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INTERNATIONAL ATOMIC ENERGY AGENCY
    Technical Meeting on The Origin of Sandstone Uranium
               Deposits: A Global Perspective
            29 May – 1 June 2012, Vienna, Austria




  Uranium mineralization hosted by the
Paleozoic sandstones in Southwest Sinai,
                 .Egypt
                               By




         Nuclear Materials Authority, El-Maadi, Cairo,
                            Egypt
Outline
 Introduction.

 lithostratigraphy of the Paleozoic succession in Southwest Sinai.

 Geological setting of U-bearing sandstones in Southwest Sinai.

 Mineralogy and petrography of the radioactive sandstones.

 Radioactivity of the studied sandstones.

 Sandstone - type uranium deposits in the promising localities.

 Inferred U- resources in evaluated deposits.

 Summary and conclusions.
Introduction

The Paleozoic clastics
exposed mainly along the
NE Egypt (Eastern Desert
and Sinai).
                                                        Sinai


These clastics exposed
along the African plate
which related to the Arabo-
Nubian massif.



The Paleozoic success-
ion in Sinai (up to 320m)
form the basal units of the
sedimentary sequence
unconformably overlies
the Precambrian basement
rocks.
                              Geological map of Egypt
….Introduction Cont

     The Paleozoic sandstones
   exposures in Southwest Sinai
 are distributed mainly as a strip
    extend from Um Bogma - G.
     Dhalal area, separating the
crystalline area of southern Sinai
from Mesozoic and Tertiary rocks
  of El Tih and Egma Plateaux of
                   central Sinai.                         Um
                                                         Bogma
                                                                                     G. Dhalal




  These exposures exist either
   as small bodies resting on the
        top of high, peneplained                                        Ras

    basement rocks or as down-                                          Millan




faulted blocks against crystalline
           basement mountains.       Simplified geologic- geomorphic map showing the distribution of
                                       .Paleozoic rocks and the studied localities in Southwest Sinai
The studied localities (host to sandstone-type
uranium mineralization) in Southwest Sinai:

 W. El Sahu area (SE. Um Bogma)

      G. Adedia

      G. Um Hamd

      G. Abu Triefia

      G. Maghara

 G. Hemeyir area

      El Khamila

      G. Hemeyir

      G. Ghorabi

      Ramlet Hemeyir

 W. El Main area

      W. Qarqur

      W. Imlieh

      W. Um Gidy

 Ras Millan area

      W. Lethi

                                                 .Geological map shows the studied localities in Southwest Sinai
Lithostratigraphy of the Paleozoic succession in Southwest Sinai

                                           Stratigraphic units included in this study
Lithostratigraphy of the Paleozoic succession in Um Bogma area (a) and annotated
            outcrop photographs showing in detail its Cambro-Ordovician and lower
                                                     Carboniferous formations (b,c).
Lithostratigraphy of the Cambro-Ordovician succession in Ras Millan area (a) and annotated
outcrop photographs showing in detail the radioactive sandstones of Araba Formation (b,c)
           and composite lithostratigraphic subdivisions of Adedia Formation (e) and detailed
      lithostratigraphic section of its radioactive uppermost part (f) and its annotated outcrop
                                                    photographs (d,g) in south W. El Sahu area.
The radioactive basal conglomerate in Southwest Sinai


The anomalous
polymictic cong-
lomerate lenses
are well extend-
ed in:

W. El Main
W. Qarqur,
W. Um Gidy,
W. Imlieh,
G. Nukhul
G. Adedia.

The lenses
                                                                                       Thorite
range in
thickness from
60 cm to 2.0 m


        a. Polymictic basal conglomerate directly overlying the basement rocks at W. Qarqur
        b. Radioactive polymictic conglomeratic lens at the base of Araba Fm., W. El Main area.
        c. Rock fragments, xenotime and quartz cemented with carbonates (pointed by arrows), iron oxides
        and
           Fe-Ti cements in the conglomerate of W. Nukhul. (P.L., X=32).
The radioactive ferruginous
                                               sandstone of El Adedia Fm.
                                               in W. El Sahu area


                            Wadi Sahu               Wadi El Sahu
                                                   28o 58 ' 33 " N
                                                   33o 22 ' 39 " E




LANDSAT of Wadi El Sahu, Southwestern Sinai.




  U- bearing ferruginous sandstone
….The radioactive ferruginous sandstones in W. El Sahu area Cont

                                                 .G. Um Hamd
The radioactive ferruginous sandstones in G. Hemeyir area


                                       El Khamila




                                       G. Hemeyir

                                                        14E 32 33
U- bearing ferruginous sandstones in G. Hemeyir area




.Photograph show the aeolian sands cover the exposures of U- bearing ferruginous sandstones
Ramlet Hemeyir




                                       Gaba
                                           l G ho
                                            rabi
     Ramlet Hemeyir                                 Gabal Ghorabi
     29o 03 ' 53 " N
                                                    29o 00 ' 59 " N
     33o 29 ' 03 " E
                                                    33o 30 ' 19 " E


.Radioactive localities in G. Hemeyir area mostly covered with aeolian sand
Map of airborne gamma ray spectrometry survey which carried out on
 the eastern side of the Gulf of Suez at Abu Zeneima-El Tor stretch
                              )(4000 Km 2
                                                                ea
                                                          yir ar
                                                       eme
                                                  G. H

                             d
                          an       a
                      m a      a re
                 B og      ahu
              Um        lS
                     .E
                   W
                S.
The radioactive Cambro-Ordovician sandstones in Ras Millan area




                                         Uc up to 1064ppm & 8359 ppm Th
The Lower Carboniferous Abu Thora Formation




                                                                   Abu Thora Fm.




     The lower Carboniferous Abu Thora Fm.
      exposed only in Um Bogma area and its
       vicinities. It is up to 242m in thickness.

