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Sintered Neo Replacement:
Dysprosium-free Rare Earth Permanent Magnet
Motors
Sintered Neo Replacement

• Fundamentals in dysprosium (Dy) market will result in
  significantly higher prices
   – Increasing demand due to growth in sintered Nd
     market
   – Insufficient supply

• When possible, magnet users should design applications
  with magnets without Dy
   – Magnets using MQPTM grades do not rely on Dy

• Application performance is comparable and can be
  optimized if MQPTM is “designed in”
Rising prices of rare earth metals:
Soaring prices of Dy
Escalating Price of Dy:
Fundamental supply-demand imbalance



High demand                                                               Low output
  in Dy rich sintered neo applications
                                                                           Estimated Production in 2010*
                                                                                           Yttrium
                                                                    Dysprosium    Erbium
                                                                                            11.7%
                                                                       2.4%        1.1%
                                                                                                            Lanthanum
                                                                        Terbium                               24.6%
                                                             Gadolinium   0.6%
                                                               1.6%
                                                               Europium
                                                                 1.0%
                                                                   Samarium
                                                                     2.0%



                                                                       Neodymium
                                                                         20.7%



                                                                                                           Cerium
                                                                                    Praseodymium           29.0%
                                                                                         5.4%



                                   *Source:National Development and Reform Commission (NDRC) Report April 2011
Dy Rich Sintered Applications


                Technology                                   Assumption                     Low Penetration High Penetration

                  Wind       Onshore Wind Turbine Additional Capacity (GW)                        23.6           48.6
                  Wind       Offshore Wind Turbines Additional Capacity (GW)                      4.9             17
Deployment in
                 Vehicles    Sales of Hybrid Electric Vehicles (HEVs) (millions)                   4.2           19.1
    2025
                 Vehicles    Sales of Plug-in Hybrid Electric Vehicles (PHEVs) (millions)        0.002           13.2
                 Vehicles    Sales of All Electric Vehicles (AEVs) (millions)                    0.001            4.6
                  Wind       Onshore Wind Turbines using RE Magnets                               10%            25%
Market Share      Wind       Offshore Wind Turbines using RE Magnets                              10%            75%
                 Vehicles    HEVs, PHEVs, and AEVs using RE Magnet Motors                        100%            100%



                Technology   Assumption                                                      Low Intensity    High Intensity
                   Wind      Average Weight of Magnets per MW (kgs)                              400               600
                 Vehicles    Average Weight of Magnets per vehicle (kgs)                           1                2
   Materials     Wind and
                             % Weight of Magnets that is Neodymium                                31%             31%
   Intensity     Vehicles
                 Wind and
                             % Weight of Magnets that is Dysprosium                              5.50%           5.50%
                 Vehicles

Source: Critical Materials Strategy by U.S Department of Energy (Dec 2010)
http://www.energy.psu.edu/oeo/ree/reports/criticalmaterialsstrategy121710.pdf
Current Rare Earth Types and Content




   Source: Critical Materials Strategy by U.S Department of Energy (Dec 2010)
   http://www.energy.psu.edu/oeo/ree/reports/criticalmaterialsstrategy121710.pdf
Low levels of Dy occurrence


                            Low levels of Dy present
                                    Yttrium
             Dysprosium    Erbium
                                     11.7%
                2.4%        1.1%
                                                                    Lanthanum
                 Terbium                                              24.6%
      Gadolinium   0.6%
        1.6%
        Europium
          1.0%
            Samarium
              2.0%



                Neodymium
                  20.7%



                                                                   Cerium
                             Praseodymium                          29.0%
                                  5.4%

                                         Estimated Production in 2010*

        *Source:National Development and Reform Commission (NDRC) Report April 2011
Possible new sources of Rare Earths:
Dy contents are low

