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Eltech Engineers
       Presents
   Useful Information
      Help You To
      Understand
        Ozone
• Ozone is a triatomic allotrope of Oxygen formed by
  recombination of Oxygen atoms. It is a colorless gas
  with characteristic pungent odor and can easily be
  detected at low level of 0.05 ppm. It is a very strong
  oxidant and is over 3000 times more powerful
  disinfectant than Chlorine. It
  disinfects, oxidizes, deodorizes, and decolorizes.

• It is very reactive and strongest commercially available
  sanitizer and decomposes back to oxygen without
  leaving a trail behind, this makes it the preferred choice
  for air disinfection and major contribution towards a
  cleaner environment.
Ozone is a molecule composed of three atoms of oxygen. Two atoms of oxygen
form the basic oxygen molecule--the oxygen we breathe that is essential to life.
The third oxygen atom can detach from the ozone molecule, and re-attach to
molecules of other substances, thereby altering their chemical composition. It
is this ability to react with other substances that forms the basis of
manufacturers claims. Ozone (O3) is one of the strongest oxidizing agents that
are readily available. It is used to reduce color, eliminate organic waste, reduce
odor and reduce total organic carbon in water. Ozone is created in a number of
different ways, including ultra violet (UV) light, corona discharge of electricity
through an oxygen stream (including air), and several others. In treating small
quantities of waste, the UV ozonators are the most common, while large-scale
systems use either corona discharge or other bulk ozone-producing methods.
Ozone is formed as oxygen (O2) is struck by a source of energy. The bonds
that hold the O2 together are broken and three O2 molecules are combined to
form two O3 molecules. The ozone begins to break down fairly quickly, and as
it does so, it reverts back into O2. The bonds that hold the Ö atoms together
are very weak, which is why ozone acts as a strong oxidant as readily as it
does.
Ambient air (oxygen) passes
through an air gap between a
high voltage electrode and a
stainless steel grounding
electrode. The “energy field of
electrons” created by the high
voltage electrode instantly
converts oxygen (O2)
molecules into ozone (O3).
Property                  Ozone                   Oxygen
Molecular                     O3                     O2
Formula
Molecular                     48                     32
Weight:
Color                     Light Blue              Colourless
Smell             -clothes after being outside    Odorless
                          on clothesline
                     - photocopy machines
                 - smell after lightning storms
Solubility in                0.64                   0.049
Water
(@ O-deg C)
Density (g/l):               2.144                  1.429
Electrochemica               2.07                   1.23
Potential, V
What is permissible Concentration of Ozone by Regulatory bodies?




                                OSHA & ACGIH (USA)                      0.1 PPM (100 PPB)




                                       FDA                              0.05 PPM (50 PPB)




                                      WHO                               0.05 PPM (50 PPB)




                                     ASHARE          0.05 PPM (50 PPB
•   Ozone is the strongest oxidant and disinfectant available for the
    treatment of aqueous solutions and gaseous mixtures.
•   Although ozone is only partially soluble in water, it is sufficiently soluble
    and stable such that its oxidation or disinfectant properties can be fully
    utilized.
•   After ozone oxidizes or disinfects, it decomposes into oxygen
•   Ozone reacts with a large variety of organic compounds resulting in
    oxygen-containing organic by-products.
•   Although ozone is the strongest oxidizing agent commercially available, it
    is safe to handle. The primary reason is that it cannot be stored and,
    therefore must be generated and used on-site.
•   Ozone in its gaseous phase is a proven deodorizer for a variety of
    odorous materials.
•   In treating potable water, wastewater, and landfill leachate, ozone has
    the proven ability to convert biorefractory organic materials to
    biodegradable materials. As a result, combining ozone oxidation with
    subsequent biological treatment can produce water or wastewater with
    lower concentrations of problematic organic compounds more cost-
    effectively than either process used individually.
•   Applying ozone to any medium (liquid or gaseous) does not add other
    chemicals.
Oxidizing Reagent   Oxidizing Potential
      Ozone                2.07
Hydrogen Peroxide          1.77
  Permanganate             1.67
 Chlorine Dioxide          1.57
Hypochlorous acid          1.49
   Chlorine Gas            1.36
Hypobromous acid           1.33
     Oxygen                1.23
     Bromine               1.09
 Hypoiodous acid           0.99
   Hypochlorite            0.94
     Chlorite              0.76
     Iodine                0.54
Action in Water                Chlorine       Ozone