Three main lithofacies could be distinguished
from base to top;

       Ferruginous sandstone lithofacies.
       Varicolored siltstone and shale lithofacies.
       Milky white sandstone lithofacies .
The Lower Carboniferous Abu Thora Formation
                                                                                                                                            33 22'                                                                                                                                                                       33 23'                                                                                                                                   33 24'
                                                                                                                               P3                                                                                                                                                                                                                                                                                                  33 20'                                          33 25'
                                                                                                                                                                                                                                                                                                                                                                                                                                                                            G . U m R in n a
                                                                                                                                                                                                                                                                                     Q                                                                                                                                                                                                                 29




                                                                                                                                            a
                                                                                                                                                                                                                                                                                                                                                                              S IN A I                                                                                                                 05'

Uranium within Abu Thora Formation




                                                                                                                                       B ab
                                                                                                                                                                                                                                                                                                                                                                                                                                                          W . S e ih
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                                                                                                                                                                                                                                                                                              e                                                                                                                                                                                                                29




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                                                                                                                                                                                                                                                                                       rr
 is controlled with major structure lines   04'                                                                                                                                                                                                            P        2

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                                such as:                                                                                                                                                                                                          W                                                                                                                                                                                         U m B ogm a                                                  00'
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                          5 km
                                                                                                         Q                                                                                                                                                     .M                        P    2
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                                                                                                                                              P3
                                                                                                                                                                                                                                                                                                                                               NS


     N-S normal fault of W. El Kharig                                                                                                                                                                                                        P
                                                                                                                                        2                                                                                                          2
                                                                                                                                                                                                                                                   2
                                                                      P1         P                                                                                                                                                                                                                                                                      P
                                                                                                                                                                                                                                                                                         P
                                                                                     1
                                                                                                                                                                                                                                                                                                  3                                                         2
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                                            29                                                                                                                                                                                                                                                                                                                                                                                Q
                                                                                                                  P                                                                                                                                                                                                                                                                                       P3                                                                                                   29
                                            03'
       extending to Ras Nukhul and El
                                                                                                                          2
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                                                         P1




                                                                                                                                                                                                                                                                                                                                                                                                                              W .
                                                                                     P       3
                                                                                             2            P   3
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                                                                                                                                                                                                                                                                                                                                                                                                                                  N as
                                                                                P3                                                     P3              P   3
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                                                                                                                                                                                                                                                                                                                                                                                                                  P       2
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                                                                                                                                                                                                                                                                                                             P3
                    Khaboba localities.                                                                                                                                                                                                                                                                                                                                                               P




                                                                                                                                                                                                                                                                                                                                                                                                                                       e ib
                                                                                                                                                                                                                                                                                                                                                                                                              2
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                                                                                                                                                                                                                                                                                                                                                                         2


                                                                                                                                                                   P
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                                                                                 Legend                                                                                        2

                                                     Q                W a d i D e p o s it s                                                                                                                                                                                                                                                                                                                                                              Q           Pc
                                                                      A b u T h o ra F m .                                                                                                                               P       3
                                                                                                                                                                                                                                 2                                                                                                                                       P3                                                             P    1
                                                                                                                                                                                                                                                                                                                                                                                                                                             2

                                                     P
                                                     P 33             S a n d s to n e a n d
                                                                      C a r b o n a c e o u s c la y
                                                                                                                                              P    1
                                                                                                                                                   2
                                                                                                                                                                                                                                                                                                                                                                P    3
                                                                                                                                                                                                                                                                                                                                                                     2
                                                                                                                                                                                                              P3
                                                    P2                U m Bogm a Fm .                                                                                  P       2
                                                                                                                                                                               2


                                                              P   3         U p p e r d o lo s to n e m e m b e r
                                                                                                                                                                           P                                                                                                             P        3                      P3                                                                                           P       1

                                                                                                                                                                                                                                                                                                                                                                                                                                                                  Q
                                                                  2                                                                                                                    3
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   NW-SE normal fault of W. Naseib
                                                                                                                                                                                                                                                                    2                             2                                                                                                                           2
                                                                                                                                                                                       2

                                                              P 22          M i d d l e i n t e r c a l a t io n m e m b e r                                                                                                                                        2
                                                                                                                                                                                                                                                                                    AT
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                                                              P 12          L o w e r d o lo s to n e m e m b e r
                                            29                                                                                                                                                                                                                                                                                      e              tAb                                                                                                                             Pc
                                                    P1                S a r a b it, A b u H a m a ta a n d                                                                                                                                                                                                                    D abb                                                                                                                                                                            29
extending as a right limb of W. El Sahu     02'                       A d e d iy a F m s .
                                                                      S a n d s t o n e , p e b b ly S a n d s t o n e                                                                                                                                                                                                                                                        P                                                     P   1

                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                               02'
                                                                                                                                                                                                                                                                                                                                                                                      3                                                 2

                                                                                                                                                                                                                                                                                                                                                            P3
                                                                                                                                                                                                                                                                                                                                                                                      2
                                                                      a n d S ilt s to n e                                                                                                                                                                                                    P        1
                                                                                                                                                                                                                                                                                                       2


                                                                      B asem ent R ocks                                                                                                                                                                                                                                                                                                                                                          P    2
                                                                                                                                                                                                                                                                                                                                                                                                                                                      2
                                                    Pc                                                                                                                                                                                                                                                       P       2
                                                                                                                                                                                                                                                                                                                                                                             P    2




                                graben.
                                                                      G r a n o d io r ite a n d d io r ite                                                                                                                                                                                                          2                                                            2

                                                                                                                                                                                                                                                                                                                                                                                                      P   2
                                                                                                                                                                                                                                                                                                                                                                                                          2                                                                    Q
                                                                      D i p - S l ip F a u l t
                                                                                                                                                                                   P                                                                                                                                                                                                      P       1                                     P3                    P   1

                                                                                                                                                                                                                                                                                                                                      P3
                                                                                                                                                                                           1
                                                                                                                                                                                                                                                                                                                                                                                                                                                                  2
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                               Pc
                                                                                                                                                                                           2                                                                                                                                                                                                      2
                                                                      L o c a t i o n o f l it h o s t r a t i g r a p h i c
                                                                      s e c tio n
                                                                                                                                                                                                                     P3                       P        1
                                                                                                                                                                                                                                                       2                                                                                       P    3
                                                                                                                                                                                                                                                                                                                                                    2
                                                                                                                                                                                                                                                                                                                                                                                                                                        P
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                               29
                                                                                                                                                                                                                                                                                                                                                                                                                                             3
                                                                                                                                                                                                                                                                                                                                                                                                                                             2