                                                Assumed Additional Production by 2015                                      Total
                                                                                                                         Additional
                 Mountain Pass    Mt. Weld     Nolans Bore    Nechalaco   Dong Pao      Hoidas Lake   Dubbo Zirconia   Production by
                    (USA)        (Australia)    (Australia)   (Canada)    (Vietnam)      (Canada)       (Australia)        2015
Lanthanum            6,640         3,840          2,000         845         1,620          594             585            16,124
Cerium               9,820         6,855          4,820         2,070       2,520          1,368          1,101           28,554
Praseodymium          860           810            590          240         200            174             120             2,994
Neodymium            2,400         2,790          2,150         935         535            657             423             9,890
Samarium              160           360            240          175          45             87             75              1,142
Europium              20             90            40            20          -              18              3              191
Gadolinium            40            150            100          145           -             39             63              537
Terbium                -             15            10            90           -             3               9              127
Dysprosium             -             30            30            35          -              12             60              167
Yttrium               20             60             -           370          35             39             474             998

TOTAL               19,960         15,000         9,980         4,925       4,955          2,991          2,913           60,724




Source: Critical Materials Strategy by U.S Department of Energy (Dec 2010)
http://www.energy.psu.edu/oeo/ree/reports/criticalmaterialsstrategy121710.pdf
Why does Sintered Neo need Dy?


• Sintered neo is much more
  inclined to have a knee in the
  second quadrant engineering
  curve at elevated temperature
   – Due to high remanence
     values of sintered neo
   – Results in irreversible losses
     in motor

• Compensation for this knee,
  motor companies could
   – Increase the magnet length
   – Adding Dy to enhance
     coercivity
Typical Sintered Neo Alloy composition


Type         T.R.E      NdPr      Dy    Gd     Tb       Fe    Co     B    Al
N35H         32.4       27.23     3.3   1.9     0      64.4    1     1    1
N35SH         33        29.64     3.4    0      0      64.8    0    1.1   1
N35UH        32.1       26.92      5    0.2     0       65     1     1    1
N38H         32.2       29.04     3.2    0      0      65.1    1     1    0
N38SH        31.9       28.29     3.6    0      0      65.4    1     1    1
N38UH        31.7       25.62     6.1    0      0      65.8   0.9    1    0
N42H          31        29.3      1.8    0      0      66.5   0.7    1    0
N42SH        30.4       26.66     3.3    0     0.4     66.9    1     1    0
N42UH        31.7       27.24     3.8    0     0.7     65.8   0.9    1    0
N45H         31.4       29.45      2     0      0      66.1   0.9    1    0
N45SH         30        27.06     0.8    0     2.1     67.4   0.9    1    0
N45UH        30.1       26.61     0.8    0     2.7     67.3   0.9    1    0
MQP-B         25.4      25.41     0      -      -      73.4    -    1     -

   Typical sintered Nd grades contain up to 6% of Dy
Advantages of Bonded Neo


• MQPTM has very good
  linearity in the second              25C-MQP-B+-20056        125C-MQP-B+-20056         25C-MQP-14-12    125C-MQP-14-12

  quadrant engineering curve                                                                                               8

  up to temperatures as high as           Load line at stall                                   Load line at no-load
                                                                                                                           7
  150-180oC                                                                                                                6

• Able to achieve equivalent                                                                                               5




                                                                                                                               B (kG)
  performance                                                                                                              4

                                                                                                                           3
• No significant increase in
                                                                                                                           2
  motor size
                                                                                                                           1
• All MQPTM grades are Dy                                                                                                  0
  free!                           -7       -6            -5          -4             -3          -2          -1        0
                                                                          H (kOe)
CASE STUDY    www.mqitechnology.com
Copyright © 2011 Magnequench Neo Powders Pte Ltd
Case Study 1:
Comparison of the Sintered Neo and
Bonded Neo based Motors



