Chapter 1 : Rate of Reaction

Kementerian Pelajaran Malaysia
Kementerian Pelajaran MalaysiaTeacher en Kementerian Pelajaran Malaysia
Chapter 1 : Rate of Reaction
Rate of reaction

 Rate of reaction is the measurement of
  the speed which reactants are converted into
  products in a chemical reaction / change in a
  selected quantity during a reaction per unit
  time.
 Average rate of reaction is the average value of
  the rate of reaction over an interval of time.
 Instantaneous rate of reaction / Rate of
  reaction at a given time are the actual rate of
  reaction at that instant.
Chapter 1 : Rate of Reaction
   Total surface area of solid reactant
   Concentration of reactant
   Temperature of reactant
   Use of catalyst
   Pressure of gaseous reactant
Chapter 1 : Rate of Reaction
Chapter 1 : Rate of Reaction
   Take note :
 The smaller the size (increase the total surface
  area), cm3, of the solid reactant, the higher the rate
  of reaction, cm3 s-1 or cm3 min-1.
 Explanation:
Effect of concentration of a liquid
   reactant on the rate of reaction
The higher the concentration, mol dm-3, of a
liquid reactant, the higher the rate of
reaction, mol dm-3 s-1 or mol dm-3 min-1.
Chapter 1 : Rate of Reaction
Chapter 1 : Rate of Reaction
   Increase in temperature, the higher the rate
    of reaction.
 Alters the rate of reaction
 It is specific in its action. It can only catalyse a
  particular reaction
 Does not change the quantity of products formed
 Only small amount of catalyst is needed to increases
  the rate of reaction. (An increase in the quantity of
  catalyst will increase the rate of reaction but only a
  very slight increase.)
 Catalyst remains chemically unchanged but may
  undergo physical changes.
Chapter 1 : Rate of Reaction
Chapter 1 : Rate of Reaction
(catalyst)
Chapter 1 : Rate of Reaction
catalyst
Effect of pressure on the rate of
                reaction
• Increase in pressure, the higher the rate of
  reaction (reversible reaction and gaseous
  reactants and gaseous product).
Chapter 1 : Rate of Reaction
1.3 Collision Theory
• According to kinetic theory of matter : Particles of matter are
  in continuous motion & constantly in collision with each other.
• Collision theory states a reaction occur when the particle of
  the     reactant      collide  with     each     other     with
  the correct orientation and achieve activation energy.
• Collision theory also states that the rate of reaction can be
  determined by frequency of collision / number of collisions
  per second & magnitude of Ea.
• Collision which achieve a minimum amount of activation
  energy & with correct orientation will result in reaction.
  (Effective collision)
• Ineffective collision is the particles that collide with
  energy less than activation energy or wrong orientation.
Activation energy, Ea
• The energy barrier that must be overcome by
  the colliding particles of the reactants so that
  the reaction can occur.
• Can be visualized by sketching the energy
  profile diagrams.
Chapter 1 : Rate of Reaction
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Chapter 1 : Rate of Reaction

  • 2. Rate of reaction  Rate of reaction is the measurement of the speed which reactants are converted into products in a chemical reaction / change in a selected quantity during a reaction per unit time.  Average rate of reaction is the average value of the rate of reaction over an interval of time.  Instantaneous rate of reaction / Rate of reaction at a given time are the actual rate of reaction at that instant.
  • 4. Total surface area of solid reactant  Concentration of reactant  Temperature of reactant  Use of catalyst  Pressure of gaseous reactant
  • 7. Take note :
  • 8.  The smaller the size (increase the total surface area), cm3, of the solid reactant, the higher the rate of reaction, cm3 s-1 or cm3 min-1.  Explanation:
  • 9. Effect of concentration of a liquid reactant on the rate of reaction The higher the concentration, mol dm-3, of a liquid reactant, the higher the rate of reaction, mol dm-3 s-1 or mol dm-3 min-1.
  • 12. Increase in temperature, the higher the rate of reaction.
  • 13.  Alters the rate of reaction  It is specific in its action. It can only catalyse a particular reaction  Does not change the quantity of products formed  Only small amount of catalyst is needed to increases the rate of reaction. (An increase in the quantity of catalyst will increase the rate of reaction but only a very slight increase.)  Catalyst remains chemically unchanged but may undergo physical changes.
  • 19. Effect of pressure on the rate of reaction • Increase in pressure, the higher the rate of reaction (reversible reaction and gaseous reactants and gaseous product).
  • 21. 1.3 Collision Theory • According to kinetic theory of matter : Particles of matter are in continuous motion & constantly in collision with each other. • Collision theory states a reaction occur when the particle of the reactant collide with each other with the correct orientation and achieve activation energy. • Collision theory also states that the rate of reaction can be determined by frequency of collision / number of collisions per second & magnitude of Ea. • Collision which achieve a minimum amount of activation energy & with correct orientation will result in reaction. (Effective collision) • Ineffective collision is the particles that collide with energy less than activation energy or wrong orientation.
  • 22. Activation energy, Ea • The energy barrier that must be overcome by the colliding particles of the reactants so that the reaction can occur. • Can be visualized by sketching the energy profile diagrams.