                                                    0 .0              0 .2                   0 .4     0 .6 k m
                                                                                                                                                                                                                                             P3                                                                                                                                                                                                                                                                01'
                                                                                                                                                                                                                                                                                                                                                                                 P
                                                                                                                                                                                                                                                                                                                                                                                                                                                                                                               30"
                                                                                                                                                                                                                                                                                                                                                                                          1
                                                                                                                                                                                                                                                                                                                                                                                          2


                                                                                                                                                                                                                                                                                                                                                                                                                              P3
                                                                                                                                                                                                       P       1
                                                                                                                                                                                                               2

                                                                                                                                                                                                                     P       2                    P        3
                                                                                                                                                                                                                                                           2                                                                                                                     P        3
                                                                                                                                                                                                                                                                                                                                                                                          2
                                                                                                                                                                                                                             2



                                                                                                                              33 22'                                                                                                                                                                  33 23'                                                                                                                                     33 24'

                                             Geological) : mapl o ofi c Ump Bogmai Nareab (after BElb AassyS et t hal., s t e r n S i n a i .
                                                  F ig .( 2 G e o g m a o f W a d a s e i - W a d i a a a r e a , o u w e
                                             2006).
Mineralogy of the polymictic basal conglomerate

         Thorite                     Uranothorite




                                            Zircon




Thorite is the most abundant Th-bearing mineral associated with other detrital
heavy minerals; including abundant uranothorite, thorianite, monazite, zircon,
xenotime besides cheralite (Th, Ca, Ce)(PO4, SO4), chevikinite (Ca, Ce, Th)4
(Fe, Mg)2(Ti, Fe)3O22 and thorutite (Th, U, Ca) TiO2.
.Mineralogy of the ferruginous sandstones of El Adedia Fm
The principal minerals                 Xenotime
                                       Xenotime
responsible for the radioactivity:



 The refractory xenotime,
apatite, allanite, euxenite
zircon, monazite as well as
secondary U minerals;
                                     Xenotime
Saleeite and becquirelite
in W. El Sahu area.

Uvanite and threadgoldite
in G. Hemeyir area.



      The gangue minerals
                                     Uvanite
       mainly are iron oxides;
magnetite, goethite, ilmenite
     in addition to barite and
                        galena.
.Mineralogy of the Araba sandstones at Ras Millan area
           Autunite                     Allanite




              Sodium meta-autunite
                                        Monazite




The minerals responsible for
radioactivity are zircon, allanite,
thorite, xenotime, monazite, davidite
                                                                                          Zircon
and secondary U minerals; saleeite,
johannite and sodium meta-autunite.


The aluminium phosphate
minerals; goyazite, florencite,                Zircon grains cemented with Fe-Ti oxides
plumbogummite were associated in
the anomalous sandstones.
Black sand lenses in El Adedia and Araba formations

The black sand lenses occur within the radioactive

  horizons of El Adedia and Araba formations.

Meander loops and channels with deep scours appear to
 be the most favourable sites for these lenses.


It consist of heavy minerals concentrate include
 zircon, monazite, xenotime, ilmenite, ilmenorutile
 and rutile. Well rounded monazite and zircon are
 the most abundant minerals.

The framework grains coated with iron and titanium
  oxides cement.

The cement materials occur as fibrous, radial and
 acicular forms.
Mineralogy of the radioactive Abu Thora sandstones
                                        Graphite
  The anomalous U content
 in Abu Thora Fm. (Uc up to
                                                     Sphene
      380 ppm) is controlled
mainly by the presence of U-
      bearing detrital grains.


 These detrital minerals are                        Apatite
sphene, apatite, euxenite,                  Zircon
zircon and monazite.

   The leached U hosted in
   the interbeded mudstones
 and siltstones is captured by
the iron oxides, clay minerals
 and organic matter contents.

   U occurs as spots within
 other minerals as graphite.
                                                               Euxenite
Radioactivity of basal conglomerate lenses

The basal conglomerate lenses have anomalous eU and eTh contents
(reach up to 157 ppm eU and 2379 ppm eTh).


The eTh/eU ratio for these sediments ranges from 1.3 to 18.2 with an
average of 5.3.


The chemical uranium (Uc) is depleted in this lithofacies (reach up to 40
ppm at W. Qarqur). It ranges from 14 to 40ppm with an average of 23.2ppm.


The high Th content is attributed to high concentration of Th and Th-U
bearing minerals such as thorite, chevikinite, cheralite, thorutite, thorianite,
zircon, monazite and xenotime.


These radioactive minerals essentially exist as inclusions in the rock
fragments (framework components) or through detrital matrix and/or cement
materials.
Radioactivity of ferruginous sandstones in south W. El Sahu area

The ferruginous sandstones has anomalous Uc; up
to 3000 ppm in south W. El Sahu area; G. Abu Triefia
    The anomalous sandstones in G. Um Hamd, G.
 Abu Triefia and G. Um Karasy show high radiometric
measurements and are enriched in radionuclides; eU,
                                     eRa and K%.                 Wadi Sahu
                                                         G. Um
 eU content reached 2040 ppm with an average of
                                                         Hamd
506 ppm.
 Ra content reached 1528 ppm, with an average of                                G. Um
                                                                                 Karasy
396 ppm.
           The high uranium and radium contents are
     attributed mainly to the presence of tongues and
                lenses of secondary U-mineralization.
 The Uc/eU ratios of these sandstones ranges from
                  0.41 to 5.1 with an average of 1.51.             G. Um
      The eU/eRa ratios for most of the mineralized              Hamd
samples exceed unity, reflecting a state of radioactive
  disequilibrium between uranium and its daughters.                           G. Um
                                                                              Karasy
                                                                      G. Abu
 The above ratios indicates the enrichment of Uc in                  Triefia
  these sandstones in the form of secondary uranium
     mineralization such as saleeite and becqurelite.
Radioactivity in G. Hemeyir area

                                                a   Gabal Hemeyir
                                                    29o 01' 36" N
                                                    33o 32' 38 " E
                                                     2400 ppm

                               G.Hemeyir
                                                b
                                                    El Khamila

   c                                                 29o 01' 38 " N
                          a                          33o 32 ' 32 " E
                                                      > 550 ppm
                   b
                                                c
                                                    G. Ghorabi

                                                    29o 01' 38 " N
                                                    33o 32 ' 32 " E
                                                      > 400 ppm

LANDSAT of Gabal Hemeyir, southwestern Sinai.
….Radioactivity in G. Hemeyir area Cont
….Radioactivity in G. Hemeyir area Cont
 Chemical uranium (Uc) in the ferruginous sandstones reach up to 2400ppm with an
average of 399.6 ppm.