                              4-Pole PMDC Motor with   4-Pole PMDC motor with
         Parameter
                               Sintered Neo Magnets     Bonded Neo Magnets
                                4-Arc Sintered neo      Isotropic Bonded Neo
       Type of Magnet
                                     (N35SH)                 (MQP-14-12)
   Total motor weight (gm)            107.80                   143.34
   Length of the motor (mm)           10.00                    12.00
    Overall diameter (mm)             42.00                    46.75
   Total copper weight (gm)           12.70                    23.80
   Total magnet weight (gm)           14.20                    24.94
    Length of Air gap (mm)             0.80                     0.80
   Current at 80 mN-m (A)             11.06                    10.20
  Efficiency at 80 mN-m (%)           73.13                    75.27
Case Study 1:
Chemical Composition and Magnet
Characteristics for Sintered Neo Magnet

                                ICP Test Result
  Element   Nd      Tb     La     Ce       Pr      Sm      Dy      Gd     T.R.E
     %    18.731   0.151   0     0.031   5.862    0.026   2.491   1.680   28.972
Case Study 1:
Comparison of Key Physical Dimensions for the
Sintered Neo and Bonded Neo based Motors




           Sintered Neo Motor   Bonded Neo Motor
Case Study 1:
Comparison of Motor Characteristics for the Sintered Neo
and Bonded Neo based Motors




                                       Torque-efficiency and Torque-output power
                                                     characteristics




     Torque-speed and Torque-current
              characteristics
Case Study 1:
Comparison of Key Physical Parameters and Cost
for the Sintered Neo and Bonded Neo based Motors
Case Study 2:
Comparison of the Sintered Neo and
Bonded Neo based Motors

                               4-Pole PMDC Motor    4-Pole PMDC Motor    4-Pole PMDC motor
         Parameter              with Sintered Neo    with Sintered Neo    with Bonded Neo
                                     Magnets              Magnets             Magnets
                               4-Arc Sintered neo   4-Arc Sintered neo   Isotropic Bonded Neo
       Type of Magnet
                                    (N35SH)                (N35)            (MQP-B+-20056)
         Dy content                   ~3%                0-0.5%                  0%
   Total motor weight (gm)           314.90               451.4                412.50
  Length of the motor (mm)           18.00                23.00                 20.00
    Overall diameter (mm)            57.50                60.72                 63.90
   Total copper weight (gm)          29.80                 21.3                 57.10
  Total magnet weight (gm)           29.10                 56.5                 37.30
    Length of Air gap (mm)            0.55                 0.55                 0.55
   Current at 220 mN-m (A)           11.08                10.55                 11.21

  Efficiency at 220 mN-m (%)         73.76                74.59                 74.09
Case Study 2:
Comparison of Key Physical Dimensions for the Sintered Neo
and Bonded Neo based Motors




   Sintered Neo (35SH)   Sintered Neo (N35)   Bonded Neo Motor
Case Study 2:
Comparison of Motor Characteristics for the
Sintered Neo and Bonded Neo based Motors




                                          Torque-efficiency and Torque-output power
                                                        characteristics




        Torque-speed and Torque-current
                 characteristics
Case Study 2:
Comparison of Key Physical Parameters and Cost for
the Sintered Neo and Bonded Neo based Motors
Case Study-3 – Comparison of the Sintered
Neo and Bonded Neo based Motors


                               4-Pole PMDC Motor    4-Pole PMDC motor
          Parameter             with Sintered Neo    with Bonded Neo
                                     Magnets             Magnets
                               4-Arc Sintered neo   Isotropic Bonded Neo
       Type of Magnet
                               (N27SH or N30SH)          (MQP-14-12)
    Total motor weight (gm)          204.35               237.00
   Length of the motor (mm)          15.50                 19.25
    Overall diameter (mm)            44.10                 49.79
   Total copper weight (gm)          28.09                 18.60
   Total magnet weight (gm)          18.47                 39.80
    Length of Air gap (mm)            0.57                 0.57
   Current at 190 mN-m (A)           27.08                 26.99
  Efficiency at 190 mN-m (%)         74.30                 73.04
Case Study 3:
Chemical Composition and Magnet
Characteristics for Sintered Neo Magnet


