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8: Corrosion/Coatings

Hand-held computer determines concrete coating thickness    204   How can the current output of magnesium rod
National Association of Pipe Coating Applications (NAPCA)            used for the cathodic protection of heat exchanger
   specifications                                           208      shells be predicted?                                         229
How much primer for a mile of pipe?                         209   What spacing for test leads to measure current
How much coal-tar enamel for a mile of pipe?                210      on a pipeline?                                               229
How much wrapping for a mile of pipe?                       210   How many magnesium anodes are needed for
Estimating coating and wrapping materials required                   supplementary protection to a short-circuited bare casing?   230
  per mile of pipe                                          210   Group installation of sacrificial anodes                        230
Coefficient of friction for pipe coating materials          211   How can the life of magnesium anodes be predicted?              231
Troubleshooting cathodic protection systems:                      How to find the voltage rating of a rectifier if
   Magnesium anode system                                   213      it is to deliver a given amount of current through
Cathodic protection for pipelines                           214      a given ground bed (graphite or carbon)                      231
Estimate the pounds of sacrificial anode material                 Determining current requirements for coated lines               231
  required for offshore pipelines                           222   Determining current requirements for coated
Comparison of other reference electrode potentials                   lines when pipe-to-soil potential values are estimated       231
  with that of copper-copper sulfate reference                    HVDC effects on pipelines                                       232
  electrode at 25° C                                        224   Troubleshooting cathodic protection systems:
Chart aids in calculating ground bed resistance                      Rectifier-ground bed             ,                           236
  and rectifier power cost                                  225   How to control corrosion at compressor stations                 237
How can output of magnesium anodes be predicted?            226   Project leak growth                                             238
How to determine the efficiency of a cathodic
  protection rectifier                                      226   Advances in Pipeline Protection                                 239
How to calculate the voltage drop in ground                       Methods of locating coating defects                             240
  bed cable quickly                                         227   Case histories                                                  243
What is the most economical size for a rectifier cable?     227   Estimate the number of squares of tape for
How to estimate the number of magnesium                             pipe coating (machine applied)                                244
   anodes required and their spacing for a bare                   Estimate the amount of primer required for tape                 245
  line or for a corrosion quot;hot spotquot;                        228   Tape requirements for fittings                                  245
How can resistivity of fresh water be                             Induced AC Voltages on Pipelines
   determined from chemical analysis?                       228
What will be the resistance to earth of a                           May Present a Serious Hazard                                  246
   single graphite anode?                                   229   Measuring Unwanted Alternating
How to estimate the monthly power bill for a
  cathodic protection rectifier                             229     Current in Pipe                                               248
What will be the resistance to earth of a group of                Minimizing shock hazards on pipelines
   graphite anodes, in terms of the resistance                      near HVAC lines                                               253
   of a single anode?                                       229   Cathodic protection test point installations                    254
Hand-held computer determines concrete coating thickness
Technical data for the engineer's file
Frank E. Hangs, Sovereign Engineering, Inc., Houston



   Pipeline crossings, under water or in unstable soil, offer                                   Computer program
many challenges to engineers.
   Pipe is buoyant, and an empty line may float in water. Wet          The following program, written for the Hewlett Packard
silts are like viscous fluids causing inadequately weighted         41CV (Figure 1), calculates the thickness of concrete weight
pipelines to pop up. There are various government entities          coating for submarine pipelines expeditiously and with
that have jurisdiction over navigable rivers, bays, marshlands,     satisfying results.
and offshore waters. These agencies may stipulate that                 The prompting feature (Figure 2) is employed to aid
pipelines be buried at certain depths and be stabilized.            users' data input. Important calculated values and a recap of
   A good way to stabilize a pipeline is to use an adequate         the inputs are printed out, and each quantity is identified.
concrete weight coating. Determining the thickness of the           Thus, the tape is a complete record. The program is flexible
concrete involves a process of balancing upward forces such         in that any inputs can be readily changed for a second run.
as buoyancy of the mud and the downward forces—weights              Thus, many quot;what i f questions can be answered quickly.
of pipe, protective coating, and concrete, allowing a factor of     Suppose a heavier-weight pipe is used? What if the
60 (negative buoyancy). Such computations with several              concrete density is changed? If the negative buoyancy is
variables can become involved and tedious.                          reduced? Etc.




        8ULBL -COHCquot;       37 RCL 15          73 *           188 STO 85          144   STO 18           177 -T=-       213 -SP GR=-
          82 ODV           38 RCL 17          74 +           189 RCL 15          145   RCL 21           178 PRCL 85    214 RRCL 14
          63 SF 12         39 +               75 Xt2         118 quot;D=? quot;       146 -T   INCR=? •         179 PVIEH      215 RVIEU
      94 quot; CONCRETE1       40 LPSTX           76 .8855       111 PRCL 15         147   RRCL 21          188 CLR        216 CLP
      05 -h COPTIHGquot;       41 *               77 •           112 PROMPT          148   PROMPT           181 quot;HPC=-     217 PDV
          96 PRfl          42 .0213           78 STO 12      113 CLP             149   CLR              182 RRCL 86    218 -D=-
          97 PDV           43 •               79 RCL 28      114 STO 15          158   STO 21           183 RVIEU      219 RRCL 15
          88 CF 12         44 RCL 13          88 •           115 RCL 16          151   RCL 11           184 CLR        228 PVIEU
       89 quot;T TRIPL=?quot;      45 •               81 STO 89      116 quot;HP=? quot;    152 quot;NEG   BUOY=? -         185 quot;HC=-      221 CLP
          18 PROMPT        46 STO 86          82 RCL 08      117 PRCL 16         153   PRCL 11          186 RRCL 87    222 -HP=-
          11 STO 95        47 RCL 15          83 X O Y       118 PROHPT          154   PROMPT           187 RVIEH      223 RRCL 16
     12 'PIPE DIPH=?quot;      43 RCL 17          84 -           119 CLP             155   CLP              188 CLP        224 PVIEH
          13 PROHPT        49 2               85 STO 10      128 STO 16          156   STO 11           189 quot;HT=-      225 CLR
          14 STO 15        58 •               86 FS? 81      121 RCL 17          157   GTO 01           198 RRCL 88    226 quot;TH PC=quot;
       15 quot;PIPE WT=?quot;      51 +               87 GTO 03    122 -TH PC=? -                               191 RVIEU      227 PRCL 17
          16 PROHPT        52 RCL 85          88 RCL 11      123 PRCL 17         158*LBL   02           192 CLR        228 RVIEH
          17 STO 16        53 +               89 X=8?        124 PROHPT          159 RCL   21           193 quot;HHD=quot;     229 CLP
    13 quot;PROT CT TH=?quot;      54 LPSTX           98 GTO 84      125 CLR             168 ST+   85           194 RRCL 89    238 -DC=quot;
          19 PROHPT        55 *               91 RCL 18      126 STO 17          161 GTO   81           195 RVIEU
          20 STO 17         56 .8213          92 RCL Ii      127 RCL 19                                 196 CLR         231 PRCL 19
      21 -DEN CONC=?quot;       57 •              93 X<=Y?       128 quot;DC=? quot;        162*LBL 83             197 -HT-HHD=quot;    232 PVIEH
          22 PROHPT         58 RCL 19         94 GTO 83      129 PRCL 19        163 RCL 88              198 RRCL 18     233 CLP
          23 STO 19         59 •              95 GTO 82      138 PROHPT         164 RCL 12              199 RVIEU       234 -DH=quot;
       24 quot;DEN MUD=?quot;       68 STO 87                        131 CLR            165 /                   288 CLR         235 RRCL 28
          25 PROMPT         61 RCL 16         96*LBL 84      132 STO 19         166 STO 13           201 -NEG BUOY=-    236 PVIEU
          26 STO 28         62 +              97 RCL 09      133 RCL 28         167 62.4                282 RRCL 11     237 CLP
   27 quot;DEN PROT CT=?quot;       63 RCL 86         98 RCL 88      134 quot;DH=? •        168 /                   283 RVIEH       238 quot;DPC=quot;
          28 PROHPT        64 +               99 X)Y?        135 PRCL 28        169 STO 14              284 CLR         239 RRCL 18
          29 STO 18        65 STO 88         188 GTO 83      136 PROHPT                                 285 quot;VT=-       248 PVIEU
        38 -T INCR=?quot;      66 RCL 15         181 GTO 82      137 CLR          178*LBL -DPTP-            286 RRCL 12     241 CLP
          31 PROMPT        67 RCL 17         182*LBL 85      138 STO 28         171 PDV                 207 RVIEU      242 -T INCR=-
          32 STO 21        68 2              183 RCL 85      139 RCL 18         172 CLR                 288 CLP         243 RRCL 21
      33 -NEG BUOY=?quot;      69 •              184 -T=? quot;      148 quot;DPC=? quot;     173 quot;RESULTS-quot;         289 -BULK DEN=quot;    244 PVIEU
          34 PROHPT        70 +              185ftRCL85      141 PRCL 18       174 -I-RECPP.-           218 RRCL 13     245 CLP
          35 STO 11        71 RCL 85         186 PROMPT      142 PROMPT         175 RVIEH               211 RVIEU       246 BEEP
          36*LBL 81        72 2              187 CLP         143 CLP            176 PDV                 212 CLR         247 END