 Uc/eU ratios for the ferruginous sandstones in G. Hemeyir area ranges from 0.49 to
27.5 with an average of 7.7.


 The eTh/eU ratio ranges from 0.12 to 0.44 with an average of 0.36.


 The radioactive sandstones at G. Hemeyir area are related to three successive
horizons include;
     The ferruginous sandstone at the topmost part of El Adedia Formation.
     The lateritic soil directly overlying the first and is represented by ferruginous siltstone (~ 1.5 m in
         thickness).
     The third horizon is the violet and mottled white S.S. at the base of Abu Thora Fm., with Uc reach up
    to
     212 ppm.

    The enrichment of uranium in these sandstones under conditions where uranium
          was removed from its source and re-deposited in permeable fault zone with
        continuous recharge and a basic dyke act as a barrier to U-bearing solutions.
Radioactivity of Araba Formation in Ras Millan area

         The anomalous sandstones are highly
radioactive along the fault zone (extend ~12 km);
       its activity is variable along this extension.

                   The radioactive horizons are:

 The basal quartzite of Araba Fm. (Uc up to 102
ppm and Th up to 7433 ppm).
                                                        Ras Millan area
The very fine sandstone at the topmost part of
Araba Fm. (Uc up to 1016 ppm and Th up to
8359 ppm).



The high eTh/eU ratios range from 1.68 to 25.6
with an average of 9.08.

      This ratios reflect the presence of detrital
   radioactive Th and Th-U bearing minerals like                               .
  xenotime, allanite, monazite, thorite, zircon and                          Fm
                                            davidite.                 a ba
                                                                  r
                                                              A
….Radioactivity of Araba Formation in Ras Millan area Cont

   The highest radioactive measurements
 were located at the downstream of W. Lethi
    (eTh = 8359 ppm and eU = 450 ppm) in
               Araba very fine sandstones.



    The sandstones far from the fault zone
are slightly enriched in uranium than thorium
                   (Uc ~ 100 ppm in average).


   U liberates from the lattice of refractory            hi
                                                      Let
                                                 W.
 minerals during the hydrothermal alteration




                                                           Cam
                                                               bro
 processes along the permeable fault zones




                                                                   -Or
                                                                      dov
  and re-precipitated as secondary uranium




                                                                         i ci a
                                                                          ns
                                                                             and
  (e.g. saleeite, johannite and sodium-meta-




                                                                                            Ca
                                                                                  st o




                                                                                              mb
                                                                                      nes




                                                                                                ro-
  autunite) in the overlying sandstones. This




                                                                                                    Ord
                                                                                                       ovi
      explains the high value of both Uc and




                                                                                                          cia
                                                                                                             ns
                                                                                                           and
      eTh/eU ratio in the same time in these




                                                                                                              s   ton
                                                                                                                     es
                                sandstones.
Radioactivity of Abu Thora Formation

                                             S. No.      Lithofacies          eU          eTh         Ra          K%          eTh/eU
  The Uc/eU ratio in most of
                                                         Ferruginous
       the mineralized and non                1          sandstones          13.4         10.4        16.2        0.62         0.81
   mineralized samples greater                           Coal bearing
                                              2                              9.72     19.78           6.61        0.36         2.12
  than 1. It ranges from 0.09 to                         black shales
   58 with an average of 12.7.                3
                                                         Varicolored
                                                                             24.72    37.09           18.0        0.24         1.91
                                                          siltstones
                                              4        White sandstones       6.0         2.83        1.16    0.035            1.5
   There is negative relation
between the eTh/eU ratios and
Uc indicates some enrichment
     of U relative to Th (U was
    enriched during secondary
                    processes).                                                                              Uc   in   White S.S.
                                                                                                             Uc   in   ferruginous S.S.
                                    1                                                                        Uc   in   Shales
                                                                                                             Uc   in   Siltstones
 The close spatial correlation
between U-bearing sandstones
    and major structures in the
        area suggested that the         50        51    52      53      54     55    56          57     58    59         60

  supergene enrichment of U in                               Average U concentration in ppm
these clastics was facilitated by
         tectonic movements.
Sandstone–type uranium deposits in the promising localities

The studied Paleozoic sandstones in southwest Sinai host two types of uranium
:mineralization

    1. The syngenetic continental/littoral paleoplacers; include mainly refractory

                              minerals which are detrital from nearby source rocks.

              Two types of placers can be recognized on the basis of depositional

                                           environment; stream and beach placers.

       The stream placers hosted mainly in the basal polymictic conglomerate



                lens directly overlying the basement rocks and in black sand lenses

                         exist in the sandstones of El Adedia and Araba formations.

       The refractory minerals concentration is depositional controlled and its
…Sandstone–type uranium deposits in the promising localities Cont

2. The tectolithologic sandstone- type uranium deposits

             It formed by the epigenetic enrichment of uranium within the sandstones
         unconformably overlying the Precambrian granitic basement rocks or faulted
                                                                              against it.


     The present U deposits are related to the permeable fault zones and stacked

     as discordant bodies through more than one stratigraphic horizon.


     The sandstones enriched in secondary uranium minerals include uranium
     phosphates and vanadates in addition to detrital mineral grains; xenotime,
     sphene, apatite, zircon, monazite, euxenite, fergusonite and allanite.


     The concentration of xenotime (YPO4) and associated authigenic Al-phosphate
     minerals may have been formed by dissolution of the detrital minerals by
Estimation of inferred U resources in uraniferous blocks of G. Um Hamd- W. El Sahu area.



