer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 101
Economy Flat Wall Paint .............................. 102
Good Quality Interior Flat with <50g/L VOC . . . . . . . . . . . . . . . . 104
High Quality Super Flat Interior Paint ..................... 105
Interior Clear Wood Finish (Rhoplex CL-l04/Sancure 815) . . . . . . 106
Interior Sanding Sealer (Rhoplex CL-105) . . . . . . . . . . . . . . . . . . 106
Interior Contractor Flat ................................ 107
Interior Good Quality Flat for Roller and Brush
Application ..................................... 108
Interior Good Quality Flat .............................. 110
Interior Semigloss Formulation .......................... 111
Interior Vinyl Acrylic Eggshell for Roller and
Brush Application ................................. 112
Interior Vinyl Acrylic Semigloss ......................... 114
Intumescent Interior White Fire-Retardant Paint . . . . . . . . . . . . . . 115
Low VOC Interior Flat ................................ 116
Solvent Free Interior Satin Paint ......................... 117
White Interior Eggshell ................................ 118
SECTION VII: LACQUERS .............................. 119
Green Lacquer ...................................... 120
DIY Waterborne Lacquer ........................... 121
White Lacquer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122
Foam Control with Agitan Additives in a High Gloss
SECI'ION VIII: PRIMERS ............................... 124
Acrylic Latex Tannin Block Primer Using Halox BW-100 . . . . . . 125
Alkyd Modified Latex Primer ........................... 126
Ancamide 2353 Curing Agent Anti-Corrosive Primer . . . . . . . . . . 127
Anquamine 401/Semi-solid Epoxy Dispersion Lead
and Chromate Free Red Iron Oxide Primer 128
Anquamine 401/Solid Resin Dispersion Lead and
Chromate Free Red Iron Oxide Primer . . . . . . . . . . . . . . . . . . 129
Corrosion Inhibitive Primer ............................. 130
Metal Wash Primer ................................... 130
Cost Effective 2K Water-Base Epoxy Primer Using
Halox SW-111 ................................... 131
Dipping Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 132
Experimental General Purpose Tannin-Stain Resistant
Water-Base Primer Using Halox Xtain A . . . . . . . . . . . . . . . . 133
. . . . . . . . . . . . . . .

Contents and Subject Index xiii
Experimental High Performance Tannin-Stain Resistant
Water-Base Primer Using Halox Xtain A . . . . . . . . . . . . . . . .
Experimental Waterbase Acrylic Red Iron Oxide Primer . . . . . . . . 135
Exterior House Paint Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138
Exterior House Paint Primer Based on Ucar Latex 163 . . . . . . . . . 139
General Purpose Latex Maintenance Primer . . . . . . . . . . . . . . . . . 140
General Purpose/Low Cost Water-Base Primer . . . . . . . . . . . . . . . 141
High Performance Bare Metal Primer ...................... 142
High Performance Galvanized Metal Primer . . . . . . . . . . . . . . . . . 143
High Performance 2K Water-Base Epoxy Primer 144
Halox SZP-391 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145
High Solids Red Iron Oxide Epoxy Primer . . . . . . . . . . . . . . . . . . 147
House Paint Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 148
Lead and Chromate Free Primer .......................... 149
Lead and Chromate Free Red Iron Oxide Primer . . . . . . . . . . . . . . 150
Lead and Chromate Free Waterborne Epoxy Primer . . . . . . . . . . . 151
Lead Based Primer ................................... 152
Lead Silico Chromate Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
Low Sheen Gray Primer ............................... 154
Non-Lead/Non-Chromate Primer ........................ 155
134
. . . . . . . . . . . . .
High Performance 2K Water-Base Epoxy Primer Using
Primer for Factory-Primer Hardboard Siding . . . . . . . . . . . . . . . . 156
Primer 20323D Based on Phosguard J-0853 and 10 ES
Wollastocoat Henkel's Waterpoxy 1401:701 System . . . . . . . . 157
Primer 203236 Based on Phosguard J-0813 and 10 ES
Primer 20596F Based on Heucophos ZPZ and 10 ES
Primer 20596G Based on Heucophos ZMP and 10 ES
Primer 21102E Based on Molycoat 212 and 10 AS
Primer 21105H Based on Phosguard J-0815 and 10 ES
Primer 211051 Based on Nalzin 2 and 10 ES
Primer 21109C Based on Strontium Chromate and 10 ES
Rapid Dry Waterborne Epoxy Primer ...................... 165
Red Inhibitive Maintenance Primer ....................... 167
Red Iron Oxide Corrosion Resistant Epoxy Primer (Two
Component System) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 168
Red Iron Oxide Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169
Red Iron Oxide Water Reducible Alkyd Primer . . . . . . . . . . . . . . . 171

xiv Contents and Subject Index
Rust Inhibitive Chromate Primer ......................... 172
Solvent Resistant. Water-Reducible Epoxy Primer . . . . . . . . . . . . 173
lT-P-1975 Federal Specification Metal Primer . . . . . . . . . . . . . . 174
Universal Primer . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175
Universal Primer Non-Lifting and High Salt Spray Resistance . . . . 176
Water-Base Acrylic Universal Primer Using Halox
Water-Base Acrylic Universal Primer Using Halox
SZP-391 & Xtain A ............................... 178
Waterborne Black Iron Oxide Primer Based on
Epotuf 37-143/37-680 (Formula No.3019-38A) . . . . . . . . . . 179
Waterborne Red Iron Oxide Primer Based on
Epotuf 37-143/37-680 (Formula No.2954-76A) . . . . . . . . . . 180
Waterborne Red Oxide Epoxy Primer ...................... 181
Waterborne Yellow Iron Oxide Primer Based on
Epotuf 37-143/37-680 (Formula No. 3019-39B) . . . . . . . . . . 182
Water Reducible Alkyd Yellow Iron Oxide Primer
Using Halox SZP-391 ............................. 183
Water Reducible Alkyd Yellow Iron Oxide Primer
Using Halox CW-491 .............................. 184
Water Reducible Epoxy-Ester Red Iron Oxide Primer . . . . . . . . . . 185
Water Reducible Epoxy-Ester Red Iron Oxide Primer
Using Halox CW-491 .............................. 187
White. Corrosion Resistant Latex Primer . . . . . . . . . . . . . . . . . . . 188
White Inhibitive Maintenance Primer ...................... 189
SZP-391 & BW-100 .............................. 177
SECTION IX:SEALANTS AND RELATED COMPOUNDS . . . . . . 190
Ancamide 2353 Curing Agent Aluminum Mastic . . . . . . . . . . . . . . 191
Clear Sealant ....................................... 192
High-Quality Exterior Latex Caulk ....................... 193
Patching Compound (Brushing Grade) ..................... 194
Patching Compound (Trowel Grade) ....................... 195
Pigmented Caulk Formulation based on 2:l Vinyl
AcrylidAcrylic Blend .............................. 196
Premium.Performance. Medium-Flexibility Caulk . . . . . . . . . . . . 197
Sealant Application ................................... 198
Translucent Caulk Formulation .......................... 199
ASTM C-920 Pigmented Caulk Formulation . . . . . . . . . . . . . . . . 200
Translucent Sealant ................................... 201
Vinyl Acrylic Sealant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202
Weather-Barrier Mastic ............................... 203
SECTION X: STAINS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205
Brown Wiping Stain .................................. 206

Contents and Subject Index xv
Interior Wiping Stain (Emulsion E-2977) . . . . . . . . . . . . . . . . . . . 207
Light Redwood Wiping Stain ............................ 208
Stain Concentrate .................................... 209
Tannin Stain Blocking Formulation ....................... 210
Acrylic Tannin Stain-Blocking Primer ..................... 210
Water Reducible Redwood Solid Color Stain . . . . . . . . . . . . . . . . 211
Stain . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207
SECI'ION XI: MISCELLANEOUS ......................... 212
Anquamine 401 Clear Coat Semi-Solid Epoxy Dispersion . . . . . . . 213
Anquamine 401 Clear Coat Solid Epoxy Dispersion . . . . . . . . . . . 214
Anquamine 401 Liquid Epoxy Clear Coat . . . . . . . . . . . . . . . . . . . 214
Aqueous Polyester-Urethane Pigment Dispersion . . . . . . . . . . . . . 215
Black Gloss Enamel .................................. 216
Clear Barriernie Coat for Vinyl ......................... 216
Clear Tint Base ..................................... 217
Clear Waterborne Cement Sealer ...................... 218
Waterborne Black Topcoat ............................. 218
Exterior/Interior Block Filler ............................ 219
High Solids Self Priming Alkyd .......................... 220
Masonry Block Fill . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 221
Masonry Blockfill .................................... 222
Water Reducible Alkyd ................................ 223
2-Component Waterborne System ........................ 224
FCA's for Waterborne Building Product Formulations
SECTION XII: TRADE NAMED RAW M A T E W S . . . . . . . . . . . 225
SECTION XIII: SUPPLIERS ADDRESSES . . . . . . . . . . . . . . . . . . 246

2 Water-Based Paint Formulations
A c r y l i c Eaulsion/Urea-Formaldehyde
Wood C l e a r c o a t M o d i f i c a t i o n
K-Flex UD-320W i s an a l i p h a t i c , s a t u r a t e d , water s o l u b l e r e s i n
m o d i f i e r . T h i s urethane d i o l m o d i f y i n g r e s i n i m p a r t s improved
s t a i n r e s i s t a n c e t o t h e f o r c e d d r y (thermoset) wood c l e a r c o a t
formul a t ion b e l ow.
What makes t h i s f o r m u l a t i o n unique, i s t h e absence o f n e u t r a l -
i z i n g amines. As a r e s u l t , a f r e e a c i d c a t a l y s t may be used
(Nacure 155) and lower temperature c u r e s may be achieved. A p o t
l i f e of 24-48 hours i s p o s s i b l e .
WB Wood C l e a r c o a t
Component:
B e e t l e 65
Methanol
S i l w e t t L-77
Rhopl ex AC-1024
Water
Exxate 700
Chemcor AS-35-3
K-Flex UD-320W
Nacure 155
Methanol
M o d i f i c a t i o n :
0%
24.5
2.4
0 . 4
49.2
7.2
1 . 4
4.1
0.0
4.9
5.9
%K-Flex UD-320W
-5% 10%
24.5 24.5
2.4 2 . 4
0 . 4 0 . 4
44.2 39.3
9 . 4 11.5
1.4 1 . 4
4 . 1 4.1
2.8 5.5
4.9 4.9
5.9 5.9
F o r m u l a t i on Procedure:
1. The components were added i n t h e o r d e r as presented, f o r
easi e r in c o r p o r a t i on.
2. The Nacure 155 c a t a l y s t was p r e - d i l u t e d w i t h t h e methanol
below i t i n t h e f o r m u l a t i o n b e f o r e i n c o r p o r a t i o n , w i t h a
Nacure 155/Methanol r a t i o o f 45.5/54.5.
S u b s t r a t e : B i r c h Faced Plywood
S e a l e r : S e l f Sealed ( 2 Coats, 2 bakes)
Sealer/Topcoat, WFT: 20-25u (0.8-1.0 m i l ) / C o a t
Sealer/Topcoat Bake: 10 min./71C (160F)
4 Hour Spot T e s t
S t a i n T e s t : 0% UD-320W 10% UD-320W
Acrylic/UD-320W/B-65 50/0/50 40/10/50
C o f f e e Severe Haze L i g h t S t a i n
M i l k Severe Haze No E f f e c t
Mustard
Water
Lemon J u i c e
No E f f e c t L i g h t S t a i n
Severe Haze No E f f e c t
S l i g h t Haze No E f f e c t
No e f f e c t was seen i n t h e 4 hour s p o t t e s t i n any o f t h e
f o r m u l a t i o n s w i t h ketchup, n a i l p o l i s h remover, i s o p r o p a n o l ,
l i q u i d c l e a n e r o r l i p s t i c k .
160F r e s u l t e d i n an H p e n c i l hardness and 100+ MEK double rubs.
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n WR-26
Drawdowns made o v e r Aluminum p a n e l s and baked 10 minutes a t

Coatingsand Topcoats 3
A l i p h a t i c Wood Coatinn Formulation
JSancure 825/Rho~lexCL-104)
61end :
Rhoplex CL-104 (38% S o l i d s )
Water
Add f o l l o w i n g w i t h good a g i t a t i o n :
Dowanol DPM
Hexyl C a r b i t o l
Mix 10-15 minutes
Sancure 825 (34% S o l i d s )
Surfactant Package (Premix t h e f o l l o w i n g ) :
Surfynol 104H
Surfynol DF-l1OL
Mineral S p i r i t s
Surfynol DF-70
DC-14
Add and mix 30 minutes
Pounds
134.2
33.8
12.75
2.55
100.0
2.6
1 . 3
1.3
1.3
0.7
Adjust t o desired v i s c o s i t y using Acrysol RM825 (Rohm & Haas Co.)
I f required, f l o w i s enhanced by a d d i t i o n o f very low l e v e l s o f
Fluorad FC-129 (3M Corp.) as a 10% s o l u t i o n i n water.
NOTE: Avoid excessive use o f fluorocarbons, as sharp surface
tension drops can cause recoat problems and strong foaming
tendencies.
Always a d j u s t t o desired v i s c o s i t y range p r i o r t o evaluating
f l o w / l e v e l and deaeration p r o p e r t i e s . Low v i s c o s i t y can
y i e l d “Picture-Framing‘‘ and/or a “ F i sh-Eye“ e f f e c t . High
v i s c o s i t y can y i e l d poor deaeration p r o p e r t i es.
Surfynol a d d i t i v e s have been shown t o provide t h e f o l l o w i n g
benef it s :
*Color u n i f o r m i t y o f s t a i n s
*Early s t a i n 1appi ng resistance
*Consistent wetting, f l o w and l e v e l i n g on various woods
*Foam c o n t r o l
With no detrimental e f f e c t upon:
*Topcoat r e c o a t a b i l i t y and i n t e r c o a t adhesion
*Gloss r e t e n t i o n upon aging
*Tannin bleed r e s i stance
*Water s e n s i t i v i t y
*Chemical resistance
SOURCE: A i r Products & Chemicals, I n c . : Surfynol Surfactants:
Formulation A (B.F. Goodrich)