                                ICP Test Result
     Element     Nd      La      Ce     Pr   Sm    Dy      Tb      Gd     T.R.E
        %      21.204   0.004   0.028 6.047 0.000 4.087   0.034   0.109   31.479
Case Study 3:
Comparison of Key Physical Dimensions for the Sintered Neo
and Bonded Neo based Motors




             Sintered Neo Motor   Bonded Neo Motor
Case Study 3:
Comparison of Motor Characteristics for the
Sintered Neo and Bonded Neo based Motors




                                   Torque-efficiency and Torque-
                                    output power characteristics




     Torque-speed and Torque-
       current characteristics
Case Study 3:
Comparison of Key Physical Parameters and Cost for
the Sintered Neo and Bonded Neo based Motors

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Designing with Dysprosium Free Permanent Magnets

  • 1. Sintered Neo Replacement: Dysprosium-free Rare Earth Permanent Magnet Motors
  • 2. Sintered Neo Replacement • Fundamentals in dysprosium (Dy) market will result in significantly higher prices – Increasing demand due to growth in sintered Nd market – Insufficient supply • When possible, magnet users should design applications with magnets without Dy – Magnets using MQPTM grades do not rely on Dy • Application performance is comparable and can be optimized if MQPTM is “designed in”
  • 3. Rising prices of rare earth metals: Soaring prices of Dy
  • 4. Escalating Price of Dy: Fundamental supply-demand imbalance High demand Low output in Dy rich sintered neo applications Estimated Production in 2010* Yttrium Dysprosium Erbium 11.7% 2.4% 1.1% Lanthanum Terbium 24.6% Gadolinium 0.6% 1.6% Europium 1.0% Samarium 2.0% Neodymium 20.7% Cerium Praseodymium 29.0% 5.4% *Source:National Development and Reform Commission (NDRC) Report April 2011
  • 5. Dy Rich Sintered Applications Technology Assumption Low Penetration High Penetration Wind Onshore Wind Turbine Additional Capacity (GW) 23.6 48.6 Wind Offshore Wind Turbines Additional Capacity (GW) 4.9 17 Deployment in Vehicles Sales of Hybrid Electric Vehicles (HEVs) (millions) 4.2 19.1 2025 Vehicles Sales of Plug-in Hybrid Electric Vehicles (PHEVs) (millions) 0.002 13.2 Vehicles Sales of All Electric Vehicles (AEVs) (millions) 0.001 4.6 Wind Onshore Wind Turbines using RE Magnets 10% 25% Market Share Wind Offshore Wind Turbines using RE Magnets 10% 75% Vehicles HEVs, PHEVs, and AEVs using RE Magnet Motors 100% 100% Technology Assumption Low Intensity High Intensity Wind Average Weight of Magnets per MW (kgs) 400 600 Vehicles Average Weight of Magnets per vehicle (kgs) 1 2 Materials Wind and % Weight of Magnets that is Neodymium 31% 31% Intensity Vehicles Wind and % Weight of Magnets that is Dysprosium 5.50% 5.50% Vehicles Source: Critical Materials Strategy by U.S Department of Energy (Dec 2010) http://www.energy.psu.edu/oeo/ree/reports/criticalmaterialsstrategy121710.pdf
  • 6. Current Rare Earth Types and Content Source: Critical Materials Strategy by U.S Department of Energy (Dec 2010) http://www.energy.psu.edu/oeo/ree/reports/criticalmaterialsstrategy121710.pdf