                                        Average                  Ore                 Metal
                                                    Density,             Average
     S. No.   Block No.   Area, m  2
                                       thickness,              amount,              amount,
                                                     g/cm3               grade, %
                                           m                     ton                  ton

              SH333F-
       1                  708.77          2.8        2.639     5237.25    0.054      2.83
               VC1

              SH333WC
       2                   733.2         2.56        2.739     5141.08    0.075      3.86
                 2

              SH333V-
       3                  5986.78         1.2        2.498     17946      0.014      2.51
                FD1

       4      SH333FD2     2500           1.2        2.712      8136      0.014      1.14

       5      SH333FD3     2500           0.6        2.712      4068      0.014      0.57

              SH333V-
       6                   2500           1.8        2.359     10615.5    0.014      1.49
                FD4

       7      SH333FD5    1909.38          1         2.712     5178.24    0.018      0.93

              SH333F-
       8                  9920.55        1.77        2.716     47691.3    0.023      10.97
               WD6
I. The inferred U resources in G. Um Hamd - W. El Sahu area.




                                    No. of        No. of         No. of      Estimated
                     Locality     excavated     excavated      evaluated     U metals
         .No
                                    Shafts       trenches        blocks       in tons


          1        G. Um Hamd         19             3              8           24.3




 The inferred U resources in G. Um Hamd locality is 28.7 ton U 3O8 or 24.3 ton U metal.

 The area south W. El Sahu; G. Abu Triefia, G. Um Karasy and G. Maghara are still under

 preliminary evaluation stage.
El Khamila locality




                                 G. Hemeyir
     W
      .
               El
                      Kh
                      am
                           ila
Inferred U resource estimation in El Khamila locality

                                                           Volume determination of ore-deposits =

                                                            170m X 140m X 2.0m = 47600m3



                                                                   U- grade % = 0.024%

                                                        U-ore tonnage = 111860 t ferruginous sandstone




                                                                U- metal tonnage = 26.85 t
                                                                U3 O8 – tonnage = 31.7 t
                                                                  3 8
Summary and Conclusions
The tectonic history of southern Sinai is considered to be one of the most important

     factors in the formation of the present tectonic-lithologic type uranium deposits.


     The uranium deposits hosted in fluvial sediments, which generally consist of a

     sequence of conglomerates-sandstones-mudstones (fining upward sequence).


 The refractory minerals in the basal conglomerates and upper parts of Adedia and

    Araba formations represent the primary source of uranium and its associated
                                                  metals in the Paleozoic sandstones.


      Another source of primary uranium is considered to be either the surrounding

      uraniferous granitic provenance, or detrital granitic and/or felsic volcanic rock
                                                     fragments in the host sandstones.
Summary and Conclusions
     The tectonic-lithologic stack type deposits are in part considered the product of
 redistribution of uranium in permeable hosts along structures took place by younger
                                                                 tectonic processes.



 The uranium mineralization are rarely located far from fault zones and are stacked
up along different horizons of these permeable localities.



         The tectonic-lithologic sandstone-type uranium deposits occur in significant
quantities in the Cambro-Ordovician sandstones of G. Hemeyir, W. El Sahu and Ras
                                                                     Millan areas.



  The large extension of the hosted sandstones indicates significant U-resources in
                                                     these localities in Southwest Sinai.



 Results point to the necessity for further exploration in detail.
06 u mineralization hosted by paleozoic sandstones in sw sinai egypt

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06 u mineralization hosted by paleozoic sandstones in sw sinai egypt