Ancamine 2410 H i g h S o l i d s C o a t i n g
A S i d e :
DER 331
TS 610
50% FC430 i n Xylene
Disperse, t h e n reduce speed
S t a i n l e s s s t e e l f l a k e
BYK 320
Aromatic 100
B S i d e :
Ancami ne 2410
E t h y l A l c o h o l
D i s s o l v e , t h e n add:
C a b o s i l TS 720
W o l l a s t o c o a t 10ES
D i s p e r s e t o 6 n . s . u .
Methyl E t h y l Ketone
T y p i c a l P r o p e r t i e s :
Non V o l a t i l e by Weight: 0.75
Non V o l a t i l e by Volume: 0 . 6 0
PVC: 0 . 1 6
CPVC: 0 . 3 4
PVC/CPVC: 0 . 4 8
P i gment Content: 0.30
NVV on V e h i c l e : 0 . 6 4
VOC g/1: 3 2 7 . 9
VOC l b s / g a l : 2 . 7 4
&
330.9
7
3.5
176
79
7 . 1
1 5 0 . 5
37.7
8.8
133.3
152.3
Wei ght/Gal l o n Comp A :
Weight/Gallon Comp 0 :
M i x i n q R a t i o : 1 : l
Gals
34.1
0 . 4
0 . 4
3 . 2
1
1 0 . 9
1 5 . 5
5.8
0 . 5
5 . 5
22.7
1 2 . 0 6
9 . 6 5
Weight p e r G a l l o n : 1 0 . 8 5
I n i t i a l V i s c o s i t y : 580 cP
Pot L i f e : 4 . 5 h r
Dry t o Touch: 0.75 h r
Dry Hard: 4 h r
Ancamine 2410 Chemical Resistance: 7 Day Immersion R e s u l t s :
Reagent :
Acetone
Cyclohexanone
PM A c e t a t e
E t h y l A c e t a t e
Ethanol
Isodecanol
Aromatic 100
To1uene
DMF
THF
EP
R e s u l t :
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
Reagent:
NMP
C1o r o x
Skydro1
50% c a u s t i c
10% c a u s t i c
6% HC1 :
S u l f u r i c :
A c e t i c A c i d
D i e t h y l ami ne
50% phenol i n x y l e n
R e s u l t :
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
No E f f e c t
81is t e r e d
81 is t e r e d
B l i s t e r e d 0 1
i e D 0 4
SOURCE: A i r Products and Chemicals, I n c . : Ancamine 2410 C u r i n g
Agent: E x h i b i t 3 F o r m u l a t i o n

Coatings and Topcoats 5
E x h i b i t 4 - S t a r t i n g Formul-ation
Ancarni ne 241O/Ancami de 500 High. Sol i d s C o a t i n g
A S i d e :
DER 331
C a b o s i l TS-610
Lbs Gals
284.6 29.3
7.6 0.43
D i s p e r s e a t H i g h Speed
Reduce Speed, t h e n add:
A1 umi num L243 106 8.59
When u n i f o r m l y mixed, add:
E p o d i l 759
SF 69
B S i d e :
Ancami ne 2410
B e e t l e 216-8
Ancamide 500
M e t h y l E t h y l Ketone
n B u t y l A l c o h o l
T y p i c a l P r o p e r t i e s :
Non V o l a t i l e by Weight: 0.72
Non V o l a t i l e by Volume: 0.64
PVC: 0.056
CPVC: 0.31
PVC/CPVC: 0.17
Pigment Content: 0.09
NVV on V e h i c l e : 0.7
VOC g / l : 290.53
VOC l b s / g a l : 2.43
86.3 11.64
0.3 0.04
77.67 8.00
22.7 2.60
81.8 10.34
29.1 4.44
73.9 11.01
81.7 12.10
9.8 1.49
Weight/Gallon Comp A : 9.68
W e i g h t / G a l l o n Comp 0: 7.53
M i x i n g R a t i o : 1:l
Weight p e r G a l l o n : 8.61
I n i t i a l V i s c o s i t y : 270 CP
Pot L i f e : 3 h r
Dry t o Touch: 1.5 h r
Dry Hard: 4 h r
C o r r o s i o n Resi stance :
E x h i b i t 4 i s a p r e l im i n a r y s t a r t i n g f o r m u l a t i o n combi n i ng
Ancamine 2410 c u r i n g agent w i t h Ancamide 500 c u r i n g agent as t h e
B s i d e . C o r r o s i o n r e s i s t a n c e i s v e r y good. C l e v e l a n d h u m i d i t y
t e s t i n g showed no a t t a c k a f t e r 700 h o u r s . S a l t s p r a y r e s u l t s
on g r i t b l a s t e d s t e e l showed no a t t a c k i n t h e f i e l d and minor
a t t a c k a t t h e s c r i b e (8 r a t i n g ) a f t e r 700 h o u r s .
SOURCE: A i r P r o d u c t s and Chemicals, I n c . : Ancamine 2410
C u r i n g Agent: E x h i b i t 4

6 Water-Eased Paint Formulations
B l a c k S i n g l e Coat K-Flex-XM-4316 P U - D ~ s p e r s l o nCured w i t h HMMM
F o r m u l a t i o n WR-40 i s a h i g h performance h i g h g l o s s b l a c k
f o r m u l a t i o n based on K-Flex XM-4316 p o l y e s t e r - u r e t h a n e d i s p e r s i o n
c r o s s l i n k e d w i t h an amino r e s i n . The f o r m u l a t i o n o f f e r s a h i g h
g l o s s c o a t ing
Component:
Pigment G r i n d Paste, P a r t 1 :
K-F1 ex XM-2311
Water, d e i o n i z e d
Dimethylethanolamine ( 1 )
Monarch 1300
K-Sperse 152 MS
Dimethylethanolamine ( 2 )
Pigment Paste, P a r t 2 :
K-Flex XM-2311
K-F1 ex XM-4316
Water, d e i o n i z e d
Pigment Paste
K-F1 ex XM-4316
Water d e i o n i zed
Resimene 747
Nacure 2547
S i l w e t L7604/L7605 ( 1 : l ) 25% i n H20
Water as r e q u i r e d f o r v i s c o s i t y adjustment
F o r m u l a t i o n C h a r a c t e r i s t i c s :
Resi n/HMMM, r a t 10 : 75/25
N o n v o l a t i l e , c a l c u l a t e d , 'YO: 39.0
T h e o r e t i c a l VOC, g/L, ( l b / g a l l o n ) : 145, ( 1 .23)
B r o o k f i e l d V i s c o s i t y , 25C, s p i n d l e #16, 60 rpm, c p . :
Cure Schedule, temperature, t i m e : 150C, 15 m i n u t e s
Dry F i l m Thickness, m i l , ( m i c r o n ) : 1 . 0 ( 2 5 )
Gloss, 60, 20, 90: 91, 81
pH: 7 . 8 - 8 . 3
F i l m P r o p e r t i e s : S u b s t r a t e , aluminum
% W t
2 . 4 0
2.95
0.15
1 .oo
0.07
0 . 1 0
1.20
1 . 2 0
1 . 1 0
10.17
63.95
6 . 2 0
9 . 5 5
0 . 1 3
0.40
9 . 6 0
300-500
F o r m u l a t i o n Notes:
Pigment G r i n d Paste P a r t 1 : B l e n d t h e K-Flex XM-2311 p o l y u r e t h a n e
d i s p e r s a n t r e s i n w i t h water and d i m e t h y l e t h a n o l a m i n e ( 1 ) and add
t h e carbon b l a c k , premix and add t h e b l e n d o f K-Sperse w i t h
d i m e t h y l e t h a n o l a m i n e ( 2 ) , check t h e pH and add more d i m e t h y l e t h a -
nolamine i f pH i s below 9.2, d i s p e r s e i n a s t e e l b a l l m i l l t o
Hegman NS 8 r a t i n g .
Pigment Paste P a r t 2 : A f t e r g r i n d i n g i n t h e s t e e l b a l l m i l l add
t h e a d d i t i o n a l K-Flex XM-2311, XM-4316 and w a t e r t o t h e b a l l
m i l l , r u n f o r an a d d i t i o n a l 30 m i n u t e s . The pigment c o n c e n t r a t e
i s s t a b l e . A f t e r l o n g e r a g i n g a d d i t i o n o f s m a l l amounts o f amine
f o r pH adjustment m i g h t be r e q u i r e d .
Letdown Formula: L e t t h e pigment p a s t e down under a g i t a t i o n
w i t h remainder o f K-Flex XM-4316, w a t e r , melamine c r o s s l i n k e r
and c a t a l y s t . Add t h e s i l i c o n e s u r f a c t a n t and use t h e remainder
o f t h e w a t e r f o r v i s c o s i t y a d j u s t m e n t s . F i n a l pH o f t h e f o r m u l a -
t i o n s h o u l d be between 7.8 t o 8 . 3 .
SOURCE: K i n g I n d u s t r i e s : P r e l i m i n a r y F o r m u l a t i o n WR-40

Clear Bake Coating
Materi a1 :
E p i -Re2 3522-W-60 Resin
~ _ _ _Pounds Gal 1ons
637.50 69.29
Thoroughly pre-nix t h e f o l l o w i n g and add t o t h e above under
g e n t l e a g i t a t i o n .
Cyme1 324
B u t y l O x i t o l Glycol Ether
2-Propoxyethanol
BYK-301 A n t i - c r a t e r i n g agent
Syntex 3981 Accelerator
53.10 5.71
22.50 3.00
40.20 5.00
2.00 0.25
2.75 0.37
Blend thoroughly. Dissolve f o l l o w i n g by warming t o 150F.
Add t o above under a g i t a t i o n before a l l o w i n g t o cool.
O i cyandi ami de
Dei oni zed water
Typical Coati ng Properties :
% N o n - v o l a t i l e - weight: 48.5
- volume: 43.2
V i s c o s i t y : 57 K.U.
pH: 7.0
Pounds/Gallon: 9.05
V o l a t i l e Composition:
Water
Organics
V o l a t i l e Organic Compounds (VOC):
Pounds/Gallon: 1.46
Grams/Li t e r : 175
13.50 0.41
133.00 15.97
_ _ _ _ _ _Pounds Gallons
388.0 46.50
62.7 8.00
F i l m Properties:*
Bake Schedule: Pencil Hardness Reverse Impact, i n . - l b s .
160
160
160
160
5 min. a t 450F 4H
30 min. a t 400F 5H
15 min. a t 400F 5H
30 min. a t 350F 4H
* Films cast #42 Myra Bar (0.75 m
f l a s h .
SOURCE: She11 Chemical Co. : S t a r t
E p i -Rez 3522-W-60 Resin
1 . ) on bonderite 1000; 10 min.
ng Formulation No. 2500:

Clear Bake Coatinq
Materia1 : Pounds
Epi -Rez 3551-WY-43 Resi n 756.0
Add under a g i t a t i o n :
Ektapro EEP
Beetle 80
Water
Typical Coating Properties:
Total Weight Solids, %: 47.5
Total Volume Solids, %: 41.8
Pounds/Gallon: 8.96
Epoxy/Urea, based on s o l i d s
V o l a t i l e Organic Compounds
Pounds/Gal l o n : 1 .85
V i s c o s i t y , B r o o k f i e l d #5 Sp
Dry F i l m Thickness: 1.0 m i l
Substrate: Bonderite 1000
Typical F i l m Properties:
21.2
86.8
31.5
%: 80/20
VOC) :
ndle, 20 rpm, cps: 1,400
Gal lons
84.00
2.68
9.54
3.78
Bake Schedule a t 350F, minutes: 20
Pencil Hardness: 3H
Reverse Impact, i n . l b s . : 80
S t a r t i n g Formulation No. 2501: Epi-Rez 3551-WY-43 Resin
Phenolic Clear Bake Coating
Pounds GallonsMateri a1 :
Water 115.5 13.87
Methylon 75108 162.5 16.75
B u t y l O x i t o l Glycol Ether 48.8 6.50
n-Butyl Alcohol 43.9 6.50
Syntex 3981 Accelerator 58.1 7.90
~~
Epi-Rez 3540-WY-55 Resin 442.9 48.48
Premix and add slowly under a g i t a t i o n :
Pounds/Gallon: 8.72
Epoxy/Phenolic: 60:40
C a t a l y s t , a c t i v e on r e s i n s o l i d s , %: 3.3
Pounds/Gallon: 2.68
V i s c o s i t y , #4 Ford Cup, seconds: 40-60
pH: 6.4
Reduction f o r Conventional Spray A p p l i c a t i o n : None
Dry F i l m Thickness: 0 . 4 m i l s
Bake Schedule: 15 min. a t 450F
Pencil Hardness: 9H
Reverse Impact, i n . l b s . : >I60
MEK Resistance, double rubs: 100
Typical F i l m Properties:
SOURCE: Shell Chemical Co.: S t a r t i n g Formulations