Oxidation Potential (Volts)-                     1.36          2.07

Disinfection:                     Bacteria     Moderate      Excellent
                                  Viruses      Moderate      Excellent

Environmentally Friendly                          No           Yes

Color Removal                                    Good        Excellent

Carcinogen Formation                            Likely       Unlikely

Organics Oxidation                             Moderate        High

Micro flocculation                               None        Moderate

pH Effect                                      Variable      Lowers

Water Half-Life                                2-3 hours     20 min.

Operation Hazards: Skin Toxicity                 High        Moderate
Inhalation Toxicity                              High          High

Complexity                                       Low           High

Capital Cost                                     Low           High

Monthly Use Cost                             Moderate-High     Low
Applications:
  Destruction of bacteria and viruses
 Oxidation of iron and manganese
 Heavy metal precipitation
 Colour destruction
 Taste improvement
 Algae and protozoa destruction
 Hardness reduction
 Hydrogen sulphide and mercaptans
elimination
   MINERAL WATER
   SWIMMING POOLS
   SEWERAGE WATER
   EFFLUENT WATER
   COOLING TOWER WATER
   AIR PURIFICATION
   CHEMICALS PROCESSING
   MEDICAL APPLICATION
With Diffuser Injection
             DIFFUSER INJECTION
                                   Float valve
                                                            Air Vent

                      Check
         Oxygen       Valve
         Cylinder              water
                                                                       Contact Tank
Compressor




                                                                           Min 5 metres
                        Ozone                                          Treated
                       Generator                                       Water Out




                                                 Diffuser


     Bubbles of Ozone pop up from the Diffuser in the tank & the
     Ozone in the bubbles gets mixed with the liquids.
METHOD OF MIXING OZONE IN WATER
With Venturi Injection
                     INJECTION BY VENTURY NOZZLES

              Oxygen Concentrator
                                               Air Vent
                            O2


                                  Ozone
        Compressor               Generator      Contact Tank

                                       Check
                                       Valve

            Raw
            Water in Pump
                                                               Treated
                                                                Water
           Check                 Venturi
           Valve                                               Out
                            Check
                            Valve


Here Ozone gets dissolved right from the moment of contact with water
                         inside the Ventury.
Venturi Injectors (Injectors) work by forcing water through a conical
body which initiates a pressure differential between the inlet and
outlet ports. This creates a vacuum inside the injector body, which
initiates ozone suction through the suction port.




    Characteristics
       • Very high ozone mass transfer rate (up to 60 to 70%)
        • Requires water pump to initiate suction
        • Efficiency rarely decreases over time
        • No moving parts
Bubble Diffusers work by emitting ozone through
hundreds of bubbles beneath the waters surface.

                  Characteristics:
                  Low ozone mass transfer rate (typically
                  around 10-15%)
                  Efficiency increases with increased water
                  depth
                  Requires air-pump to transfer oxygen
                  below surface
                  Diffuser holes become fouled decreasing
                  transfer efficiency
If you think a venturi injector is good enough,

                                   think again. Venturi injectors do attain fairly good

                                   mass transfer, but using a static mixer can greatly

                                   improve your mass transfer efficiency up to 90 to

                                   95%.




Notice how the bubbles are made into a fine mist as they move from left to right

resulting in significantly greater ozone mass transfer than using a venturi alone.

Pipe size is 1-1/2" diameter.
Ozone oxidizes the transition metals to their higher oxidation state
in which they usually form less soluble oxides, easy to separate by
filtration. e.g. iron is usually in the ferrous state when it is dissolved
in water. With ozone it yields ferric iron, further oxidized in water to
Ferric Hydroxide that is very insoluble and precipitates out for
filtration.
Other metals: Arsenic (in presence of
Iron), Cadmium, Chromium, Cobalt, Copper, Lead, Manganese, Ni
ckel, Zinc - can be treated in a similar way. At Ozone levels above
4 ppm however, Manganese will form soluble
permanganate, showing up as a pink color.
A-108, Diamond Ind. Est., Ketki Pada Rd., Nr. Toll Naka,
Off. W.E. Highway, Dahisar (E), Mumbai- 400 068. India
         Telefax +91-22-2897 2424 / 2727
    Contact Person : Mr.Rajesh Chauhan (Darji)

    Email :      rajesh@eltech.in




                 Thank You for being
                    With Us……..