  • 1. INTERNATIONAL ATOMIC ENERGY AGENCY Technical Meeting on The Origin of Sandstone Uranium Deposits: A Global Perspective 29 May – 1 June 2012, Vienna, Austria Uranium mineralization hosted by the Paleozoic sandstones in Southwest Sinai, .Egypt By Nuclear Materials Authority, El-Maadi, Cairo, Egypt
  • 2. Outline  Introduction.  lithostratigraphy of the Paleozoic succession in Southwest Sinai.  Geological setting of U-bearing sandstones in Southwest Sinai.  Mineralogy and petrography of the radioactive sandstones.  Radioactivity of the studied sandstones.  Sandstone - type uranium deposits in the promising localities.  Inferred U- resources in evaluated deposits.  Summary and conclusions.
  • 3. Introduction The Paleozoic clastics exposed mainly along the NE Egypt (Eastern Desert and Sinai). Sinai These clastics exposed along the African plate which related to the Arabo- Nubian massif. The Paleozoic success- ion in Sinai (up to 320m) form the basal units of the sedimentary sequence unconformably overlies the Precambrian basement rocks. Geological map of Egypt
  • 4. ….Introduction Cont The Paleozoic sandstones exposures in Southwest Sinai are distributed mainly as a strip extend from Um Bogma - G. Dhalal area, separating the crystalline area of southern Sinai from Mesozoic and Tertiary rocks of El Tih and Egma Plateaux of central Sinai. Um Bogma G. Dhalal These exposures exist either as small bodies resting on the top of high, peneplained Ras basement rocks or as down- Millan faulted blocks against crystalline basement mountains. Simplified geologic- geomorphic map showing the distribution of .Paleozoic rocks and the studied localities in Southwest Sinai
  • 5. The studied localities (host to sandstone-type uranium mineralization) in Southwest Sinai:  W. El Sahu area (SE. Um Bogma)  G. Adedia  G. Um Hamd  G. Abu Triefia  G. Maghara  G. Hemeyir area  El Khamila  G. Hemeyir  G. Ghorabi  Ramlet Hemeyir  W. El Main area  W. Qarqur  W. Imlieh  W. Um Gidy  Ras Millan area  W. Lethi .Geological map shows the studied localities in Southwest Sinai
  • 6. Lithostratigraphy of the Paleozoic succession in Southwest Sinai Stratigraphic units included in this study
  • 7. Lithostratigraphy of the Paleozoic succession in Um Bogma area (a) and annotated outcrop photographs showing in detail its Cambro-Ordovician and lower Carboniferous formations (b,c).
  • 8. Lithostratigraphy of the Cambro-Ordovician succession in Ras Millan area (a) and annotated outcrop photographs showing in detail the radioactive sandstones of Araba Formation (b,c) and composite lithostratigraphic subdivisions of Adedia Formation (e) and detailed lithostratigraphic section of its radioactive uppermost part (f) and its annotated outcrop photographs (d,g) in south W. El Sahu area.
  • 9.
  • 10. The radioactive basal conglomerate in Southwest Sinai The anomalous polymictic cong- lomerate lenses are well extend- ed in: W. El Main W. Qarqur, W. Um Gidy, W. Imlieh, G. Nukhul G. Adedia. The lenses Thorite range in thickness from 60 cm to 2.0 m a. Polymictic basal conglomerate directly overlying the basement rocks at W. Qarqur b. Radioactive polymictic conglomeratic lens at the base of Araba Fm., W. El Main area. c. Rock fragments, xenotime and quartz cemented with carbonates (pointed by arrows), iron oxides and Fe-Ti cements in the conglomerate of W. Nukhul. (P.L., X=32).
  • 11. The radioactive ferruginous sandstone of El Adedia Fm. in W. El Sahu area Wadi Sahu Wadi El Sahu 28o 58 ' 33 " N 33o 22 ' 39 " E LANDSAT of Wadi El Sahu, Southwestern Sinai. U- bearing ferruginous sandstone
  • 12. ….The radioactive ferruginous sandstones in W. El Sahu area Cont .G. Um Hamd
  • 13. The radioactive ferruginous sandstones in G. Hemeyir area El Khamila G. Hemeyir 14E 32 33
  • 14. U- bearing ferruginous sandstones in G. Hemeyir area .Photograph show the aeolian sands cover the exposures of U- bearing ferruginous sandstones
  • 15. Ramlet Hemeyir Gaba l G ho rabi Ramlet Hemeyir Gabal Ghorabi 29o 03 ' 53 " N 29o 00 ' 59 " N 33o 29 ' 03 " E 33o 30 ' 19 " E .Radioactive localities in G. Hemeyir area mostly covered with aeolian sand
  • 16. Map of airborne gamma ray spectrometry survey which carried out on the eastern side of the Gulf of Suez at Abu Zeneima-El Tor stretch )(4000 Km 2 ea yir ar eme G. H d an a m a a re B og ahu Um lS .E W S.
  • 17. The radioactive Cambro-Ordovician sandstones in Ras Millan area Uc up to 1064ppm & 8359 ppm Th
  • 18. The Lower Carboniferous Abu Thora Formation Abu Thora Fm. The lower Carboniferous Abu Thora Fm. exposed only in Um Bogma area and its vicinities. It is up to 242m in thickness. Three main lithofacies could be distinguished from base to top;  Ferruginous sandstone lithofacies.  Varicolored siltstone and shale lithofacies.  Milky white sandstone lithofacies .
  • 19. The Lower Carboniferous Abu Thora Formation 33 22' 33 23' 33 24' P3 33 20' 33 25' G . U m R in n a Q 29 a S IN A I 05' Uranium within Abu Thora Formation B ab W . S e ih P3 W .S e ih ib a se W . 29 W . tN G. e 29 N as S a r a b it rr is controlled with major structure lines 04' P 2 Di P3 E l K h a d im Q P3 2 04' e ib P 2 a ab P3 2 .B P3 P A b u H a m a ta 29 W 1 2 such as: W U m B ogm a 00' 5 km Q .M P 2 P3 W . 2 P3 W .A bu E l or K ey M ap N as P 1 ei P 3 2 P 1 2 2 P 1 2 d e ib P 1 Q a M o g h e ira t 2 Q B ab P 1 P 2 P 2 T a le t 1 2 2 P 1 2 P P 2 W . TS S e lie m 2 2 2 P 2 2 P 3 P3 NS N-S normal fault of W. El Kharig P 2 2 2 P1 P P P 1 3 2 2 AM 2 2 29 Q P P3 29 03' extending to Ras Nukhul and El 2 2 P1 W . P 3 2 P 3 2 Pc 03' N as P3 P3 P 3 2 P 2 2 P3 Khaboba localities. P e ib 2 2 P 3 P 3 2 P 2 2 Legend 2 Q W a d i D e p o s it s Q Pc A b u T h o ra F m . P 3 2 P3 P 1 2 P P 33 S a n d s to n e a n d C a r b o n a c e o u s c la y P 1 2 P 3 2 P3 P2 U m Bogm a Fm . P 2 2 P 3 U p p e r d o lo s to n e m e m b e r P P 3 P3 P 1 Q 2 3 P NW-SE normal fault of W. Naseib 2 2 2 2 P 22 M i d d l e i n t e r c a l a t io n m e m b e r 2 AT P 3 P 2 P3 P3 2 or u -T h 2 P 12 L o w e r d o lo s to n e m e m b e r 29 e tAb Pc P1 S a r a b it, A b u H a m a ta a n d D abb 29 extending as a right limb of W. El Sahu 02' A d e d iy a F m s . S a n d s t o n e , p e b b ly S a n d s t o n e P P 1 02' 3 2 P3 2 a n d S ilt s to n e P 1 2 B asem ent R ocks P 2 2 Pc P 2 P 2 graben. G r a n o d io r ite a n d d io r ite 2 2 P 2 2 Q D i p - S l ip F a u l t P P 1 P3 P 1 P3 1 2 Pc 2 2 L o c a t i o n o f l it h o s t r a t i g r a p h i c s e c tio n P3 P 1 2 P 3 2 P 29 3 2 0 .0 0 .2 0 .4 0 .6 k m P3 01' P 30" 1 2 P3 P 1 2 P 2 P 3 2 P 3 2 2 33 22' 33 23' 33 24' Geological) : mapl o ofi c Ump Bogmai Nareab (after BElb AassyS et t hal., s t e r n S i n a i . F ig .( 2 G e o g m a o f W a d a s e i - W a d i a a a r e a , o u w e 2006).