Clear Bake Coating
Materi a1 :
Epi -Rez 3540-WY-55 Resin
Water
Premix and add:
Beetle Urea Formaldehyde Resin
n-Butyl Alcohol
Syntex 3981 Accelerator
Pounds
579.6
113.7
80.7
43.2
55.9
Gal l o n s
63.42
13.65
8.92
6.40
7.61
Pounds/Gallon: 8.73
Epoxy/Urea: 80/20
C a t a l y s t , % ( A c t i v e on r e s i n s o l i d s ) : 2
Pounds/Gal 1on: 2.19
Grams/Liter: 263
V i s c o s i t y , #4 Ford Cup, seconds: 60-80
pH: 7.1
Phenolic Clear Bake Coating
Materia1 :
Part A:
Premix and add under a g i t a t i o n :
Santol ink EP560
Ektapro EEP
Add under a g i t a t i o n :
Water
_ _ _ _ _ _Pounds Gal 1ons
662.1 73.56
93.1 10.18
80.6 10.16
5 0 . 8 6.10
Typical Coati ng P r o p e r t i es :
Pounds/Gallon: 8.87
Epoxy/Phenolic, based on s o l i d s , percent: 80/20
Pounds/Gal 1on: 2.90
Grams/Liter: 348
Viscosity, #4 Ford Cup, seconds: 70-80
Dry F i l m Thickness: 0 . 5 m i l
Bake Schedule a t 350F. minutes: 20
Pencil Hardness: 5H
Reverse Impact, i n . l b s . : s160
MEK Resistance, Double Rubs: 100
Typi c a l F i 1m Properties :
S t a r t i n g Formulation No. 2505: €pi-Rez 3551-WY-43 Resin
SOURCE: S h e l l Chemical Co. : S t a r t i n g Formulations

C l e a r Wood CoatinQ-A & B 8 C
_-K-F1 ex UD-320W Modi f ie d
The f o l l o w i n g wood c o a t i n g f o r m u l a t i o n e v a l u a t e s K-Flex
UD-320W a t 5 and 10% m o d i f i c a t i o n on s o l i d s . The system was
c a t a l y z e d w i t h K-Cure 129W. Cure response was examined on
c l e a n b a r e and 840 t r e a t e d Aluminum a t a r a p i d schedule o f 60
sec./82C. Hardness improvements were found a t a l l l e v e l s o f
m o d i f i c a t i o n (See f i l m p r o p e r t i e s ) . The t r e a t e d s u b s t r a t e gave
s o f t e r f i l m s i n i t i a l l y compared t o b a r e m e t a l , but improved
p r o p e r t i e s were observed a f t e r 24 h o u r s a g i n g . K-Flex UD-320W
m o d i f i c a t i o n i n c r e a s e d f i l m hardness b u t d i d n o t improve w a t e r
r e s i s t a n c e p r o p e r t i e s
Formul a t i on :
Rhoplex AC-1024
B e e t l e 65
K-Flex UD-320W
K-Cure 129W
A c r y l i c / P o l y o l / U r e a
% S o l i d s
F i l m P r o p e r t i e s :
FC-430
S u b s t r a t e : Aluminum (Clean Bare)
Cure: 60 sec./82C
F i l m Thickness: 0 . 7 + - 0 . 1 m i l DFT
W*
66.7
33.3
0 . 0
0 . 1 3
1 . 7
SO/-/50
6 6 . 7
A : 50,’-/50
I n i t i a l
24 Hours
0 : 45/5/50
I n i t i a l
24 Hours
C : 35/10/55
I n i t i a l
24 Hours
Penci 1 KHN25
HB-F 4.19
F-H 11.20
HB-F 6 . 2 5
H-2H 14.20
HB-F 5.41
H-2H 15.50
W- Wt%C
61 .8 51.4
34.3 40.4
3 . 9 8 . 2
0 . 1 3 0.13
1 . 7 1.8
45/5/50 35/10/55
6 7 . 5 72.2
Crosshatch
Adhesion
MEK Rubs (%Loss)
200 0
200 0
200 0
200 0
180 0
200 0
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-10 A & B & C

I n g r e d i e n t s :
Resin Phase:
Water
Maincote PR-71
Ammonia (28)
D i r e c t t o Metal A c r y l i c Latex Coating
S t a r t i n a P o i n t Formulation
Lbs Gals
45.9 5.510204
2.05 0.273333
481.2 55.31034
Set aside f o r l a t e r a d d i t i o n , i n t o a separate vessel add:
Water Phase:
Water
Bentone AD
Tamol 165
Drewpl us L-493
B u t y l Cel l o s o l v e
D i b u t y l Phthalate
Ammonia (28)
Premix:
Chrom. Grn. Oxide 5-5310
A c t i r o x 215
Nyad 1250
Disperse t o 5 n.s.u. Then
homogenization, add, whi
E t h y l Alcohol
15% NaN02 i n Water
20% QR-708 i n Water
150
1.4
11.2
1
36.6
7.3
n
47.9
89.8
116.3
l e t down w i t h r e s i n phase
e mixing, t h e f o l l o w i n g :
18
3.06
12.75
18.00720
0.064641
1.222707
0.133155
4 .a73501
0.8371 55
0.4
1.078828
3.368847
4.805785
4 f t e r
2.748091
0.337375
1 .514251
General Performance Benef t s :
E x c e l l e n t adhesion t o s t e e l , galvanized s t e e l and aluminum
S u i t a b l e f o r s i n g l e coat s e r v i c e
Excel 1ent recoatabi 1it y w i t h s o l v e n t based f i n i s h e s
High r e s i s t a n c e t o s a l t spray, 3000 hours from 2 d r y m i l s on
Appl icab1e under margi nal c o n d i t i o n s (40F)
c o l d r o l l e d s t e e l
SOURCE: Nyco Minerals, I n c . : Suggested Formulation

Low Gloss Vinvl/ABS Topcoat
Materi a1
Spensol L53
D i sperse-Ayd
Surfynol 104H
Fl a t t ing Agent TS100
Lodyne S107B
Lbs. Gals .
808.7 92.85
6.6 0.75
6.0 0.75
25.0 1.so
1.4 0.15
Disperse a t high speed f o r 15-20 minutes, then premix and add:
M i cheml ube 737
Water
Anal y s i s:
Percent Sol i d s , Weight : 31 .8
Percent Solids, Volume: 28.4
V i s c o s i t y @ 25C, #2 Zahn, Secs.: 20-25
Gloss (60/20): 7/4
VOC (excluding water):
Pounds/Gal 1on : 2.4
pH: 8.0-8.5
Formulation 2124-54C
16.4 2.0
16.7 2.0
Clear Topcoat for F l e x i b l e Substrates
Materia1 :
Spensol L53
Surfynol 104H
C o l l o i d 679
Ucar SCT 100
M i cheml ube 737
Water
Lbs. Gals.
826.5 95.00
4 . 0 0.50
1.9 0.25
2.3 0.25
16.4 2.00
16.7 2.00
Add t h e above m a t e r i a l s i n order under good a g i t a t i o n .
NOTE: An o p t i o n a l a z i r i d i n e c r o s s l i n k i n g agent can be added t o
t h e above formula a t a l e v e l o f 7-10 lbs./100 gallons.
Analysis:
Percent Sol ids, Wei ght : 29.8
V i s c o s i t y @ 25C, #4 Ford, Secs.: 65+-5
Pounds/Gallon: 8.7
Grams/Liter: 374
Pounds/Gallon: 3.1
PH: 8.5t-0.3
Formulation 2307-248
SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formulations

S t r i p p a b l e C o a t i n g Sample F o r m u l a t i o n A
_____Unmodi f ied
In n r e d i e n t s :
Ucar Latex 447
Ucar F i l m e r IBT
Foamaster VF
Water
C o a t i n g P r o p e r t i e s :
AMP-95
V i s c o s i t y , cP: 1060
Stormer V i s c o s i t y , KU: 70
pH Value: 6.6
T o t a l S o l i d s , % by w e i g h t : 59.3
Pounds
797.3
2 . 1
47.5
2.1
40.9
S t r i p p a b l e C o a t i n q Sample F o r m u l a t i o n B
-Lower- Adhesion
I n q r e d i e n t s :
Ucar Latex 447
AMP-95
Foamaster VF
Soya L e c i t h i n
Water
V i s c o s i t y , cP: 1820
pH Value: 6 . 7
T o t a l S o l i d s , % by w e i g h t : 60.3
S u b s t r a t e S t r i p p a b i 1i t y :
S u b s t r a t e :
Galvanized S t e e l
A1 -Bonderi t e
A1-A1 o d i ne
Cold R o l l e d S t e e l
My1a r
G1ass
P o l y s t y r e n e
Gloss A1 kyd
P o l y e s t e r
X=peeled c l e a n and easi l y
_ _ ~Pounds
777.0
2 . 1
46.7
2.1
20.0
41.1
G a l l o n s
88.54
0.27
6.01
0.27
4.91
G a l l o n s
86.33
0.27
5.91
0.27
2.29
4.93
Formula A
X
X
X
X
X
X
X
X
X
Formula B
X
X
X
X
X
X
X
X
X
SOURCE: Ucar Emulsion Systems: Ucar Latex 447: F o r m u l a t i o n s A & B

S t r i p p a b l e Coatina Formulations
Thickened w i t h Ucar Polyphobe Rheology M o d i f i e r s
Formula C
Good Leveling
Pounds Gal lonsI n g r e d i e n t s :
Ucar Latex 447 780.9 06.77
AMP-95 4.4 0.57
Ucar Filmer IBT 46.8 5.95
Foamaster VF 2.1 0.28
Water 40.6 4.89
Ucar Polyphobe 107 13.4 1.54
~~
Coating Properties:
V i s c o s i t y , cP: 2500
pH Value: 8.1
Total Solids, % by weight: 60.1
Formula D
High B u i l d
Ucar Latex 447
Ucar Filmer IBT
Foamaster VF
Water
Ucar Polyphobe 102
Coating Properties:
AMP-95
V i s c o s i t y , cP: 3200
Stormer Viscosity, KU: 84
pH Value: 8.9
Total Solids, % by weight: 58.8
Substrate S t r i p p a b i 1it y :
Substrate:
Galvanized Steel
A1-Bonderi t e
A1-Alodi ne
Cold Rolled Steel
Mylar
G1ass
Polystyrene
Gloss Alkyd
Polyester
X=peeled clean and e a s i l y NT=not
~~Pounds Gal 1ons
702.7 06.97
4.8 0.62
46.9 5.94
2.1 0.27
40.6 4.07
11.6 1.33
Formula C Formula D
X X
X X
NT NT
X X
X X
X X
NT NT
X X
NT NT
t e s t e d
SOURCE: Ucar Emulsion Systems: Ucar Latex 447: Formulations

S t r i p p a b l e C o a t i n q f o r P l a s t i c S u b s t r a t e s
Premix #1 :
Ucar V e h i c l e 441
Defoamer (1 )
Soya L e c i t h i n (2)
Premix #2:
T r i o c t y l Phosphate
S t r i p p i n g A i d (3)
Water
Premix #3:
T h i c k e n e r (4)
Water
Premix #4:
T r i e t h y l a m i n e
I s o p r o p a n o l , 91%
Water
Water
Pounds
603.8
9.1
10.1
40.2
13.9
39.2
27.1
27.2
7.2
8.6
14.3
48.3
Gal l o n s Wt%
69.80 71.12
1 .31 1.07
1.16 1.19
5.22 4.74
1.47 1.64
4.71 4.62
3.10 3.19
3.26 3.20
1.18 0.85
1.27 1.01
1.72 1 .68
5.80 5.69
i e r s :
) Defoamer - P a t c o t e 513 ( P a t t e r s o n Chemical) o r e q u i v a l e n t .
) Soya L e c i t h i n - K e l e c i n 1081 (Spencer K e l l o g g ) o r e q u i v -
a1e n t .
e q u i v a l e n t .
(3) S t r i p p i n g A i d - Strodex PK-90 ( D e x t e r Chemicals) o r
(4) T h i c k e n e r - A c r y s o l ASE-60 (Rohm and Haas) o r e q u i v a l e n t .
Procedure:
Blend Premix #1 f i r s t , i n t h e o r d e r shown, and t h e n add t h e
r e m a i n i n g Premixes i n numerical o r d e r . A l l o w f i v e t o 10 minutes
o f a g i t a t i o n between a d d i t i o n s o f Premixes. The l a s t increment
o f w a t e r , shown below Premix #4, can b e added i n stages t o a l l o w
p r o p e r a g i t a t i o n .
T o t a l S o l i d s , % by w t : 40.1
pH: 8.6
V i s c o s i t y , B r o o k f i e l d , cP: 2410
V i s c o s i t y , Stormer, KU: 84
Heat-Age S t a b i l i t y , 2 wk a t 12OF: Pass
Freeze-Thaw S t a b i l i t y , 3 c y c l e s : Pass
SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 441: F o r m u l a t i o n
Suggestion LP-1924