                                        Figure 1. Hewlett Packard-41CV computer program.
Nomenclature and storage registers inputs
                                                                                                     RESULTS-RECAP.
                                                                                                     T=4.625e
Reg. no.                                                                                             HPC=4.6885
                                                                                                     HC=479.3309
 05 T            = Concrete thickness, in. Assume trial                                              WT=578.6385
                   value. Final answer is cumulated in                                               MHD=553.4462
                   Reg. 0.5.                                                                         HT-HHD=25.1843
                                                                                                     HEG BUOY=20.89ee
 15 D            = Pipe diameter, in.                                                                VT=6.1494
                                                                                                     BULK DEN=94.8954
 16 WP           = Weight of pipe, lb/lf.                                                            SP GR=1.5979
                                                                                                     5=24.8869
 17 TH PC        = Thickness of protective coating.                                                  HP=94.6288
                   Usually 3/32 in. or 0.0938 in.                                                    TH PC=8.8938
                                                                                                     DC=165.8808
 19 DC           = Density of concrete, lb/cu ft. Usually                                            DH=98.0888
                                                                                                     DPC=95.6888
                   140, 165, 190.                                                                    T IHCR=8.1258
 20 DM           = Density of mud or fluid,
                   lb/cu ft. River mud is around 90.
                                                             Figure 2. Most common questions asked when checking
 18 DPC           = Density of protective                    coating buoyancy.
                    coating, lb/cu ft. 95 is average.
 21 T INCR        = Increment of T. Decimal of in. 0.125
                    is suggested for numerical precision—                              Formulas
                    not that a tolerance of this order
                    can be constantly achieved in the        WPC = (D + (THPC))(THPC)0.0218(DPC)
                    pipe coating world. Increment can be     WC = (D + 2(THPC) + T)T 0.0218(DC)
                    made smaller, if desired.
 11 NEG BUOY = Negative buoyancy. Desired minimum            VT = (D + 2(THPC) + 2T)20.0055
               value, lb/lf. Can be 0 in special
                                                             WMD = (VT)(DM)
               circumstances—e.g., to ascertain if a
               given pipe will float in water, or will a       Note: The user is encouraged to employ the most reliable
               certain coated pipe sink in mud?              and suitable data available, such as the density of protective
                                                             coating, mud, and concrete.
  Each value keyed in is printed on the tape as a check of
inputs and the program prompting feature queries user for                              Examples
value of next named input (Figure 2).
                                                                Put program into calculator, XEQ Size 30. The printed
                                                             RESULTS-RECAP portions of each of three examples are
                   Calculated values                         given. When the user XEQ quot;CONCquot; and inputs the data
                                                             from the lower part of the tabulation, he or she will get the
                                                             same calculated values above.
Reg. no.                                                        Figure 2 includes the most common questions asked
 06 WPC        = Weight of protective coating,               when checking coating buoyancy. Always be sure flag 01 is
                                                             clear XEQ quot;CONCquot; and put in new trial T and R/S. Also R/S
                 lb/lf.
                                                             after all other inputs. After all prompted data are keyed
 07   WC       = Weight of concrete coating, lb/lf.          in, the processing starts and results are printed out. Notice
 08   WT       = Total weight—pipe and coatings, lb/lf.      T = 4.6250 in. has an actual negative buoyancy of 25.1843. If
 09   WMD      = Weight of mud (fluid) displaced, lb/lf.     T = 4.5 in., the actual negative buoyancy= 18.4510, which is
                                                             less than 20. A precise solution is between 4.5 in. and 4.625 in.
 10   WT-WMD = Actual negative buoyancy, lb/lf.
                                                                If the user wants to find T, which produces an actual
 12   VT       = Total volume displaced by pipe and          negative buoyancy nearer 20: STO 4.5 in RO 5, STO § in.
                 coatings, cu ft/If.                         (0.0625 in.), in R21, XEQ 01. This produces T = 4.5625
 13   BULK DEN = Bulk density, wt/vt.lb/cu ft.               where actual negative buoyancy is 1.8113 greater than 20.
 14   SP GR    = Specific gravity, bulk den/den water.       This refinement can be found in choosing small T INCR.
                                                             Note that the weight of the concrete coating is now
                                                             471.8269 lb/lf and we have approached closer to 20.
Calculated values. Weight of protective coating and
                                                                                                                                                                                        RESULTS-RECAP
concrete, total weight and volume of pipe, and coatings per
linear foot will be of value in transporting coated pipe, etc.                                                                                                                         T=3.2598
                                                                                                                                                                                       HPC=3.9834
   Note: Results—RECAP of any run (which is in storage)                                                                                                                                MO273.9914
can be reprinted as often as desired by XEQ quot;DATA.quot;                                                                                                                                    HT=375.7248
   If NEG BUOY is 0 and flag 01 is not set, then the program                                                                                                                           HHD=352.5529
                                                                                                                                                                                       HT-MHB=23.1728
causes WT to approach WMD and calculates for this                                                                                                                                      NEG BUOY=28.8880
situation.                                                                                                                                                                             VT=3.9173
                                                                                                                                                                                       BULK DEN=95.9154
   If a printer is not available, results can be obtained as                                                                                                                           SP GR=1.5371
follows:
                                                                                                                                                                                       11=28.8888
1. XEQ 05, put in data and R/S after each item.                                                                                                                                        «P=97.8380
                                                                                                                                                                                       TH PC=6.8938
2. When beep sounds, RCL registers one by one in order                                                                                                                                 DC=165.8900
   given above (so as to identify values).                                                                                                                                             BH=90.8«90
                                                                                                                                                                                       DPC=95.9098
   Figure 3 illustrates the changing of two input values:                                                                                                                              T IHCR=B.1250
namely the pipe diameter and weight. The XEQ 05 routine
calls up the contents of the input registers one at a time and                                                                           Figure 3. Changing of two input valves.
questions them. Always put in a new T value. Then R/S.
   When D = ? comes up, key in new value and R/S. Same
with pipe WT = ?. Assume other data remain unchanged,                                                                                          XEQ quot;DflTfiquot;
R/S each time. (Any one value or any combination of values
                                                                                                                          RESULTS-RECAP.                                               BULK BEN=46.9065
may be changed before rerunning the program.)                                                                                                                                          SP GR=0.7517
   Figure 4 determines if a given pipe, 14 in. at 36.71 lb/lf                                                             T-e.eeee
                                                                                                                          UPC-21.3368                                                  6=14.0800
and 1A in. of protective weight coating density of 135 lb/cu ft,                                                                                                                       HP=36.7180
                                                                                                                          №=8.0000
will float. T, DC, T INCR, and NEG BUOY are all zero. DM                                                                  HT=58.8463                                                   TH PC=8.5000
becomes the density of water 62.4. Set flag 01 and XEQ 05.                                                                HHD=77.2280                                                  BPC=135.0880
                                                                                                                          HT-WHB=-19.1733                                              BC=8.8000
Key in data and R/S. When all data are in place only one                                                                  NEG BUOY=0.0080                                              BH=62.4000
computation is allowed, then printed out. WT-WMD tells us                                                                 VT=I.2375                                                    T INCR=0.0000
the upward forces exceed the downward forces by 19.1733
                                                                                                          Figure 4. Result of calculations to determine whether the pipe
lb/lf; also the specific gravity is 0.7517, so the pipe floats.
                                                                                                          will float.
Also note that BULK DEN is less than the density of water.


National Association of Pipe Coating Applications (NAPCA) specifications*

                               RECOMMENDED SPECIFICATION DESIGNATIONS FOR ENAMEL COATINGS
                                                These are recommended enamel coating system designations for
                   SPECIFICATION                coal tar or asphalt coatings, except for specialty requirements.
                      SYMBOL
                                                                                         FIBERGLASSWRAP




                                                                                                                                                          POLYETHYLENE
                                                                       93.75 MILS MIN.




                                                                                                                                                                         HEAVY KRAFT
                                                                                                          #15 FELT WRAP




                                                                                                                                                          WITH KRAFT




                                                                                                                                                                                       ELECTRICAL
                                                 SHOT BLAST




                                                                                                                                                                                       INSPECTION
                                                                                                                                              GLASS MAT
                                                                                                                             SEAL COAT
                    •PART *1




                                   •• PART #2




                                                                       ENAMEL
                                                              PRIMER




                                                                                                                                                                         PAPER




*NOTE: These are not all the specifications approved by NAPCA. For other specifications, consult an NAPCA member.
AGSF-
        TGM-
        AGM-
        TGMF-
        AGMF-
        TGMP-
        AGMP-
#
    P A R T # 1 SYMBOLS-                                • # P A R T # 2 SYMBOLS
    ENAMEL & WRAPPERS                                       GRADESOF ENAMEL
                                                       3— Fully-Plasticized Coal Tar
    T-Coal Tar          G-Fiberglass
    A-Asphalt           S-Seal Coat                        (ordered by penetration
    F-#15 Felt          GM-Glass Mat                       dictated by ambient temperature)
    P—Polyethylene wrapper                             4— High Temperature Surface Coa! Tar
       w/kraft paper                                   7 - Asphalt
    O—Outer wrap
       To specify Outer Wrap, use            EXAMPLE: 93.75 mils (minimum) fully-plasticized coal tar enamel
       letter O in place of F.
                                             wrapped with fiberglass, felt and kraft — the symbol would be TGF-3.

    Reprinted courtesy of National Association of Pipe Coating Applicators.




                        STANDARD APPLIED PIPE COATING WEIGHTS
                          FOR NAPCA COATING SPECIFICATIONS
                                                 Refer to NAPCA 1-65-83

      Spec.
      Symbol
         PIPE                                                 Weight in Pounds-Per 100 Lineal Feet
         SIZE




                                                                                                     (continued on next page)
(table continued)
     Spec.
     Symbol
         PIPE                                        Weight in Pounds - Per 100 Lineal Feet
         SIZE




     Al! weights provide for standard cutbacks.
     Weights per 100 lineal feet are figured on the following material weights per square foot of pipe surface:

                                               Weight                                                                  Weight
                                              Lbs.-Per                                                                Lbs.-fer
                                               Sq. Ft.                                                                 Sq. Ft.
     Coal Tar Primer & Enamel—1/32quot; Min.         .2461                         #15 Pipeline Felt
     Coal Tar Primer & Enamel-2/32quot; Min.          .4850                            (Tar or asphalt saturated)            1271
     Coal Tar Primer & Enamel—3/32quot; Min.          .7238                        Outerwrap                                 1225
     Asphalt Primer & Enamel—1/32quot; Min.           .2000                        .010            Fiberglass Wrap           0110
     Asphalt Primer & Enamel—2/32quot; Min.           .3950                        Kraft Paper                                0200
     Asphalt Primer & Enamel—3/32quot; Min.          .5912                         Glass Mat                                 0114
                                                                               Polyethylene                               0450


  Reprinted courtesy of National Association of Pipe Coating Applicators.




                            NAPCA SPECIFICATIONS PIPELINE FELTS

PROPERTY                                                  #15TAR              #15 TAR             #•15 ASPH.          #15 ASPH.
                                                            N.R.                R.F.                 N.R.               R.F.
Saturated FaIt - Not Parforatad
  Weight (MIn.) lbs. per 100 s.f.                             12                  12                   12                 12
  (ASTM-D-146-59 Sec. 1-9)
  Saturation (Percent)           MIN.                        18                   18                   22                22
  (ASTM-D-146-59 Sec. 18         MAX.                        28                   28                   40                40
  by extraction)
  Ash Content (MIN).) (Percent)                              70                   70                   70                 70
  (ASTM-D-146-59 Sec. 21)
  Callper (Min.) (inches)                                  .021                 .018                 .021               .018
  (ASTM-D-645-64T Method C)
  Tensile Strength (Min.)
  (lbs. per Inch of width)
  JASTM-D-146-59 Sec. 12a)
    With fiber grain                                         35                   37                   35                37
    Across fiber grain                                       12                No. spec.               12             No. spec.
  Tear Strength (Min.) (Grams)
  (ASTM-D-689-62)
   Across fiber grain                                       400                  Not                  400                Not
   With fiber grain                                         240               applicable              240             applicable

                                                                                                            (continued on next page)
Loss on heating (Max.) (Percent)                    10                   10               10            10
             (AWWA C203-66 Sec. 2.6.6)
             Pliability
             (AWWA C203-66 Sec. 2.6.4)                       No cracking       No cracking         No cracking   No cracking

           Saturated and Perforated Felt
             (1/16quot; perforations on 1 quot;
               Staggered Centers)
             Tensile Strength (MIn.)
             (lbs. per inch of width)
             (ASTM-D-146-59 Sec. 12a)
               With fiber grain                                  30                   35               30           35
               Across fiber grain                                10                 No spec.           10         No. spec.
             Tear Strength (MIN.) (Grams)
             (ASTM-D-689-62)
              Across fiber grain                                348                Not                348           Not
              With fiber grain                                  190             applicable            190        applicable

           Umaturated Felt
             Asbestos Content (%) (MIN.)
             (ASTM-D-1918-67)                                    85                   85               85            85

           N.R. —NON REINFORCED
           R.F. — REINFORCED LENGTHWISE WITH PARALLEL FIBER GLASS YARNS ON NOMINAL ¥•quot; CENTERS.


          Reprinted courtesy of National Association of Pipe Coating Applicators.




                                    Minimum Test Voltages for Various Coating Thicknesses

                                                         Coating Thicknesses
                                   32nd Inch                     Mils                          Test Volts




                                  Reprinted courtesy of National Association of Pipe Coating Applicators.




How much primer for a mile of pipe?