  • 20.
  • 21. Mineralogy of the polymictic basal conglomerate Thorite Uranothorite Zircon Thorite is the most abundant Th-bearing mineral associated with other detrital heavy minerals; including abundant uranothorite, thorianite, monazite, zircon, xenotime besides cheralite (Th, Ca, Ce)(PO4, SO4), chevikinite (Ca, Ce, Th)4 (Fe, Mg)2(Ti, Fe)3O22 and thorutite (Th, U, Ca) TiO2.
  • 22. .Mineralogy of the ferruginous sandstones of El Adedia Fm The principal minerals Xenotime Xenotime responsible for the radioactivity:  The refractory xenotime, apatite, allanite, euxenite zircon, monazite as well as secondary U minerals; Xenotime Saleeite and becquirelite in W. El Sahu area. Uvanite and threadgoldite in G. Hemeyir area. The gangue minerals Uvanite mainly are iron oxides; magnetite, goethite, ilmenite in addition to barite and galena.
  • 23. .Mineralogy of the Araba sandstones at Ras Millan area Autunite Allanite Sodium meta-autunite Monazite The minerals responsible for radioactivity are zircon, allanite, thorite, xenotime, monazite, davidite Zircon and secondary U minerals; saleeite, johannite and sodium meta-autunite. The aluminium phosphate minerals; goyazite, florencite, Zircon grains cemented with Fe-Ti oxides plumbogummite were associated in the anomalous sandstones.
  • 24. Black sand lenses in El Adedia and Araba formations The black sand lenses occur within the radioactive horizons of El Adedia and Araba formations. Meander loops and channels with deep scours appear to be the most favourable sites for these lenses. It consist of heavy minerals concentrate include zircon, monazite, xenotime, ilmenite, ilmenorutile and rutile. Well rounded monazite and zircon are the most abundant minerals. The framework grains coated with iron and titanium oxides cement. The cement materials occur as fibrous, radial and acicular forms.
  • 25. Mineralogy of the radioactive Abu Thora sandstones Graphite  The anomalous U content in Abu Thora Fm. (Uc up to Sphene 380 ppm) is controlled mainly by the presence of U- bearing detrital grains.  These detrital minerals are Apatite sphene, apatite, euxenite, Zircon zircon and monazite.  The leached U hosted in the interbeded mudstones and siltstones is captured by the iron oxides, clay minerals and organic matter contents.  U occurs as spots within other minerals as graphite. Euxenite
  • 26. Radioactivity of basal conglomerate lenses The basal conglomerate lenses have anomalous eU and eTh contents (reach up to 157 ppm eU and 2379 ppm eTh). The eTh/eU ratio for these sediments ranges from 1.3 to 18.2 with an average of 5.3. The chemical uranium (Uc) is depleted in this lithofacies (reach up to 40 ppm at W. Qarqur). It ranges from 14 to 40ppm with an average of 23.2ppm. The high Th content is attributed to high concentration of Th and Th-U bearing minerals such as thorite, chevikinite, cheralite, thorutite, thorianite, zircon, monazite and xenotime. These radioactive minerals essentially exist as inclusions in the rock fragments (framework components) or through detrital matrix and/or cement materials.
  • 27. Radioactivity of ferruginous sandstones in south W. El Sahu area The ferruginous sandstones has anomalous Uc; up to 3000 ppm in south W. El Sahu area; G. Abu Triefia The anomalous sandstones in G. Um Hamd, G. Abu Triefia and G. Um Karasy show high radiometric measurements and are enriched in radionuclides; eU, eRa and K%. Wadi Sahu G. Um  eU content reached 2040 ppm with an average of Hamd 506 ppm.  Ra content reached 1528 ppm, with an average of G. Um Karasy 396 ppm. The high uranium and radium contents are attributed mainly to the presence of tongues and lenses of secondary U-mineralization. The Uc/eU ratios of these sandstones ranges from 0.41 to 5.1 with an average of 1.51. G. Um The eU/eRa ratios for most of the mineralized Hamd samples exceed unity, reflecting a state of radioactive disequilibrium between uranium and its daughters. G. Um Karasy G. Abu The above ratios indicates the enrichment of Uc in Triefia these sandstones in the form of secondary uranium mineralization such as saleeite and becqurelite.
  • 28. Radioactivity in G. Hemeyir area a Gabal Hemeyir 29o 01' 36" N 33o 32' 38 " E 2400 ppm G.Hemeyir b El Khamila c 29o 01' 38 " N a 33o 32 ' 32 " E > 550 ppm b c G. Ghorabi 29o 01' 38 " N 33o 32 ' 32 " E > 400 ppm LANDSAT of Gabal Hemeyir, southwestern Sinai.
  • 29. ….Radioactivity in G. Hemeyir area Cont
  • 30. ….Radioactivity in G. Hemeyir area Cont  Chemical uranium (Uc) in the ferruginous sandstones reach up to 2400ppm with an average of 399.6 ppm.  Uc/eU ratios for the ferruginous sandstones in G. Hemeyir area ranges from 0.49 to 27.5 with an average of 7.7.  The eTh/eU ratio ranges from 0.12 to 0.44 with an average of 0.36.  The radioactive sandstones at G. Hemeyir area are related to three successive horizons include;  The ferruginous sandstone at the topmost part of El Adedia Formation.  The lateritic soil directly overlying the first and is represented by ferruginous siltstone (~ 1.5 m in thickness).  The third horizon is the violet and mottled white S.S. at the base of Abu Thora Fm., with Uc reach up to 212 ppm. The enrichment of uranium in these sandstones under conditions where uranium was removed from its source and re-deposited in permeable fault zone with continuous recharge and a basic dyke act as a barrier to U-bearing solutions.