S t r i p p a b l e C o a t i nq F o r m u l a t i o n s
Inqr e dient-s :
Thickener ( 1 ) (11% N . V )
B u t y l C a r b i t o 1 Sol v e n t
Water
Weight p e r G a l l o n , l b : 8 . 6
p H 8 . 0
Formul a t ion LP-3760
I n g r e d i entg:
Thickener ( 1 ) (11% N.V.)
B u t y l Carbi t o 1 S o l v e n t
W e t t i n g Agent ( 2 )
Water
Weight p e r G a l l o n , l b : 8.6
p H : 8 . 0
F o r m u l a t i o n LP-3761
i c a r V e h i c l e 441
B u t y l C a r b i t o l S o l v e n t
Water
Weight p e r G a l l o n , l b : 8 . 6
pH: 8 . 0
B u t y l C a r b i t o 1 S o l v e n t
Water
Weight p e r G a l l o n , l b : 8.6
pH: 8 . 0
~-Pounds
840.0
5 . 4
8 . 4
10.0
-~Gal 1ons
9 7 . 1
0.7
1 . o
1 . 2
Pounds Gal 1ons
830.0 9 5 . 9
5.4 0 . 7
8 . 4 1 . o
6 . 6 0 . 8
3.3 0 . 4
10.0 1 . 2
Pounds G a l l o n s
827.0 9 5 . 6
5.4 0 . 7
8 . 4 1 . o
10.0 1 . I
3 . 3 0 . 4
1 0 . 0 I . 2
Pounds Gal 1ons
820.0 94.8
5 . 2 0 . 6
8 . 2 1 .o
16.4 1 . 9
3.3 0 . 4
1 0 . 7 1 . 3
Suppl ie r s :
( 1 ) Thickener - A c r y s o l G-110 (Rohm and Haas) o r e q u i v a l e n t .
( 2 ) W e t t i n g Agent - I n t e r w e t #33 ( I n t e r s t a b ) o r e q u i v a l e n t .
Note: I n c l u d e a s u i t a b l e p r e s e r v a t i v e i n each f o r m u l a s u g g e s t i o n .
SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 441: F o r m u l a t i o n s

Topcoat f o r Prefin ished Hardboard S i d i n g
Inqredients:
PiQment Or4 nd:
Water
T e r g i t o l Nonionic Surfactant
Tamol 731
Foamaster VF
T i -Pure R-960
Nytal 400
S i l c r o n G-601
Nuocide 960
Letdown :
Ucar Vehicle 462
Cyme1 325
Arcosol ve PP Sol vent
Cycat 4040
Foamaster VF
CAO-1 Anti-Oxidant
Tinuvin 328 UV Absorber
NP-10
Pounds
134.8
4.7
9.3
1.o
174.4
46.5
46.5
4.5
Gal lons
16.2
0.6
1 .o
0.2
5.2
2.7
2.0
0.6
535.4 60.8
45.2 4.4
36.1 4.9
2.8 0.3
1.1 0.1
3.0 0.3
6.5 0.7
Paint Properties:
Pigment Volume Concentration, %: 28
Crosslinker, phr: 15
Cosolvent, phr: 15
Volume Solids, %: 41
Weight per Gallon, l b : 10.6
SOURCE: Ucar Emulsion Systems: Ucar Vehicle 462: Formulation
Suggestion

Water-Borne A1 kvd/Mel ami ne
Kood C l e a r c o a t M o d i f i c a t i o n
K-Flex XM-2304 i s an e x p e r i m e n t a l p r i m a r y h y d r o x y l c o n t a i n i n g
a l i p h a t i c , s a t u r a t e d u r e t h a n e r e s i n m o d i f i e r . T h i s water-borne
alkyd/melamine wood c l e a r c o a t f o r m u l a t i o n demonstrates improved
s t a i n r e s i s t a n c e and f l o w / l e v e l i n g u s i n g t h i s p r o d u c t .
%K-Flex XM-2304
Component: 0% 5% 10%
C a r g i l l 7412
Resimene 747
I s o p r o p a n o l
Water
K-Flex XM-2304
Nacure 155
K-F1 ex XM-2304:
% S o l i d s ( C a l c u l a t e d )
W e t t i n g
Alkyd/XM-Z304/HMMM
31 . 5 2 8 . 3 25.1
31 . 5 31.5 31.5
14.8 1 4 . 8 14.8
1 5 . 7 15.6 1 5 . 6
0 . 0 3 . 5 6 . 5
6 . 5 6.5 6 . 5
0% 5% 10%
66.6 6 6 . 5 66.4
5 0 / 0 / 5 0 45/5/50 40/10/50
Poor Good Best
S u b s t r a t e : Sanded and Sealed B i r c h Faced Plywood
S e a l e r : Commerci a1 V i n y l Sander/Sealer
Topcoat, WFT: 20-25u ( 0 . 8 - 1 . 0 m i l )
Topcoat Bake: 10 min./71C (160F)
4 Hour Spot T e s t
S t a i n Test
Mustard
Ketchup
C o f f e e
Homog. M i l k
Lemon J u i c e
L i q u i d C1eaner
N a i l P o l i s h Remover
0% XM-2304
M i l d A t t a c k
S t a i n
Severe S t a i n
Severe A t t a c k
M i l d A t t a c k
Severe A t t a c k
Severe Atack
5% XM-2304 10% XM-2304
M i l d A t t a c k No E f f e c t
No E f f e c t No E f f e c t
M i l d S t a i n M i l d S t a i n
M i l d A t t a c k M i l d A t t a c k
M i l d A t t a c k No E f f e c t
Severe A t t a c k / M i l d A t t a c k
No E f f e c t No E f f e c t
W h i l e a l l 3 f o r m u l a s were u n a f f e c t e d i n t h e 4 hour s p o t t e s t
by b l e a c h and m i n e r a l o i l , t h e y a l l e x h i b i t e d a m i l d a t t a c k by
Peps1 Cola; s t a i n i n g f r o m water; and a severe a t t a c k f r o m
i s o p r o p a n o l .
W i t h t h e above c u r e c o n d i t i o n a l l t h r e e f o r m u l a s gave an
H-2H p e n c i l hardness and 100+ MEK d o u b l e r u b s a t 23 u ( 0 . 9
m i 1) on A1umi num.

Water-Borne Alkyd/Melamine
Wood Clearcoat Modification
K-Flex UD-320W i s an a l i p h a t i c , s a t u r a t e d , water s o l u b l e
r e s i n m o d i f i e r . T h i s u r e t h a n e d i o l m o d i f y i n g r e s i n i m p a r t s
s t a i n r e s i s t a n c e t o t h e f o r c e d d r y ( t h e r m o s e t ) alkyd/melamine
wood c l e a r c o a t f o r m u l a t i o n below.
What makes t h i s f o r m u l a t i o n unique i s t h e absence o f n e u t r a l -
i z i n g amines. As a r e s u l t , a f r e e a c i d c a t a l y s t may be used
(Nacure 155) and lower t e m p e r a t u r e c u r e s may be achieved. The
b i n d e r r e s i n ( a l k y d ) i s water d i l u t a b l e w i t h t h e a d d i t i o n o f
a c o s o l v e n t such as i s o p r o p a n o l . A p o t l i f e o f 8-10 hours i s
p o s s i b l e .
WB Wood C 1e a r c o a t -Modi f ic a t i o n
Component:
C a r g i l l 7412
Resimene 747
I s o p r o p a n o l
Water
K-F1 ex UD-320W
Nacure 155
K-Flex UD-320W:
% Sol i d s ( C a l c u l a t e d )
A1 kyd/K-F1 ex UD-32OW/HMMM
% K-Flex UD-320W
0% 5% 10%
31 . 5 28.3 25.1
31 . 5 31.5 3 1 . 5
14.8 14.8 14.8
15.7 15.4 15.0
0 . 0 3 . 5 7 . 1
6.5 6.5 6 . 5
0% 5% 10%
6 6 . 6 66.5 66.4
50/0/50 45/5/50 40/10/50
S u b s t r a t e : Sanded and Sealed B i r c h Faced Plywood
S e a l e r : Commerci a1 V i n y l Sander/Seal e r
Topcoat, WFT: 20-25u ( 0 . 8 - 1 . 0 m i l )
Topcoat, Bake: 10 min./71C (160F)
S t a i n T e s t
Mustard
Ketchup
C o f f e e
Homog. M i l k
Lemon J u i c e
Pepsi Cola
N a i l P o l i s h Remover
4 Hour Spot Test
0% UD-320W 5% UD-320W
Severe S t a i n Severe S t a i n
S t a i n No E f f e c t
Severe A t t a c k No E f f e c t
M i l d A t t a c k Severe A t t a c k
Severe A t t a c k No E f f e c t
10% UD-320W
No E f f e c t
No E f f e c t
M i l d S t a i n
No E f f e c t
Severe A t t a c k
No E f f e c t
No E f f e c t
W h i l e a l l 3 f o r m u l a s were u n a f f e c t e d i n t h e 4 hour s p o t t e s t
by b l e a c h and m i n e r a l o i l , t h e y a l l e x h i b i t e d s t a i n i n g from water
and a severe a t t a c k f r o m i s o p r o p a n o l and l i q u i d c l e a n e r
W i t h t h e above c u r e c o n d i t i o n a l l t h r e e f o r m u l a s gave an H-2H
p e n c i l hardness and 100+ MEK double r u b s a t 23u ( 0 . 9 m i l ) on
A1umi num.

Waterborne Clear Hiqh Gloss Topcoat
Edaplan LA-402 was used i n a Waterborne High Gloss Wood
Topcoat t o improve w e t t i n g and l e v e l i n g . I n combination w i t h
Agitan 315 foam c o n t r o l agent, superior f i l m p r o p e r t i e s are
ach ieved .
Materi a1 : &
Rhoplex E-3188 (Rohm & Haas) 608.00 71 .77
Water 101.33 11.96
Adjust pH t o 8.5-9.0
Ammonia (28%) 5.27 0.62
Premix and add slowly:
Water
Dowanol PnB (DOW Chemical)
Arcosolve DPM (Arco Chemical)
Arcosolve DPt8 (Arco Chemical)
Tributoxyethyl phosphate
Add f o l l o w i n g w h i l e mixing:
FCA (Foam Control Agent)
Wetting Agent
Michem 392-25 (Michelman)
Adjust v i scosit y
Acrysol RM-825 (Rohm & Haas)
Water
Properties:
% N o n v o l a t i l e (by weight): 31.2
% N o n v o l a t i l e (by volume): 29.4
Weight per Gallon (pounds): 8.48
Theoretical VOC ( g r a m s / l i t e r ) : 106
V i s c o s i t y (cPs): 150+-10%
14.79 1.75
14.79 1.75
14.79 1.75
9.93 1.17
9.93 1.17
0.49 0.06
2.47 0.29
14.11 1.67
0.51 0.06
50.67 5.98
SOURCE: King I n d u s t r i e s : WR-31: A d d i t i v e s f o r Waterborne Wood
Formulations

White Gloss Maintenance Topcoat
Pigment G r i nd:
Methyl C a r b i t o l Solvent
Water
Bentone LT
Ammonium Hydroxide, 28% Aqueous S o l u t i o n
Tamol 681
T r i t o n Nonionic S u r f a c t a n t CF-10
Nuosept 95
DeeFo HG-12
Acrysol RM-2020
Acrysol SCT-275
Tronox CR-828
Letdown :
Methyl C a r b i t o l Solvent )Premix
Acrysol SCT-275 1
Ucar Vehicle 435
Troysan Polyphase AF-1
DeeFo HG-12
Sodium N i t r i t e , 15% Aqueous S o l u t i o n
Adjust t o minimum pH 8.7
Pounds
59.6
18.4
1.o
1.8
18.2
2.2
2.3
1.9
17.2
8.6
225.0
8.5
8 . 6
626.9
15.8
4.9
1.9
9.0
1.8
Pai n t P r o p e r t i es :
Pigment Volume Concentration (PVC), %: 18.3
T o t a l Solids, %:
pH Value, i n i t i a l : 8.7
V i s c o s i t y :
Stormer, KU: 78
I C I , poise: 1.1
by volume: 36.1
Freeze-Thaw S t a b i l i t y , 3 cycles: Pass
Heat S t a b i l i t y , 2 weeks a t 140F: Pass
F i l m Properties:
Contrast Ratio, 6-mil wet drawdown: 0.958
Gloss, 60: 70
Gloss, 20: 25
Gal 1ons
7.00
2.21
0.06
0.25
2.00
0.25
0.25
0.25
2.00
1 .oo
6.59
1.oo
1.oo
72.06
2.00
0.50
0.25
1.08
0.25
Suggestion M-2453

White Gloss Topcoat
____M a t e r i a1 :
A r o l o n 580-W-42
Tamol SG-1
T r i t o n CF-10
C o l l o i d 694
E t h y l e n e G l y c o l
B u t y l Carbi t o 1
D o w i c i l 75
Water
Mix a t low speed:
T i t a n o x 2101
G r i n d under h i g h shear 15-20 m i n u t e s .
Under low shear, add letdown.
Water
Col l o i d 694
A r o l o n 820-W-49
Propylene G l y c o l
B u t y l Carbi t o 1 A c e t a t e
C o b a l t Hydrocure I1
Hydroxyethyl C e l l u l o s e QP-300 (10% S o l n )
Ammonia
*lo% QP-300 i n E t h y l e n e G l y c o l
A n a l y s i s :
Pigment Volume Concentration, Percent: 20.0
Pigment/Binder R a t i o : 0.94/1
Percent S o l i d s , Weight: 57.4
Percent S o l i d s , Volume: 44.0
V i s c o s i t y @ 25C, KU: 72-76
Pounds/Gallon: 11.08
VOC ( e x c l u d i n g w a t e r ) :
Pounds/Gallon: 1.2
pH: 8.8-9.0
Lbs. Gals.
65.0 7.30
5.0 0.52
3.0 0.34
2.5 0.35
23.0 2.48
10.0 1.26
1 .o 0.08
18.0 2.16
300.0 8.57
20.0 2.40
2.5 0.35
598.0 67.95
18.0 2.08
8 . 0 0.98
0 . 4 0.05
5.0 0.53
1 .o 0.13
SOURCE: R e i c h h o l d Chrmicals, I n c . : A r o l o n 820: Formula 194-2