  Multiply pipe O.D. by 2% to get gallons of primer per                    Pipe 41Z2 in. in diameter will take 41Z2 x 2% or 123/8 gallons
mile.                                                                   of primer per mile (12 gallons in round figures).
                                                                           The given multiplier is applicable only where the pipe is
                                                                        new and in good condition. For rough pipe the multiplying
                                                                        factor should be upped from 2% to 3.45. In other words,
Examples.                                                               rough 20-in. pipe will require 20 x 3.45 or 69 gallons of
   Pipe 24 in. in diameter will require 24 x 2% or 66 gallons           primer per mile.
of primer per mile;                                                        It is hard to estimate the amount of spillage and waste.
   Pipe 16 in. in diameter will require 16 x 2% or 44 gallons           Temperature and relative humidity affect the way the primer
of primer per mile; and                                                 goes on the pipe.
How much coal-tar enamel for a mile of pipe?

   For an average cover of %2 in., multiply outside              8.625 x 0.6 =5.2 tons per mile
diameter of pipe by 0.6. The answer is in tons of enamel         5.2x15% =0.8
per mile. (Add 15% to take care of gate valves, drips, bends,                = 6 tons per mile
etc.)
                                                                   These factors strongly affect the amount of coating used
                                                                 per mile on pipelines: 1. Temperature of the pipe and
  Examples. How many tons of coal-tar enamel will be
                                                                 ambient temperatures. (It is assumed that the temperature
required to apply a %2-in. coat to a 26-in. pipeline?
                                                                 of the enamel can be controlled.) 2. The kind of dope
26 x 0.6 = 15.6 tons per mile                                    machine. 3. Humidity. 4. The number of bends per mile. 5.
                                                                 The number of valves, crossovers, etc. 6. Condition of the
  Add 15% to take care of gate valves, bends etc.                pipe.
                                                                   This latter point has a great effect on the amount of
15.6 + 2.3 = 17.9 or 18 tons per mile
                                                                 enamel required for a mile of pipeline. In fact, where
  How many tons of coal-tar enamel will be required to           reconditioned pipe is being coated, it is recommended that
apply a %2~in- coat to a 8.625-in. pipeline?                     the amount of enamel be increased by about 20%.


How much wrapping for a mile of pipe?

   For 14-in. to 48-in. pipe multiply the diameter in inches     (4 + 1) x 15 = 75 squares of felt
by 15 to get the number of squares (100 ft ). For pipe sizes
                                                                   These figures are conservative and do not allow for
of 12% in. and smaller, add 1 to the nominal size of pipe and
                                                                 wrapping drips, for patching holidays, and for short ends that
multiply by 15.
                                                                 are usually discarded. They allow for machine wrapping
   Examples. How many squares of asbestos felt would be
                                                                 using /^-in. lap on diameters up to 10/4 m - a n d using 1-in. lap
required to wrap 1 mile of 30-in. pipeline?
                                                                 on larger diameters.
30 x 15 = 450 squares of felt                                      For smaller diameters of pipe, this figure should be
                                                                 increased about 5% to take care of additional wastage and
  How many squares of felt would be required to wrap 1
                                                                 patching.
mile of 4-in. pipe?


Estimating coating and wrapping materials required per mile of pipe
                                                                 Nominal                            Glass      Kraft    15-Pound
              Primer and coal-tar enamel                         Pipe        Primer     Coal-tar    Wrap       Paper       Felt
                                                                 Size        Gallons    Enamel     Squares    Squares    Squares
                                                                                         Tons
   Gallons of primer and tons of coal-tar enamel are based on
covering new pipe in good condition. For rough pipe,
increase primer quantities by 25% and the coal-tar quantities
by 20%. No allowance is included for spillage or waste.



                        Wrappings

   Squares are based on machine wrapping, allowing /4-in.
laps on pipe sizes through 10 in. and 1-in. laps on pipe sizes
greater than 10 in. No allowance is included for wrapping
drips, patching holidays, or short ends, which are usually
discarded.
Coefficient of friction for pipe coating materials

Tests indicate that previous values appear to be valid for thinfilm epoxies and conservative for coal tars

J. B. Ligon, Assistant Professor, Mechanical Engineering-Engineering Mechanics Dept., Michigan Technological
University, Houghton, Mich., and G. R. Mayer, Project Engineering Manager, Bechtel, Inc., San Francisco

   A major factor in the stress analysis of buried pipelines is    where:     F = Longitudinal soil friction force (Ib)
the movement that pipe undergoes in the presence of tem-                    /ji = Coefficient of friction (dimensionless)
perature and pressure differentials during its life. This move-              p = Normal soil pressure acting on the pipe
ment is highly dependent upon friction resistance of the soil.                    surface (psi)
   Although ample information is available on the static                   dA = Soil to pipe differential contact area (in.2)
coefficient of friction for many materials, there is a lack of         fA pdA = Total normal soil force on pipe surface (Ib)
data on friction between soils and various coatings used in
                                                                     The above relation is independent of the pressure per unit
the pipeline industry. In the past, friction coefficient
                                                                   area of the mating surfaces as long as very high contact
information was extrapolated from data in the literature
                                                                   pressures are not encountered, which is the case for a buried
that were believed to have a similarity to the external pipe
                                                                   pipeline.
coating to soil interface.
                                                                     In terms of a buried pipeline supporting a soil burden up
   However, with the development of thinfilm epoxy resin
                                                                   to three pipe diameters of depth, the soil force relation
coating systems and the increasing use of these systems in
                                                                   becomes:
the pipeline industry, a change from a conventional coal tar
felt coating to a thinfilm epoxy coating would indicate a
significant change in the friction coefficient design criteria
due to the extreme contrast in the surface texture of the two
materials.
   To evaluate the effect of the difference in surface texture     where: Wp = Weight of pipe and contents (lb/in.)
on a pipeline system, test procedures were developed to                    D = Pipe diameter (in.)
determine the coefficient of friction for both coal tar felt and           H = Depth of the pipe centerline (in.)
thinfilm epoxy to various soils and to obtain more reliable                Y = Specific weight of the soil (lb/in.3)
information for future pipeline designs using these coating           The sensitivity of the soil friction forces to the coefficient
materials.                                                         of friction is readily apparent from the above relation. Since
   Static friction tests were conducted to find the coefficient    this force is inversely proportional to the active length that a
of friction between coal tar felt and thinfilm epoxy pipe          pipeline moves as a result of temperature and pressure
coating and eight representative backfill soil samples from        expansion, the coefficient of friction becomes a major factor
typical locations along a pipeline right of way. The results       in pipeline stress design.
indicate that the friction coefficients are significantly larger
than those previously extrapolated from literature and that           Test system. The theoretical soil friction force acting on
coal tar has a higher friction resistance in respect to            the surface of a coated plate can be calculated from the
anchorage of a pipeline.                                           relation:
   For the coal tar felt coating, the coefficient varies from
0.59 to 0.91 depending on the soil and moisture content. The       F = ^N
thinfilm epoxy coating varies from 0.51 to 0.71 under the
same conditions.                                                   where: N = Normal force acting on the plate surfaces (Ib)
                                                                         W = Total weight of plate and external load (Ib)
                         Definitions

   Static coefficient of friction. The theoretical long-
itudinal soil force acting on the pipe surface can be
                                                                                                          COATED PLATE
calculated from the relation:
Since the coefficient of friction parameter is the same in           Thinfilm epoxy. The epoxy coating simulated a thinfilm
all of the previous expressions, the plate test system can be         epoxy resin pipeline coating applied by the fusion method.
used to simulate the soil-to-pipeline interface.                        Plates used in the tests were coated by the fluidized bed
                                                                      method. However, the surface texture was the same as that
                                                                      expected by coating plant production equipment.
  Coal tar felt. The coal tar coating, an enamel and felt
combination, was prepared to simulate an actual coated
                                                                                                       Results
pipeline.
  The surface of a steel plate was coal tar coated and then              Coal tar to soils. Figure 1 illustrates that the friction
wrapped in a 15-lb felt. Therefore, the soil surface contact          coefficient varies from 0.59 to 0.91 for the various soils tested
was predominantly with the felt material.                             at field moisture content.


          LOCATION   SOIL DESCRIPTION    MOISTURE
                     SANOY SIiT (ML)
                     SiLTY SAND {SM>
                     SItT ( M t I
                     SiLTY SAND (SM)
                     SIlTY SANO (SM)
                     SAND - SILT (SM)
                     SANDY SILT (ML)
                     SlLTY • SAND (SM)

           UMlFiED SGlL CLASSIFICATION SYMBOL




                                                                                      Figure 1. Coefficient of friction for coal tar coating
                                                                                      to soil.




                                                           LOCATION    SOiI OESCWPTiON     MOISTURE
                                                                       SANDY SiIT (ML) 1
                                                                       SiLTY SANO (SM)
                                                                       SfLT |ML)
                                                                       SIlTY SAND (SM)
                                                                       SlLTY SANO CSM)
                                                                       SAND-SO (SM)
                                                                       SANDY SILT (ML)
                                                                       SILTY SAND (SM)
                                                                       SRAVa-SAKO
                                                                       SILT (GM)
                                                                UNFIEO SOIL CtASSJFiCATiON SYMBOL



Figure 2. Coefficient of friction for thin film epoxy
to soil.
The mechanism by which the friction coefficient changes          Since such information on this coating was not available in
among the various soils is not apparent from the results of        the literature, no comparison to similar tests could be made.
these tests, since the soil samples used did not vary                 Temperatures in the 1200F range should have little or no
considerably in description. However, the range over               effect on the coefficient of friction of epoxy to soil.
which the factor changes is considerably greater than that
previously extrapolated from the literature, as follows:
                                                                                            Conclusions
                                     Coefficient of friction
Soil description                       commonly used                  Although it is virtually impossible to precisely simulate the
                                                                   surface contact situation of a pipeline in a back-filled trench,
Silt                                          0.3
                                                                   the test procedure and apparatus reported here are a means
Sand                                          0.4                  of approximating it. The results indicate that coal tar coatings
Gravel                                        0.5                  have a higher friction resistance than epoxy coatings as far as
                                                                   anchoring capabilities of the soil are concerned.
   The tests also indicate that the moisture content alters the       The selection of a coating, based on its soil friction
friction factor to some extent, as would be expected.              resistance, could be of economic value in reducing those
   In order to investigate the influence of temperature, tests     situations where extreme expansions call for reinforced
were conducted with coal tar felt wrapping heated to 1200F.        fittings or elaborate culverts to overcome excessive stress
Only a slight softening beneath the coating surface was            levels in a pipeline system.
observed, and it is believed that temperatures up to this             The test results show that previous values commonly used
range will not significantly affect the magnitude of the           for the coefficient of friction were conservative for similar
friction coefficient.                                              soils, and it is suggested that some conservatism still be
                                                                   incorporated in future analyses.
                                                                       Since the tests indicated that the friction coefficient of the
   Thinfilm epoxy to soils. As expected, results shown in          epoxies was similar to those previously used for coal tar
Figure 2 indicate that the friction factor range of 0.51 to 0.71   coatings, their continued use for epoxy-coated pipelines
for the epoxy is somewhat lower than that of the coal tar.         should be valid. A more conservative approach to these
   Again, the mechanism is not clear, but the results are fairly   values is recommended in soils where the presence of
consistent with the friction coefficient increasing in most        excessive moisture could change the friction factor substan-
instances in the same order of magnitude as for coal tar.          tially when interfaced with a smooth epoxy coating.




