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MINERALS


   Chapter 2
MINERALS

Basic building block of rocks
Over 4,000 minerals identified
Mineral Definition (requirements):
1) Solid
2) Naturally Occurring
Mineral Definition

3) Inorganic – no biologic origin
4) Definite Chemical Composition
Ex: Halite = NaCl
     Quartz = SiO2
Definite Chemical Composition

Can vary within limits
 Ex: Olivine = (Mg,Fe)2SiO4
Mg and Fe can substitute for each
 other (Fig. 2.22)
Definite Chemical Composition

Ex: Diamond = C (Carbon)
    Graphite = C (Carbon)
Mineral Definition

5) Ordered Crystalline Structure
Ex: Halite (NaCl)
Ordered Crystalline Structure

Diamond = high pressure
- complex bonding of carbon
  atoms
Graphite = low pressure
  - carbon atoms bond in sheets
Mineral Definition

1) Solid
2) Naturally Occurring
3) Inorganic
4) Definite Chemical Composition
5) Ordered Crystalline Structure
Structure of Minerals

1) Atom – smallest building block of
   an element
Composed of atomic particles
    - protons (+)
   - neutrons
   - electrons (-)
Periodic Table of the Elements
(p. 38)
Atoms

Atomic Number = number of
  protons
- defines which element atom
  belongs to
Atomic Mass = sum of protons &
               neutrons
Balanced Atoms

Number of electrons = number of
  protons
Rule:
1st energy level = 2 electrons max
All other energy levels = 8
  electrons max
Atoms

Valence electrons = electrons in
 outermost orbital shell
Atoms bond b/c they want full
 outer shell of electrons
Types of Bonding

1) Ionic Bonding
Ion = atom with an electrical
   charge (+) or (-)
- caused by losing or gaining
   electrons
Ionic Bonding

Atoms bond b/c opposites attract
 (like magnets)
Ex: Halite (NaCl)
Types of Bonding

2) Covalent Bonding
- outer orbital shells overlap
- atoms share valence electrons
Ex: Oxygen gas (O2)
Atomic Bonding

3) Metallic bonding
- valence electrons move freely
  between ions
- accounts for high electrical
  conductivity
Structure of Minerals

2) Element – composed entirely of
 same kind of atoms
 - all atoms have same number of
  ___________
92 naturally occurring elements
Element

Some minerals are elements:
Ex: Native Copper
    Gold
    Sulfur
    Graphite
Structure of Minerals

3) Compound – combination of
  two or more elements
- characteristics are different than
  individual elements
     Ex: Halite NaCl
Compound

Most minerals are compounds:
   Quartz = SiO2
   Galena = PbS (lead sulfide)
   Hematite = Fe2O3 (iron oxide)
   Sphalerite = ZnS
Chemical Composition of Crust

98.3% of crust composed of 8
  elements (Figure 2.19)
Other 84 elements share 1.7% of
  remaining crust
- includes gold, zinc, lead, carbon,
  sulfur, silver, …
Mineral Groups

1) Silicate Group - 90% of all
   minerals
   Basic building block is the silica
   tetrahedron SiO44-
    (Si = silicon; Si+O = silica)
Silica tetrahedron (SiO44-)

Negative charge bonds with
 positive ions
Other six abundant elements of
 crust are positive ions (Ex: K)
Mineral Groups

2) Nonsilicate Group – scarce
  compared to silicates
Includes:
a) rock-forming minerals
 Ex: halite, gypsum, calcite
Nonsilicate Mineral Group

b) Native elements
    Ex: sulfur, copper, gold
c) Metal ores
  Ex: galena (PbS)
      magnetite (Fe3O4)
Nonsilicate Mineral Group

d) Industrial minerals
 Ex: fluorite, corundum
Silicate Mineral Structures

Silicate minerals have unique
  silica tetrahedra structures (Fig.
  2.21)
- each structure is related to its
  cleavage patterns (or fracture)
Silicate Mineral Structures
Bonds between silica tetrahedra
 are strong
Bonds between tetrahedra and
 positive ions are weak
Cleavage occurs between
 tetrahedra and positive ions
Types of Silicate Structures (Fig.
2.23)

Mineral             Structure
Olivine       Isolated framework
(Mg,Fe)2SiO4 No shared oxygens
Si:O = 1:4
No cleavage b/c (+) ions not in
 alignment
Types of Silicate Structures

Mineral          Structure
Augite          Single chain
(Mg,Fe)SiO3 One oxygen is
 Si:O = 1:3         shared
Types of Silicate Structures

 Mineral         Structure
Hornblende     Double Chain
              Two oxygens are
                    shared
Types of Silicate Structures

Mineral               Structure
Biotite &        Sheet silicates
Muscovite
(+) ions link sheets of tetrahedra
  together
Creates one plane of cleavage
Types of Silicate Structures

Mineral               Structure
Quartz             3-D framework
SiO2             structure
1:2
All oxygen atoms are shared (no
  cleavage)
“Silica rich” vs. “silica poor”

Based on Si:0 ratio
- as more oxygen atoms are
  shared, the percentage of silicon
  in structure increases
  (compared to oxygen)
“Silica rich” vs. “silica poor”

Ex: “silica poor”
    Olivine (1:4) (Mg,Fe)2SiO4
Ex: “silica rich”
    Quartz (1:2) SiO2
Silicate Minerals

Hold clues to the environmental
 conditions where they form
Minerals are stable when
 conditions are similar to where
 they formed
Environments:

1) Magma crystallizing
- quartz, feldspar, micas
Ex: Bowen’s Reaction Series
Environments:

2) Weathering at surface
- minerals that are unstable in new
conditions at Earth’s surface
  change into clay
  minerals
Ex: kaolinite
Silicate Minerals

3) Mountain building processes
    (high heat & pressure)
Ex: garnet, micas
Economic Minerals
(Nonsilicates)

Metal Ore
Ore = useful mineral that can be
 mined for a profit
Profitability depends upon:

1) Concentration above the level
   of average crustal abundance
   (Figure 2.19)
Lower crustal abundance = higher
   concentration necessary for
   profitability
Concentration

Ex: Copper
Crustal abundance ~0.0135%
Copper Ore = 50 times this amount
Concentration

Ex: Aluminum
Crustal abundance ~8.13%
Aluminum ore (bauxite) = 4 times this
 amount
Profitability depends upon:

2) Economic Changes
- demand increases, so price
  increases
- previously unprofitable deposits
  become profitable
Profitability depends upon:

3) New technology:
- decreases overhead costs
- withdraws more mineral from the
  rock
Ex: Gold mining with cyanide
Examples of metal ores:

Hematite = Fe2O3 = iron ore
Sphalerite (Zn,Fe)S = zinc ore
Galena = PbS = lead ore
Rocks

Mixture of minerals
Some rx are impure quantities of
 the same mineral
 Ex: Limestone = calcite
        (rock)      (mineral)
Rocks

Most rx are composed of several
 minerals
Ex: Granite = quartz, feldspar,
               hornblende
3 groups of rocks

1)

2)

3)

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EASC 116 Ch. 2 Minerals