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Ozone generator by eltech engineers

  • 1. Eltech Engineers Presents Useful Information Help You To Understand Ozone
  • 2. • Ozone is a triatomic allotrope of Oxygen formed by recombination of Oxygen atoms. It is a colorless gas with characteristic pungent odor and can easily be detected at low level of 0.05 ppm. It is a very strong oxidant and is over 3000 times more powerful disinfectant than Chlorine. It disinfects, oxidizes, deodorizes, and decolorizes. • It is very reactive and strongest commercially available sanitizer and decomposes back to oxygen without leaving a trail behind, this makes it the preferred choice for air disinfection and major contribution towards a cleaner environment.
  • 3. Ozone is a molecule composed of three atoms of oxygen. Two atoms of oxygen form the basic oxygen molecule--the oxygen we breathe that is essential to life. The third oxygen atom can detach from the ozone molecule, and re-attach to molecules of other substances, thereby altering their chemical composition. It is this ability to react with other substances that forms the basis of manufacturers claims. Ozone (O3) is one of the strongest oxidizing agents that are readily available. It is used to reduce color, eliminate organic waste, reduce odor and reduce total organic carbon in water. Ozone is created in a number of different ways, including ultra violet (UV) light, corona discharge of electricity through an oxygen stream (including air), and several others. In treating small quantities of waste, the UV ozonators are the most common, while large-scale systems use either corona discharge or other bulk ozone-producing methods. Ozone is formed as oxygen (O2) is struck by a source of energy. The bonds that hold the O2 together are broken and three O2 molecules are combined to form two O3 molecules. The ozone begins to break down fairly quickly, and as it does so, it reverts back into O2. The bonds that hold the Ö atoms together are very weak, which is why ozone acts as a strong oxidant as readily as it does.
  • 4. Ambient air (oxygen) passes through an air gap between a high voltage electrode and a stainless steel grounding electrode. The “energy field of electrons” created by the high voltage electrode instantly converts oxygen (O2) molecules into ozone (O3).
  • 5. Property Ozone Oxygen Molecular O3 O2 Formula Molecular 48 32 Weight: Color Light Blue Colourless Smell -clothes after being outside Odorless on clothesline - photocopy machines - smell after lightning storms Solubility in 0.64 0.049 Water (@ O-deg C) Density (g/l): 2.144 1.429 Electrochemica 2.07 1.23 Potential, V
  • 6. What is permissible Concentration of Ozone by Regulatory bodies? OSHA & ACGIH (USA) 0.1 PPM (100 PPB) FDA 0.05 PPM (50 PPB) WHO 0.05 PPM (50 PPB) ASHARE 0.05 PPM (50 PPB
  • 7. Ozone is the strongest oxidant and disinfectant available for the treatment of aqueous solutions and gaseous mixtures. • Although ozone is only partially soluble in water, it is sufficiently soluble and stable such that its oxidation or disinfectant properties can be fully utilized. • After ozone oxidizes or disinfects, it decomposes into oxygen • Ozone reacts with a large variety of organic compounds resulting in oxygen-containing organic by-products. • Although ozone is the strongest oxidizing agent commercially available, it is safe to handle. The primary reason is that it cannot be stored and, therefore must be generated and used on-site. • Ozone in its gaseous phase is a proven deodorizer for a variety of odorous materials. • In treating potable water, wastewater, and landfill leachate, ozone has the proven ability to convert biorefractory organic materials to biodegradable materials. As a result, combining ozone oxidation with subsequent biological treatment can produce water or wastewater with lower concentrations of problematic organic compounds more cost- effectively than either process used individually. • Applying ozone to any medium (liquid or gaseous) does not add other chemicals.