Troubleshooting cathodic protection systems: Magnesium anode system

   The basic technique is the same as that outlined earlier;
more measurements are required because of the multiplicity
of drain points. First, the current output of stations nearest
the point of low potential should be checked; if these are
satisfactory, a similar check should be extended in both
directions until it is clear that the trouble must be on the
line. When a given anode group shows a marked drop in
current output, the cause may be drying out, shrinkage of
backfill, or severed or broken lead wires. If the current is
zero, the pipe-to-soil potential of the lead wire will show
whether it is still connected to the pipe or the anode, and                                         < Broken Wire
                                                                                                    •

thus indicate the direction to the failure. If the current is      Figure 1. Locating idle anodes by surface potentials. The solid
low, there may be a loss of one or more anodes by a                line shows the potentials found along a line of anodes when all
severed wire; a pipe-to-soil potential survey over the anodes      are delivering current; the dotted line exhibits the change when
will show which are active, just as in the case of rectifier       there is a break in the anode lead at the point indicated. Single
                                                                   disconnected anodes may also be located by this method. A
anodes.                                                            driven ground rod, a pipe lead, or even a rectifier terminal may
   Trouble indicated on the line, rather than at the anode         be used for the reference ground; all readings should be
stations, is tracked down in the same manner as that used for      referred to the same reference.
line protected by rectifiers—first, investigating locations                                  next, checking potentials; and finally, making a line current
where something that has been done might be responsible;                                     survey.


Cathodic protection for pipelines

  Estimate the rectifier size required for an infinite line.                                    Use a value of—0.3 volts for AE x . This is usually enough
Refer to Figure 1. If coating conductance tests have not been                                to raise the potential of coated steel to about—0.85 volts.
performed, pick a value from Table 1.                                                           Use a value of 1.5 volts for AE at the drain point. Higher
                                                                                             values may be used in some circumstances; however, there
                                                                                             may be a risk of some coating disbondment at higher
                         Table 1                                                             voltages.
          Typical Values of Coating Conductance                                                 Calculate I at the drain point.
Micromhos/sq ft                                       Coating Condition
1-10                    Excellent coating—high resistivity soil                              AI A = amp./in. x AE x /0.3 x D
10-50                   Good coating—high resistivity soil
50-100                  Excellent coating—low resistivity soil
100-250                 Good coating—low resistivity soil
                                                                                             where D = pipe OD, inches.
250-500                Average coating—low resistivity soil
                                                                                               Example. 30-in. OD line with coating conductivity= 100
500-1,000              Poor coating—low resistivity soil                                     micromhos/sq ft. What is the current change at the drain



                                                          Based on 0.25-inch wall pipe and steel resistivity of 18.8 microhm-cm
                          _* x — , amperes per inch
                          D AEx




                                                                                    Thousands of Feet, x

                                               Figure 1. Drainage current versus distance for a coated infinite line.
Based on 0.25-inch wall pipe and steel resistivity of 18.8 microhm-cm




                           — x — , amperes per inch
                                            . u
                           D AEJ
                           IA 0 3




                                                                                  Thousands of Feet, L

                                            Figure 2. Drainage current versus distance for a coated finite line.


point, and how far will this current protect an infinitely long                         micromhos/sq ft. What is AE A /E T and what AI A is required?
pipeline?                                                                               Assume that

AE A = 1.5                                                                              E x = 0.3

AE x = 0.3                                                                              From Figure 2 read

AE A /AE x = 5.0                                                                        AE A /E X = 5.8

                                                                                        AE A = 1.74
Refer to Figure 1 and read
                                                                                        AI A /D x 0.3/E x = 1.8 amp./in.
L = 30,000 ft
                                                                                        AI A =1.8 x 3.5 = 6.3 amp.
AIA/D x 0.3/AEx = 0.7 (from Figure 1)
                                                                                           Estimate       ground       bed    resistance   for   a   rectifier
AIA = 0.7x 30 = 21 amp.                                                                 installation.

21 amps will protect the line for 30,000 ft in either direction                            Example. A ground bed for a rectifier is to be installed
from the drain point.                                                                   in 1,000 ohm-cm soil. Seven 3-in. x 60-in. vertical graphite
   Estimate rectifier size for a finite line. Refer to Figure 2.                        anodes with backfill and a spacing of loft will be used. What
   A 31Z2 -in. OD line 20,000 ft long is protected by insulating                        is the resistance of the ground bed?
flanges at both ends and has a coating conductivity of 500                                 Refer to Figure 3. The resistance is 0.56 ohms.
Anode Bed Resistance, R A (ohms)




                                                                                           Anode
                                                                                          Spacing
                                                                                                     Figure 3. Anode bed resistance versus number
                                                                                                     of anodes. 3-in. x 60-in. vertical graphite anodes
                                                                                                     in backfill.




                                   Number of Anodes
                                                          Anode Resistance, RA (ohms)




Figure 4. Anode bed resistance versus number of                                                                                                  Anode
anodes. 2-in. x 60-in. vertical bare anodes.                                                                                                    Spacing




                                                                                                           Number of anodes



   Figure 3 is based on a soil resistivity of 1,000 ohms-cm. If                         soil resistivity is 3,000 ohms-cm. What is the ground bed
the soil resistivity is different, use a ratio of the actual soil                       resistance? Refer to Figure 4. The resistivity from the chart
resistivity divided by 1,000 and multiply this by the reading                           is 0.55 ohms. Since the chart is based on soil resistivity of
obtained from Figure 3.                                                                 1,000 ohms-cm, the ground bed resistivity is 3,000/1,000 x
   A rectifier ground bed is to be composed of 10 — 2 x                                 0.55 or 1.65 ohms.
60-in. bare quot;Durironquot; silicon anodes spaced 20 ft apart. The
The resistance of multiple anodes installed vertically and         Figure 5 is based on Equation 1 and does not include the
connected in parallel may be calculated with the following        internal resistivity of the anode. The resistivity of a single
equation:                                                         vertical anode may be calculated with Equation 2.

R = 0.00521P/NL x (2.3 Log 8L/d - 1 + 2L/S Log 0.656N)            R = 0.00521P/L x (2.3 Log 8L/d - l)                         (2)
                                                            (1)
                                                                     If the anode is installed with backfill, calculate the
where:                                                            resistivity using the length and diameter of the hole in
     R = Ground bed resistance, ohms                              which the anode is installed. Calculate the resistivity using
     P = Soil resistivity, ohm-cm                                 the actual anode dimensions. The difference between these
     N = Number of anodes                                         two values is the internal resistance of the anode. Use the
      d = Diameter of anode, feet                                 value of P, typically about 50 ohm-cm, for the backfill
     L = Length of anode, feet                                    medium.
      S = Anode spacing, feet                                        Figure 5 is based on 1,000 ohm-cm soil and a 7-ft x 8-in.
                                                                  hole with a 2-in. x 60-in. anode.
   If the anode is installed with backfill such as coke breeze,
use the diameter and length of the hole in which the anode is       Example. Determine the resistivity of 20 anodes installed
installed. If the anode is installed bare, use the actual         vertically in 1,500 ohm-cm soil with a spacing of 20 ft.
dimensions of the anode.                                            Read the ground bed resistivity from Figure 5.
  Anode Bed R e s . Ohms




                                                                                                                    Spacing




                                              Number of Anodes
                                                Figure 5. Anode bed resistance.
R = 0.202 ohm                                                          either in standard alloy or high purity alloy. Galvanic
                                                                       anodes are usually pre-packaged with backfill to facilitate
Since the anodes are to be installed in 1,500 ohm-cm soil and
                                                                       their installation. They may also be ordered bare if desired.
Figure 5 is based on 1,000 ohm-cm soil, multiply R by the
                                                                       Galvanic anodes offer the advantage of more uniformly
ratio of the actual soil resistivity to 1,000 ohm-cm.
                                                                       distributing the cathodic protection current along the
                                                                       pipeline, and it may be possible to protect the pipeline
R = 0.202 x 1,500/1,000                                                with a smaller amount of current than would be required
                                                                       with an impressed current system but not necessarily at a
R = 0.303 ohm                                                          lower cost. Another advantage is that interference with other
                                                                       structures is minimized when galvanic anodes are used.
The internal resistivity for a single 2-in. x 60-in. vertical             Galvanic anodes are not an economical source of cathodic
anode installed in 50 ohm-cm backfill (7ftx8-in. hole) is              protection current in areas of high soil resistivity. Their use is
0.106 ohm.                                                             generally limited to soils of 3,000 ohm-cm except where
   Since 20 anodes will be installed in parallel, divide the           small amounts of current are needed.
resistivity for one anode by the number of anodes to obtain               Magnesium is the most-used material for galvanic anodes
the internal resistivity of the anode bank.                            for pipeline protection. Magnesium offers a higher solution
                                                                       potential than zinc and may therefore be used in areas of
0.106/20 = 0.005 ohm                                                   higher soil resistivity. A smaller amount of magnesium will
                                                                       generally be required for a comparable amount of current.
                                                                       Refer to Figure 6 for typical magnesium anode performance
The total resistivity of the 20 anodes installed vertically will       data. These curves are based on driving potentials of —0.70
therefore be 0.308 ohm (0.303 + 0.005).                                volts for H-I alloy and —0.90 volts for Galvomag working
                                                                       against a structure potential of —0.85 volts referenced to
                                                                       copper sulfate.
                     Galvanic Anodes                                      The driving potential with respect to steel for zinc is less
                                                                       than for magnesium. The efficiency of zinc at low current
 Zinc and magnesium are the most commonly used                         levels does not decrease as rapidly as the efficiency for
materials for galvanic anodes. Magnesium is available                  magnesium. The solution potential for zinc referenced to a
                      Soil Resistivity - Ohms-Cm.




                                                     Anode Current -       Milliamperes
                                                    Figure 6. Magnesium anode current.
1 Anode
                                                                          2 Anodes
                                                                          3 Anodes
                                                                          4 Anodes
                                                                          8 Anodes
                                                                          Six Anodes



    Soil Resistivity Ohms-Cm




                                                                                       Spacing 15 ft.




                                                                                       1.4 In.xl.4 In.
                                                                                       By 5 Ft. Long




                               Current Output M i l l i a m p e r e s
                                 Figure 7a. Current output zinc anodes.
Soil Resistivity Ohms-Cm




                                                                                       Spacing 15 f t .




                                                                                       1.4-In.xi.4-In.
                                                                                       B 5 - f t . Long
                                                                                        y




                               Current Output M i l l i a m p e r e s
                                 Figure 7b. Current output zinc anodes.
Water Resistivity Ohms-Cm




                                                                                                                   Spacing   15   ft.