Wood Topcoat Model Formulations
Rohm and Haas: Wt%
Rhoplex WL-96 (42%) 73.9
Patcote 519 0 . 2
B u t y l Carbi t o 1 ) 6.2
Dowanol PNB ) Premix 3.1
Michem Lube 110 (25% S o l i d s ) 2.9
Ammonia (14%) Adjust t o pH 8.0 0.1
Water 13.6
S.C. Johnson: Wt%
Joncryl 554 90.9
Ektasolve EB 3.6
Jonwax 26 4.5
Water 1.o
Goodyear : Wt%
Ektasolve EP 8 . 5
S a n t i c i z e r 160 2.7
D i e t h y l ami ne 1.1
Drew L-475 0.2
Water 9 . 1
P l i o l i t e 7104 (44%) 58.5
W i tcobond 234 19.9
Sanncor : Wt%
Water 16.1
Dowanol DPM 4.9
Rhoplex WL-96 (42%) 35.3
Sancure 815 42.3
Dehydran 1293 0.5
BYK 306 0.5
Acrysol RM-825 0.3
Ammonia ( 14%) Approx. 0.1
Evaluation i n Clear Topcoats:
Surfynol 104 s u r f a c t a n t was evaluated i n waterborne c l e a r
topcoats t o c o n f i r m i t s m u l t i p l e b e n e f i t s i n actual wood
c o a t i n g formulas. Since t h e most s t r i n g e n t performance require-
ments are r e l a t e d t o high-end wood coatings. Model topcoat
formulations o f t h i s type were selected f o r study.
Surfynol 104 s u r f a c t a n t was added a t 1% t o t h e model topcoat
formulations.
I n order t o evaluate a p p l i c a t i o n and f i l m property b e n e f i t s ,
Surfynol 104 s u r f a c t a n t ' s b e n e f i t s include:
*Improved f 1ow and 1eve1 ing
*Superior substrate w e t t i n g
*Low foam, and o f t e n defoaming performance
*Rapid d i spl acement o f a i r bubbles
*Mi n imal r e s o l ubi 1izat ion in water
SOURCE: A i r Products 8 Chemicals, I n c . : Surfynol Surfactants:
Suggested Formulations

Coil Coatings 25
Chromate Coi 1-Coati na Primer
Pigment Grind:
Deio n i zed Water
Ethylene G1ycol
N,N-Dimethylethanolamine
Foamaster VF
T e r g i t o l Nonionic S u r f a c t a n t NP-10
Polywet ND-2
L-203-D Strontium Chromate
233 Basic Zinc Chromate
T i -Pure R-900
Letdown :
N, N-Di methyl ethanol ami ne
Ucar Vehicle 462
Carbi t o 1 Solvent
Arcosolve PP Solvent
Cyme1 303
Foamaster VF
Deionized Water
~ _ _ _Pounds Gallons
46.0 5.54
3.8 0.41
0.6 0.09
0.3 0.03
3.8 0.45
15.3 1.63
25.6 0.83
25.6 0.81
204.5 5.96
5.9 0.79
629.5 71.85
16.1 1.88
16.1 2.15
35.5 3.55
1.8 0.22
31.7 3.81
Wei sht%
4.33
0.35
0.06
0.03
0.35
1.44
2.41
2.41
19.25
0.56
59.26
1.52
1.52
3.42
0.17
2.92
Procedure:
order l i s t e d . Thoroughly mix l i q u i d components b e f o r e adding
pigments. Add pigments s l o w l y and s t i r u n t i l uniform. Grind a t
h i g h speed f o r 10 minutes o r u n t i l g r i n d reaches about 50C.
For t h e letdown, add t h e i n g r e d i e n t s i n t h e order shown,
making sure t h e mix i s uniform a f t e r each a d d i t i o n . For a l e s s
c r i t i c a l procedure, premix f i l m i n g a i d s w i t h c r o s s l i n k e r and
water. Mix p a i n t a t l e a s t 10 minutes a f t e r t h e f i n a l a d d i t i o n .
P a i n t P r o p e r t i 8s:
Charge t h e f i r s t s i x g r i n d components t o a Cowles mixer i n
Pigment:Binder Ratio: 0 . 8 : l .O
T o t a l N o n v o l a t i l e s , % by weight: 54.3
Resin:Me1ami ne: 89; 11
Organic i n E f f l u e n t , % by volume: 10
V i s c o s i t y , B r o o k f i e l d , cP: 300
pH Value: 9
SOURCE: Ucar Emulsion Systems: Ucar Veh
Suggestion LP-3821
9
c l e 462: Formulation

Low-Sheen Coil-Coatinq Topcoat
I n q r e d ie n t s :
Pigment G r i nd:
Ethylene Glycol
Polywet ND-2
T e r g i t o l Nonionic S u r f a c t a n t NP-10
Foamaster VF
N, N-Di methyl ethanol ami ne
Dei o n i zed Water
S i l c r o n G-601
T i -Pure R-960 o r Zopaque RCL-6
Letdown :
Foamaster VF
Deionized Water
Pigment G r i nd
Cyme1 303
Procedure:
_ _ _ ~Pounds Gallons
2.42 0.26
9.69 1.03
2.39 0.27
1.17 0.15
0.30 0.04
95.87 11.53
48.46 2.77
193.80 5.82
2.11 0.27
22.10 2.65
3.26 0.44
585.18 66.80
354.10 21.87
30.20 4.02
39.50 3.95
Weight%
0.23
0.93
0.23
0.11
0.03
9.25
4.68
18.70
0.20
2.13
0.32
56.47
34.16
2.91
3.81
Charge t h e f i r s t s i x g r i n d components t o a Cowles mixer tank
i n t h e order l i s t e d . Mix a t low speed f o r 5 minutes. Slowly add
t h e pigments and s t i r u n t i l uniform. Grind a t h i g h speed f o r
10 minutes o r u n t i l g r i n d reaches 50C.
blend i n t o Ucar Vehicle 462 w i t h slow a g i t a t i o n . Reduce t h e
pigment g r i n d w i t h t h e n e u t r a l i z e d l a t e x and s t i r a t low speed
f o r 10 minutes. Add t h e melamine r e s i n and s o l v e n t . S t i r a t
moderate speed f o r 10 minutes.
P a i n t P r o p e r t i e s :
For t h e letdown, combine t h e antifoam, water, and t h e amine;
Pigment:Binder R a t i o : 0 . 8 : l .O
Pigment Volume Concentration, %: 19.7
T o t a l N o n v o l a t i l e s , % by weight: 53.6
Organic i n E f f l u e n t , % by volume: 10.5
Resi n:Mel ami ne: 87: 13
SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 462: Formulation
Suggestion LP-3794

Coil Coatings 27
Medium-Gloss Coil-Coating Topcoat
Pigment Grind:
Ethylene Glycol
T e r g i t o l Nonionic S u r f a c t a n t NP-
Foamaster VF
Polywet ND-2
Deionized Water
Ti-Pure R-960 o r Zopaque RCL-6
Letdown :
Foamaster VF
Deionized Water
N,N-Dimethylethanol ami ne
Ucar Vehicle 462
Pigment G r i nd
Cyme1 303
Deionized Water
Pounds
2.48
10 2.53
0.47
10.06
0.35
52.89
253.28
4.29
4.61
2.97
630.31
322.06
31.57
35.22
26.02
Gal 1ons
0.27
0.29
0.06
1.07
0.05
6.36
7.61
Wei qht%
0.23
0.24
0.04
0.95
0.03
5.00
23.96
0.55 0.41
0.55 0.44
0.40 0.28
71.96 59.64
15.69 30.45
4.20 2.99
3.52 3.33
3.13 2.46
Procedure:
Charge t h e f i r s t s i x g r i n d components t o a Cowles mixer tank
i n t h e order l i s t e d . Mix a t low speed f o r 5 minutes. Slowly add
t h e t i t a n i u m d i o x i d e and s t i r u n t i l uniform. Grind a t h i g h speed
f o r 10 minutes o r u n t i l g r i n d reaches 50C.
For t h e letdown, combine t h e f i r s t increment o f water, t h e
antifoam, and t h e amine; blend i n t o t h e Ucar Vehicle 462 w i t h
slow a g i t a t i o n . Reduce t h e pigment g r i n d w i t h t h e n e u t r a l i z e d
l a t e x and s t i r a t low speed f o r 10 minutes. Add t h e remaining
water, melamine r e s i n , and s o l v e n t . S t i r a t moderate speed f o r
10 minutes.
Pigment:Binder R a t i o : 0.8:l .O
Pigment Volume Concentration (PVC): 18.9
T o t a l Nonvolatiles, % by weight: 53.1
Organic i n E f f l u e n t , % by volume: 10.5
Resin:Melami ne: 89: 11
pH Value: 9
Suggestion LP-3793

Pigment G r i nd:
D i spersant (1 )
Soya L e c i t h i n (2)
Ethylene Glycol
Water
Defoamer (3)
Calcium Carbonate (4)
Titanium D i o x i d e (5)
Let Down:
Dispersant ( 1 )
Defoamer (3)
Melamine ( 6 )
B u t y l C e l l o s o l v e Solvent
Thickener (7)
Blue T i n t Paste ( 8 )
S u o ~ lie r s :
Pounds
3.3
3.1
4.7
74.3
0.7
263.0
25.6
630.2
3 . 1
4 . 9
1.6
5.6
14.4
6.3
2.6
Gallons
0.33
0.33
0.50
8.93
0.09
11.69
0.73
72.86
0.31
0.53
0.20
0.56
1.92
0.73
0.29
Wei qht%
0.32
0.30
0.45
7.12
0.07
25.21
2.46
60.38
0.30
0.47
0.15
0.54
1.38
0.60
0.25
Dispersant - Strodex PK-90 (Dexter Chemical) o r e q u i v a l e n t
Dispersant - Ross and Rowe 551 (Ross and Rowe Chemicals)
o r e q u i v a l e n t .
Defoamer - Foamaster VF (Diamond Shamrock) o r e q u i v a l e n t .
Calcium Carbonate - Atomite (Thompson, Weinman) o r equiv-
a l e n t .
Titanium Dioxide - Ti-Pure R-900 (duPont) o r e q u i v a l e n t .
Me1ami ne - Cyme1 350 (American Cyanamid) o r e q u i v a l e n t .
Thickener - Acrysol G-110, 22% (Rohm and Haas) o r equiv-
a1e n t .
Aqueous Dispersion - Thalo Blue (Tenneco) o r e q u i v a l e n t .
Procedure:
order l i s t e d . Mix a t low speed f o r one minute. Slowly add p i g -
ments and s t i r u n t i l uniform. Grind a t h i g h speed u n t i l d e s i r e d
g r i n d f ineness has been accompl ished.
For t h e letdown, pre-blend Ucar V e h i c l e 441, Strodex PK-90,
soya l e c i t h i n , and defoamer. With slow a g i t a t i o n , add t o t h e
pigment g r i n d . S t i r a t low speed f o r 5 t o 10 minutes. Pre-blend
B u t y l C e l l o s o l v e Solvent and melamine and add t o l e t down. S t i r
f o r f i v e minutes. Add b l u e t i n t paste and t h i c k e n e r and s t i r
f o r 5 t o 10 minutes. If done s l o w l y and c a r e f u l l l y , l e t down
Charge t h e f i r s t f i v e components t o a Cowles mixer tank i n t h e
components may be added s e q u e n t i a l l y .
Coating P r o p e r t i e s :
N o n v o l a t i l e s , %: 54 t o 55
pH: 8 . 0
Pigment/Binder R a t i o : 1 . O
V i s c o s i t y a t 25C ( B r o o k f i e l d LVT, 60 r p m ) , cP: 200
SOURCE: Ucar Emulsion Systems: Ucar V e h i c l e 441: Formu
Suggestion LP-3024
o 300
a t i on

A c r y l ic Emu1s i o n Enamel -B&C
K-F1 ex UD-320W M o d i f i e d
K-F1 ex UD-320W modi f i c a t 1on o f t h i s w h i t e a c r y l ic/melami ne
emulsion f o r g e n e r a l i n d u s t r i a l a p p l i c a t i o n s demonstrated s e v e r a l
advantages in c l u d i ng: improved f l o w / l e v e l ing, h i g h e r g l o s s ,
improved g l o s s r e t e n t i o n on QUV exposure-higher s o l i d s ( l o w e r
VOC) and lower c o s t p e r pound on a s o l i d s b a s i s .
G r i n d Composition:
J o n c r y l 540
S u r f y n o l 104
T i - P u r e R-960
Water
( G r i n d t o 6+ Hegman on t h e B a l l M i l l )
Letdown Composition:
G r ind
J o n c r y l 540
HMMM
K-Flex UD-320W
Nacorr 1552
Water
Enamel C h a r a c t e r i s t i c s :
AMP-95
V i s c o s i t y , cps (25C): 200-205
Pigment/Binder R a t i o : 0 . 7 6 : l . O
pH: 8.70-8.75
Q
41.8
1. o
1 .o
4 8 . 6
7 . 6
Wt%-B Wt04-&
100.0 100.0
50.9 39.1
1 9 . 9 2 9 . 1
3 . 6 7.2
1 . 3 1 . 3
23.0 25.0
A p p l i c a t i o n and Cure:
S u b s t r a t e : B o n d e r i t e 1000 ( i r o n phosphated CRS)
Cure Schedule: 15'/300F (150C)
DFT ( m i l s ) : 0.9+-0.01 ( 2 2 . 5 ~ )
A c r y l ic/K-Flex/HMMM:
Penci 1 Hardness
Knoop Hardness (259)
MEK R e s i s t a n c e (2X)
Crosshatch Adhesion
Impact R e s i s t a n c e :
D i r e c t ( i n l b s ) :
Reverse ( i n l b s ) :
C1eve1 and H u m i d i t y (55C)
0 C
65/5/30 57/16/33
4H-5H 4H-5H
17.0 1 8 . 4
100 100
100% 100%
100-110 100-110
20- 30 20 -30
9/M 9/MD
SOURCE: K i n g I n d u s t r i e s : F o r m u l a t i o n UDW-12 B & C