  • 7. Low levels of Dy occurrence Low levels of Dy present Yttrium Dysprosium Erbium 11.7% 2.4% 1.1% Lanthanum Terbium 24.6% Gadolinium 0.6% 1.6% Europium 1.0% Samarium 2.0% Neodymium 20.7% Cerium Praseodymium 29.0% 5.4% Estimated Production in 2010* *Source:National Development and Reform Commission (NDRC) Report April 2011
  • 8. Possible new sources of Rare Earths: Dy contents are low Assumed Additional Production by 2015 Total Additional Mountain Pass Mt. Weld Nolans Bore Nechalaco Dong Pao Hoidas Lake Dubbo Zirconia Production by (USA) (Australia) (Australia) (Canada) (Vietnam) (Canada) (Australia) 2015 Lanthanum 6,640 3,840 2,000 845 1,620 594 585 16,124 Cerium 9,820 6,855 4,820 2,070 2,520 1,368 1,101 28,554 Praseodymium 860 810 590 240 200 174 120 2,994 Neodymium 2,400 2,790 2,150 935 535 657 423 9,890 Samarium 160 360 240 175 45 87 75 1,142 Europium 20 90 40 20 - 18 3 191 Gadolinium 40 150 100 145 - 39 63 537 Terbium - 15 10 90 - 3 9 127 Dysprosium - 30 30 35 - 12 60 167 Yttrium 20 60 - 370 35 39 474 998 TOTAL 19,960 15,000 9,980 4,925 4,955 2,991 2,913 60,724 Source: Critical Materials Strategy by U.S Department of Energy (Dec 2010) http://www.energy.psu.edu/oeo/ree/reports/criticalmaterialsstrategy121710.pdf
  • 9. Why does Sintered Neo need Dy? • Sintered neo is much more inclined to have a knee in the second quadrant engineering curve at elevated temperature – Due to high remanence values of sintered neo – Results in irreversible losses in motor • Compensation for this knee, motor companies could – Increase the magnet length – Adding Dy to enhance coercivity
  • 10. Typical Sintered Neo Alloy composition Type T.R.E NdPr Dy Gd Tb Fe Co B Al N35H 32.4 27.23 3.3 1.9 0 64.4 1 1 1 N35SH 33 29.64 3.4 0 0 64.8 0 1.1 1 N35UH 32.1 26.92 5 0.2 0 65 1 1 1 N38H 32.2 29.04 3.2 0 0 65.1 1 1 0 N38SH 31.9 28.29 3.6 0 0 65.4 1 1 1 N38UH 31.7 25.62 6.1 0 0 65.8 0.9 1 0 N42H 31 29.3 1.8 0 0 66.5 0.7 1 0 N42SH 30.4 26.66 3.3 0 0.4 66.9 1 1 0 N42UH 31.7 27.24 3.8 0 0.7 65.8 0.9 1 0 N45H 31.4 29.45 2 0 0 66.1 0.9 1 0 N45SH 30 27.06 0.8 0 2.1 67.4 0.9 1 0 N45UH 30.1 26.61 0.8 0 2.7 67.3 0.9 1 0 MQP-B 25.4 25.41 0 - - 73.4 - 1 - Typical sintered Nd grades contain up to 6% of Dy
  • 11. Advantages of Bonded Neo • MQPTM has very good linearity in the second 25C-MQP-B+-20056 125C-MQP-B+-20056 25C-MQP-14-12 125C-MQP-14-12 quadrant engineering curve 8 up to temperatures as high as Load line at stall Load line at no-load 7 150-180oC 6 • Able to achieve equivalent 5 B (kG) performance 4 3 • No significant increase in 2 motor size 1 • All MQPTM grades are Dy 0 free! -7 -6 -5 -4 -3 -2 -1 0 H (kOe)
  • 12. CASE STUDY www.mqitechnology.com Copyright © 2011 Magnequench Neo Powders Pte Ltd
  • 13. Case Study 1: Comparison of the Sintered Neo and Bonded Neo based Motors 4-Pole PMDC Motor with 4-Pole PMDC motor with Parameter Sintered Neo Magnets Bonded Neo Magnets 4-Arc Sintered neo Isotropic Bonded Neo Type of Magnet (N35SH) (MQP-14-12) Total motor weight (gm) 107.80 143.34 Length of the motor (mm) 10.00 12.00 Overall diameter (mm) 42.00 46.75 Total copper weight (gm) 12.70 23.80 Total magnet weight (gm) 14.20 24.94 Length of Air gap (mm) 0.80 0.80 Current at 80 mN-m (A) 11.06 10.20 Efficiency at 80 mN-m (%) 73.13 75.27