                                                                                                                   l.4-In.xl.4-In.
                                                                                                                   Jy 5-ft. Long




                                                              Current Output M i l l i a m p e r e s
                                                                Figure 8a. Current output zinc anodes.
                            Anode Bed Resistance, RA (ohms)




                                                                                                          Anode
                                                                                                         Spacing




                                                                           Number of Anodes

                                                               Figure 8b. Current output zinc anodes.
copper sulfate cell is —1.1 volts; standard magnesium has a             have an efficiency of 50% at normal current densities.
solution potential of —1.55 volts; and high purity magnesium            Magnesium anodes may be consumed by self-corrosion if
has a solution potential of —1.8 volts.                                 operated at very low current densities. Refer to Figures 7a,
   If, for example, a pipeline is protected with zinc anodes at         7b, 8a, and 8b for zinc anode performance data. The data in
a polarization potential of —0.9 volts, the driving potential           Figures 7a and 7b are based on the anodes being installed in
will be —1.1 — (—0.9) or —0.2 volts. If standard magnesium is           a gypsum-clay backfill and having a driving potential of —0.2
used, the driving potential will be —1.55 —(—0.9) or —0.65              volts. Figures 8a and 8b are based on the anodes being
volts. The circuit resistance for magnesium will be approxi-            installed in water and having a driving potential of —0.2
mately three times as great as for zinc. This would be                  volts.1
handled by using fewer magnesium anodes, smaller anodes,                   Example. Estimate the number of packaged anodes
or using series resistors.                                              required to protect a pipeline.
   If the current demands for the system are increased due to             What is the anode resistance of a packaged magnesium
coating deterioration, contact with foreign structures, or by           anode installation consisting of nine 32-lb. anodes spaced 7 ft
oxygen reaching the pipe and causing depolarization, the                apart in 2,000 ohm-cm soil?
potential drop will be less for zinc than for magnesium                    Refer to Figure 9. This chart is based on 17# packaged
anodes. With zinc anodes, the current needs could increase              anodes in 1,000 ohm-cm soil. For nine 32-lb. anodes, the
by as much as 50% and the pipe polarization potential would             resistivity will be:
still be about 0.8 volts. The polarization potential would
drop to about 0.8 volts with only a 15% increase in current              1 x 2,000/1,000 x 0.9 = 1.8 ohm
needs if magnesium were used.
   The current efficiency for zinc is 90%, and this value holds          See Figure 10 for a table of multiplying factors for other
over a wide range of current densities. Magnesium anodes                 size anodes.
                            Anode Bed Resistance, RA (ohms)




                                                                                                   Anode
                                                                                                  Spacing




                                                              Number of Anodes

                Figure 9. Anode bed resistance versus number of anodes; 17# packaged magnesium anodes.
Next Page
                                                            Chart based on 17-Ib. magnesium anodes installed in 1,000 ohm-cm soil in groups of
                                                              10 spaced on 10-ft centers.
                                                            For other conditions multiply number of anodes by the following multiplying factors:
                                                            For soil resistivity: MF = —£—                  For 9-lb. anodes: MF = 1.25
                                                            For conventional magnesium: MF = 1.3            For 32-Ib. anodes: MF = 0.9




                            Number of Anodes per 1,000 ft




                                                                                                                                                   Number of Anodes per Mile
                                                                                  Coating Conductivity (micromhos/sq.ft)

                                                             Figure 10. Number of anodes required for coated line protection.




  Example. A coated pipeline has a coating conductivity                                                                                     Source
of 100 micromhos/sq. ft and is 10,000 ft long, and the
diameter is 10/4 in. How many 17-lb magnesium anodes will                                                 Pipeline Corrosion and Cathodic Protection, Gulf Publishing
be required to protect 1,000 ft? Refer to Figure 7 and read 2                                             Company, Houston, Texas.
anodes per 1,000 ft. A total of twenty 171b. anodes will be
required for the entire line.
                                                                                                                                          Reference

                                                                                                          1. From data prepared for the American Zinc Institute.


Estimate the pounds of sacrificial anode material required for offshore pipelines

  This rule of thumb is based on the following assumptions:                                               life in years = the Ib. of galvanic anode material that will be
                                                                                                          required.
  • 5% of pipeline considered bare
  • 3 milliamperes/sq. ft required for protection
  • 30-year design life
   Basis for rule: sq. ft of surface area of pipeline/linear                                              Multiplier = OD x lb./amp.-yr x (12 PI/144)
ft x % of bare pipe x 3.0 m.a./sq. ft x lb./amp.-year x design                                                              x 30 x 0.05 x 0.003 x 1,000