Enamels 31
S y n e r g i s t i c E f f e c t s o f Combinina Nacorr w i t h
A n t i - C o r r o s i v e Pinment i n an A i r Dry Water R e d u c i b l e
A1kyd M o d i f i e d A c r y l i c Enamel
Improvements i n t h e c o r r o s i o n r e s i s t a n c e o f a w a t e r r e d u c i b l e
a i r d r y a c r y l i c enamel a r e p o s s i b l e u s i n g Nacorr r u s t and c o r r -
o s i o n i n h i b i t o r s , When used i n c o m b i n a t i o n w i t h a c a l c i u m s t r o n t -
ium p h o s p h o s i l i c a t e c o r r o s i o n i n h i b i t i n g pigment (Halox SW-1111,
a d e f in i t e improvement in c o r r o s i o n r e s i s t a n c e was o b t a i ned.
S a l t spray t e s t i n g was c a r r i e d o u t o v e r i r o n phosphated p a n e l s
( B o n d e r i t e 1000).
G r i n d :
Aquamac 1090
Nacorr
2-Butoxyethanol
N y t a l 400
Halox SW-111
Raven B l a c k 16
Hal ox
C o n t r o l SW-111
3 . 7 9 3.79
2.79 2.79
11.61 9 . 2 9
2.38
0.71 0.71
____ ----
____
Letdown: (Add g r a d u a l l y w h i l e on m i l l a t low rpm):
C o b a l t Hydrocure 0.06 0.06
Manganese Hydrocure 0.08 0.08
Water 15.85 15.85
Ammonium Hydroxide, 30% 0.28 0.27
Aquamac 640 (post-add 8 shake) 64.83 64.80
Hal ox
C h a r a c t e r i s t i c s : C o n t r o l SW-111
P i gment/Bi nder R a t i o 0.4 0.4
T o t a l Resin S o l i d s , % by w e i g h t 32.0 32.0
Halox, % based on t o t a l p a i n t w e i g h t -- 2 . 4
N o n - V o l a t i l e , % by w e i g h t 44.3 4 4 . 4
Nacorr, % based on t o t a l p a i n t w e i g h t -- __
S u b s t r a t e : B o n d e r i t e 1000 I r o n Phosphated CRS
Cure: 7 days a t room temperature (22-23C)
A p p l i c a t i o n : Spray
F i l m Thickness: 20-25 m i c r o n s
Hal ox
F o r m u l a t i o n T e s t Procedure: C o n t r o l SW-111
Penci 1 Hardness
Tukon Hardness, KHN25
2B-B 28-8
1.2 2 . 2
H a l o x t
Nacorr
3 . 7 6
0.78
2.77
9 . 2 1
2.36
0 . 7 0
0 . 0 6
0 . 0 8
15.72
0.27
64.29
H a l o x t
Nacorr
0.4
44.0
31.8
0 . 8
2 . 4
Halox+
Nacorr 1151
28-8
2 . 2
Crosshatch Adhesion, % removed 0 0 0
S a l t Spray, 100 h o u r s Light-med Very l i g h t No r u s t
S a l t Spray, 310 h o u r s Very Very Medi u m
r u s t r u s t
dense r u s t dense r u s t r u s t
The use o f N a c o r r s w i t h t h e a n t i - c o r r o s i v e pigment o f f e r e d t h e
b e s t c o r r o s i o n r e s u l t s i n t h i s s t u d y . They had l i t t l e o r no
d e l e t e r i o u s e f f e c t on o t h e r p a i n t p r o p e r t i e s .
SOURCE: K i n g I n d u s t r i e s : Nacorr WR-14

Ancamide 2353 Fast Drvina White Gloss Enamel
Part A:
Grind Base:
DER 660x80 (Dow)
Nuosperse 657 ( H u l s America)
Beetle 216-8 (American Cyanamid)
Dowanol PM (Dow)
TiPure R-960 (DuPont)
Let Down:
High Flash Naphtha (Ashland)
Methyl Propyl Ketone (Eastman)
Part 8:
Ancamide 2353 ( A i r Products)
n-Butanol (Ashland)
Properties :
Part A V i s c o s i t y : 86KU
Part B V i s c o s i t y : 64KU
M i xed V i s c o s i t y : 80KU
PVC: 15.2%
Vo 1ume
SOURCE
S o l i d s : 62.2%
-Lb
472.55
3.54
2.84
47.26
307.16
73.72
14.18
131.44
34.78
VOC, @ 80KU: 2.8 l b / g a l
Mix Ratio: 4:l by Volume
I n d u c t i o n Time: 0
Pot L i f e , h r : 3
Dry Times:
Set t o Touch, min: 50
Dust Free, min: 75
Hard Dry: Overnight
60 Gloss: 104
Gal
51.47
0.42
0.34
6.20
9.44
10.03
2.10
14.86
5.14
A i r Products and Chemicals, I n c . : Ancamide 2353 Curing
Agent: Table 12 Formulation

Enamels 33
Ancamide 2353 Low VOC White Gloss Enamel
P a r t A:
Grind Base:
L i q u i d DGEBA Epoxy
Nuosperse 657 (Huls America)
Surfynol 740 ( A i r Products)
Dowanol PM (Dow)
TiPure R-960 (DuPont)
Let Down:
High Flash Naphtha (Ashland)
Methyl Propyl Ketone (Eastman)
Part 8 :
Ancamide 2353 ( A i r Products)
n-Butanol (Ashland)
Propert ies :
Part A V i s c o s i t y : 73 KU
Part B V i s c o s i t y : 64 KU
Mixed V i s c o s i t y : 70 KU
PVC: 17%
Volume S o l i d s : 70%
352.76 36.43
3.88 0.46
1.76 0.25
48.68 6.32
388.04 11.92
67.73 9.22
14.11 2.09
212.03 23.46
63.14 9.34
VOC, @ 70 KU: 2.2 l b / g a l
Mix Ratio: 2:l by Volume
I n d u c t i o n Time: 0
Pot L i f e , h r : 2
Dry Times:
Set t o Touch, h r : 5
Dust Free, h r : 7
Hard Dry: Overnight
60 Gloss: 102
SOURCE: A i r Products and Chemicals, I n c . : Ancamide 2353 Curing
Agent: Tab1e 11 Formulation

Carv Gloss White Enamel
I n a r e d i e n t s :
Pigment Grind:
Water
Tamol 731
Byk 023
T i -Pure R-900
Natrosol Plus 330
Water
Nuosept 145
Letdown :
Ucar Latex 481
Water
B u t y l Carbi t o 1 Sol vent
Solvent 142HT
LE-410 Emulsion
Surfynol 104E
Volume S o l i d s , %: 40.6
Weight S o l i d s , %: 51.9
Stormer, KU: 85
I C I , Poise: 2.0
pH Value: 9-9.6
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 0.1
Heat-Age S t a b i l i t y , 120F, weeks passed: 4
VOC, grams per l i t e r : 196
Pounds
39.0
20.0
9 . 6
2.4
2.5
240.0
1.1
5.0
1 . 4
620.0
19.6
12.8
32.8
15.0
2.0
Gal 1ons
5.20
2.40
1.05
0.27
0.35
7.02
0.10
0.60
0.16
71.84
2.35
1.60
5.00
1.82
0.24
T y p i c a l T i t a n i u m Dioxide Pigment Performance
T i t a n i u m D i o i x d e Stormer I C 1 Gloss Values
KU Poise 60 20
T i -Pure R-900 85 2.0 85 52
T i -Pure R-902 83 2.1 79 41
T i -Pure R-960 86 2.0 79 41
T i -Pure R-706 82 1.7 90 60
Tronox CR-828
Tiona RCL-535
Kronos 2310
T i o x i d e TR 90
T i o x i d e TR 93
T i o x i d e TR 80
86 2.0 87 59
83 1.7 87 59
84 1.8 84 53
83
86
85
1.7 88 54
1 . 8 86 57
2.0 90 68
SOURCE: Ucar Emulsion Systems: Ultra-Gloss Latexes: Formulation
Suggestion E-2218C

Enamek 35
C a w Gloss White Enamel
Pigment Grind:
B u t y l C e l l os01ve Solvent
Water
Tamol 731
T r i t o n Nonionic Surfactant CF-10
Byk 023
T i -Pure R-900
Water
Nuosept 145
Letdown :
Ucar Latex 481
B u t y l C a r b i t o l Solvent
Sol vent 142HT
LE-410 Emulsion
Ucar Polyphobe 102 Rheo. Mod.
Ucar Polyphobe 106HE Rheo. Mod.
Water
Surfynol 104E
P a i n t Properties:
Volume Solids, %: 40.7
Weight Solids, %: 52.1
Stormer, KU: 86
ICI, Poise: 2.5
pH Value: 9-9.6
Freeze-Thaw S t a b i l i t y , cycles passed: 0-1
F i 1m Properties :
Gloss, 60: 88
Gloss, 20: 47
Flow and Leveling: Excellent
Dry-to-Touch, hour: 1
Recoat, hours: 2-4
Water/Bl is t e r Resistance: Excel l e n t
Pounds
39.0
20.0
9.6
2.4
2 . 5
240.0
5.8
1.4
2.0
620.0
12.8
32.8
15.0
5.0
2.7
10.0
2.0
Gal 1ons
5.20
2.40
1.05
0.27
0.35
7.02
0.70
0.16
0.27
71.84
1.60
5.00
1.82
0.57
0.31
1.20
0.24
Suggestion E-221 6G

C l e a r Enamel (For Maximum S o l v e n t and A b r a s i o n Resistance)
_ _ _ _ _ _Pounds Gal l o n sM a t e r i a1.L
P a r t A:
Epi-Rez 5522-WY-55 Resin 490.6 54.82
Michem Lube 743 Mar and S l i p Agent 41 . O 5.00
C y c l o Sol 63 32.3 4.37
E k t a s o l v e EP, 2-Propoxyethanol 33.2 4.37
Water 53.6 6.44
P a r t 0 :
Epi-Cure 8290-Y-60 C u r i n g Agent
DeeFo P I - 4 Concentrate Defoamer
Water
Composite Blend: V i s c o s i t y
P a r t A 58 K.U.
P a r t B 68 K.U.
P a r t s A and 0 85 K.U.
145.8 16.51
4.0 0.49
66.6 8.00
650.7 75.00
216.4 25.00
T y p i c a l C o a t i n g P r o p e r t i e s :
T o t a l Weight S o l i d s , %: 41.8
T o t a l Volume S o l i d s , %: 37.6
Pounds/Gallon: 2.74
G r a m s / L i t e r : 329
I n d u c t i o n Time, minutes: 30
Resi n Composi ti on :
Epoxy Resin, %: 75.0
C u r i n g Agent, %: 25.0
T o t a l , %: 100.0
SOURCE: S h e l l Chemical Co.: S t a r t i n g F o r m u l a t i o n No. 1802:
€pi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 C u r i n g Agent

Enamels 37
Gloss Safety Red Enamel
P i gment G r i nd :
Ucar Latex 481
T o l u i d i n e Red 10-6C-41-L100
Aquatrend I 1 Red I r o n Oxide Disp. 878-1046
Colanyl Carmine Disp. 13-3148 (Azo Red)
Foamaster 333
Natrosol Plus 330
Water
Nuosept 145
Letdown :
Ucar Latex 481
Solvent 140
LE-410 Emulsion
Aquatrend I 1 Red I r o n Oxide Disp. 878-1046
Colanyl Carmine Disp. 13-3148 (Azo Red)
Surfynol 104E
Pigment Volume Concentration, %: 11 .O
Stormer, KU: 88
ICI, Poise: 1.5
pH Value: 8.5-9.5
Freeze-Thaw S t a b i l i t y , c y c l e s passed: 5
Heat-Age S t a b i l i t y , 12OF, weeks passed: 4
Gloss, 60: 81
Gloss, 20: 40
Flow and Leveling: E x c e l l e n t
Dry-to-Touch, hour: I
Recoat, hours: 2-4
Pounds
173.4
10.0
110.0
9.4
7.8
15.0
1 .o
8.3
1.2
416.9
38.3
12.4
32.8
15.0
5.0
3.0
2.0
Gal l o n s
20.09
1.14
11.58
0.59
0.76
2.00
0.09
1.oo
0.13
48.31
5.10
1.55
5.00
1.82
0.31
0.29
0.24
Suggestion E-2222C

Gloss Safety Yellow Enamel
I n p r e dient s :
Pi ament G r i nd:
Pounds
BuTyl Cellosolve Solvent
Water
Tamol 731
Foamaster 333
T i -Pure R-900
Natrosol Plus 330
Water
Nuosept 145
B u t y l Cellosolve Solvent
Letdown :
Ucar Latex 481
Water
Byk 026
Sol vent 142HT
LE-410 Emulsion
Aquis Dalamar Yellow Disp. YW-811D
Aquatrend I 1 Yellow I r o n Oxide Disp. 878-0012
Aquatrend I1 Lamp Black Disp. 878-9908
Surfynol 104E
Paint Properties:
Stormer, KU: 89
ICI, Poise: 1.7
pH Value: 8.5-9.5
F i 1m P r o p e r t i es :
Gloss, 60: 86
Gloss, 20: 46
F1ow and Level ing : Excel 1e n t
Recoat, hours: 2-4
Water/Blister Resistance: E x c e l l e n t
12.8
10.0
5 . 0
10.0
15.0
66.3
2.8
5.0
1.2
24.8
572.9
24.0
2.0
12.8
32.8
15.0
76.2
12.1
0.1
2.0
Gallons
1.70
1.20
0.54
1.14
2.00
1.94
0.25
0.60
0.13
3.30
66.39
2.88
0.25
1.60
5.00
1.82
8.28
0.73
0.01
0.24
Suggestion E-2225C