  • 8. Oxidizing Reagent Oxidizing Potential Ozone 2.07 Hydrogen Peroxide 1.77 Permanganate 1.67 Chlorine Dioxide 1.57 Hypochlorous acid 1.49 Chlorine Gas 1.36 Hypobromous acid 1.33 Oxygen 1.23 Bromine 1.09 Hypoiodous acid 0.99 Hypochlorite 0.94 Chlorite 0.76 Iodine 0.54
  • 9. Action in Water Chlorine Ozone Oxidation Potential (Volts)- 1.36 2.07 Disinfection: Bacteria Moderate Excellent Viruses Moderate Excellent Environmentally Friendly No Yes Color Removal Good Excellent Carcinogen Formation Likely Unlikely Organics Oxidation Moderate High Micro flocculation None Moderate pH Effect Variable Lowers Water Half-Life 2-3 hours 20 min. Operation Hazards: Skin Toxicity High Moderate Inhalation Toxicity High High Complexity Low High Capital Cost Low High Monthly Use Cost Moderate-High Low
  • 10. Applications:  Destruction of bacteria and viruses  Oxidation of iron and manganese  Heavy metal precipitation  Colour destruction  Taste improvement  Algae and protozoa destruction  Hardness reduction  Hydrogen sulphide and mercaptans elimination
  • 11.
  • 12. MINERAL WATER  SWIMMING POOLS  SEWERAGE WATER  EFFLUENT WATER  COOLING TOWER WATER  AIR PURIFICATION  CHEMICALS PROCESSING  MEDICAL APPLICATION
  • 13. With Diffuser Injection DIFFUSER INJECTION Float valve Air Vent Check Oxygen Valve Cylinder water Contact Tank Compressor Min 5 metres Ozone Treated Generator Water Out Diffuser Bubbles of Ozone pop up from the Diffuser in the tank & the Ozone in the bubbles gets mixed with the liquids.
  • 14. METHOD OF MIXING OZONE IN WATER
  • 15. With Venturi Injection INJECTION BY VENTURY NOZZLES Oxygen Concentrator Air Vent O2 Ozone Compressor Generator Contact Tank Check Valve Raw Water in Pump Treated Water Check Venturi Valve Out Check Valve Here Ozone gets dissolved right from the moment of contact with water inside the Ventury.
  • 16. Venturi Injectors (Injectors) work by forcing water through a conical body which initiates a pressure differential between the inlet and outlet ports. This creates a vacuum inside the injector body, which initiates ozone suction through the suction port. Characteristics • Very high ozone mass transfer rate (up to 60 to 70%) • Requires water pump to initiate suction • Efficiency rarely decreases over time • No moving parts
  • 17. Bubble Diffusers work by emitting ozone through hundreds of bubbles beneath the waters surface. Characteristics: Low ozone mass transfer rate (typically around 10-15%) Efficiency increases with increased water depth Requires air-pump to transfer oxygen below surface Diffuser holes become fouled decreasing transfer efficiency
  • 18. If you think a venturi injector is good enough, think again. Venturi injectors do attain fairly good mass transfer, but using a static mixer can greatly improve your mass transfer efficiency up to 90 to 95%. Notice how the bubbles are made into a fine mist as they move from left to right resulting in significantly greater ozone mass transfer than using a venturi alone. Pipe size is 1-1/2" diameter.
  • 19. Ozone oxidizes the transition metals to their higher oxidation state in which they usually form less soluble oxides, easy to separate by filtration. e.g. iron is usually in the ferrous state when it is dissolved in water. With ozone it yields ferric iron, further oxidized in water to Ferric Hydroxide that is very insoluble and precipitates out for filtration. Other metals: Arsenic (in presence of Iron), Cadmium, Chromium, Cobalt, Copper, Lead, Manganese, Ni ckel, Zinc - can be treated in a similar way. At Ozone levels above 4 ppm however, Manganese will form soluble permanganate, showing up as a pink color.
  • 20. A-108, Diamond Ind. Est., Ketki Pada Rd., Nr. Toll Naka, Off. W.E. Highway, Dahisar (E), Mumbai- 400 068. India Telefax +91-22-2897 2424 / 2727 Contact Person : Mr.Rajesh Chauhan (Darji) Email : rajesh@eltech.in Thank You for being With Us……..