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Corrosion & Coatings

  • 1. 8: Corrosion/Coatings Hand-held computer determines concrete coating thickness 204 How can the current output of magnesium rod National Association of Pipe Coating Applications (NAPCA) used for the cathodic protection of heat exchanger specifications 208 shells be predicted? 229 How much primer for a mile of pipe? 209 What spacing for test leads to measure current How much coal-tar enamel for a mile of pipe? 210 on a pipeline? 229 How much wrapping for a mile of pipe? 210 How many magnesium anodes are needed for Estimating coating and wrapping materials required supplementary protection to a short-circuited bare casing? 230 per mile of pipe 210 Group installation of sacrificial anodes 230 Coefficient of friction for pipe coating materials 211 How can the life of magnesium anodes be predicted? 231 Troubleshooting cathodic protection systems: How to find the voltage rating of a rectifier if Magnesium anode system 213 it is to deliver a given amount of current through Cathodic protection for pipelines 214 a given ground bed (graphite or carbon) 231 Estimate the pounds of sacrificial anode material Determining current requirements for coated lines 231 required for offshore pipelines 222 Determining current requirements for coated Comparison of other reference electrode potentials lines when pipe-to-soil potential values are estimated 231 with that of copper-copper sulfate reference HVDC effects on pipelines 232 electrode at 25° C 224 Troubleshooting cathodic protection systems: Chart aids in calculating ground bed resistance Rectifier-ground bed , 236 and rectifier power cost 225 How to control corrosion at compressor stations 237 How can output of magnesium anodes be predicted? 226 Project leak growth 238 How to determine the efficiency of a cathodic protection rectifier 226 Advances in Pipeline Protection 239 How to calculate the voltage drop in ground Methods of locating coating defects 240 bed cable quickly 227 Case histories 243 What is the most economical size for a rectifier cable? 227 Estimate the number of squares of tape for How to estimate the number of magnesium pipe coating (machine applied) 244 anodes required and their spacing for a bare Estimate the amount of primer required for tape 245 line or for a corrosion quot;hot spotquot; 228 Tape requirements for fittings 245 How can resistivity of fresh water be Induced AC Voltages on Pipelines determined from chemical analysis? 228 What will be the resistance to earth of a May Present a Serious Hazard 246 single graphite anode? 229 Measuring Unwanted Alternating How to estimate the monthly power bill for a cathodic protection rectifier 229 Current in Pipe 248 What will be the resistance to earth of a group of Minimizing shock hazards on pipelines graphite anodes, in terms of the resistance near HVAC lines 253 of a single anode? 229 Cathodic protection test point installations 254
  • 2. Hand-held computer determines concrete coating thickness Technical data for the engineer's file Frank E. Hangs, Sovereign Engineering, Inc., Houston Pipeline crossings, under water or in unstable soil, offer Computer program many challenges to engineers. Pipe is buoyant, and an empty line may float in water. Wet The following program, written for the Hewlett Packard silts are like viscous fluids causing inadequately weighted 41CV (Figure 1), calculates the thickness of concrete weight pipelines to pop up. There are various government entities coating for submarine pipelines expeditiously and with that have jurisdiction over navigable rivers, bays, marshlands, satisfying results. and offshore waters. These agencies may stipulate that The prompting feature (Figure 2) is employed to aid pipelines be buried at certain depths and be stabilized. users' data input. Important calculated values and a recap of A good way to stabilize a pipeline is to use an adequate the inputs are printed out, and each quantity is identified. concrete weight coating. Determining the thickness of the Thus, the tape is a complete record. The program is flexible concrete involves a process of balancing upward forces such in that any inputs can be readily changed for a second run. as buoyancy of the mud and the downward forces—weights Thus, many quot;what i f questions can be answered quickly. of pipe, protective coating, and concrete, allowing a factor of Suppose a heavier-weight pipe is used? What if the 60 (negative buoyancy). Such computations with several concrete density is changed? If the negative buoyancy is variables can become involved and tedious. reduced? Etc. 8ULBL -COHCquot; 37 RCL 15 73 * 188 STO 85 144 STO 18 177 -T=- 213 -SP GR=- 82 ODV 38 RCL 17 74 + 189 RCL 15 145 RCL 21 178 PRCL 85 214 RRCL 14 63 SF 12 39 + 75 Xt2 118 quot;D=? quot; 146 -T INCR=? • 179 PVIEH 215 RVIEU 94 quot; CONCRETE1 40 LPSTX 76 .8855 111 PRCL 15 147 RRCL 21 188 CLR 216 CLP 05 -h COPTIHGquot; 41 * 77 • 112 PROMPT 148 PROMPT 181 quot;HPC=- 217 PDV 96 PRfl 42 .0213 78 STO 12 113 CLP 149 CLR 182 RRCL 86 218 -D=- 97 PDV 43 • 79 RCL 28 114 STO 15 158 STO 21 183 RVIEU 219 RRCL 15 88 CF 12 44 RCL 13 88 • 115 RCL 16 151 RCL 11 184 CLR 228 PVIEU 89 quot;T TRIPL=?quot; 45 • 81 STO 89 116 quot;HP=? quot; 152 quot;NEG BUOY=? - 185 quot;HC=- 221 CLP 18 PROMPT 46 STO 86 82 RCL 08 117 PRCL 16 153 PRCL 11 186 RRCL 87 222 -HP=- 11 STO 95 47 RCL 15 83 X O Y 118 PROHPT 154 PROMPT 187 RVIEH 223 RRCL 16 12 'PIPE DIPH=?quot; 43 RCL 17 84 - 119 CLP 155 CLP 188 CLP 224 PVIEH 13 PROHPT 49 2 85 STO 10 128 STO 16 156 STO 11 189 quot;HT=- 225 CLR 14 STO 15 58 • 86 FS? 81 121 RCL 17 157 GTO 01 198 RRCL 88 226 quot;TH PC=quot; 15 quot;PIPE WT=?quot; 51 + 87 GTO 03 122 -TH PC=? - 191 RVIEU 227 PRCL 17 16 PROHPT 52 RCL 85 88 RCL 11 123 PRCL 17 158*LBL 02 192 CLR 228 RVIEH 17 STO 16 53 + 89 X=8? 124 PROHPT 159 RCL 21 193 quot;HHD=quot; 229 CLP 13 quot;PROT CT TH=?quot; 54 LPSTX 98 GTO 84 125 CLR 168 ST+ 85 194 RRCL 89 238 -DC=quot; 19 PROHPT 55 * 91 RCL 18 126 STO 17 161 GTO 81 195 RVIEU 20 STO 17 56 .8213 92 RCL Ii 127 RCL 19 196 CLR 231 PRCL 19 21 -DEN CONC=?quot; 57 • 93 X<=Y? 128 quot;DC=? quot; 162*LBL 83 197 -HT-HHD=quot; 232 PVIEH 22 PROHPT 58 RCL 19 94 GTO 83 129 PRCL 19 163 RCL 88 198 RRCL 18 233 CLP 23 STO 19 59 • 95 GTO 82 138 PROHPT 164 RCL 12 199 RVIEU 234 -DH=quot; 24 quot;DEN MUD=?quot; 68 STO 87 131 CLR 165 / 288 CLR 235 RRCL 28 25 PROMPT 61 RCL 16 96*LBL 84 132 STO 19 166 STO 13 201 -NEG BUOY=- 236 PVIEU 26 STO 28 62 + 97 RCL 09 133 RCL 28 167 62.4 282 RRCL 11 237 CLP 27 quot;DEN PROT CT=?quot; 63 RCL 86 98 RCL 88 134 quot;DH=? • 168 / 283 RVIEH 238 quot;DPC=quot; 28 PROHPT 64 + 99 X)Y? 135 PRCL 28 169 STO 14 284 CLR 239 RRCL 18 29 STO 18 65 STO 88 188 GTO 83 136 PROHPT 285 quot;VT=- 248 PVIEU 38 -T INCR=?quot; 66 RCL 15 181 GTO 82 137 CLR 178*LBL -DPTP- 286 RRCL 12 241 CLP 31 PROMPT 67 RCL 17 182*LBL 85 138 STO 28 171 PDV 207 RVIEU 242 -T INCR=- 32 STO 21 68 2 183 RCL 85 139 RCL 18 172 CLR 288 CLP 243 RRCL 21 33 -NEG BUOY=?quot; 69 • 184 -T=? quot; 148 quot;DPC=? quot; 173 quot;RESULTS-quot; 289 -BULK DEN=quot; 244 PVIEU 34 PROHPT 70 + 185ftRCL85 141 PRCL 18 174 -I-RECPP.- 218 RRCL 13 245 CLP 35 STO 11 71 RCL 85 186 PROMPT 142 PROMPT 175 RVIEH 211 RVIEU 246 BEEP 36*LBL 81 72 2 187 CLP 143 CLP 176 PDV 212 CLR 247 END Figure 1. Hewlett Packard-41CV computer program.
  • 3. Nomenclature and storage registers inputs RESULTS-RECAP. T=4.625e Reg. no. HPC=4.6885 HC=479.3309 05 T = Concrete thickness, in. Assume trial WT=578.6385 value. Final answer is cumulated in MHD=553.4462 Reg. 0.5. HT-HHD=25.1843 HEG BUOY=20.89ee 15 D = Pipe diameter, in. VT=6.1494 BULK DEN=94.8954 16 WP = Weight of pipe, lb/lf. SP GR=1.5979 5=24.8869 17 TH PC = Thickness of protective coating. HP=94.6288 Usually 3/32 in. or 0.0938 in. TH PC=8.8938 DC=165.8808 19 DC = Density of concrete, lb/cu ft. Usually DH=98.0888 DPC=95.6888 140, 165, 190. T IHCR=8.1258 20 DM = Density of mud or fluid, lb/cu ft. River mud is around 90. Figure 2. Most common questions asked when checking 18 DPC = Density of protective coating buoyancy. coating, lb/cu ft. 95 is average. 21 T INCR = Increment of T. Decimal of in. 0.125 is suggested for numerical precision— Formulas not that a tolerance of this order can be constantly achieved in the WPC = (D + (THPC))(THPC)0.0218(DPC) pipe coating world. Increment can be WC = (D + 2(THPC) + T)T 0.0218(DC) made smaller, if desired. 11 NEG BUOY = Negative buoyancy. Desired minimum VT = (D + 2(THPC) + 2T)20.0055 value, lb/lf. Can be 0 in special WMD = (VT)(DM) circumstances—e.g., to ascertain if a given pipe will float in water, or will a Note: The user is encouraged to employ the most reliable certain coated pipe sink in mud? and suitable data available, such as the density of protective coating, mud, and concrete. Each value keyed in is printed on the tape as a check of inputs and the program prompting feature queries user for Examples value of next named input (Figure 2). Put program into calculator, XEQ Size 30. The printed RESULTS-RECAP portions of each of three examples are Calculated values given. When the user XEQ quot;CONCquot; and inputs the data from the lower part of the tabulation, he or she will get the same calculated values above. Reg. no. Figure 2 includes the most common questions asked 06 WPC = Weight of protective coating, when checking coating buoyancy. Always be sure flag 01 is clear XEQ quot;CONCquot; and put in new trial T and R/S. Also R/S lb/lf. after all other inputs. After all prompted data are keyed 07 WC = Weight of concrete coating, lb/lf. in, the processing starts and results are printed out. Notice 08 WT = Total weight—pipe and coatings, lb/lf. T = 4.6250 in. has an actual negative buoyancy of 25.1843. If 09 WMD = Weight of mud (fluid) displaced, lb/lf. T = 4.5 in., the actual negative buoyancy= 18.4510, which is less than 20. A precise solution is between 4.5 in. and 4.625 in. 10 WT-WMD = Actual negative buoyancy, lb/lf. If the user wants to find T, which produces an actual 12 VT = Total volume displaced by pipe and negative buoyancy nearer 20: STO 4.5 in RO 5, STO § in. coatings, cu ft/If. (0.0625 in.), in R21, XEQ 01. This produces T = 4.5625 13 BULK DEN = Bulk density, wt/vt.lb/cu ft. where actual negative buoyancy is 1.8113 greater than 20. 14 SP GR = Specific gravity, bulk den/den water. This refinement can be found in choosing small T INCR. Note that the weight of the concrete coating is now 471.8269 lb/lf and we have approached closer to 20.
  • 4. Calculated values. Weight of protective coating and RESULTS-RECAP concrete, total weight and volume of pipe, and coatings per linear foot will be of value in transporting coated pipe, etc. T=3.2598 HPC=3.9834 Note: Results—RECAP of any run (which is in storage) MO273.9914 can be reprinted as often as desired by XEQ quot;DATA.quot; HT=375.7248 If NEG BUOY is 0 and flag 01 is not set, then the program HHD=352.5529 HT-MHB=23.1728 causes WT to approach WMD and calculates for this NEG BUOY=28.8880 situation. VT=3.9173 BULK DEN=95.9154 If a printer is not available, results can be obtained as SP GR=1.5371 follows: 11=28.8888 1. XEQ 05, put in data and R/S after each item. «P=97.8380 TH PC=6.8938 2. When beep sounds, RCL registers one by one in order DC=165.8900 given above (so as to identify values). BH=90.8«90 DPC=95.9098 Figure 3 illustrates the changing of two input values: T IHCR=B.1250 namely the pipe diameter and weight. The XEQ 05 routine calls up the contents of the input registers one at a time and Figure 3. Changing of two input valves. questions them. Always put in a new T value. Then R/S. When D = ? comes up, key in new value and R/S. Same with pipe WT = ?. Assume other data remain unchanged, XEQ quot;DflTfiquot; R/S each time. (Any one value or any combination of values RESULTS-RECAP. BULK BEN=46.9065 may be changed before rerunning the program.) SP GR=0.7517 Figure 4 determines if a given pipe, 14 in. at 36.71 lb/lf T-e.eeee UPC-21.3368 6=14.0800 and 1A in. of protective weight coating density of 135 lb/cu ft, HP=36.7180 №=8.0000 will float. T, DC, T INCR, and NEG BUOY are all zero. DM HT=58.8463 TH PC=8.5000 becomes the density of water 62.4. Set flag 01 and XEQ 05. HHD=77.2280 BPC=135.0880 HT-WHB=-19.1733 BC=8.8000 Key in data and R/S. When all data are in place only one NEG BUOY=0.0080 BH=62.4000 computation is allowed, then printed out. WT-WMD tells us VT=I.2375 T INCR=0.0000 the upward forces exceed the downward forces by 19.1733 Figure 4. Result of calculations to determine whether the pipe lb/lf; also the specific gravity is 0.7517, so the pipe floats. will float. Also note that BULK DEN is less than the density of water. National Association of Pipe Coating Applications (NAPCA) specifications* RECOMMENDED SPECIFICATION DESIGNATIONS FOR ENAMEL COATINGS These are recommended enamel coating system designations for SPECIFICATION coal tar or asphalt coatings, except for specialty requirements. SYMBOL FIBERGLASSWRAP POLYETHYLENE 93.75 MILS MIN. HEAVY KRAFT #15 FELT WRAP WITH KRAFT ELECTRICAL SHOT BLAST INSPECTION GLASS MAT SEAL COAT •PART *1 •• PART #2 ENAMEL PRIMER PAPER *NOTE: These are not all the specifications approved by NAPCA. For other specifications, consult an NAPCA member.
  • 5. AGSF- TGM- AGM- TGMF- AGMF- TGMP- AGMP- # P A R T # 1 SYMBOLS- • # P A R T # 2 SYMBOLS ENAMEL & WRAPPERS GRADESOF ENAMEL 3— Fully-Plasticized Coal Tar T-Coal Tar G-Fiberglass A-Asphalt S-Seal Coat (ordered by penetration F-#15 Felt GM-Glass Mat dictated by ambient temperature) P—Polyethylene wrapper 4— High Temperature Surface Coa! Tar w/kraft paper 7 - Asphalt O—Outer wrap To specify Outer Wrap, use EXAMPLE: 93.75 mils (minimum) fully-plasticized coal tar enamel letter O in place of F. wrapped with fiberglass, felt and kraft — the symbol would be TGF-3. Reprinted courtesy of National Association of Pipe Coating Applicators. STANDARD APPLIED PIPE COATING WEIGHTS FOR NAPCA COATING SPECIFICATIONS Refer to NAPCA 1-65-83 Spec. Symbol PIPE Weight in Pounds-Per 100 Lineal Feet SIZE (continued on next page)