Enameh 39
Gloss White Enamel
M a t e r ia1 :
P a r t A:
Epi -rez 3520-WY-55 Resin
Michemlube 182 Mar and S l i p Agent
Water
P a r t 0:
Epi-Cure 8537-WY-60 Curing Agent
Ektasolve DB Acetate
T r i e t h y l a m i n e
Patcote 519 Defoamer
Kronos 2020 o r Tronox CR-800
Pounds
411.6
27.8
13.7
160.0
8.2
3 . 7
4.0
250.0
Gal 1ons
45.03
3.33
1.64
17.70
1.oo
0.61
0.57
7.33
High Speed d i s p e r s e t o a t e x t u r e o f 10 P.C.S., then add:
Epi-Cure 8537-WY-60 Curing Agent
Water
42.4 4.69
150.0 18.10
Composi t e 81end :
P a r t A
P a r t B
P a r t s A and B
V i scosi t y
85 KU 453.1 50.00
110 KU 619.1 50.00
99 KU
T y p i c a l Coating P r o p e r t i e s :
T o t a l Weight S o l i d s , %: 55.8
PVC, %: 17.3
Pounds/Gal 1on : 1.61
Resin Composition (based on s o l i d s ) :
Curing Agent, %: 35.0
T o t a l , %: 100.0
Reduction f o r Conventional Spray (by volume):
P a r t s A and B: 17 P a r t s
Water: 1 Part
SOURCE: S h e l l Chemical Co.: S t a r t i n g Formulation No. 1606:
Epi-Rez 3520-WY-55 Resin/Epi-Cure 8537-WY-60 Curing
Agent

Gloss W h i t e~ . . ~Enamel
M a tcr i_a 1-1
P a r t A :
Michemlube 182 Mar and S l i p Agent
Water
P a r t B :
Epi-Cure 8536-MY-60 C u r i n g Agent
Deefo P I - 4 Concentrate Defoamer
R u t i l e T i t a n i u m D i o x i d e , Kronos 2020 o r
Tronox CR-800
High speed d i s p e r s e t o a t e x t u r e o f 10 P . C . S
Epi-Cure 8536-MY-60 C u r i n g Agent
Water
T o t a l Weight S o l i d s , %: 5 1 . 5
T o t a l Volume S o l i d s , %: 3 7 . 6
PVC, % : 19.5
Pounds/Gal l o n s : 1 .89
C u r i n g Agent, %: 37.8
~~Pounds
329.4
8 8 . 6
27.8
160.0
4 . 0
250.0
G a l l o n s
36.04
3 . 3 3
10.63
19.28
0 . 4 9
7.33
t h e n add:
2 2 . 5 2.71
168.2 20.19
None r e q u i r e d
Epi-Rez 3520-WY-55 Resin/Epi-Cure 8536-MY-60 C u r i n g
Agent

Enamels 41
G l o s s W h i t e Enamel (Maximum S o l v e n t and A b r a s i o n Resistance)
M a t e r i a1 :
P a r t A:
€pi-Rez 5522-WY-55 Resin
C y c l o Sol 63
E k t a s o l v e EP, 2-Propoxyethanol
Water
P a r t 8:
Epi -Cure 8290-Y-60 C u r i n g Agent
Deefo P I - 4 C o n c e n t r a t e Defoamer
T i - P u r e R-960 o r Kronos 2160
Water
H i g h speed d i s p e r s e t o a t e x t u r e o f 10 P . S . C
Water
G l a c i a l A c e t i c A c i d
Composite Blend: V i s c o s i t y
P a r t A 61 K . U .
P a r t B 103 K . U .
P a r t s A and B 83 K . U .
T o t a l Weight S o l i d s , Oh: 54.0
PVC, %: 1 9 . 2
Pounds/Gallon: 2 . 3 4
G r a m s / L i t e r : 280
I n d u c t i o n Time, m i n u t e s : 30
C u r i n g Agent, %: 2 5 . 5
~ _ _ _Pounds Gal 1ons
442.2 49.41
2 2 . 2 3 . 0 0
22.7 3.00
9 3 . 8 11 .26
135.1 15.30
4.0 0.49
250.0 7 . 7 4
1 2 . 5 1 .so
6 6 . 1 7.93
3 . 2 0.37
580.9 66.67
470.9 33.33
P a r t s A and B: 25 p a r t s
Water: 1 p a r t
Epi-Rez 5522-WY-55 Resin/Epi-Cure 8290-Y-60 C u r i n g Agent

Green A i r Dry Enamel f o r Flexible Substrates
Materi a1 :
Spensol L53
Amrnoni um Hydroxi de
D i sperse-Ayd W28
C o l l o i d 679
Ucar SCT 100
Sunbrite Yellow 272-0558
Sunbri t e Green 264-8142
Titanox 2101
Mapico 1075
Lbs.
261.6
1.9
4.4
1.9
2.3
50.0
25.0
25.0
50.0
Gals.
30.00
0.25
0.50
0.25
0.25
4.69
1.43
0.75
1.48
Add the above i n order under good a g i t a t i o n , then pebble o r
sandmill g r i n d t o 7 Hegman.
Letdown:
Spensol L53 526.7 60.40
Analysis:
Pigment Volume Concentration, Percent: 24.7
Pigrnent/Binder Ratio: 0.6/l.O
Percent Solids, Weight: 41.2
Percent Sol ids, Vol ume: 33.8
V i s c o s i t y @ 25C, #2 Zahn, Secs.: 50-60
Pounds/Gallon: 9.5
Grams/Liter: 289
Pounds/Gallon: 2.4
pH: 8.5+-0.3
SOURCE: Reichhold Chemicals, I n c . : Spensol L: Formula 2316-62A

Enamels 43
H iqh-Hidinq Esashe11 Enamel
PoundsI n s r e d ie n t s :
Pigment Grind:
Water 226.7
Cel l o s i ze Hydroxyethyl C e l l u l ose ER-4400 2.0
Nuosept 145 2 . 3
Tamol 731 9.2
T r i t o n Nonionic S u r f a c t a n t N-57 2.3
AMP-95 1.o
Propylene Glycol 51.8
Col l o i d 643 1.9
Tronox CR-800 225.0
Optiwhi t e 100.0
Burgess No. 98 25.0
Letdown :
Ucar F i l m e r I B T
B u t y l Carbi t o 1 Solvent
Acrysol SCT-275
Ucar Latex 379G
Col l o i d 643
Pai n t P r o p e r t i e s
PVC, %: 35.6
Volume Sol ids
Weight Sol i d s
Weight per Ga
Stormer. KU:
I C I . n o i s e : 1
%: 37.6
%: 53.4
l o n , l b :
04
. 4
11.9
11.9
17.2
418.2
2 . 8
1 . 0 9
G a l 1ons
27.21
0.18
0.25
1.oo
0.25
0.13
6.00
0.25
6.54
5.46
1.15
1.50
1.50
2.00
46.21
0.37
I .
pH, i n i t i a l : 8.2
Freeze-thaw S t a b i l i t y , 3 c y c l e s : Pass
Heat-Aged S t a b i l i t y , 2 weeks a t 120F: Pass
F i 1m P r o p e r t i e s :
Ref 1ectance, %: 91.9
Gloss, 60: 8
Sheen, 85: 22
Contrast R a t i o , 3-mil f i l m * : 0.968
Flow and l e v e l i n g , brushed: Good
*Opacity increased w i t h t o n i n g .
SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-1998A

MacGregor Gloss B1ack Enamel
Pigment Grind:
Ucar Latex 481
Byk 023
Aurasperse Carbon B1ack W-7012
Water
Nuosept 145
Ammoni urn Hydroxide, 28% Aqueous Sol u t i on
Letdown :
Ucar Latex 481
Dee Fo 102OF
Butyl C e l l osolve Sol vent
Sol vent 142HT
LE-410 Emu1s i on
Water
Ucar Polyphobe 106HE Rheo. Mod.
Surfynol 104E
Pounds
88.0
2.5
10.0
45.0
8.3
1 . 2
2 . 4
556.0
5.0
39.0
12.4
32.8
15.0
15.0
8.3
4.5
2 . 0
Gallons
10.20
0.35
1.14
4.69
1.oo
0.13
0.29
64.43
0.68
5.21
1.57
5.00
1.80
1.80
0.95
0.52
0.24
Paint Properties:
Stormer, KU: 90
I C I , Poise: 2.6
pH Value: 8.5-9
Freeze-Thaw S t a b i l i t y , cycles passed: 5
F i l m Properties:
Gloss, 60: 91
Gloss, 20: 65
Flow and Leveling: Excel l e n t
Recoat, hours: 2
Suggest ion E-2221 E

Enamels 45
Pinehurst Gloss Green Enamel
Pigment Grind:
Water
Tamol 731
Byk 023
Chromium Oxide Green W-6017
Aurasperse Carbon Black W-7012
Aurasperse Phthalo Green W-6013
Yellow I r o n Oxide 878-1812
Natrosol Plus 330
Water
Nuosept 145
Letdown :
Ucar Latex 481
Water
Solvent 142HT
Water
LE-410 Emulsion
Surfynol 104E
Pounds
7.5
5.8
5.0
10.0
2.5
53.3
3.2
25.4
7.0
2.0
4.2
1.2
640.0
8.3
12.4
32.8
31 . 5
8 . 8
15.0
2.0
Gal 1ons
1.oo
0.70
0.54
1.14
0.31
3.08
0.34
2.54
0.42
0.18
0.59
0.13
74.16
1 .oo
1.55
5.00
4.20
1.06
1.82
0.24
Stormer, KU: 88
I C I , Poise: 2.3
pH Value: 8.5-9.5
F i l m Properties:
Gloss, 60: 88
Gloss, 20: 64
Flow and Level ing: Excel 1ent
Recoat. hours: 2-4
Water/Blister Resistance: E x c e l l e n t
Suggestion E-22429

S e l f - P r i m i n a I n t e r i o r Semi-Gloss Enamel
Pigment G r i n d :
Water
Busperse 203
I g e p a l CTA-639
Bubreak 448
Water*
C e l l o s i z e QP 15,000*
Atomi t e
T i - P u r e R-900
Disperse 10-15 minutes on a high-speed m i l l
Add t h e f o l l o w i n g w i t h slow a g i t a t i o n .
L e t Down:
Rhopl ex R-AC-507
E t h y l e n e g l y c o l
Texanol
Water
*These i n g r e d i e n t s a r e premixed.
Lbs.
100.0
14.0
3 . 0
3.0
25.0
2.0
73.0
200.0
550.0
40.0
25.0
32.0
E x t e r i o r Maintenance-Type C o a t i n g
Pigment G r i n d :
Water
Tam01 -681
8ubreak 448
I g e p a l CTA-639
E-845
Ti-Pure R-900
Atomi t e
Mica
Kadox 911
Disperse 10-15 minutes on a high-speed m i 11.
Add t h e f o l l o w i n g w i t h slow a g i t a t i o n .
L e t Down:
Rhopl ex MV-23
Texanol
E t h y l e n e g l y c o l
Water
Lbs.
100.0
14.0
3.0
3.0
40.0
150.0
191.o
25.0
12.0
527.0
5.0
30.0
30.0
&&
9 . 3 7
1 .31
0.28
0.28
2 . 3 4
0.19
6.84
18.74
51.55
3.75
2.34
3.01
Wt%
8.85
1.24
0.27
0.27
3.54
13.27
16.90
2.21
1.06
46.64
0.44
2.65
2.66
SOURCE: Buckman L a b o r a t o r i e s : B u t r o l 35: F o r m u l a t i o n Suggestions

Enamels 47
Semigloss Enamel
Inqredients:
Piament Grind:
WaIer
C e l l o s i z e Hydroxyethyl Cellulose ER-15,000
Nuosept 145
Tamol 731
T r i t o n Nonionic Surfactant N-57
Propylene G1ycol
Byk 035
Tronox CR-800
Letdown :
Thickener; premix*
Ucar Latex 3796
Ucar Filmer IBT
Byk 035
T r i t o n Anionic Surfactant GR-7M
AMP-95
Pounds
268.2
2.0
2.4
9.2
2.1
1 .o
43.2
1.o
250.0
29.9
428.4
20.0
1.9
0.5
Gal 1ons
32.20
0.18
0.25
1 .oo
0.25
0.13
5.00
0.13
7.27
3.48
2.52
0.25
0.06
47.28
Pa
*Premix consists o f 1 : l : l blend o f Propylene Glycol; Rohm
and Haas' Acrysol SCT-275 thickener:water, respectively.
n t Properties:
PVC, %: 23.0
Stormer, KU: 82
I C I , poise: 0 . 4
pH, i n i t i a l : 8.5
Freeze-thaw S t a b i l i t y , 3 cycles: Pass
F i 1m Properti es :
Reflectance, %: 89.5
Gloss, 60: 59
Contrast Ratio, 3-mil f i l m : 0.967
Flow and Leveling:
brushed: Very Good
drawdown, NYPC Blade: 8
SOURCE: Ucar Emulsion Systems: Formulation Suggestion I-1989A