  • 31. Radioactivity of Araba Formation in Ras Millan area The anomalous sandstones are highly radioactive along the fault zone (extend ~12 km); its activity is variable along this extension. The radioactive horizons are:  The basal quartzite of Araba Fm. (Uc up to 102 ppm and Th up to 7433 ppm). Ras Millan area The very fine sandstone at the topmost part of Araba Fm. (Uc up to 1016 ppm and Th up to 8359 ppm). The high eTh/eU ratios range from 1.68 to 25.6 with an average of 9.08. This ratios reflect the presence of detrital radioactive Th and Th-U bearing minerals like . xenotime, allanite, monazite, thorite, zircon and Fm davidite. a ba r A
  • 32. ….Radioactivity of Araba Formation in Ras Millan area Cont The highest radioactive measurements were located at the downstream of W. Lethi (eTh = 8359 ppm and eU = 450 ppm) in Araba very fine sandstones. The sandstones far from the fault zone are slightly enriched in uranium than thorium (Uc ~ 100 ppm in average).  U liberates from the lattice of refractory hi Let W. minerals during the hydrothermal alteration Cam bro processes along the permeable fault zones -Or dov and re-precipitated as secondary uranium i ci a ns and (e.g. saleeite, johannite and sodium-meta- Ca st o mb nes ro- autunite) in the overlying sandstones. This Ord ovi explains the high value of both Uc and cia ns and eTh/eU ratio in the same time in these s ton es sandstones.
  • 33. Radioactivity of Abu Thora Formation S. No. Lithofacies eU eTh Ra K% eTh/eU The Uc/eU ratio in most of Ferruginous the mineralized and non 1 sandstones 13.4 10.4 16.2 0.62 0.81 mineralized samples greater Coal bearing 2 9.72 19.78 6.61 0.36 2.12 than 1. It ranges from 0.09 to black shales 58 with an average of 12.7. 3 Varicolored 24.72 37.09 18.0 0.24 1.91 siltstones 4 White sandstones 6.0 2.83 1.16 0.035 1.5 There is negative relation between the eTh/eU ratios and Uc indicates some enrichment of U relative to Th (U was enriched during secondary processes). Uc in White S.S. Uc in ferruginous S.S. 1 Uc in Shales Uc in Siltstones The close spatial correlation between U-bearing sandstones and major structures in the area suggested that the 50 51 52 53 54 55 56 57 58 59 60 supergene enrichment of U in Average U concentration in ppm these clastics was facilitated by tectonic movements.
  • 34. Sandstone–type uranium deposits in the promising localities The studied Paleozoic sandstones in southwest Sinai host two types of uranium :mineralization 1. The syngenetic continental/littoral paleoplacers; include mainly refractory minerals which are detrital from nearby source rocks.  Two types of placers can be recognized on the basis of depositional environment; stream and beach placers.  The stream placers hosted mainly in the basal polymictic conglomerate lens directly overlying the basement rocks and in black sand lenses exist in the sandstones of El Adedia and Araba formations.  The refractory minerals concentration is depositional controlled and its
  • 35. …Sandstone–type uranium deposits in the promising localities Cont 2. The tectolithologic sandstone- type uranium deposits  It formed by the epigenetic enrichment of uranium within the sandstones unconformably overlying the Precambrian granitic basement rocks or faulted against it.  The present U deposits are related to the permeable fault zones and stacked as discordant bodies through more than one stratigraphic horizon.  The sandstones enriched in secondary uranium minerals include uranium phosphates and vanadates in addition to detrital mineral grains; xenotime, sphene, apatite, zircon, monazite, euxenite, fergusonite and allanite.  The concentration of xenotime (YPO4) and associated authigenic Al-phosphate minerals may have been formed by dissolution of the detrital minerals by
  • 36.
  • 37. Estimation of inferred U resources in uraniferous blocks of G. Um Hamd- W. El Sahu area. Average Ore Metal Density, Average S. No. Block No. Area, m 2 thickness, amount, amount, g/cm3 grade, % m ton ton SH333F- 1 708.77 2.8 2.639 5237.25 0.054 2.83 VC1 SH333WC 2 733.2 2.56 2.739 5141.08 0.075 3.86 2 SH333V- 3 5986.78 1.2 2.498 17946 0.014 2.51 FD1 4 SH333FD2 2500 1.2 2.712 8136 0.014 1.14 5 SH333FD3 2500 0.6 2.712 4068 0.014 0.57 SH333V- 6 2500 1.8 2.359 10615.5 0.014 1.49 FD4 7 SH333FD5 1909.38 1 2.712 5178.24 0.018 0.93 SH333F- 8 9920.55 1.77 2.716 47691.3 0.023 10.97 WD6
  • 38. I. The inferred U resources in G. Um Hamd - W. El Sahu area. No. of No. of No. of Estimated Locality excavated excavated evaluated U metals .No Shafts trenches blocks in tons 1 G. Um Hamd 19 3 8 24.3  The inferred U resources in G. Um Hamd locality is 28.7 ton U 3O8 or 24.3 ton U metal.  The area south W. El Sahu; G. Abu Triefia, G. Um Karasy and G. Maghara are still under preliminary evaluation stage.
  • 39.
  • 40. El Khamila locality G. Hemeyir W . El Kh am ila
  • 41. Inferred U resource estimation in El Khamila locality Volume determination of ore-deposits = 170m X 140m X 2.0m = 47600m3 U- grade % = 0.024% U-ore tonnage = 111860 t ferruginous sandstone U- metal tonnage = 26.85 t U3 O8 – tonnage = 31.7 t 3 8
  • 42. Summary and Conclusions The tectonic history of southern Sinai is considered to be one of the most important factors in the formation of the present tectonic-lithologic type uranium deposits.  The uranium deposits hosted in fluvial sediments, which generally consist of a sequence of conglomerates-sandstones-mudstones (fining upward sequence).  The refractory minerals in the basal conglomerates and upper parts of Adedia and Araba formations represent the primary source of uranium and its associated metals in the Paleozoic sandstones.  Another source of primary uranium is considered to be either the surrounding uraniferous granitic provenance, or detrital granitic and/or felsic volcanic rock fragments in the host sandstones.
  • 43. Summary and Conclusions  The tectonic-lithologic stack type deposits are in part considered the product of redistribution of uranium in permeable hosts along structures took place by younger tectonic processes.  The uranium mineralization are rarely located far from fault zones and are stacked up along different horizons of these permeable localities.  The tectonic-lithologic sandstone-type uranium deposits occur in significant quantities in the Cambro-Ordovician sandstones of G. Hemeyir, W. El Sahu and Ras Millan areas.  The large extension of the hosted sandstones indicates significant U-resources in these localities in Southwest Sinai.  Results point to the necessity for further exploration in detail.