  • 6. (table continued) Spec. Symbol PIPE Weight in Pounds - Per 100 Lineal Feet SIZE Al! weights provide for standard cutbacks. Weights per 100 lineal feet are figured on the following material weights per square foot of pipe surface: Weight Weight Lbs.-Per Lbs.-fer Sq. Ft. Sq. Ft. Coal Tar Primer & Enamel—1/32quot; Min. .2461 #15 Pipeline Felt Coal Tar Primer & Enamel-2/32quot; Min. .4850 (Tar or asphalt saturated) 1271 Coal Tar Primer & Enamel—3/32quot; Min. .7238 Outerwrap 1225 Asphalt Primer & Enamel—1/32quot; Min. .2000 .010 Fiberglass Wrap 0110 Asphalt Primer & Enamel—2/32quot; Min. .3950 Kraft Paper 0200 Asphalt Primer & Enamel—3/32quot; Min. .5912 Glass Mat 0114 Polyethylene 0450 Reprinted courtesy of National Association of Pipe Coating Applicators. NAPCA SPECIFICATIONS PIPELINE FELTS PROPERTY #15TAR #15 TAR #•15 ASPH. #15 ASPH. N.R. R.F. N.R. R.F. Saturated FaIt - Not Parforatad Weight (MIn.) lbs. per 100 s.f. 12 12 12 12 (ASTM-D-146-59 Sec. 1-9) Saturation (Percent) MIN. 18 18 22 22 (ASTM-D-146-59 Sec. 18 MAX. 28 28 40 40 by extraction) Ash Content (MIN).) (Percent) 70 70 70 70 (ASTM-D-146-59 Sec. 21) Callper (Min.) (inches) .021 .018 .021 .018 (ASTM-D-645-64T Method C) Tensile Strength (Min.) (lbs. per Inch of width) JASTM-D-146-59 Sec. 12a) With fiber grain 35 37 35 37 Across fiber grain 12 No. spec. 12 No. spec. Tear Strength (Min.) (Grams) (ASTM-D-689-62) Across fiber grain 400 Not 400 Not With fiber grain 240 applicable 240 applicable (continued on next page)
  • 7. Loss on heating (Max.) (Percent) 10 10 10 10 (AWWA C203-66 Sec. 2.6.6) Pliability (AWWA C203-66 Sec. 2.6.4) No cracking No cracking No cracking No cracking Saturated and Perforated Felt (1/16quot; perforations on 1 quot; Staggered Centers) Tensile Strength (MIn.) (lbs. per inch of width) (ASTM-D-146-59 Sec. 12a) With fiber grain 30 35 30 35 Across fiber grain 10 No spec. 10 No. spec. Tear Strength (MIN.) (Grams) (ASTM-D-689-62) Across fiber grain 348 Not 348 Not With fiber grain 190 applicable 190 applicable Umaturated Felt Asbestos Content (%) (MIN.) (ASTM-D-1918-67) 85 85 85 85 N.R. —NON REINFORCED R.F. — REINFORCED LENGTHWISE WITH PARALLEL FIBER GLASS YARNS ON NOMINAL ¥•quot; CENTERS. Reprinted courtesy of National Association of Pipe Coating Applicators. Minimum Test Voltages for Various Coating Thicknesses Coating Thicknesses 32nd Inch Mils Test Volts Reprinted courtesy of National Association of Pipe Coating Applicators. How much primer for a mile of pipe? Multiply pipe O.D. by 2% to get gallons of primer per Pipe 41Z2 in. in diameter will take 41Z2 x 2% or 123/8 gallons mile. of primer per mile (12 gallons in round figures). The given multiplier is applicable only where the pipe is new and in good condition. For rough pipe the multiplying factor should be upped from 2% to 3.45. In other words, Examples. rough 20-in. pipe will require 20 x 3.45 or 69 gallons of Pipe 24 in. in diameter will require 24 x 2% or 66 gallons primer per mile. of primer per mile; It is hard to estimate the amount of spillage and waste. Pipe 16 in. in diameter will require 16 x 2% or 44 gallons Temperature and relative humidity affect the way the primer of primer per mile; and goes on the pipe.
  • 8. How much coal-tar enamel for a mile of pipe? For an average cover of %2 in., multiply outside 8.625 x 0.6 =5.2 tons per mile diameter of pipe by 0.6. The answer is in tons of enamel 5.2x15% =0.8 per mile. (Add 15% to take care of gate valves, drips, bends, = 6 tons per mile etc.) These factors strongly affect the amount of coating used per mile on pipelines: 1. Temperature of the pipe and Examples. How many tons of coal-tar enamel will be ambient temperatures. (It is assumed that the temperature required to apply a %2-in. coat to a 26-in. pipeline? of the enamel can be controlled.) 2. The kind of dope 26 x 0.6 = 15.6 tons per mile machine. 3. Humidity. 4. The number of bends per mile. 5. The number of valves, crossovers, etc. 6. Condition of the Add 15% to take care of gate valves, bends etc. pipe. This latter point has a great effect on the amount of 15.6 + 2.3 = 17.9 or 18 tons per mile enamel required for a mile of pipeline. In fact, where How many tons of coal-tar enamel will be required to reconditioned pipe is being coated, it is recommended that apply a %2~in- coat to a 8.625-in. pipeline? the amount of enamel be increased by about 20%. How much wrapping for a mile of pipe? For 14-in. to 48-in. pipe multiply the diameter in inches (4 + 1) x 15 = 75 squares of felt by 15 to get the number of squares (100 ft ). For pipe sizes These figures are conservative and do not allow for of 12% in. and smaller, add 1 to the nominal size of pipe and wrapping drips, for patching holidays, and for short ends that multiply by 15. are usually discarded. They allow for machine wrapping Examples. How many squares of asbestos felt would be using /^-in. lap on diameters up to 10/4 m - a n d using 1-in. lap required to wrap 1 mile of 30-in. pipeline? on larger diameters. 30 x 15 = 450 squares of felt For smaller diameters of pipe, this figure should be increased about 5% to take care of additional wastage and How many squares of felt would be required to wrap 1 patching. mile of 4-in. pipe? Estimating coating and wrapping materials required per mile of pipe Nominal Glass Kraft 15-Pound Primer and coal-tar enamel Pipe Primer Coal-tar Wrap Paper Felt Size Gallons Enamel Squares Squares Squares Tons Gallons of primer and tons of coal-tar enamel are based on covering new pipe in good condition. For rough pipe, increase primer quantities by 25% and the coal-tar quantities by 20%. No allowance is included for spillage or waste. Wrappings Squares are based on machine wrapping, allowing /4-in. laps on pipe sizes through 10 in. and 1-in. laps on pipe sizes greater than 10 in. No allowance is included for wrapping drips, patching holidays, or short ends, which are usually discarded.
  • 9. Coefficient of friction for pipe coating materials Tests indicate that previous values appear to be valid for thinfilm epoxies and conservative for coal tars J. B. Ligon, Assistant Professor, Mechanical Engineering-Engineering Mechanics Dept., Michigan Technological University, Houghton, Mich., and G. R. Mayer, Project Engineering Manager, Bechtel, Inc., San Francisco A major factor in the stress analysis of buried pipelines is where: F = Longitudinal soil friction force (Ib) the movement that pipe undergoes in the presence of tem- /ji = Coefficient of friction (dimensionless) perature and pressure differentials during its life. This move- p = Normal soil pressure acting on the pipe ment is highly dependent upon friction resistance of the soil. surface (psi) Although ample information is available on the static dA = Soil to pipe differential contact area (in.2) coefficient of friction for many materials, there is a lack of fA pdA = Total normal soil force on pipe surface (Ib) data on friction between soils and various coatings used in The above relation is independent of the pressure per unit the pipeline industry. In the past, friction coefficient area of the mating surfaces as long as very high contact information was extrapolated from data in the literature pressures are not encountered, which is the case for a buried that were believed to have a similarity to the external pipe pipeline. coating to soil interface. In terms of a buried pipeline supporting a soil burden up However, with the development of thinfilm epoxy resin to three pipe diameters of depth, the soil force relation coating systems and the increasing use of these systems in becomes: the pipeline industry, a change from a conventional coal tar felt coating to a thinfilm epoxy coating would indicate a significant change in the friction coefficient design criteria due to the extreme contrast in the surface texture of the two materials. To evaluate the effect of the difference in surface texture where: Wp = Weight of pipe and contents (lb/in.) on a pipeline system, test procedures were developed to D = Pipe diameter (in.) determine the coefficient of friction for both coal tar felt and H = Depth of the pipe centerline (in.) thinfilm epoxy to various soils and to obtain more reliable Y = Specific weight of the soil (lb/in.3) information for future pipeline designs using these coating The sensitivity of the soil friction forces to the coefficient materials. of friction is readily apparent from the above relation. Since Static friction tests were conducted to find the coefficient this force is inversely proportional to the active length that a of friction between coal tar felt and thinfilm epoxy pipe pipeline moves as a result of temperature and pressure coating and eight representative backfill soil samples from expansion, the coefficient of friction becomes a major factor typical locations along a pipeline right of way. The results in pipeline stress design. indicate that the friction coefficients are significantly larger than those previously extrapolated from literature and that Test system. The theoretical soil friction force acting on coal tar has a higher friction resistance in respect to the surface of a coated plate can be calculated from the anchorage of a pipeline. relation: For the coal tar felt coating, the coefficient varies from 0.59 to 0.91 depending on the soil and moisture content. The F = ^N thinfilm epoxy coating varies from 0.51 to 0.71 under the same conditions. where: N = Normal force acting on the plate surfaces (Ib) W = Total weight of plate and external load (Ib) Definitions Static coefficient of friction. The theoretical long- itudinal soil force acting on the pipe surface can be COATED PLATE calculated from the relation:
  • 10. Since the coefficient of friction parameter is the same in Thinfilm epoxy. The epoxy coating simulated a thinfilm all of the previous expressions, the plate test system can be epoxy resin pipeline coating applied by the fusion method. used to simulate the soil-to-pipeline interface. Plates used in the tests were coated by the fluidized bed method. However, the surface texture was the same as that expected by coating plant production equipment. Coal tar felt. The coal tar coating, an enamel and felt combination, was prepared to simulate an actual coated Results pipeline. The surface of a steel plate was coal tar coated and then Coal tar to soils. Figure 1 illustrates that the friction wrapped in a 15-lb felt. Therefore, the soil surface contact coefficient varies from 0.59 to 0.91 for the various soils tested was predominantly with the felt material. at field moisture content. LOCATION SOIL DESCRIPTION MOISTURE SANOY SIiT (ML) SiLTY SAND {SM> SItT ( M t I SiLTY SAND (SM) SIlTY SANO (SM) SAND - SILT (SM) SANDY SILT (ML) SlLTY • SAND (SM) UMlFiED SGlL CLASSIFICATION SYMBOL Figure 1. Coefficient of friction for coal tar coating to soil. LOCATION SOiI OESCWPTiON MOISTURE SANDY SiIT (ML) 1 SiLTY SANO (SM) SfLT |ML) SIlTY SAND (SM) SlLTY SANO CSM) SAND-SO (SM) SANDY SILT (ML) SILTY SAND (SM) SRAVa-SAKO SILT (GM) UNFIEO SOIL CtASSJFiCATiON SYMBOL Figure 2. Coefficient of friction for thin film epoxy to soil.
  • 11. The mechanism by which the friction coefficient changes Since such information on this coating was not available in among the various soils is not apparent from the results of the literature, no comparison to similar tests could be made. these tests, since the soil samples used did not vary Temperatures in the 1200F range should have little or no considerably in description. However, the range over effect on the coefficient of friction of epoxy to soil. which the factor changes is considerably greater than that previously extrapolated from the literature, as follows: Conclusions Coefficient of friction Soil description commonly used Although it is virtually impossible to precisely simulate the surface contact situation of a pipeline in a back-filled trench, Silt 0.3 the test procedure and apparatus reported here are a means Sand 0.4 of approximating it. The results indicate that coal tar coatings Gravel 0.5 have a higher friction resistance than epoxy coatings as far as anchoring capabilities of the soil are concerned. The tests also indicate that the moisture content alters the The selection of a coating, based on its soil friction friction factor to some extent, as would be expected. resistance, could be of economic value in reducing those In order to investigate the influence of temperature, tests situations where extreme expansions call for reinforced were conducted with coal tar felt wrapping heated to 1200F. fittings or elaborate culverts to overcome excessive stress Only a slight softening beneath the coating surface was levels in a pipeline system. observed, and it is believed that temperatures up to this The test results show that previous values commonly used range will not significantly affect the magnitude of the for the coefficient of friction were conservative for similar friction coefficient. soils, and it is suggested that some conservatism still be incorporated in future analyses. Since the tests indicated that the friction coefficient of the Thinfilm epoxy to soils. As expected, results shown in epoxies was similar to those previously used for coal tar Figure 2 indicate that the friction factor range of 0.51 to 0.71 coatings, their continued use for epoxy-coated pipelines for the epoxy is somewhat lower than that of the coal tar. should be valid. A more conservative approach to these Again, the mechanism is not clear, but the results are fairly values is recommended in soils where the presence of consistent with the friction coefficient increasing in most excessive moisture could change the friction factor substan- instances in the same order of magnitude as for coal tar. tially when interfaced with a smooth epoxy coating. Troubleshooting cathodic protection systems: Magnesium anode system The basic technique is the same as that outlined earlier; more measurements are required because of the multiplicity of drain points. First, the current output of stations nearest the point of low potential should be checked; if these are satisfactory, a similar check should be extended in both directions until it is clear that the trouble must be on the line. When a given anode group shows a marked drop in current output, the cause may be drying out, shrinkage of backfill, or severed or broken lead wires. If the current is zero, the pipe-to-soil potential of the lead wire will show whether it is still connected to the pipe or the anode, and < Broken Wire • thus indicate the direction to the failure. If the current is Figure 1. Locating idle anodes by surface potentials. The solid low, there may be a loss of one or more anodes by a line shows the potentials found along a line of anodes when all severed wire; a pipe-to-soil potential survey over the anodes are delivering current; the dotted line exhibits the change when will show which are active, just as in the case of rectifier there is a break in the anode lead at the point indicated. Single disconnected anodes may also be located by this method. A anodes. driven ground rod, a pipe lead, or even a rectifier terminal may Trouble indicated on the line, rather than at the anode be used for the reference ground; all readings should be stations, is tracked down in the same manner as that used for referred to the same reference.