48 Water-Eased Paint Formulations
Semiq loss Enamel
Ingredient s :
Pigment Grind:
Water
Propylene Glycol
Tamol 1124
Proxel GXL
Col 1o i d 640
T i -Pure R-900
T r i t o n Nonionic Surfactant N-101
ASP-1 70
Water
Letdown :
Water
C o l l o i d 640
NeoCar Latex 6040
Water
Ucar Filmer IBT
Ucar Polyphobe 102 Rheology M o d i f i e r
Water
Paint Properties:
PVC, %: 24.9
Stormer, KU: 88-93
I C I , poise: 1.1
pH Value: 8.75-9.25
F i l m Properties:
Gloss, 20: 20
Gloss, 60: 65
Contrast Ratio, 3-mil f i l m : 0.980
ASTM Scrub Cycles, w i t h shim: 1600
Block Resistance, 1 day: Exc
Wet Adhesion, 4 hours: Exc
Flow and Leveling: Exc
S t a i n Removal : Exc
Pounds
15.0
55.0
5.0
1. o
2.0
230.0
4.0
15.0
50.0
39.9
1 .o
425.0
100.0
30.0
4.0
20.0
50.0
Gal 1ons
1.80
6.35
0.51
0.11
0.26
6.90
0.46
0.70
6.00
4.79
0.13
47.39
12.00
3.79
0.52
2.30
6.00
Source: Ucar Emulsion Systems: NeoCar Polymers: Formulation
Suggestion E-2481

Enamels 49
Southern P i n e s Gloss W h i t e Enamel
Pigment G r i n d :
Propylene G l y c o l
Water
Tamol 731
T r i t o n N o n i o n i c S u r f a c t a n t CF-10
Byk 023
T i -Pure R-900
Nuosept 145
Water
Ammoni um Hydroxi de, 28% Aqueous Sol u t i on
Letdown :
Ucar L a t e x 481
B u t y l C a r b i t o l S o l v e n t
Sol v e n t 142HT
T r i t o n A n i o n i c S u r f a c t a n t GR-5M
Byk 026
LE-410 Emu1s i on
Water
S u r f y n o l 104E
Pai n t P r o p e r t i e s :
Pigment Volume C o n c e n t r a t i o n , %: 1 7 . 6
Weight S o l i d s , %: 53.1
Stormer, KU: 90
I C I , P o i s e : 1 . 9
pH Value: 8 . 5 - 9 . 5
Heat-Age S t a b i l i t y , 12OF, weeks passed: 4
VOC, grams p e r l i t e r : 174
Gloss, 60: 88
Gloss, 20: 52
F1ow and Level ing : Excel 1e n t
Dry-to-Touch, h o u r : 2
Recoat, h o u r s : 4
Water/Bl is t e r Resistance: Excel 1e n t
___Pounds
40.0
2 0 . 0
9 . 6
2 . 4
2.5
240.0
1 . 4
1 1 . 1
2 . 0
620.0
1 2 . 8
2 0 . 0
1 . o
1 . o
1 5 . 0
20.0
1 1 . 9
2 . 0
G a l l o n s
4.62
2.40
1 . 0 5
0 . 2 7
0 . 3 5
7 . 0 2
0 . 1 6
1 . 3 3
0 . 2 4
71.84
1 . 6 2
3 . 0 5
0 . 1 2
0.14
1 . 8 2
2 . 3 0
1.43
0 . 2 4
SOURCE: Ucar Emulsion Systems: U l t r a - G l o s s Latexes: F o r m u l a t i o n
Suggestion E-2251 C

Spensol L54 Oranqe Enamel
Materi a1 :
Water
Ammoni um Hydroxi de
Bentone EW
Lbs. Gals.
30.0 3.60
1.1 0.15
3.0 0.14
Premix the above three materials and Cowles grind 15-20 minutes
to fully disperse Bentone EW. Then add the following materials
under good agitation:
Spensol L54
Surfynol GA
Aerosol OT-75
Nalco 2300
Molybdate Orange
Water
Pebble or sand mill grind to 7 N . S .
Letdown :
_____Materi a1 :
Spensol L54
Surfynol 104H
15% Solution FC430 in Water
Ucar SCT-100
Analysis:
Pigment Volume Concentration,
Pigment/Binder Ratio: 0.5/1 .O
Percent Solids, Weight: 39.1
Viscosity, #4 Ford, Secs.: 80-
Pounds/Gallon: 9.7
Grams/Li ter : 303
Pounds/Gallon: 2.5
Gloss (60): 50-60
pH: 8.5+-0.3
Percent: 9.0
.90
87.3 10.00
4.4 0.50
2.3 0.25
0.5 0.06
125.0 2.70
41.7 5.00
Lbs.
670.9
2.0
2.1
2.3
Gals.
76.85
0.25
0.25
0.25
SOURCE: Reichhold Chemicals, Inc.: Spensol L: Formula 2154-59A

Enamels 51
Waterborne Black Enamel
Based on Eootuf 37-143/37-680
XForrula No. 3019-28A1
Component A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Add f o l l o w i n g i n order under a g i t a t i o n :
Wollastokup 10 ES
Raven 410
High speed disperse t o 5 N.S.
Add f o l l o w i n g under a g i t a t i o n :
Epotuf 37-680
& Gals
78.91 8.91
24.41 3.34
3.68 0.49
7.37 0.04
48.40
20.02
2.00
1.38
Epotuf 37-680
2-Butoxy Ethanol
432.06 48.77
9.54 1.27
Component 0:
Mix f o l l o w i n g under high-speed a g i t a t i o n u n t i l uniform:
Epotuf 37-1 43 91.85 10.32
Epotuf 37-058 7.95 1.07
2-Butoxy Ethanol 73.09 9.84
Tap Water 98.04 11.77
Wei ght/Gal l o n (Lbs. ) : 8.96
Percent S o l i d s (Wt.): 57.50
Percent S o l i d s ( V o l . ) : 37.30
PVC (%): 46.30
VOC ( Lbs. /Gal 1on) : 2.80
SOURCE: Reichhold Chemicals, I n c . : Formula 3019-28A

Waterborne Blue Enamel
Based On Epotuf 37-143/37-600
LFormula No. 3019-31Gl
Component A :
Epotuf 37-680
Arcosolv PTB
2-8utoxy Ethanol
Oowanol PPH
Add following in order under agitation:
Wollastokup 10 ES
Sunfast 81ue 248-3750
Tioxide TR92
High speed disperse to 5 N . S .
Add following under agitation:
j&S Gals
133.28 15.04
24.31 3.33
3.63 0.48
7.38 0 .84
64.54
34.37
22.02
Epotuf 37-600 368. 1
2.67
2.29
0.66
1.58
Component B:
Mix following under high-speed agitation until uniform:
EDotUf 37-143 88.91
Epotuf 37-058
2-Butoxy Ethanol
Tap Water
Weight/Gallon (Lbs.): 9.29
Percent Solids (Wt.) : 57.50
Percent Solids (Vol.): 37.30
PVC (%): 46.30
VOC (Lbs./Gallon): 2.83
9.99
7.62 1.03
91 .15 12.14
82.89 9.95
SOURCE: Reichhold Chemicals, Inc.: Formula No. 3019-31G

Enamels 53
Waterborne Dark Blue Enamel
Based on Epotuf 37-143/37-600
(Formula No. 3019-31Dl
Component A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Wollastokup 10 ES
Sunfast Blue 248-3750
Epotuf 37-680
!& Gals
134.16 15.14
24.47 3.35
3.65 0.49
7.43 0.84
64.97
34.60
Epotuf 37-680 370.85
Component 0 :
Epotuf 37-1 43
Epotuf 37-050
2-Butoxy Ethanol
Tap Water
89.50
7.67
91.75
83.44
Weight/Gallon ( L b s . ) : 9.12
PVC (%): 46.30
VOC (Lbs/Gallon): 2.83
SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-31D
2.68
2.31
41 .86
10.06
1.04
12.22
10.02

Waterborne Green Enamel
XFormula No. 3019-31F)
Based on E D O t U f 37-143/37-680
Component A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Epotuf 37-680
Wollastokup 10 ES
S u n b r i t e Y e l l o w 75
Sunfast Blue 248-3750
T i o x i d e TR92
Epotuf 37-680
2-Butoxy Ethanol
~ Lbs
165.99
23.12
3.47
8.05
78.51
23.71
9.68
9.21
295.72
29.74
Component B:
Epotuf 37-058 6.97
Tap Water 123.78
Epotuf 37-143 82.10
2-Butoxy Ethanol 59.85
Wei ght/Gal 1on (Lbs .) : 9.20
Percent Sol i d s (Wt .) : 57.50
PVC (%): 46.30
SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-31F
18.73
3.17
0.46
0.91
3.24
2.22
0.65
0.28
33.38
3.96
9.22
0.94
7.97
14.86

Enamels 55
Waterborne Oranqe Enamel
Based on E p o t u f 37-143/37-600
(Formula 3019-3111
Component A:
A r c o s o l v PTB
2-Butoxy Ethanol
Dowanol PPH
Add f o l l o w i n g i n o r d e r under a g i t a t i o n :
Wollastokup 10 ES
Sunbri t e Ye1 low 74
Novoperm Red F3RK-70
High speed d i s p e r s e t o 5 N . S .
Epotuf 37-680
EpOtuf 37-680
2-Butoxy Ethanol
Lbs
179.20 20.23
22.73 3.11
3.41 0.45
8.36 0.95
78 * 45
26.52
8.20
282.39
30.04
Component B:
M i x f o l l o w i n g under high-speed a g i t a t i o n u n t i l u n i f o r m :
EpOtuf 37-143 82.02
Epotuf 37-058 7.80
Tap Water 122.11
Wei ght/Gal 1on ( Lbs . ) : 9 . 1 2
Percent S o l i d s ( W t . ) : 57.50
PVC (%): 46.30
VOC ( L b s . / G a l l o n ) : 2.80
SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-311
3.24
2.49
0 . 7 6
31.87
4 . 0 0
9 . 2 2
1.oo
8.07
14.66

Waterborne Red Enamel
Based on Epotuf 37-143/37-6%0
(Formula No. 3019-3181
Component A :
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Wollastokup 10 ES
High speed disperse t o 5 N . S .
2-Butoxy Ethanol
Tap Water
Epotuf 37-680
Epotuf 37-680
!&
97.48 11.oo
25.04 3.43
3.73 0.50
9.29 1 .06
60.09 2.48
20.69 1.92
377.11
18.73
12.91
Component 8 :
Epotuf 37-1 43 80.34
Epotuf 37-058 7.88
Tap Water 118.45
Wei ght/Gal 1on ( Lbs .) : 8.97
Percent Sol i d s (Wt .) : 57.50
PVC (%): 46.30
SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-318
42.56
2.49
1.55
9.03
1.06
14.22
8.69

Enamels 57
Waterborne Red Orange Enamel
Based on EDOtUf 37-143/37-600
I f o r m u l a No. 3019-31El
Component A:
Arcosolv PTB
2-Butoxy Ethanol
Dowanol PPH
Epotuf 37-680
Wol l a s t o k u p 10 ES
S u n b r i t e Yellow 74
T i o x i d e TR 92
High speed d i s p e r s e t o 5 N.S.
Epotuf 37-680
2-Butoxy Ethanol
Arcosolv PTB
Lbs Gals
157.10 17.73
23.40 3.21
3.49 0.46
8.57 0.97
73.31
19.47
8.20
7.56
307.00
25.51
5.40
Component 8:
Epotuf 37-143 84.28
Epotuf 37-058 7.36
Tap Water 124.03
Weight/Gallon ( L b s . ) : 9.12
PVC (%I: 46.30
VOC ( L b s . / G a l l o n ) : 2.80
SOURCE: Reichhold Chemicals, I n c . : Formula No. 3019-31E
3.03
1.83
0.76
0.23
34.65
3.40
0.75
9.47
1.00
7.63
14.89

Waterborne Y e l l o w EDOXY Enamel
Based on EDOtuf 37-143/37-680
(Formula No. 3019-31Cl
Component A:
Arcosolv PT8
2-Butoxy Ethanol
Dowanol PPH
Wollastokup 10 ES
S u n b r i t e Yellow 74
T i o x i d e TR-92
High speed d i s p e r s e t o 5 N.S.
Epotuf 37-680
Epotuf 37-680
2-8utoxy Ethanol
Lbs Gal
198.55 22.41
22.56 3.09
3.36 0.45
8.21 0.93
83.03
32.49
12.63
3.43
3.05
0.38
263.53 29.74
26.43 3.52
Component 8 :
Epotuf 37-143 80.25 9.02
Epotuf 37-058 6.91 0.93
2-Butoxy Ethanol 65.03 8.66
Tap Water 119.86 14.39
Wei g h t / G a l l on (Lbs. ) : 9.23
PVC (%): 46.30
SOURCE: Reichhold Chemicals, I n c . : Formula 3019-31C

EnameLF 59
Whisoering Pines Semigloss White Enamel
Inqredients:
Pigment Grind:
Propylene Glycol
Water
6yk 023
Tamol 731
T i -Pure R-902
Path 9
Nuosept 145
Water
Ammoni um Hydroxi de,
Pounds
30.0
53.3
2.5
10.0
230.0
40.0
1.5
16.7
28% Aqueous Sol u t i on 2.0
Letdown :
Ucar Latex 461
Ucar Filmer I6T
Sol vent 142HT
LE-410 Emulsion
Ucar Polyphobe 102 Rheo. Mod
Water
Surfynol 104E
556.0
12.4
31.5
15.0
16.9
19.7
2.0
Gal 1ons
3.47
6.40
0.35
1.09
6.92
1.98
0.17
2.00
0.94
64.66
1.57
4.80
1.BO
1.94
2.37
0.24
Stormer, KU: 93
I C I , Poise: 2.1
pH Value: 8.5-9.5
Heat-Age S t a b i l i t y , 120F. weeks passed: 4
F i l m Properties:
Gloss, 60: 54
Gloss, 20: 14
Flow and Leveling: Excellent
Recoat, hours: 4
Water/61 is t e r Resistance: Excel l e n t
Suggestion E-2245C

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