  • 14. Case Study 1: Chemical Composition and Magnet Characteristics for Sintered Neo Magnet ICP Test Result Element Nd Tb La Ce Pr Sm Dy Gd T.R.E % 18.731 0.151 0 0.031 5.862 0.026 2.491 1.680 28.972
  • 15. Case Study 1: Comparison of Key Physical Dimensions for the Sintered Neo and Bonded Neo based Motors Sintered Neo Motor Bonded Neo Motor
  • 16. Case Study 1: Comparison of Motor Characteristics for the Sintered Neo and Bonded Neo based Motors Torque-efficiency and Torque-output power characteristics Torque-speed and Torque-current characteristics
  • 17. Case Study 1: Comparison of Key Physical Parameters and Cost for the Sintered Neo and Bonded Neo based Motors
  • 18. Case Study 2: Comparison of the Sintered Neo and Bonded Neo based Motors 4-Pole PMDC Motor 4-Pole PMDC Motor 4-Pole PMDC motor Parameter with Sintered Neo with Sintered Neo with Bonded Neo Magnets Magnets Magnets 4-Arc Sintered neo 4-Arc Sintered neo Isotropic Bonded Neo Type of Magnet (N35SH) (N35) (MQP-B+-20056) Dy content ~3% 0-0.5% 0% Total motor weight (gm) 314.90 451.4 412.50 Length of the motor (mm) 18.00 23.00 20.00 Overall diameter (mm) 57.50 60.72 63.90 Total copper weight (gm) 29.80 21.3 57.10 Total magnet weight (gm) 29.10 56.5 37.30 Length of Air gap (mm) 0.55 0.55 0.55 Current at 220 mN-m (A) 11.08 10.55 11.21 Efficiency at 220 mN-m (%) 73.76 74.59 74.09
  • 19. Case Study 2: Comparison of Key Physical Dimensions for the Sintered Neo and Bonded Neo based Motors Sintered Neo (35SH) Sintered Neo (N35) Bonded Neo Motor
  • 20. Case Study 2: Comparison of Motor Characteristics for the Sintered Neo and Bonded Neo based Motors Torque-efficiency and Torque-output power characteristics Torque-speed and Torque-current characteristics
  • 21. Case Study 2: Comparison of Key Physical Parameters and Cost for the Sintered Neo and Bonded Neo based Motors
  • 22. Case Study-3 – Comparison of the Sintered Neo and Bonded Neo based Motors 4-Pole PMDC Motor 4-Pole PMDC motor Parameter with Sintered Neo with Bonded Neo Magnets Magnets 4-Arc Sintered neo Isotropic Bonded Neo Type of Magnet (N27SH or N30SH) (MQP-14-12) Total motor weight (gm) 204.35 237.00 Length of the motor (mm) 15.50 19.25 Overall diameter (mm) 44.10 49.79 Total copper weight (gm) 28.09 18.60 Total magnet weight (gm) 18.47 39.80 Length of Air gap (mm) 0.57 0.57 Current at 190 mN-m (A) 27.08 26.99 Efficiency at 190 mN-m (%) 74.30 73.04
  • 23. Case Study 3: Chemical Composition and Magnet Characteristics for Sintered Neo Magnet ICP Test Result Element Nd La Ce Pr Sm Dy Tb Gd T.R.E % 21.204 0.004 0.028 6.047 0.000 4.087 0.034 0.109 31.479
  • 24. Case Study 3: Comparison of Key Physical Dimensions for the Sintered Neo and Bonded Neo based Motors Sintered Neo Motor Bonded Neo Motor
  • 25. Case Study 3: Comparison of Motor Characteristics for the Sintered Neo and Bonded Neo based Motors Torque-efficiency and Torque- output power characteristics Torque-speed and Torque- current characteristics
  • 26. Case Study 3: Comparison of Key Physical Parameters and Cost for the Sintered Neo and Bonded Neo based Motors