  • 12. line protected by rectifiers—first, investigating locations next, checking potentials; and finally, making a line current where something that has been done might be responsible; survey. Cathodic protection for pipelines Estimate the rectifier size required for an infinite line. Use a value of—0.3 volts for AE x . This is usually enough Refer to Figure 1. If coating conductance tests have not been to raise the potential of coated steel to about—0.85 volts. performed, pick a value from Table 1. Use a value of 1.5 volts for AE at the drain point. Higher values may be used in some circumstances; however, there may be a risk of some coating disbondment at higher Table 1 voltages. Typical Values of Coating Conductance Calculate I at the drain point. Micromhos/sq ft Coating Condition 1-10 Excellent coating—high resistivity soil AI A = amp./in. x AE x /0.3 x D 10-50 Good coating—high resistivity soil 50-100 Excellent coating—low resistivity soil 100-250 Good coating—low resistivity soil where D = pipe OD, inches. 250-500 Average coating—low resistivity soil Example. 30-in. OD line with coating conductivity= 100 500-1,000 Poor coating—low resistivity soil micromhos/sq ft. What is the current change at the drain Based on 0.25-inch wall pipe and steel resistivity of 18.8 microhm-cm _* x — , amperes per inch D AEx Thousands of Feet, x Figure 1. Drainage current versus distance for a coated infinite line.
  • 13. Based on 0.25-inch wall pipe and steel resistivity of 18.8 microhm-cm — x — , amperes per inch . u D AEJ IA 0 3 Thousands of Feet, L Figure 2. Drainage current versus distance for a coated finite line. point, and how far will this current protect an infinitely long micromhos/sq ft. What is AE A /E T and what AI A is required? pipeline? Assume that AE A = 1.5 E x = 0.3 AE x = 0.3 From Figure 2 read AE A /AE x = 5.0 AE A /E X = 5.8 AE A = 1.74 Refer to Figure 1 and read AI A /D x 0.3/E x = 1.8 amp./in. L = 30,000 ft AI A =1.8 x 3.5 = 6.3 amp. AIA/D x 0.3/AEx = 0.7 (from Figure 1) Estimate ground bed resistance for a rectifier AIA = 0.7x 30 = 21 amp. installation. 21 amps will protect the line for 30,000 ft in either direction Example. A ground bed for a rectifier is to be installed from the drain point. in 1,000 ohm-cm soil. Seven 3-in. x 60-in. vertical graphite Estimate rectifier size for a finite line. Refer to Figure 2. anodes with backfill and a spacing of loft will be used. What A 31Z2 -in. OD line 20,000 ft long is protected by insulating is the resistance of the ground bed? flanges at both ends and has a coating conductivity of 500 Refer to Figure 3. The resistance is 0.56 ohms.
  • 14. Anode Bed Resistance, R A (ohms) Anode Spacing Figure 3. Anode bed resistance versus number of anodes. 3-in. x 60-in. vertical graphite anodes in backfill. Number of Anodes Anode Resistance, RA (ohms) Figure 4. Anode bed resistance versus number of Anode anodes. 2-in. x 60-in. vertical bare anodes. Spacing Number of anodes Figure 3 is based on a soil resistivity of 1,000 ohms-cm. If soil resistivity is 3,000 ohms-cm. What is the ground bed the soil resistivity is different, use a ratio of the actual soil resistance? Refer to Figure 4. The resistivity from the chart resistivity divided by 1,000 and multiply this by the reading is 0.55 ohms. Since the chart is based on soil resistivity of obtained from Figure 3. 1,000 ohms-cm, the ground bed resistivity is 3,000/1,000 x A rectifier ground bed is to be composed of 10 — 2 x 0.55 or 1.65 ohms. 60-in. bare quot;Durironquot; silicon anodes spaced 20 ft apart. The
  • 15. The resistance of multiple anodes installed vertically and Figure 5 is based on Equation 1 and does not include the connected in parallel may be calculated with the following internal resistivity of the anode. The resistivity of a single equation: vertical anode may be calculated with Equation 2. R = 0.00521P/NL x (2.3 Log 8L/d - 1 + 2L/S Log 0.656N) R = 0.00521P/L x (2.3 Log 8L/d - l) (2) (1) If the anode is installed with backfill, calculate the where: resistivity using the length and diameter of the hole in R = Ground bed resistance, ohms which the anode is installed. Calculate the resistivity using P = Soil resistivity, ohm-cm the actual anode dimensions. The difference between these N = Number of anodes two values is the internal resistance of the anode. Use the d = Diameter of anode, feet value of P, typically about 50 ohm-cm, for the backfill L = Length of anode, feet medium. S = Anode spacing, feet Figure 5 is based on 1,000 ohm-cm soil and a 7-ft x 8-in. hole with a 2-in. x 60-in. anode. If the anode is installed with backfill such as coke breeze, use the diameter and length of the hole in which the anode is Example. Determine the resistivity of 20 anodes installed installed. If the anode is installed bare, use the actual vertically in 1,500 ohm-cm soil with a spacing of 20 ft. dimensions of the anode. Read the ground bed resistivity from Figure 5. Anode Bed R e s . Ohms Spacing Number of Anodes Figure 5. Anode bed resistance.
  • 16. R = 0.202 ohm either in standard alloy or high purity alloy. Galvanic anodes are usually pre-packaged with backfill to facilitate Since the anodes are to be installed in 1,500 ohm-cm soil and their installation. They may also be ordered bare if desired. Figure 5 is based on 1,000 ohm-cm soil, multiply R by the Galvanic anodes offer the advantage of more uniformly ratio of the actual soil resistivity to 1,000 ohm-cm. distributing the cathodic protection current along the pipeline, and it may be possible to protect the pipeline R = 0.202 x 1,500/1,000 with a smaller amount of current than would be required with an impressed current system but not necessarily at a R = 0.303 ohm lower cost. Another advantage is that interference with other structures is minimized when galvanic anodes are used. The internal resistivity for a single 2-in. x 60-in. vertical Galvanic anodes are not an economical source of cathodic anode installed in 50 ohm-cm backfill (7ftx8-in. hole) is protection current in areas of high soil resistivity. Their use is 0.106 ohm. generally limited to soils of 3,000 ohm-cm except where Since 20 anodes will be installed in parallel, divide the small amounts of current are needed. resistivity for one anode by the number of anodes to obtain Magnesium is the most-used material for galvanic anodes the internal resistivity of the anode bank. for pipeline protection. Magnesium offers a higher solution potential than zinc and may therefore be used in areas of 0.106/20 = 0.005 ohm higher soil resistivity. A smaller amount of magnesium will generally be required for a comparable amount of current. Refer to Figure 6 for typical magnesium anode performance The total resistivity of the 20 anodes installed vertically will data. These curves are based on driving potentials of —0.70 therefore be 0.308 ohm (0.303 + 0.005). volts for H-I alloy and —0.90 volts for Galvomag working against a structure potential of —0.85 volts referenced to copper sulfate. Galvanic Anodes The driving potential with respect to steel for zinc is less than for magnesium. The efficiency of zinc at low current Zinc and magnesium are the most commonly used levels does not decrease as rapidly as the efficiency for materials for galvanic anodes. Magnesium is available magnesium. The solution potential for zinc referenced to a Soil Resistivity - Ohms-Cm. Anode Current - Milliamperes Figure 6. Magnesium anode current.
  • 17. 1 Anode 2 Anodes 3 Anodes 4 Anodes 8 Anodes Six Anodes Soil Resistivity Ohms-Cm Spacing 15 ft. 1.4 In.xl.4 In. By 5 Ft. Long Current Output M i l l i a m p e r e s Figure 7a. Current output zinc anodes. Soil Resistivity Ohms-Cm Spacing 15 f t . 1.4-In.xi.4-In. B 5 - f t . Long y Current Output M i l l i a m p e r e s Figure 7b. Current output zinc anodes.
  • 18. Water Resistivity Ohms-Cm Spacing 15 ft. l.4-In.xl.4-In. Jy 5-ft. Long Current Output M i l l i a m p e r e s Figure 8a. Current output zinc anodes. Anode Bed Resistance, RA (ohms) Anode Spacing Number of Anodes Figure 8b. Current output zinc anodes.
  • 19. copper sulfate cell is —1.1 volts; standard magnesium has a have an efficiency of 50% at normal current densities. solution potential of —1.55 volts; and high purity magnesium Magnesium anodes may be consumed by self-corrosion if has a solution potential of —1.8 volts. operated at very low current densities. Refer to Figures 7a, If, for example, a pipeline is protected with zinc anodes at 7b, 8a, and 8b for zinc anode performance data. The data in a polarization potential of —0.9 volts, the driving potential Figures 7a and 7b are based on the anodes being installed in will be —1.1 — (—0.9) or —0.2 volts. If standard magnesium is a gypsum-clay backfill and having a driving potential of —0.2 used, the driving potential will be —1.55 —(—0.9) or —0.65 volts. Figures 8a and 8b are based on the anodes being volts. The circuit resistance for magnesium will be approxi- installed in water and having a driving potential of —0.2 mately three times as great as for zinc. This would be volts.1 handled by using fewer magnesium anodes, smaller anodes, Example. Estimate the number of packaged anodes or using series resistors. required to protect a pipeline. If the current demands for the system are increased due to What is the anode resistance of a packaged magnesium coating deterioration, contact with foreign structures, or by anode installation consisting of nine 32-lb. anodes spaced 7 ft oxygen reaching the pipe and causing depolarization, the apart in 2,000 ohm-cm soil? potential drop will be less for zinc than for magnesium Refer to Figure 9. This chart is based on 17# packaged anodes. With zinc anodes, the current needs could increase anodes in 1,000 ohm-cm soil. For nine 32-lb. anodes, the by as much as 50% and the pipe polarization potential would resistivity will be: still be about 0.8 volts. The polarization potential would drop to about 0.8 volts with only a 15% increase in current 1 x 2,000/1,000 x 0.9 = 1.8 ohm needs if magnesium were used. The current efficiency for zinc is 90%, and this value holds See Figure 10 for a table of multiplying factors for other over a wide range of current densities. Magnesium anodes size anodes. Anode Bed Resistance, RA (ohms) Anode Spacing Number of Anodes Figure 9. Anode bed resistance versus number of anodes; 17# packaged magnesium anodes.
  • 20. Next Page Chart based on 17-Ib. magnesium anodes installed in 1,000 ohm-cm soil in groups of 10 spaced on 10-ft centers. For other conditions multiply number of anodes by the following multiplying factors: For soil resistivity: MF = —£— For 9-lb. anodes: MF = 1.25 For conventional magnesium: MF = 1.3 For 32-Ib. anodes: MF = 0.9 Number of Anodes per 1,000 ft Number of Anodes per Mile Coating Conductivity (micromhos/sq.ft) Figure 10. Number of anodes required for coated line protection. Example. A coated pipeline has a coating conductivity Source of 100 micromhos/sq. ft and is 10,000 ft long, and the diameter is 10/4 in. How many 17-lb magnesium anodes will Pipeline Corrosion and Cathodic Protection, Gulf Publishing be required to protect 1,000 ft? Refer to Figure 7 and read 2 Company, Houston, Texas. anodes per 1,000 ft. A total of twenty 171b. anodes will be required for the entire line. Reference 1. From data prepared for the American Zinc Institute. Estimate the pounds of sacrificial anode material required for offshore pipelines This rule of thumb is based on the following assumptions: life in years = the Ib. of galvanic anode material that will be required. • 5% of pipeline considered bare • 3 milliamperes/sq. ft required for protection • 30-year design life Basis for rule: sq. ft of surface area of pipeline/linear Multiplier = OD x lb./amp.-yr x (12 PI/144) ft x % of bare pipe x 3.0 m.a./sq. ft x lb./amp.-year x design x 30 x 0.05 x 0.003 x 1,000